BRPI0416406A - method for producing a catalyst or pre-catalyst suitable to assist in the production of alkenyl alkanoates, composition for catalyzing the production of an alkenyl alkanoate and method for producing alkenyl alkanoates - Google Patents

method for producing a catalyst or pre-catalyst suitable to assist in the production of alkenyl alkanoates, composition for catalyzing the production of an alkenyl alkanoate and method for producing alkenyl alkanoates

Info

Publication number
BRPI0416406A
BRPI0416406A BRPI0416406-7A BRPI0416406A BRPI0416406A BR PI0416406 A BRPI0416406 A BR PI0416406A BR PI0416406 A BRPI0416406 A BR PI0416406A BR PI0416406 A BRPI0416406 A BR PI0416406A
Authority
BR
Brazil
Prior art keywords
catalyst
alkenyl
production
producing
alkanoates
Prior art date
Application number
BRPI0416406-7A
Other languages
Portuguese (pt)
Inventor
Tao Wang
Leslie E Wade
Victor Wong
Valery Sokolovskii
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BRPI0416406A publication Critical patent/BRPI0416406A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J35/51—
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0072—Preparation of particles, e.g. dispersion of droplets in an oil bath
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0248—Coatings comprising impregnated particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds

Abstract

"MéTODO PARA PRODUZIR UM CATALISADOR OU PRé-CATALISADOR ADEQUADO PARA AUXILIAR NA PRODUçãO DE ALCANOATOS DE ALQUENILA, COMPOSIçãO PAPA CATALISAR A PRODUçãO DE UM ALCANOATO DE ALQUENILA E MéTODO DE PRODUçãO DE ALCANOATOS DE ALQUENILA". A presente invenção refere-se a pelo menos quatro diferentes aspectos relacionados com estrutura de catalisadores, métodos de fabricação destes catalisadores e métodos de utilização daqueles catalisadores para fabricar alcanoatos de alquenila. Separadamente ou juntos, os diversos aspectos da invenção referem-se a aperfeiçoar a produção de alcanoatos de alquenila e VA em especial, incluindo a redução de subprodutos e eficiência de produção melhorada. Um primeiro aspecto da presente invenção refere-se a um catalisador único de paládio/ouro ou pré-catalisador (opcionalmente calcinado) que inclui ródio ou outro metal. Um segundo aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador que é baseado em um material de suporte em camadas onde uma camada do material de suporte é substancialmente isenta de componentes catalíticos. Um terceiro aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador sobre um material de suporte que contém zircónia. Um quarto aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador que é produzido a partir de componentes catalíticos substancialmente isentos de cloro."METHOD FOR PRODUCING A PRODUCT CATALYST OR PRE-CATALYST SUITABLE FOR SUPPORTING ALKENYL ALCANOATE PRODUCTION, COMPOSITION TO CATALYST THE PRODUCT OF AN ALKENYL ALCANOATE PRODUCTION". The present invention relates to at least four different aspects related to catalyst structure, methods of manufacturing these catalysts and methods of using those catalysts to manufacture alkenyl alkanoates. Separately or together, the various aspects of the invention relate to improving the production of alkenyl and VA alkanoates in particular, including by-product reduction and improved production efficiency. A first aspect of the present invention relates to a single palladium / gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect relates to a palladium / gold catalyst or precatalyst which is based on a layered support material where a layer of the support material is substantially free of catalytic components. A third aspect concerns a palladium / gold catalyst or pre-catalyst on a zirconia-containing support material. A fourth aspect relates to a palladium / gold catalyst or pre-catalyst that is produced from substantially chlorine-free catalytic components.

BRPI0416406-7A 2003-12-19 2004-11-19 method for producing a catalyst or pre-catalyst suitable to assist in the production of alkenyl alkanoates, composition for catalyzing the production of an alkenyl alkanoate and method for producing alkenyl alkanoates BRPI0416406A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53093603P 2003-12-19 2003-12-19
PCT/US2004/038814 WO2005065821A1 (en) 2003-12-19 2004-11-19 Layered support material for catalysts

Publications (1)

Publication Number Publication Date
BRPI0416406A true BRPI0416406A (en) 2007-01-09

Family

ID=34748748

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0416406-7A BRPI0416406A (en) 2003-12-19 2004-11-19 method for producing a catalyst or pre-catalyst suitable to assist in the production of alkenyl alkanoates, composition for catalyzing the production of an alkenyl alkanoate and method for producing alkenyl alkanoates

Country Status (15)

Country Link
EP (1) EP1694437A1 (en)
JP (1) JP4772694B2 (en)
KR (1) KR100890655B1 (en)
CN (1) CN100569364C (en)
AR (1) AR056250A1 (en)
AU (1) AU2004311900B2 (en)
BR (1) BRPI0416406A (en)
CA (1) CA2547318C (en)
NO (1) NO20062528L (en)
NZ (1) NZ547073A (en)
PL (1) PL380018A1 (en)
RU (1) RU2380154C2 (en)
UA (1) UA94208C2 (en)
WO (1) WO2005065821A1 (en)
ZA (1) ZA200604363B (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2380661A3 (en) * 2004-12-20 2012-02-01 Celanese International Corporation Modified support materials for catalysts
DE102007025362A1 (en) 2007-05-31 2008-12-11 Süd-Chemie AG Doped Pd / Au coated catalyst, process for its preparation and its use
DE102007025443A1 (en) * 2007-05-31 2008-12-04 Süd-Chemie AG Pd / Au coated catalyst containing HfO 2, process for its preparation and its use
DE102007025223A1 (en) 2007-05-31 2008-12-04 Süd-Chemie AG Zirconia-doped VAM shell catalyst, process for its preparation and its use
DE102007025442B4 (en) 2007-05-31 2023-03-02 Clariant International Ltd. Use of a device for producing a coated catalyst and coated catalyst
DE102007025444A1 (en) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM shell catalyst, process for its preparation and its use
CN101428238B (en) * 2007-11-07 2011-02-09 中国石油化工股份有限公司上海石油化工研究院 Layered composite carrier with thermal stability
DE202008017277U1 (en) * 2008-11-30 2009-04-30 Süd-Chemie AG catalyst support
JP2011121048A (en) * 2009-12-09 2011-06-23 Rohm & Haas Co Method for blending and loading solid catalyst material into tubular structure
DE102011101459A1 (en) * 2011-05-13 2012-11-15 Süd-Chemie AG Process for the preparation of a metal-containing coated catalyst without Zwischenkalzinierung
DE102012008714A1 (en) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Pre-impregnation of coated catalysts with an acetate
TWI510293B (en) * 2012-09-19 2015-12-01 Clariant Int Ltd Copper-promoted shell catalyst for producing alkenyl carboxylic acid esters, and the method for producing said copper-promoted shell catalyst.
US10525448B2 (en) 2015-07-22 2020-01-07 Basf Corporation High geometric surface area catalysts for vinyl acetate monomer production
CN105478154B (en) * 2015-12-14 2019-09-03 中石化南京催化剂有限公司 One kind being used for the agent of high activity fluid catalytic
KR102309341B1 (en) * 2017-11-30 2021-10-05 롯데케미칼 주식회사 Catalyst support having a core-shell structure with enhanced thermal stability and preparation method thereof
EP4201519A1 (en) 2021-12-21 2023-06-28 Clariant International Ltd Shell catalyst for producing alkenyl carboxylic acid esters with improved pd and au distribution
EP4201523A1 (en) 2021-12-21 2023-06-28 Clariant International Ltd Shell catalyst for producing alkenyl carboxylic acid esters with improved pd distribution

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FR2469204A1 (en) * 1979-11-12 1981-05-22 Inst Francais Du Petrole NEW WATER VAPOR DEALKYLATION CATALYSTS OF AROMATIC HYDROCARBONS
DE19501891C1 (en) * 1995-01-23 1996-09-26 Degussa Process for the preparation of a supported catalyst and its use for the production of vinyl acetate
IN188013B (en) * 1995-05-23 2002-08-10 Hoechst Celanese Corp
US5705679A (en) * 1996-04-02 1998-01-06 Nicolau; Ioan Honeycomb catalyst for vinyl acetate synthesis
DE19613791C2 (en) * 1996-04-04 2002-01-31 Celanese Chem Europe Gmbh Catalyst, process for its production and process for the production of vinyl acetate
SA97180048B1 (en) * 1996-05-24 2005-12-21 هوكست سيلانس كوربوريشن HETEROGENEOUS BIMETALLIC VINYL ACETATE FOR THE PRODUCTION OF VINYL ACETATE
WO1999039824A1 (en) * 1998-02-05 1999-08-12 Engelhard Corporation Suppression of aging for pd-au vinyl acetate monomer catalyst
ID26891A (en) * 1998-06-02 2001-02-15 Celanese Internasional Corp VINYL ACETATE CATALYST CONSIST OF METAL AND GOLD PALLADIUMS MADE WITH AURATIC POTASSIUM
DE19827844A1 (en) * 1998-06-23 1999-12-30 Aventis Res & Tech Gmbh & Co Production of shell catalysts useful in e.g. hydrogenation and oxidation, especially gas phase production of vinyl acetate
JP2000024518A (en) * 1998-07-10 2000-01-25 Tokyo Roki Co Ltd Production of catalyst device
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Also Published As

Publication number Publication date
AU2004311900A1 (en) 2005-07-21
RU2006119178A (en) 2007-12-20
CN1929916A (en) 2007-03-14
AR056250A1 (en) 2007-10-03
RU2380154C2 (en) 2010-01-27
CA2547318A1 (en) 2005-07-21
NO20062528L (en) 2006-07-03
KR100890655B1 (en) 2009-03-26
ZA200604363B (en) 2007-10-31
NZ547073A (en) 2010-05-28
CN100569364C (en) 2009-12-16
EP1694437A1 (en) 2006-08-30
JP4772694B2 (en) 2011-09-14
CA2547318C (en) 2010-11-02
AU2004311900B2 (en) 2008-10-02
KR20060100454A (en) 2006-09-20
PL380018A1 (en) 2006-12-11
WO2005065821A1 (en) 2005-07-21
JP2007514540A (en) 2007-06-07
UA94208C2 (en) 2011-04-26

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Legal Events

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O E 13 DA LPI.

B09B Patent application refused [chapter 9.2 patent gazette]

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