BR112017005495B1 - DETERGENT COMPOSITION FOR WASHING CLOTHES AND DOMESTIC FABRIC TREATMENT METHOD - Google Patents
DETERGENT COMPOSITION FOR WASHING CLOTHES AND DOMESTIC FABRIC TREATMENT METHOD Download PDFInfo
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- BR112017005495B1 BR112017005495B1 BR112017005495-7A BR112017005495A BR112017005495B1 BR 112017005495 B1 BR112017005495 B1 BR 112017005495B1 BR 112017005495 A BR112017005495 A BR 112017005495A BR 112017005495 B1 BR112017005495 B1 BR 112017005495B1
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- Prior art keywords
- detergent composition
- weight
- laundry detergent
- negatively charged
- composition according
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- VDBNYAPERZTOOF-UHFFFAOYSA-N isoquinolin-1(2H)-one Chemical compound C1=CC=C2C(=O)NC=CC2=C1 VDBNYAPERZTOOF-UHFFFAOYSA-N 0.000 description 1
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 1
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- 239000000787 lecithin Substances 0.000 description 1
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- 238000000034 method Methods 0.000 description 1
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- GVOWHGSUZUUUDR-UHFFFAOYSA-N methyl 2-methylaminobenzoate Chemical compound CNC1=CC=CC=C1C(=O)OC GVOWHGSUZUUUDR-UHFFFAOYSA-N 0.000 description 1
- 229940102398 methyl anthranilate Drugs 0.000 description 1
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- 235000006679 mint Nutrition 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- VKCYHJWLYTUGCC-UHFFFAOYSA-N nonan-2-one Chemical compound CCCCCCCC(C)=O VKCYHJWLYTUGCC-UHFFFAOYSA-N 0.000 description 1
- IYTXKIXETAELAV-UHFFFAOYSA-N nonan-3-one Chemical compound CCCCCCC(=O)CC IYTXKIXETAELAV-UHFFFAOYSA-N 0.000 description 1
- 239000001702 nutmeg Substances 0.000 description 1
- KBPLFHHGFOOTCA-UHFFFAOYSA-N octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical Effects 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229930007459 p-menth-8-en-3-one Natural products 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000020030 perry Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- MDHYEMXUFSJLGV-UHFFFAOYSA-N phenethyl acetate Chemical compound CC(=O)OCCC1=CC=CC=C1 MDHYEMXUFSJLGV-UHFFFAOYSA-N 0.000 description 1
- 229940100595 phenylacetaldehyde Drugs 0.000 description 1
- 150000008103 phosphatidic acids Chemical class 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- NJRWNWYFPOFDFN-UHFFFAOYSA-L phosphonate(2-) Chemical compound [O-][P]([O-])=O NJRWNWYFPOFDFN-UHFFFAOYSA-L 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000003211 photoinitiator Substances 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920000196 poly(lauryl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000003389 potentiating Effects 0.000 description 1
- 239000004540 pour-on Substances 0.000 description 1
- 230000001376 precipitating Effects 0.000 description 1
- 125000001844 prenyl group Chemical group [H]C([*])([H])C([H])=C(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 229910052904 quartz Inorganic materials 0.000 description 1
- 235000005227 red mallee Nutrition 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229940071207 sesquicarbonate Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000000429 sodium aluminium silicate Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- DAPMZWDGZVFZMK-UHFFFAOYSA-N sodium;2-[2-[4-[4-[2-(2-sulfophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonic acid Chemical group [Na].[Na].OS(=O)(=O)C1=CC=CC=C1C=CC1=CC=C(C=2C=CC(C=CC=3C(=CC=CC=3)S(O)(=O)=O)=CC=2)C=C1 DAPMZWDGZVFZMK-UHFFFAOYSA-N 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 108060007849 sprT Proteins 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- UHEPJGULSIKKTP-UHFFFAOYSA-N sulcatone Chemical compound CC(C)=CCCC(C)=O UHEPJGULSIKKTP-UHFFFAOYSA-N 0.000 description 1
- 238000005670 sulfation reaction Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 235000011178 triphosphate Nutrition 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229960003986 tuaminoheptane Drugs 0.000 description 1
- 235000016788 valerian Nutrition 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Abstract
A presente invenção provê uma composição branqueadora e alvejante para lavagem de roupas doméstica compreendendo um tensoativo carregado, um polialquilfenol alcoxilado carregado negativamente e uma fragrância.The present invention provides a household laundry bleach and bleach composition comprising a charged surfactant, a negatively charged alkoxylated polyalkylphenol and a fragrance.
Description
[0001] A presente invenção se refere ao uso de composições branqueadoras e alvejantes para lavagem de roupas.[0001] The present invention relates to the use of bleaching and bleaching compositions for washing clothes.
[0002] Manter e melhorar a brancura e alvejamento dos tecidos durante a lavagem de roupas doméstica são desejáveis. Um problema é a redeposição de sujeira removida de uma peça de roupa para outra. O problema é exacerbado pela presença de óleos humanos (sebo) nas peças de roupa e na lavagem que serve para potencializar a deposição de sujeira na lavagem. Este processo leva a uma perda geral de brancura e limpeza através da carga de lavagem. Para melhorar este problema, o polímero dispersante, como um polietileno iminas alcoxiladas, tem sido amplamente adicionado aos detergentes para lavagem. PEI etoxilado (PEI = polietileno imina) é conhecido como um polímero antirredeposição da CA 121 0009. Determinadas enzimas de celulase também têm sido utilizadas para evitar a redeposição por meio da alteração das propriedades de superfície dos tecidos de algodão. A Novozymes descreve nos documentos WO02/099091 e WO04/053039 as celulases para uso na lavagem de roupas doméstica.[0002] Maintaining and improving the whiteness and whiteness of fabrics during household laundry is desirable. One problem is the redeposition of dirt removed from one garment to another. The problem is exacerbated by the presence of human oils (tallow) in garments and in the wash which serves to enhance the deposition of dirt in the wash. This process leads to an overall loss of whiteness and cleanliness across the wash load. To ameliorate this problem, dispersing polymer, such as an alkoxylated polyethylene imines, has been widely added to laundry detergents. Ethoxylated PEI (PEI = polyethylene imine) is known as an anti-redeposition polymer from CA 121 0009. Certain cellulase enzymes have also been used to prevent redeposition by altering the surface properties of cotton fabrics. Novozymes describes in WO02/099091 and WO04/053039 cellulases for use in washing household laundry.
[0003] O documento EP1321510 (Shipley) descreve uma composição de limpeza industrial que contém um poliarilfenol alcoxilado para remover resíduos químicos orgânicos de fotorresistência que são usados na manufatura de semicondutores e demais dispositivos eletrônicos e circuitos. Os resíduos químicos orgânicos são materiais remanescentes do processo de produção e incluem fotoiniciadores, termoiniciadores, monômeros acrílicos e metacrílicos.[0003] EP1321510 (Shipley) describes an industrial cleaning composition that contains an alkoxylated polyarylphenol to remove photoresist organic chemical residues that are used in the manufacture of semiconductors and other electronic devices and circuits. Organic chemical residues are materials left over from the production process and include photoinitiators, thermoinitiators, acrylic and methacrylic monomers.
[0004] Há a necessidade de tecnologias adicionais para reduzir a redeposição e potencializar a limpeza em produtos de lavagem de roupa doméstica.[0004] There is a need for additional technologies to reduce redeposition and enhance cleaning in household laundry products.
[0005] Descobrimos que os polialquilfenóis alcoxilados carregados negativamente potencializam a brancura e o alvejamento de roupas durante a lavagem doméstica.[0005] We have found that negatively charged alkoxylated polyalkylphenols potentiate the whiteness and bleaching of garments during household washing.
[0006] Em um aspecto, a presente invenção provê uma composição de detergente para lavagem de roupas que compreende:(i) tensoativo carregado, preferivelmente o nível de tensoativo carregado varia de 4 a 50% em peso, mais preferivelmente de 6 a 30% em peso, mais preferivelmente de 8 a 20% em peso;(ii) polialquilfenol alcoxilado carregado negativamente, preferivelmente em um nível de 0,1 a 20% em peso, mais preferivelmente de 0,5 a 10% em peso, mais preferivelmente de 2 a 9% em peso; e(iii) fragrância, preferivelmente de 0,05 a 0,5% em peso de fragrância.[0006] In one aspect, the present invention provides a laundry detergent composition comprising: (i) loaded surfactant, preferably the level of loaded surfactant ranges from 4 to 50% by weight, more preferably from 6 to 30% by weight, more preferably from 8 to 20% by weight; (ii) negatively charged alkoxylated polyalkylphenol, preferably at a level of 0.1 to 20% by weight, more preferably from 0.5 to 10% by weight, most preferably of 2 to 9% by weight; and (iii) fragrance, preferably from 0.05 to 0.5% by weight of fragrance.
[0007] Em outro aspecto, a presente invenção provê uma composição de detergente para lavagem de roupas que compreende:(i) de 4 a 50% em peso, preferivelmente de 6 a 30% em peso, mais preferivelmente de 8 a 20% em peso de tensoativo aniônico selecionado dentre: sulfonatos de alquilbenzeno linear; sulfatos de alquila; sulfatos de éter alquílico; e misturas destes;(ii) de 0,5 a 10% em peso, preferivelmente de 2 a 9% em peso de polialquilfenol alcoxilado carregado negativamente, tendo a estrutura a seguir: [0007] In another aspect, the present invention provides a laundry detergent composition comprising: (i) from 4 to 50% by weight, preferably from 6 to 30% by weight, more preferably from 8 to 20% by weight weight of anionic surfactant selected from: linear alkylbenzene sulfonates; alkyl sulfates; alkyl ether sulfates; and mixtures thereof; (ii) from 0.5 to 10% by weight, preferably from 2 to 9% by weight of negatively charged alkoxylated polyalkylphenol having the following structure:
[0008] em que R é selecionado dentre SO3; COO- e PO32-, preferivelmente selecionado dentre: SO3-; e COO-;[0008] where R is selected from SO3; COO- and PO32-, preferably selected from: SO3-; and COO-;
[0009] em que n é selecionado dentre: 6; 7; 8; 9; 10; 11; 12; 13; 14; 15; 16; 17; 18; 19; 20; 21; 22; 23; 24; 25; 26; 27; 28; 29; 30; 31; 32; 33; 34; 35; 36; 37; 38; 39; 40; 41; 42; 43; 44; 45; 46; 47; 48; 49; e 50; e,(iii) fragrância, preferivelmente de 0,05 a 0,5% em peso de fragrância.[0009] where n is selected from: 6; 7; 8; 9; 10; 11; 12; 13; 14; 15; 16; 17; 18; 19; 20; 21; 22; 23; 24; 25; 26; 27; 28; 29; 30; 31; 32; 33; 34; 35; 36; 37; 38; 39; 40; 41; 42; 43; 44; 45; 46; 47; 48; 49; and 50; and, (iii) fragrance, preferably from 0.05 to 0.5% by weight of fragrance.
[0010] Em um aspecto adicional, a presente invenção provê um método doméstico de tratamento de um tecido, o método compreendendo as etapas de:(i) tratamento de um tecido com uma solução aquosa dos polialquilfenóis alcoxilados carregados negativamente, a solução aquosa compreendendo de 10 ppm a 5000 ppm do polialquilfenol alcoxilado carregado negativamente; e de 0,0 g/L a 6 g/L, preferivelmente de 0,2 a 4 g/L, de um ou mais tensoativos; e,(ii) enxágue e secagem opcionais do tecido.[0010] In a further aspect, the present invention provides a domestic method of treating a fabric, the method comprising the steps of: (i) treating a fabric with an aqueous solution of the negatively charged alkoxylated polyalkylphenols, the aqueous solution comprising of 10 ppm to 5000 ppm of the negatively charged alkoxylated polyalkylphenol; and from 0.0 g/L to 6 g/L, preferably from 0.2 to 4 g/L, of one or more surfactants; and, (ii) optional rinsing and drying of the fabric.
[0011] No método, o nível da fragrância na solução aquosa é preferivelmente de 0,1 a 100 ppm, mais preferivelmente de 1 a 10 ppm.[0011] In the method, the level of fragrance in the aqueous solution is preferably from 0.1 to 100 ppm, more preferably from 1 to 10 ppm.
[0012] Nos aspectos do método da presente invenção, o tensoativo usado é preferivelmente conforme preferido para os aspectos da composição da presente invenção.[0012] In the method aspects of the present invention, the surfactant used is preferably as preferred for the compositional aspects of the present invention.
[0013] O tecido é preferivelmente um item de vestuário, roupa de cama ou toalha de mesa. Os itens preferidos de vestuário são camisas, calças, roupa íntima e camisolas que contêm algodão.[0013] The fabric is preferably an item of clothing, bedding or tablecloth. Favorite clothing items are shirts, pants, underwear and sweaters that contain cotton.
[0014] Preferivelmente, o polialquilfenol alcoxilado carregado negativamente é trialquilfenol alcoxilado carregado negativamente, mais preferivelmente tri(n-butil)fenol alcoxilado.[0014] Preferably, the negatively charged alkoxylated polyalkylphenol is negatively charged alkoxylated trialkylphenol, more preferably alkoxylated tri(n-butyl)phenol.
[0015] Preferivelmente, o trialquilfenol alcoxilado carregado negativamente é um polietilenoglicol mono(2,4,6-tris(n-butil)fenil) éter carregado negativamente.[0015] Preferably, the negatively charged alkoxylated trialkylphenol is a negatively charged polyethylene glycol mono(2,4,6-tris(n-butyl)phenyl) ether.
[0016] Preferivelmente, o polialquilfenol alcoxilado carregado negativamente contém uma média de 2 a 70 grupos alcóxi, mais preferivelmente de 6 a 50 grupos alcóxi.[0016] Preferably, the negatively charged alkoxylated polyalkylphenol contains an average of from 2 to 70 alkoxy groups, more preferably from 6 to 50 alkoxy groups.
[0017] Preferivelmente, a alcoxilação é etoxilação.[0017] Preferably, the alkoxylation is ethoxylation.
[0018] O grupo alquila no polialquilfenol alcoxilado é preferivelmente selecionado dentre grupos alquila C3 a C15 lineares ou ramificados.[0018] The alkyl group in the alkoxylated polyalkylphenol is preferably selected from linear or branched C3 to C15 alkyl groups.
[0019] Preferivelmente, o polialquilfenol alcoxilado carregado negativamente possui 3 grupos alquila ligados ao fenol. Preferivelmente, eles estão na posição 2,4,6 no fenol. O alcoxilato está ligado à posição 1.[0019] Preferably, the negatively charged alkoxylated polyalkylphenol has 3 alkyl groups attached to the phenol. Preferably, they are at position 2,4,6 on the phenol. The alkoxylate is attached to the 1-position.
[0020] Preferivelmente, o alcoxilado é protegido por um grupo carregado negativamente selecionado dentre SO3- COO-, e PO32-, preferivelmente selecionado dentre SO3- e COO-.[0020] Preferably, the alkoxylate is protected by a negatively charged group selected from SO3-COO-, and PO32-, preferably selected from SO3- and COO-.
[0021] O grupo alquila no polialquilfenol alcoxilado é preferivelmente selecionado dentre grupos alquila C3 a C15 lineares ou ramificados.[0021] The alkyl group in the alkoxylated polyalkylphenol is preferably selected from linear or branched C3 to C15 alkyl groups.
[0022] Mais preferivelmente, o polietilenoglicol mono(2,4,6-tris(n-butil)fenil) alcoxilado é um polialquilfenol alcoxilado carregado negativamente da seguinte estrutura: [0022] More preferably, the mono(2,4,6-tris(n-butyl)phenyl)alkoxylated polyethylene glycol is a negatively charged alkoxylated polyalkylphenol of the following structure:
[0023] em que R é selecionado dentre SO3; COO- e PO32-, selecionado preferivelmente dentre SO3- e COO-, mais preferivelmente SO3-.[0023] where R is selected from SO3; COO- and PO32-, preferably selected from SO3- and COO-, more preferably SO3-.
[0024] Preferivelmente, n = 2 a 70, mais preferivelmente n= 6 a 50, ainda mais preferivelmente de 6 a 18.[0024] Preferably n=2 to 70, more preferably n=6 to 50, even more preferably 6 to 18.
[0025] A designação n representa os números médios de mols de unidades alcóxi na cadeia polialcóxi.[0025] The designation n represents the average number of moles of alkoxy units in the polyalkoxy chain.
[0026] Os compostos estão disponíveis a partir dos fornecedores industriais, por exemplo, Rhodia, Clariant, Aoki Oil; Stepan; TOHO Chemical Industry Co.[0026] The compounds are available from industrial suppliers, eg Rhodia, Clariant, Aoki Oil; Stepan; TOHO Chemical Industry Co.
[0027] No contexto da presente invenção, o polialquilfenol alcoxilado carregado negativamente não é considerado um tensoativo e não contribui numericamente para o tensoativo conforme aqui definido.[0027] In the context of the present invention, the negatively charged alkoxylated polyalkylphenol is not considered a surfactant and does not numerically contribute to the surfactant as defined herein.
[0028] A composição para lavagem de roupas compreende tensoativo carregado, e o tensoativo carregado mais preferido é tensoativo aniônico (que inclui uma mistura deste).[0028] The laundry composition comprises loaded surfactant, and the most preferred loaded surfactant is anionic surfactant (which includes a mixture thereof).
[0029] Os compostos detergentes aniônicos adequados que podem ser usados são geralmente sais de metal alcalino solúveis em água de sulfatos orgânicos e sulfonatos que possuem radicais alquila contendo de aproximadamente 8 a aproximadamente 22 átomos de carbono, sendo o termo alquila utilizado para incluir a porção alquila de maiores radicais alquila.[0029] Suitable anionic detergent compounds that can be used are generally water-soluble alkali metal salts of organic sulfates and sulfonates that have alkyl radicals containing from approximately 8 to approximately 22 carbon atoms, the term alkyl being used to include the moiety alkyl of higher alkyl radicals.
[0030] Os exemplos de compostos detergentes aniônicos sintéticos adequados são alquilssulfatos de sódio e potássio, especialmente aqueles obtidos por sulfatação de alcoóis superiores C8 a C18, produzidos, por exemplo, a partir de sebo ou óleo de coco, sulfonatos de alquilbenzeno de sódio e potássio C9 a C20, particularmente sulfonatos de alquilbenzeno de sódio linear secundário C10 a C15; e alquilgliceriléter sulfato de sódio, especialmente aqueles éteres dos alcoóis superiores derivados do sebo e do óleo de coco e alcoóis sintéticos derivados do petróleo.[0030] Examples of suitable synthetic anionic detergent compounds are sodium and potassium alkyl sulfates, especially those obtained by sulfation of C8 to C18 higher alcohols, produced, for example, from tallow or coconut oil, sodium alkylbenzene sulfonates and C9 to C20 potassium, particularly C10 to C15 linear secondary sodium alkylbenzene sulfonates; and sodium alkyl glyceryl ether sulfate, especially those ethers of higher alcohols derived from tallow and coconut oil and synthetic alcohols derived from petroleum.
[0031] O tensoativo aniônico é selecionado preferivelmente dentre: sulfonato de alquilbenzeno linear; sulfatos de alquila; sulfatos de éter alquílico; sabões; sulfonatos de alquil (preferivelmente metil) éster, e misturas destes.[0031] The anionic surfactant is preferably selected from: linear alkylbenzene sulfonate; alkyl sulfates; alkyl ether sulfates; soaps; alkyl (preferably methyl) ester sulfonates, and mixtures thereof.
[0032] Os tensoativos aniônicos mais preferidos são selecionados dentre: sulfonato de alquilbenzeno linear; sulfatos de alquila; sulfatos de éter alquílico e misturas destes. Preferivelmente, o sulfato de éter alquílico é um n-sulfato de éter alquílico C12-C14 com uma média de 1 a 3 unidades de EO (etoxilato). O lauril éter sulfato de sódio (SLES) é particularmente preferido. Preferivelmente, o sulfonato de alquilbenzeno linear é um sulfonato de alquilbenzeno de sódio C11 a C15. Preferivelmente, os sulfatos de alquila são um alquilssulfato de sódio C12 a C18 linear ou ramificado. Dodecil sulfato de sódio é particularmente preferido (SDS, também conhecido como sulfato de alquila primário).[0032] The most preferred anionic surfactants are selected from: linear alkylbenzene sulfonate; alkyl sulfates; alkyl ether sulfates and mixtures thereof. Preferably, the alkyl ether sulfate is a C12-C14 alkyl ether n-sulfate with an average of 1 to 3 EO (ethoxylate) units. Sodium lauryl ether sulfate (SLES) is particularly preferred. Preferably, the linear alkylbenzene sulfonate is a C11 to C15 sodium alkylbenzene sulfonate. Preferably, the alkyl sulfates are a linear or branched C12 to C18 sodium alkyl sulfate. Sodium dodecyl sulfate is particularly preferred (SDS, also known as primary alkyl sulfate).
[0033] O nível de tensoativo aniônico na composição para lavagem de roupas varia preferivelmente de 4 a 50% em peso, mais preferivelmente de 6 a 30% em peso, e mais preferivelmente de 8 a 20% em peso.[0033] The level of anionic surfactant in the laundry composition preferably ranges from 4 to 50% by weight, more preferably from 6 to 30% by weight, and most preferably from 8 to 20% by weight.
[0034] Preferivelmente, dois ou mais tensoativos aniônicos estão presentes, por exemplo, sulfonato de alquilbenzeno linear junto a um sulfato de éter alquílico.[0034] Preferably, two or more anionic surfactants are present, for example linear alkylbenzene sulfonate together with an alkyl ether sulfate.
[0035] Preferivelmente, a composição para lavagem de roupas em adição ao tensoativo aniônico compreende tensoativo não iônico alquila etoxilada, preferivelmente de 2 a 8% em peso de alquila alcoxilada, preferivelmente tensoativo não iônico etoxilado.[0035] Preferably, the laundry composition in addition to the anionic surfactant comprises alkyl ethoxylated nonionic surfactant, preferably from 2 to 8% by weight alkoxylated alkyl, preferably ethoxylated nonionic surfactant.
[0036] Os compostos detergentes não iônicos adequados que podem ser utilizados incluem, em particular, os produtos de reação dos compostos que possuem um grupo hidrofóbico alifático e um átomo de hidrogênio reativo, por exemplo, alcoóis, ácidos ou amidas alifáticos, especialmente óxido de etileno, tanto isoladamente quanto com óxido de propileno. Os compostos detergentes não iônicos específicos são os produtos de condensação de alcoóis alifáticos C8 a C18 primários ou secundários lineares ou ramificados com óxido de etileno.[0036] Suitable nonionic detergent compounds that may be used include, in particular, the reaction products of compounds having an aliphatic hydrophobic group and a reactive hydrogen atom, for example, aliphatic alcohols, acids or amides, especially ethylene, either alone or with propylene oxide. Specific nonionic detergent compounds are the condensation products of linear or branched primary or secondary C8 to C18 aliphatic alcohols with ethylene oxide.
[0037] Preferivelmente, o tensoativo não iônico etoxilado de alquila é um álcool primário C8 a C18 com uma etoxilação média de 7 EO a 9 EO unidades.[0037] Preferably, the alkyl ethoxylated nonionic surfactant is a C8 to C18 primary alcohol with an average ethoxylation of 7 EO to 9 EO units.
[0038] Os tensoativos não iônicos e aniônicos do sistema tensoativo podem ser escolhidos a partir dos tensoativos descritos em “Surface Active Agents” Vol. 1, por Schwartz & Perry, Interscience 1949, Vol. 2 por Schwartz, Perry & Berch, Interscience 1958, na edição atual de “McCutcheon's Emulsifiers and Detergents” publicada pela Manufacturing Confectioners Company ou em “Tenside-Taschenbuch”, H. Stache, 2a Ed., Carl Hauser Verlag, 1981.[0038] The non-ionic and anionic surfactants of the surfactant system can be chosen from the surfactants described in “Surface Active Agents” Vol. 1, by Schwartz & Perry, Interscience 1949, Vol. 2 by Schwartz, Perry & Berch, Interscience 1958 , in the current edition of “McCutcheon's Emulsifiers and Detergents” published by the Manufacturing Confectioners Company or in “Tenside-Taschenbuch”, H. Stache, 2nd Ed., Carl Hauser Verlag, 1981.
[0039] Preferivelmente, os tensoativos utilizados são saturados.[0039] Preferably, the surfactants used are saturated.
[0040] Também aplicáveis são os tensoativos como aqueles descritos em EP-A-328 177 (Unilever), que demonstram resistência à dessalinização, os tensoativos alquil poliglicosídeos descritos em EP-A-070 074 e alquil monoglicosídeos.[0040] Also applicable are surfactants such as those described in EP-A-328 177 (Unilever), which demonstrate resistance to desalination, the alkyl polyglycoside surfactants described in EP-A-070 074 and alkyl monoglycosides.
[0041] Em outro aspecto, o tensoativo carregado pode ser um catiônico, de modo que a formulação seja um amaciante para roupas. As composições de detergente baseadas em tensoativos aniônicos ou aniônicos/não iônicos são, no entanto, a realização mais preferida.[0041] In another aspect, the charged surfactant may be a cationic so that the formulation is a fabric softener. Detergent compositions based on anionic or anionic/nonionic surfactants are, however, the most preferred embodiment.
[0042] Quando a presente invenção é utilizada como um amaciante para roupas, ela precisa conter um composto catiônico.[0042] When the present invention is used as a fabric softener, it must contain a cationic compound.
[0043] Os mais preferidos são os compostos de amônio quaternário.[0043] The most preferred are quaternary ammonium compounds.
[0044] É vantajoso se o composto de amônio quaternário for um composto de amônio quaternário que possui pelo menos uma cadeia alquila C12 a C22.[0044] It is advantageous if the quaternary ammonium compound is a quaternary ammonium compound having at least one C12 to C22 alkyl chain.
[0045] É preferido se o composto de amônio quaternário possuir a fórmula a seguir: [0045] It is preferred if the quaternary ammonium compound has the following formula:
[0046] em que R1 é uma cadeia alquila ou alcenila C12 a C22; R2, R3 e R4 são selecionados de forma independente a partir de cadeias alquilas C1 a C4, e X- é um ânion compatível. Um composto preferido deste tipo é o composto de amônio quaternário brometo de cetiltrimetilamônio quaternário.[0046] wherein R1 is a C12 to C22 alkyl or alkenyl chain; R2, R3 and R4 are independently selected from C1 to C4 alkyl chains, and X- is a compatible anion. A preferred compound of this type is the quaternary ammonium compound cetyltrimethylammonium quaternary ammonium bromide.
[0047] Uma segunda classe de materiais para uso com a presente invenção é o amônio quaternário da estrutura acima, em que R1 e R2 são selecionados de forma independente a partir da cadeia alquila ou alcenila C12 a C22; R3 e R4 são selecionados de forma independente a partir das cadeias alquila C1 a C4, e X- é um ânion compatível.[0047] A second class of materials for use with the present invention is the quaternary ammonium of the above structure, wherein R1 and R2 are independently selected from the C12 to C22 alkyl or alkenyl chain; R3 and R4 are independently selected from the C1 to C4 alkyl chains, and X- is a compatible anion.
[0048] A composição compreende opcionalmente um silicone.[0048] The composition optionally comprises a silicone.
[0049] Os materiais de builder podem ser selecionados dentre 1) materiais sequestrantes de cálcio, 2) materiais precipitantes, 3) materiais de troca iônica de cálcio e 4) misturas destes.[0049] The builder materials can be selected from 1) calcium sequestering materials, 2) precipitating materials, 3) calcium ion exchange materials and 4) mixtures thereof.
[0050] Os exemplos de materiais de builder sequestrantes de cálcio incluem polifosfatos de metais alcalinos, como tripolifosfato de sódio e sequestrantes orgânicos, como ácido etilenodiamino tetra-acético.[0050] Examples of calcium sequestering builder materials include alkali metal polyphosphates such as sodium tripolyphosphate and organic sequestering materials such as ethylenediamine tetraacetic acid.
[0051] Os exemplos de materiais de builder precipitantes incluem ortofosfato de sódio e carbonato de sódio.[0051] Examples of precipitant builder materials include sodium orthophosphate and sodium carbonate.
[0052] Os exemplos de materiais de builder de troca iônica de cálcio incluem os diversos tipos de aluminossilicatos cristalinos ou amorfos insolúveis em água, cujos zeólitos são os representantes bem conhecidos, por exemplo, zeólito A, zeólito B (também conhecido como zeólito P), zeólito C, zeólito X, zeólito Y e também o zeólito tipo P, conforme descrito em EP-A-0.384.070.[0052] Examples of calcium ion exchange builder materials include the various types of water-insoluble crystalline or amorphous aluminosilicates, whose zeolites are the well-known representatives, e.g. zeolite A, zeolite B (also known as zeolite P) , zeolite C, zeolite X, zeolite Y and also zeolite type P, as described in EP-A-0,384,070.
[0053] A composição também pode conter 0 a 65% de um builder ou agente complexante, como ácido etilenodiamino tetra-acético, ácido dietilenotriamino penta-acético, ácido alquílico ou alcenilssuccínico, ácido nitrilotriacético ou outros builders mencionados abaixo. Muitos builders também são agentes estabilizantes de branqueamento em virtude de sua capacidade de complexar íons de metal.[0053] The composition may also contain 0 to 65% of a builder or complexing agent, such as ethylenediamine tetraacetic acid, diethylenetriamine pentaacetic acid, alkyl or alkenyl succinic acid, nitrilotriacetic acid or other builders mentioned below. Many builders are also bleach stabilizing agents by virtue of their ability to complex metal ions.
[0054] O zeólito e o carbonato (carbonato (inclusive bicarbonato e sesquicarbonato)) são builders preferidos, sendo os carbonatos particularmente preferidos.[0054] Zeolite and carbonate (carbonate (including bicarbonate and sesquicarbonate)) are preferred builders, with carbonates being particularly preferred.
[0055] A composição pode conter como builder um aluminossilicato cristalino, preferivelmente um aluminossilicato de metal alcalino, mais preferivelmente um aluminossilicato de sódio. Este está normalmente presente em um nível inferior a 15% em peso. Os aluminossilicatos são materiais que possuem a fórmula geral:0,8-1,5 M2O. Al2O3 0,8-6 SiO2[0055] The composition may contain as a builder a crystalline aluminosilicate, preferably an alkali metal aluminosilicate, more preferably a sodium aluminosilicate. This is normally present at a level of less than 15% by weight. Aluminosilicates are materials that have the general formula: 0.8-1.5 M2O. Al2O3 0.8-6 SiO2
[0056] em que M é um cátion monovalente, preferivelmente sódio. Estes materiais contêm alguma ligação à água e precisam possuir uma capacidade de troca iônica de cálcio de pelo menos 50 mg de CaO/g. Os aluminossilicatos de sódio preferidos contêm 1,5-3,5 SiO2 unidades na fórmula acima. Eles podem ser facilmente preparados pela reação entre o silicato de sódio e o aluminato de sódio, conforme amplamente descrito na literatura. A proporção de tensoativos para aluminossilicatos (onde presente) é preferivelmente superior a 5:2, mais preferivelmente superior a 3:1.[0056] wherein M is a monovalent cation, preferably sodium. These materials contain some water binding and must have a calcium ion exchange capacity of at least 50 mg CaO/g. Preferred sodium aluminosilicates contain 1.5-3.5 SiO2 units in the above formula. They can be easily prepared by the reaction between sodium silicate and sodium aluminate, as widely described in the literature. The ratio of surfactants to aluminosilicates (where present) is preferably greater than 5:2, more preferably greater than 3:1.
[0057] Alternativa ou adicionalmente aos builders de aluminossilicatos, os builders de fosfato podem ser utilizados. Na técnica, o termo ‘fosfato’ engloba difosfato, trifosfato e espécies de fosfonatos. Outras formas de builders incluem silicatos, como silicatos solúveis, metassilicatos, silicatos em camadas (por exemplo, SKS-6 da Hoechst).[0057] As an alternative or in addition to aluminosilicate builders, phosphate builders can be used. In the art, the term 'phosphate' encompasses diphosphate, triphosphate and phosphonate species. Other forms of builders include silicates such as soluble silicates, metasilicates, layered silicates (eg SKS-6 from Hoechst).
[0058] Preferivelmente, a formulação de detergente para lavagem de roupas é uma formulação de detergente para lavagem de roupas formada sem fosfato, ou seja, contém menos de 1% em peso de fosfato. Preferivelmente, as formulações de detergente em pó para lavagem de roupas são predominantemente formados de carbonato. Os pós devem fornecer preferivelmente um pH em uso de 9,5 a 11.[0058] Preferably, the laundry detergent formulation is a laundry detergent formulation formed without phosphate, i.e., it contains less than 1% by weight of phosphate. Preferably, the laundry detergent powder formulations are predominantly carbonate formed. Powders should preferably provide an in-use pH of 9.5 to 11.
[0059] Mais preferivelmente, o detergente para lavagem de roupas é um detergente líquido aquoso para lavagem de roupas, preferivelmente com um pH de 7 a 9.[0059] More preferably, the laundry detergent is an aqueous liquid laundry detergent, preferably having a pH of 7 to 9.
[0060] No detergente líquido aquoso para lavagem de roupas, é preferido que o monopropilenoglicol esteja presente em um nível de 1 a 30% em peso, mais preferivelmente de 2 a 18% em peso, para prover à formulação viscosidade apropriada para despejo.[0060] In the aqueous liquid laundry detergent, it is preferred that the monopropylene glycol be present at a level of from 1 to 30% by weight, more preferably from 2 to 18% by weight, to provide the formulation with appropriate pour-on viscosity.
[0061] A composição compreende preferivelmente um agente fluorescente (branqueador óptico). Os agentes fluorescentes são bem conhecidos e muitos desses agentes fluorescentes estão comercialmente disponíveis. Normalmente, estes agentes fluorescentes são fornecidos e usados na forma de seus sais de metal alcalino, por exemplo, os sais de sódio.[0061] The composition preferably comprises a fluorescent agent (optical brightener). Fluorescent agents are well known and many such fluorescent agents are commercially available. Typically, these fluorescing agents are supplied and used in the form of their alkali metal salts, for example sodium salts.
[0062] As classes preferidas de agentes fluorescentes são: compostos de diestiril bifenil, por exemplo, Tinopal (Marca Comercial) CBS-X, compostos de ácido dissulfônico diamino estilbeno, por exemplo, Tinopal DMS pure Xtra e Blankophor (Marca Comercial) HRH, e compostos de pirazolina, por exemplo, Blankophor SN.[0062] Preferred classes of fluorescing agents are: distyryl biphenyl compounds, e.g. Tinopal (Trade Mark) CBS-X, diamine stilbene disulfonic acid compounds, e.g. Tinopal DMS pure Xtra and Blankophor (Trade Mark) HRH, and pyrazoline compounds, for example, Blankophor SN.
[0063] Os agentes fluorescentes preferidos são: 2-(4-estiril-3-sulfofenil)-2H- naptol[1,2-d]triazol de sódio, 4,4'-bis{[(4-anilino-6-(N metil-N-2 hidroxietil) amino 1,3,5-triazina-2-il)]amino}estilbeno-2-2' dissulfonato dissódico, 4,4'-bis{[(4- anilino-6-morfolino-1,3,5-triazina-2-il)]amino} estilbeno-2-2' dissulfonato dissódico e 4,4'-bis(2-sulfoestiril)bifenil dissódico.[0063] Preferred fluorescent agents are: Sodium 2-(4-styryl-3-sulfophenyl)-2H-naptol[1,2-d]triazole, 4,4'-bis{[(4-anilino-6- (N-methyl-N-2 hydroxyethyl)amino 1,3,5-triazine-2-yl)]amino}stilbene-2-2' disodium disulfonate, 4,4'-bis{[(4-anilino-6-morpholino -1,3,5-triazine-2-yl)]amino}stilbene-2-2' disodium disulfonate and disodium 4,4'-bis(2-sulfostyryl)biphenyl.
[0064] A composição compreende uma fragrância. A fragrância está preferivelmente na faixa de 0,001 a 3% em peso, mais preferivelmente de 0,05 a 0,5% em peso, mais preferivelmente de 0,1 a 1% em peso. Muitos exemplos apropriados de fragrâncias são providos em CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide, publicado por CFTA Publications e OPD 1993 Chemicals Buyers Directory 80th Annual Edition, publicado pela Schnell Publishing Co.[0064] The composition comprises a fragrance. The fragrance is preferably in the range from 0.001 to 3% by weight, more preferably from 0.05 to 0.5% by weight, most preferably from 0.1 to 1% by weight. Many examples of suitable fragrances are provided in CTFA (Cosmetic, Toiletry and Fragrance Association) 1992 International Buyers Guide, published by CFTA Publications and OPD 1993 Chemicals Buyers Directory 80th Annual Edition, published by Schnell Publishing Co.
[0065] Preferivelmente, a fragrância compreende pelo menos uma nota (composto) dentre: alfa-isometilionona, salicilato de benzila; citronelol; cumarina; hexil cinamal; linalol; ácido pentanoico, 2-metil-, etil éster; octanal; acetato de benzila; 1,6-octadieno-3-ol, 3,7-dimetil-, 3-acetato; ciclohexanol, 2- (1,1-dimetiletil)-, 1-acetato; delta-damascona; beta-ionona; acetato de verdila; dodecanal; aldeído hexil cinâmico; ciclopentadecanolida; ácido benzenoacético, 2-feniletil éster; amil salicilato; beta-cariofileno; etil undecilenato; antranilato de geranila; alfa-pirona; benzoato de beta-feniletil; alfa-santalol; cedrol; acetato de cedrila; formato de cedro; salicilato de ciclohexila; gama-dodecalactona e acetato de beta feniletil fenil.[0065] Preferably, the fragrance comprises at least one note (compound) from: alpha-isomethylionone, benzyl salicylate; citronellol; coumarin; cinnamal hexyl; linalool; pentanoic acid, 2-methyl-, ethyl ester; octanal; benzyl acetate; 1,6-octadiene-3-ol, 3,7-dimethyl-, 3-acetate; cyclohexanol, 2-(1,1-dimethylethyl)-, 1-acetate; delta-damascone; beta-ionone; verdel acetate; dodecanal; cinnamic hexyl aldehyde; cyclopentadecanolide; benzeneacetic acid, 2-phenylethyl ester; amyl salicylate; beta-caryophyllene; ethyl undecylenate; geranyl anthranilate; alpha-pyrone; beta-phenylethyl benzoate; alpha-santalol; cedrol; cedryl acetate; cedar shape; cyclohexyl salicylate; gamma-dodecalactone and beta phenylethyl phenyl acetate.
[0066] Os compostos úteis da fragrância incluem materiais de origem natural e sintética. Eles incluem compostos e misturas únicos. Exemplos específicos destes componentes podem ser encontrados na literatura atual, por exemplo, em Manual de Ingredientes Aromatizantes de Fenaroli, 1975, CRC Press; Complementos Alimentares Sintéticos, 1947 por M. B. Jacobs, editado por Van Nostrand; ou Perfume and Flavor Chemicals by S. Arctander 1969, Montclair, N.J. (EUA).[0066] Useful fragrance compounds include materials of natural and synthetic origin. They include unique compounds and mixtures. Specific examples of these components can be found in the current literature, for example, in Fenaroli's Manual of Flavoring Ingredients, 1975, CRC Press; Synthetic Food Supplements, 1947 by M. B. Jacobs, edited by Van Nostrand; or Perfume and Flavor Chemicals by S. Arctander 1969, Montclair, N.J. (USA).
[0067] É corriqueiro para uma pluralidade de componentes de fragrância estar presente em uma formulação. Nas composições da presente invenção, contempla-se que haverá quatro ou mais, preferivelmente cinco ou mais, mais preferivelmente seis ou mais, ou mesmo sete ou mais diferentes componentes de fragrância.[0067] It is commonplace for a plurality of fragrance components to be present in a formulation. In the compositions of the present invention, it is contemplated that there will be four or more, preferably five or more, more preferably six or more, or even seven or more different fragrance components.
[0068] Nas misturas de fragrância, preferivelmente 15 a 25% em peso são notas de cabeça. As notas de cabeça são definidas por Poucher (Journal of the Society of Cosmetic Chemists 6(2):80 [1955]). As notas de cabeça preferidas são selecionadas dentre óleos cítricos, linalol, acetato de linalila, lavanda, dihidromircenol, óxido de rosa e cis-3-hexanol.[0068] In fragrance blends, preferably 15 to 25% by weight are top notes. Headnotes are defined by Poucher (Journal of the Society of Cosmetic Chemists 6(2):80 [1955]). Preferred top notes are selected from citrus oils, linalool, linalyl acetate, lavender, dihydromyrcenol, rose oxide and cis-3-hexanol.
[0069] A Associação Internacional de Fragrância publicou uma lista de ingredientes de fragrância (perfumes) em 2011. (http://www.ifraorg.org/en- us/ingredients#.U7Z4hPldWzk)[0069] The International Fragrance Association published a list of fragrance ingredients (perfumes) in 2011. (http://www.ifraorg.org/en-us/ingredients#.U7Z4hPldWzk)
[0070] O Instituto de Pesquisa para Materiais de Fragrância provê uma base de dados de perfumes (fragrâncias) com informações de segurança.[0070] The Research Institute for Fragrance Materials provides a perfume (fragrance) database with safety information.
[0071] A nota de cabeça da fragrância pode ser utilizada para sugerir o benefício de brancura e brilho da invenção.[0071] The top note of the fragrance can be used to suggest the whiteness and shine benefit of the invention.
[0072] Algumas ou todas as fragrâncias podem ser encapsuladas, os componentes típicos de fragrância que são vantajosos de encapsular incluem aqueles com um ponto de ebulição relativamente baixo, preferivelmente aqueles com um ponto de ebulição inferior a 300, preferivelmente 100 a 250 graus Celsius. Também é vantajoso encapsular componentes de fragrância que possuem um baixo CLog P (ou seja, aqueles que apresentarão uma tendência maior a serem divididos em água), preferivelmente com um CLog P inferior a 3,0. Estes materiais de ponto de ebulição relativamente baixo e CLog P relativamente baixo foram denominados ingredientes de fragrância de “florescência tardia” e incluem um ou mais dos materiais a seguir:[0072] Some or all fragrances can be encapsulated, typical fragrance components that are advantageous to encapsulate include those with a relatively low boiling point, preferably those with a boiling point of less than 300, preferably 100 to 250 degrees Celsius. It is also advantageous to encapsulate fragrance components that have a low CLog P (ie those that will have a greater tendency to break down in water), preferably with a CLog P of less than 3.0. These relatively low boiling point and relatively low CLog P materials have been termed “late blooming” fragrance ingredients and include one or more of the following materials:
[0073] Alil caproato, acetato de amila, propionato de amila, aldeído anísico, anisol, benzaldeído, acetato de benzila, acetona de benzila, álcool benzílico, formato de benzil, isovalerato de benzila, propionato de benzila, beta gama hexenol, goma de cânfora, levo-carvona, d-carvona, álcool cinâmico, formato de cinamila, cis-jasmona, cis-3-hexenil acetato, álcool cumínico, ciclal c, dimetil benzil carbinol, dimetil benzil carbinol acetato, acetato de etila, aceto acetato de etila, etil amil cetona, benzoato de etila, butirato de etila, etil hexil cetona, acetato de etil fenil, eucaliptol, eugenol, acetato de fenchil, flor acetato (acetato de triciclo decenil), fruteno (propionato de triciclo decenil), geraniol, hexenol, acetato de hexenil, acetato de hexil, formato de hexil, álcool hidratrópico, hidroxicitronelal, indona, álcool isoamílico, isomentona, acetato de isopulegil, isoquinolona, ligustral, linalol, óxido de linalol, formato de linalil, mentona, mentilacetofenona, metil amil cetona, antranilato de metila, benzoato de metila, acetato de metil benil, metil eugenol, metil heptenona, carbonato de metil heptino, cetona de metil heptil, cetona de metil hexil, acetato de metil fenil carbinil, salicilato de metila, metil-n-metil antranilato, nerol, octalactona, álcool octílico, p-cresol, p-cresol metil éter, p-metóxi acetofenona, p-metil acetofenona, fenóxi etanol, fenil acetaldeído, acetato de fenil etil, álcool feniletílico, fenil etil dimetil carbinol, acetato de prenila, bornato de propil, pulegona, óxido de rosa, safrol, 4-terpinenol, alfa-terpinenol e/ou viridina. É corriqueiro para uma pluralidade de componentes de fragrância estar presente em uma formulação. Nas composições da presente invenção, considera-se que haverá quatro ou mais, preferivelmente cinco ou mais, mais preferivelmente seis ou mais, ou mesmo sete ou mais diferentes componentes de fragrância a partir da lista fornecida de fragrâncias de florescência tardia fornecida acima presente na fragrância.[0073] Allyl caproate, amyl acetate, amyl propionate, anis aldehyde, anisole, benzaldehyde, benzyl acetate, benzyl acetone, benzyl alcohol, benzyl formate, benzyl isovalerate, benzyl propionate, beta gamma hexenol, gum camphor, levo-carvone, d-carvone, cinnamic alcohol, cinnamyl formate, cis-jasmone, cis-3-hexenyl acetate, cumin alcohol, cyclal c, dimethyl benzyl carbinol, dimethyl benzyl carbinol acetate, ethyl acetate, acetate acetate ethyl, ethyl amyl ketone, ethyl benzoate, ethyl butyrate, ethyl hexyl ketone, ethyl phenyl acetate, eucalyptol, eugenol, fenchyl acetate, floracetate (tricycle decenyl acetate), fructene (tricycle decenyl propionate), geraniol, hexenol, hexenyl acetate, hexyl acetate, hexyl formate, hydrotropic alcohol, hydroxycitronellal, indone, isoamyl alcohol, isomenthone, isopulegyl acetate, isoquinolone, ligustral, linalool, linalool oxide, linalyl formate, menthone, menthylacetophenone, methyl amyl ce methyl anthranilate, methyl benzoate, methyl benzyl acetate, methyl eugenol, methyl heptenone, methyl heptin carbonate, methyl heptyl ketone, methyl hexyl ketone, methyl phenyl carbinyl acetate, methyl salicylate, methyl-n- methyl anthranilate, nerol, octalactone, octyl alcohol, p-cresol, p-cresol methyl ether, p-methoxy acetophenone, p-methyl acetophenone, phenoxy ethanol, phenyl acetaldehyde, phenyl ethyl acetate, phenylethyl alcohol, phenyl ethyl dimethyl carbinol, acetate of prenyl, propyl bornate, pulegone, rose oxide, safrole, 4-terpinenol, alpha-terpinenol and/or viridine. It is commonplace for a plurality of fragrance components to be present in a formulation. In the compositions of the present invention, it is envisaged that there will be four or more, preferably five or more, more preferably six or more, or even seven or more different fragrance components from the provided list of late blooming fragrances provided above present in the fragrance. .
[0074] Outro grupo de fragrâncias ao qual a presente invenção pode ser aplicada são os assim denominados materiais de ‘aromaterapia’. Estes incluem muitos componentes também usados em perfumaria, inclusive componentes de óleos essenciais, como Salva esclareia, Eucalipto, Gerânio, Lavanda, extrato de flor de noz-moscada, Néroli, noz-moscada, Hortelã, Folha de Violeta Doce e Valeriana.[0074] Another group of fragrances to which the present invention can be applied are the so-called 'aromatherapy' materials. These include many components also used in perfumery, including essential oil components such as Clary Sage, Eucalyptus, Geranium, Lavender, Nutmeg Flower Extract, Neroli, Nutmeg, Mint, Sweet Violet Leaf and Valerian.
[0075] É preferido que a composição de tratamento para lavagem de roupas não contenha um alvejante de peroxigênio, por exemplo, percarbonato de sódio, perborato de sódio e perácido.[0075] It is preferred that the laundry treatment composition does not contain a peroxygen bleach, for example, sodium percarbonate, sodium perborate and peracid.
[0076] A composição pode compreender um ou mais dos polímeros a seguir. Os exemplos são carboximetilcelulose, poli(etilenoglicol), poli(álcool vinílico), policarboxilatos, como poliacrilatos, copolímero de ácido maleico/acrílico e copolímeros de lauril metacrilato/ácido acrílico.[0076] The composition may comprise one or more of the following polymers. Examples are carboxymethylcellulose, poly(ethylene glycol), poly(vinyl alcohol), polycarboxylates such as polyacrylates, maleic acid/acrylic acid copolymer and lauryl methacrylate/acrylic acid copolymers.
[0077] Podem estar presentes polímeros para evitar depósito de corante, por exemplo, poli(vinilpirrolidona), poli(vinilpiridina-N-óxido) e poli(vinilimidazol). Enzimas[0077] Polymers may be present to prevent dye deposition, for example poly(vinylpyrrolidone), poly(vinylpyridine-N-oxide) and poly(vinylimidazole). enzymes
[0078] Uma ou mais enzimas preferidas estão presentes em uma composição para lavagem de roupas da invenção e ao praticar um método da invenção.[0078] One or more preferred enzymes are present in a laundry composition of the invention and in practicing a method of the invention.
[0079] Preferivelmente, o nível de cada enzima na composição para lavagem de roupas da invenção varia de 0,0001% em peso a 0,1% em peso de proteína.[0079] Preferably, the level of each enzyme in the laundry composition of the invention ranges from 0.0001% by weight to 0.1% by weight of protein.
[0080] A enzima é preferivelmente selecionada dentre: proteases; lipases e celulases, mais preferivelmente uma protease.[0080] The enzyme is preferably selected from: proteases; lipases and cellulases, more preferably a protease.
[0081] As enzimas especialmente contempladas incluem proteases, alfa- amilases, celulases, lipases, peroxidases/oxidases, pectato liases e mananases, ou misturas destes.Enzymes especially contemplated include proteases, alpha-amylases, cellulases, lipases, peroxidases/oxidases, pectate lyases and mannanases, or mixtures thereof.
[0082] As lipases adequadas incluem aquelas de origem bacteriana ou fúngica. Mutantes quimicamente modificados ou de proteína modificada por engenharia genética estão incluídos. Exemplos de lipases úteis incluem lipases de Humicola (sinônimo Thermomyces), por exemplo, de H. lanuginosa (T. lanuginosus), conforme descrito nos documentos EP 258 068 e EP 305 216 ou de H. insolens conforme descrito no documento WO 96/13580, uma lipase de Pseudomonas, por exemplo, de P. alcaligenes ou de P. pseudoalcaligenes (EP 218 272), P. cepacia (EP 331 376), P. stutzeri (GB 1,372,034), P. fluorescens, linhagem da espécie Pseudomonas SD 705 (WO 95/06720 e WO 96/27002), P. wisconsinensis (WO 96/12012), uma lipase de Bacillus, por exemplo, de B. subtilis (Dartois et al. (1993), Biochemica et Biophysica Acta, 1131, 253-360), B. stearothermophilus (JP 64/744992) ou B. pumilus (WO 91/16422).[0082] Suitable lipases include those of bacterial or fungal origin. Chemically modified or genetically engineered protein mutants are included. Examples of useful lipases include lipases from Humicola (synonymous Thermomyces), for example from H. lanuginosa (T. lanuginosus) as described in EP 258 068 and EP 305 216 or from H. insolens as described in WO 96/13580 , a lipase from Pseudomonas, e.g. from P. alcaligenes or from P. pseudoalcaligenes (EP 218 272), P. cepacia (EP 331 376), P. stutzeri (GB 1,372,034), P. fluorescens, Pseudomonas SD strain 705 ( WO 95/06720 and WO 96/27002 ), P. wisconsinensis ( WO 96/12012 ), a lipase from Bacillus, e.g. from B. subtilis (Dartois et al. (1993), Biochemica et Biophysica Acta, 1131 , 253-360), B. stearothermophilus (JP 64/744992) or B. pumilus (WO 91/16422).
[0083] Outros exemplos são variantes de lipase, como aquelas descritas nos documentos WO 92/05249, WO 94/01541, EP 407 225, EP 260 105, WO 95/35381, WO 96/00292, WO 95/30744, WO 94/25578, WO 95/14783, WO 95/22615, WO 97/04079 e WO 97/07202, WO 00/60063.[0083] Other examples are lipase variants such as those described in WO 92/05249, WO 94/01541, EP 407 225, EP 260 105, WO 95/35381, WO 96/00292, WO 95/30744, WO 94 /25578, WO 95/14783, WO 95/22615, WO 97/04079 and WO 97/07202, WO 00/60063.
[0084] As enzimas de lipase preferidas comercialmente disponíveis incluem Lipolase™ e Lipolase Ultra™, Lipex™ e Lipoclean™ (Novozymes A/S).[0084] Preferred commercially available lipase enzymes include Lipolase™ and Lipolase Ultra™, Lipex™ and Lipoclean™ (Novozymes A/S).
[0085] O método da invenção pode ser realizado na presença de fosfolipase classificada como EC 3.1.1.4 e/ou EC 3.1.1.32. Conforme aqui utilizado, o termo fosfolipase é uma enzima que possui atividade em relação aos fosfolipídios.[0085] The method of the invention can be carried out in the presence of phospholipase classified as EC 3.1.1.4 and/or EC 3.1.1.32. As used herein, the term phospholipase is an enzyme that has activity towards phospholipids.
[0086] Os fosfolipídios, como lecitina ou fosfatidilcolina, consistem em glicerol esterificado com dois ácidos graxos em uma posição externa (sn-1) e intermediária (sn-2) e esterificado com ácido fosfórico na terceira posição; o ácido fosfórico, por sua vez, pode ser esterificado em um aminoálcool. Fosfolipases são enzimas que participam da hidrólise de fosfolipídios. Diversos tipos de atividade de fosfolipase podem ser distinguidos, inclusive fosfolipases A1 e A2, que hidrolisam um grupo de acila graxo (na posição sn-1 e sn-2, respectivamente) para formar lisofosfolipídeos; e lisofosfolipase (ou fosfolipase B), que pode hidrolisar o grupo acila graxo restante em lisofosfolipídeo. A fosfolipase C e fosfolipase D (fosfodiesterases) liberam diacil glicerol ou ácido fosfatídico, respectivamente.[0086] Phospholipids, such as lecithin or phosphatidylcholine, consist of glycerol esterified with two fatty acids in an outer (sn-1) and intermediate (sn-2) position and esterified with phosphoric acid in the third position; phosphoric acid, in turn, can be esterified to an amino alcohol. Phospholipases are enzymes that participate in the hydrolysis of phospholipids. Several types of phospholipase activity can be distinguished, including phospholipases A1 and A2, which hydrolyze a fatty acyl group (at the sn-1 and sn-2 position, respectively) to form lysophospholipids; and lysophospholipase (or phospholipase B), which can hydrolyze the remaining fatty acyl group into lysophospholipid. Phospholipase C and phospholipase D (phosphodiesterases) release diacyl glycerol or phosphatidic acid, respectively.
[0087] As proteases adequadas incluem aquelas de origem animal, vegetal ou microbiana. Prefere-se a origem microbiana. Mutantes quimicamente modificados ou de proteína modificada por engenharia genética estão incluídos. A protease pode ser uma serina protease ou metaloprotease, preferivelmente uma protease microbiana alcalina ou uma protease similar à tripsina. As enzimas de protease preferidas comercialmente disponíveis incluem Alcalase™, Savinase™, Primase™, Duralase™, Dyrazym™, Esperase™, Everlase™, Polarzyme™, e Kannase™ (Novozymes A/S), Maxatase™, Maxacal™, Maxapem™, Properase™, Purafect™, Purafect OxP™, FN2™ e FN3™ (Genencor International Inc.).[0087] Suitable proteases include those of animal, plant or microbial origin. Microbial origin is preferred. Chemically modified or genetically engineered protein mutants are included. The protease may be a serine protease or metalloprotease, preferably an alkaline microbial protease or a trypsin-like protease. Preferred commercially available protease enzymes include Alcalase™, Savinase™, Primase™, Duralase™, Dyrazym™, Esperase™, Everlase™, Polarzyme™, and Kannase™ (Novozymes A/S), Maxatase™, Maxacal™, Maxapem™ , Properase™, Purafect™, Purafect OxP™, FN2™ and FN3™ (Genencor International Inc.).
[0088] O método da invenção pode ser realizado na presença de cutinase classificada em EC 3.1.1.74. A cutinase usada de acordo com a invenção pode ser de qualquer origem. Preferivelmente, as cutinases são de origem microbiana, em particular de origem bacteriana, fúngica ou de levedura.[0088] The method of the invention can be carried out in the presence of cutinase classified in EC 3.1.1.74. The cutinase used according to the invention can be of any origin. Preferably, the cutinases are of microbial origin, in particular of bacterial, fungal or yeast origin.
[0089] As amilases adequadas (alfa e/ou beta) incluem aquelas de origem bacteriana ou fúngica. Mutantes quimicamente modificados ou de proteína modificada por engenharia genética estão incluídos. As amilases incluem, por exemplo, alfa-amilases obtidas a partir de Bacillus, por exemplo, uma cepa especial de B. licheniformis, descrito mais detalhadamente em GB 1.296.839, ou as cepas da espécie Bacillus reveladas em WO 95/026397 ou WO 00/060060. As amilases comercialmente disponíveis são Duramyl™, Termamyl™, Termamyl Ultra™, Natalase™, Stainzyme™, Fungamyl™ e BAN™ (Novozymes A/S), Rapidase™ e Purastar™ (da Genencor International Inc.).[0089] Suitable amylases (alpha and/or beta) include those of bacterial or fungal origin. Chemically modified or genetically engineered protein mutants are included. Amylases include, for example, alpha-amylases obtained from Bacillus, for example, a special strain of B. licheniformis, described in more detail in GB 1,296,839, or strains of the Bacillus species disclosed in WO 95/026397 or WO 00/060060. Commercially available amylases are Duramyl™, Termamyl™, Termamyl Ultra™, Natalase™, Stainzyme™, Fungamyl™ and BAN™ (Novozymes A/S), Rapidase™ and Purastar™ (from Genencor International Inc.).
[0090] As celulases adequadas incluem aquelas de origem bacteriana ou fúngica. Mutantes quimicamente modificados ou de proteína modificada por engenharia genética estão incluídos. As celulases adequadas incluem celulases dos gêneros Bacillus, Pseudomonas, Humicola, Fusarium, Thielavia, Acremonium, por exemplo, as celulases fúngicas produzidas a partir de Humicola insolens, Thielavia terrestris, Myceliophthora thermophila e Fusarium oxysporum, reveladas nos documentos US 4.435.307, US 5.648.263, US 5,691,178, US 5,776,757, WO 89/09259, WO 96/029397 e WO 98/012307. As celulases comercialmente disponíveis incluem Celluzyme™, Carezyme™, Celluclean™, Endolase™, Renozyme™ (Novozymes A/S), Clazinase™ e Puradax HA™ (Genencor International Inc.), e KAC-500(B)™ (Kao Corporation). Prefere-se Celluclean™.[0090] Suitable cellulases include those of bacterial or fungal origin. Chemically modified or genetically engineered protein mutants are included. Suitable cellulases include cellulases of the genera Bacillus, Pseudomonas, Humicola, Fusarium, Thielavia, Acremonium, for example fungal cellulases produced from Humicola insolens, Thielavia terrestris, Myceliophthora thermophila and Fusarium oxysporum, disclosed in US 4,435,307, US 5,648,263 , US 5,691,178 , US 5,776,757 , WO 89/09259 , WO 96/029397 and WO 98/012307 . Commercially available cellulases include Celluzyme™, Carezyme™, Celluclean™, Endolase™, Renozyme™ (Novozymes A/S), Clazinase™ and Puradax HA™ (Genencor International Inc.), and KAC-500(B)™ (Kao Corporation ). Celluclean™ is preferred.
[0091] As peroxidases/oxidases preferidas incluem aquelas de origem vegetal, bacteriana ou fúngica. Mutantes quimicamente modificados ou de proteína modificada por engenharia genética estão incluídos. Os exemplos de peroxidases úteis incluem peroxidases de Coprinus, por exemplo, de C. cinereus, e variantes destes conforme aqueles descritos em WO 93/24618, WO 95/10602 e WO 98/15257. As peroxidases comercialmente disponíveis incluem Guardzyme™ e Novozym™ 51004 (Novozymes A/S).[0091] Preferred peroxidases/oxidases include those of plant, bacterial or fungal origin. Chemically modified or genetically engineered protein mutants are included. Examples of useful peroxidases include peroxidases from Coprinus, for example from C. cinereus, and variants thereof as described in WO 93/24618, WO 95/10602 and WO 98/15257. Commercially available peroxidases include Guardzyme™ and Novozym™ 51004 (Novozymes A/S).
[0092] As enzimas adequadas adicionais para uso são discutidas nos documentos WO2009/087524, WO2009/090576, WO2009/107091,WO2009/111258 e WO2009/148983.[0092] Additional suitable enzymes for use are discussed in WO2009/087524 , WO2009/090576 , WO2009/107091 , WO2009/111258 and WO2009/148983 .
[0093] Qualquer enzima presente na composição pode ser estabilizada usando-se agentes estabilizantes convencionais, por exemplo, um poliol, como propilenoglicol ou glicerol, um açúcar ou álcool de açúcar, ácido láctico, ácido bórico ou um derivado de ácido bórico, por exemplo, um borato de éster aromático, ou um derivado de ácido borônico fenil, como 4-formilfenil ácido borônico, e a composição pode ser formulada conforme descrito, por exemplo, no documento WO 92/19709 e WO 92/19708.[0093] Any enzyme present in the composition can be stabilized using conventional stabilizing agents, for example a polyol such as propylene glycol or glycerol, a sugar or sugar alcohol, lactic acid, boric acid or a boric acid derivative, for example , an aromatic ester borate, or a phenyl boronic acid derivative such as 4-formylphenyl boronic acid, and the composition can be formulated as described, for example, in WO 92/19709 and WO 92/19708.
[0094] Quando os grupos alquila forem suficientemente longos para formar cadeias ramificadas ou cíclicas, estes englobarão cadeias alquila ramificadas, cíclicas e lineares. Os grupos alquila são preferivelmente lineares ou ramificados, mais preferivelmente lineares.[0094] When the alkyl groups are long enough to form branched or cyclic chains, they will encompass branched, cyclic and linear alkyl chains. Alkyl groups are preferably linear or branched, more preferably linear.
[0095] O artigo indefinido “um” ou “uma” e seu artigo definido correspondente “o(a)”, conforme aqui utilizados, significam pelo menos um, ou um ou mais, exceto se especificado de outro modo.Parte Experimental[0095] The indefinite article “a” or “an” and its corresponding definite article “the”, as used herein, mean at least one, or one or more, unless otherwise specified. Experimental Part
[0096] Preparou-se um detergente líquido aquoso para lavagem de roupas da formulação a seguir: [0096] An aqueous liquid laundry detergent of the following formulation was prepared:
[0097] A formulação foi utilizada para lavar oito peças de pano de malha de algodão de 5 x 5 cm em um tergotômetro ajustado em 200 rpm. Conduziu-se uma hora de lavagem em 800 mL de água dura 6° French a 20 °C, com 2,3 g/L da formulação. Para simular a sujeira particulada, 0,04 g/L de negro de fumo 100% comprimido (ex., Sigma-Aldrich) foi adicionado ao líquido de lavagem. Para simular a sujeira oleosa, 6,3 g de uma lâmina de sujeira SBL2004 (ex Warwick Equest) foram adicionados ao líquido de lavagem.[0097] The formulation was used to wash eight pieces of 5 x 5 cm cotton mesh cloth in a tergotometer set at 200 rpm. One hour wash was conducted in 800 ml of 6° French hard water at 20°C, with 2.3 g/l of the formulation. To simulate particulate dirt, 0.04 g/L of 100% compressed carbon black (eg, Sigma-Aldrich) was added to the wash liquid. To simulate oily dirt, 6.3 g of an SBL2004 dirt blade (ex Warwick Equest) was added to the wash liquid.
[0098] Depois que a lavagem foi concluída, os monitores de algodão foram retirados e secos, e a refletância foi medida em um refletômetro. A coloração cinza foi avaliada a partir do valor de refletância a 740 nm, R740, (exceto UV).[0098] After the washing was completed, the cotton monitors were removed and dried, and the reflectance was measured on a reflectometer. The gray color was evaluated from the reflectance value at 740 nm, R740, (except UV).
[0099] As formulações foram testadas contendo 8,7% em peso de Sokalan HP20 (BASF), um polímero de polietileno imina etoxilado PEI(600) 20 EO, um polímero de comparação para benefícios de antirredeposição.[0099] Formulations were tested containing 8.7% by weight of Sokalan HP20 (BASF), a PEI(600) 20 EO ethoxylated polyethylene imine polymer, a comparator polymer for anti-redeposition benefits.
[0100] Foi testada a formulação contendo 8,7% em peso de polialquilfenol alcoxilado carregado negativamente (Hostapal BV CONC ex Clariant que é sulfato de 2,4,6-tributilfenol éter com 7 EO).[0100] The formulation containing 8.7% by weight of negatively charged alkoxylated polyalkylphenol (Hostapal BV CONC ex Clariant which is 2,4,6-tributylphenol ether sulfate with 7 EO) was tested.
[0101] Os resultados estão resumidos na tabela abaixo. Os limites de confiança de 95% também são fornecidos calculados a partir do desvio padrão nas medições dos 8 monitores. O valor R740 é a média das medições dos 8 monitores. [0101] The results are summarized in the table below. The 95% confidence limits are also provided calculated from the standard deviation in the measurements from the 8 monitors. The R740 value is the average of the measurements from the 8 monitors.
[0102] O sal de sódio de sulfato de tributilfenol éter aumentou o R740 dos monitores. Os altos valores R740 se igualam a tecidos mais brancos e mais limpos. O polialquilfenol alcoxilado provê benefícios significativamente melhores do que a polietilenoimina etoxilada, Sokalan HP20, que, sob a condição atual, não ofereceu beneficio significativo.[0102] The sodium salt of tributylphenol sulfate ether increased the R740 of the monitors. High R740 values equate to whiter, cleaner fabrics. The alkoxylated polyalkylphenol provides significantly better benefits than the ethoxylated polyethyleneimine, Sokalan HP20, which, under the current condition, offered no significant benefit.
Claims (18)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP14185265 | 2014-09-18 | ||
EP14185265.7 | 2014-09-18 | ||
PCT/EP2015/067274 WO2016041676A1 (en) | 2014-09-18 | 2015-07-28 | Whitening composition |
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BR112017005495A2 BR112017005495A2 (en) | 2017-12-19 |
BR112017005495B1 true BR112017005495B1 (en) | 2021-11-30 |
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