BR112022005043A2 - Composição de catalisador e sistema com vida útil estendida - Google Patents
Composição de catalisador e sistema com vida útil estendidaInfo
- Publication number
- BR112022005043A2 BR112022005043A2 BR112022005043A BR112022005043A BR112022005043A2 BR 112022005043 A2 BR112022005043 A2 BR 112022005043A2 BR 112022005043 A BR112022005043 A BR 112022005043A BR 112022005043 A BR112022005043 A BR 112022005043A BR 112022005043 A2 BR112022005043 A2 BR 112022005043A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- composition
- shelf life
- extended shelf
- improved
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/78—Benzoic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6541—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof and metals of C08F4/64 or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/14—Preparation of carboxylic acid esters from carboxylic acid halides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/651—Pretreating with non-metals or metal-free compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
- C08F4/6543—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/27—Amount of comonomer in wt% or mol%
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/35—Crystallinity, e.g. soluble or insoluble content as determined by the extraction of the polymer with a solvent
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Composição de catalisador de Ziegler-Natta é divulgada. A composição de catalisador inclui um doador de elétron interno com cinética de polimerização melhorada, um tempo de vida longo, estereosseletividade melhorada e/ou resposta de hidrogênio melhorada.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201962902048P | 2019-09-18 | 2019-09-18 | |
PCT/US2020/050042 WO2021055212A1 (en) | 2019-09-18 | 2020-09-10 | Catalyst composition and system having extended lifetime |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112022005043A2 true BR112022005043A2 (pt) | 2022-07-05 |
Family
ID=74883177
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112022005043A BR112022005043A2 (pt) | 2019-09-18 | 2020-09-10 | Composição de catalisador e sistema com vida útil estendida |
Country Status (12)
Country | Link |
---|---|
US (1) | US11945896B2 (pt) |
EP (1) | EP4031587A4 (pt) |
JP (1) | JP2022549143A (pt) |
KR (1) | KR20220085772A (pt) |
CN (1) | CN114729067A (pt) |
AR (1) | AR120023A1 (pt) |
BR (1) | BR112022005043A2 (pt) |
CA (1) | CA3151380A1 (pt) |
CO (1) | CO2022003698A2 (pt) |
MX (1) | MX2022003252A (pt) |
TW (1) | TW202118798A (pt) |
WO (1) | WO2021055212A1 (pt) |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1098272B (it) * | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
US5124298A (en) | 1990-10-22 | 1992-06-23 | Shell Oil Company | Olefin polymerization catalyst |
FI90248C (fi) | 1991-11-29 | 1994-01-10 | Borealis As | Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten |
US5962361A (en) | 1998-10-14 | 1999-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Methods of making and using catalyst precursor |
US6818711B2 (en) | 2003-01-01 | 2004-11-16 | Fina Technology, Inc. | Polymerization of olefins using a ziegler-natta catalyst system having an external electron donor |
US20080207972A1 (en) | 2006-03-01 | 2008-08-28 | Ineos Usa Llc | Propylene polymer catalyst donor component |
BRPI0918346A2 (pt) | 2008-12-31 | 2015-12-15 | Dow Global Technologies Llc | diéster aromático de fenileno substituído |
KR101874650B1 (ko) | 2010-02-26 | 2018-07-04 | 더블유.알. 그레이스 앤드 캄파니-콘. | 치환된 아미드 에스테르 내부 전자 공여체를 갖는 전촉매 조성물 |
DE102010060780A1 (de) | 2010-11-24 | 2012-05-24 | Continental Reifen Deutschland Gmbh | Verfahren zur Herstellung von polymer-funktionalisierten Füllstoffpartikeln |
MY164913A (en) * | 2010-12-21 | 2018-02-15 | Grace W R & Co | Process for production of high melt flow propylene-based polymer and product from same |
EP2803679A1 (en) * | 2013-05-17 | 2014-11-19 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
BR112017017446B1 (pt) | 2015-03-10 | 2022-04-12 | Basell Poliolefine Italia S.R.L. | Componente catalisador sólido, catalisador e processo para a (co)polimerização de olefinas |
MX2019002378A (es) * | 2016-08-30 | 2019-09-04 | Grace W R & Co | Sistema catalizador para la produccion de poliolefinas y metodo para elaborar y usar las mismas. |
CN110023351B (zh) | 2016-10-06 | 2022-04-26 | 格雷斯公司 | 采用内给电子体的组合制得的主催化剂组合物 |
-
2020
- 2020-09-10 US US17/761,451 patent/US11945896B2/en active Active
- 2020-09-10 KR KR1020227012571A patent/KR20220085772A/ko unknown
- 2020-09-10 WO PCT/US2020/050042 patent/WO2021055212A1/en active Application Filing
- 2020-09-10 JP JP2022517348A patent/JP2022549143A/ja active Pending
- 2020-09-10 BR BR112022005043A patent/BR112022005043A2/pt unknown
- 2020-09-10 CN CN202080080039.2A patent/CN114729067A/zh active Pending
- 2020-09-10 EP EP20864777.6A patent/EP4031587A4/en active Pending
- 2020-09-10 MX MX2022003252A patent/MX2022003252A/es unknown
- 2020-09-10 CA CA3151380A patent/CA3151380A1/en active Pending
- 2020-09-18 TW TW109132312A patent/TW202118798A/zh unknown
- 2020-09-21 AR ARP200102623A patent/AR120023A1/es unknown
-
2022
- 2022-03-28 CO CONC2022/0003698A patent/CO2022003698A2/es unknown
Also Published As
Publication number | Publication date |
---|---|
EP4031587A4 (en) | 2023-10-25 |
US20220380491A1 (en) | 2022-12-01 |
US11945896B2 (en) | 2024-04-02 |
EP4031587A1 (en) | 2022-07-27 |
TW202118798A (zh) | 2021-05-16 |
KR20220085772A (ko) | 2022-06-22 |
WO2021055212A1 (en) | 2021-03-25 |
CA3151380A1 (en) | 2021-03-25 |
MX2022003252A (es) | 2022-04-27 |
CO2022003698A2 (es) | 2022-04-19 |
JP2022549143A (ja) | 2022-11-24 |
CN114729067A (zh) | 2022-07-08 |
AR120023A1 (es) | 2022-01-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] |