BR112021006011A2 - fungicidal mixtures, pesticidal composition, use of the mixture and method for controlling phytopathogenic pests - Google Patents

Abstract

fungicidal mixtures, pesticidal composition, use of the mixture and method for controlling phytopathogenic pests. The present invention relates to fungicidal mixtures comprising, as active components: (1) phenpropimorph as compound i, and (2) a fungicidal compound ii, wherein compound ii is a succinate dehydrogenase inhibitor and is selected from the group consisting of: 2-(difluoromethyl)-n-[(3r)-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-n-(1 ,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-n-[(3r)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide, 2- (difluoromethyl)-n-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-n-[(3r)-3-ethyl-1,1- dimethyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-n-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl) -n-(3-isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-n-[(3r)-3-isobutyl-1,1-dimethyl-indan -4-yl]pyridine-3-carboxamide, inpirfluxam, bixafem, pidiflumetophem, benzovindyflupyr, fluxapyroxad, fluindapyr, isoflucipram, sedaxan o, and (3) a fungicidal compound iii of the dmi class of fungicides (c14-demethylase inhibitor in sterol biosynthesis), wherein compound iii is selected from the group consisting of: prothioconazole, difenoconazole, tetraconazole, cyproconazole, metconazole, 4-[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]- 3-pyridyl]oxy]benzonitrile, tebuconazole, mefentrifluconazole.

Description

“FUNGICIDAL MIXTURES, PESTICIDE COMPOSITION, USE OF MIXTURE AND METHOD TO CONTROL PHYTOPATOGENIC PESTS” DESCRIPTION

[001] The present invention relates to fungicidal mixtures, comprising as active components: (1) phenpropimorph as compound I, and (2) a fungicidal compound II, wherein compound II is a succinate dehydrogenase inhibitor and is selected from from the group consisting of: 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N- (1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1, 1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-( difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl -indan-4-yl]pyridine-3-carboxamide, inpirfluxam, bixafem, pidiflumetophem, benzovindiflupyr, fluxapyroxad, fluindapyr, isoflucipr am, sedaxane, and (3) a fungicidal compound III of the DMI class of fungicides (C14-demethylase inhibitor in sterol biosynthesis), wherein compound III is selected from the group consisting of: prothioconazole, difenoconazole, tetraconazole, cyproconazole, metconazole, 4-[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl ]-3-pyridyl]oxy]benzonitrile, tebuconazole, mefentrifluconazole.

[002] Furthermore, the invention relates to the use of the mixture to control harmful phytopathogenic fungi and to a method for controlling phytopathogenic pests, wherein the pest, its habitat, breeding grounds (breeding grounds), the site or plants to be are protected from pest attack, the soil or plant propagation material is treated with an effective amount of the mixture.

[003] The term “plant propagation material” should be understood as all generative parts of the plant, such as seeds and vegetative material, such as cuttings and tubers (e.g. potato), which can be used for the multiplication of the plant. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, shoots, shoots and other plant parts, including seedlings or seedlings and young plants, which are being transplanted after germination, or after emergence from the ground.

These young plants can also be protected before transplanting by total or partial treatment by immersion or pouring. In a particularly preferred example embodiment, the term propagation material denotes seeds.

[004] Compounds I, II and III, as well as their pesticidal action and methods for their production are generally known (cf.: http://www.alanwood.net/pesticides/); these substances are commercially available. 4–[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3 -pyridyl]oxy]benzonitrile is known from WO 2016/187201. 2-(difluoromethyl)-N-(1,1,3-trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4- yl]pyridine-3-

carboxamide, 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl- 1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2 -(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3-isobutyl-1,1 -dimethyl-indan-4-yl)pyridine-3-carboxamide and 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indan-4-yl]pyridine-3-carboxamide are known from WO 2015/197530 .

[005] Phenpropimorph ternary mixtures are known from EP-3162208, WO 2018/162999 and IPCOM000244894D.

[006] A typical problem that arises in the field of pest control lies in the need to reduce dosage rates of the active ingredient in order to reduce or avoid adverse environmental or toxicological effects, while still allowing effective pest control.

[007] With respect to the present invention, the term pest encompasses animal pests and harmful fungi.

[008] Another problem encountered concerns the need to have pest control agents available that are effective against a broad spectrum of harmful animal pests and harmful fungi.

[009] There is also a need for pest control agents that combine immediate action activity (knock-down effect) with prolonged control, that is, fast action with long-lasting action.

[010] Another difficulty with the use of pesticides is that the repeated and exclusive application of an individual pesticidal compound leads, in many cases, to a rapid selection of pests, which means that animal pests and harmful fungi have developed naturally or adapted by acquiring resistance against the active compound in question. There is, therefore, a need for pest control agents that help to prevent pests or prevent them from acquiring resistance.

[011] Especially to control fungal diseases in soybean, it is a challenge and currently more than one active ingredient is needed to obtain sufficient activity. It is expected that in the future all products will consist of at least three active ingredients (ternary mixtures).

[012] Phenpropimorph has been known for many years. However, the compound has only recently been introduced to the soybean fungicide market. It was surprisingly found that novel ternary mixtures of phenpropimorph with other selected compounds are synergistically highly active. Because of this and the limited number of highly active compounds, phenpropimorph is expected to become a key partner of other active ingredients in ternary blends.

[013] It was therefore an object of the present invention to provide pesticide mixtures that solve the problems of dose rate reduction and/or that increase the spectrum of activity and/or combine knock-down activity with prolonged control and/or or manage plant resistance and/or health promotion.

[014] We conclude that this objective is achieved, in part or in full, by the fungicidal mixtures as defined above.

[015] It has especially been found that the mixtures defined above show remarkably improved action against pests compared to the control rates that are possible with the individual compounds and/or are suitable for improving plant health when applied to plants, parts of plants, seeds, or the place where they grow. Especially high activity was shown in soybeans.

[016] It was found that the action of the mixtures of the invention, comprising compound I, compound II and compound III, goes far beyond the fungicidal action and/or plant health improvement of the active compounds present in the mixture when used alone ( synergistic action).

[017] Furthermore, we found that the simultaneous application, whether jointly or separately, of compound I, compound II and compound III; or the successive application of compound I, compound II and compound III, allows better control of harmful fungi, compared to the control rates that are possible with individual compounds (synergistic mixtures).

[018] In addition, we have found that the simultaneous application, either jointly or separately, of compound I, compound II and compound III, or the successive application of compound I, compound II and compound III, provides improved effects for the health of plants in compared to the effects on plant health that are possible with the compounds when applied individually.

[019] The weight ratio of compound I and compound II in ternary mixtures is from 500:1 to 1:500, preferably from 100:1 to 1:100 more preferably from 50:1 to 1:50, most preferably from 20:1 to 1:20, also including ratios of 10:1 to 1:10, 1:5 to 5:1, or 1:1. The weight ratio of compound I and compound III in ternary mixtures is from 500:1 to 1:500, preferably from 100:1 to 1:100 more preferably from 50:1 to 1:50, most preferably from 20: 1 to 1:20, also including ratios of 10:1 to 1:10, 1:5 to 5:1, or 1:1.

[020] All blends referred to above are also referred to below as “blends of the invention”.

[021] The present invention relates to synergistic three-way mixtures shown in the Table below, which comprise three components, as appropriate: Mixture Compound I Compound II Compound III Culture 1 fenpropimorph inpirfluxam difenoconazole soy 2 fenpropimorph inpirfluxam mefentrifluconazole soy 3 fenpropimorph inpirfluxam tetraconazole soy 4 fenpropimorph inpirfluxam cyproconazole soy 5 fenpropimorph inpirfluxam metconazole soy

Mixture Compound I Compound II Compound III Culture 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-6-phenpropimorph inpirfluxam soy sulfanyl-1,2, 4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 7 fenpropimorph bixafen difenoconazole soy 8 fenpropimorph bixafen mefentrifluconazole soy 9 fenpropimorph bixafen tetraconazole soy 10 fenpropimorph bixafen metconazole soy 4-[[6-[2-(2, 4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-phenpropimorph bixafen soya sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 12 fenpropimorph pidiflumetofem difenoconazole soy 13 fenpropimorph pidiflumetofem tetraconazole soy 14 fenpropimorph pidiflumetofem metconazole soy 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-15-phenpropimorph pidiflumetofem soy sulfanil -1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 16 fenpropimorph benzovindiflupyr difenoconazole soy 17 fenpropimorph benzovindiflupyr Tetraconazole soy 18 fenpropimorph benzovindiflupyr Metconazo l soya 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-phenpropimorph benzovindiflupyr soya sulfanyl-1,2,4-triazol-1- yl)propyl]-3-pyridyl]oxy]benzonitrile 20 fenpropimorph fluxapyroxad difenoconazole soy 21 fenpropimorph fluxapyroxad tetraconazole soy 22 fenpropimorph fluxapyroxad metconazole soy 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro- 2-hydroxy-3-(5-23 phenpropimorph fluxapyroxade soy sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 24 fenpropimorph flundapyr prothioconazole soy 25 fenpropimorph flundapyr tebuconazole soy 26 phenpropimorph fluindapyr difenoconazole soy 27 fenpropimorph fluindapyr mefentrifluconazole soy 28 fenpropimorph fluindapyr tetraconazole soy

Mixture Compound I Compound II Compound III Culture 29 fenpropimorph fluindapyr cyproconazole soy 30 fenpropimorph fluindapyr metconazole soy 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5- 31 fenpropimorph flundapyr soy sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 32 fenpropimorph isoflucipram prothioconazole soy 33 fenpropimorph isoflucipram tebuconazole soy 34 fenpropimorph isoflucipram diphenoconazole soy 35 phenpropimorph isoflucipram mefentriflupropiconazole soy 36 fenpropimorph isoflucipram tetraconazole soy 37 fenpropimorph isoflucipram cyproconazole soy 38 fenpropimorph isoflucipram metconazole soy 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-39 phenpropimorph isoflucipram soy sulfanil -1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 40 fenpropimorph sedaxane prothioconazole soy 41 fenpropimorph sedaxane tebuconazole soy 42 fenpropimorph sedaxane difenoconazole soy 43 fenpropimorph sedaxane mefentrifluconazole soy 44 fenpropimorph sedaxane tetraconazole soya 45 fenpropimorph sedaxane cyproconazole soya 46 fenpropimorph sedaxane metconazole soya 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-47 phenpropimorph sedaxane soya sulfanil -1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-(1,1,3-fenpropimorph trimethylindan-4-yl)pyridine-3- prothioconazole soy carboxamide 2-(difluoromethyl)-N-(1,1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-tebuconazole soy carboxamide 2-(difluoromethyl)-N-(1,1,3- fenpropimorph trimethylindan-4-yl)pyridine-3-xifenoconazole soya carboxamide 2-(difluoromethyl)-N-(1,1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-mefentrifluconazole soya carboxamide 2-(difluoromethyl)-N -(1,1,3- fenpropimorph tetraconazole soy trimethylindan-4-yl)pyridine-3-

Mixture Compound I Compound II Compound III Carboxamide Culture

2-(difluoromethyl)-N-(1,1,3- fenpropimorph trimethylindan-4-yl)pyridin-3-cyproconazole soy carboxamide 2-(difluoromethyl)-N-(1,1,3- fenpropimorph trimethylindan-4 -yl)pyridine-3-metconazole soy carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-(1,1,3-difluoro-2- hydroxy-3-(5-phenpropimorph trimethylindan-4-yl)pyridine-3-soysulfanyl-1,2,4-triazol-1-carboxamide yl)propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl) -N-[(3R)- 56 fenpropimorph 1,1,3-trimethylindan-4-prothioconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)- 57 fenpropimorph 1,1,3- trimethylindan-4-tebuconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-fenpropimorph 1,1,3-trimethylindan-4-diphenoconazole soyayl]pyridine-3-carboxamide 2-( difluoromethyl)-N-[(3R)-59 fenpropimorph 1,1,3-trimethylindan-4-mefentrifluconazole soy yl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-60 fenpropimorph 1,1, 3-trimethylindan-4-tetraconazole soyayl]pyridine-3-carboxamide 2-(difluoro omethyl)-N-[(3R)-61 fenpropimorph 1,1,3-trimethylindan-4-cyproconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-62 fenpropimorph 1,1, 3-trimethylindan-4-metconazole soyayl]pyridine-3-carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-difluoro -2-hydroxy-3-(5-phenpropimorph 1,1,3-trimethylindan-4-soysulfanyl-1,2,4-triazol-1-yl]pyridine-3-carboxamide yl)propyl]-3-pyridyl ]oxy]benzonitrile 2-(difluoromethyl)-N-(3-ethyl-phenpropimorph 1,1-dimethyl-indan-4-prothioconazole soy yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl - 65 fenpropimorph 1,1-dimethyl-indan-4-tebuconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-66 fenpropimorph 1,1-dimethyl-indan-4-diphenoconazole soyayl )pyridine-3-carboxamide

Mixture Compound I Compound II Compound III Culture 2-(difluoromethyl)-N-(3-ethyl-phenpropimorph 1,1-dimethyl-indan-4-mefentrifluconazole soyyl)pyridine-3-carboxamide 2-(difluoromethyl)-N- (3-ethyl-fenpropimorph 1,1-dimethyl-indan-4-tetraconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-fenpropimorph 1,1-dimethyl-indan-4 - cyproconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-fenpropimorph 1,1-dimethyl-indan-4-metconazole soyayl)pyridine-3-carboxamide 4-[[6- [2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-(3-ethyl-difluoro-2-hydroxy-3-(5-phenpropimorph 1,1-dimethyl-indan-4) - soy sulfanyl-1,2,4-triazol-1-yl)pyridine-3-carboxamide yl)propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-[(3R)-3-fenpropimorph ethyl-1,1-dimethyl-indan-4-prothioconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-fenpropimorph ethyl-1,1-dimethyl-indan-4- tebuconazole soya yl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-fenpropimorph ethyl-1,1-dimethyl-indan-4-difenoconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-fenpropimorph ethyl-1,1-dimethyl-indan-4- mefentrifluconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-fenpropimorph ethyl-1,1-dimethyl-indan-4-tetraconazole soyayl]pyridine-3-carboxamide 2-( difluoromethyl)-N-[(3R)-3- fenpropimorph ethyl-1,1-dimethyl-indan-4-cyproconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3- 78 fenpropimorph ethyl-1,1-dimethyl-indan-4-metconazole soyayl]pyridine-3-carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)- N-[(3R)-3-difluoro-2-hydroxy-3-(5-phenpropimorph ethyl-1,1-dimethyl-indan-4-soy sulfanyl-1,2,4-triazol-1-yl]pyridine -3-carboxamide yl)propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-(1,1-phenpropimorph dimethyl-3-propyl-indan-4-prothioconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(1,1-phenpropimorph tebuconazole soy dimethyl-3-propyl-indan-4-

Mixture Compound I Compound II Compound III Culture yl)pyridine-3-carboxamide

2-(difluoromethyl)-N-(1,1-phenpropimorph dimethyl-3-propyl-indan-4-diphenoconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(1,1- fenpropimorph dimethyl -3-propyl-indan-4-mefentrifluconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(1,1-fenpropimorph dimethyl-3-propyl-indan-4-tetraconazole soyayl)pyridine-3 -carboxamide 2-(difluoromethyl)-N-(1,1-phenpropimorph dimethyl-3-propyl-indan-4-cyproconazole soyyl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(1,1-86 fenpropimorph dimethyl-3-propyl-indan-4-metconazole soyayl)pyridine-3-carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-( 1,1-difluoro-2-hydroxy-3-(5-phenpropimorph dimethyl-3-propyl-indan-4-soysulfanyl-1,2,4-triazol-1-yl)pyridine-3-carboxamide yl)propyl ]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-[(3R)-fenpropimorph 1,1-dimethyl-3-propyl-indan-4-prothioconazole soyayl]pyridine-3-carboxamide 2-( difluoromethyl)-N-[(3R)-fenpropimorph 1,1-dimethyl-3-propyl-indan-4-tebuconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-fenpropimorph 1,1-dimethyl-3-propyl-indan-4-diphenoconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl )-N-[(3R)-91 fenpropimorph 1,1-dimethyl-3-propyl-indan-4-mefentrifluconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-92 fenpropimorph 1 ,1-dimethyl-3-propyl-indan-4-tetraconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-fenpropimorph 1,1-dimethyl-3-propyl-indan-4 - cyproconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-fenpropimorph 1,1-dimethyl-3-propyl-indan-4-metconazole soyayl]pyridine-3-carboxamide 4- [[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-difluoro-2-hydroxy-3-(5-fenpropimorph 1,1-dimethyl -3-propyl-indan-4-soysulfanyl-1,2,4-triazol-1-yl]pyridine-3-carboxamide yl)propyl]-3-pyridyl]oxy]benzonitrile

Mixture Compound I Compound II Compound III Culture 2-(difluoromethyl)-N-(3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-prothioconazole soyyl)pyridine-3-carboxamide 2-(difluoromethyl)-N- (3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-tebuconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-phenpropimorph isobutyl-1,1-dimethyl-indan-4 - difenoconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-mefentrifluconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)- N-(3-100 phenpropimorph isobutyl-1,1-dimethyl-indan-4-tetraconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-101 phenpropimorph isobutyl-1,1-dimethyl-indan -4-cyproconazole soyayl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-metconazole soyayl)pyridine-3-carboxamide 4-[[ 6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-(3-difluoro-2-hydroxy-3-(5-phenpropimorph isobutyl-1,1-dimethyl-indan) -4- soy sulfanyl-1,2,4-triazol-1-yl)pyridine-3-carboxamide yl)propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-[(3R)-3-phenpropimorph isobutyl -1,1-dimethyl-indan-4-prothioconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-fenpropimorph isobutyl-1,1-dimethyl-indan-4-tebuconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-diphenoconazole soyayl]pyridine-3-carboxamide 2-(difluoromethyl )-N-[(3R)-3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-mefentrifluconazole Sojayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-108 phenpropimorph isobutyl-1,1-dimethyl-indan-4-tetraconazole Sojayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-phenpropimorph isobutyl-1,1-dimethyl-indan-4 - cyproconazole Sojayl]pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-3-phenpropimorph isobutyl-1,1-dimethyl-indan-4-metconazole Sojayl]pyridine-3-carboxamide

Mixture Compound I Compound II Compound III Culture 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-3-difluoro-2-hydroxy- 3-(5-phenpropimorph isobutyl-1,1-dimethyl-indan-4-Soya sulfanyl-1,2,4-triazol-1-yl]pyridine-3-carboxamide yl)propyl]-3-pyridyl]oxy] benzonitrile

[022] The mixtures of the invention can be converted into customary/common types of agrochemical compositions, for example, solutions, suspensions, dusts, powders, pastes, granules, capsules, tablets, and mixtures thereof. Examples for types of composition are suspensions (eg SC, OD, FS), emulsifiable concentrates (eg EC), emulsions (eg EW, EO, ES, ME), capsules (eg CS, ZC) , pastes, tablets, wettable powder or dust (e.g. WP, SP, WS, DP, DS), pressed (e.g. BR, TB, DT), granules (e.g. WG, SG, GR, FG, GG , MG), insecticidal articles (eg LN) as well as gel formulations for the treatment of plant propagation materials such as seeds (eg GF). These and other types of compositions are defined in the “Catalogue of pesticide formulation types and international coding system”, Technical Monograph No. 2, 6th Ed. May 2008, CropLife International.

[023] The compositions are prepared in a known manner, as described by Mollet and Grubemann, “Formulation technology”, Wiley VCH, Weinheim, 2001; or Knowles, “New developments in crop protection product formulation”, Agrow Reports DS243, T&F Informa, London, 2005.

[024] Suitable auxiliaries are solvents, liquid vehicles, solid vehicles or fillers, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, wetting agents, repellents, baits/attractors (attractants), food stimulants, compatibilizers,

bactericides, anti-freezing agents, anti-foaming agents, dyes, tackifiers and binders/binders.

[025] Suitable solvents and liquid vehicles are water and organic solvents, such as mineral oil fractions of medium to high boiling point, eg kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, for example toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, for example ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example cyclohexanone; esters, e.g. esters of lactates, carbonates, fatty acids, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, for example N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.

[026] Suitable solid fillers or carriers are earth minerals, for example silicates, silica gels, talc, kaolin, limestone, lime, chalk, clays, dolomite, earth diatoms, bentonite, calcium sulfate, magnesium sulfate, oxide of magnesium; polysaccharides, for example cellulose, starch; fertilizers, eg ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of plant origin, for example, cereal flour, tree bark, wood flour, nutshell flour, and mixtures thereof.

[027] Suitable surfactants are surfactant compounds such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surface-active agents can be used as an emulsifier, dispersant, solubilizer, wetting agent, penetration enhancer, protective colloid or adjuvant. Examples of surfactants are listed in McCutcheon, Vol.1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Edition or North American Edition).

[028] Suitable anionic surfactants are alkaline, alkaline-earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, fatty acid and oil sulfonates, ethoxylated alkylphenol sulfonates, alkoxylated arylphenol sulfonates, condensed naphthalene sulfonates, dodecyl- and tridecylbenzene sulfonates, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of esters of fatty acids. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates, carboxylated alcohol or alkylphenol ethoxylates.

[029] Suitable nonionic surfactants are alkoxylated, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants and mixtures thereof.

Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and/or propylene oxide may be used for the alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, esters of sucrose and glucose or alkylpolyglycosides. Examples of polymeric surfactants are homo- or copolymers of vinyl pyrrolidone, vinyl alcohols, or vinyl acetate.

[030] Suitable cationic surfactants are quaternary surfactants, for example, quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.

Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are block polymers of type A-B or A-B-A, comprising blocks of polyethylene oxide and polypropylene oxide, or of type A-B-C comprising alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases.

Examples of polyacids are alkaline salts of polyacrylic acid or comb polymers of polyacids. Examples of polybases or polyvinylamines are polyethyleneamines.

[031] Suitable adjuvants are compounds that have a negligible or even absent pesticidal activity of their own, and that improve the biological performance of the mixtures of the invention on the target.

Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Additional examples are listed in Knowles, Adjuvants and additives, Agrow Adjuvants and additives, Agrow Reports DS256, T&F Informa - UK, 2006, chapter 5.

[032] Suitable thickeners are polysaccharides (eg, xanthan gum, carboxymethyl cellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates.

[033] Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinone and benzisothiazolinone.

[034] Suitable antifreeze agents are ethylene glycol, propylene glycol, glycerin and urea.

[035] Suitable antifoaming (or antifoaming) agents are silicones, long-chain alcohols, and fatty acid salts.

[036] Suitable dyes (eg in red, blue or green) are low water soluble pigments and water soluble dyes. Examples are inorganic dyes (e.g. iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (e.g. alizarin, azocyanine and phthalocyanine dyes).

[037] Suitable tackifiers or binding agents are polyvinylpyrrolidones, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.

[038] Examples for the types of composition and their preparation are: i) Water-soluble concentrates (SL, LS): 10-60% by weight of a mixture of the invention and 5-15% by weight of wetting agent (e.g. , alkoxylated alcohol) are dissolved in water and/or a water-soluble solvent (e.g. alcohols) added up to 100% by weight. The active substance dissolves after dilution with water; ii) Dispersible concentrates (DC): 5-25% by weight of a mixture of the invention and 1-10% by weight of dispersant (e.g. polyvinylpyrrolidone) are dissolved in organic solvent (e.g. cyclohexanone) added to 100% in weight. Dilution with water forms a dispersion; iii) Emulsifiable concentrates (EC): 15-70% by weight of a mixture of the invention and 5-10% by weight of emulsifiers (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in water-insoluble organic solvent ( for example aromatic hydrocarbons) up to 100% by weight. Dilution with water forms an emulsion; iv) Emulsions (EW, EO, ES): 5-40% by weight of a mixture of the invention and 1-10% by weight of emulsifier (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20-40 % by weight of water-insoluble organic solvent (eg aromatic hydrocarbon). This mixture is introduced into water until it reaches 100% by weight through an emulsifying machine and transformed into a homogeneous emulsion.

Dilution with water forms an emulsion;

v) Suspensions (SC, OD, FS):

In a ball mill, 20-60% by weight of a composition of the invention is milled with the addition of 2-10% by weight of dispersants and wetting agents (e.g. sodium lignosulfonate and ethoxylated alcohol),

0.1-2% by weight of thickener (eg xanthan gum) and water are added up to 100% by weight to obtain a fine active substance suspension.

Dilution with water forms a stable suspension of the active substance.

For the FS-type composition, up to 40% by weight of binder (eg polyvinyl alcohol) is added;

vi) Water dispersible granules and water soluble granules (WG, SG):

50-80% by weight of a mixture of the invention is finely ground with the addition of dispersing agents and wetting agents (e.g. sodium lignosulfonate and ethoxylated alcohol) to 100% by weight and the mixture is prepared as water-dispersible granules. or water-soluble by means of technical apparatus (eg extrusion, spray tower, fluidized bed). Dilution with water forms a stable dispersion or suspension of the active substance;

vii) Water dispersible powders and water soluble powders (WP,

SP, WS):

50-80% by weight of mixtures according to the present invention are ground in a rotor-stator mill with addition of 1-5% by weight of dispersants (e.g. sodium lignosulfonate), 1-3% by weight of agents. wetting agents (e.g. ethoxylated alcohol) and solid carrier (e.g. silica gel) up to 100% by weight.

Dilution with water forms a stable dispersion or suspension of the active substance; viii) Gel (GW, GF): In a ball mill, 5-25% of a composition of the invention is milled with the addition of 3-10% by weight of dispersants (e.g. sodium lignosulfonate), 1-5 % by weight of thickeners (eg carboxymethyl cellulose) and water up to 100% by weight to form a fine suspension of the active substance. Dilution with water forms a stable suspension of the active substance; ix) Microemulsions (ME): 5-20% by weight of a mixture of the invention is added to 5-30% by weight of organic solvent mixture (e.g. fatty acid dimethylamide and cyclohexanone), 10-25% by weight of a mixture of surfactants (for example, alcohol ethoxylates and ethoxylated arylphenol) and water to make up 100% by weight. This mixture is stirred for 1 h to spontaneously produce a thermodynamically stable microemulsion; x) Microcapsules (CS): The oil phase comprising 5-50% by weight of a mixture of the invention, 0-40% by weight of water-insoluble organic solvent (e.g. aromatic hydrocarbons), 2-15% by weight of acrylic monomers (eg methyl methacrylate, methacrylic acid and a di- or triacrylate) is dispersed in an aqueous solution of a protective colloid (eg polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.

Alternatively, an oil phase comprising 5-50% by weight of the inventive mixture according to the present invention, 0-40% by weight of water-insoluble organic solvent (e.g. aromatic hydrocarbons), and an isocyanate monomer ( eg diphenylmethane-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (eg polyvinyl alcohol). Addition of a polyamine (eg hexamethylenediamine) results in the formation of polyurea microcapsules. The monomers amount to 1-10% by weight. The % by weight refers to the total CS composition; xi) Dusting powder (DP, DS): 1-10% by weight of a mixture of the invention is finely ground and intimately mixed with a solid carrier (e.g. finely divided kaolin) to 100% by weight; xii) Granules (GR, FG): 0.5-30% by weight of a mixture of the invention are finely ground and intimately mixed with a solid carrier (eg silicate) to 100% by weight. Granulation is achieved by extrusion, spray-drying (spray-drying) or fluidized bed; and xiii) Ultra-low volume (UL) liquids: 1-50% by weight of a mixture of the invention is dissolved in organic solvent (eg aromatic hydrocarbon) added up to 100% by weight.

[039] Compositions of types i) to xiii) may optionally comprise other auxiliaries, such as 0.1-1% by weight of bactericides, 5-15% by weight of antifreeze agents, 0.1-1% by weight of anti-foaming agents, and 0.1-1% by weight of dyes.

[040] The resulting agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75% by weight of active substance. The active substances are used in a purity of 90% to 100%, preferably 95% to 100% (according to the NMR spectrum).

[041] Seed treatment solutions (LS), suspoemulsions (SE), fluid concentrates (FS), powder for dry treatment

(DS), water dispersible powder for semi-fluid dispersion treatment (WS), water soluble powder (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are commonly used for the treatment of plant propagation, especially seeds. The compositions in question provide, after dilution from two to ten times, concentrations of active substance between 0.01 and 60% by weight, preferably between 0.1 and 40%, in the ready-to-use preparations. Application can be carried out before or during sowing. Methods for applying the mixtures of the invention and compositions thereof, respectively, on plant propagation material, especially seeds, include dressing, coating, granulating, dusting, dipping and seeding furrow application of propagation material. . Preferably, the inventive mixtures and compositions, respectively, are applied to the plant propagation material by a method such that germination is not induced, for example, by seed coating, pelleting, covering and dusting.

[042] When used in plant protection, the amounts of active substances applied, depending on the type of effect desired, are between 0.001 and 2 kg per ha, preferably from 0.005 to 2 kg per ha and more preferably from 0.01 to 1kg per ha, and in particular from 0.05 to 0.75 kg per ha.

[043] In the treatment of plant propagation materials such as seeds, for example by sprinkling, coating or soaking, amounts of active substances from 0.1 to -10 kg, preferably from 1-1000 g, more preferably from 1-100 g per 100 kg of plant propagation material (preferably seeds).

[044] When used to protect stored materials or products, the amount of active substance applied depends on the type of application area and the desired effect. Values usually applied in the protection of materials are from 0.001 g to 2 kg, preferably 0.005 g to 1 kg, of active substance per cubic meter of treated material.

[045] Various types of oils, humectants, adjuvants, fertilizers, or additional micronutrients and pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, protective agents (or phytoprotectants)) can be added to the active substances, or to compositions comprising such substances or, if appropriate, not until immediately before use (tank mix). These agents can be mixed with the compositions of the invention in a weight ratio (weight ratio) of 1:100 to 100:1, preferably 1:10 to 10:1.

[046] The user applies the composition according to the present invention from a pre-dosing device, a backpack sprayer, a spray tank, a spray plane, or irrigation system. Typically, the agrochemical composition is made with water, buffer, and/or other auxiliary agents to the desired application concentration and the ready-to-use spray solution or agrochemical composition according to the invention is thus obtained. Typically, 20 to 2000 litres, preferably 50 to 400 litres, of the ready-to-use spray solution is applied per hectare of agricultural usable area.

[047] According to an example of embodiment, the individual components of the composition according to the invention, such as parts of a kit, or parts of a binary mixture, can be mixed by the user himself in a spray tank or any type container used for applications (eg seed treatment drums, seed granulation machines, knapsack sprayer) and other auxiliaries can be added if appropriate.

[048] Accordingly, an exemplary embodiment of the invention is a kit for preparing a usable pesticidal composition, which kit comprises; a) a composition comprising component 1), preferably compound i of formula I as defined in the present invention and at least one auxiliary; and b) a composition comprising component 2) as defined in the present invention and at least one auxiliary; and optionally c) a composition comprising at least one auxiliary and, optionally, an additional active component 3) as defined in the present invention.

[049] As stated above, the present invention comprises the use of the mixture to control harmful phytopathogenic fungi and a method of controlling phytopathogenic pests, wherein the pest, its habitat, breeding grounds (breeding grounds), the site or plants to be are protected from pest attack, the soil or plant propagation material is treated with an effective amount of the mixture.

[050] Advantageously, the mixtures of the invention are suitable for controlling the following fungal diseases in plants: Albugo spp. (white rust) on ornamental plants, vegetables (eg A. candida) and sunflowers (eg A. tragopogonis); Alternaria spp. (Alternaria leaf spot) on vegetables (e.g. A. dauci or A. porri), canola oil (A. brassicicola or brassicae), beetroot (A. tenuis), fruit (e.g. A. grandis ), rice, soybeans, potatoes and tomatoes (e.g. A. solani, A. grandis or A. alternata), tomatoes (e.g. A. solani or A. alternata) and wheat (e.g. A. triticina); Aphanomyces spp. in beets, vegetables and greens; Ascochyta spp. in cereals and legumes, such as A. tritici (anthracnose) in wheat and A. hordei in barley; Aureobasidium zeae (syn. Kapatiella zeae) in maize; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), such as southern leaf spot (D. maydis) or northern leaf spot (B. zeicola) in maize, such as spot blister (B.

sorokiniana) in cereals and, for example, B. oryzae in rice and grass; Blumeria (formerly Erysiphe) graminis (powder mildew) on cereals (eg on wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) on fruits and berries (eg strawberries), vegetables (eg lettuce, carrots, celery and cabbage); B. squamosa or B. allii in the onion family), canola, ornamental plants (eg, B. elliptica), grapes, forest plants and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (rot or wilt) on broadleaf trees and perennials such as C. ulmi (Dutch elm disease) on elms; Cercospora spp. (Cercospora leaf spots) on maize (eg, gray leaf spots: C. zeae-maydis), rice, sugar beet (eg C. beticola), sugar cane, legumes, vegetables, coffee and soybeans (eg for example, C. sojina or C. kikuchii) and rice; Cladobotryum (syn. Dactylium) spp (eg, C. mycophilum (formerly, Dactylium dendroides, teleomorph: Nectria albertinii, Nectria rosella sin. Hypomyces rosellus) on mushrooms; Cladosporium spp. on tomatoes (eg, C. fulvum: leaf mold ) and cereals such as C. herbarum (black ear) on wheat; Claviceps purpurea (ergot) on cereals; Cochliobolus (anamorph: Helminthosporium de Bipolaris) spp. (leaf spots) on maize (C. carbonum), cereals (for e.g. C. sativus, anamorph: B. sorokiniana) and rice (e.g. C.

miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (eg C. gossypii), maize (eg C. graminicola: Anthracnose stem rot), soft fruits, potatoes (eg C. coccodes: black spots), beans (eg , Ç.

lindemuthianum), soybeans (eg, C. truncatum or C. gloeosporioides), vegetables (eg, C. lagenarium or C. capsici), fruits (eg, C. acutatum), coffee (eg, C. coffeanum or C. kahawae) and C.

gloeosporioides in different seasons; Corticium spp., eg C. sasakii

(sheath rust) in rice; Corynespora cassiicola (leaf spots) on soybean and ornamental plants; Cycloconium spp., such as C. oleaginum on olive trees; Cylindrocarpon spp. (eg, canker of fruit trees or decline of young grapes, teleomorph: Nectria or Neonectria spp.) on fruit trees, grapes (eg, C. liriodendri, teleomorph: Neonectria liriodendri: black foot disease) and ornamental plants; Dematophora (teleomorph: Rosellinia) necatrix (stem and root rot) in soybean; Diaporthe spp., such as D. phaseolorum (damp-off) on soybean; Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. in maize, cereals such as barley (e.g. D. teres, reticular leaf spot) and wheat (e.g. D. tritici-repentis: brown leaf spot), rice and grass; Esca (decline, apoplexy) in grapes, caused by Formitiporia (syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and/or Botryosphaeria obtusa; Elsinoe spp. in pome fruit (E.

pyri), soft fruits (E. veneta: anthracnose) and grapes (E. ampelina: anthracnose); Entyloma oryzae (leaf soot) on rice; Epicoccum spp. (black mold) on wheat; Erysiphe spp. (powder mildew) on beets (E. betae), vegetables (e.g. E. pisi), such as pumpkins (e.g. E.

cichoracearum), cabbage, canola (eg, E. cruciferarum); Eutypa lata (cancer or Eutypa decline, anamorph: Cytosporina lata, sin. Libertella blepharis) on fruit, grapes and ornamental wood; Exserohilum (syn.

Helminthosporium) spp. in maize (eg E. turcicum); Fusarium (teleomorph: Gibberella) spp. (withering, stem or root rot) in various plants, such as F. graminearum or F. culmorum (root rot, head blight or scab) in cereals (e.g. wheat or barley), F.

oxysporum on tomatoes, F. solani (F. sp. glycines, now syn. F. virguliforme), F. tucumaniae and F. brasiliense, each causing sudden death syndrome in soybean, and F. verticillioides in corn; Gaeumannomyces graminis (foot disease) in cereals (eg wheat or barley) and maize; Gibberella spp. in cereals (eg G. zeae) and rice (eg G. fujikuroi: Bakanae disease); Glomerella cingulata on grapes, apples and other plants and G. gossypii on cotton; grain coloring complex in rice; Guignardia bidwellii (black rot) on grapes; Gymnosporangium spp. in rosaceous and juniper plants, such as G. sabinae (rust) in pears; Helminthosporium spp.

(syn. Drechslera, teleomorph: Cochliobolus) in maize, cereals, potatoes and rice; Hemileia spp., such as H. vastatrix (coffee leaf rust) in coffee; Isariopsis clavispora (syn. Cladosporium vitis) on grapes; Macrophomina phaseolina (sin. phaseoli) (root and stem rot) in soybean and cotton; Microdochium (syn. Fusarium) nivale (pink snow mold) in cereals (eg wheat or barley); Microsphaera diffusa (powder mildew) in soybean; Monilinia spp., such as M. laxa, M. fructicola and M. fructigena (syn. Monilia spp.: twig and flower blight, brown rot) on drupes and other rosaceous plants; Mycosphaerella spp. on cereals, bananas, soft fruits and peanuts, such as M. graminicola (anamorph: Zymoseptoria tritici, formerly Septoria tritici: Septoria rust) on wheat or M. fijiensis (syn.

Pseudocercospora fijiensis: black Sigatoka disease) and M. musicola on bananas, M. arachidicola (syn. M. arachidis or Cercospora arachidis), M.

berkeleyi on peanuts, M. pisi on peas and M. brassiciola on Brassica; Peronospora spp. (downy mildew) on cabbage (e.g. P. brassicae), canola (e.g. P. parasitica), onions (e.g. P. destructor), tobacco (P. tabacina) and soybeans (e.g. P. manshurica ); Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybean; Phialophora spp., such as in grapes (e.g. P. tracheiphila and P. tetraspora) and soybeans (e.g. P. gregata: stem rot); Phoma lingam (syn. Leptosphaeria biglobosa and L. maculans: stem and root rot) on canola and cabbage, P. betae (root rot, leaf spot and damping-off) on sugar beet and P. zeae-maydis (syn. Phyllostica zeae) in maize; Phomopsis spp. in sunflower, grapes (eg P. viticola: leaf spot and can) and soybean (eg stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) on corn; Phytophthora spp. (withering and rotting of roots, leaves, fruits and stems) of various plants such as paprika and squash (e.g. P. capsici), soybeans (e.g. P.

megasperm, yes. P. soyae), potatoes and tomatoes (eg P. infestans: late blight) and broadleaf trees (eg P. ramorum: sudden death of oak); Plasmodiophora brassicae (cabbage hernia) on cabbage, canola, radish and other plants; Plasmopara spp., such as P. viticola (grape downy mildew) on grapes and P. halstedii on sunflower; Podosphaera spp. (powder mildew) on rosaceous plants, hops, pomes and soft fruits (e.g. P.

leucotricha on apples) and pumpkins (P. xanthii); Polymyxa spp, for example in cereals such as barley and wheat (P. graminis) and sugar beet (P. betae) and viral diseases transmitted in this way; Pseudocercosporella herpotrichoides (syn. Oculimacula yallundae, O. acuformis: mad bed, teleomorph: Tapesia yallundae) in cereals such as wheat or barley; Pseudoperonospora (downy mildew) on various plants, such as P. cubensis on pumpkins or P. humili on hops; Pseudopezicula tracheiphila (fire red disease or “brenner rot”, anamorph: Phialophora) in grapes; Puccinia spp. (rusts) on various plants, such as P. triticina (leaf rust or brown), P. striiformis (streaked or yellow rust), P. hordei (dwarf rust), P. graminis (black or stem rust), or P. recondita (brown or leaf rust) on cereals such as wheat, barley or rye, P. kuehnii (orange rust) on sugar cane and P. asparagi on asparagus; Pyrenopeziza spp., such as P. brassicae on canola; Pyrenophora (anamorph: Drechslera) tritici-repentis (brown spot) on wheat or P. teres (reticular spot) on barley; Pyricularia spp., such as P. oryzae (teleomorph: Magnaporthe grisea: rice blast) on rice and P. grisea on grass and cereals; Pythium spp. (tipping) on grass, rice, corn, wheat, cotton, canola, sunflower, soybeans, sugar beet, legumes, vegetables and various other plants (eg P. ultimum or P. aphanidermatum) and P.

oligandrum in mushrooms; Ramularia spp., such as R. collo-cygni (Ramularia leaf spots, physiological leaf spots) on barley and R.

beticola in beetroot; Rhizoctonia spp. on cotton, rice, potato, grass, corn, canola, potato, sugar beet, legumes, vegetables and various other plants such as R. solani (stem and root rot) on soybean, R. solani (sheath rust) on rice or R. cerealis (Rhizoctonia spring rust) on wheat or barley; Rhizopus stolonifer (black mold, soft root) on strawberries, carrots, cabbage, grapes and tomatoes; Rhynchosporium secalis and R. commune (burn) on barley, rye and triticale; Sarocladium oryzae and S.

attenuatum (sheath rot) in rice; Sclerotinia spp. (stem rot or white mold) in vegetables (S. minor and S. sclerotiorum) and field crops such as canola, sunflower (eg, S. sclerotiorum) and soybean, S.

rolfsii (syn. Athelia rolfsii) in soybeans, peanuts, legumes, vegetables, corn, cereals and ornamental plants; Septoria spp. in various plants, such as S. glycines (brown spot) on soybean, S. tritici (syn. Zymoseptoria tritici, Septoria rust) on wheat and S. (syn. Stagonospora) nodorum (Stagonospora spot) on cereals; Uncinula (syn. Erysiphe) necator (powder mildew, anamorph: Oidium tuckeri) on grapes; Setosphaeria spp. (leaf rust) on maize (eg S. turcicum, sin. Helminthosporium turcicum) and grass; Sphacelotheca spp. (soot) in maize (eg S. reiliana, syn. Ustilago reiliana: superior soot), sorghum and sugar cane; Sphaerotheca fuliginea (syn.

Podosphaera xanthii (powder mildew)) on pumpkins; Spongospora subterranea (powdery scab) on potatoes and viral diseases transmitted in this way; Stagonospora spp. in cereals, such as S. nodorum (Stagonospora spot, teleomorph: Leptosphaeria (syn. Phaeosphaeria) nodorum, syn.

Septoria nodorum) in wheat; Synchytrium endobioticum in potatoes (warts); Taphrina spp., such as T. deformans (leaf curl) on peaches and T.

pruni (plum leprosy) on plums; Thielaviopsis spp. (black root rot) in tobacco, drupes, legumes, vegetables, soybeans and cotton, such as T.

basicola (syn. Chalara elegans); Tilletia spp. (common bulge or fetid soot) in cereals, such as T. tritici (syn. T. caries, wheat bulge) and T. controversial (dwarf bulge) in wheat; Trichoderma harzianum on mushrooms; Typhula incarnata (gray snow mould) on barley or wheat; Urocystis spp., such as U.

occulta (stem soot) on rye; Uromyces spp. (rust) on vegetables such as beans (eg U. appendiculatus, sin. U. phaseoli), beets (eg U. betae or U. beticola) and pulses (eg U. vignae, U. . pisi, U. viciae-fabae and U. fabae); Ustilago spp. (loose soot) in cereals (eg U. nuda and U. avaenae), maize (eg U. maydis: corn soot) and sugar cane; Venturia spp. (scab) in apples (eg V. inaequalis) and pears; and Verticillium spp. (withering) on various plants, such as fruits and ornamentals, grapes, soft fruits, vegetables, and field crops, such as V. longisporum on canola, V. dahliae on strawberries, canola, potatoes and tomatoes, and V. fungicola in mushrooms; Zymoseptoria tritici in cereals; Phaeosphaeria maydis and Puccinia polysora.

[051] Preferably, the mixtures of the invention are suitable for controlling the following fungal diseases in soybean: Alternaria spp. (Alternaria leaf spot); Cercospora spp. (leaf spots on Cercospora), eg C. sojina or C. kikuchii); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose), e.g. C. truncatum or C.

gloeosporioides); Corynespora cassiicola (leaf spots); Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot); Diaporthe spp., eg D. phaseolorum (damp-off); Fusarium (teleomorph: Gibberella) spp. (root rot or stem wilt), e.g. F.

tucumaniae and F. brasiliense, each of which causes sudden death syndrome in soybeans; Macrophomina phaseolina (synonym; phaseoli) (root and stem rot); Microsphaera diffusa (powdery mildew); Peronospora spp. (downy mildew), for example, P. manshurica; Phakopsora pachyrhizi and P. meibomiae (soybean rust); Phialophora spp., eg P. gregata: stem rot; Phomopsis spp., eg stem rot: P. phaseoli (teleomorph: Diaporthe phaseolorum); Pythium spp. (tipping); Phytophthora spp. (withered root, leaf, fruit and stem), e.g. P.

megasperm, synonym; P. soya); Rhizoctonia spp., eg R. solani (root and stem rot); Sclerotinia spp. (stem rot or white mold); Septoria spp., eg S. glycines (brown spot); S.

rolfsii (synonym; Athelia rolfsii); Thielaviopsis spp. (black root rot).

[052] More preferably, the mixtures of the invention are suitable for controlling the following fungal diseases in soybean: Alternaria spp. (Alternaria leaf spot); Cercospora spp. (leaf spots on Cercospora), eg C. sojina or C. kikuchii); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose), e.g. C. truncatum or C.

gloeosporioides); Corynespora cassiicola (leaf spots); Diaporthe spp., eg D. phaseolorum (damp-off); Fusarium (teleomorph: Gibberella) spp. (withered root or stem), for example, F. tucumaniae and F. brasiliense, each of which causes sudden death syndrome in soybeans; Macrophomina phaseolina (sin. phaseoli) (root and stem rot); Peronospora spp. (downy mildew), for example, P. manshurica; Phakopsora pachyrhizi and P. meibomiae (soybean rust); Phomopsis spp., eg stem rot: P. phaseoli (teleomorph: Diaporthe phaseolorum); Phytophthora spp. (root, leaf, fruit and root of withered stems), e.g. P.

megasperm, yes. P. soya); Rhizoctonia spp., eg R. solani

(root and stem rot); Septoria spp., eg S. glycines (brown spot).

[053] More preferably, the mixtures of the invention are suitable for controlling Phakopsora pachyrhizi and P. meibomiae (soybean rust) on soybeans.

[054] The mixtures according to the present invention, respectively, are also suitable for combating harmful fungi in the protection of stored or harvested products and in the protection of materials.

[055] The term “materials protection” should be understood to designate the protection of technical and non-living materials, such as adhesives, glues, wood, paper and cardboard, textiles, leather, paint dispersions, plastics, cooling lubricants, fiber or fabrics, against infestation and destruction by harmful microorganisms such as fungi and bacteria. As for the protection of wood and other materials, special attention is paid to the following harmful fungi: Ascomycetes such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes such as Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Deuteromycetes such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichorma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes such as Mucor spp., and additionally in the protection of stored and harvested products the following yeasts of note: Candida spp. and Saccharomyces cerevisae.

[056] They are particularly important for controlling a large amount of fungi in various cultivated plants such as bananas, cotton, plant species (eg cucumbers, beans and cucurbits), cereals such as wheat, rye, barley, rice, oats; coffee, potato, corn, fruit species, soybeans, tomatoes, vines, ornamental plants, sugar cane and also a large number of seeds. In a preferred embodiment, the mixtures of the invention are used in soybeans (soybeans), cereals and corn.

[057] In general, "pesticideally effective amount" means the amount required of the mixtures of the invention or of compositions comprising the mixtures to achieve an observable effect on growth, including the effects of necrosis, retardation of death, prevention and removal, destruction, or otherwise decrease in the occurrence and activity of the target organism. The pesticidally effective amount may vary for the various mixtures/compositions used in the invention. A pesticidally effective amount of the mixtures/compositions will also vary according to prevailing conditions, such as desired pesticidal effect and duration, climate, target species, desired location and mode of application, and the like.

[058] As noted above, the present invention comprises a method of improving the health of plants, wherein the plant, the location where the plant is growing or is expected to grow, or the plant propagation material, from which the plant grows, is treated with a phytosanitary effective amount of a mixture of the invention.

[059] The term "plant effective amount" means an amount of the mixtures of the invention which is sufficient to achieve the effects on plant health, as defined below. More exemplary information on amounts, forms of application and proportions suitable for use is provided below. In any case, the person skilled in the art is well aware of the fact that an amount can vary over a wide range and is dependent on many factors, for example, the cultivated plant or material and climatic conditions.

[060] When mixtures are prepared, it is preferred to use the pure active compounds, to which other active compounds against pests can be added, such as insecticides, herbicides, fungicides or other active compounds, herbicidal or growth regulators or fertilizers as active components. additional as needed.

[061] The mixtures of the invention are employed by treating the fungi or plants, plant propagation material (preferably seeds), materials or soil to be protected from fungal attack with a pesticidally effective amount of the active compounds. Application can be carried out before and after infection of the materials, plants or plant propagation materials (preferably seeds) by pests.

[062] In the context of the present invention, the term plant refers to an entire plant, a part of the plant or the plant propagation material.

[063] The mixtures of the invention and their compositions are particularly important in the control of a multitude of phytopathogenic fungi in various cultivated plants, such as cereals, for example wheat, rye, barley, triticale, oats or rice; beet, for example sugar beet or fodder beet; fruits, such as pomes, stone fruits or soft fruits, for example apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or blackcurrants; leguminous plants such as lentils, peas, alfalfa or soybeans; oil plants such as rapeseed, canola; mustard, olives, sunflowers, coconut, cocoa, castor, palm, peanut or soy; cucurbits, such as pumpkins, cucumbers or melons; fibrous plants such as cotton, flax, hemp or jute; citrus fruits such as oranges, lemons, grapefruits or tangerines; vegetables such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, cucurbits or paprika; lauraceous plants such as avocado, cinnamon or camphor; raw materials for energy, such as corn, soy, rapeseed, sugar cane or palm; corn; tobacco; nuts; coffee; tea; bananas; vines (table grapes and grapes for juice and vine grapes); hop; peat; sweet grass (also called

Stevia); natural rubber plants or ornamental and forestry plants, such as flowers, shrubs, broadleaf trees or pines, for example conifers; and on plant propagation material, such as seeds, and harvest material from these plants.

[064] Preferably, the mixtures of the invention and their compositions are used to control a number of fungi in crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rapeseed, pulses. , sunflower, coffee or sugar cane; fruits; vines; ornamental plants; or vegetables such as cucumbers, tomatoes, beans or pumpkins.

[065] Preferably, the treatment of plant propagation materials with the mixtures of the invention and their compositions, respectively, is used to control a multitude of fungi in cereals, such as wheat, rye, barley and oats; potatoes; tomatoes; grape; rice, corn, cotton and soy.

[066] The term “cultivated plants” is also intended to include plants that have been modified by breeding, mutagenesis or genetic engineering, including but not limited to agricultural biotechnology products on the market or under development (see http://cera- gmc.org/, see the GM crop database). Genetically modified plants are plants in which the genetic material has been modified using recombinant DNA techniques that, under natural circumstances, could not be easily obtained by crossing, mutation or natural recombination. Typically, one or more genes are integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant. These genetic modifications include, but are not limited to, targeted post-translational modification of protein(s), oligo- or polypeptides, for example, by glycosylation or polymer additions, such as prenylated, acetylated or farnesylated moieties or PEG moieties.

[067] Plants that have been modified by breeding, mutagenesis or genetic engineering, for example, have been made tolerant to applications of specific classes of herbicides, such as auxin herbicides such as dicamba or 2,4-D; bleaching herbicides such as dioxygenase inhibitors (HPPD hydroxylphenylpyruvate) or phytoenyl desaturase inhibitors (PDS); acetolactate synthase (ALS) inhibitors such as sulfonylureas or imidazolinones; enolpyruvylshikimate-3-phosphate (EPSPS) inhibitors such as glyphosate; glutamine synthetase (GS) inhibitors such as glufosinate; protoporphyrinogen oxidase-IX inhibitors; lipid biosynthesis inhibitors such as acetyl-CoA carboxylase (ACCase) inhibitors; or oxynyl herbicides (ie bromoxynil or yoxynil) as a result of conventional breeding methods or genetic engineering.

In addition, plants have been made resistant to multiple herbicide classes through multiple genetic modifications, such as resistance to glyphosate and glufosinate or to glyphosate and a herbicide of another class, such as ALS inhibitors, HPPD inhibitors, auxin herbicides, or ACCase inhibitors. These herbicide resistance technologies are, for example, described in Pest Management Sci. 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Sci. 57, 2009, 108; Southern. J. Agricultural. Res. 58, 2007, 708; Science 316, 2007, 1185; and the references cited therein. Several crop plants have been made tolerant to herbicides by conventional breeding methods (mutagenesis), e.g. Clearfield® summer rape (Canola, BASF SE, Germany) tolerant to imidazolinones, e.g. imazamox, or ExpressSun® sunflowers (DuPont, USA), sulfonylurea tolerant, e.g. Tribenuron. Genetic engineering methods have been used to make cultivated plants such as soybeans, cotton, corn, sugar beets and rapeseed,

tolerant to herbicides such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady ® (glyphosate tolerant, Monsanto, USA) and LibertyLink ® (glufosinate tolerant, Bayer CropScience, Germany)).

[068] In addition, plants are also covered by the use of recombinant DNA techniques capable of synthesizing one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly Bacillus thuringiensis, such as δ-endotoxins, for example, CryIA (b), CryIA(c), CryIF, CryIF(a2), CryIIA(b), CryIIIA, CryIIIB(b1) or Cry9c; vegetative insecticidal proteins (VIP), for example, VIP1, VIP2, VIP3 or VIP3A; insecticidal proteins from nematode colonizing bacteria, eg Photorhabdus spp. or Xenorhabdus spp.; toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins; fungi produced toxins such as streptomycete toxins, plant lectins such as pea or barley lectins; agglutinins; proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome inactivating proteins (RIPs), such as ricin, corn RIP, abrin, luphine, saporin or bryodin; steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone or HMG-CoA reductase inhibitors; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormone esterase; diuretic hormone receptors (helicokinin receptors); stilbene synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention such insecticidal proteins or toxins are also to be expressly understood as pre-toxins, hybrid proteins, truncated or otherwise modified proteins. Hybrid proteins are characterized by a novel combination of protein domains, (see, for example, WO document

02/015701). Other examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, for example,

in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529,

EP-A 451 878, WO 03/18810 and WO 03/52073. Methods for producing such genetically modified plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above.

These insecticidal proteins contained in genetically modified plants provide protection for the plants that produce these proteins against harmful pests belonging to all taxonomic groups of arthropod insects, especially beetles.

(Coleoptera), two-winged insects (Diptera), moths (Lepidoptera) and parasitic nematodes (Nematoda). Genetically modified plants capable of synthesizing one or more insecticidal proteins are, for example, described in the publications mentioned above, some of which are commercially available, such as YieldGard® (corn cultivars that produce the toxin

Cry1Ab), YieldGard® Plus (corn cultivars that produce the Cry1Ab and Cry3Bb1 toxin), Starlink® (corn cultivars that produce the Cry9c toxin),

Herculex RW® (corn cultivars that produce Cry34Ab1, Cry35Ab1 and the enzyme phosphinothricin-N-acetyltransferase [PAT]); NuCOTN ® 33B (cotton cultivars that produce Cry1Ac toxin), Bollgard® I (cotton cultivars that produce Cry1Ac toxin) Bollgard® II (cotton cultivars that produce Cry1Ac and Cry2Ab2 toxins); VipCot® (cotton cultivars that produce a VIP toxin); NewLeaf® (potato cultivars that produce the Cry3A toxin); Bt-

Xtra®, NatureGard®, KnockOut®, BiteGard®, Proteta®, Bt11 (e.g.

Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France (corn cultivars that produce Cry1Ab toxin and PAT Enzyme), MIR604 from

Syngenta Seeds SAS, France (corn cultivars producing a modified version of the Cry3A toxin, WO 03/018810), MON 863 from Monsanto Europe SA, Belgium (corn cultivars producing the Cry3Bb1 toxin), IPC 531 from Monsanto Europe SA, Belgium (cotton cultivars that produce a modified version of the Cry1Ac toxin) and 1,507 from Pioneer Overseas Corporation, Belgium (corn cultivars that produce the Cry1F toxin and the PAT enzyme).

[069] In addition, plants that, through the use of recombinant DNA techniques, are able to synthesize one or more proteins to increase the resistance or tolerance of said plants to bacterial, viral or fungal pathogens are also covered. Examples of such proteins, termed “pathogenesis-related proteins” (PR proteins, see e.g. EP-A 0392225), plant disease resistance genes (e.g. potato cultivars, which express resistance genes acting against Phytophthora infestans derived from the Mexican wild potato Solanum bulbocastanum) or T4-Lysozyme (for example, potato cultivars that have the capacity to synthesize these proteins with greater resistance against the bacteria Erwinia amylvora). Methods for producing such genetically modified plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above.

[070] In addition, plants that, through the use of recombinant DNA techniques, are able to synthesize one or more proteins to increase productivity (for example, greater biomass production, grain yield, starch content, oil or protein content), tolerance to drought, salinity or other environmental factors limiting growth or tolerance to fungal, viral or bacterial pests and pathogens of these plants.

[071] In addition, plants that, through the use of recombinant DNA techniques, contain a modified amount of content substances or new substances, specifically to improve human or animal nutrition, for example, oilseed crops that produce long-chain omega-3 fatty acids or health-promoting unsaturated omega-9 fatty acids (eg, Nexera ® from Dow Agro Sciences, Canada).

[072] In addition, plants are also covered which, through the use of recombinant DNA techniques, contain a modified amount in the content of substances or new substances, specifically to improve the production of raw material, for example, potatoes that produce increased amounts of amylopectin (eg Amflora ® potato, BASF SE, Germany).

[073] The separate or joint application of the compounds of the mixtures of the invention is carried out by spraying or atomizing the seeds, seedlings, plants or the soils before or after sowing the plants, or before or after the emergence of the plants.

[074] The mixtures of the invention and the compositions comprising them can be used to protect wooden materials such as trees, fences, sleepers, etc. and buildings such as houses, outbuildings, factories, but also building materials, furniture, leathers, fibers, vinyl items, electrical wires and cables, etc. from pests such as ants and/or termites, and to control ants and termites from causing damage to crops or humans (eg when pests invade homes and public facilities).

[075] The usual application rates in the protection of materials are, for example, from 0.01 g to 1000 g of active compound per m 2 of treated material, and desirably from 0.1 g to 50 g per m2.

[076] For use in spray compositions, the active ingredient content is from 0.001 to 80% by weight, preferably from 0.01 to 0.01 to

50% by weight, and more preferably from 0.01 to 15% by weight.

STOVE

[077] Solutions for spraying were prepared in several steps: - The stock solution (standard solution) was prepared: a mixture of acetone and/or dimethyl sulfoxide and the wetting/emulsifying agent Wettol, which is based on ethoxylated alkylphenols, in a ratio ( volume) solvent-emulsifier of 99 to 1 was added to the initial weight of the compound to give a total volume of 5 ml; - Then, water was added to the total volume of 100 mL; and - This stock solution was diluted with the solvent-emulsifier-water mixture described at said concentration.

EXAMPLE 1

CURATIVE CONTROL OF SOYBEAN RUST CAUSED BY PHAKOPSORA PACHYRHIZI

[078] Leaves of soybean seedlings grown in pots were inoculated with spores of Phakopsora pachyrhizi. To ensure the success of the artificial inoculation, the plants were transferred to a humid chamber with a relative humidity of about 95% and a temperature of 20 to 24 ºC for 24 h. The next day, the plants were grown for 2 days in a greenhouse at a temperature between 23ºC and 27ºC and a relative humidity between 60% and 80%. Then, the plants were sprayed to runoff with an aqueous suspension containing the concentration of active ingredient or its mixture as described below. The plants were left to air dry.

Then, the test plants were cultivated for 14 days in a greenhouse at 23-27 ºC and relative humidity between 60 and 80%. The extent of fungal attack on leaves was visually evaluated as a % diseased leaf area.

Calculated Efficacy Active compound / mixture Concentration Efficacy Mixture according to active (ppm) observed Colby (%) Untreated control 90% disease Product alone Phenpropimorph 250 - 39 63 - 12 16 - 6 Fluindapir 4 - 19 Prothioconazole 4 - 24 Mixtures of three components Fenpropimorph 250 63 : 1 : 1 87 63 Fluindapyr 4 Prothioconazole 4 EXAMPLE 2

PROTECTIVE CONTROL OF SOYBEAN RUST CAUSED BY PHAKOPSORA PACHYRHIZI

[079] Leaves of soybean seedlings grown in pots were sprayed to runoff with an aqueous suspension containing the concentration of active ingredient or its mixture as described below. The plants were left to air dry. The test plants were grown for two days in a greenhouse at 23-27 ºC and a relative humidity between 60 and 80%. Then, the plants were inoculated with spores of Phakopsora pachyrhizi. To ensure the success of the artificial inoculation, the plants were transferred to a humid chamber with a relative humidity of about 95% and a temperature of 20 to 24 ºC for 24 h. The test plants were grown for fourteen days in a greenhouse at 23-27 ºC and a relative humidity between 60 and 80%. The extent of fungal attack on leaves was visually evaluated as a % diseased leaf area.

[080] Diseases were converted into efficacy ratings.

[081] An efficacy of 0 means that the level of infection of treated plants corresponds to that of untreated control plants; an efficacy of 100 means that the treated plants were not infected.

[082] The expected efficacies of mixtures of active compounds were determined using the formula of Colby [R.S. Colby, “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds, 15, 20-22, (1967)] and compared with observed efficacies.

Calculated Efficacy Active compound / mixture Concentration Efficacy Mixture according to observed active (ppm) Colby (%) Untreated control 90% disease Product alone Fenpropimorph 250 - 54 63 - 16 16 - 6 Benzovindiflupir 4 - 58 Fluindapir 4 - 69 1 - 20 Difenoconazole 250 - 39 63 - 28 Prothioconazole 4 - 75 Tetraconazole 63 - 52 Three component mixtures Fenpropimorph 250 63 : 1 : 63 94 88 Benzovindiflupir 4 Difenoconazole 250 Fenpropimorph 63 16 : 1 : 16 87 75 Benzovindiflupir 4 Difenorconazole 63 fen3 3 : 63 80 68 Fluindapyr 1 Tetraconazole 63 Phenpropimorph 63 16 : 1 : 16 95 87 Fluindapyr 4

Calculated Efficacy Active compound / mixture Concentration Efficacy Mixture according to active (ppm) observed Colby (%)

Tetraconazole 63 Fenpropimorph 63 63 : 1 : 4 92 83 Fluindapyr 1 Prothioconazole 4

Claims (12)

1. FUNGICIDAL MIXTURES, characterized in that they comprise as active components: (1) phenpropimorph as compound I, and (2) a fungicidal compound II, wherein compound II is a succinate dehydrogenase inhibitor and is selected from the group consisting of : 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide 2-(difluoromethyl)-N-(1,1,3- trimethylindan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N -(3-ethyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan-4 -yl]pyridine-3-carboxamide, 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-(3 -isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide, 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1,1-dimethyl-indan-4-yl] pyridine-3-carboxamide, inpirfluxam, bixafem, pidiflumetophem, benzovindiflupyr, fluxapyroxad, fluindapyr, isoflucipram, sedaxane, and ( 3) a fungicidal compound III of the DMI class of fungicides (C14-demethylase inhibitor in sterol biosynthesis), wherein compound III is selected from the group consisting of: prothioconazole, difenoconazole, tetraconazole, cyproconazole, metconazole, 4- [6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-triazol-1-yl)propyl]-3-pyridyl] oxy]benzonitrile, tebuconazole, mefentrifluconazole. MIXTURE according to claim 1, characterized in that it is selected from: Compound I Compound II Compound III fenpropimorph inpirfluxam difenoconazole fenpropimorph inpirfluxam mefentrifluconazole fenpropimorph inpirfluxam tetraconazole fenpropimorph inpirfluxam cyproconazole fenpropimorph inpirfluxam metconazole 4-[[6-[2-( 2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-fenpropimorph inpirfluxam triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile fenpropimorph bixafen difenoconazole fenpropimorph bixafem mefentrifluconazole fenpropimorph bixafem tetraconazole fenpropimorph bixafem metconazole 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4- fenpropimorph bixaphen triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile fenpropimorph pidiflumetophem difenoconazole fenpropimorph pidiflumetophem tetraconazole fenpropimorph pidiflumetophem metconazole 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro- 2-hydroxy-3-(5-sulfanyl-1,2,4-fenpropimorph pidiflumetophem triaz ol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile fenpropimorph benzovindiflupyr Difenoconazole fenpropimorph benzovindiflupyr Tetraconazole fenpropimorph benzovindiflupyr Metconazole 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2- hydroxy-3-(5-sulfanyl-1,2,4-phenpropimorph benzovindiflupyr triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile fenpropimorph fluxapyroxad difenoconazole fenpropimorph fluxapyroxad tetraconazole fenpropimorph fluxapyroxad metconazole 4-[[6-[2 -(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-fenpropimorph fluxapyroxade triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile fenpropimorph fluindapyr prothioconazole fenpropimorph fluindapyr tebuconazole fenpropimorph fluindapyr difenoconazole Compound I Compound II Compound III fenpropimorph fluindapyr mefentrifluconazole fenpropimorph fluindapyr tetraconazole fenpropimorph fluindapyr cyproconazole fenpropimorph fluindapyr metconazole 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5- sulfanyl-1,2,4-phenpropimorph fluindapyr triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile fenpropimorph isoflucipram prothioconazole fenpropimorph isoflucipram tebuconazole fenpropimorph isoflucipram diphenoconazole fenpropimorph isoflucipram mefentrifluconazole fenpropimorph isoflucipram tetraconazole fenpropimorph isoflucipram tetraconazole phenpropiconazole phenpropiconazole cyclopropiconazole cyprimoconazole cyclopropiconazole cypropiconazole isoflucipram tetraconazole isoflucipram cypropimorph isoconazole [6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-fenpropimorph isoflucipram triazol-1-yl)propyl]-3- pyridyl]oxy]benzonitrile fenpropimorph sedaxane prothioconazole fenpropimorph sedaxane tebuconazole fenpropimorph sedaxane difenoconazole fenpropimorph sedaxane mefentrifluconazole fenpropimorph sedaxane tetraconazole fenpropimorph sedaxane cyproconazole fe npropimorph sedaxane metconazole 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-phenpropimorph sedaxane triazol-1-yl )propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-(1,1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N-(1, 1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-(1,1,3-fenpropimorph trimethylindan-4-yl)pyridine-3-xifenoconazole carboxamide 2-(difluoromethyl) -N-(1,1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-(1,1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-tetraconazole carboxamide 2-(difluoromethyl)-N-(1,1,3-fenpropimorph cyproconazole trimethylindan-4-yl)pyridine-3- Compound I Compound II Compound III carboxamide 2-(difluoromethyl)-N-(1,1,3-phenpropimorph trimethylindan-4-yl)pyridine-3-metconazole carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2 -(difluoromethyl)-N-(1,1,3-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-phenpropimorph trimethylindan-4-yl)pyridin-3-triazol-1-yl) propyl]-3-carboxamide pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N-[(3R)-1,1,3-phenpropimorph trimethylindan-4-yl]pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N -[(3R)-1,1,3-phenpropimorph trimethylindan-4-yl]pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1,3-fenpropimorph trimethylindan-4-yl ]pyridine-3-xifenoconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1,3-phenpropimorph trimethylindan-4-yl]pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-[(3R )-1,1,3-phenpropimorph trimethylindan-4-yl]pyridin-3-tetraconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1,3-phenpropimorph trimethylindan-4-yl]pyridine-3 - cyproconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1,3-phenpropimorph trimethylindan-4-yl]pyrid ina-3-metconazole carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-1,1,3-difluoro-2- hydroxy-3-(5-sulfanyl-1,2,4-phenpropimorph trimethylindan-4-yl]pyridin-3-triazol-1-yl)propyl]-3-carboxamide pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N -(3-ethyl-1,1-dimethyl-phenpropimorph prothioconazole indan-4-yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-phenpropimorph tebuconazole indan-4- yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-phenpropimorph difenoconazole indan-4-yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3- ethyl-1,1-dimethyl-phenpropimorph mefentrifluconazole indan-4-yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-phenpropimorph tetraconazole indan-4-yl)pyridine- 3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-phenpropimorph cyproconazole indan-4-yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-1, 1-dimethyl-phenpropimorph metconazole indan-4-yl)pyridine-3-carboxamide Compound I Compound II Compound III 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-difluoro-2- hydroxy-3-(5-sulfanyl-1,2,4-phenpropimorph indan-4-yl)pyridine-3-carboxamide triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N -[(3R)-3-ethyl-1,1-phenpropimorph dimethyl-indan-4-yl]pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1- fenpropimorph dimethyl-indan-4-yl]pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-fenpropimorph dimethyl-indan-4-yl]pyridine-3-diphenoconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-phenpropimorph dimethyl-indan-4-yl]pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-[(3R)- 3-ethyl-1,1-phenpropimorph dimethyl-indan-4-yl]pyridin-3-tetraconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-phenpropimorph dimethyl-indan-4 -yl]pyridine-3-cyproconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-phenpropimorph dimethyl-indan-4-yl]pyridine-3-metconazole car boxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-difluoro-2-hydroxy-3 -(5-sulfanyl-1,2,4-phenpropimorph dimethyl-indan-4-yl]pyridin-3-triazol-1-yl)propyl]-3-carboxamide pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N- (1,1-dimethyl-3-phenpropimorph propyl-indan-4-yl)pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N-(1,1-dimethyl-3-phenpropimorph propyl-indan-4-yl) pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-(1,1-dimethyl-3-phenpropimorph propyl-indan-4-yl)pyridine-3-diphenoconazole carboxamide 2-(difluoromethyl)-N-(1,1 -dimethyl-3-phenpropimorph propyl-indan-4-yl)pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-(1,1-dimethyl-3-phenpropimorph propyl-indan-4-yl)pyridine-3- tetraconazole carboxamide 2-(difluoromethyl)-N-(1,1-dimethyl-3-phenpropimorph propyl-indan-4-yl)pyridine-3-cyproconazole carboxamide 2-(difluoromethyl)-N-(1,1-dimethyl-3 - fenpropimorph propyl-indan-4-yl)pyridine-3-metconazole carboxamide Compound I Compound II Compound III 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-(1,1-dimethyl-3-difluoro-2-hydroxy- 3-(5-sulfanyl-1,2,4-phenpropimorph propyl-indan-4-yl)pyridin-3-triazol-1-yl)propyl]-3-carboxamide pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N -[(3R)-1,1-dimethyl-phenpropimorph 3-propyl-indan-4-yl]pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-phenpropimorph 3 -propyl-indan-4-yl]pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-phenpropimorph 3-propyl-indan-4-yl]pyridine-3-diphenoconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-phenpropimorph 3-propyl-indan-4-yl]pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-[(3R)- 1,1-dimethyl-phenpropimorph 3-propyl-indan-4-yl]pyridine-3-tetraconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-phenpropimorph 3-propyl-indan-4 -yl]pyridine-3-cyproconazole carboxamide 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-phenpropimorph 3-propyl-indan-4-yl]pyridine- 3-metconazole carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-difluoro-2-hydroxy- 3-(5-sulfanyl-1,2,4-phenpropimorph 3-propyl-indan-4-yl]pyridin-3-triazol-1-yl)propyl]-3-carboxamide pyridyl]oxy]benzonitrile 2-(difluoromethyl) -N-(3-isobutyl-1,1-phenpropimorph dimethyl-indan-4-yl)pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N-(3-isobutyl-1,1-phenpropimorph dimethyl-indan-4 -yl)pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-(3-isobutyl-1,1-phenpropimorph dimethyl-indan-4-yl)pyridine-3-diphenoconazole carboxamide 2-(difluoromethyl)-N-( 3-isobutyl-1,1-phenpropimorph dimethyl-indan-4-yl)pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-(3-isobutyl-1,1-phenpropimorph dimethyl-indan-4-yl)pyridine -3- tetraconazole carboxamide 2-(difluoromethyl)-N-(3-isobutyl-1,1-phenpropimorph dimethyl-indan-4-yl)pyridine-3-cyproconazole carboxamide 2-(difluoromethyl)-N-(3-isobutyl- 1,1-phenpropimorph dimethyl-indan-4-yl)pyridine-3-metconazole carboxamide Compound I Compound II Compound III 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-(3-isobutyl-1,1-difluoro-2-hydroxy- 3-(5-sulfanyl-1,2,4-phenpropimorph dimethyl-indan-4-yl)pyridin-3-triazol-1-yl)propyl]-3-carboxamide pyridyl]oxy]benzonitrile 2-(difluoromethyl)-N -[(3R)-3-isobutyl-phenpropimorph 1,1-dimethyl-indan-4-yl]pyridine-3-prothioconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-isobutyl-phenpropimorph 1,1 -dimethyl-indan-4-yl]pyridine-3-tebuconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-isobutyl-phenpropimorph 1,1-dimethyl-indan-4-yl]pyridine-3-diphenoconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-isobutyl-phenpropimorph 1,1-dimethyl-indan-4-yl]pyridine-3-mefentrifluconazole carboxamide 2-(difluoromethyl)-N-[(3R)- 3-isobutyl-phenpropimorph 1,1-dimethyl-indan-4-yl]pyridin-3-tetraconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-isobutyl-phenpropimorph 1,1-dimethyl-indan-4 -yl]pyridine-3-cyproconazole carboxamide 2-(difluoromethyl)-N-[(3R)-3-isobutyl-phenpropimorph 1,1-dimethyl-inda n-4-yl]pyridine-3-metconazole carboxamide 4-[[6-[2-(2,4-difluorophenyl)-1,1-2-(difluoromethyl)-N-[(3R)-3-isobutyl- difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4-phenpropimorph 1,1-dimethyl-indan-4-yl]pyridin-3-triazol-1-yl)propyl]-3-carboxamide pyridyl] oxy]benzonitrile 3. MIXTURE according to claim 1 or 2, characterized in that it is selected from: Compound I Compound II Compound III Phenpropimorph Inpirfluxam Mefentrifluconazole Phenpropimorph Pidiflumetophem Difenoconazole Phenpropimorph Fluindapyr Prothioconazole Phenpropimorph Fluindapyr Tebuconazole Fluindapyr Mefentrifluconazole Phenpropimorph Fluindapyr Tetraconazole Phenpropimorph Isoflucipram Prothioconazole Phenpropimorph Isoflucipram Prothiomorph (difluoromethyl)-N-(1,1,3-trimethylindan-4-Phenpropimorph Prothioconazole yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-Penpropimorph Prothioconazole 4 -yl]pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-ethyl-1,1-dimethyl-indan-Penpropimorph Prothioconazole 4-yl)pyridine-3-carboxamide Compound I Compound II Compound III 2-(Difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-Phenpropimorph Prothioconazole indan-4-yl]pyridine-3-carboxamide 2-(difluoromethyl)-N- (1,1-Dimethyl-3-propyl-Phenpropimorph Prothioconazole indan-4-yl)pyridine-3-carboxamide 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-Phenpropimorph Prothioconazole indan -4-yl]pyridine-3-carboxamide 2-(difluoromethyl)-N-(3-isobutyl-1,1-dimethyl-Phenpropimorph Prothioconazole indan-4-yl)pyridine-3-carboxamide 2-(difluoromethyl)-N- [(3R)-3-Isobutyl-1,1-Phenpropimorph Prothioconazole dimethyl-indan-4-yl]pyridine-3-carboxamide 4. MIXTURE according to any one of claims 1 to 3, characterized in that it is selected from: Compound I Compound II Compound III Phenpropimorph Pidiflumetophem Difenoconazole Fenpropimorph Fluindapyr Prothioconazole Phenpropimorph Fluindapyr Tebuconazole Fenpropimorph Fluindapyr Tetraconazole Phenpropimorph Isoflucipram Prothioconazole Phenpropimorph 2-(difluoromethyl) -N-[(3R)-1,1-dimethyl-3-propyl-indan-Prothioconazole 4-yl]pyridine-3-carboxamide 5. MIXTURE according to any one of claims 1 to 4, characterized in that it is: Compound I Compound II Compound III Phenpropimorph 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-Prothioconazole indan-4-yl]pyridine-3-carboxamide 6. PESTICIDE COMPOSITION, characterized in that it comprises a liquid or solid carrier and a mixture as defined in any one of claims 1 to 5. 7. USE OF THE MIXTURE, as defined in any one of claims 1 to 6, or of the pesticidal composition as defined in claim 5, characterized in that it is to control harmful phytopathogenic fungi. 8. USE, according to claim 7, characterized in that it is for controlling harmful phytopathogenic fungi in soybeans. 9. USE according to any one of claims 7 to 8, for controlling Phakopsora pachyrhizi and P. meibomiae (soybean rust). 10. METHOD FOR CONTROLLING PHYTOPATOGENIC PESTS, characterized by the pest, its habitat, breeding areas, location or plants that will be protected against the attack of said pests, the soil or plant propagation material being treated with an effective amount of the mixture as defined in any one of claims 1 to 5. 11. METHOD, according to claim 10, characterized in that the mixture as defined in any one of claims 1 to 5 is applied in an amount of 0.01 g to 10 kg per 100 kg of plant propagation material. METHOD according to any one of claims 10 to 11, characterized in that the mixture as defined in any one of claims 1 to 5 is applied simultaneously, jointly or separately, or successively.