BR0207835A - Catalyst system for olefin trimerization and olefin compound trimerization process - Google Patents

Catalyst system for olefin trimerization and olefin compound trimerization process

Info

Publication number
BR0207835A
BR0207835A BR0207835-0A BR0207835A BR0207835A BR 0207835 A BR0207835 A BR 0207835A BR 0207835 A BR0207835 A BR 0207835A BR 0207835 A BR0207835 A BR 0207835A
Authority
BR
Brazil
Prior art keywords
trimerization
catalyst system
olefin
optionally substituted
groups
Prior art date
Application number
BR0207835-0A
Other languages
Portuguese (pt)
Inventor
Patrick Jozef Wilhelmu Deckers
Bart Hessen
Original Assignee
Stichting Dutch Polymer Inst
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stichting Dutch Polymer Inst filed Critical Stichting Dutch Polymer Inst
Publication of BR0207835A publication Critical patent/BR0207835A/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Abstract

"SISTEMA CATALISADOR PARA A TRIMERIZAçãO DE OLEFINAS E PROCESSO DE TRIMERIZAçãO DE COMPOSTOS OLEFìNICOS". A invenção refere-se a um sistema catalisador para a trimerização seletiva da olefinas, sendo que o sistema é baseado em um complexo de titânio da fórmula (Cp-B(R)~ n~Ar)TiR^ 1^~ 3~, na qual: Cp é um ligante do tipo ciclopentadienila, opcionalmente substituído, B é um grupo de ligação, baseado em um único átomo selecionado dos grupos 13 a 16, inclusive, do sistema periódico, Ar é um grupo aromático, opcionalmente substituído, R é, independentemente, hidrogênio, ou um resíduo de hidrocarboneto, opcionalmente substituído e opcionalmente contendo heteroátomos, ou os grupos R e B são unidos um ao outro para formar um anel, N é um número inteiro igual à (valência de B menos 2), e R^ 1^ são um grupo mono-aniónico, e compreende adicionalmente um ativador. O presente sistema catalisador elimina o uso de compostos de cromo tóxicos."CATALYST SYSTEM FOR OLEFIN TRIMERIZATION AND OLEPHIC COMPOUND TRIMERIZATION PROCESS". The invention relates to a catalyst system for the selective trimerization of olefins, the system being based on a titanium complex of the formula (Cp-B (R) -n-Ar) TiR ^ 1 ^ ~ 3 ~, in which: Cp is an optionally substituted cyclopentadienyl-type binder, B is a linking group based on a single atom selected from groups 13 to 16 inclusive of the periodic system, Ar is an optionally substituted aromatic group, R is, independently, hydrogen, or an optionally substituted hydrocarbon residue optionally containing heteroatoms, or the groups R and B are joined together to form a ring, N is an integer equal to (valence of B minus 2), and R R1 is a mono anionic group, and further comprises an activator. The present catalyst system eliminates the use of toxic chromium compounds.

BR0207835-0A 2001-02-22 2002-02-22 Catalyst system for olefin trimerization and olefin compound trimerization process BR0207835A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NL0101149 2001-02-22
PCT/NL2002/000119 WO2002066405A1 (en) 2001-02-22 2002-02-22 Catalyst system for the trimerisation of olefins

Publications (1)

Publication Number Publication Date
BR0207835A true BR0207835A (en) 2004-06-22

Family

ID=32089839

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0207835-0A BR0207835A (en) 2001-02-22 2002-02-22 Catalyst system for olefin trimerization and olefin compound trimerization process

Country Status (2)

Country Link
BR (1) BR0207835A (en)
WO (1) WO2002066405A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10145619A1 (en) 2001-09-15 2003-04-10 Basf Ag Process for the trimerization of alpha olefins
ITMI20031738A1 (en) * 2003-09-11 2005-03-12 Polimeri Europa Spa CATALYTIC COMPOSITION FOR THE OLIGOMERIZATION OF ETHYLENE, MONOCYCLOPENTADIENYL COMPLEX COMPOSITION OF TITANIUM.
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
JP5807325B2 (en) 2009-09-30 2015-11-10 住友化学株式会社 Transition metal complex, method for producing the transition metal complex, catalyst for trimerization, method for producing 1-hexene, method for producing ethylene polymer, substituted cyclopentadiene compound, and method for producing the substituted cyclopentadiene compound
JP5900089B2 (en) 2011-03-29 2016-04-06 住友化学株式会社 Transition metal complex, method for producing the transition metal complex, catalyst for trimerization, method for producing 1-hexene, substituted cyclopentadiene compound, and method for producing the substituted cyclopentadiene compound
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2087578C (en) * 1993-01-19 1998-10-27 William Kevin Reagen Preparing catalyst for olefin polymerization
TW307777B (en) * 1993-04-28 1997-06-11 Shell Int Research

Also Published As

Publication number Publication date
WO2002066405A1 (en) 2002-08-29
WO2002066405A8 (en) 2003-10-02

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