BR112017007390A2 - integrated process and system for continuous production of liquid hydrogen. - Google Patents

integrated process and system for continuous production of liquid hydrogen.

Info

Publication number
BR112017007390A2
BR112017007390A2 BR112017007390A BR112017007390A BR112017007390A2 BR 112017007390 A2 BR112017007390 A2 BR 112017007390A2 BR 112017007390 A BR112017007390 A BR 112017007390A BR 112017007390 A BR112017007390 A BR 112017007390A BR 112017007390 A2 BR112017007390 A2 BR 112017007390A2
Authority
BR
Brazil
Prior art keywords
hydrogen
hydrogen gas
metal
continuous production
energy
Prior art date
Application number
BR112017007390A
Other languages
Portuguese (pt)
Inventor
Gupta Nikunj
Alexander Pasfield Thomas
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of BR112017007390A2 publication Critical patent/BR112017007390A2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/22—Inorganic acids
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C25B15/08—Supplying or removing reactants or electrolytes; Regeneration of electrolytes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B5/00—Electrogenerative processes, i.e. processes for producing compounds in which electricity is generated simultaneously
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0005—Light or noble gases
    • F25J1/001—Hydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228—Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
    • F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
    • F25J1/0284—Electrical motor as the prime mechanical driver
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2260/00—Coupling of processes or apparatus to other units; Integrated schemes
    • F25J2260/30—Integration in an installation using renewable energy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Abstract

trata-se de um processo integrado para produção contínua de hidrogênio líquido, que compreende (a) produzir hidrogênio gasoso através de eletrólise; e (b) liquefazer o dito hidrogênio gasoso em uma unidade de liquefação de hidrogênio, em que a unidade de liquefação é potencializada essencialmente através de energia de fontes renováveis, e (c) quando potência adicional é necessária, usar energia elétrica gerada em um processo em que a energia elétrica e hidrogênio são cogerados através de um processo de eletrólise integrado que compreende: (d) eletrolisar um sal metálico ou uma mistura de sais metálicos e água no metal ou dos metais correspondentes, ácido ou ácidos, e oxigênio (fase de armazenamento de energia) e (e) produzir hidrogênio gasoso e recuperar eletricidade em uma reação de regeneração do metal (ou metais), e do ácido (ou ácidos) da etapa (d) (fase de regeneração); em que pelo menos parte do hidrogênio gasoso gerado na etapa (e) é usado na etapa (b) do processo.It is an integrated process for the continuous production of liquid hydrogen, which comprises (a) producing hydrogen gas through electrolysis; and (b) liquefy said hydrogen gas in a hydrogen liquefaction unit, wherein the liquefaction unit is essentially powered by energy from renewable sources, and (c) when additional power is required, use electrical energy generated in a process. wherein electric energy and hydrogen are cogenerated through an integrated electrolysis process comprising: (d) electrolyzing a metal salt or mixture of metal salts and water into the metal or corresponding metals, acid or acids, and oxygen (phase of energy storage) and (e) produce hydrogen gas and recover electricity in a regeneration reaction of the metal (or metals) and acid (or acids) of step (d) (regeneration phase); wherein at least part of the hydrogen gas generated in step (e) is used in step (b) of the process.

BR112017007390A 2014-10-28 2015-10-26 integrated process and system for continuous production of liquid hydrogen. BR112017007390A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14190677 2014-10-28
PCT/EP2015/074712 WO2016066571A1 (en) 2014-10-28 2015-10-26 Process for producing liquid hydrogen

Publications (1)

Publication Number Publication Date
BR112017007390A2 true BR112017007390A2 (en) 2018-02-14

Family

ID=51795564

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017007390A BR112017007390A2 (en) 2014-10-28 2015-10-26 integrated process and system for continuous production of liquid hydrogen.

Country Status (7)

Country Link
US (1) US20170321332A1 (en)
CN (1) CN107074538A (en)
AU (1) AU2015340752B2 (en)
BR (1) BR112017007390A2 (en)
CL (1) CL2017000975A1 (en)
ES (1) ES2643558B1 (en)
WO (1) WO2016066571A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SI25573A (en) * 2017-12-13 2019-06-28 Univerza V Novi Gorici Procedure for storing electrical energy in solid matter
WO2019190305A1 (en) * 2018-03-27 2019-10-03 Harit Ecotech Sdn. Bhd. A hydroxygen generator for reducing carbon emission and increasing fuel efficieny
FR3098576B1 (en) 2019-07-08 2022-04-29 Air Liquide Process and installation for the production of liquid hydrogen
EP4067533A1 (en) * 2021-03-30 2022-10-05 Linde GmbH Method and system for the production of liquid hydrogen by means of electrolysis

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3036805A1 (en) * 1980-09-30 1982-05-06 Karlheinz 7321 Zell Hanzlik Electrolytic hydrogen generated from sunlight via solar cells - is liquefied and then used as motor vehicle fuel
US4910963A (en) * 1988-11-21 1990-03-27 Vanzo Gordon F Solar energy process
CN1352323A (en) * 2000-11-03 2002-06-05 穆瑞力 Method and apparatus for producing hydrogen by utilizing solar energy and/or wind energy
CN1854063A (en) * 2005-04-28 2006-11-01 黄潮 Electrochemical zinc-water hydrogen making and storing method
US20080127646A1 (en) * 2005-10-11 2008-06-05 Doland George J System and Method for Energy and Hydrogen Production
EP2132820A4 (en) * 2007-04-03 2014-12-24 New Sky Energy Inc Electrochemical system, apparatus, and method to generate renewable hydrogen and sequester carbon dioxide
CN101492825A (en) * 2009-01-05 2009-07-29 陈有孝 Process for producing hydrogen gas by using solar energy
FR2948654B1 (en) * 2009-07-30 2015-01-16 Gerkaro COGENERATION OF ELECTRIC ENERGY AND HYDROGEN
CN101892491A (en) * 2010-07-28 2010-11-24 张建洲 Comprehensive application system for generating electricity by natural energy and electrolyzing seawater or brackish water
CN102453922A (en) * 2010-11-03 2012-05-16 尹华文 Solar hydrogen production system engineering
AU2012261208A1 (en) * 2011-04-11 2013-10-24 Antecy B.V. Self-contained solar-powered energy supply and storage system
ES2553082T3 (en) * 2011-08-29 2015-12-04 Karl-Hermann Busse Power supply system, in particular for the building technology sector
AU2014100315A4 (en) * 2014-04-01 2014-05-01 Cooper, Bretton MR Liquid air facilitating renewable hydrogen exports

Also Published As

Publication number Publication date
AU2015340752A1 (en) 2017-04-20
ES2643558R1 (en) 2017-12-13
CL2017000975A1 (en) 2018-01-12
AU2015340752B2 (en) 2018-02-01
US20170321332A1 (en) 2017-11-09
ES2643558A2 (en) 2017-11-23
WO2016066571A1 (en) 2016-05-06
CN107074538A (en) 2017-08-18
ES2643558B1 (en) 2018-09-19

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B11D Dismissal acc. art. 38, par 2 of ipl - failure to pay fee after grant in time