BRPI0415451A - monitoramento e controle da polimerização usando indicadores de avanço melhorados - Google Patents
monitoramento e controle da polimerização usando indicadores de avanço melhoradosInfo
- Publication number
- BRPI0415451A BRPI0415451A BRPI0415451-7A BRPI0415451A BRPI0415451A BR PI0415451 A BRPI0415451 A BR PI0415451A BR PI0415451 A BRPI0415451 A BR PI0415451A BR PI0415451 A BRPI0415451 A BR PI0415451A
- Authority
- BR
- Brazil
- Prior art keywords
- control
- monitoring
- reactor
- polymerization
- conditions
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1809—Controlling processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0033—Optimalisation processes, i.e. processes with adaptive control systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
- B01J19/1812—Tubular reactors
- B01J19/1837—Loop-type reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/00108—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/002—Sensing a parameter of the reaction system inside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00193—Sensing a parameter
- B01J2219/00195—Sensing a parameter of the reaction system
- B01J2219/00202—Sensing a parameter of the reaction system at the reactor outlet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00209—Control algorithm transforming a sensed parameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00211—Control algorithm comparing a sensed parameter with a pre-set value
- B01J2219/00218—Dynamically variable (in-line) parameter values
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00191—Control algorithm
- B01J2219/00222—Control algorithm taking actions
- B01J2219/00227—Control algorithm taking actions modifying the operating conditions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00243—Mathematical modelling
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Automation & Control Theory (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"MONITORAMENTO E CONTROLE DA POLIMERIZAçãO USANDO INDICADORES DE AVANçO MELHORADOS". A presente invenção refere-se de uma forma geral aos métodos de monitoramento e controle de reações de polimerização incluindo as reações que produzem produtos poliméricos multimodais usando múltiplos catalisadores em um reator único. As modalidades da invenção fornecem métodos de rapidamente monitorar e controlar as reações de polimerização sem a necessidade de experimentar e testar as propriedades polimóricas. O método usa dados de controle do reator e dados de inventário do material em uma função de indicador de avanço matemática para controlar as condições do reator, e desse modo os produtos produzidos sob estas condições.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51235503P | 2003-10-17 | 2003-10-17 | |
US51250203P | 2003-10-17 | 2003-10-17 | |
PCT/US2004/032174 WO2005040227A2 (en) | 2003-10-17 | 2004-09-30 | Polymerization monitoring and control using improved leading indicators |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0415451A true BRPI0415451A (pt) | 2006-12-19 |
BRPI0415451B1 BRPI0415451B1 (pt) | 2013-11-26 |
Family
ID=35414966
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0415451-7B1A BRPI0415451B1 (pt) | 2003-10-17 | 2004-09-30 | Método de polimerização de olefina e método de obter o controle de um indicador de avanço em uma reação de polimerização de fase gasosa em um reator de polimerização |
BRPI0415515-7A BRPI0415515B1 (pt) | 2003-10-17 | 2004-09-30 | Métodos para calcular um valor-alvo de indicador conducente para controlar um reator de polimerização |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0415515-7A BRPI0415515B1 (pt) | 2003-10-17 | 2004-09-30 | Métodos para calcular um valor-alvo de indicador conducente para controlar um reator de polimerização |
Country Status (10)
Country | Link |
---|---|
US (2) | US7838605B2 (pt) |
EP (2) | EP1732954B1 (pt) |
JP (2) | JP2007508444A (pt) |
CN (3) | CN100579990C (pt) |
AR (2) | AR046181A1 (pt) |
BR (2) | BRPI0415451B1 (pt) |
CA (2) | CA2542736A1 (pt) |
RU (2) | RU2361883C2 (pt) |
TW (2) | TW200523272A (pt) |
WO (2) | WO2005040227A2 (pt) |
Families Citing this family (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1336625A1 (en) * | 2002-02-14 | 2003-08-20 | Novolen Technology Holdings C.V. | Solid catalytic component and catalytic system of the Ziegler-Natta type, process for their preparation and their use in the polymerisation of alk-1-enes |
US8058366B2 (en) * | 2003-10-17 | 2011-11-15 | Univation Technologies, Llc | Polymerization monitoring and method of selecting leading indicators |
US7321015B2 (en) * | 2004-12-07 | 2008-01-22 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
US7323523B2 (en) * | 2004-12-07 | 2008-01-29 | Nova Chemicals (International) S.A. | Adjusting polymer characteristics through process control |
US7790816B2 (en) * | 2006-08-04 | 2010-09-07 | Univation Technologies, Llc | Method of maintaining heat transfer capacity in a polymerization reaction system |
US7847036B2 (en) | 2006-12-18 | 2010-12-07 | Univation Technologies, Llc | Method for reducing and/or preventing production of excessively low density polymer product during polymerization transitions |
EP2055721A1 (en) * | 2007-11-05 | 2009-05-06 | Total Petrochemicals Research Feluy | Method for optimising the transition from one polymer grade to another |
US8876942B2 (en) * | 2007-12-27 | 2014-11-04 | Univation Technologies, Llc | Systems and methods for removing entrained particulates from gas streams, and reactor systems |
EP2172490A1 (en) * | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Controlled polymerisation process |
WO2010077606A1 (en) * | 2008-12-08 | 2010-07-08 | Rensselaer Polytechnic Institute | Redox-initiated cationic polymerization using vapor-state reducing agents |
US8822610B2 (en) * | 2008-12-22 | 2014-09-02 | ATRP Solutions, Inc. | Control over controlled radical polymerization processes |
US8940842B2 (en) | 2012-09-24 | 2015-01-27 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations |
US9926390B2 (en) | 2012-09-28 | 2018-03-27 | Ineos Europe Ag | Method for production of polymer |
US8957168B1 (en) * | 2013-08-09 | 2015-02-17 | Chevron Phillips Chemical Company Lp | Methods for controlling dual catalyst olefin polymerizations with an alcohol compound |
TWI526972B (zh) * | 2013-12-24 | 2016-03-21 | 財團法人工業技術研究院 | 聚合烯類的融熔指數推估方法 |
US9469698B2 (en) * | 2014-04-29 | 2016-10-18 | Chevron Phillips Chemical Company Lp | Process for forming polyolefins |
WO2015197558A1 (en) * | 2014-06-25 | 2015-12-30 | Basell Polyolefine Gmbh | Process for controlling an ethylene polymerization process |
CN105327656A (zh) * | 2014-08-06 | 2016-02-17 | 南京化工职业技术学院 | 一种多工艺气固相反应装置 |
KR102202990B1 (ko) * | 2014-10-01 | 2021-01-13 | 어드밴스드 폴리머 모니터링 테크놀로지스, 인크. | 자동 연속 온라인 모니터링을 사용한 중합체 반응 및 가공의 제어를 위한 시스템 및 방법 |
CA2967415C (en) * | 2014-11-25 | 2023-06-13 | Univation Technologies, Llc | Methods of monitoring and controlling the melt index of a polyolefin product during production |
KR102001610B1 (ko) * | 2016-03-31 | 2019-10-01 | 주식회사 엘지화학 | 고분자 구조의 정량 분석방법 및 분석장치 |
WO2018045231A1 (en) * | 2016-08-31 | 2018-03-08 | Advanced Polymer Monitoring Technologies, Inc., Dba/Fluence Analytics | Device and methods to actively control the production of multi-stage polymer production |
CN109863178B (zh) * | 2016-10-28 | 2021-11-16 | 尤尼威蒂恩技术有限责任公司 | 控制反应器分流和产物参数 |
CA3046800A1 (en) | 2016-12-15 | 2018-06-21 | Univation Technologies, Llc | Rating polymerization processes |
WO2018118258A1 (en) * | 2016-12-20 | 2018-06-28 | Exxonmobil Chemical Patents Inc. | Methods for controlling start up conditions in polymerization processes |
US11098139B2 (en) * | 2018-02-28 | 2021-08-24 | Chevron Phillips Chemical Company Lp | Advanced quality control tools for manufacturing bimodal and multimodal polyethylene resins |
EP3584726A1 (en) * | 2018-06-18 | 2019-12-25 | Covestro Deutschland AG | Method and computer system for determining polymeric product properties |
CN111748049B (zh) * | 2019-03-27 | 2021-07-16 | 中国石油化工股份有限公司 | 一种烯烃聚合方法及系统 |
CN112195695B (zh) * | 2020-09-27 | 2022-03-22 | 四川紫荆花开智能网联汽车科技有限公司 | 一种智能网联汽车动态封闭测试系统 |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4243619A (en) * | 1978-03-31 | 1981-01-06 | Union Carbide Corporation | Process for making film from low density ethylene hydrocarbon copolymer |
US4588790A (en) * | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
US4543399A (en) * | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
FR2625506B1 (fr) * | 1987-12-31 | 1992-02-21 | Bp Chimie Sa | Procede et appareillage de fabrication de polymeres controlee a l'aide d'un systeme de regulation comprenant un spectrophotometre infrarouge |
US5151474A (en) * | 1990-02-16 | 1992-09-29 | The Dow Chemical Company | Process control method for manufacturing polyolefin |
US5352749A (en) * | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
US5436304A (en) * | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
US5462999A (en) * | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
KR100190268B1 (ko) * | 1993-04-26 | 1999-06-01 | 에인혼 해롤드 | 유동상에서 단량체를 중합시키는 방법 |
US5326853A (en) * | 1993-09-16 | 1994-07-05 | Gencorp Inc. | Low formaldehyde, high gel fraction latex binder |
US5525678A (en) * | 1994-09-22 | 1996-06-11 | Mobil Oil Corporation | Process for controlling the MWD of a broad/bimodal resin produced in a single reactor |
BE1009406A3 (fr) * | 1995-06-09 | 1997-03-04 | Solvay | Methode de regulation de procedes de synthese de produits chimiques. |
US6207606B1 (en) * | 1998-05-15 | 2001-03-27 | Univation Technologies, Llc | Mixed catalysts and their use in a polymerization process |
DE19823599A1 (de) * | 1998-05-27 | 1999-12-09 | Beb Erdgas & Erdoel Gmbh | Verfahren und Vorrichtungen zur Überwachung von Anlagen der chemischen Industrie |
US6218484B1 (en) * | 1999-01-29 | 2001-04-17 | Union Carbide Chemicals & Plastics Technology Corporation | Fluidized bed reactor and polymerization process |
BR9906022A (pt) | 1999-12-30 | 2001-09-25 | Opp Petroquimica S A | Processo para a produção controlada de polietileno e seus copolìmeros |
US6723804B1 (en) * | 2000-11-03 | 2004-04-20 | Chevron Phillips Chemical Company, Lp | Monitoring and control of slurry processes for polymerizing olefins |
CA2460316A1 (en) * | 2001-09-11 | 2003-03-20 | Exxonmobil Chemical Patents Inc. | Method for preparing polyolefins |
US7799877B2 (en) | 2001-11-15 | 2010-09-21 | Univation Technologies, Llc | Polymerization monitoring and control using leading indicators |
-
2004
- 2004-09-28 US US10/953,263 patent/US7838605B2/en not_active Expired - Fee Related
- 2004-09-29 US US10/953,262 patent/US7585923B2/en not_active Expired - Fee Related
- 2004-09-30 CA CA002542736A patent/CA2542736A1/en not_active Abandoned
- 2004-09-30 CN CN200480028781A patent/CN100579990C/zh not_active Expired - Fee Related
- 2004-09-30 CN CN2008101701003A patent/CN101539758B/zh not_active Expired - Fee Related
- 2004-09-30 RU RU2006116624/04A patent/RU2361883C2/ru not_active IP Right Cessation
- 2004-09-30 RU RU2006116625/04A patent/RU2342402C2/ru not_active IP Right Cessation
- 2004-09-30 JP JP2006535526A patent/JP2007508444A/ja not_active Abandoned
- 2004-09-30 BR BRPI0415451-7B1A patent/BRPI0415451B1/pt not_active IP Right Cessation
- 2004-09-30 JP JP2006535525A patent/JP2007509205A/ja not_active Abandoned
- 2004-09-30 CN CNB2004800303210A patent/CN100535019C/zh not_active Expired - Fee Related
- 2004-09-30 EP EP04789353A patent/EP1732954B1/en not_active Expired - Fee Related
- 2004-09-30 WO PCT/US2004/032174 patent/WO2005040227A2/en active Application Filing
- 2004-09-30 WO PCT/US2004/032173 patent/WO2005040226A2/en active Application Filing
- 2004-09-30 EP EP04785316A patent/EP1675877B1/en not_active Expired - Fee Related
- 2004-09-30 BR BRPI0415515-7A patent/BRPI0415515B1/pt not_active IP Right Cessation
- 2004-09-30 CA CA002542378A patent/CA2542378A1/en not_active Abandoned
- 2004-10-13 TW TW093131049A patent/TW200523272A/zh unknown
- 2004-10-13 TW TW093131050A patent/TW200517404A/zh unknown
- 2004-10-15 AR ARP040103744A patent/AR046181A1/es unknown
- 2004-10-20 AR ARP040103745A patent/AR046117A1/es unknown
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BRPI0415451A (pt) | monitoramento e controle da polimerização usando indicadores de avanço melhorados | |
WO2009149328A3 (en) | Methods and instrumentation for during-synthesis monitoring of polymer functional evolution | |
BRPI0513057A (pt) | produção de polìmero em condições supercrìticas | |
BR0313749A (pt) | Microesferas ocas sintéticas | |
BR112014004556A2 (pt) | banda de rodagem de pneu com melhorada tração no seco/na neve | |
BR0116006A (pt) | Processo para produção de dispersões poliméricas água-em-água | |
BRPI0409116A (pt) | método e sistema para avaliação sistemática de parámetros de avaliação de equipamento técnico | |
BR0309947A (pt) | Processo para a produção de camadas de polìmero | |
BRPI0920242B8 (pt) | processo para a preparação de polímero superabsorvente contendo argila | |
DE602004014350D1 (de) | Expandierbare vinylaromatische polymere und verfahren zu ihrer herstellung | |
BRPI0411340A (pt) | conservante particulado de madeira e método para produzir o mesmo | |
MY152868A (en) | Method for producing water-absorbent polymer particles with a higher permeability by polymerising droplets of a monomer solution | |
BRPI0613715A8 (pt) | Método e aparelho para dimensionar um membro | |
BR0014379A (pt) | Fabricação de um produto de olefina a partir de um oxigenato | |
BRPI0516374A (pt) | reatores de polimerização tubulares e polìmeros feitos nos mesmos | |
BRPI1010460A8 (pt) | Método para monitoração da condição de um aparelho localizado em uma instalação submersa e meio de monitoração de condição para a monitoração de um componente de uma instalação submersa | |
WO2009009361A3 (en) | Methods for melt-processing thermoplastic fluoropolymers | |
BRPI0605532A8 (pt) | Método para formar um selo frio em uma película polimérica | |
Mahajan et al. | Mechanisms of crazing in glassy polymers revealed by molecular dynamics simulations | |
MX2010000003A (es) | Neumatico que incluye hendiduras segmentadas. | |
Fan et al. | Glass interface effect on high-strain-rate tensile response of a soft polyurethane elastomeric polymer material | |
BRPI0801008A2 (pt) | composiÇço catalisadora Á base de nÍquel | |
BR0213922A (pt) | Processo para a fabricação de pelotas expansìveis e referido produto | |
Nguyen | Kinetics of mechanochemical degradation by gel permeation chromatography | |
EP2241419A3 (de) | Vorrichtung zum Aufschneiden eines Lebensmittelprodukts |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 30/09/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 15A ANUIDADE. |
|
B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2533 DE 23-07-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |