BRPI0701839A2 - automated direct and indirect electrogravimetric process - Google Patents

Abstract

AUTOMATED DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS. It belongs to the field of the mining, electrochemical, electrothermal and industrial thermochemical industry, more particularly to an electrochemical electrogravimetry and thermoelectrogravimetric process applied to the production of high quality metals from the mineral industry being a new method of mineral earth treatment process, concentrated, for example CuFeS2 sulphide ore, Chalcopyrite, copper and iron sulphide, executed in the cell machines as shown in Figs 2, 3, 5, 8, 9, 12 to 19 and 117, of direct process execution and machines 21, 22, 50, 48 of the indirect process generally comprised in the flowcharts of Figures 28 and 29 and operational flowcharts of Figures 37 to 43, and can be better understood with a panoramic view from above visualizing Figure 32 illustrates the mounting of the working platform resulting in the gravimetric extraction of the constituent metals in the mineral earth and its electronic conjugation with the metallols such as sulfur, arsenic, tellurium, and the nonmetals of interest of the periodic table performed by the direct and indirect electrogravimetric process. This invention of process of how to extract the metals and their corresponding metallic hydroxide, directly via electrochemistry of electrogravimetry in electrogravimetric cell Mineral fig 2, 3, and indirectly via instant casting of mineral earth in Thermoelectrogravimetric Oven fig 21, 48, 50 resulting in complex alloy which is further decomposed by electrogravimetry its constituents are separated by this process from this primary ore of origin, together with the set of inventive machines represented in figures 1 to 120 annexed, of which the present DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS is carried out and these Electrogravimetry Electrochemical Cell machines and the thermoelectrogravimetric Oven with character Special features created by the inventing proprietor are illustrated in the accompanying industrial drawings of the figures described in this report for the purpose of this patent. According to the description of this process the production of high quality metal takes place in the mineral deposit itself which provides a summary of processes lowering ore treatment costs of which the following metal ore mineral lands are included in this process ranked first as the most difficult to be processed by today's industry but that by this automated direct and indirect electrogravimetric electrochemical process eliminates treatment problems both in technique and in the environment by achieving self-sufficiency in the production of high quality metals. these are possible, the direct and indirect electrogravimetric process easily handles ores containing metals, such as sulphides, phosphides, tellurides, arsenides, selenites, antithymers, some metals being combined with amethysts and not group 14, 15, 16 metals These are the complex elements that the mineral industry has the most benefit from as they are crystallized and totally insoluble in mineral acids are described by the industry as interfering, rebellious and refractory, hence the titular author developed through his experiences of It is a special way of decomposing this ore and extracting these metals easily without emitting toxic derivatives in nature reducing costs, seeing the possibility of deploying the system with technology in the industry being this unlike all other known processes that in this inventive process. and the unknown presented in this report is mainly able to decompose this crystallized and complex mineral earth by extracting metals in the presence of their interferents as the elements described above via electrogravimetry electrochemistry and thermoelectrogravimetry decreasing costs without emitting all derivatives. toxic in nature by delivering a noble metal end product to the market with high chemical composition purity with the industrial application of this Indirect and Direct Electrogravimetric Process purpose of the present invention. Current processes are known to treat only soluble elements such as the following sulfates, phosphates, Antimonates, Bromates, Arsenates, Chlorides, Nitrates In this process the groups described above are also processed and this other group more easily the oxides, borides, carbonates, nitrite, fluorides, or complex mixtures of all of these previously described above, also serves to industrial waste whose tailings are a complex mixture of heavy metals combined or not with metallics using technical effects such as those created in this process where manganese oxide can be purified, separated heavy metals and rare figs 120, and still be used for treatment of exemplary sewer we demonstrate the m complexes associated with sulfur ametal in the Chalcopyrite ore, which from this compound extends to all the other minerals, figure 34, 51, 115, CuFeS2, copper and iron sulfide in its composition but which in its complexity are extracted from electronic conjugation by this process separating from the nonmetals and amethel quality atoms in this mineral containing further metals such as zinc, cadmium, silver, gold, palladium, cobalt, nickel, gallium, indium, lead, antimony manganese, germanium, tin , bismuth, and others such as chromium, niobium, tungsten, vanadium, to a lesser extent joined with amethysts and nonmetals that through the techniques described in this report will be quantitatively separated by the DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS being collected in the compartment (1) or in the compartment. (2) from cell 2, and 3, and 12 to 19, according to the process stage performed ELETROGRAVIM PROCESS DIRECT ETHIC (182). Industrial processing of the sulphide mineral earth is performed without any treatment in the primary ore other than the primary grinding as finely ground as possible with the smallest grain that this ore (16) can be added directly to the MINERAL ELECTROGRAVIMETRIC CELLS described in this process. (182) as described in the flowchart of Fig. 28 and 29 where the extraction of the constituent metals of the ore is by electric force via electrogravimetry electrochemical illustrated more particularly in a panoramic way in Fig. 1 In this new process method created by the holder who extended his In opposite and audacious researches, the electrolyte can be complex of very varied composition and full of interfering and suspended solid material, being one of the inventive features that differentiates this DIRECT ELECTROGRAVIMETRIC PROCESS from the current known The Cells presented here as shown in the attached figures a est and document has been characterized by the direct process by extracting the metal directly decomposing the raw ground ore of CuFeS2 origin, Chalcopyrite illustrated in Figure 34, 51, 115 initially added to the cell being a novelty where 99% metal can be removed of purity fig 114, 116, and 119 DIRECT PROCESS (182); uses two cell models, namely STATIONARY AND MOBILE ELECTROGRAVIMETRIC CELL with inventive feature deferred specialties created by the holder The first so-called MINERAL STATIONARY ELECTROGRAVIMETRIC CELL illustrated in figures 2, 3, 5, 7, 8, 53 and 12 to 19 and 117, using the working methodology related to the DIRECT ELECTROGRAVIMETRIC PROCESS The other called MOVING ELECTROGRAVIMETRIC CELL illustrated in figures 9, 31, 55 which uses the same process methodology referring to the DIRECT ELECTROGRAVIMETRIC PROCESS but moving in motion on iron This process uses very low voltage voltages and saves time and speed. This process contains an operating secret created by the holder which together results in a differentiated technique in the operating process stages to be processed together with a automation of this whole system a, this automation program is all about gaining speed of production and remote control over long distances providing comfort in process control which makes it the brain of the process described and attached to this document, DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS AUTOMATION. Mineral earth is added to the viscous mud forming machine (48) of the ore (181), where it is conveyed by pumps to the electrode (13) which is a floor-shaped electrode of the machine compartment (1) illustrated in figure 2. , 3, 7, 8, 9, 12, 13, 14, 15, 16, 17, 19, 53, 55 of the MINERAL ELECTROGRAVIMETRIC CELL (3), this machine constructed of the shapes presented in this report has a dividing wall (9), which is more particularly illustrated in FIG. 4 with constructional changes as illustrated in FIGS. 54 and 57, the outer and inner wall forming a single electrolyte liquid retaining vessel is constructed of acid attack material being glass, plastic, rubber fig 2, 3, 5, 10, iron fig. 9, or concrete fig, 7, 8, 12, 15, 16, 19, internally lined in an appropriate tar or rubber bath with the wall (9), with split holes (52), fig 4, 54, 57, according to Fig. 54 contains inside nylon, and a sponge (246), inert to chemical attacks embedded in two walls constructed of plastic material, rubber, glass, and masonry with holes (247) according to Fig. 57 this wall (9) It is constructed of siphon-shaped masonry (52) that allows free circulation of electrolyte (14) throughout the cell by separating housing (1) from housing (2) so that it does not allow solid

Description

AUTOMATED DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS

The present patent relates to "AUTOMATED DIRECT INDIRECT ELECTROGRAVIMETRIC PROCESS" belongs to the field of the mining industry, electrothermal electrochemistry and industrial thermochemistry, or more particularly to an electrogravimetric and thermoelectrogravimetric process applied to the production of high quality metals from of the mineral industry being a new method of treatment of concentrated mineral earth treatment, for example the CuFeS2 sulfide ore, chalcopyrite, copper and iron sulfide, resulting in the gravimetric extraction of the constituent metals in the mineral earth separating from its electronic conjugation with the ametals sulfur, arsenic, tellurium, and nonmetals of interest by direct and indirect electrogravimetric process. This process invention of how to extract metals such as copper and its CuO oxide, hydrated CuOH, corresponding metal hydroxide, "directly" via Mineral Electrogravimetric Cell electrogravimetry electrochemical fig. 2, 3, and "indirectly" via instantaneous smelting of mineral earth in Thermoelectrogravimetric Furnace resulting in complex alloy which is further decomposed into stationary electrogravimetric cell and mobile wagon by electrogravimetry and its constituents separated by this process from this primary ore of origin, together with the set of inventive machines represented in the attached figures from 1 to 120, of which the present DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS is performed, and these Electrogravimetry Electrochemical Cell machines and the Thermoelectrogravimetric Oven with special characteristics created by the inventor holder are illustrated in the drawings. appended to the figures described in this report for the purpose of this patent.

According to the description of this process the production of high quality metal takes place in the mineral deposit itself, which provides a summary of processes lowering ore treatment costs of which the following mineral minerals of metal ores are included in this process: ranked first as the most difficult to be processed by today's industry, but that by this automated direct and indirect electrogravimetry electrochemical process eliminates treatment problems in both the technical and environmental environments. The elements of concentrated mineral earth, which are possible to treat, are these, which the DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS easily processes: ores containing metals, such as: sulfides, phosphides, tellurides, arsenides, selenites, antimonyeths, some metals being combined with the amethals and nonmetals of group 14, 15, 16, 17 of the periodic table. The complex elements that the mineral industry has the most beneficiation problems, as they are crystallized, totally insoluble in mineral acids, are described by the industry as interfering, rebellious, refractory, so the author has developed through his analytical experiments a special means of analysis. Extracting these metals easily without emitting toxic derivatives in nature decreasing costs, seeing the possibility of deploying the system with technology in the industry being this unlike all other known processes that in this inventive process, unknown by starting electrochemically directly from the Ore, presented in this report, is mainly able to decompose this crystallized and complex mineral earth Fig. 34, 115, extracting the metals in the presence of their interfering I, as the elements described above via electrogravimetry electrochemistry and thermoelectrogravimetric decreasing costs compared to current processes without emitting toxic derivatives, such as natural nature gases, delivering a final, metallic, noble product to the market with high chemical composition purity, with the industrial application of this direct and indirect Electrogravimetric Process, object of the present patent. . Current processes are known to treat only soluble elements, such as those described below: oxides, carbonates, sulfates, phosphates, antimoniates, bromates, arsenates, chlorides, nitrates. In this process also the groups described above and this other group are more easily processed: oxides, borides, carbonates, nitrides, fluorides, and complex mixtures of all previously described above.

For example, we demonstrate the metals associated with the sulfur ametal complex, in the Chalcopyrite ore, figure 34, 51, 115, CuFeS2, copper and iron sulfide in their largest composition, but in their complexity, are extracted from their electronic conjugation by This process separates from the nonmetals of quality, atoms in this mineral, containing other metals such as zinc, cadmium, silver, gold, palladium, cobalt, nickel, gallium, indium, lead, manganese antimony, germanium, tin, bismuth, and others such as chromium, niobium, tungsten, vanadium, to a lesser extent, joined with miscellaneous nonmetals and metals than through the techniques described in this report, will be quantitatively separated by the DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS.

DIRECT ELECTROGRAVIMETRIC PROCESS (182)

Industrial processing of the sulphide mineral earth is carried out without any treatment in the primary ore other than primary milling, and milled as finely as possible with the smallest possible particle size directly in the described MINERAL ELECTROGRAVIMETRIC CELLS. in this direct process 182 as described in the flow chart of FIG. 28 and 29, where the extraction of the constituent metals of the ore is by electric force, via electrochemical electrogravimetry illustrated more particularly from were panoramic in fig.1.

As is well known to those skilled in this art, there are currently numerous electrochemical processes and different types of old electrochemical electrochemical cells already known, as illustrated in FIG. 56 and its varied characteristics, however, all start from a well-known refining process, that is, from an already solubilized metal and basic salt already constituted from a single metal, solubilized in acid, and in a base such as sodium and potassium, to electroplating being known in advance to refine metals, which require a very clean electrolyte liquid, which may have come from a soluble metal salt with a single soluble metal of a single, definite composition, and technicians in this area always recommend an electrolyte. of clean and filtered metallic salt, none of these processes, part of a decomposition of the ore in its natural state, taken from the deposit with only the primary grinding that is the case of this new inventive electrochemical process.

Therefore, inversely in this new process method created by the proprietor, who extended his research in opposite and audacious directions, the electrolyte must be complex, of very varied composition, full of interferents and suspended solid material, that is, from the ore in its natural state. with only the primary grinding being this one of the inventive characteristics that differentiates this DIRECT ELECTROGRAVIMETRIC PROCESS, from the present known ones. The Cells presented here, as shown in the figures attached to this document, are characterized by performing the direct process starting from an extraction of the metal directly from the raw, ground CuFeS2, chalcopyrite origin, illustrated in figure 34, 51, 115, initially added to the electrogravimetric cell of fig. 2, 3, in the compartment (1), and removing the metals of interest in the compartment (2), extracting the soluble solids in the electrolyte (14), which is an innovation and which in the face of this invention proceeds with automation command, described in this report, ending with the delivery of a noble product to the market as illustrated in fig. 114, 115, 116, 118, 119, 120.> DIRECT PROCESS (182) uses two cell models namely:

STATIONARY AND MOBILE ELECTROGRAVIMETRIC CELL, inventive feature with differentiated specialties created by the holder. The first denominated MINERAL STATIONARY ELECTROGRAVIMETRIC CELL, illustrated in figures 2, 3, 5, 7, 8, 53 and from 12 to 19 and 117, using the working methodology referring to the DIRECT ELECTROGRAVIMETRIC CELL CELL, illustrated in Fig. 9, 31, 55, which uses the same process methodology as for the DIRECT ELECTROGRAVIMETRIC PROCESS but with movable characteristic, working in motion on iron triles, as much as the other, it uses the working methods as illustrated by the flowchart of fig. 28, 29, and 37-41, representing the basic operating method and compliance with work stages.

This process uses very low voltage voltage, saves time and speed. This project contains an operating secret created by the holder that together results in a differentiated technique, in the stages of operation process to be processed together with an automation program, of this whole system, this automation program sums up in gaining speed of production and remote control over long distances, providing comfort in process control attached to this document, DESCRIPTION OF DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS AUTOMATION. To better understand this process it is necessary to add dividing titles and numbering the items for easier understanding as follows. The set of machines that make up this inventive character is illustrated in the following figures:

DESCRIPTION OF THE FIGURES

fig. 1 shows the execution of DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS in horizontal and panoramic perspective can be viewed with motion printing.

fig. 2 shows in explosive perspective the first Cell created by the inventor being the Mineral Stationary Electrogravimetric Cell as a small analog laboratory apparatus utilizing external electrical force and its differentiated details as the starting piece.

fig. 3 shows in explosive perspective the digitalized Mineral Stationary Electrogravimetric Cell with adaptation of a digital panel of which the gravimetric scale is also digital.

fig. 4 shows in explosive perspective the wall that will be used to divide the Cell into two compartments (1) and (2) .fig. 5 shows the Mineral Stationary Electrogravimetric Cell in horizontal perspective using internal electrical force.

fig. 6 shows in horizontal and panoramic perspective detailing the direct process.

fig. 7 shows in perspective the section of the Mineral Stationary Electrogravimetric Cell being a claim model of differentiated compartment,

fig. 8 shows in a three-dimensional perspective of a circular shape the Mineral Stationary Electrogravimetric Cell being a claim model.

fig. 9 illustrates in perspective of vertical section the Mobile Electrogravimetric Cell Wagon.

fig. 10 shows a simplified horizontal perspective drawing of a small assembly with simple utensils for practical testing.

fig. 11 shows the figures of the tests performed by the proprietor and their results.

fig. 12 shows in horizontal perspective an industrial assembly of the Mineral Stationary Electrogravimetric Cell for treatment of thousands of tons a day in a first stage, direct process.

Fig 13 shows in horizontal perspective an industrial assembly of the Mineral Stationary Electrogravimetric Cell in a second stage of operation according to the direct process.

fig. 14 shows in horizontal perspective an industrial assembly of the Minerai Stationary Electrogravimetric Cell in a third stage, direct process.

fig 15 shows in horizontal perspective the industrial assembly of the Mineral Stationary Stationary Electrogravimetric Cell in infinite series from left to right.

Fig 16 shows in horizontal and enlarged perspective the industrial assembly of the Mineral Stationary Stationary Electrogravimetric Cell in infinite series from left to right.

Fig 17 shows in horizontal perspective the three main stages of the Stationary Electrogravimetric Cells performing the direct process.fig. 18 shows in horizontal and three-dimensional perspective how the terrain must be prepared for the construction of the Stationary Mineral Stationary Electrogravimetric Cell Industrial Platform with prevention and safety against chemical leakage accidents with 10 ° grade slope terrain.

fig. 19 shows in horizontal and vertical perspective the cell in ore containment storage and filtration of electrolytes in underground tanks.

Fig. 20 shows in panoramic perspective the main machines performing the indirect process.

fig. 21 shows in horizontal perspective the thermoelectrogravimetric oven that corresponds to the indirect process.

fig. 22 shows in horizontal and panoramic perspective the ore digestion process to operate at high production speed in the indirect process.

fig. 23 shows the electronic electro circuit that feeds the Mineral Stationary Electrogravimetric Cell and the Mobile Wagon Electrogravimetric Cell.

Fig. 24 shows a connection circuit of the digital data displays of the Mineral Stationary Electrogravimetric Cell and the Mobile Wagon Electrogravimetric Cell.

fig. 25 shows the electronic circuit of the indirect process thermoelectrogravimetric oven.

fig. 26 shows in perspective the Five-Stationary Stationary Electrogravimetric Cell, powered by five external Ed-force electrical sources with different and variable voltage values that operate in the execution of direct and indirect processes.

fig. 27 illustrates the power circuit of the Thermoelectrogravimetric furnace which provides for indirect process plasma firing.

fig. 28 illustrates the basic flowchart of the DIRECT AND INDIRETO ELECTROGRAVIMETRIC PROJECT. 29 illustrates the flowchart of the DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROJECT with detailed follow-up.

fig. 30 shows the reservoir tangue of process liquid derivatives which has the property of filtering and precipitating solids by regenerating the acid electrolyte and correcting its PH.

fig. 31 illustrates the serial operation moving on rails of the Wagon Mobile Electrogravimetric Cell.

fig. 32 shows a top and panoramic view of the assembly of the Mineral Stationary Electrogravimetric Platform and its set of direct and indirect machines and processes.

fig. 33 shows a horizontal view of the differentiated construction of compartment (1) of the Mineral Stationary Electrogravimetric Cell and slope to hold liquids in detail, operates in ore treatment and refining of complex alloys of the direct and indirect process.

fig. 34 illustrates the photo of CuFeS2 chalcopyrite ore that is decomposed electrogravimetrically with execution in the direct and indirect process, fig. 35 shows the photo of the red CuO oxide copper metal extracted in an electrogravimetric cell, direct process.

fig. 36 illustrates the display boards that provide accurate digital panel information that transmits the chemical and electronic physical information from the digitized and automated direct and indirect process.

fig. 37 illustrates the flowchart of operation of the first basic stages of the direct process.

fig. 38 illustrates the basic operation flowchart of the second stage of direct process execution

fig. 39 illustrates the flowchart of the basic operation of the third stage, direct process.

fig. 40 illustrates the flowchart of the basic operation of the fourth stage, direct process.

fig. 41 Illustrates the flowchart of the basic operation of the fifth stage, direct process. 42 illustrates the flow chart of the execution of the first basic stage of the thermoelectrogravimetric process.

fig. 43 illustrates the high speed flow diagram of the rotary kiln thermoelectrogravimetric process.

fig. 44 illustrates the paper electrode pressed and impregnated with graphite and paraffin.

fig. 45 illustrates the cyanide underground tank and its panoramic operation.

fig. 46 illustrates the supply of the mineral electrogravimetric cell

fig. 47 illustrates the hydraulic electrolyte filter by discarding waste by pneumatic systems

fig. 48 illustrates construction of rotary kiln running high speed indirect process system

fig. 49 illustrates electrode position and electrolyte liquid level in the stationary mineral electrogravimetric cell.

fig. 50 illustrates the thermoelectrogravimetric mineral decomposition furnace performing the indirect process with the aid of two lateral electrodes,

fig. 51 illustrates chalcopyrite ore and its complex changes freshly extracted from the surface cover of a newly discovered mine.

fig. 52 illustrates the crystalline form of complex bonding of the constituent atoms of chalcopyrite ore and how to apply the electro-physical forces of decomposition frequency to electronically bonded molecules.

fig. 53 illustrates the mineral stationary electrogravimetric cell being controlled by a control room.

fig. 54 illustrates the wall dividing into two compartments (1) and (2) constructed differently.

fig. 55 illustrates the supply, processing and unloading of production and the disposal of tailings from the mobile electrogravimetric cell mineral wagon.

fig. 56 illustrates the ancient inventions of analog electrogravimetric apparatus simply for the determination of metal and a soluble salt. 57 differently illustrates the siphon-shaped dividing wall.

fig. 58 illustrates in three-dimensional form the beginning of construction of the mineral stationary electrogravimetric cell.

fig. 59 illustrates the relative command point in a graph that has an effect on the direct and indirect process machines for the automation system,

fig. 60 Illustrates the scan fetch variation at synchronization run in a hidden page graphic that synchronizes the command relativities of the automation process.

fig. 61 illustrates the start of execution of the automated direct and indirect electrogravimetric process displayed on the control board on the remote computer monitor.

fig. 62 illustrates a larger dimension of the chart page which on its sides is increasing and infinite.

fig. 63 illustrates a command point found on the chart page that generates command effect on process machines.

fig. 64 illustrates the circuit having the property of informing the value of the back voltage and the discrete elements that emit power signal per second and through switches cause this energy that initially interferes with the decomposition process to be returned for the benefit of the process,

fig. 65 illustrates the elements of interest separated by the direct and indirect electrogravimetric process.

fig. 66 illustrates in a panoramic flowchart the processes that make up the automated direct and indirect electrogravimetric process with the soft program as a brain.

fig. 67 illustrates the cpu and the remote computer and the internal command computer controlling the entire process system.

fig. 68 illustrates the division of energy in kwh that each process consumes,

fig. 69 illustrates computers that perform different tasks in supplying, stocking, extracting, and meeting demand as other related minor activities. 70 illustrates in a flowchart the computers that perform direct process tasks.

fig. 71 illustrates in a flowchart the computers that perform the tasks of ore melting and removing the alloys from the indirect process.

fig. 72 illustrates in a flowchart the computers that perform the high speed process tasks of the rotary kiln, digester and capacitors.

Fig. 73 illustrates the command frames on a computer monitor that start the execution of the direct process.

Fig. 74 illustrates the chart that defines the amount of ore to be processed and its physical and chemical data.

fig. 75 illustrates the optional switchboards for choosing the element and the supply of process machines.

fig. 76 illustrates the table defining the supply, filtration, collection of derived gases and vapors, and tailings removal.

fig. 77 illustrates the control board which will indicate the physical data of the stationary and mobile cell that will be used for the execution of the process,

fig. 78 illustrates the energy control board expended to perform the supply process.

fig. 79 illustrates the quantity and volume control panel and the energy in KWh to supply the machine with the ore to be processed.

fig. 80 illustrates the chemical option switchgear of the electrode construction element to be supplied to the housing (2).

fig. 81 illustrates the surface option switchboard and the amount of electrodes to be supplied.

fig. 82 shows on the control board the amount of energy that will be supplied to perform the electrode supply.

fig. 83 illustrates the automation command frame that defines the element that will be added to the machine to perform the process.

fig. 84 illustrates the table defining the weight and volume percentages of the elements that will be added to the machines to perform the process. 85 illustrates the control board defining the energy that will be consumed to supply the elements described in the table of FIG. 84.

fig. 86 illustrates the automation command box that defines which element to extract.

fig. 87 illustrates the chart that defines the initial physical and chemical data to perform the scan that contains the electrophysical and chemical quantities that allow the synchronization of the process for perfect execution for maximum performance.

fig. 88 illustrates the optional frame for choosing the element to be processed.

fig. 89 illustrates the frame with the data of the element on which to scan to synchronize commands.

fig. 90 illustrates the scan result table that establishes a synchronization of values of physical and chemical quantities to begin the execution of the direct and indirect process.

fig. 91 illustrates the optional framework for choosing the initial meaning of the indirect process.

fig. 92 illustrates the control panel of the thermoelectrogravimetric oven.

fig. 93 illustrates the control board of the energy to be consumed by the thermoelectrogravimetric furnace.

fig. 94 illustrates the control panel of the thermoelectrogravimetric rotary kiln.

fig. 95 illustrates the control panel of the energy that will be consumed by the rotary thermoelectro-gravimetric device.

fig. 96 illustrates the control board defining the digester supply.

fig. 97 illustrates the control board of the energy that will be consumed to supply the digester until the end of the process.

fig. 98 illustrates the condenser operations control board.

fig. 99 illustrates the control board of the energy that will be consumed for condenser operation.

fig. 100 illustrates the control panel of the liquid pumping system by adding and removing from the machines. 101 illustrates the automation control board of the energy that will be consumed by the pumping system.

fig. 102 illustrates the control panel of the hydraulic and pneumatic filtration system defining what should be retained.

fig. 103 illustrates the control board of the energy that will be consumed to filter a particular compound.

fig. 104 illustrates the control panel of the hydraulic and pneumatic system.

fig. 105 illustrates the control panel of the energy that will be consumed to perform the supply, removal, filtration, slag disposal, tailings operations.

fig. 106 illustrates the control panel of the hydraulic and pneumatic system for complex alloy filling by removing and adding to machines,

fig. 107 illustrates the control board of the energy that will be spent to perform the complex hydraulic and pneumatic transport of the alloys.

fig. 108 illustrates the control panel for the carriage of tailings and slag on trucks.

fig. 109 illustrates when commanding the energy that will be consumed to transport tailings and slag at a given time.

fig. 110 illustrates the control board defining the storage system for liquid solids and gases and derivatives.

fig. 111 shows the control panel of the energy that will be consumed to perform the stockpiling.

fig. 112 shows the framework that monitors and meets demand.

fig. 113 shows the table of the energy consumed to meet the demand.

fig. 114 shows the electrode (5) taken from the housing (2) of the electrogravimetric cell charged with copper metal and oxidized copper CuO in valence state 1.

fig. 115 shows the sulphide ore with agglomerated crystals of golden color included in silicate.

fig. 116 shows the electrode (5) taken from the housing (2) of the adhered copper electrogravimetric cell in the shiny metallic state.fig. 117 shows the stationary electrogravimetric cell in panoramic perspective viewed from above and underground constructed with horizontal view,

fig. 118 shows the copper metallic precipitate and copper hydroxide is poured over a plain paper.

fig. 119 shows the enlarged precipitate where you can see crystallized copper metal flowers and copper metal hydrated amorphous hydroxide on the enlarged paper being the result of the completely soluble noble product for numerous industrial applications of 99% purity that must be delivered to the market given the demand.

fig. 120 shows the noble and rare metals retained in compartment (1) by the direct and indirect process in the first and second stage of the process extracted in the fourth stage and withdrawn in the fifth stage and melted in a vacuum reduction thermoelectrogravimetric furnace of fig 21. Understanding the Introduction above and the presentation of the illustrated industrial design figures of this process and their indicative items begins the DETAILED DESCRIPTION OF THE DIRECT (182) AND INDIRECT (183) ELECTROGRAVIMETRIC PROCESS.

In figure 1 we see the direct and indirect process presented in a panoramic way, distinguishing the sense of applied methodology, in which: the complex mineral earth, eg chalcopyrite, more particularly illustrated in figure 34, composed of the closest molecular formula of CuFeS2, copper and iron sulfide. It is extracted from the mine and transported by trucks Fig 1, (37), to a crusher and mill (38), dumped into a coiled tube (46), and conveyed towards one of processes (182) and (183). , determined by the automation program. This sense of direct and indirect process is chosen through predetermined quantitative knowledge of the molecular chemical constituents of mineral earth. If the ore has a very high silicate and earth metal content of group 8 and 10 of the periodic table, it should be processed by the direct process after finely ground. If the ore is concentrated and contains insignificant low silica content and a non-earth metal content of group 11 and 12 of the periodic table of economic interest, it should be processed by the indirect process, which is faster in extraction. These two processes, and even more stages, can be performed together, processing numerous types of varied ores, assembled in the same industry as a platform called the Mineral Electrogravimetric Platform more particularly detailed in Fig. 32.

Taking the direction of the DIRECT PROCESS the mineral earth is added in the ore viscous slurry forming machine (48) (181). where it is carried by pumps to the electrode (13), which is a floor-shaped electrode of the machine compartment (1) illustrated in figure 2, 3, 7, 8, 9, 12, 13, 14, 15, 16, 17, 19, 53, 55 of the MINERAL ELECTROGRAVIMETRIC CELL (3), this machine constructed of the shapes shown in this report in the accompanying figures has a partition wall (9), which is more particularly illustrated in FIG. 4, which allows the electrolyte to circulate through a siphon (52), with alterations in construction as shown in Figure 54, which is a wall constructed of plastic, concrete, rubber (245), with holes (247), which allows passage The electrolyte (14) and the dug inside are placed with a coarse sponge alone or wrapped in nylon cloth, such as umbrella cloths, inert to acid attacks, allowing the electrolyte to pass freely and not allowing it to pass through. suspended ore to maintain a single PH chemical state throughout the cell. In fig. 57 this partition wall, which is a different form of construction, has a differentiated siphon opening (52). The outer and inner wall of the cell forming a single container (3) for retaining the electrolyte chemical liquid (14) is constructed of acid attack material, being of glass, plastic, rubber fig. 2, 3, 5, 10, iron fig. 9, concrete fig, 7, 8, 12, 15, 16, 19, internally coated in a suitable tar or rubber bath, with the dividing wall fig. 4, 54, 57, with straight or siphon-shaped holes 52, as shown in FIG. 54 contains a chemical attack sponge 246 embedded in two walls constructed of plastics material, rubber, glass, masonry, with holes 247 as shown in FIG. 57 this wall (9) is constructed of siphon-shaped masonry (52) which allows free circulation of electrolyte (14) throughout the cell separating compartment (1) from compartment (2) to that does not allow the suspended mineral solid (16) added in compartment (1) to pass into compartment (2), establishing a single PH chemical state throughout the cell.

In compartment (1), the ore decomposition (16) is processed after the slow and controlled electrolyte addition technique (14), which is composed of an acid formed by the largest constitution of this processed aser mineral earth. in its complexity from the mineral earth fig.1 item (37) extracted from the deposit, which in this report is exemplarily an electrolyte composed of a complex mixture of metals and nonmetals and ametals of group 8, 9, 10, 11, 12, 14, 15, 16, 17 described in the international periodic table being the salt formers of sulfur, phosphorus, arsenic, antimony, tellurium, bromine, sludge, chlorine, fluorine, nitrogen, and a content of various alkaline earth metals constituting the chalcopyrite described. formerly forming a complex electrolyte of: sulphates, phosphates, arsenates, bromates, antimoniates, tellurides, iodides, chlorides, nitrates, fluorides, these elements being metametal and nonmetal metals and some alkali metals t errors in the mineral earth, to a greater or lesser extent, and the largest proportion will be in this report, exemplarily according to the tests performed, that of sulfur, which will form a complex electrolyte, in its largest composition of the basic molecular formula of; sulfuric acid H2SO4, alkaline earth metal sulfate, such as NaSO4 KSO4, which will achieve a high acidity during numerous process operations, reaching a certain pH value. Unlike other cells on the market, this electrolyte cannot be mechanically moved at the time of performing these inventive process stages so as not to suspend the solids of the compartment (1), the only movement allowed is the movement exerted by the natural release of the molecules. In the form of gas in the electrodes, these gases will be absorbed by the metallic chemical elements of the ore and electrolyte attracted by the electric force Ed of decomposition voltage.

In the first stage that is performed particularly on the Mineral Electrogravimetric Cell, as in a laboratory analysis process, illustrated in figure 2, 3, and an industrial process for treating thousands of tons of mineral earth, daily illustrated in figure 12, 13, 14, 15, 16, 17, 19, and the Mineral Wagon Mobile Electrogravimetric Cell, illustrated in Figure 9, will have the initial addition of electrolyte composed of a 35% mixture in water of Sulfuric Acid and Sodium Sulphate. Sulfuric acid H2S04 will have an addition of 20%, sodium sulfate NaSOt 15%, and water H2O 75%, and in the next operations of the electrogravimetric process will be reused from the same electrolyte that each operation will become more dense and concentrated due to the absorption of the metals and nonmetals removed from the mineral earth by this process, which increases the acidity, being good for the process performance, also increasing the decomposition speed by becoming more conductive of electricity, which should electrolyte in its regeneration, simply be filtered, corrected, precipitating other excessive constituents electrogravimetrically, in order to make room for solubilizing in the next stages the repetitive metallic elements and derivatives, in the next supply of electrogravimetric extraction tank reservoir operation of fig. 30. The electrolyte chemical compositions that can be used are those shown in the table below, bearing in mind that the preferred and highest yielding compound is sulfuric acid, added purely or with small amounts of sodium, which transforms the ametals into acids and sulfates. By absorbing and increasing the acidity in each operation, improving the energy yield that the more the electrolyte is acidic, will decrease the electrical resistivity of the electrolyte by ohms, increasing the decomposition power decreasing the Ed force which gives energy gains KWh. <table > table see original document page 19 </column> </row> <table>

Continuously the ore (16) is technically seated and controlled on the electrode (13) is in turn moistened after the addition of the electrolyte. After the beginning of the working march, becoming partially conductive, slowly participating in the electrochemical reaction, forming a negative chalcopyrite electrode, which is referred to in this process as the SULPHET ELECTRODE (SULPHIDE CATHOD), which gradually and fully participates. faster reaction time, thus being decomposed by the chemical actuation of the elements released by external direct current electrogravimetric electric force supplied by the circuit shown in figure 23. P This circuit contains a key (115), polarity inverter, which must be connected according to the electrical polarity defined for each electrode, according to the process operation stage. Electricity is conducted to the cell by the cables (10) of the housing (2), connected to the electrode (5), of a metallic chemical character, when the polarity is negative, and of an inert chemical character, when the polarity is positive, the connection. (11), connected to the electrode (13), which is a floor, constructed of inert material, good conductor of electricity such as: graphite blocks, content around 80%, and high purity silica, homogeneously mixed and finely ground, A binder such as tar is added around 0.5% pressed, in the form of high-temperature sealing block blocks. Silicon carbide blocks are also used to be used with electrolytes of various formulas, as well as metal lead plates, which can have positive polarity when the electrolyte is only sulfuric acid. It begins the decomposition of mineral earth in compartment (1), oxidizing the sulfide ore in a first stage Fig. 12 and 13, where the polarity and the chemical constitution of the electrodes was previously defined and the positive polarity will be with the electrode (5). ) which must be inert like the graphite paper electrode 193 described in FIG. 44 of housing (2) constructed of suitable acid attack resistant paper (213) surface-coated with a paraffin-impregnated graphite layer (214) containing a hook (212). The sulfide electrode (1) of compartment (13) will in turn have negative polarity, which at the end of the process leaves the ore with a black and pigmented color of CuFeOH- iron hydroxide in the first stage, reversing the polarity in the second stage removing the metals of interest in the case Copper leaving a red flesh-colored metal in compartment (2) and a sandy tailings residue in compartment (1) containing heavy and noble metals.

FIRST STAGE OF DIRECT PROCESS (182)

At this first stage executed in the cell described above fig. 2, 3, 5, 7, 8, 12 to 19, being further detailed in the flow chart of fig. 37 and illustrated in fig. 6 and 12, the ELECTRODE (5) of compartment (2) will become an anode, so it must be of chemical composition of a suitable material which is not attacked by acidic elements. The inventive character graphite or silicon carbide or pressure impregnated paper with paraffin and graphite illustrated in Fig. 44 in this first stage or of lead plated, nickel, stainless steel, platinum plated according to the applied electrolyte. This electrode has a long working life because it is inert to the chemical attack and is more particularly chosen according to a basic table as follows: TABLE FOR CHOOSING ELECTRODE CHEMICAL ELEMENT REFER TO FIRST STAGE ELECTROLYTE (182)

<table> table see original document page 21 </column> </row> <table>

It is hung on hooks of positive polarity in the compartment (2) by hydraulic and pneumatic machines and should be left until the first stage is completed and replaced by copper electrodes that are thin sheets of 3 to 5mm thickness in the second. internship.

ELECTROLYTE (14) Subsequently, the electrolyte which is to be defined according to the quantitative and qualitative prior analysis of the mineral material, which in the case of chalcopyrite may be acidic, such as sulfuric acid H2SO4 purely in 35% percent, is then added. Basic alkaline like NaSCM sodium sulfate also 35%, or even a formula composed of these two elements being more acidic than basic composed of 20% sulfuric acid, and 15% sodium sulfate, this electrolyte has room to absorb Soluble in its constitution 40% of the quantitatively complexed nonmetals and nonmetals in the ore to be decomposed by this inventive process, the electrolyte may still be as indicated in the table above the first stage and the table below for the second stage.

ELECTRODE (13)

The electrode (13) of compartment (1), with negative polarity, has a cathode character and the mineral earth sitting on this electrode that is a floor will have negative polarity character attracting the alkaline metals of the atoms of: hydrogen H2, sodium Na Potassium K, at this stage the hydrogen atoms and potassium sodium will be born on the electrode surface (13) below the mineral earth which during the 48 hour process penetrate all the negative polarity mineral earth, combining with the Metals, completely oxidizing the CuFeS2, CuS and ^ FeS ore metals into CuOH-FeOH- hydroxides and Oxides, and the nonmetals and non-metals transforming into soluble acids pass into the solution, absorbed by the electrolyte, CuFeS2 + H2O + IH2SO4 + electrical force Ed = H2 + SOH- + H2O + CuOH- + FeOH- + IH2SO4 = 2H2SO4 + H2O, resulting in an acid sulfur electrolyte in this first stage, in this first stage, the material mi neral becomes pigmented black fig, 13 and 17, 65, (293), composed of dense insoluble hydroxide of iron and copper, because it is negative and is in compartment (1), negative polarity, which remains in this chemical state until the beginning of the second stage of the process, and the nonmetals and the metal elements become soluble in the electrolyte increasing their concentration and conductive electrical capacity and chemical state of PH value, this being a first stage of the direct electrogravimetric process. Finishing the march of this first stage increased the high complex concentration of ametals and nonmetals in the electrolyte, the largest constituent being sulfur ametal, extracted from sulfuric acid ore when the electrolyte is acidic or basic H2S04, NaS04.

ELECTROCHEMICAL REACTIONS DIRECT PROCESS

FIRST STAGE

FIRST STAGE: compartment (1) negative and compartment (2) positive.

Water + sulfuric acid + sodium sulfate + ore + electricity = (H2O + 2H2SO4 + 2NaSÜ4 + 4CuFeS2) + (Ed- + Ed +) =

The. Comp. (2) positive electrode (5) Ed +. (S04- + S04- + O2-) + (Ed +) = (O2- + 2S04-) + 2H20 = 2H2S06

B. Comp. (1) negative electrode (13) Ed-. 4CuFeS2 + H2O + 2H2SO4 + 2NaS04 + (Ed- + Ed +) = 4CuFeS2 + 2H2O = Sulphide or chalcopyrite cathode electrode (13) ore (16)

4CuFeS2H- + 2H2SO4 + 2NaSÜ4 + H2O + (Ed-) = 4CuFeS20H-

4H2 + 2Na2 + 20H- + (Ed-) = (2CuOH- + 2FeOH -) (4CuFeOH2-) Hydroxide = Element sought.

{(2CuFe'S20H-) + (2HSÜ2-) + (NaSÜ2-) + (NaSOH-)} + {(H2O +) + (NaSOH-)} + (Ed-) =

(CuFeOH- + NaSOH-) + (HSO2 + H2 + Na + H2O) + (Ed-) =

H2SO8 + NaSOs + H2O + 2CuFeOH-Hydroxide = element sought

SECOND STAGE OF DIRECT PROCESS (182)

Compartment (1) positive and compartment (2) negative.

This process stage is more particularly illustrated in figures 13 and 17 where we change the polarity of the electrodes by changing the direction of the electric current by reversing the polarities via the switch (115) of the circuit illustrated in figure 23 the electrode (5) of the housing (2). will have the negative polarity and should be replaced at this second stage by electrodes of copper or other group 11, and 12 of the periodic table, metal sheets for the extraction of copper, zinc, silver, gold, cadmium, platinum , mercury according to the following basic table.

TABLE FOR CHOOSING THE ELECTRICAL CHEMICAL ELEMENT FOR THE ELECTROLYTE USED FOR THE SECOND STAGE PROCESS (182) Formula Electrolytes Anode Cathode

<table> table see original document page 24 </column> </row> <table> <table> table see original document page 25 </column> </row> <table>

This electrode which is hung on hooks connected to the digital scale (6) fig. 23, which records in a digitalized and gravimetric manner the metallic deposit on the electrode (5) of each element separately and can witness the deposit by increasing the reading of the digits in the table (21) and (28) of the panel (36) illustrated in the figure (3 ) and figure 36.

EXTRACTION OF METALS ELECTROCHEMICAL REACTION FROM SECOND STAGE OF DIRECT PROCESS (182)

Starting the second stage march as shown in the flow diagram of fig. 38 through key (31) the electricity at Coulomb with a predetermination of the electrochemical decomposition voltage Ed calculated according to the attached automation description, seen in the reading of table (17), precisely established by key (32) of the power supply of fig. 23 of the coil (111), which generates a voltage and power effect on coil (114), which powers the electrogravimetric cell circuit. This voltage is established through a predetermined calculation of the equation that is obtained from proportional chemical physical data described later in the descriptive automation report p. 62. This Ed decomposition electric current, which passes through the conducting electrolyte which has a certain electrical resistivity of the electrochemical decomposition Rd, seen in the reading of the table (21), influence on the production velocity being proportional to the electrolyte temperature ° Cd, and The chemical constitution of the electrolyte and its PH value, as seen in the reading of the chart (27), this physical property of the electrolyte is defined by its chemical composition that becomes variable and complex throughout the operation because it becomes more conductive as others solubilized ametal chemicals, concentrate the solution. This electric current is controlled manually or automatically via the armature (109) and inductor (110) shown in figure 23. When the electrochemical decomposition voltage is determined by means of automation calculations, travel is initiated by the switch (31). ), the oxidized metals begin to participate in the electrochemical reaction with positive polarity character in compartment (1), illustrated in figure 13. The hydroxide of the metals formed in the first phase FeOH- and CuOH-dc black and pigmented fig. 65 (293), becomes positive FeOH + and CuOH +, influenced by the continuous applied polarity, begins to decompose attacked by SOH-, SO2, in compartment (1), transforming into soluble sulfates. At the top of the electrode (13), the nascent atoms of the nascent state attracted by positive electric charge such as sulfur SOH-, which attracted by positive charge combine with the previously insoluble FeOH and CuOH hydroxides, now form another salt, composed of soluble CuS04 and FeS04 which are broken by the external electrical force Ed, migrate in the opposite direction, the Cu and Fe metals, to the compartment (2), adhered to the electrode (5), where it deposits the metals of group 11 and 12, The group 15, 16, 17, SOH-ametals of the periodic table migrate to the positive pole and return to the sulfuric acid solution. In this compartment (2), they can deposit in two distinct gravimetric forms in the form of metal adhered to the electrode (5) fig. 116, recording its metal production weight by the digital gravimetric scale (6) fig. 36 and oxidized hydrated as a metal hydroxide of interest which was previously requested by the automation program illustrated in Fig. 35, 119, (49), (344) as CuO, according to the decomposition stress determined by the automation program described herein. attached document p. 62. This voltage applied to the electrode (5) extracts these metals in a metallic manner leaving the common group 8, 9, 10 earth metals soluble in the solution (345) and can be otherwise extracted at another sixth stage, like dense, shiny metallic iron or hydroxide. It may be better understood according to the flow chart of FIG. 38, for the second stage. The other metals in group 8, 9, 10, 11, such as platinum, ruthenium, rhodium, iridium and noble heavy and qualitative gold in turn remain inert as insoluble hydroxides until the fourth stage to be extracted. Upon completion of the run and time of metal extraction in the second stage, switch (32) of panel 36 of FIG. 3

Second stage: Compartment (1) positive Ed + and compartment (2) negative Ed-.

Water + sulfuric acid + sodium sulfate + copper and iron hydroxide. (2H2Ü + 4H2SÜ4 + 2NaSO4) + (6CuFeOH2-) + (Ed- + Ed +) =

The. Enclosure (1) Ed + positive electrode (13)

(H2 ++ 0 - + 2H2 ++ S04 - + 2Na ++ S04 - + 6Cu ++ Fe ++ OH2-) + (Ed +) = (2SÜ4 - + 2SÜ4 - + OH2-) + (Fe + + Cu +) (Ed +) = (O2- + 4SÜ4 -) + 2H2 O = 4H2SO6 + NaSÜ4 + 6CuFeOH2- = C112SO4 + Faith2SÜ4 + CuSO4 + NaCuSOs + 2H2O

B. Compartment (2) Negative electrode Ed- (5) Extraction of wanted element Cu + .CU2 ++ S04 - + Fe2 ++ S04 - + CuS ++ 04 - + Na ++ Cu ++ S08 - + H2 ++ SOe- + 2H2 ++ 0 - + (Ed-) =

(H2 + Fe2 + Cu2 + Na2 + H2O) + (H2SO6 + NaSÜ4) + Ed- = (+ CuOH- + NaOH-) + (FeSÜ4 H2SO2 + H2O) + (Ed-) =

FeOH + CuOH- + NaSÜ4 + H2SO4 + H2O + O2 Cu-OH- + FeS04 + NaSÜ4 + H2SÜ4 + H2O + O2 + (Ed-) = Decomposition stress to break only the attractive strength of copper sulphate by extracting copper and leaving the iron in the solution.

Cu-OH- + Cu-O- + (Ed-) = 6Cu + + 6CuOH +, copper oxide and inert metal hydroxide, element sought and extracted in compartment (2) whether or not adhered to electrode (5), fig. 114, 116, 119.

THIRD STAGE OF DIRECT PROCESS (182) COLLECTION OF PROCESSED ELECTROLYTE CONTAINING DERIVATIVES

Illustrated in the flowchart of Fig. 39, the panel cell power switch 31 of Fig. 3 and 36, either automatically or manually, the electrolyte is slowly removed by separating into a reservoir 151 illustrated in FIG. 30 collected in the housing 147 which will be properly filtered by the filter wall 156 and by filters. of hydraulic system Fig. 32, filter 81, stored in the reservoir fig. 45, (147, 149, 148) fig. 203, 202, fig. 19 and later reused at the beginning of another first stage. After all this mineral earth processing, the tail (82) is withdrawn into a tank (151), squeezed (79) by the hydraulic piston (78), extruded out by the piston (77). The solubilized derivatives precipitated by this process in the reservoir electrolyte (147) will be collected and dried and intended for agricultural industrial applications such as chemical and other fertilizers. The electrolyte with its precipitated constituents, preferably by electrochemical process, so as not to change the acidic nature and its pH leaving its higher density constituents in the tank (147), is filtered and reused in another first stage.

METALS

For the metals adhered to the electrode 5 of the housing 2, fig. 114, 116, are removed by pneumatic system, or rolled into cables towards a warehouse where they will be stored for commercialization, but still in the compartment (2), we have the metal hydroxides that did not deposit in the electrode of metallic form but that constitutes a red colored hydrated CuOH pigmented sludge, as shown in Figure 11, Item (49), and Figure 35, (176, 177) and FIG. 118, 119 (344), which is a raw material for numerous industrial applications, this oxidized CuO metal has absorbed oxygen from the electrolyte water, and is removed with mechanical blades that scrape the bottom of the housing floor (2). ) in the stationary cells shown in FIGS. 12 and 19, and in the cells of FIGS. 7, 8, and 33 are removed with pumps (45) in the form of hydrous copper oxide red mud, FIG. 11 item (49).

REJECT

As for the tailings, having no other constituent of viable extraction interest can be discarded as illustrated by opening the floodgates 197 of FIG. 14 carried by tractors and machines or sucked in by pumps 45) fig. 1, to a suitable place after properly neutralized.

NOBLE REJECT

There will be a noble tail, more particularly described in FIG. 19, reference (82), this sandy tailings sludge contains noble or semi-metallic metallic elements which will decompose in their primary form, combined with the ametals, eg AuS gold sulfide or oxide, PtS platinum sulfide, oxides of MnO, PbO, and others that transform into insoluble hydrated oxides such as those of manganese, lead, gold, platinum, black and pigmented and other noble and semi-noble. In this process another fourth stage of tailings treatment process which can be processed in this same cell described below operates.

Fourth Stage

EXTRACTION OF THE NOBLE PROCESS (182)

Mineral earth after being processed by two stages that decomposes the whole earth and the common metals are removed, leaves a sandy earth with milky white silica residue containing group 13 metals such as silicon and silica from the periodic table and others. in oxide form as illustrated in fig.19. (80). Some metals such as Manganese, Lead, Platinum, Gold and others that had the primary combination of Sulphide, Phosphide, Telluride, Arsenietes, Antimoniide, have oxidized in the first stage of the process and will remain inert in the second stage because they have no affinity for electrolyte ametals. and remained in compartment (1) in the form of dense insoluble hydroxide. To remove these metals we will neutralize the tailings by washing with clean water, fig. 19, and this procedure was performed soon after the electrolyte (14) and metals removal. At this stage we add an alkaline electrolyte such as | sodium cyanide NaCN fig. 19, with 6% content, with 10% NaOH or CaOH, in clean water acquiring a certain PH (202), which is stored in an underground reservoir tank fig. 19 item (197), waiting for this process stage. The metals will be solubilized electrogravimetrically in the Mineral Stationary Cell starting the march with key 31, the metals present in this tailings settled on the electrode (13), solubilized in compartment (1), and the negative CNOH-molecules. are attracted by the electrode (13), which at this stage has positive polarity releasing on its surface in the nascent state, combined with oxidized metals that have positive character becoming soluble A11O2 + CNOH-, PtÜ2 + CNOH- = 2PtCNOH- 2AuCNOH- molecules. By delivering these metals into the negative compartment adhered to the electrode 5 or precipitated in the form of insoluble hydroxide they form noble black sludge, which should be melted as illustrated in FIG. 120. Filtered on the charcoal column 34, the metal-free electrolyte is stored in the underground reservoir tank of FIG. 45 in the housing 201 in an impure manner to be filtered by the filter 200 stored in the reservoir 202 and reused thousands of times in this fourth stage with only minor corrections. After the complete extraction of all constituents of economic interest, and the removal of the liquid electrolyte neutralizes and discards the waste that will be sucked by the pump (45), and transported as sandy mud to an appropriate locomotive by truck or truck. The noble metals are further separated by centrifugation and flotation, where the tailing sand is centrifuged to form a black precipitate which is collected as a noble sludge where it will have a rare and noble metal constitution from group 3 to 11 of the periodic table.

INDUSTRIAL ASSEMBLY OF THE ELECTRIC GRAVIMETRIC CELL PLATFORM MINERAL STATIONARY PROCESS (182)

More particularly illustrated in FIGS. 12 through 19 and 32, to operate in the DIRECT AND INDIRECT INDUSTRIAL PROCESS, featuring a gigantic platform fig. 32, immense, which is built on a terrain with a slope of 10 ° as illustrated in Fig. 18 in series infinitely Figures 15 and 16, with basic material of masonry, iron, internally coated with tar, rubber, ceramics, suitable pastes especially against chemical acid attacks, where their floodgates (197), close the pneumatic and hydraulic pressure, mechanical. This proprietary industrially designed Cell is capable of handling thousands of tons and extracting thousands of tons of metal daily. This Mineral Stationary Electrogravimetric Cell has the same characteristics as fig. 2 and 3, use the same electrochemical electrimetry operation process methodology and stages described in the flow charts of FIG. 35 to 42, for all cells of this process, particularly the cells of figures 12 to 19, 117, are constructed to receive in their supply thousands of tons of pre-ground trucked ore that circulates and dumps the ore transported within it. in the housing (1) above the electrode (13), this electrode which is a floor-shaped electrode fig. 18, conductor of electricity such as graphite or lead plate coated with a platinum layer, or constructed of silicon carbide. This ore can also be transported by train wagons, which dump the ore onto conveyor belts or pipes leading into compartment (1), the cell can also be transported as a viscous slurry electrolyzed with the electrolyte carried by pumps. hydraulics (45) fig. 1, 32, which dumps all this chalcopyrite mineral sludge into the compartment (1), to be decomposed by extracting the metals of interest and soluble derivatives by external electrogravimetry. In turn the housing (2) is supplied differently with electrodes (5) constructed of suitable metal or material of the same metal to be extracted, are hung on hooks connected to a digital scale (6), with pneumatically moving hydraulic machines and cables. emergent carriers fully or partially submerge this electrode in the electrolyte which may reach a maximum depth of four meters according to the process operation. The metals are delivered to compartment (2) in the form of a metal or a metal hydroxide which after drying forms an anhydrous CuO oxide of interest to be extracted figure 35, (176, 177).

Stationary Electrogravimetric Cell or Digitized Mineral Mobile Process (182)

Fig. 3 illustrates the cell in a digitized, ready to be automated manner where a panel (36) is fitted to the electrode (5) with rod (8) forming the digital gravimetric balance (6). This way of obtaining the information related to this industrial process, brings comfort, speed in the operations of direct process stages. The scanned information is received in a panel fig. 36, and via computer through the automation program described in the attached report. Understanding the importance of knowing what happens inside the stationary mineral electrogravimetric cell requires understanding its operation, which is basically as described in the three stages described above for cost-effective productivity and energy savings and complete processing. In order to be operational, accurate digital information of the physical and chemical quantities as shown in fig. 3 of the digital panel of 36 and fig. 36 traced by the automation program on the graph page fig. 63 described below:

LARGE PHYSICAL USES IN THE PROCESS

Working decomposition stress Ed (17), which according to fig. 3 and 36, this voltage determines the decomposition of a mineral material and also determines how a metal progressively directs itself to the electrode (5) compartment (2) of cell (3) fig. 2 and 3, and the electrode 60 and the thermoelectrogravimetric oven fig. 21

Decomposition Amperage Ad (18), panel Fig. 36, according to these quantities is determined by the amount and speed of decomposition of the mineral earth to be processed and the amount and speed of metal extraction, according to the intensity of the electric current in Coulomb.

Galvanometric Reading, G, (19), fig. 3, with these quantities it is possible to read the direction of the electric current and the degree of its inclination, being able to detect interferences and correct them.

Overvoltage, Es, (20), with this information can be determined the volume of hydrogen produced in the process and can control the excessive birth of hydrogen in electrodes (13) and (5).

Weight in grams per second recorder recorded by the digital gravimetric gravimetric scale embedded in the electrode (5) to control the output in seconds, hours, day, week, month, year. The ohmic decomposition resistivity Rd (22) of the electrolyte, in order to control overheating of the electrolyte at the time of the process. THE . The precise ohmic resistivity value, ideal for the process, is achieved by emerging and submerging the electrodes in the compartment (2). Concentrating and further solubilizing the electrolyte by adding water or concentrated acid.

Anodic overvoltage Ea (23), by means of these quantities, can control interference in the compartment in which the polarity is positive.

Cathodic overvoltage Ec (24), by means of this physical quantity, it is possible to control the interference in the compartment in which the polarity is negative.

Decomposition temperature ° Cd (25), working temperature is required to control the heating influencing ph, Rd, Ed, KWh.

With the return voltage Er, 26, this magnitude is known from an inventive property by placing two inverted polarity diodes in the circuit connecting electrodes 13 and 5, this illustration is more particularly understood in the circuit of fig. 23, item 113 and 116, fig. 64 (291), (292). This return voltage is generated inside the cell as a battery element and causes interference that is controlled when the value of this return voltage is known. Through this inventive character the holder has delved into this detail in detail, has discovered another property to which the return voltage information can be received and by means of these inverted diodes placed in the circuit it is possible to quantitatively determine all dislocated elements in the electrolyte by centimeter by cubic. extract them.

By the acid potential of the electrolyte reported in the table, PH, (27), knowing this magnitude, I can control the dissociation rate of molecules by adding more water decreases ph, and more acid increases ph.

Weight reading in tonne hour in the table, TN / h, (28), to control production according to yield in KWh. As an example: “The process is running at 50,000 tons per hour.” Al warning alarm, (29), when a process has been terminated or has been interrupted for some reason.

Digital reading of the decomposition power applied in Kwh / d (30) with it controls the production and process cost.

Thickness in mm and / mm (258); of the metallic deposit, calculated and informed by the automation program, regarding the weight of the metal adhered to the electrode (5).

Immersion in cm2 of the positive electrode AC / cm2 (260); records the size of the electrode's immersed area in the electrolyte in cm2, in order to calculate the intensity of the electric current to be applied.

Immersion in cm 2 of Anode An / cm 2 (259); records the size of the electrode's immersed area in the electrolyte in cm2, in order to calculate the intensity of the electric current to be applied.

MOBILE ELECTROGRAVIMETRIC CELL MINERAL WAGON

The operation process of the WAGON MOBILE ELECTROGRAVIMETRIC CELL fig.9, is started following the methodology applied for the FIRST STAGE DIRECT ELECTROGRAVIMETRIC PROCESS, it is connected to the key (31), it adjusts to the electrode polarity through the inverter switch (115). ), the voltage is also adjusted to the working voltage precisely indicated by an equation calculation that can be calculated either manually or by an automation program described in this report. AUTOMATION PROCESS, detailed below, with the preset voltage Once calculated, it can be manually adjusted by the switch (32), which provides a voltage sweep without changing the working amperage. This design of digitizing the cells of this process is best illustrated in Figure 24, where it performs all stages of the direct process, and still processes the complex alloy electrodes of the indirect process. MOBILE ELECTROGRAVIMETRIC CELL DIRECT PROCESS MINERAL WAGON (182)

MOBILE CELL, demonstrating that the direct process described in this report can be performed on a mobile cell fig. 9 and 55, having iron wheels 56, and moving on rails 57, having the same main indications of the cell of FIG. 2 and 3 having the same qualification, only the structure of this cell, ie the container box (3), of which it is formed utilizes rubber-lined iron plate material against chemical acid attack, divided by a wall (9) , and fig. 54 and fig. 57, already described above, in two compartments (1) and (2), using two lateral electrodes (5) that are hung on hooks that are fixed to a digital scale (6) in the two lateral compartments (2) where the The extracted metal (49) and fig. 119, which will be removed by the lower caps (55), contain a floor-shaped electrode (13) in the central compartment (1) to which the ground ore (16) is added about 200 to 500. tons of ground primary ore supplied by the opening of the upper iron cap 53 and discarded after processing by the opening of the lower cap 54 fed by external direct current electric force from the circuit of FIG. 23, digitalized according to the drawing of figure 24, its movement is made by diesel machines such as the conventional ones already known or by electric motors embedded in the gearbox, their working process is more particularly illustrated in fig. 31, of this describable process, where hundreds of Direct Electrogravimetric Cell Mineral Process Wagon (182), direct. It runs in series on iron rails (57), in a circle shape for the execution of the process. This illustration of fig. 31 and 55 the indication cell (161) which is supplied at the station (165) with ground ore and electrolyte indicated for the process, counterclockwise moving the mobile indication cell (162), in the process already almost completed, the indicating cell 163, stationed at station 158, is in the process of disposing of the electrolyte in the tank 160, moving forward where we see the cell 164, discharging the metal and hydroxide from the Metal discarding the tailings moving forward is washed at the station (159) by dumping the waste into an appropriate tank.

INDIRECT ELECTROGRAVIMETRIC PROCESS (183)

Industrial processing of mineral earth treatment is carried out as follows: that in addition to primary milling prior to any other operation within the Cells, an instant smelting of previously dosed sulfide ore with a certain weight calculated in tonne being a mineral earth is performed. of CuFeS2 chalcopyrite ore concentrate, fig. 34, | 51, 115, Iron and Copper Sulfide, which is decomposed from its conjugate electronic bond, with other elements, such as sulfur ametal, by a direct current electric plasma discharge, and high frequency induction firing, which together these two forces in a period of time, separates their constituents metals, nonmetals, ametals, in a special furnace fig. 21 and> 50, inventive in nature, similar to those already on the market but with differentiated specialties from those existing in the ovens known by the state of the art. The result of electrogravimetric casting is a qualitatively and quantitatively complex metal alloy with a certain weight and physical density. This alloy is extracted by thermoelectric force via thermochemistry and electrothermia in the thermoelectrogravimetric furnace containing various P metals, being, for example, the highest proportion, iron and Copper in the case of chalcopyrite, which is laminated according to its composition, naturally contains casing metal to be disintegrated and fully decomposed in compartment (1) in the Mineral Stationary Electrogravimetric Cell (3), described in this process in Figure 20, providing the delivery of a noble product of copper, nickel, zinc, iron, antimony, silver, cadmium, tin, gold, palladium, silver, platinum and other rare or semi-precious metals of high purity according to the source ore to be deal with this process.

HIGH SPEED While still introducing the indirect process in an introductory manner, this process can be high-speed as far as thermoelectrogravimetric casting is concerned, where production speed is controlled by an automation program described in this report using a STATIONARY OVEN (42) described. 1 and 21 and another ROTARY OVEN 89 described in FIG. 22 and 38 which together with a CENTRIFUGE DIGESTER (75), and VAPOR AND GAS WASHER (70), and a HYDRAULIC FILTER (81) which provides solubilization of the constituent metals of the mineral earth producing a complex filtered electrolyte causing these metals in this electrolyte are extracted separately by the HIGH SPEED INDIRECT PROCESS. This set of procedures that from this.

ELECTROGRAVIMETRIC PROCESS DIRECT AND INDIRECT PROCESS

AUTOMATED

Created by the inventing proprietor, its viability and implantation in the mineral industry became possible, for the extraction of metals of greater economic interest, from the technical inventions of different marches and stages, implanted by the proprietor in this process and the use of the machines illustrated in the drawings. annexes being a panoramic set shown from figure 1 to 120 thus providing two distinct working methods in the same invention called DIRECT AND INDIRECT PROCESS.

Still further detailing the illustration of FIG. 1 is taken the meaning of the INDIRECT PROCESS in which the ground earth 37, after being ground is transported and its initial weight registering in advance, then added in an oven with inventive special features illustrated in fig. 21, hereinafter referred to as MINERAL DECOMPOSITION THERMOELETROGRAVIMETRIC OVEN (42), having a low vacuum property which is fed by the inventive circuits of FIG. 25, and another circuit of fig. 27, which work together to gravimetrically decompose the mineral earth, separating nonmetal and ametal metallic constituents by external electrical force in high frequency KWh, and direct current flame force, reducing gravimetrically and collecting the resulting alloy from the process in molds, and still collecting the gasified and vaporized nonmetals and nonmetals in a condenser (70), which is a gas scrubber which after combined with water turn into raw material for other industrial applications avoiding their dumping into the medium environment. The shape of this alloy should be as small as possible in order to accelerate its decomposition in the machine. MINERAL ELECTROGRAVIMETRIC CELL assembled according to the drawings in Figs. 7 and 8. After the alloy (58) reaches the desired shape, these alloys are hung on hooks by the aid of hydraulic and pneumatic machines next to each other in the compartment (1) of this cell fig. 7 and 8, being decomposed by an electrochemical electrogravimetry process indirectly in a gravimetric manner and the metals migrate to the compartment (2), and adhere to the electrode (5), which records their production weight in the gravimetric balance (6), of the compartment 2, or otherwise physically chemical these metals precipitate as a hydrated hydroxide or oxide resembling a precipitated clay or mud as illustrated in FIG. 35 and 118, with a certain percentage of the metal of interest. In this same drawing of fig. 1, indirect, after the decomposition of thousands of metal alloys (58), left at the bottom of the compartment (1), a slurry of metals that will not be solubilized by this process as manganese, lead, and other noble metals, as well as pieces of metal that has not completely decomposed (82), these in turn are dredged by a hydraulic pump (45), where the ones of interest will be centrifuged and separated to return to the direct or indirect process or to be driven to other processes.

TAKING SENSE OF THE INDIRECT ELECTROGRAVIC METRIC PROCESS

Particularly the indirect process is performed in a SPECIAL ELECTROTHERMIC AND THERMOCHEMICAL OVEN called FORNOTERMOELETROGRAVIMETRIC of Figure 21, endowed with specialties, new inventions, differentiated process methods from the current one because it contains new characteristics in which the ore (16) is added in the furnace ( 42), being reduced to a complex metal alloy by high frequency kwh electrical power provided by a special inventive external source, more particularly illustrated circuit of FIG. 25 and another plasma external electrical force more particularly illustrated in inventive circuit of FIG. 27, being able to work with these two forces consecutively providing to the instant gravimetric casting, a quantity of ore, previously ground, and heavy, with defined density and precise information of its metallic, nonmetallic constituents, conjugation ametals. This element is separated by high frequency electric force and direct current, its metallic constituents are decomposed as shown in fig. 52, where a certain frequency Hzd, and a certain power Wd, is applied to the ore through the copper tube coil 41, which induces a frequency that reaches the ore molecules (224), combined with the nonmetals and ammetals. , causing them to vibrate by changing the sense of different magnetic polarity thousands of times per second (232), (238), and (240), generating intense heating, causing the heavier positive metals to pour into the furnace bottom (65), attracted even more strongly by a plasma discharge (61), applied in conjunction with the high frequency discharge that draws all metals to the bottom of the furnace and the nonmetals (239) of The lower melting and boiling point as the metals turn into gasified steam (242), rise to the top of the furnace and even more strongly attracted by the positive pole of the electrode plasma discharge (59). The metals are collected as a complex alloy attracted by the negative electrode 60 at the bottom of the furnace bottom which is a pan-shaped shape collecting the metals. Nonmetals, ametals and their gaseous derivatives are attracted separately in the low vacuum, in the form of gas and steam in the upper part of the furnace, preferably free of oxygen from the atmosphere to save this oxygen environmentally, being characteristic of the process not to use the chemical constituents of the furnace. air environment. The gases collected at the top of the furnace are sucked in steam by the pump (69), the heavier ones condensing in the condenser (70) in the form of denser dust (71). This capacitor holds in the form of dust some heavier elements such as arsenic, selenium, tellurium, polonium, astatine. The stage of this process is best illustrated in the thermoelectrogravimetric flow chart of FIG. 42, where the process march is initiated by connecting the key 218, which is a key that drives the direct process 183, interconnected the key 216, of the circuit of FIG. 25, the key 217, the circuit of FIG. 27, and other systems of an electric nature ie transporting the ore to the kiln and the scheduled opening of the lid (73) of the kiln, intermittently opens and adds the ore ground by weight of a certain ton, the ore falls into the oven's central compartment in a magnetic field (61) where it is circulated by a water-cooled copper tube coil for cooling upon reaching the high-frequency plasma field where it comes to be. decompose with gravimetric separation of the elements. Thermoelectrogravimetric Casting: It is programmed to drop about a ton or more of ore at a given time eg 10 ', minutes in an oven fig. 50, retort-shaped (66) where it receives this ore within it (61), in a given field, an intermittent high frequency plasma discharge is automatically triggered in this field. Plasma: Fired from two special water-cooled compact carbon metal electrodes being this electrode of graphite, coal, silicon carbide or other water-cooled refractory element, and high frequency: through a coil of copper-cooled tube the water encased outside the furnace one or more discharges calculated by the weight of the ore chemical composition and physical properties its refractoriness, energy that must be released in, kcal and power in kwh, for the total reduction of ore turning into a metal alloy with certain properties, brittle, malleable, acid soluble or insoluble. In case it is insoluble and is brittle, it is necessary to place it with metals of group 11 and 12 of the periodic table, preferably the same copper, and to melt it in a channel induction furnace to turn it into a malleable alloy. and soluble in acid.

THERMOELETROGRAVIMETRIC EFFECT

By this circuit 25 and 27, the effect of fig. 52 to divide the ore molecule having up to 25% composition of the homogeneously sulphite milky silica accompanying the ore with mathematical and figurative description of the mixture consisting of: Si02 / CuFeS2 + CuFeS2 (224), in some variations an determined frequency by varying the potentiometer (104), fig. 25, and variable inductor (95) of the supply circuit that induces the physical heating frequency only in the copper molecule, fig. 52, Cu, (226), liquefying at elevated temperature forming an alloy of 2Cu2, (240), and a slag of 2SiFeS2 (237), with traces of viscous silica, and a sulfur vapor gas S2 + S02 collected in the condensers. and washers. In another variation, a frequency that only reaches the metals is induced forming an alloy of 2CuFe2 (243), and a viscous slag of Si02 and steam of S2 (242). It can still through this circuit induce another frequency only in the iron molecule (225) which will cause the liquefying effect and join the iron molecules to an alloy in its largest iron or copper composition (238) forming a viscous silica slag, copper and sulfur Si02, CuS (239), as this description is explained by the inventive thermoelectrogravimetric name. Then, after the liquefaction of the thermoelectrogravimetric reduction metal elements, the metal ball or alloy falls into a mold or rolling mill where it is transformed into a thin electrode and automatically refines into an electrogravimetric cell. Retort 66: fig. 50, conducts the gases through the retort (66), released at the time of reduction and are sent to condensers and a water shower tank where they transform ametal halogens into acids if oxygen and soluble mineral salts are present. Or they are still disposed of in the gaseous state in deep underground wells, about 800, 1000 meters or more where they combine with carbonates and others, thus being neutralized and stabilized in the depths of the earth. Gases + water = acids or bases + groundwater saline = neutral mineral salts.

MODIFIED HIGH FREQUENCY THERMOELETROGRAVIMETRIC OVEN FOR ELECTROGRAVIMETRIC MOLDING OF ORE

COMPLEXES

High Frequency: An automatic high frequency system discharges the fired energy in kWh to reduce the total ton or more or less ore to provide the correct fluidity to discard the slag and release liquid metal at the bottom of the furnace. which will be framed below. High Frequency Induction: Performs the casting of ore molecules as if these molecules were an electrical resistance, the heating of this energy is provided by two circuits in fig. 21 and 25 of the innovative circuit. We can calculate the energy in kWh amount of heat amount of electrical power in unit of time required to reduce 1 TN of ore in the 10 minute step by discarding its slag and gases by receiving the cast alloy transformed into an electrode for refining.

We will transform the electric energy into metal and derivatives, spending only what is necessary for the reduction according to the equations below. We look for the value of the spent power in Kilocalories Q, of the molecular decomposition of any ore eg CuFeS2, copper and iron sulfide, which will give us the decomposition power Wd for the molecular reduction. In this case we assume that the ore is a conductor and want to magnify it to complete fusion, so we look for the value J = joule where 0.24 is an equivalence constant. We seek the magnitudes of this complex of calculation to arrive at the exact power of the fusion where we take into account: The signs - and +++: indicate the charge of the molecule or atom. The condition of polarity.

(Ore + Kcal =

(KWh + Khz + MAT / Ed / c.c) + Ore =

Complex alloy).

(1TN / CuFeS2 = 25 ° C) + (Hz + Ed / c.c) + (Wd) =

(1 / TNCuFe +++ S2 -) + (2,500 ° C = y, Kwh)

Hz + / - = (Cu ++ Fe ++. Cu - - Fe - -) (S ++ O ++. S - - O - -)

Ed + / c.c = (S2 - .0--) =

Gaseous metals evaporated and pumped to condensers and scrubbers.

Ed- / c.c = (Cu ++. Fe ++) =

Extracted metal alloy at the bottom of the oven

Hz = Frequency applied to dissociate a specific metallic or non-metallic molecule.

Ed / c.c = MAT decay current voltage applied to attract atoms in positive or negative sense.

Ad = Decomposition amperage applied to fully reach ore in volume and weight.

Wd = Total applied power required to decompose an amount of mineral mass at a given temperature and time. ° Cd = Total decomposition temperature of mineral volume and weight.

Q = Joule kilocalories needed to reduce

1TN of mining, m

Rm = Homic resistance of conductor Rm, resistance of the mineral to a given temperature.

Ra = Homic resistance of conductor Rm at a given temperature and a certain distance.

Ed = Electrical energy Ed of decomposition voltage in volts.

I = Current flow I Amps

0.24 = 0.24 constant

1. Equation

Q = 0.24. I2. R. t

Q = 0.24 constant (1Kwh = 864 Kilocalories)

Q = 0.00024 .3600 .1000 = 864

P = E. I = Watt

Q = 0.24. E. I. t

E = E. I. t

How much electrical energy is needed to reduce one ton of CuSFe2, iron sulfide and copper ore? Q = 864. (Rm. Ra). I2. t 1000

1kWh = 860 Kilocalories, commensurate with the temperature required to liquefy the metals and evaporate the ametals.

Hz = Proportional to volume and size of ground particles

Ed = Proportional to the standard oxidation potential volts of the atoms to be decomposed.

Ad = Proportional to the volume and weight and electrical conductivity of the ore.

HIGH SPEED INDIRECT ELECTROGRAVIMETRIC PROCESS

More particularly in the illustration of fig. 22 we have the machines of known character with a rotary oven but with inventive characteristics closed in container 211 fig. 48, in low vacuum, added to improve this inventive process as the need to protect oxygen from the air that is absorbed by the current roasting process, which throws toxic combined oxygen ametals into the environment from the old processes. which are still used today, and the difference with this new inventive process presented here is that it does not allow this to happen, given the following high-speed details: these machines should be part of the indirect process when a high production speed much faster than the process details described above. It is a thermochemical process method, initially fig. 48, is carried out by a rotary kiln (89), lined internally with a special high fused silica brick wall, (205) which does not allow the ore to react at high temperature with the walls (204) outside of this kiln. it is iron that is iron its energy is fed by a high frequency circuit particularly illustrated in fig. 25, which raises the temperature by concentrating solely on the ore according to the applied frequency figa. 52, to target only the molecules of this ore, which in this case is previously ground CuFeS2 (224) molecules, which is rapidly raised to a temperature between 700 ° C to 1200 ° C. In turn this ore is heated at this temperature and controlled by weight into a centrifugal digester tank (75), whose inner walls are characterized by being constructed of high fused silica brick against acid attack, which in its interior in a certain level contains a moving centrifugal liquid, it is expected from this ground and pulverized ore that its liquid is constituted with a certain percentage of acid composed of the same ore existing in the ore in turn sulfur acids H2O + H2SO4. + 700 ° C to 1200 + CuFeS2. = CuSO4 + FeSO4 + H2SO4 + H2O. The vapors and gases generated on preliminary heating inside the furnace are sucked in by the pump (86), and the gases and vapors generated in the digester tank are sucked in by the pump (69), towards the condensers and gas scrubbers (70), built in as many as necessary until the vapors are cooled and condensed, turning them into liquid (85), with acidic property that can be reused in the process. The liquids, together with the digested sludge formed inside the digester (75), are pumped by the pump (76) to a high pressure hydraulic filter (81) which, through a vertical piston (78), presses and squeezes all the slurry. digested acid until the last drop of acidic liquid turns into a dense sandy square block of silica (79), a side cover opens and the extruded piston throws out the squeezed tailing block (80), which will be discarded or treated differently to remove noble metals. The liquid containing the essence of the process which is the metals of economic interest such as copper and even iron solubilized in this process are collected in the tank 114 described in FIG. 30, where after filtering and shipping the Mineral Stationary Electrogravimetric Cells this process can be better understood as a thermohydrothermal process.

This project is suitable for use in different mining processes and worldwide research in industrial mining and in the determination of metals from the source ore, in various laboratories in the large-scale production of high-demand electrochemical refining metal extraction. and thermochemical and other derivatives such as CuOH metal hydroxide and CuO anhydrous oxide, of economic interest with purity levels around 99% this project constitutes a revolution in the mineral industry, electrochemical and thermochemistry in industrial mineral electrofusion, with It is possible to treat thousands or even millions of tons of ground primary ore a day, extract millions of tons of refined metal daily in an operation that corresponds to one to five process stages, highly controlled and monitored by automatic program alarms and sensors. automation-specific computer system. Without emitting toxic derivatives into the atmosphere such as sulfur gases, and others it does not produce toxic derivatives of industrial waste from tailings such as tar compared to oil that in large production has no solution to get rid of them, because the The present invention is environmentalist. This process is of low cost of production does not create toxic derivatives that must be emitted in the atmosphere and nature and the process costs are highly economical compared to the electrothermal production of aluminum which to extract one ton of aluminum is spent 17,803 kwh per ton. in counterpart this new method being O

ELECTROGRAVIMETRIC PROJECT it is possible to extract a ton of copper with only 2,548 kwh per ton for the DIRECT PROCESS and 4,572 kwh per ton for the INDIRECT PROCESS. In this report you can better understand in general with the illustrations of the panoramic process flow charts 28, 29 the process flow charts of FIGS. 37 to 43 and process automation the flow charts of FIG. 66 to 72 and the illustration of figures 1 and 32 showing the platform assembly. All elements of the international periodic table can be extracted from their complex mineral conjugation by the direct and indirect electrogravimetric process described in this report in the soluble, liquid, solid, gaseous, or anhydrous, hydrophthalic hydromethyl solid state on the machines described in this report as the cells. stationary and mobile electrogravimetric device fig. 2 and 3 and 9,12 to 19, and a stationary or rotary thermoelectrogravimetric oven reversing the electrode polarities and using corresponding process stages applying external direct current BT and MAT electric force and high frequency electric force at KHz and MHz provided by circuits of fig. 23, 25, 27.

AUTOMATION OF DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS

Founding of a technical control device for the machines presented in this report and scheduled execution of this process to produce the effect of decomposing ore and extracting soluble state metals and acid-soluble or base state where machine controls are controlled. by process methodology of automation, digitized and automatic remote controls of long distances, by computer presented in a panoramic way in an innovative process of inventive nature in this report of this AUTOMATED DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS.

As is well known to those skilled in this art, there are numerous automated electrochemical and thermoelectric processes that perform automatic commands in cells and foundry furnaces are also designed to perform electroplating and electroplating processes from existing and benefited salts and alloys of automatic furnaces. induction for melting of known alloys. Carrying the aim of the present invention of automated electrogravimetric process is distinguished by inventive techniques designed to perform this process bringing comfort and precision promoting close and programmed productivity over long distances in accordance with international technical standards and the environment. It is distinguished by processing with the aid of an automation method, which executes the commands of the machines and their work stages described in this process in a programmed way, which digitizes all the chemical physical information monitored and commanded by workers in front of the computer fig. 69, each has a function of taking care of a respective task of the process in operation, monitoring information on the: qualitative and quantitative chemical formula and density of the raw and subsequently ground ore and its amount by weight to be processed in a given time, the amount of solubilized salts and the chemical formula and ohmic resistance, PH of the electrolyte used and the dissoluble metal molecules solubilized in the electrolyte at work, reporting on the liquid and solid supply accurately and in detail the storage of liquids and solids, informing precisely: the amount of metal that exists before extraction and the production, per day, month and year of metals according to the energy spent for production in TN, the power spent to produce in KWh, and nonmetal derivatives, and their storage daily and monthly, differentiated by informing: the applied power energy, the production speed in tons hour, process cost and yield, working temperature, electrode replacement, chemical composition, decomposition salt concentration in compartment and (1), salt concentration in compartment (2), differentiated by calculating The values for the physical magnitude of electricity, Ed, Rd, Ad, Wd, Hzd, Er, E / i, ° C, in a synchronized manner to accurately extract a particular metal and automatically compose the electrolyte chemical formula by regulating the acidic or basic character in PH, and the ohmic resistance, adding neutral, acidic and basic liquid, to be possible to the extraction of a given metal. A secret of the decomposition voltage scanning system defined at infinite command points of graphs and attached tables created for automated and direct electrogravimetric process execution remotely and digitized remotely in the control room by computer or over long distances. Obtaining all information of physical and chemical quantities in a digital and computerized way that can control the system and operation of machines automatically programming all the operation anticipating in advance the production of weight of ton hour, day and month and the replacement of mineral raw material. and stock chemical additives such as controlling the entire system over long distances by receiving all information of chemical physical quantities accurately.

AUTOMATION BASIS FOR DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS

Remembering that the ore in the whole process is an electrode and an electrochemical resistance to decompose in the direct process and an electrochemical resistance to heat and melt in the indirect process. How to interpret the engineering table? We look for a point in the reference, 0, which identifies the line number of the wanted atom from the engineering table for CuFeS2 ore elements, fig. 34 particularly decomposing its elements, which is the metals, copper Cu symbol column 1, line 29, Fe iron, column 1, line 26, and sulfur ametals S, column 1, line 16, which it is desired to extract. In column 2, this row number indicates its standard potential Volts, finding the metallic or ametal element that we wish to extract in the engineering table 1st, 2nd, 3rd, 4th, 5th, we look for the work function we wish to perform in the horizontal columns. indicated by thirty and symbols in 32 columns. Finding the absolute point in relation to the work operation we want to perform, the program triggers the graphics pages fig. 59 which will find the proportionality value between the physical and chemical quantities fixed at a command point in this graph, will effect a command effect on the relays and sensors on the automatic drive switches of the machine used to perform the process and the decomposition of the ore by separating its metal elements from the ametals or turning it into another chemical compound of greatest interest. Fig. 13, 35, 114, 116, 118, 119. In the graph pages fig. 59 to 63, the points between quantities establish a physicochemical condition within that of the electrogravimetric cell (3) machines fig. 2 and 3 or from the thermoelectrogravimetric oven (42) fig. 21 which is interpreted as a command order that has the effect of a given work fig. 63. The points and numbers of these pages in relation to the search are infinite. When you have all the results of calculations regarding the execution of the expected effect and its numbers of magnitude that you searched for and executed the program, you achieve system synchronization that comes down to a joint order of several command elements that starts to perform a single march. of the process in a general sense: the absolute physicochemical state to initiate the decomposition of CuFeS2 chalcopyrite ore, initially insoluble in the direct process with negative polarity by being on a negative electrode (13) compartment (1), transforming it in CuFeOH2-, hydrated black pigment fig. 65, (293), insoluble with negative polarity by standing on a negative inert electrode, reversing the electrode poles becomes positive and decomposing into soluble CuFeS08 salt breaking the molecule and decomposing it into FeS04 + Cu soluble iron sulfate , in metallic copper extracted in the electrode (5) of the compartment (2) Fig. 119, and the sulfuric acid sulfate molecule 2H2SO4, soluble in the electrode (13) in the compartment (1) again yielding in KWh. This would still take time manually, but we can just clik a mouse on a computer monitor that displays the engineering table, the column that belongs to the metal you are looking for eg Copper, and program the automatic work system. Productivity is programmed at KWh = 2,500 Kwh / TN, meaning the gear is in production for one ton hour. We initially calculated as an example the decomposition stress Ed required to effect the expected molecular breakdown effect on the ore which is insoluble and poorly conductive, remembering that it is a chalcopyrite electrode moistened by the electrolyte that now conducts the electric current and participate in the electrochemical reaction , this quantity Ed, is proportional to the decomposition amperage quantity Ad, in relation to the TN weight and the ore surface in m2, the ore volume m3 and the ohmic resistivity of the electrolyte liquid (14), being proportional to the amount of energy per second of the applied power quantity Wd, and still proportional to the initial temperature departure, which in this case is the ambient, between 25 to 40 ° C, necessary to realize the expected effect on the ore quantity in TN, and the ohmic resistivity of the mineral element. in Rd, its weight Kg, proportional to the applied power. The distance between the electrodes is proportional to the decrease in resistivity and the increase in power. To better illustrate the working process, a graph fig. 59 illustrating the following: SYNCHRONIZATION TABLE: synchronization refers to the external working electromotive forces and the internal forces it generates in the dissociation of the electronic bonds of molecules and atoms as a cell element that generates the overvoltage or internal counter electromotive force. The physical forces of labor are represented by the symbols of the following quantities. Td = Decomposition temperature, Ed = Decomposition voltage or Voltage, Ed / i = Internal return or working decomposition voltage for internal electrogravimetry, Rd = Decomposition resistivity in ohms, Ad / cm3 = Decomposition amperes per cubic centimeter, Ad / dm2 = Amps of decomposition per square decimeter, Wd = Decomposition power, Er = Voltage or return voltage, Internal force, 'PH = Acid potential, resistivity of electrolyte solution or liquid, amount of dislodged acid in electrolyte. electrical conductivity, resistivity, amount of alkaline soluble base, electrical conductivity, E ° = Oxidation potential of the wanted element acid medium of the metal or ore which either decomposes by direct or indirect electrogravimetry, E6 ° = Oxidation potential basic medium of the metal to be extracted. Or the ore to be decomposed. The temperature of the electrolyte in the cell is minimum and maximum from 25,999 to 79,999 ° C in cold and hot, and must remain at a constant constant temperature at the time of work, if the temperature increases all values for voltage Ed, Ad, Wd, Rd, PH, Er, Ad / cm 3, Ad / cm 2. Since the work execution is based on proportionality, the command program will automatically adjust the quantities so that the energies are supplied according to the production need. Synchronizations for the quantities described above are performed by the synchronization table on a computer monitor as follows: <table> table see original document page 54 </column> </row> <table> <table> table see original document page 55 </column> </row> <table>

THE

í

PS s

PS

-

- 1

1

= s

- i - - - - - - - _ _:

-

s

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s

1 p7 1 i! í f 1 1 j5 1 ia 1 1- 1 1 I * 1 I! 1 i 1 <table> table see original document page 56 </column> </row> <table> <table> table see original document page 57 </column> </row> <table> <table> table see original document page 58 </column> </row> <table>

_ELIJIA

-P

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—Li

jeíIí

21 j:

j I

you *

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=. = - 1

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.2Synchronization Table Symbols for Electrogravimetric Process Automation

<table> table see original document page 59 </column> </row> <table> ENGINEERING TABLE: This table was developed in order to command the proportionality quantities between the atom of the molecule and to obtain the physicochemical information that can be obtained. please refer to and the effect you want to necessarily perform at the time of work execution. Initially this table is the key to finding the answer to a question and performing the desired effect. Ex: how can I reduce the CuS molecule by electrogravimetric process? Immediately the answer flows on the monitor screen in a command menu box bringing all response regarding the execution of this work, at this moment I can give a mouse click to start the work operation. Built with 84 vertical and 32 horizontal columns. Program Engineering Table page displayed on computer monitor: This is the page that will appear on the computer monitor, contains the table that performs the automation program functions, performs the program equation calculations for each chemical element and can be operated. manually or automatically through the computer. It is driven by the engineering chart symbols according to the legend below. Ex: Copper, column 1, row 29, Cu? Symbol, Standard potential volts acid medium column 2, and row 29, value: -0.342 (2). Basic oxidation potential column 3 Eb °, line 29. Density of the ore, metal, electrolyte, d, column 4 line 29. Valencia of the atom metal sought a, column 5 line 29. Cathodic voltage Ec, column 6 line 29, Voltage Decomposition of Molecular Conjugation to Metal with Ametals Column 7 Ed Row 29. Electrochemical Equivalent in Ampere Hour, E / Ah Column 8, Row 29. Amperes per Square Decimeter Column 9, Adm2, Row 29. Amperes cm2 A / cm2 column 10 , line 29. Gram hour of bonded metal fig. 94, to the electrode (5) registered by the scale (6) gr / h, column 11 line 29. Minimum working temperature ° Cm, column 12 line 29. Maximum working temperature ° CMx, column 13, line 29. PH acid potential H20 + H2S04 acid electrolyte column 14, line 29. Negative polarity electrode overvoltage Es / c column 15, line 29. Electrode overvoltage to positive polarity Es / column 16 line 29. Electrode distance in cm A>, A <column 17, 18. row 29. Deposit thickness in millimeters column 21 and / mm row 29, proportional to weight in grams. Indicated anode chemical element column 22 A / ind, line 29. Indicated cathode chemical element column 23 C / ind line 29. Solution complex formula column 24 salts line 29. Metals not adhering to the indicated cathode column 25 M <row 29. Ore of origin column 26 X. Solubility of ore in electrolyte solution XD, column 27 row 26. Possibility of extraction of associated metals and what stage? Column 28 row 29. Minimum molar concentration gr / l of solution column 29 , Min%, row 29. Favorable precipitation at high concentration comp. (2) Recommended reagent acid medium column 30, +0, row 29. Favorable precipitation at high concentration comp. (2) recommended reagent basic medium column 31 b °, row 29. Atomic weight of metal sought column 32 m. Operations system: Each symbol is a question and requires an answer with accurate calculations and information. The development of this program defines the comfort and effectiveness of the system of electrogravimetric operations. Automated will accomplish in minutes what would take a long time to calculate. Program: Performs all equation calculations and scans the engineering table and graph pages for the exact quantities to execute the process, to perform all execution operations quickly, saving a tremendous amount of time than we would do. manually reaching system synchronization. Execution program: fig. 63 to 113, responsible for cell supply, ore addition and electrolyte addition and chemical reagent, defines the working temperature, making it possible to read the amount of disjointed molecules in the electrolyte, informs: the amount of metal that will be extracted, the voltage of opposite force Er fig. 64, internal counter electromotive fig. 5, adjust the distance of the electrodes and the degree of immersion of them, calculate the extraction time, turn on the cell, adjust the extraction voltage Ed: mathematically calculating, amperage Ad, acid potential PH, level working power, record weight the initial electrode (5) of the compartment (1), the final weight, the weight of the ore added, the weight of the metal that is progressively deposited on the electrode (5), replenishes the chemical reagents, after all: after extrals all the metal automatically discards the liquids and solids to a suitable location fig. 19, where they will be filtered, neutralized stored, awaiting their return and discarding tailings in ditches of origin. These functions are performed in the following table: <table> table see original document page 63 </column> </row> <table> <table> table see original document page 64 </column> </row> <table>

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La La La P5 3 5 =! SR <table> table see original document page 65 </column> </row> <table> <table> table see original document page 66 </column> </row> <table> <table> table see original document page 67 </column></row><table> <table> table see original document page 68 </column> </row> <table> GRAPHIC POINTS OF GREATNESS: fig. 63, 87, 89, 90, is a quantity found at a physical scanning point (283) that establishes the exact menu command point of the program, that is, the moment when the electrical physical quantity was found, to extract a given metal, proportional to the chemical equilibrium with the electrolyte. In order to decompose the ore and extract the copper I have to find the exact working voltage, having a source ranging from 0.000 to 12,000 volts, which allows to find the exact extraction point between this ratio, having the basic information accurate for the Automated, digitized electrogravimetric operations work in perfect gear, the frame digits for voltage, amperage, ohmic resistance, acid potential, working power, electrode weight, soluble matter are visually represented on a monitor screen with digits from 0.0000 to 11.9999, as fig. 3 and 36, ratio Ed, of digital reading fig. 60 (283), voltage voltage sweep to perform molecular breakdown. Adjusting the direct process electrolyte ohmic resistivity provides the chemical equilibrium for the process execution by obtaining the value of the Rd ratio, adjusting the immersed surface and distance between the electrodes (5), in cm, achieved by immersion and submersion and slip in. electrode leads. The value that allows the amount of metal ions deposit deposited on surface area Ad / cm2 to be obtained in hours and seconds determines the production in hours A / h. The ratio of energy spent in power Wd is proportional to production and yield, ratio between weight TN, production mass and the amount of energy KWh, Wd, to be consumed. Current flow in amps A / dcm2 per square centimeter. Test example: extracted from 4 grams of ground chalcopyrite ore fig. 10 and 11, compartment (1) 1g Copper metal, Cu between Ed 2, 5 volts in acid medium, amperage Ad 1 amp. dm2, time in hours W / h, A / h, 10 minutes, temperature 25 ° C, initial electrode weight 1.5 grams, final weight 2.4 grams, electrolyte resistivity 2.2 ohms, electrode distance 3cm , electrolyte chemical composition, water 65%, concentrated sulfuric acid 20%, sodium sulfate 15%, internal return voltage Er 0, 82 Volts. Targets: 1st - supply the cell with ore in compartment (1) and at the end of a predetermined time rescue the refined metal of interest in compartment (2). 2nd - the tailings return to the same place from which they were taken. 3rd - A low cost in KWh, the work execution, provides command comfort in the operations of this machine. 4th - the commands, readings, digital pneumatic mechanical movements and the whole computer-automated system, technique: a given metal can be requested by the program for its extraction starting from a calculation of its oxidation potential of its molecules, even being mixed with an unknown number of various compound elements complex impurities without this compound influencing or hindering their extraction as illustrated in the circuit of FIG. 24 and 64. Automated this electrogravimetric and thermoelectrogravimetric system, it starts to work with yields, precision, great efficiency, because the speed, and the methodology of the system to get the work done and information, provides comfort in operations and fast extraction of the desired metal. Molecules of a given metallic element mixed with countless other elements of different metals, of complex mixture, respond obediently to a given external electromotive force Ed, providing the effect of their molecular breaking in the solid state with alternating current of frequency Hz and MAT / cc / Ed, wet, soluble and | insoluble, wet, direct current and BT / dc, voltage of decomposition Ed, to the extent that their anion and cation constituents follow the path we have defined by proper command, depositing evenly on the metal-to-metal electrodes indirect system liquid, solid metal, and oxidized mud metal as a direct system hydroxide, provided that the physical and chemical conditions are in equilibrium, predetermined by the program. The amount of metal extracted is proportional to the ampere current flow with the same voltage remaining on this current. More Amps More Metal, Same Voltage, Ed. Less Amps Less Metal, Same Voltage Ed. The internal force Er, opposite of interference with the external, will work together compensating the external when using the circuit illustrated in fig. 24, the electrolyte chemical reactions will be continuous when the resistivity equilibrium is obtained. The PH will influence the extraction and produce chemical effects and the electrical physical values must be corrected or changed. The resistivity is corrected at one point by the distance, immersion and submersion of the electrodes will produce the ohms, Rd physicochemical equilibrium and the constant extraction to the point. completion of operations. The property that the conjugate elements must emit against electromotive force in acidic or basic medium upon its breakdown is taken to have the absolute information of the elements contained in a given area in cm3 and cm2 in a processing machine and this property is determined as a result. qualitative and quantitative. The circuit fig. 23, 25, 27, 64, provides this scan capability: The number from 0 to 12 volts is infinitely a thousandths ratio must be accurate, DIGITAL READING, eg from 0.0000 volts up to 12.0000 volts we have: 0, 0001 to 0.1000 difference from 0.0999 ex: 0.0001 to 0.1000 volts eg 0.0001 to 11.9999 volts. VOLTAGE, Ed, it is important to divide the Voltage into one thousandth as well as the Amperage in order to find the EXACT POINT, Ed, A / dm2 graph of decomposition and decomposition amperage, fig. 59 and 63. The breakdown or decomposition of molecules of the chemical compound to be extracted. The system automatically adjusts the exact point by clicking on the command menu box. Finding the decomposition point on the chart page starts the extraction march by continuing all the chain commands. We achieve this magnitude of voltage variation by applying a constant current transformer. That has the property of traveling by a large dimension of magnitude between the points; a .--------------------------------. b, ie between a and b we have: a = 0.000000000000 volts, eb = 12.000000000000 volts. TEMPERATURE: The exact temperature point reading is taken from 25 ° C to 79 ° C, which must be constant for the exact point of extraction, so we will use the hundredth ratio for an absolute reading. 000,0 ° C from 0 to 100 ° C the space between 000,0 ° C and 100,0 ° C is 100,0 times eg 28,9 ° C. then the Graph Page function fig. 63, in its essence proportional differences between infinite quantities. Chemical variations: chemical and physical by the resistivity of the electrolyte, read in ohms that will be infinitely from 0000000000,000000000 to 9999999999,0000000000 Rd, ohms by a digital panel or screen command menu board on the computer monitor fig. 61. Then the program will adjust the electrode distance in millimeters and centimeters or meter and the immersion in cm2. Having an exact point name called Rd (283), fig. 60, decomposition resistivity. Synchronization: It is the reason for the perfect working adjustment between all chemical and physical quantities, voltage, temperature, amperage, PH, electrolyte resistivity, time, production, power. GRAPHIC PAGE: Proportional quantities, imagine a huge chart page having its increasing sides infinitely from> 0.00000000000000 to <12.00000000000000 this page works hidden on the monitor and can be viewed in a frame when requested, it is part of the automation program of the direct and indirect electrogravimetric system. It appears as a large surface with millions of dots comprised in numbers of magnitude, such as a pixel screen, each with a specific function that has an effect within the machine. Between two proportional quantities: relativity between, Volts Ed, and Amperes Ad the program finds the exact point between these two quantities so that a certain amount of goal can be extracted for example! covers at a certain time. As if we manually gave a mouse click at that given point for the program to perform this function. Due to the size of the sides it would be impossible to perform this detail manually having to leave this function to an automation program that executes it mathematically with great speed and accuracy. In addition to the amperage and voltage we have the point between the quantities of: The resistivity of the electrolyte in ohms: is proportional to the temperature: as the temperature increases, the resistivity decreases. Also Ed is proportional to temperature because it is proportional to Rd, having to increase or decrease it according to temperature. The resistivity of the electrolyte is also proportional to the acidity of the electrolyte, measured in PH. Functions performed by the GRAPHIC PAGE which is a proportionality program: being proportional to the magnitude between the temperature and resistivity of the electrolyte Td, Rd. Acid potential, PH and resistivity, Rd. Molecular concentration of good or bad conductor salts of electricity and ohms CM resistivity, molar concentration of salts in liquids, Rd. Values found by the scanning program using a chart page described in this inventive process. Command monitor: we can give remote command to the operating system of an Electrogravimetric Platform fig. 32, anywhere in the world, making the cell work perfectly thousands of miles away.

Monitoring the entire system, being accessible to all events and indispensable information that occur inside the machines. Mainly productivity in hours, weeks and months. INTERFERENTS: In quantum chemistry the interferers gave considerable error margins, not counting the repetitions of the reports, still did not identify certain metallic elements contained in the mineral complex. Mostly the refractory ores left many to be desired and resulted in abandoned mines as recorded across the country. In External Electrogravimetry, the same is not true of using an external electrical force, Ed decomposition voltage volts electromotive force volts. Which force the breaking of the bond between molecular conjugation to dissociate. This effect is called breakdown of molecular conjugation caused by contact or attraction of polarity, which forces cations and anions to migrate to their electrodes and compartments corresponding to their attracting force, electrical charges of attractive polarity. In internal electrogravimetry fig. 5 Molecular conjugation interferers also lose strength because the Cell has become a cell element producing attractive internal force and even the slow energy required to break down by discharging the metal deposit or spongy hydroxide element into the housing (2). . The only interference that could occur in the electrogravimetric process would be the counter-electromotive force generated by the chemical reactions of the elements contained in the cell, which is already dominated by the circuit invented by the author to read and control the internal return force Er fig. 23, 64, the so-called impurities are the same interferers in the electrolyte, are identified by the program that uses features of this system that allow the total control of these impurities, having an electromotive force of a given value in a physically balanced chemical environment, a metallic element. defined will be forced to decompose and migrate to the point of deposition in the attractive compartment in the electrode of attractive polarity, obeying a value of decomposition voltage, we call this Ed force, it is the attractive force that will force the molecule to break in the middle, becoming obedient to an exact value of electrical force regardless of the impurities contained in the electrolyte migrating to the opposite attraction pole. This action depends proportionally on the physical and chemical conditions of the electrolyte. Involuntary act of progressive sense atoms in their molecular breakdown in the separation of their ions. We set the path for the elements by offering them to pass predetermined paths with precise forces of magnitude in a definite physicochemical environment of such equilibrium value from which their positive or negative charge will definitely go to the attractive electrode. We use the electromotive forces of electrochemistry. As long as there is an exact force of Ed voltage, attracting at the electrode terminals the molecular mass elements will be decomposed and extracted to the last amethral anion metal ion if we maintain the correct physicochemical conditions. - HOW THE PROGRAM PERFORMS EQUATIONS; The engineering table scan is obtained in Column one, the searched element. Suppose that Copper, Cu Symbol immediately identified the program its oxidation potential column two, executes the equations below and finds the value Ed column seven, automatically adjusts the system to start the extraction of the metal. Finding the Ed value, decomposition voltage in column seven, the temperature in column twelve and thirteen, dipping and submerging and adjusting the distance between the electrodes in column 17 and 18, A <> C to find Ad and performing synchronization actions. Starts an addition to the balance digits read on the computer fig. 36, and 61 on the weight scale of the catage, meaning that the metal is depositing as shown in the graphs of FIG. The program performs an equation of calculations with results that causes the expected effect at work time.

Legend of the equation elements.

E = Source voltage

I = Source Amperage

R = Circuit Resistance

W = Circuit Power

Ed = decomposition stress

Ad = Decomposition Amperage

Rd = Ohmic Decomposition Resistance

Wd = Decomposition power

PH = acid potential

N = Valence Number

Ea = anode voltage

Ec = cathodic strain

Er = Return Electromotive Force

Es.a = Anodic oxygen overvoltage or overvoltage.

Es.c = Cathodic hydrogen overvoltage.EO = Anode oxygen electrode voltage which is an oxygen constant value 1.23

E (H20) = Normal oxidation potential of water 1,229

Sa = anodic overvoltage

Sc = Cathodic overvoltage

E ° = standard volts potential or standard acid oxidation potential

Eb ° = Standard Potential Basic Medium

We start from the electrogravimetry of the copper and iron sulfide chalcopyrite ore for example: CuFeS2 Which in contact with the electrolyte will turn into, CuS04, Fe2SÜ4, Copper sulfate and iron sulfate; electrolyte concentration = 1M, one mol = 1N in sulfuric acid, electrolyte concentration H2S04. E ° = Oxidation potential of the metal in this case Copper, Cu + = 0,342 for acidic solution.

Ec = Cathodic voltage if the electrode is copper which will be the same value E ° = 0.342

Ma = anodic metal

Mc = cathodic metal

Pr / a = Anodic conjugate pair, metal or neutral element Pr / c = Cathodic conjugate pair, Cu + Cu + metal A / dm2 = Decomposition amperage per square decimeter CM = molar concentration cm31. LOOKING FOR DECOMPOSITION VOLTAGE

The. Equation

Ed = Ea - Ec = 1.23 - 0.3422 = 0.8888

2. ELECTRODE OVERVOLTAGE

B. Equation

Ed = (Ea + ■ Ma) - (Ec + Mc) Ed = (1.23 + 0.342) + (0 - 0.07) = 1.6422 Ec = 0 Mc = 0.07

ç. Equation

Ed = (1.23 + 0.342) + (0.342 + 0) = 1.9144

Having an interest of calculating what is the absolute decomposition voltage of the molecules corresponding to the complete release of the metal in the cathode establishing the following formula. Since the oxygen concentration in the solution is constant we do not need to enter it into this equation since we already have its definite value EO = 1.23 volts. The element sought is the decomposition stress of the conjugation of sulfide, hydroxide, and sulfate molecules, where the attraction element will be: copper, sulfur, iron. Clarifying how copper calculations are performed means calculations for all other elements described in the engineering and synchronization table. To extract copper by logic we would start from its absolute standard potential in the engineering table 0.342 volts. But due to the force on the electrodes that is formed corresponding to chemical effects of cation exchange and molecular breakage as shown by the formula and the distance of the electrodes regarding the Ed tension.

d. Equation

Er = EO - E ° Cu = 1.23 - 0.342 = 0.8888 volts

For continuous extraction, this missing value must be added to the normal extraction value 0.342 0.8888 = 1.23 volts which, together with the overvoltage values, will give the exact value of Ed.

In addition to this drawback we also have the anodic and cathodic overvoltage that forms at the time of extraction given by the equation:

and. Equation

Es = Sc + Sa

Ed = (EO - EMC) + (So + SMc)

3. The foundation of all the above equations is summarized in: We founded Nernst on his theory from the year 1888 to 1889, with the osmotic theory of current production at a temperature of; 17 ° C. For the oxidation and reduction electrode potentials we arrive at a constant voltage equilibrium of:

Constant:

0.0001 98T = 0.058 = 0.029

Cathodic StressEc - O..o422 + {(0.05b) = 0.02? } + 0.01 Mol = 0.381 1

Having the value (Ec = 0.3811) We now calculate the stress and decomposition of the conjugate pair if CuSC> 4.

f. Equation

Ed = (EO + E ° Cu) + (Ec + Ea)

Ed = (1.23 + 0.3422) + (0.3811 + 0.0) = 1.9533

We then conclude that in order to continuously extract copper by overcoming its overvoltage interferents, the opposite force must increase its decomposition voltage from 0.342 to 1.9533. Subtracting this difference we have: 1,6111 volts. We also conclude that we have the electromotive force increased by 82.4809% per cent and still have 82% obstacle to break the copper sulfate CuS04 conjugate pair molecules to establish the absolute attractive force that extracts the metal.

INTERNAL ELECTROGRAMMETRY

Opposing External Electrogravimetry. Today we decided to adopt internal electrolysis as a starting point to study the phenomena of opposite force, return voltage Er, or counter electromotive force, overvoltage, factors that influence external electromotive force electrogravimetry. And still find some form of alternative extraction.

FORCE AGAINST

RETURNING ELECTRICITY.

Throwing the theory that: Through the counter electromotive force generated in the cell as a cell element, we take advantage of this property to know the amount of metal in the electrolyte per cubic decimeter dm3, receiving the emission of its molecular electric charge through a receiver system. as the circuit fig. 64, (116 and 117) Er receiver, return voltage, which is captured between the points fig. 23 Er (113, 117), by automating, digitally obtaining information that expresses absolute and accurate results we can determine the effects of chemical physical reactions within a cell fig. 5 which functions as a battery element operating with internal electromotive force, and subsequently applying this knowledge to achieve direct extraction of metal as an alternative energy although slow decomposition occurs perfectly, absolute test results fig. 10 and 11. If we close switch 31, fig.3 and (51), fig. 5 the digits of frame 21 of the external or internal force process, we begin to appreciate the effects on the digital scales, Amps, Volts, Ohmic resistance, Solarization G, Ph, C ° fig. 36 j. .As the metal begins to deposit on the electrode (5) the digits for the electrode weight begin to increase in grams / second = g / s. We can automate the system by penalizing the mechanical distance movements of the electrodes to achieve physical-chemical equilibrium Rd.

ELECTROGRAMMETRIC PLATFORM MONITORING: By being aware of all information we can accurately monitor extraction operations if anything is unbalanced. Immediately a corresponding frame alarm (29) sounds to warn the operator to manually intervene on the video screen The root of the problem will appear and how to solve it, this is an assumption because most of the time the system provides the convenience of having a program designed for this purpose to solve any inconvenience. High speed cell: It is positioned on a digital hydraulic scale to measure the added and excluded elements fig. 1. Has a funnel-shaped bottom fig. 7 and 8, to pump out the waste and liquids. Electrodes: They are suspended, hung on hooks and these hooks are digital scales (6), in order to read their wear in anode weight, and the production weight of the extracted metal deposited in the electrode (5). Electronic system: All digital allows reading of panel (36) fig. 3 and 36: Adm2 amperage, Ed voltage, Ohmic resistivity Rd, PH / d, Temperature ° C / d, G electrode polarization, Automatic relays, with warning alarms, thermostat selector switches, timers. Compartment identification Note: Reversing the negative or positive polarities of cells in the description of electrochemical methods of extracting the metal or its hydrated oxide does not change the order of the compartment being compartment (1) and (2), indicated in the Stationary Electrogravimetric Cell design. and movable - For initial effect it will always be (1) ore receiver and (2) metal puller - but polarities change according to the electrochemical process and stage methods that apply without changing the identification of the compartments.

OPTIONAL DETAILED DESCRIPTION OF PERFORMING DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS: Initially the operating system is presented as described in fig. 59 to 113 the Automated Direct and Indirect Electrogravimetric process execution operators are distributed in number of fourteen operators performing the execution functions on fourteen computers illustrated in FIG. 69 of; 263 to 276, with two operators administering the entire system generally monitored with alarms and sensors internally according to the flow charts attached fig. 66 to 72 by computer 264 and the remote distance by computer 263, computers and operators are distributed according to functions in a synchronized manner by a program fig. 66, soft 274 which performs the distributed processes for each operator as illustrated in FIG. 66, with frame 182 being recognized as the execution of the Direct process wherein ore 16 is added directly into the Stationary Electrogravimetric Cell fig. 1 and 31 and Mobile Wagon Cell (3) directly executing process (281) delivering the metals (49) and (50) of interest with 99% purity content. Table 183 is recognized as the execution of the indirect process in which ore (16) is added into a furnace (42), executing the process (279), transformed into complex cast metal alloy and, if possible, further decomposed rolling by electrogravimetry inside the Stationary Electrogravimetric Cell and Mobile Wagon Cell (3) performing the process (281), and delivering the 99% purity metals of interest. Table 280 is recognized as the execution of the high speed process where the ore is heated as illustrated in FIG. 48 in a low vacuum solubilized rotary kiln 89 as illustrated in FIG. a digester (75), especially resulting in soluble metal-containing saline sludge that is directed to a hydraulic filter (81), which separates the tailings (79), and the filtered electrolyte liquid (14) that is added into the cell (3) for the execution of process (281), which extracts metals (40) and (50), with a 99% high purity electrogravimetry technical methodology fig. 35, 114, 116, 11.8, 119. According to fig. 70 which illustrates the direct process 182 of automated control of the electric power distribution of the frame 278 which illustrates the electric power distribution fig. 68 with low voltage direct current Wd / BT power supplying the process (281) whose computer soft program operator (265) and (268) is in charge of administering this board and programming the supply of this power and its speed of according to the amount of metal required by the computer operator's demand (270), and determine the amount of ore to be decomposed and the direct process execution time the day of the start of work and the day of the end of the process. Table 232 illustrates the administration of energy provided by the circuit of FIG. 25, for the execution of the process (183), the instant ore melting process and the complex alloy extraction of the process (279), which through the soft program in the computer (265), previously determines the extraction of the complex alloy. and further decomposition by the process (281), and the previous programming of the energy required to extract the metal required by the demand. Table 277 illustrates the direct current MAT / cc plasma discharge power supply that feeds the furnace 42 together with the energy 232 previously programmed to perform complex alloy flow and thereafter the process execution. (281) and the required energy (278) of electrogravimetric decomposition that gravimetrically extracts the metals required by the demand. OPERATIONAL PROCESS EXECUTION

(182), (183), (279), (280), (281)

Describing in detail the automation operational process we have the flow charts illustrated in fig. 66 to 119 in which the operators and operating computers are distributed according to the following functions: According to figures 69 and 70 we have the COMPUTER (265): the operator receives instruction, in its computed through an electronic sound or through a paper provided by the technical analyst who will instruct you to schedule the demand-driven metal production which in this report is 147,000 TN of copper-containing ore at = 40,902 tonnes data provided by the computer operator (270) which in this case is metal Cu symbol copper from CuFeS2 Chalcopyrite ore, copper and iron sulphide, previously homogeneously ground and conveniently stored. This paper contains the precise qualitative and quantitative analysis of the stock ore and the amount of ore required to extract the 40,902 tons of copper and is presented to the operator (265) as a kind of order. The computer operator (265) will pass this amount to the program according to the most probable ore formula which in this report has its concentration: silicates, Si02 25%, chalcopyrite, CuFeS2 75%, we have: 37.1% copper 30.6% iron, 34.9% sulfur by weight according to Fig. 73 of Table (300) choosing the process which in this illustration is Direct (182) and Fig. 74 of table (301) where the ore density which is 3.252 and the grinding particle size 8.8 in microns the polarity of the initial negative decomposition, the addition compartment (1) to the automatic or manual programming is informed.

DIRECT PROCESS (182)

COMPUTER (266): According to fig. 69 and 70 we have the computer operator (266) who receives on his computer through an electronic sound or a paper provided by the analyst who will instruct him to schedule the supply for the execution of the process (182) being the solid and liquid supply, collection gases and liquids, the removal of tailings, and solid, gaseous and liquid derivatives, automatically determining the speed, quantity, time, and power output to be supplied in KWh or MWh to cell 3 opening the frame 302 of FIG. 75, and (303) of fig. 76, on your computer you choose the desired options and start the filling process starting with the opening of the frame 304 fig. 77 to define the capacity of the cell and how many cells will be used and the energy power that will be spent to supply this cell according to table 305 of FIG. 78 starting solids supply as shown in Table 306 of FIG. 79, where it establishes the amount of ore following the electrode supply fig. Frame 307, fig. 81 (308) fig. Table 309 and then the liquid supply according to FIG. Table 310, fig. Frame 311, fig. 85 table (312). COMPUTER (267): The operator of this computer handles the control of common hydraulic and pneumatic ore supply, electrode and filtration stationary machines, and capacitors for the execution of the first and second process stages (182) along with the process (281). ) as well as the control of tailings disposal and liquid storage and extraction of the extracted metal, removal of solid and liquid derivatives by opening the tables (331) in fig. 104 and table 332 of FIG. 105. COMPUTER (268): The operator of this computer handles the physical chemical working reactions of the process (281) of the execution of the direct process gears and stages (182) such as polarity inversion, working voltage, energy power spent for execution. etc. being the scan as described on the graph page where the program performs the operations finding the physical and chemical quantities that is displayed as described previously on the digital panel fig.36 starting the operation through the frame 313 of fig. 86 and 314 of FIG. Frame 315, fig. 88, and table 316 fig. 89, referring to the conjugated ametal, which are the initial data for performing the scan according to the result of fig. 90 of the scan result table (317), equation calculations where the program sets command points on the graph page by filling the engineering page on line (29) for copper and the conjugated ametal. COMPUTER (269): The operator of this computer takes care of the storage and classification and location of the elements to be delivered to the market as well as the energy spent to perform this process as shown in fig. 110, 111, of tables (337) and (338). COMPUTER (270), the northeast computer operator performs the fulfillment of the demand sales quotations on the market by classifying the prices according to the classification of the products available in stock and the energy spent to perform the proper service according to fig. 112 and 113 of Tables 339 and 340.

INDIRECT PROCESS (183)

COMPUTER (267): The operator of this computer opens the frames by fig. 73 (300) defining the amount of ore that will process and informing its qualitative and quantitative analysis and other physical data according to table (301) of fig. 74 defining which process will be performed in table 318 of FIG. 91. COMPUTER (266): according to fig. 69, flow chart of fig. 71, and 72, we have the computer operator 266 receiving his computer via an electronic sound or a paper provided by the analyst who will instruct him to schedule the supply for process execution 183) fig. 66 the furnace supply (279) being fig.66 solids and gas and liquid collection from the acid condensers, the removal of slag tailings, solid, gaseous and liquid acid derivatives, automatically determining the speed, the amount, the power and type of power to be supplied in KWh or MWh as shown in the supply control tables in fig. 75 of frame 302 and fig. 76 of the frame 303 for furnace supply 42) fig. 21 opening the frame 319 of FIG. 92, we define the velocity of the circulating water in the coil (41), the opening cap (73) for the ore inlet, the velocity of the addition of TN of the ore (16) the furnace capacity in Kg, the interior vacuum of the furnace in melting moment to avoid excessive oxidation in order to preserve oxygen from air maximum slag temperature, maximum temperature of liquid alloy, maximum temperature in plasma field and high frequency, discharge frequency, discharge time, plasma discharge time, MAT voltage / cc / Ed frequency particularly applied in the CuFeS2 molecule, and in the elements S, Fe, Cu ,. COMPUTER (267): The operator of this computer handles the control of common hydraulic and pneumatic ore supply machines, gas pumping, and solids retention in condensers, slag extrusion, electrode removal (58), and transport to the cell in the process ( 281) through the frame (325) fig. 98, table 337 of FIG. 110

PROCESS (279) COMPLEX ALLOY MERGER

COMPUTER 271: According to the flow chart of fig. 71 the computer operator (271) performs the function of programming the ore fusion power supply resulting in a complex alloy by MAT / cc plasma charge firing, and a high frequency KW / Hz and how the furnace should work at a given temperature. , the working time in hours and days opening table 313 of FIG. 86 and table 315 of FIG. 88 and table (316) dafig. 89 establish the initial data for a scan to find Wd power, Ed voltage, and Ad amperage, in relation to the TN amount and the volume in m3 of ore added to the furnace, opening the scan result control box. which can be programmed manually or automatically via the frame 317 of FIG. COMPUTER (268): The operator of this computer handles the working physicochemical reactions of the process (183) of executing the INDIRECT process gears and stages in process cell (3) (281) and recomposing the complex alloys produced in the process (279). ) With working voltage, energy power spent for execution illustrated in Fig. 90 table (317). COMPUTER (270): This computer's operator performs demand-side sales on stock market quotes by sorting prices according to the classification of products available in stock.

PROCESS (280) HIGH SPEED

According to fig. 66 and 72 is executed via COMPUTER276: the operator of this computer takes care of the working execution of process related machines (280) which is mainly the continuous operation of the rotary kiln (89) of the amount of energy (232) supplied in KW / Hz, and the operation time for heating the ore (16) to a certain temperature being controlled to be poured into the digester (75) through table (321) fig. 94, and fig. 95 (322) proceeding with ore digestion as shown in Table (323) fig. 96, and table 324) fig. Collecting the process-derived gases by liquefying and solubilizing water in the condenser (70) through the frame (325) fig. 98 and table (326) fig.99 COMPUTER (273): The computer operator (273) takes care of the controlled addition of acids into the digester and heated ore into the digester which are solubilizing all metals of interest and forming a slimy slurry. This operator automatically adds pumping to the filter 81, fig. 47, which squeezes this slurry and filters the complex liquid with solubilized metal salts which are directed to the process (281) to gravimetrically extract the metals required by the demand then programmed through table (329) fig. 102 and frame 330 fig. 102.COMPUTER (268): The operator of this computer handles the working physicochemical reactions of process (183) of running the INDIRECT process gears and stages in process cell (3) (281) and recomposing the complex alloys produced in process (289) ) and the electrolyte produced in process 280, determining the working voltage, energy power expended for execution by the flow chart of FIG. 75, (304) fig. Frame 307 fig. 80, frame 308 FIG. 81, frame 310 FIG. 83 frame 311 FIG. 84, table 313 fig. 86, frame 314 fig. 87 ,. table 315 fig. 88, frame 316) fig, 89 resulting in the disynchronization scan of the physical and chemical quantities of frame 317 of fig. The beginning of the march of decomposition of the solubilized elements.COMPUTER (270): The operator of this computer executes the demand for sales quotations on the stock market, classifying prices according to the classification of products available in stock. Opens command menu boxes and dialog boxes on the monitor screen and with some manual adjustments performed manually with the mouse and keyboard of the computer on the monitor screen. Firstly, the process fig, 73 and 74 is chosen and the output is programmed in hours, day, and month, defined on paper by a demand analyst to transfer this data to the process typed in this dialog box. After the concentrated and ground ore in TN is added to the mixer 48 fig. 1 which mixes the electrolyte ore into a viscous mud by agitation, defines the amount to be treated, as will use the value 147,000 TN, then we will start the first gear, opening the process execution program displayed on the computer's monitor screen. a frame 303 opens fig. 76, Cell replenishment page by activating a key by an open mouse click that initiates the first gear, which is the viscous mud-shaped dominium supply gear in the cell compartment (1) by hydraulic pumps to the value of 147,000 TN of ore. that reaching a level would end the addition by a float that drives an automatic relay that turns on the pumps that supply the cell. After completing this first march we started the second gear supplying the cell with the electrodes (5) in the compartment (2) we opened a frame (307) fig. 80, 81 frame (308), 82, frame (309), on the computer monitor referring to the electrode supply page, on this page we have all the necessary information regarding the choice of electrode construction material and chemical formula, the thickness in cm and mm, the total surface area and the initial working weight the total electrodes to complete the value in cm2 of the total working area, with one click we chose the electrode for this first process or the second process stage that currently deforms automatic switches that drive hydraulic and pneumatic machines that suspend the electrodes by positioning them in series or parallel. Third gear: It is necessary to define the chemical formula of the electrolyte to be used as command and by clicking on the supply page in a frame (310) fig. 83, and table 311 fig. 84, which provides the necessary physicochemical information for the electrolyte composition in its volume in m3, according to the chemical nature of the ore to be decomposed proportional to the processing speed. For one more mouse click in this same frame to calculate the initial chemical formula to be applied, the amount of acid in cm3 to be added to the electrolyte that is added when the program activates the automatic relays that presses a switch that sets the addition pumping speed. of the liquid being added slowly until reaching the ideal concentration and working pH and electrochemical resistivity per cm2, this addition is interrupted by sensors that are programmed to turn off when the determined volume has been reached then shut down by the relay system the pumps. After the third correction and chemical formulation of the electrolyte in an appropriate tank is performed, the fourth gear starts in the supply frame (312) fig. 85, of the formulated liquid is clicked with the mouse and begins the addition in m3 / s, at a defined speed of the liquid in the cell until reaching the maximum allowed m3 level for processing that is determined by a float no more than four meters above the ground. which activates a relay switch automatically switching off the pumps, after reaching the electrolyte level programmed by the operator, begins the fourth supply gear that is used the FIRST STAGE frame, opens a table fig. 73, 74, 75, (302) efig. 76 (303), which is the first stage page, setting the electrode polarity with the mouse in a clik triggers automatic relays that adjust the key (115) defining the polarity indicated by the first stage frame displayed on the monitor fig. 74 (301) and 87 Advanced icon, we calculated the decomposition stress Ed. We opened a page called the engineering table. 78 to 83 of this report, which starting from the chemical formula of CuFeS2 Calcopyrite adecomposite ore Copper and iron sulphide being the metallic element of interest sought is the copper which in this table you select in column 1, row 29 by clicking on this point will open a page. refer to the chemical and physical condition information that this cell must work through. I can operate automatically by giving an enter, which schedule will automatically adjust the physical chemical status of the job, or manually as follows: Ex: Copper, column 1, line29, symbol Cu ?, Standard potential volts half acid column 2, E line 29, -0.342 (2). Basic oxidation potential column 3 Eb °, line 29. Density domain, metal, electrolyte, d, column 4 line 29. Valencia of the atom metal searched a, column 5 line 29. Cathode voltage Ec, column 6 line 29, Molecular Conjugation of Metal with Ametals Column7 Ed Row 29. Electrochemical Equivalent in Ampere Hour, E / Ah Column 8, Row29. Amperes per square decimeter column 9, Adm2, line 29. Amperes cm2A / cm2 column 10, line 29. Gram time of metal adhered to electrode (5) recorded by balance (6) gr / h, column 11 line 29. Minimum working temperature ° Cm, column 12 line 29. Maximum working temperature ° CMx, column 13, line 29. Acid potential of electrolyte H20 + H2S04 acid column 14, line 29. Electrode overvoltage with negative polarity Es / column 15, line 29. Overvoltage positive polarity electrodeE / column 16 row 29. Electrode distance in cm A>, A <column 17, 18.line 29. Deposit thickness in millimeters column 21 and / mm row 29, proportional to weight in grams. Chemical element of indicated anode column22 A / ind, line 29. Chemical element of indicated anode cathode column 23 C / ind line29. Solution complex formula column 24 salts row 29. Metals not adhering to the indicated cathode column 25 M <row 29. Ore of origin column26 X. Solubility of ore in electrolyte solution XD, column 27 row 26.Possibility of extraction of associated metals and what is the stage? column 28 row 29. Minimum molar concentration gr / l of solution column 29, Min%, row 29. Favorable precipitation at high concentration comp. (2) reagent recommended acid medium column 30, +0, row 29. Favorable precipitation and high concentration comp. (2) recommended reagent basic medium column 31 b °, line 29. Atomic weight of the wanted metal column 32 m line 29. Once the physicochemical balance within the cell is set, the synchronization page showing the calculated ratio results automatically appears on the monitor screen. 90 frame scan result (317), requesting an enter, clicks the mouse on the OK menu immediately the cell starts working synchronously composing the electrolyte formed of exemplarily: water + sulfuric acid + sodium sulfate, which releases the hydrogen and sodium metals OH - and NaOH - on the electrode surface (13) and on the ore surface which at this stage was transformed into sulfide cathode fig. 2, 3, which receives the electrode electrode (13) and the compartment (1) polarity in which it is positioned negative electrical property attracting these metals in the compartment (1) at this stage the sulfur and other ametals are oxidized and solubilized in sodium desulfate form and sulfuric acid or ametal, leaving hydrolyzed oxidized metals in the form of black hydroxides fig.13, fig. 65 (293). MONITORING: In the first stage picture we can see the digital panel fig. 36, the physicochemical events within the cell and the application of the quantities and the effect results. On the TN / h digital board, let's look at the digits of scale (6) in the increasing direction informing that ometal is depositing. In table Wd we see the decreasing digits of energy in Kwh example: programmed to provide the exact energy of 3,675,000 KWh to extract 40,902 TN of metal which when finished extracting the panel digits will be zeroed as follows: 00,000,000 KWh, then it will sound the alarm warning that the process was successful, resulting in a product as illustrated in fig. 114 wherein the electrode is coarse and rough with copper oxide hydrated CuO formula of red pigmented precipitate adhered to the electrode or accumulated at the bottom of compartment (2) of the stationary and mobile stationary electrogravimetric cell, as shown in fig.118 depicting the hydrated precipitate poured over a paper and fig. 119 being the air-acting electrolyte (345) wherein the precipitate is a mixture of metallic flowers (344) and CuO flowers (49) at the bottom of the cell with a 99% pureness content. And otherwise as illustrated in fig. 116 where the metal element has been metalically extracted adhered to the electrode (5).

Claims (15)

1. DIRECT AND INDIRECT AUTOMATED ELECTROGRAVIMETRIC PROCESS characterized by executing mineral earth treatment methodology of electrogravimetric and thermoelectrogravimetric mining process belonging to the field of extractive mining and electrochemical separation of metals and derivatives, characterized by processing complex crystallines and difficult to treat crystallines ores , previously ground and ground, resistant to chemical attack, insoluble in mineral acids that is performed by this process in two distinct methods, the direct and indirect electrogravimetric process, which uses the machines indicated in the attached drawings of fig. 1 to fig. 120, which by the methods of this process prevent the emission of toxic, solid and gaseous vapors into the environment, characterized by extracting metal directly from ore, such as sulphide, which are ore with unremarkable characteristics without removing oxygen from the air, retaining the ametals in solution and replacing it. Air oxygen by water oxygen, characterized by being different from current operating processes, which emit toxic gases from ametals combined with oxygen from air S02 and other toxic gases in the atmosphere, characterized by being processed at a very low energy cost and absorbing carbon dioxide. because it produces liquid derivatives of salts of the soluble ametals which are reused in the same process thousands of times as a panoramic platform mounted environmental process as illustrated in FIGS. 1, 6, and 32. The technically general method illustrated in the flow charts of this process as illustrated in FIG. 28 and 29 taking from The direct (182) and indirect (183) process directions, characterized by using techniques as illustrated in the flowcharts of figures 37 to 43 of the basic stages of work operation and inventive methodology for the direct and indirect process, characterized by containing techniques of electrochemical methods. of electrogravimetry of inventive process stages, executed in the machines of this direct and indirect process being the; ELECTRONIC GRAMMATIC STATIONARY figures; 2, 3, 5, 7, 8, 12, -13, 14, 15, 16, 19, 53 of an inventive nature applied to perfectly perform this direct and indirect process characterized by processing complex ores as illustrated in FIGS. 34 and 51 and-115 for extracting metals in the purely metallic state and in the chemistry of the CuOH hydroxide precipitate, figs; 114, 115, 118, 119 and Cu metal status, fig. 116, and for extracting rare and noble metals as illustrated in FIG. 120, electrochemical via electrogravimetry with high purity, presenting in one piece fig. 2 and 3, constructed of different shapes and differentiated models, 7, 8, 9, 10, 12, 15, 16, 19, 33, 46, 49, -53, 55, 57, 117, in series (15, 16) with container (3) of iron, glass, concrete, masonry, rubber, plastic, (2) divided into two compartments (1) and (2) separated by walls (9), fig, 4, 54, liquid-impermeable to solids in Siphon-shaped (52), constructed of rubber, plastic, masonry, (245), dug inside with holes (247), where it is filled with sponge, nylon, (246), inert to chemical attack allowing the passage of liquids and preventing the passage of electrode-containing solids (13), in the form of a floor positioned at the bottom of the container (3) compartment (1), constructed of acid etching chemical such as; graphite, lead, platinum, silicon carbide, externally connected by a rod (15), supplied with acidic or basic electrolyte (14), throughout the container (3), and with ground ore (16) in the housing (1) , seated on the electrode (13) fed by a circuit (23) through the conductor (11) that receives the electric charge and decomposes the ore oxidizing and solubilizing the ametals in a first stage, oxidizing the metals with chemical oxygen binding of the water saving the oxygen of the air, and another electrode (5), constructed of common chemical material when applied the second stage according to the attached table: metallic iron sheets, copper, lead, plated with, inert first stage as; plain metal plated with noble metals such as gold platinum, graphite paper (44), silicon carbide, attached to the outside by a rod hook (8), scale (6), which records the bonded metal yield, weight in grams of the electrode (5), analogue (7), and digital fig. 3 on panel 36 and fig. 36, characterized in that it records all the chemical physical information of this process in the panel (36), digitally, in this machine applies to the industrial process methodology of the direct process, fig, 37, 38, 39, 40, 41, are inventive machines powered by electric power. BT for direct process, continuous external energy through an electronic circuit fig. 23 source displayed in the digital panel Ed (17), applied to this process which visualizes the construction forms and models for laboratory and industrial application, and another WAGON MOBILE ELECTROGRAVIMETRIC CELL fig. 9, 31, 55 characterized in that a container (3) of thick iron plates is constructed externally by means of adequate mechanical construction and welds, having in the form of a gigantic single-piece box executing the process in thousands of units in series.31 which moves on iron rails ( 57) contains opening and tops (53) and bottoms (54, 55) internally rubber lined divided into compartments (1) and (2) separated by two walls (9) containing the electrodes (13) positioned in the compartment (1) of chemical material inert, lead, graphite, silicon carbide, and other (5) positioned in the compartments (2) hanging on swing-linked hooks (6) which records the production of analogically (7) edigital (36) metal bonded in the special electronic circuit Fig.24 The quantities of the process are read from the panel (36), supplied in the compartment (1) with ground ore and throughout the container (3) with the acidic or basic electrolyte. uses the same industrial process methodology fig.37, 38, 39, 40, 41 and 55 as the previous cell to process complex ores fig.34 with the characteristic of moving on iron rails powered by continuous electrical power provided by a connected electro-electronic circuit (23) The electrode (13) and (5) characterized by using the cells described above by performing the DIRECT PROCESS and inventive methodology using the techniques of the basic stages of the direct process (182), characterize the inversion of the electrical polarity of the electrodes (13) and (5) to start and complete the process to perfection which is an inventive methodology characterized by ionizing the ore (16) from the electrically (1) compartment that acquires negative polarity in this first stage by applying continuous external electrical force to the electrode (13) supporting the complex ore (16) ground to its decomposition by transferring its negative polarity to moistened omelium via electrochemical characterized by following the technical fig.37 which defines the execution of the first stage of the direct process which performs oxidation of the ore by electrochemical process, characterized by containing a key (115) which defines the domain polarity which is the negative electrical polarity of the electrode (13) at this first stage and another key (32) that defines the adjustable electrical voltage Ed (17) of the circuit (23) that feeds the mineral stationary electrogravimetric cell characterizing the electrode (13) by attracting the hydrogen and alkali metals of group 1 The periodic table is characterized by solubilizing the group 15, 16, 17 metallurgical table ametals by increasing the electrolyte acidity and oxidizing the domain metals (16) in the compartment (1) and the nominium semimetals, characterized by containing the compartment electrode (5) (2) which has positive polarity at this first stage and which is replaced by the electrode of inert chemical composition Chemicals fig. 44.in this first stage Starting the working gear on the key switch 31 of the circuit of FIG. 23 completely oxidizing the ore of compartment (1) which according to the amount of ore and the execution time of the first stage calculates this quantity in Kwh characterized by executing in this same cell the second stageofig.38 containing a key (115) characterized by inverting apolarity of the electrodes in this second inventive process stage and contain the electrode 13 constructed of inert material which in this second process stage takes the positive polarity containing on its surface the oxidized ore fig. 13 marched by the actuation of the key (32) initiating the march the oxidized ore pigmented black decor positively ionized by the electrode (13) characterized by attracting the negative ametals in this second stage of group 15, 16, 17, decomposes in this second stage, solubilizes and breaks its molecules by force of the electric current that continues at a certain voltage supplied by the electronic circuit fig 23 and adjusted in the voltage regulator switch (32) dividing its elements that migrate in opposite directions, the metals to the electrode (5) that at this stage was exchanged by ferrous or copper metal electrodes which extract the solubilized metals of interest from group 8, 9, 10, 11, 12 of the periodic table gravimetrically adhered to the electrode and precipitated as metal hydroxides in the compartment (2) fig. 35 characterized by extracting the solubles in a highly soluble manner, saving from combining these metals with the air oxygen in the electrolyte (14) in this second stage where they remain soluble, performing the third stage fig. 39 the electrolyte (14) is sent to the tank (147) fig. 30 for decanting and filtering and reused in continuous processes, the metal-loaded electrode (5) is removed fig. 114, 116, and scraping the floor of the room (2) by removing the precipitated metal hydroxide (49) fig. 34, 118, 119, neutralizes and the tailings 80 are removed by trusses fig. 32 and discard in abandoned ditches to replace the space, characterized by the fourth stage fig. 40 without removing the cell waste (1) from the cell by washing the waste with clean water, add the electrolyte (202) and set the electrical polarity, and the voltage Ed (17) on the switch (32) starts to operate by activating the switch (31 ) solubilizes the noble and heavy metals of group 8, 9, 10, 11, 12, extracted in a metallic manner by adhering to the electrode (5) or in the form of hydroxidometallic in the compartment (2) fig. 115, 118, 119, characterized by operating with internal energy fig. 5 as a cell element that decomposes the ore by positively ionizing the mineral molecules by attracting the electrolyte solubilizing and attacking and breaking down the molecular crystalline bonding of the conjugate elements to the solubilizing metals and emigrating to the electrode (5) of the compartment (2) characterized by indirectly performing The INDIRECT PROCESS characterized by using the oven fig. 1 industrial thermoelectrogravimetric (42), driven by the circuit-powered switch (218) of figures 25 and 27 which feeds the load-firing oven circuit fig. 27 in MAT / cc / KWh, continuous current plasma and high frequency KHz / KWh charge firing powered by the circuit of figure 25, this inventive feature kiln 21 and 50 which dumped the ore through the opening of the automatic door (73) this ore complex in the field of thermoelectrogravimetric reduction (61) receiving the firing discharged by the two circuits together, is transformed into a complex metallic nature alloy depositing at the bottom of the furnace (65) attracted by the negative polarity electrode (60) then bled and extruded (43) by injection in molds and intended for cells for electrogravimetric decomposition, with the ametals evaporating at high temperature rising (67) to the upper top of the furnace attracted by the positive polarity electrode (59) sucked by the pump (59) the heaviest (71) condense in the condenser (72) and the lightest ones are sent to the gas washer and solubilizer (70), characterized by the process high speed direct using a rotary kiln fig. 48 thermoelectrochemical (89) illustrated in figure 22 operates at high speed powered by the circuit of figure 27 which provides high frequency kWh firing of these details of this process illustrated from a panoramic view in figure 1 and 32 using the respective machines presented for the application of this industrial process illustrated in figures 1, 20, 22, 21, 32 characterized by being executed by DIRECT AND INDIRECT ELECTROGRAVIMETRIC PROCESS and command of an AUTOMATED system, characterized in that its machines and its production are controlled by command of process automation method and digitalized of remote control presented in panoramic way in An innovative process of an inventive nature is attached to the flowcharts in Figures 66 to 72 and to the tables in Figure 73 to 113 in which computers are controlled by Fig. 69. The supply of the direct and indirect process, the operation of all machines in a synchronized manner by using inventive engineering and synchronization tables to accurately perform equation calculations that allow for the expected effect within the machines to extract the sought-after elements of interest, characterized by a common scanning system for graphic pages that define the value of operational greatness. which informs all the physical chemical effects that happen inside the machines by monitoring by sensors and alarms and programming the production in physical energy of KWh. DIRECT AND INDIRECT AUTOMATED ELECTROGRAVIMETRIC PROCESS according to claim 1, characterized in that it is processed using the emphasized process stages and the direct process of basic stages for execution fig. 37 to 41, in the cells of special inventive models fig. 2, 3, 5, 7, 8 characterized in that it is built on its base (3) of glass, plastic and rubber when applied to laboratory use of concrete, masonry and iron when applied to productive industrial construction figure 2, 3, 5, - 7, 8, 9, 12, 15, 19, internally coated with rubber and containing an electrode (13) in the step-shaped housing (1) at the bottom of this cell connected to the circuit of Figure 23 by the lead (11) which is divided into two compartments (1) and (2) by a wall (9) of an inventive nature contain siphon-shaped holes (52) fig. 4 for the purpose of constituting a single chemical state of PH throughout the liquid electrolyte content (14) within the cell reaching the housing (2) containing an electrode (5) connected to the circuit of FIG. 25 by the conductor (10) hanging on an analog scale (6) fig.2 by a rod (8) and on a digital scale fig 3 by a rod (8) connected to the digital panel (36) fig 3 where it records the chemical physical effects. of the process in the digital readers (17), (18), (19), (20), (21), (22), (23), (24), (25), (26), (27), ( 28), (29), (20), (21), (22), (23), (24), (25), (26), (27), (28), (29), (30) , (258), (259), (260), (261), a lever style inverter switch (115) characterized by containing the start of operation switch switch (31) and a grid connection (33) with details construction and electronic connection illustrated basically in fig. 24 with the characteristic of being processed in a mobile cell illustrated in fig. 9 which moves on iron rails (56) its outer base (3) is a constructed iron box, its interior is rubber lined, contains a central compartment (1) containing a floor-shaped electrode (13) fixed to the central doors lower compartments (54) and two side compartments (2) containing two electrodes (5) hanging from digitally-balanced hooks (6) with two lower lateral ports (55) performing the more detailed circular motion direct process in Figure 31 containing four workstations (161). ) that supplies the mobile electrogravimetric cell (161) which runs the tracks (57) counterclockwise, executing the moving process (162) at 180 ° park at station (158) discards the electrolyte and process derivatives through the lower openings in the tank ( 160) follows counterclockwise about 90 ° parking at station (168) discards the tailings and stores the metals (50) and hydroxide metal derivatives (49) clockwise to a waste wash station (159). Direct and indirect automated electrogravimetric process according to claim 1, characterized in that it processes complex and rebel ores fig. 34, 51, 115 use two machines illustrated in Figures 1 and 32 of Stationary and Mobile Electrogravimetric Cell fig. 2, 3, 5, 7, 8, 9, fig. 12 to 19 117 digitized analog to carry out the direct and indirect process which is an electrochemical electrogravimetry process using static techniques fig. 37, 38, 39, 40, 41, designed to perform perfectly this process, which utilizes continuous electrical power provided by circuit fig, 23 which records the chemical chemical effects occurring within the cell container (3) and the electrolyte (14) connected in accordance with the digital circuit fig. 24, and the panel fig. 36, oxidizes the metals contained in the ore of group 8,9, 10, 11, 12 of the periodic table in a first stage fig.12 seconds the technique fig. 37, solubilizing the ametals of group 15,16,17, from the periodic table formed the black hydroxide pigment of metals fig. 13 initiates the second stage by reversing the electrode apolarity and extracting the metals by electrogravimetric force. 4. Automatic and indirect automated electrocardiographic process according to claim 1, characterized in that the electrode (13) in the housing (1) is constructed of inert material such as graphite, lead, platinum, gold, silicon carbide against chemical attack, good material. electrical conductor, floorform positioned at the central base at the bottom of the cell (3) to receive on its surface properly seated ore, lined internally with inert rubber and tar material (15) having an outer connecting rod and connected to the external circuit (23) by conductor (11) fig.2. DIRECT AND INDIRECT AUTOMATED ELECTROGRAVIMETRIC PROCESS according to claim 1, characterized in that the electrode (5) of the cell (3) is fig. 1 and 2 of the housing 2 be constructed of inert material such as graphite fig. 44, lead, platinum, gold, silicon carbide, good electrically conductive material to be used in the first stage, fig. 37 which must be exchanged for another electrode constructed of group 11 and 12 sheet metal from the periodic table when the second stage fig. 38 and 114. A direct and indirect automated electrogravimetric process according to claim 1, characterized in that there is a wall (9) dividing the compartments (1) and (2) according to fig. 9, 54, 57, constructed of plastic, rubber, in two. siphon-shaped comforter plates 52, 247 and a sponge 246 inert acid attacks separating the two plates fig. 54 for laboratory application and masonry and concrete for production industry application as illustrated in FIGS. From 12 to 19 being the dafig partition wall. fig. 9, 54, and 57, which causes the effect of setting a PH value on the entire cell. DIRECT INDIRECT AUTOMATIC ELECTROGRAVIMETRIC PROCEDURE according to claim 1, characterized by the fact that it operates in a digitized manner fig. 3, 36, 24 being fed by the circuit fig. 23 which is digitized by the digital circuit fig. One can read the accurate chemical effect information of the electrolyte by performing the direct process. Automatic and indirect automatic electrogravimetric process according to claim 1, characterized in that the analogous and digital gravimetric recording records the weight of the extracted meta in the compartment (2) adhered to the electrode (5) which is hooked onto the balance rod (8) (6) which connected to the digital circuit fig. 24 the information on the panel is read as shown in figures 3 and 36. Direct and automatic automated electrogravimetric process according to claim 1, characterized in that it operates with internal energy fig. 5 as a cell element that decomposes the ore by positively ionizing the mineral molecules by drawing the solubilized ametals into the appropriate electrolyte and attack decomposes the molecular crystalline bonding of the solubilizing metals and emigrating to the electrode (5) of the compartment (2). A direct and indirect automated electrogravimetric process according to claim 1, characterized in that it is performed indirectly using the electrochemical machine illustrated in figures 21 and 50 which uses a high frequency KWh electric force and a plasma discharge KWh electric power. by electronic circuit fig. 25 and 27 connected to coil 41 which induces a magnetic frequency in the conjugated ground ore molecules. 52 (224, 322) reducing ore fig. 34 in field (61) decomposing the ore as illustrated by asfig. Fig.52 separating the metal and ametal constituents (237, 238, 239, -240,241, 242,243) together in the same time lapse assisted by a direct current plasma discharge firing by the circuit Fig.27 (67) which attracts the metals. for the electrode negative coil (60) and the positive electrode pole ametals (59) by separating the molten alloy (65) in the lower oven bottom pan and the gases and vapors in the upper upper oven and sucked in by the pump (69) the denser ones (71) condense in the capacitor (72). DIRECT AND INDIRECT AUTOMATED ELECTROGRAVIMETRIC PROCESS according to claim 1, characterized in that it is performed at high speed in the indirect direction fig. 22 as illustrated by the drawing of the machine fig. 48, a rotary kiln (89) which heats the ore by a high frequency system circulated by a water cooled copper tube coil (41) that induces the magnetic frequency in the molecular conjugation of the mineral earth fig. 52 by rapidly raising the temperature (87) by pouring the heated ore into the digester (75) which solubilizes the constituent metals by pumping the lamadigeride (76) to the hydraulic filter (82) which squeezes the mud and filters the electrolyte containing the solubilized metal elements and amethets to be extracted by indirect electrogravimetric process. Automatic and indirect automated electrogravimetric process according to claim 1, characterized in that it is processed with the aid of an automation method according to the tables and flow charts attached fig. 66 to 113, which executes the commands of the machines and their working stages described in this programmed process, which digitizes all the physical chemical information (36) fig. 36 of the working process characterized by informing to: qualitative and quantitative chemical formula and domain density and its quantity by weight to be processed in a certain time, characterized by informing to: chemical quantity and the ohmic resistance, PH of the electrolyte used and the metallic molecules solubilized liquids, characterized by reporting and programming: the supply of liquids and solids, characterized by detailed information on the storage of liquids and solids, characterized by precisely informing: the production of metals, derivatives, and their storage, characterized by reporting: the applied power of energy, characterized by reporting: the production speed in tons hour, characterized by reporting the cost and yield of the process, characterized by reporting: the working temperature, characterized by reporting: the replacement of solid eliquid electrodes, characterized by containing: a scanned system secretDecomposition stresses defined in graphs and tables created for the execution of direct and indirect electrogravimetric process in a remote and digitized way remotely in the room or at long distances, characterized by processing the ore through the machines of fig. Annex and deliver to the market a noble product of 99% purity directly from the ore source according to fig. 115, 118, 119, 120. Direct and indirect automated electrogravimetric process according to claim 1, characterized in that it can be used in different mining processes and worldwide research in industrial mining and metal determination from the ore of origin, in various laboratories in large-scale production. High demand scale of electrochemical and thermochemical refining metal extraction and other derivatives such as CuOH metal hydroxide and anhydrous CuO oxide of economic interest with purity content around 99% This project constitutes a revolution in the electrochemical and electrochemical mineral industry in mineral electro-casting With it, it is possible to treat thousands or even millions of tons of primary ore per day, extract millions of tons of refined metal daily in an operation that corresponds to one to five highly controlled and automatically monitored process stages. s alarms and alarms of a specific illustrated automation computer program attached. Without emitting toxic derivatives into the atmosphere such as sulfur and other gases, it does not produce toxic industrial waste from waste in the wild compared to petroleum waste, such as those in large production tar, there is no solution to sort them, which when found It is used in electric tar absorbing harmful oxygen from the air, which protects the oxygen from the air by solubilizing and absorbing the gaseous amines because the present invention is environmentalist. Direct and indirect automated electrogravimetric process according to Claim 1, characterized in that it is generally better to understand the flowchart illustrations of Figures 28, 29 and the flowcharts of Fig. 37 to 43 and of the process automation the flowcharts of the process. of fig. 66 to 72 and the illustration of Figures 1 and 32 showing the mounting of the platform and all the elements of the international periodic table can be extracted from their complex mineral conjugation by the direct and indirect electrogravimetric process described in the soluble, liquid, solid, gaseous, or soluble state. anhydrous solid metal and amorphous hydrometallic wet, in the machines described in this report as stationary and mobile electrogravimetric cells fig. 2e 3 and 9, 12-19, and ourotative stationary thermoelectrogravimetric oven fig. 48, reversing the electrical polarities fig. 64 keys 115 of the electrodes and using corresponding process stages applying external direct current and high frequency BT and MAT electrical power in KHz and MHz with power in KWh provided by the circuit of FIG. 23, 25, 27. Automatic and indirect automated electrogravimetric process according to claim 1, characterized in that running the process with the low cost of production does not create toxic derivatives which are to be emitted into the atmosphere and nature and the cost of the process is highly economical. consumption of 2,548 kwh of electricity for the direct process and 4,572 kwh of energy per ton of copper for the indirect process.