BR112021023323A2 - Ésteres de glicerol etoxilados e método para a produção dos mesmos - Google Patents

Ésteres de glicerol etoxilados e método para a produção dos mesmos

Info

Publication number
BR112021023323A2
BR112021023323A2 BR112021023323A BR112021023323A BR112021023323A2 BR 112021023323 A2 BR112021023323 A2 BR 112021023323A2 BR 112021023323 A BR112021023323 A BR 112021023323A BR 112021023323 A BR112021023323 A BR 112021023323A BR 112021023323 A2 BR112021023323 A2 BR 112021023323A2
Authority
BR
Brazil
Prior art keywords
glycerol esters
production
ethoxylated glycerol
catalyst
found
Prior art date
Application number
BR112021023323A
Other languages
English (en)
Inventor
Dirk Leinweber
Felix Hövelmann
Hannah Benson
Original Assignee
Clariant Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Int Ltd filed Critical Clariant Int Ltd
Publication of BR112021023323A2 publication Critical patent/BR112021023323A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
    • C08G65/2615—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen the other compounds containing carboxylic acid, ester or anhydride groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/24—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran
    • C07C67/26—Preparation of carboxylic acid esters by reacting carboxylic acids or derivatives thereof with a carbon-to-oxygen ether bond, e.g. acetal, tetrahydrofuran with an oxirane ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/30—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with trihydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/2645—Metals or compounds thereof, e.g. salts
    • C08G65/2651—Alkaline earth metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
    • C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
    • C08G65/269—Mixed catalyst systems, i.e. containing more than one reactive component or catalysts formed in-situ
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/001—General concepts, e.g. reviews, relating to catalyst systems and methods of making them, the concept being defined by a common material or method/theory
    • B01J2531/002—Materials
    • B01J2531/004—Ligands

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

ésteres de glicerol etoxilados e método para a produção dos mesmos. a presente invenção refere-se ao uso de um tipo específico de catalisador de cálcio (c) para a preparação de ésteres de glicerol alcoxilados, ésteres de glicerol alcoxilados preparados na presença do catalisador e um processo para a preparação dos ésteres de glicerol alcoxilados. verificou-se que na presença do catalisador de cálcio (c) mencionado acima, a reação de alcoxilação requer um período de tempo significativamente menor. além disso, verificou-se que os ésteres de glicerol etoxilados preparados na presença de catalisador de cálcio (c) levam a produtos mais homogêneos com valores de hidroxila significativamente mais menores, menos decomposição e capacidade de processamento melhorada.
BR112021023323A 2019-05-28 2020-05-26 Ésteres de glicerol etoxilados e método para a produção dos mesmos BR112021023323A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP19177001 2019-05-28
PCT/EP2020/064544 WO2020239750A1 (en) 2019-05-28 2020-05-26 Ethoxylated glycerol esters and method for the production thereof

Publications (1)

Publication Number Publication Date
BR112021023323A2 true BR112021023323A2 (pt) 2022-03-29

Family

ID=66668831

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112021023323A BR112021023323A2 (pt) 2019-05-28 2020-05-26 Ésteres de glicerol etoxilados e método para a produção dos mesmos

Country Status (5)

Country Link
US (1) US20220259375A1 (pt)
EP (1) EP3976574A1 (pt)
CN (1) CN114026059A (pt)
BR (1) BR112021023323A2 (pt)
WO (1) WO2020239750A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022228945A1 (en) * 2021-04-30 2022-11-03 Clariant International Ltd Mixture of methyl ester ethoxylates
CN118056000A (zh) 2021-10-07 2024-05-17 科莱恩国际有限公司 用于机器洗碗的包含乙氧基化甘油酯和改性脂肪醇烷氧基化物的洗涤剂组合物
WO2023083995A1 (en) 2021-11-12 2023-05-19 Clariant International Ltd Hand dish-washing composition containing ethoxylated glycerol esters

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1985000365A1 (en) 1983-07-05 1985-01-31 Union Carbide Corporation Alkoxylation using calcium catalysts and products therefrom
US4835321A (en) 1987-04-28 1989-05-30 Vista Chemical Company Alkoxylaton process using calcium based catalysts
DE3914131A1 (de) 1989-04-28 1990-10-31 Henkel Kgaa Verwendung von calcinierten hydrotalciten als katalysatoren fuer die ethoxylierung bzw. propoxylierung von fettsaeureestern
US5386045A (en) 1991-08-22 1995-01-31 Vista Chemical Company Process for alkoxylation of esters and products produced therefrom
US5627121A (en) * 1995-06-15 1997-05-06 Condea Vista Company Process for preparing alkoxylation catalysts and alkoxylation process
KR100441677B1 (ko) * 1995-11-16 2004-10-26 액세스 비지니스 그룹 인터내셔날 엘엘씨 액체접시세척세제
PL343853A1 (en) * 2000-11-13 2002-05-20 Inst Ciezkiej Syntezy Orga Oxyalkylenation catalyst and method of obtaining same
EP2181763B1 (en) * 2008-10-29 2012-06-20 Shell Internationale Research Maatschappij B.V. Catalyst and process for alkoxylation
DK2666848T3 (en) * 2012-05-22 2017-10-23 Kao Corp Sa Diluent surfactant composition

Also Published As

Publication number Publication date
EP3976574A1 (en) 2022-04-06
WO2020239750A1 (en) 2020-12-03
CN114026059A (zh) 2022-02-08
US20220259375A1 (en) 2022-08-18

Similar Documents

Publication Publication Date Title
BR112021023323A2 (pt) Ésteres de glicerol etoxilados e método para a produção dos mesmos
CL2021000028A1 (es) Anticuerpo multiespecifico (divisional de solicitud 937-2020).
BR112018013174A2 (pt) composição e método para crescimento de cabelo
SA519402457B1 (ar) تركيبات ومنتجات كتلة حيوية منشَّطة محتوية على البكتين وطرق لإنتاجها
BR112018010503A2 (pt) ovo de ave, método para replicar um vírus, vírus, método para produzir uma composição de vacina, composição de vacina, ave transgênica, e método para produzir uma ave
BR112017022867A2 (pt) método para produzir celulose microcristalina descolorada
MX335964B (es) Procedimiento para la extraccion de pectina.
BR112017011332A2 (pt) método de produção de lignina com quantidade reduzida de substâncias odoríferas
BR112021025366A2 (pt) Mistura de cera de abelha e um éster de lactilato
BR112018006928A2 (pt) método para preparação de compostos, substância ou mistura de substâncias obteníveis por um método, uso de pelo menos uma substância ou uma mistura de substâncias, composição de fragrância, agente, e, método para purificação de um composto.
BR112015032129A2 (pt) composição, sachê soluvel em água e processo de preparação da composição
BR112017024229A2 (pt) composição, métodos para formar uma composição injetável e para recuperar compostos de hidrocarboneto, e, uso de uma composição.
BR112019004258A2 (pt) implante que contém carbonato de cálcio inibidor
BR112021026245A2 (pt) Método de extração.
AR127263A2 (es) Método para producir una lechada de yeso para hacer productos de yeso y método para fabricar productos de yeso
BR112017018063A2 (pt) processo para preparação de um composto, uso de um composto, e, composição
EA201792525A1 (ru) Способ и установка для приготовления биомассы
BR112017022327A2 (pt) processo de retícula de polipropileno, processo de reciclagem de polipropileno reticulado, e uso do polipropileno reticulado
BR112018077040A2 (pt) resfriamento de elementos de madeira acetilados
CL2015002376A1 (es) Fibra de madera acetilada
BR112017028390A2 (pt) processo para preparação de um derivado de furfural
BR112015008730A2 (pt) processo para a produção de ácidos graxos monoramificados ou ésteres de alquila dos mesmos, uso de um zeólito como um catalisador, reutilização de um catalisador de zeólito, e, composição
BR112012032819A2 (pt) catalisador para a reação de formaldeído, processo para produzir um ácido carbgoxílico ou éster etilenicamente insaturado, e, uso do catalisador
PE20151879A1 (es) Proceso para la fabricacion de productos a partir de fibra de madera acetilada
BR112017014681A2 (pt) composição de ácido graxo