BR9607652A - Compound of 4-acyl-amino-piperdin n-oxide composed of processes for the preparation of a 4-acyl-amino-piperdin n-oxide and purification by distillation of monomers that undergo polymerization via free radicals using a 4-n-oxide -acyl-amino-piperidine mixture and solid or liquid organic material - Google Patents

Compound of 4-acyl-amino-piperdin n-oxide composed of processes for the preparation of a 4-acyl-amino-piperdin n-oxide and purification by distillation of monomers that undergo polymerization via free radicals using a 4-n-oxide -acyl-amino-piperidine mixture and solid or liquid organic material

Info

Publication number
BR9607652A
BR9607652A BR9607652A BR9607652A BR9607652A BR 9607652 A BR9607652 A BR 9607652A BR 9607652 A BR9607652 A BR 9607652A BR 9607652 A BR9607652 A BR 9607652A BR 9607652 A BR9607652 A BR 9607652A
Authority
BR
Brazil
Prior art keywords
acyl
amino
oxide
piperdin
distillation
Prior art date
Application number
BR9607652A
Other languages
Portuguese (pt)
Inventor
Andreas Koch
Gregor Tremmel
Konrad Mitulla
Alexander Aumuller
Holger Herbst
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of BR9607652A publication Critical patent/BR9607652A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/30—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing heterocyclic ring with at least one nitrogen atom as ring member
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D211/00—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings
    • C07D211/92—Heterocyclic compounds containing hydrogenated pyridine rings, not condensed with other rings with a hetero atom directly attached to the ring nitrogen atom
    • C07D211/94—Oxygen atom, e.g. piperidine N-oxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/59—Hydrogenated pyridine rings

Abstract

PCT No. PCT/EP96/01122 Sec. 371 Date Sep. 22, 1997 Sec. 102(e) Date Sep. 22, 1997 PCT Filed Mar. 15, 1996 PCT Pub. No. WO96/29311 PCT Pub. Date Sep. 26, 19964-Acylaminopiperidine N-oxides IaA1B1(Ia)where A1 is hydrogen or an organic radical and B1 is a radical IIa where R1-R4 are each C1-C4-alkyl and R1 and R2, on the one hand, and R3 and R4, on the other hand, may furthermore be bonded to form a 5-membered or 6-membered ring, R5 is H or C114 C4-alkyl and R6 is H or C1-C18-alkyl, are used for stabilizing organic materials against the harmful effect of free radicals, particularly in the distillation of monomers which undergo free radical polymerization, especially styrene.
BR9607652A 1995-03-21 1996-03-15 Compound of 4-acyl-amino-piperdin n-oxide composed of processes for the preparation of a 4-acyl-amino-piperdin n-oxide and purification by distillation of monomers that undergo polymerization via free radicals using a 4-n-oxide -acyl-amino-piperidine mixture and solid or liquid organic material BR9607652A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19510184A DE19510184A1 (en) 1995-03-21 1995-03-21 4-acylaminopiperidine-N-oxyls
PCT/EP1996/001122 WO1996029311A1 (en) 1995-03-21 1996-03-15 4-acylamino piperidin-n-oxyls

Publications (1)

Publication Number Publication Date
BR9607652A true BR9607652A (en) 1998-06-16

Family

ID=7757248

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9607652A BR9607652A (en) 1995-03-21 1996-03-15 Compound of 4-acyl-amino-piperdin n-oxide composed of processes for the preparation of a 4-acyl-amino-piperdin n-oxide and purification by distillation of monomers that undergo polymerization via free radicals using a 4-n-oxide -acyl-amino-piperidine mixture and solid or liquid organic material

Country Status (19)

Country Link
US (1) US5922244A (en)
EP (1) EP0815082B1 (en)
JP (1) JP4152435B2 (en)
KR (1) KR100413167B1 (en)
CN (1) CN1181056C (en)
AT (1) ATE212014T1 (en)
AU (1) AU5144496A (en)
BG (1) BG101836A (en)
BR (1) BR9607652A (en)
CA (1) CA2211902A1 (en)
CZ (1) CZ274397A3 (en)
DE (2) DE19510184A1 (en)
EA (1) EA199700246A1 (en)
ES (1) ES2171659T3 (en)
NO (1) NO974336D0 (en)
PL (1) PL322309A1 (en)
SK (1) SK108497A3 (en)
TW (1) TW326446B (en)
WO (1) WO1996029311A1 (en)

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DE59704135D1 (en) * 1996-06-05 2001-09-13 Basf Ag MIXTURES, CONTAINING MONOMERS AND STABILIZERS
DE69710163T2 (en) * 1996-12-02 2002-10-02 Ondeo Nalco Energy Serv Lp Inhibition of the polymerization of vinyl aromatic monomers
DE19651307A1 (en) 1996-12-10 1998-06-18 Basf Ag Mixtures of compounds containing vinyl group-containing compounds and stabilizers
US5932735A (en) * 1997-06-13 1999-08-03 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-hydroxy-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
US5928558A (en) * 1997-06-13 1999-07-27 Ciba Specialty Chemicals Corporation Derivatives of 1-oxyl-4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
DE19725519A1 (en) 1997-06-17 1998-12-24 Basf Ag Mixture of substances containing compounds containing vinyl groups and stabilizers
US6447644B1 (en) 1997-07-23 2002-09-10 Ciba Specialty Chemicals Corporation Inhibition of pulp and paper yellowing using nitroxides, hydroxylamines and other coadditives
WO1999005108A1 (en) 1997-07-23 1999-02-04 Ciba Specialty Chemicals Holding Inc. Inhibition of pulp and paper yellowing using nitroxides and other coadditives
EP1056711B1 (en) 1997-08-07 2004-10-06 Basf Aktiengesellschaft Process for stabilising (metha)acrylic esters against unwanted radical polymerisation
US6864313B2 (en) * 1998-06-25 2005-03-08 Ciba Specialty Chemicals Corp. Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
TWI246519B (en) 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
CA2337032C (en) 1998-07-14 2008-12-02 Glen Thomas Cunkle Derivatives of 1-oxyl-4-hydroxy- or 4-amino-2,2,6,6-tetramethylpiperidine as polymerization inhibitors for (meth)acrylate monomers
US6008359A (en) * 1998-09-03 1999-12-28 Isp Investments Inc. Piperidine antioxidants and compositions therewith for preventing the fading of artificial hair dye
DE19850625A1 (en) * 1998-11-03 2000-05-04 Basf Ag Process for the preparation of nitroxyl compounds of secondary amines
DE19922103A1 (en) * 1999-05-17 2000-11-23 Basf Ag Inhibiting polymerisation of vinyl monomers using composition containing nitroxyl compound, a preferably aromatic nitro compound as retarder, oxygen and optionally transition metal compound and co-stabilizer
US6300533B1 (en) * 1999-08-16 2001-10-09 Uniroyal Chemical Company, Inc. Inhibition of polymerization of ethylenically unsaturated monomers
KR100763663B1 (en) * 1999-12-03 2007-10-04 유니로얄 캐미칼 캄파니, 인크. Composition and method for inhibiting polymerization and polymer growth
CN100441551C (en) * 2000-10-16 2008-12-10 尤尼罗亚尔化学公司 C-nitrosoaniline compounds and their blends as polymerization inhibitors
US6685823B2 (en) 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
DE10223613B4 (en) * 2002-05-27 2006-01-05 Basf Ag Process for the anionic polymerization of styrene monomers and their use
US7696290B2 (en) * 2004-12-03 2010-04-13 Crompton Corporation Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors
KR101276975B1 (en) * 2005-02-04 2013-06-19 켐트라 코포레이션 Means for controlling the exothermic reaction of styrenic monomers with sulfonic acids
DE102008040401A1 (en) 2007-07-20 2009-01-22 Basf Se Monomer composition, useful for polymerization reaction, comprises liquid N-vinyl-epsilon-caprolactam and a N-oxyl-compound of a secondary amine, which carries no hydrogen atoms at the alpha-carbon atom
DE102008042101A1 (en) 2007-09-24 2009-04-02 Basf Se Monomer composition, comprises vinyl ether having at least two vinyl groups and a stabilizer comprising N-oxyl compound of a secondary amine and/or a phenol derivative
EP2450400A3 (en) * 2008-08-28 2012-08-08 Basf Se Stabilisers for inanimate organic materials
JP6398480B2 (en) * 2014-07-15 2018-10-03 Jnc株式会社 Diamine, polyamic acid or derivative thereof, liquid crystal aligning agent, liquid crystal alignment film, and liquid crystal display element
JP6877366B2 (en) 2015-06-17 2021-05-26 ビーエイエスエフ・ソシエタス・エウロパエアＢａｓｆ Ｓｅ Composition for Immediately Stopping Radical Polymerization
CN108586320B (en) * 2018-04-24 2020-05-19 宿迁联盛科技股份有限公司 Polymeric rubber stabilizer and preparation method thereof
JP7399468B2 (en) * 2020-01-24 2023-12-18 国立大学法人東海国立大学機構 organic friction modifier

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SU1027150A1 (en) * 1981-10-21 1983-07-07 Научно-Исследовательский Институт Механики И Физики При Саратовском Ордена Трудового Красного Знамени Государственном Университете Им.Н.Г.Чернышевского Process for stabilizing styrene of methylmethacrylate
JPS58194931A (en) * 1982-05-07 1983-11-14 Adeka Argus Chem Co Ltd Synthetic resin composition
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DE3738736A1 (en) * 1987-11-14 1989-05-24 Basf Ag 4-FORMYLAMINOPIPERIDE DERIVATIVES AND THE USE THEREOF AS STABILIZERS
US5254760A (en) * 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
ES2126185T3 (en) * 1994-08-19 1999-03-16 Huels Chemische Werke Ag INHIBITION OF THE POLYMERIZATION OF STYRENE.

Also Published As

Publication number Publication date
BG101836A (en) 1998-09-30
EA199700246A1 (en) 1998-02-26
MX9706337A (en) 1998-07-31
CA2211902A1 (en) 1996-09-26
US5922244A (en) 1999-07-13
JPH11502212A (en) 1999-02-23
ATE212014T1 (en) 2002-02-15
CN1179150A (en) 1998-04-15
SK108497A3 (en) 1998-03-04
TW326446B (en) 1998-02-11
KR19980703127A (en) 1998-10-15
KR100413167B1 (en) 2004-04-28
EP0815082A1 (en) 1998-01-07
NO974336L (en) 1997-09-19
DE59608597D1 (en) 2002-02-21
AU5144496A (en) 1996-10-08
PL322309A1 (en) 1998-01-19
EP0815082B1 (en) 2002-01-16
NO974336D0 (en) 1997-09-19
DE19510184A1 (en) 1996-09-26
WO1996029311A1 (en) 1996-09-26
CZ274397A3 (en) 1998-01-14
ES2171659T3 (en) 2002-09-16
CN1181056C (en) 2004-12-22
JP4152435B2 (en) 2008-09-17

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08G Application fees: restoration [chapter 8.7 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 15/08/2006, OBSERVADAS AS CONDICOES LEGAIS.

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 15/08/2016