BR102013019112A2 - COMPOSITION OF MATERIALS EXTRACTED FROM RECYCLED WASTE AND RESULTING MATERIAL - Google Patents

COMPOSITION OF MATERIALS EXTRACTED FROM RECYCLED WASTE AND RESULTING MATERIAL Download PDF

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BR102013019112A2
BR102013019112A2 BRBR102013019112-4A BR102013019112A BR102013019112A2 BR 102013019112 A2 BR102013019112 A2 BR 102013019112A2 BR 102013019112 A BR102013019112 A BR 102013019112A BR 102013019112 A2 BR102013019112 A2 BR 102013019112A2
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Brazil
Prior art keywords
waste
materials
extracted
recycled waste
wood
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BRBR102013019112-4A
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Portuguese (pt)
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Almeida Barros Jose Sergio De
Pitta Danilo Martinelli
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Almeida Barros Jose Sergio De
Pitta Danilo Martinelli
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Application filed by Almeida Barros Jose Sergio De, Pitta Danilo Martinelli filed Critical Almeida Barros Jose Sergio De
Priority to BRBR102013019112-4A priority Critical patent/BR102013019112A2/en
Publication of BR102013019112A2 publication Critical patent/BR102013019112A2/en
Priority to PCT/BR2014/000242 priority patent/WO2015010177A1/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00129Extrudable mixtures
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

RESUMO COMPOSIÇÃO DE MATERIAIS EXTRAIDOS DO RESÍDUO RECICLADO E MATERIAL RESULTANTE O problema é a obtenção de materiais sintéticos para substituir a madeira em extinção e por outro lado reciclar resíduos da indústria de transformação e do lixo urbano e a solução reivindicada é o agrupamento de materiais de diferentes estruturas químicas, extraídos dos resíduos reciclados da indústria de transformação e do lixo urbano, em formulação específica, termoprocessado em extrusora, resultando em material com características funcionais similares às da madeira; se caracteriza por agrupar plásticos sujos, isto é, da forma como encontrado nos pontos de coleta de lixo urbano ou industrial, para serem reprocessados simultaneamente; e explorou as características químicas e físicas de cada plástico sujo e pesquisou a quantidade em peso percentual de cada material extraído do resíduo reciclado compreendendo: 45% a 70% de PE, PEAD e PEBD , 4% a 9% de PP, 1% a 4% de POLYESTER, 0,1% a 4% de TECIDO de algodão, 0,1% a 4% de COLA e BORRACHA, 4% a 18% de FIBRA VEGETAL e MADEIRA, 3% a 10% de OS, ABS, HIPS, PET, PC, PU, EPS e BLISTER, 0,1% a 7% de AREIA, TERRA e DEJETOS ORGÂNICOS. 1/1SUMMARY COMPOSITION OF MATERIALS EXTRACTED FROM RECYCLED WASTE AND RESULTING MATERIAL The problem is to obtain synthetic materials to replace endangered wood and to recycle waste from the processing industry and urban waste and the claimed solution is to group together materials from different chemical structures, extracted from recycled waste from the manufacturing industry and urban waste, in a specific formulation, thermoprocessed in extruder, resulting in material with functional characteristics similar to those of wood; is characterized by grouping dirty plastics, that is, as found in urban or industrial waste collection points, to be reprocessed simultaneously; and explored the chemical and physical characteristics of each dirty plastic and researched the percentage by weight of each material extracted from the recycled waste comprising: 45% to 70% PE, HDPE and LDPE, 4% to 9% PP, 1% to 4% POLYESTER, 0.1% to 4% Cotton FABRIC, 0.1% to 4% COLA and RUBBER, 4% to 18% VEGETABLE FIBER & WOOD, 3% to 10% OS, ABS, HIPS, PET, PC, PU, EPS and BLISTER, 0.1% to 7% of SAND, LAND and ORGANIC WASTE. 1/1

Description

COMPOSIÇÃO DE MATERIAIS EXTRAÍDOS DO RESÍDUO RECICLADO E MATERIAL RESULTANTECOMPOSITION OF MATERIALS EXTRACTED FROM RECYCLED WASTE AND RESULTING MATERIAL

Trata-se de agrupamento de materiais de diferentes estruturas químicas, extraídos dos resíduos reciclados da indústria de transformação e da coleta de lixo urbano, em formulação específica, processado em extrusora, resultando em material com características funcionais similares às da madeira.This is a grouping of materials of different chemical structures, extracted from recycled waste from the manufacturing industry and urban waste collection, in a specific formulation, processed in extruder, resulting in material with functional characteristics similar to those of wood.

O processo de craqueamento dos hidrocarbonetos resulta na conversão dos componentes do gás natural ou do petróleo em monômeros, tais como etileno, propileno, buteno e estireno. A combinação de diferentes monômeros produzem resinas plásticas, aqui denominados "plásticos", com propriedades e características diferentes.The hydrocarbon cracking process results in the conversion of natural gas or petroleum components into monomers such as ethylene, propylene, butene and styrene. The combination of different monomers produces plastic resins, here called "plastics", with different properties and characteristics.

Para manter as características próprias de cada plástico, após a reciclagem, cada tipo de plástico precisa ser reprocessados separadamente. Por causa das suas variadas propriedades físicas e químicas, diferentes plásticos, se reprocessados em conjunto, perdem suas propriedades originais e o produto decorrente possui característica própria e independente das características dos materiais agrupados e usados como matéria prima, na reciclagem. O plástico conhecido por PET - polietileno tereftalato e o HDPE - polietileno de alta densidade são exemplos de plásticos que normalmente são reprocessados separadamente. Isso é possível economicamente devido a grande quantidade de produtos fabricados com esses plásticos. O PET é usado na fabricação de embalagens, sacolas, garrafas de bebidas e outras. O HDPE é usado para recipiente do tipo iogurte, detergentes, margarinas, sacolas para lixo e outras. A maioria dos plásticos recicláveis está distribuída em diferentes pontos de coleta e se apresenta em pequenas quantidades, elevando o custo do ciclo se reprocessados separadamente. A dificuldade está em agrupar esses plásticos de diferentes estruturas químicas extraídos dos resíduos reciclados da indústria de transformação e da coleta de lixo urbano, em formulação com porcentagem específica de cada plástico coletado, de modo que, quando reprocessado simultaneamente em extrusora, resulta em material com características químicas, físicas e funcionais úteis e com aplicação industrial. A dificuldade de reprocessamento é aumentada quando se deseja agrupar plásticos sujos, isto é, da forma como encontrado nos pontos de coleta de lixo urbano ou industrial; são encontrados com recobrimento de tintas, gorduras, terra, areia, além da presença de fibras vegetais e outros. Os principais materiais plásticos e não plásticos encontrados para reciclagem são:To maintain the characteristics of each plastic after recycling, each type of plastic needs to be reprocessed separately. Because of their varied physical and chemical properties, different plastics, if reprocessed together, lose their original properties and the resulting product has its own characteristics independent of the characteristics of the grouped materials used as raw material in recycling. Plastic known as PET - polyethylene terephthalate and HDPE - high density polyethylene are examples of plastics that are normally reprocessed separately. This is economically possible due to the large amount of products made from these plastics. PET is used in the manufacture of packaging, bags, beverage bottles and others. HDPE is used for yogurt containers, detergents, margarines, garbage bags and more. Most recyclable plastics are distributed at different collection points and are in small quantities, increasing the cost of the cycle if reprocessed separately. The difficulty lies in grouping these plastics from different chemical structures extracted from the recycled waste from the manufacturing industry and from the urban waste collection, in a formulation with a specific percentage of each collected plastic, so that when simultaneously reprocessed in an extruder, it results in material with useful chemical, physical and functional characteristics and with industrial application. The difficulty of reprocessing is increased when it is desired to group dirty plastics, that is, as found at urban or industrial waste collection points; They are found with coatings of paints, fats, earth, sand, besides the presence of vegetable fibers and others. The main plastic and non-plastic materials found for recycling are:

• PE- Polietileno. Resina termoplástica obtida da polimerização do gás etileno; se com polímeros de alto peso molecular são• PE- Polyethylene. Thermoplastic resin obtained from polymerization of ethylene gas; with high molecular weight polymers are

utilizados na indústria plástica, em forma de filme.used in the plastic industry in film form.

• PEAD- Polietileno de alta densidade• HDPE- High Density Polyethylene

• PEBD- Polietileno de baixa densidade• LDPE- Low Density Polyethylene

• PP- Polipropileno. Resina termoplástica obtida da polimerização do propileno; são utilizados para calafetagem,• PP- Polypropylene. Thermoplastic resin obtained from propylene polymerization; are used for caulking,

enchimentos na indústria de embalagens, peças automobilísticas e adesivos.fillers in the packaging, auto parts and adhesives industry.

• PS - Poliestireno• PS - Polystyrene

• ABS - Acrilonitrila butadieno estireno · HIPS -PoliestirenodeaItoimpacto • PET - Polietileno tereftalato• ABS - Acrylonitrile Butadiene Styrene · HIPS -PolyestyrenodeaItimpact • PET - Polyethylene terephthalate

• PC - Policarbonato• PC - Polycarbonate

• POLIESTER- Resina termoplástica saturada que inclui o PET e resina insaturada obtidas da reação de condensação entre ácidos e• POLIESTER- Saturated thermoplastic resin including PET and unsaturated resin obtained from the condensation reaction between acids and

glicóisglycols

• PU - Poliuretano. Polímeros obtidos da reação de isocianato orgânico com compostos contendo grupo de oxilas; a espuma de poliuretano é usada para isolamento térmico em câmaras frigoríficas, enchimentos de paredes, moveis e na• PU - Polyurethane. Polymers obtained from the reaction of organic isocyanate with oxy group-containing compounds; polyurethane foam is used for thermal insulation in cold rooms, wall fillers, furniture and in

construção de edificaçõesbuilding construction

• EPS - Poliestireno expandido BLISTER- Blister• EPS - Expanded polystyrene BLISTER-Blister

• NYLON - São termoplásticos de poliamida encontrados em peças de veículos automotores, peças de equipamentos eletro-eletronicos e• NYLON - These are polyamide thermoplastics found in automotive parts, electro-electronic equipment parts, and

embalagens.packaging.

• Outros - Perbunan, Policloropreno, Poliisopreno e Plexiglas.• Others - Perbunan, Polychloroprene, Polyisoprene and Plexiglas.

O documento de patentes Pl 0408319-9, depositado no INPI-BR emPatent document Pl 0408319-9, filed with INPI-BR on

04/03/2004, descreve um método de reciclagem e redução de material plástico ou não plástico utilizando fonte de infravermelho. O documento Pl 0701132-6, depositado no INPI-BR em 30/5/2007, consiste na utilização do processo de transformação dos resíduos através da utilização de reagentes químicos que promove a reação de oxi-redução. Qualquer extrusora que utiliza fonte direta ou indireta de calor, com controle de temperatura, possui potencial técnico para processar material plástico e não plástico. O material resultante vai depender mais da composição da matéria prima que das características da extrusora. A "Composição de Materiais Extraídos do Resíduo Reciclado e Material Resultante", descrito neste relatório, se caracteriza por agrupar plásticos sujos, isto é, da forma como encontrado nos pontos de coleta de lixo urbano ou industrial, para reprocessar simultaneamente. Explorou as características químicas e físicas de cada plástico sujo e pesquisou a quantidade em peso percentual de cada um de modo a resultar um produto com características suficientemente igual às características mecânicas da madeira.04/03/2004, describes a method of recycling and reducing plastic or non-plastic material using an infrared source. Document P 0701132-6, filed with the INPI-BR on 30/05/2007, consists of the use of the waste transformation process through the use of chemical reagents that promotes the oxy-reduction reaction. Any extruder using direct or indirect heat source with temperature control has technical potential to process plastic and non-plastic material. The resulting material will depend more on the composition of the raw material than on the characteristics of the extruder. The "Composition of Materials Taken From Recycled Waste And Resulting Material", described in this report, is characterized by grouping dirty plastics, that is, as found at urban or industrial waste collection points, for simultaneous reprocessing. He explored the chemical and physical characteristics of each dirty plastic and researched the amount by weight of each to yield a product with characteristics sufficiently equal to the mechanical characteristics of the wood.

A composição, resultante em percentagem do peso total, de cada material extraído do resíduo reciclado e reivindicado neste documento, compreende:The resulting composition as a percentage of the total weight of each material extracted from the recycled waste claimed herein comprises:

PE (PEAD e PEBD) - 45% a 70%HDPE (HDPE and LDPE) - 45% to 70%

PP - 4% a 9%PP - 4% to 9%

POLYESTER - 1 % a 4%POLYESTER - 1% to 4%

PANO/TECIDO - 0,1% a 4%CLOTH / FABRIC - 0.1% to 4%

COLA/BORRACHA - 0,1% a 4%Glue / Rubber - 0.1% to 4%

FIBRA VEGETAL/MADEIRA - 4% a 18%VEGETABLE FIBER / WOOD - 4% to 18%

PS/ABS/HIPS/PET/PC/PU/E PS/BLISTE R - 3% a 10%PS / ABS / HIPS / PET / PC / PU / E PS / BL BL - 3% to 10%

AREIA/TERRA/DEJETOS ORGÂNICOS - 0,1% a 7%SAND / GROUND / ORGANIC WASTE - 0.1% to 7%

O material reciclável compreendido na formulação é inicialmente triturado, depois misturado e levado à extrusora; posteriormente laminado e resfriado para o corte do produto final. Não há, na formulação, adição de aditivos, agentes de aceleração de decomposição, nem agentes de reticulação que aumenta a formação de pontes de valência entre os compostos. Também não é utilizado retardante de cura que reduz a velocidade do processo para obter a cura de algum polímero. O material resultante do reprocessamento é diferente de cada uma das matérias usadas como matéria prima. O material resultante exibe diferentes propriedades físicas e mecânicas, incluindo tamanho de partícula, densidade, dureza, flexibilidade, escoamento e compactabilidade. Essas propriedades conferem características suficientemente diferenciadas e que solucionam um problema do estado da técnica; substituem a madeira. Mantida a formulação reivindicada, o produto resultante possui estabilidade física e química para sua utilização industrial.The recyclable material comprised in the formulation is initially ground, then mixed and taken to the extruder; then laminated and cooled to cut the final product. There are no additives in the formulation, no decomposition accelerating agents, no crosslinking agents that increase the formation of valence bridges between the compounds. Also, no cure retardant is used which slows down the process to cure some polymer. The material resulting from reprocessing is different from each of the materials used as raw material. The resulting material exhibits different physical and mechanical properties including particle size, density, hardness, flexibility, yield and compactability. These properties confer sufficiently differentiated characteristics that solve a problem of the state of the art; replace wood. Keeping the claimed formulation, the resulting product has physical and chemical stability for its industrial use.

Claims (3)

1. COMPOSIÇÃO DE MATERIAIS EXTRAÍDOS DO RESÍDUO RECICLADO E MATERIAL RESULTANTE formado pelo agrupamento de materiais de diferentes estruturas químicas extraídos dos resíduos reciclados da indústria de transformação e da coleta de lixo urbano, caracterizado por conter na sua composição 45% a 70% de PE, PEAD e PEBD , 4% a 9% de PP,1% a 4% de POLYESTER, 0,1% a 4% de TECIDO de algodão, 0,1% a 4% de COLA e BORRACHA, 4% a 18% de FIBRA VEGETAL e MADEIRA, 3% a10% de OS, ABS, HIPS, PET, PC, PU, EPS e BLISTER, 0,1% a 7% de AREIA, TERRA e DEJETOS ORGÂNICOS.1. COMPOSITION OF MATERIALS EXTRACTED FROM RECYCLED WASTE AND RESULTANT MATERIAL formed by the grouping of materials of different chemical structures extracted from the recycled waste of the manufacturing industry and urban waste collection, characterized in that it contains 45% to 70% PE, HDPE and LDPE, 4% to 9% PP, 1% to 4% POLYESTER, 0.1% to 4% Cotton FABRIC, 0.1% to 4% COLA and RUBBER, 4% to 18% VEGETABLE AND WOOD FIBER, 3% to 10% OS, ABS, HIPS, PET, PC, PU, EPS and BLISTER, 0.1% to 7% of SAND, EARTH and ORGANIC DEJECTS. 2. MATERIAL RESULTANTE obtido por termofusão em extrusora, caracterizado pelo fato de ser preparado pela composição de materiais conforme descrito na reivindicação 1 (um).RESULTANT MATERIAL obtained by thermofusion in extruder, characterized in that it is prepared by the composition of materials as described in claim 1 (one). 3. MATERIAL RESULTANTE de acordo com a reivindicação 2(dois), caracterizado pelo fato de ser útil para pelo menos um dentre um material de construção civil, como caixaria na concretagem; um material de edificações, como rodapés, forras de portas e janelas; um material da indústria de moveis, painéis e objetos decorativos.RESULTANT MATERIAL according to claim 2 (2), characterized in that it is useful for at least one of a building material, as a casket in the concrete; building material such as baseboards, door and window coverings; a material from the furniture, paneling and decorative objects industry.
BRBR102013019112-4A 2013-07-25 2013-07-25 COMPOSITION OF MATERIALS EXTRACTED FROM RECYCLED WASTE AND RESULTING MATERIAL BR102013019112A2 (en)

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PCT/BR2014/000242 WO2015010177A1 (en) 2013-07-25 2014-07-11 Composition made from materials extracted from recycled waste, and resulting material

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016074053A1 (en) * 2014-11-10 2016-05-19 Jair ANCIOTO Method for reusing solid waste from ordinary refuse rejected from conventional recycling processes and construction waste by mixing with a binding composite to make bricks or similar products

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CN109206701A (en) * 2017-07-03 2019-01-15 镇江市睿泽文化传播有限公司 A kind of lightweight advertisement plate
CN109265789A (en) * 2018-07-29 2019-01-25 深圳市心版图科技有限公司 A kind of composite material and preparation method of high-modulus
CN109797486A (en) * 2019-01-26 2019-05-24 江西大晟节能新材股份有限公司 A kind of leftover pieces recycling manufacture at polyester-mixed cotton cloth preparation process
MX2021003222A (en) * 2021-03-18 2022-09-19 Ramon Martin Espinosa Solis Recycled plastic plate of the construction system for housing construction.
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US7790784B2 (en) * 2003-10-24 2010-09-07 The Crane Group Companies Limited Composition of matter

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016074053A1 (en) * 2014-11-10 2016-05-19 Jair ANCIOTO Method for reusing solid waste from ordinary refuse rejected from conventional recycling processes and construction waste by mixing with a binding composite to make bricks or similar products

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B03B Publication of an application: anticipated publication
B08F Application fees: dismissal - article 86 of industrial property law
B08K Lapse as no evidence of payment of the annual fee has been furnished to inpi (acc. art. 87)