BR102018069428A8 - Processo para adsorver oxigênio de uma corrente de alimentação contendo oxigênio contendo adsorventes de rho, composição de zeólito de rho e uso da composição - Google Patents
Processo para adsorver oxigênio de uma corrente de alimentação contendo oxigênio contendo adsorventes de rho, composição de zeólito de rho e uso da composiçãoInfo
- Publication number
- BR102018069428A8 BR102018069428A8 BR102018069428A BR102018069428A BR102018069428A8 BR 102018069428 A8 BR102018069428 A8 BR 102018069428A8 BR 102018069428 A BR102018069428 A BR 102018069428A BR 102018069428 A BR102018069428 A BR 102018069428A BR 102018069428 A8 BR102018069428 A8 BR 102018069428A8
- Authority
- BR
- Brazil
- Prior art keywords
- oxygen
- rho
- composition
- feed stream
- adsorbents
- Prior art date
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title abstract 7
- 239000001301 oxygen Substances 0.000 title abstract 7
- 229910052760 oxygen Inorganic materials 0.000 title abstract 7
- 238000000034 method Methods 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 239000003463 adsorbent Substances 0.000 title abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/165—Natural alumino-silicates, e.g. zeolites
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
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- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0407—Constructional details of adsorbing systems
- B01D53/0423—Beds in columns
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0473—Rapid pressure swing adsorption
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0476—Vacuum pressure swing adsorption
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
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- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28011—Other properties, e.g. density, crush strength
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0259—Physical processing only by adsorption on solids
- C01B13/0262—Physical processing only by adsorption on solids characterised by the adsorbent
- C01B13/027—Zeolites
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- C01B21/00—Nitrogen; Compounds thereof
- C01B21/04—Purification or separation of nitrogen
- C01B21/0405—Purification or separation processes
- C01B21/0433—Physical processing only
- C01B21/045—Physical processing only by adsorption in solids
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B23/00—Noble gases; Compounds thereof
- C01B23/001—Purification or separation processes of noble gases
- C01B23/0036—Physical processing only
- C01B23/0052—Physical processing only by adsorption in solids
- C01B23/0057—Physical processing only by adsorption in solids characterised by the adsorbent
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
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- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
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- B01D2253/1085—Zeolites characterized by a silicon-aluminium ratio
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- B01D2259/4141—Further details for adsorption processes and devices using different types of adsorbents within a single bed
- B01D2259/4145—Further details for adsorption processes and devices using different types of adsorbents within a single bed arranged in series
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- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2210/00—Purification or separation of specific gases
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/60—Processes or apparatus using other separation and/or other processing means using adsorption on solid adsorbents, e.g. by temperature-swing adsorption [TSA] at the hot or cold end
- F25J2205/66—Regenerating the adsorption vessel, e.g. kind of reactivation gas
- F25J2205/72—Pressurising or depressurising the adsorption vessel
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- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
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- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
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- F25J3/04721—Producing pure argon, e.g. recovered from a crude argon column
- F25J3/04733—Producing pure argon, e.g. recovered from a crude argon column using a hybrid system, e.g. using adsorption, permeation or catalytic reaction
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Separation Of Gases By Adsorption (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
PROCESSOS MELHORADOS QUE USAM COMPOSIÇÕES ADSORVENTES DE RHO. São revelados novos processos para adsorver oxigênio com o uso de composições adsorventes que compreendem zeólitos de RHO cineticamente seletivos para oxigênio. Os zeólitos de RHO podem ser usados em processos de adsorção com oscilação de pressão para separar oxigênio de correntes contendo oxigênio, como para, porém sem limitado, a purificar uma corrente de alimentação de argônio bruto ou separar o oxigênio de uma corrente de alimentação de ar.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/718,620 | 2017-09-28 | ||
US15/718,620 US10343139B2 (en) | 2017-09-28 | 2017-09-28 | Processes using improved RHO adsorbent compositions |
Publications (3)
Publication Number | Publication Date |
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BR102018069428A2 BR102018069428A2 (pt) | 2019-04-16 |
BR102018069428A8 true BR102018069428A8 (pt) | 2023-02-14 |
BR102018069428B1 BR102018069428B1 (pt) | 2024-01-23 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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BR102018069428-6A BR102018069428B1 (pt) | 2017-09-28 | 2018-09-24 | Processo para adsorver oxigênio de uma corrente de alimentação contendo oxigênio contendo adsorventes de rho |
Country Status (12)
Country | Link |
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US (1) | US10343139B2 (pt) |
EP (1) | EP3461550B1 (pt) |
KR (1) | KR102128167B1 (pt) |
CN (1) | CN109569503B (pt) |
AR (1) | AR113187A1 (pt) |
BR (1) | BR102018069428B1 (pt) |
CA (1) | CA3018291C (pt) |
CL (1) | CL2018002710A1 (pt) |
ES (1) | ES2800949T3 (pt) |
MX (1) | MX2018011639A (pt) |
RU (1) | RU2696385C1 (pt) |
TW (1) | TWI666049B (pt) |
Families Citing this family (8)
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US7954490B2 (en) | 2005-02-09 | 2011-06-07 | Vbox, Incorporated | Method of providing ambulatory oxygen |
US10646848B2 (en) * | 2017-09-28 | 2020-05-12 | Air Products And Chemicals, Inc. | RHO adsorbent compositions, methods of making and using them |
US10950836B2 (en) * | 2018-01-24 | 2021-03-16 | GM Global Technology Operations LLC | Separators for lithium-containing electrochemical cells and methods of making the same |
US11433346B2 (en) | 2019-10-16 | 2022-09-06 | Exxonmobil Upstream Research Company | Dehydration processes utilizing cationic zeolite RHO |
EP4228810A1 (en) * | 2020-10-14 | 2023-08-23 | Umicore AG & Co. KG | Passive nitrogen oxide adsorber |
US20230182066A1 (en) * | 2021-12-10 | 2023-06-15 | ExxonMobil Technology and Engineering Company | Air separation processes using zeolite itq-55 |
CN114749145B (zh) * | 2022-04-28 | 2023-07-18 | 东北石油大学 | 吸附分离氮气与甲烷的分子筛及制备方法 |
CN116422289B (zh) * | 2023-04-07 | 2024-01-12 | 东北石油大学 | 一种从炼厂气中脱除n2的分子筛及其制备方法和应用 |
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EP1309399B1 (en) * | 2000-08-18 | 2004-05-26 | E.I. Du Pont De Nemours And Company | Gas separation process |
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PT103615B (pt) | 2006-12-14 | 2010-08-31 | Univ Do Porto | Coluna de separação e processo de adsorção com modulação de pressão para purificação de gases |
WO2014088756A1 (en) * | 2012-12-06 | 2014-06-12 | Exxonmobil Research And Engineering Company | Gas separation method using ddr type zeolites with stabilized adsorption activity |
WO2015020014A1 (ja) | 2013-08-05 | 2015-02-12 | 三菱化学株式会社 | ゼオライト及びその製造方法と用途 |
FR3032130B1 (fr) * | 2015-02-02 | 2019-12-27 | Arkema France | Adsorbants zeolithiques de haute surface externe, leur procede de preparation et leurs utilisations |
JP6546504B2 (ja) * | 2015-10-20 | 2019-07-17 | レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード | 酸素製造システム及び酸素製造方法 |
AU2016357289A1 (en) * | 2015-11-16 | 2018-06-14 | Exxonmobil Upstream Research Company | Adsorbent materials and methods of adsorbing carbon dioxide |
CN106799202B (zh) * | 2015-11-18 | 2019-12-27 | 中国科学院大连化学物理研究所 | 一种用于气体分离的分子筛及其制备和应用 |
JP2019501766A (ja) * | 2015-12-29 | 2019-01-24 | ユーオーピー エルエルシー | バインダーレスゼオライト吸着剤およびバインダーレスゼオライト吸着剤の製造方法 |
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US10646848B2 (en) * | 2017-09-28 | 2020-05-12 | Air Products And Chemicals, Inc. | RHO adsorbent compositions, methods of making and using them |
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AR113187A1 (es) | 2020-02-05 |
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TW201914684A (zh) | 2019-04-16 |
EP3461550A1 (en) | 2019-04-03 |
RU2696385C1 (ru) | 2019-08-01 |
ES2800949T3 (es) | 2021-01-05 |
CL2018002710A1 (es) | 2019-05-17 |
CN109569503B (zh) | 2021-11-16 |
BR102018069428B1 (pt) | 2024-01-23 |
KR20190037141A (ko) | 2019-04-05 |
US20190091651A1 (en) | 2019-03-28 |
CN109569503A (zh) | 2019-04-05 |
TWI666049B (zh) | 2019-07-21 |
EP3461550B1 (en) | 2020-04-08 |
US10343139B2 (en) | 2019-07-09 |
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