BR112013025510A2 - titanium oxo-chelate catalyst formulation and compound, uses of a titanium oxo-chelate catalyst formulation, and a polymerizable composition, composition, coated substrate, and process for polymerizing compounds - Google Patents

titanium oxo-chelate catalyst formulation and compound, uses of a titanium oxo-chelate catalyst formulation, and a polymerizable composition, composition, coated substrate, and process for polymerizing compounds

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Publication number
BR112013025510A2
BR112013025510A2 BR112013025510A BR112013025510A BR112013025510A2 BR 112013025510 A2 BR112013025510 A2 BR 112013025510A2 BR 112013025510 A BR112013025510 A BR 112013025510A BR 112013025510 A BR112013025510 A BR 112013025510A BR 112013025510 A2 BR112013025510 A2 BR 112013025510A2
Authority
BR
Brazil
Prior art keywords
catalyst formulation
chelate catalyst
composition
compound
titanium oxo
Prior art date
Application number
BR112013025510A
Other languages
Portuguese (pt)
Inventor
Carroy Antoine
Lordelt Caroline
Bauer Didier
Faller Marc
Kohli Setck Rachel
Hintermann Tobias
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of BR112013025510A2 publication Critical patent/BR112013025510A2/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0205—Oxygen-containing compounds comprising carbonyl groups or oxygen-containing derivatives, e.g. acetals, ketals, cyclic peroxides
    • B01J31/0208—Ketones or ketals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/222—Catalysts containing metal compounds metal compounds not provided for in groups C08G18/225 - C08G18/26
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225—Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/68—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C09D175/16—Polyurethanes having carbon-to-carbon unsaturated bonds having terminal carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides, epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/48—Ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Catalysts (AREA)
  • Paints Or Removers (AREA)
  • Polymerization Catalysts (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Sealing Material Composition (AREA)

Abstract

formulação e composto catalisador de oxo-quelato de titânio, usos de uma formulação de catalisador de oxo-quelato de titânio, e de uma composição polimerizável, composição, substrato revestido, e, processo para polimerizar compostos uma formulação de catalisador de oxo-quelato de titânio, compreendendo (i) pelo menos um composto da fórmula i em que, r~ 1~, r~ 2~, r~ 3~, r~ 4~, r~ 5~, r~ 6~, r~ 7~, r~ 8~, r~ 9~, r~ 10~, r~ 11~ e r~ 12 independentemente um do outro são, por exemplo, hidrogênio, halogênio, alquila c~ 1~-c~ 20~, arila c~ 6~-c~ 14~ que é não substituído ou substituído; ou r~ 1~, r~ 2~, r~ 3~, r~ 4~, r~ 5~, r~ 6~, r~ 7~, r~ 8~, r~ 9~, r~ 10~, r~ 11~ e r~ 12~ junto com o átomo de c ao qual eles são anexados formam um grupo arila c~ 6~-c~ 14~ que é não substituído ou substituído; ou r~ 1~, r~ 2~, r~ 3~, r~ 4~, r~ 5~ e/ou r~ 6~, r~ 7~, r~ 8~ e/ou r~ 10~ e r~ 11~ junto com o átomo de c ao qual eles são anexados formam um anel carbocíclico de 5 a 7 membros; pelo menos um composto de ligante de quelato da fórmula iia, iib ou iic em que r~ 1~, r~ 2~, r~ 3~, r~ 4~, r~ 5~ e r~ 6~ são definidos conforme anteriormente para a fórmula i, é adequado como formulação de catalisador fotolatente para polimerizar compostos, que são capazes de reticular a presença de um ácido de lewis.titanium oxo-chelate catalyst formulation and compound, uses of a titanium oxo-chelate catalyst formulation, and a polymerizable composition, composition, coated substrate, and process to polymerize compounds a titanium oxo-chelate catalyst formulation titanium, comprising (i) at least one compound of formula i wherein, r ~ 1 ~, r ~ 2 ~, r ~ 3 ~, r ~ 4 ~, r ~ 5 ~, r ~ 6 ~, r ~ 7 ~ , r ~ 8 ~, r ~ 9 ~, r ~ 10 ~, r ~ 11 ~ and r ~ 12 independently of each other are, for example, hydrogen, halogen, c ~ 1-c ~ 20 ~ alkyl, aryl c ~ Which is unsubstituted or substituted; or r ~ 1 ~, r ~ 2 ~, r ~ 3 ~, r ~ 4 ~, r ~ 5 ~, r ~ 6 ~, r ~ 7 ~, r ~ 8 ~, r ~ 9 ~, r ~ 10 ~ R 11 and R 12 together with the C atom to which they are attached form a C 6 -C 14 aryl group which is unsubstituted or substituted; or r ~ 1 ~, r ~ 2 ~, r ~ 3 ~, r ~ 4 ~, r ~ 5 ~ and / or r ~ 6 ~, r ~ 7 ~, r ~ 8 ~ and / or r ~ 10 ~ er Together with the c atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate binder compound of the formula iia, iib or iic wherein r1, r2, r3, r4, r5 and r6 are as defined above for Formula I is suitable as a photolatent catalyst formulation for polymerizing compounds which are capable of cross-linking the presence of a Lewis acid.

BR112013025510A 2011-04-05 2012-04-02 titanium oxo-chelate catalyst formulation and compound, uses of a titanium oxo-chelate catalyst formulation, and a polymerizable composition, composition, coated substrate, and process for polymerizing compounds BR112013025510A2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201161471704P 2011-04-05 2011-04-05
EP11161087 2011-04-05
PCT/EP2012/055920 WO2012136606A1 (en) 2011-04-05 2012-04-02 Photo-latent titanium-oxo-chelate catalysts

Publications (1)

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BR112013025510A2 true BR112013025510A2 (en) 2018-07-03

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Country Status (8)

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US (2) US9809727B2 (en)
EP (1) EP2694211A1 (en)
JP (1) JP6184401B2 (en)
KR (1) KR101882045B1 (en)
CN (1) CN103596684B (en)
BR (1) BR112013025510A2 (en)
RU (1) RU2610090C9 (en)
WO (1) WO2012136606A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9339832B2 (en) 2012-03-22 2016-05-17 Basf Se Spraygun for producing cured coating films and methods of use thereof
CA2877030A1 (en) 2012-06-22 2013-12-27 Basf Se Multicomponent crystals comprising imatinib mesilate and selected co-crystal formers
JP6481321B2 (en) * 2014-10-03 2019-03-13 Dic株式会社 Urethane catalyst, polyol mixture, adhesive, and laminated film
US10053596B2 (en) 2016-08-30 2018-08-21 Prc-Desoto International, Inc. Curable film-forming compositions demonstrating increased wet-edge time
CN110105533A (en) * 2019-05-05 2019-08-09 湖北三江航天江河化工科技有限公司 Double solidification linear polyurethane acrylates of polyfunctionality and preparation method thereof

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5336449B2 (en) 1972-05-27 1978-10-03
DE2962089D1 (en) 1978-07-14 1982-03-18 Basf Ag Light-curable moulding, impregnating and coating compositions and shaped articles prepared therefrom
AU570707B2 (en) 1983-09-02 1988-03-24 Fmc Corporation Bag making apparatus
US4575330A (en) 1984-08-08 1986-03-11 Uvp, Inc. Apparatus for production of three-dimensional objects by stereolithography
US4973623A (en) 1989-05-26 1990-11-27 Dow Corning Corporation Fast curing oximo-ethoxy functional siloxane sealants
SE9200564L (en) 1992-02-26 1993-03-15 Perstorp Ab DENDRITIC MACROMOLECYLE OF POLYESTER TYPE, PROCEDURES FOR PRODUCING THEREOF AND USING THEREOF
DE4228514A1 (en) 1992-08-27 1994-03-03 Hoechst Ag Binder for powder coatings
BE1007373A3 (en) 1993-07-30 1995-05-30 Dsm Nv Radiation-curable binder composition for powder paints formulations.
US5545600A (en) 1994-12-21 1996-08-13 Knudsen; George A. Process for the preparation of dialkyltin dialkoxide
KR100418164B1 (en) 1995-07-31 2004-03-19 미쓰비시 마테리알 가부시키가이샤 High-Purity Ti complexes, Methods for Producing the same and BST Film-Forming Liquid compositions
JPH1072475A (en) 1996-08-29 1998-03-17 Nippon Sanso Kk High-purity titanium beta-diketonate complex and its production
JP3957112B2 (en) * 1997-10-31 2007-08-15 三菱マテリアル株式会社 Solution raw materials and dielectric thin films for complex oxide dielectric thin film formation
CA2292483A1 (en) 1998-12-17 2000-06-17 Sinzi Hirato Electrodeposition paint composition
DE19935471A1 (en) 1999-07-28 2001-02-08 Goldschmidt Ag Th A composition for deposition of storage stable, extremely hard, weather resistant surface coatings without additional primers, contains silicone resin, finely divided colloidal silicic acid, silane, and non-aromatic epoxide resin
US6372879B1 (en) * 2000-01-07 2002-04-16 Atofina Chemicals, Inc. Polyester polycondensation with catalyst and a catalyst enhancer
GB0000569D0 (en) * 2000-01-12 2000-03-01 Ici Plc Organometallic compositions
US6664323B2 (en) 2001-02-02 2003-12-16 General Electric Company Moisture curable sealants
JP2002356651A (en) 2001-05-30 2002-12-13 Dow Corning Toray Silicone Co Ltd Silicone composition for water repellent coating
US6620871B2 (en) 2001-06-07 2003-09-16 Nike, Inc. Rubber compositions with increased shelf life and reduced cure temperatures and times
DE10260299A1 (en) 2002-12-20 2004-07-01 Bayer Ag Reactive systems, their manufacture and their use
US6969754B2 (en) 2003-12-11 2005-11-29 Valspar Sourcing, Inc. Blocked isocyanate crosslinker solution
CN1910250B (en) 2004-01-30 2010-05-05 株式会社钟化 Adhesive composition
US20070249484A1 (en) 2004-07-21 2007-10-25 Johannes Benkhoff Process for the Photoactivation and use of a Catalyst by an Inverted Two-Stage Procedure
DE102004044085A1 (en) 2004-09-09 2006-03-16 Tesa Ag Pressure-sensitive adhesive with dual crosslinking mechanism
JP2006206781A (en) 2005-01-28 2006-08-10 Tosoh Corp Catalyst composition for producing polyurethane resin and method for producing polyurethane resin
DE102005029282A1 (en) 2005-06-23 2006-12-28 Henkel Kgaa Silane cross-linking adhesive or sealing compounds, useful for adhering woods, plastics and metals, comprises polymer compounds, coupling agents, desiccants and/or reactive diluents
US7365145B2 (en) * 2005-09-14 2008-04-29 Momentive Performance Materials Inc. Moisture curable silylated polymer containing free polyols for coating, adhesive and sealant application
JP4957052B2 (en) 2006-04-04 2012-06-20 Ｎｏｋ株式会社 Vulcanized adhesive composition
WO2007147851A1 (en) 2006-06-22 2007-12-27 Ciba Holding Inc. Actinic radiation-curable coating composition
DE102006047738A1 (en) 2006-10-06 2008-04-10 Tesa Ag Heat-activated adhesive tape, in particular for the bonding of electronic components and printed conductors
WO2008045395A2 (en) 2006-10-10 2008-04-17 Dow Corning Corporation Process for making organopolysiloxane compositions
GB2444255A (en) 2006-11-30 2008-06-04 Formerol Ltd Mouldable one-part RTV silicone elastomer
JP5028139B2 (en) 2007-05-10 2012-09-19 株式会社カネカ Curable composition
RU2489450C9 (en) 2007-10-17 2014-01-27 Басф Се Photolatent catalysts based on organometallic compounds
JP5285892B2 (en) 2007-10-25 2013-09-11 東レ・ダウコーニング株式会社 Room temperature curable organopolysiloxane composition
EP2477739B1 (en) * 2009-09-15 2019-04-10 Basf Se Photo-latent titanium catalysts
JP5894919B2 (en) * 2009-09-15 2016-03-30 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ Photolatent titanium chelate catalyst

Also Published As

Publication number Publication date
JP6184401B2 (en) 2017-08-23
US20180105719A1 (en) 2018-04-19
US9809727B2 (en) 2017-11-07
EP2694211A1 (en) 2014-02-12
KR101882045B1 (en) 2018-07-25
CN103596684B (en) 2015-09-16
RU2610090C2 (en) 2017-02-07
KR20140022044A (en) 2014-02-21
CN103596684A (en) 2014-02-19
WO2012136606A1 (en) 2012-10-11
US20140018461A1 (en) 2014-01-16
JP2014518561A (en) 2014-07-31
RU2610090C9 (en) 2018-04-26
RU2013148611A (en) 2015-05-10

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

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