BR112022005043A2 - Composição de catalisador e sistema com vida útil estendida - Google Patents

Composição de catalisador e sistema com vida útil estendida

Info

Publication number
BR112022005043A2
BR112022005043A2 BR112022005043A BR112022005043A BR112022005043A2 BR 112022005043 A2 BR112022005043 A2 BR 112022005043A2 BR 112022005043 A BR112022005043 A BR 112022005043A BR 112022005043 A BR112022005043 A BR 112022005043A BR 112022005043 A2 BR112022005043 A2 BR 112022005043A2
Authority
BR
Brazil
Prior art keywords
catalyst
composition
shelf life
extended shelf
improved
Prior art date
Application number
BR112022005043A
Other languages
English (en)
Inventor
Coalter Joseph Iii
Kent Rose
Marwitz Adam
Epstein Ronald
Elder Michael
Original Assignee
Grace W R & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grace W R & Co filed Critical Grace W R & Co
Publication of BR112022005043A2 publication Critical patent/BR112022005043A2/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/78Benzoic acid esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6541Pretreating with metals or metal-containing compounds with magnesium or compounds thereof and metals of C08F4/64 or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/14Preparation of carboxylic acid esters from carboxylic acid halides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/27Amount of comonomer in wt% or mol%
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/35Crystallinity, e.g. soluble or insoluble content as determined by the extraction of the polymer with a solvent

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Composição de catalisador de Ziegler-Natta é divulgada. A composição de catalisador inclui um doador de elétron interno com cinética de polimerização melhorada, um tempo de vida longo, estereosseletividade melhorada e/ou resposta de hidrogênio melhorada.
BR112022005043A 2019-09-18 2020-09-10 Composição de catalisador e sistema com vida útil estendida BR112022005043A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962902048P 2019-09-18 2019-09-18
PCT/US2020/050042 WO2021055212A1 (en) 2019-09-18 2020-09-10 Catalyst composition and system having extended lifetime

Publications (1)

Publication Number Publication Date
BR112022005043A2 true BR112022005043A2 (pt) 2022-07-05

Family

ID=74883177

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112022005043A BR112022005043A2 (pt) 2019-09-18 2020-09-10 Composição de catalisador e sistema com vida útil estendida

Country Status (12)

Country Link
US (1) US11945896B2 (pt)
EP (1) EP4031587A4 (pt)
JP (1) JP2022549143A (pt)
KR (1) KR20220085772A (pt)
CN (1) CN114729067A (pt)
AR (1) AR120023A1 (pt)
BR (1) BR112022005043A2 (pt)
CA (1) CA3151380A1 (pt)
CO (1) CO2022003698A2 (pt)
MX (1) MX2022003252A (pt)
TW (1) TW202118798A (pt)
WO (1) WO2021055212A1 (pt)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
US5124298A (en) 1990-10-22 1992-06-23 Shell Oil Company Olefin polymerization catalyst
FI90248C (fi) 1991-11-29 1994-01-10 Borealis As Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten
US5962361A (en) 1998-10-14 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Methods of making and using catalyst precursor
US6818711B2 (en) 2003-01-01 2004-11-16 Fina Technology, Inc. Polymerization of olefins using a ziegler-natta catalyst system having an external electron donor
US20080207972A1 (en) 2006-03-01 2008-08-28 Ineos Usa Llc Propylene polymer catalyst donor component
BRPI0918346A2 (pt) 2008-12-31 2015-12-15 Dow Global Technologies Llc diéster aromático de fenileno substituído
KR101874650B1 (ko) 2010-02-26 2018-07-04 더블유.알. 그레이스 앤드 캄파니-콘. 치환된 아미드 에스테르 내부 전자 공여체를 갖는 전촉매 조성물
DE102010060780A1 (de) 2010-11-24 2012-05-24 Continental Reifen Deutschland Gmbh Verfahren zur Herstellung von polymer-funktionalisierten Füllstoffpartikeln
MY164913A (en) * 2010-12-21 2018-02-15 Grace W R & Co Process for production of high melt flow propylene-based polymer and product from same
EP2803679A1 (en) * 2013-05-17 2014-11-19 Basell Poliolefine Italia S.r.l. Catalyst components for the polymerization of olefins
BR112017017446B1 (pt) 2015-03-10 2022-04-12 Basell Poliolefine Italia S.R.L. Componente catalisador sólido, catalisador e processo para a (co)polimerização de olefinas
MX2019002378A (es) * 2016-08-30 2019-09-04 Grace W R & Co Sistema catalizador para la produccion de poliolefinas y metodo para elaborar y usar las mismas.
CN110023351B (zh) 2016-10-06 2022-04-26 格雷斯公司 采用内给电子体的组合制得的主催化剂组合物

Also Published As

Publication number Publication date
EP4031587A4 (en) 2023-10-25
US20220380491A1 (en) 2022-12-01
US11945896B2 (en) 2024-04-02
EP4031587A1 (en) 2022-07-27
TW202118798A (zh) 2021-05-16
KR20220085772A (ko) 2022-06-22
WO2021055212A1 (en) 2021-03-25
CA3151380A1 (en) 2021-03-25
MX2022003252A (es) 2022-04-27
CO2022003698A2 (es) 2022-04-19
JP2022549143A (ja) 2022-11-24
CN114729067A (zh) 2022-07-08
AR120023A1 (es) 2022-01-26

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Legal Events

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