WO2002066405A8 - Catalyst system for the trimerisation of olefins - Google Patents

Catalyst system for the trimerisation of olefins

Info

Publication number
WO2002066405A8
WO2002066405A8 PCT/NL2002/000119 NL0200119W WO02066405A8 WO 2002066405 A8 WO2002066405 A8 WO 2002066405A8 NL 0200119 W NL0200119 W NL 0200119W WO 02066405 A8 WO02066405 A8 WO 02066405A8
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst system
olefins
optionally
trimerisation
groups
Prior art date
Application number
PCT/NL2002/000119
Other languages
French (fr)
Other versions
WO2002066405A1 (en
Inventor
Patrick Jozef Wilhelmu Deckers
Bart Hessen
Original Assignee
Stichting Dutch Polymer Inst
Patrick Jozef Wilhelmu Deckers
Bart Hessen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Stichting Dutch Polymer Inst, Patrick Jozef Wilhelmu Deckers, Bart Hessen filed Critical Stichting Dutch Polymer Inst
Priority to AU2002233829A priority Critical patent/AU2002233829A1/en
Priority to DE60228556T priority patent/DE60228556D1/en
Priority to KR10-2003-7010904A priority patent/KR20040002868A/en
Priority to CA002438684A priority patent/CA2438684A1/en
Priority to EP02700895A priority patent/EP1377535B1/en
Priority to BR0207835-0A priority patent/BR0207835A/en
Priority to JP2002565925A priority patent/JP2004524959A/en
Publication of WO2002066405A1 publication Critical patent/WO2002066405A1/en
Priority to US10/645,425 priority patent/US7056995B2/en
Publication of WO2002066405A8 publication Critical patent/WO2002066405A8/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/146—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Abstract

The invention relates to a catalyst system for the selective trimerisation of olefins, which system is based on a titanium complex of formula (Cp-B (R) nAr) TiR13, wherein: Cp is a cyclopentadienyl type ligand, optionally substituted, B is a bridging group, based on a single atom selected from the groups 13 to 16 inclusive of the Periodic System, Ar is a aromatic group, optionally substituted, R is, independently, hydrogen, or a hydrocarbon residue, optionally being substituted and optionally containing heteroatoms, or groups R and B are joined together to from a ring, N is an integer equal to the (valency of B minus 2), and R1 is a mono-anionic group, and further comprises an activator. The present catalyst system obviates the use of toxic chromium compounds.
PCT/NL2002/000119 2001-02-22 2002-02-22 Catalyst system for the trimerisation of olefins WO2002066405A1 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AU2002233829A AU2002233829A1 (en) 2001-02-22 2002-02-22 Catalyst system for the trimerisation of olefins
DE60228556T DE60228556D1 (en) 2001-02-22 2002-02-22 METHOD FOR THE SELECTIVE TRIMERIZATION OF OLEFINES
KR10-2003-7010904A KR20040002868A (en) 2001-02-22 2002-02-22 Catalyst system for the trimerisation of olefins
CA002438684A CA2438684A1 (en) 2001-02-22 2002-02-22 Catalyst system for the trimerisation of olefins
EP02700895A EP1377535B1 (en) 2001-02-22 2002-02-22 Process for selective trimerisation of olefins
BR0207835-0A BR0207835A (en) 2001-02-22 2002-02-22 Catalyst system for olefin trimerization and olefin compound trimerization process
JP2002565925A JP2004524959A (en) 2001-02-22 2002-02-22 Catalyst system for olefin trimerization.
US10/645,425 US7056995B2 (en) 2001-02-22 2003-08-21 Catalyst System for the trimerization of olefins

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NLPCT/NL01/00149 2001-02-22
NL0101149 2001-02-22

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL2001/000149 Continuation-In-Part WO2002066404A1 (en) 2001-02-22 2001-02-22 Catalyst system for the trimerisation of olefins

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/645,425 Continuation-In-Part US7056995B2 (en) 2001-02-22 2003-08-21 Catalyst System for the trimerization of olefins

Publications (2)

Publication Number Publication Date
WO2002066405A1 WO2002066405A1 (en) 2002-08-29
WO2002066405A8 true WO2002066405A8 (en) 2003-10-02

Family

ID=32089839

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NL2002/000119 WO2002066405A1 (en) 2001-02-22 2002-02-22 Catalyst system for the trimerisation of olefins

Country Status (2)

Country Link
BR (1) BR0207835A (en)
WO (1) WO2002066405A1 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10145619A1 (en) 2001-09-15 2003-04-10 Basf Ag Process for the trimerization of alpha olefins
ITMI20031738A1 (en) * 2003-09-11 2005-03-12 Polimeri Europa Spa CATALYTIC COMPOSITION FOR THE OLIGOMERIZATION OF ETHYLENE, MONOCYCLOPENTADIENYL COMPLEX COMPOSITION OF TITANIUM.
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
JP2011099091A (en) 2009-09-30 2011-05-19 Sumitomo Chemical Co Ltd Manufacturing method for ethylenic polymer
JP5900089B2 (en) 2011-03-29 2016-04-06 住友化学株式会社 Transition metal complex, method for producing the transition metal complex, catalyst for trimerization, method for producing 1-hexene, substituted cyclopentadiene compound, and method for producing the substituted cyclopentadiene compound
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2087578C (en) * 1993-01-19 1998-10-27 William Kevin Reagen Preparing catalyst for olefin polymerization
TW307777B (en) * 1993-04-28 1997-06-11 Shell Int Research

Also Published As

Publication number Publication date
WO2002066405A1 (en) 2002-08-29
BR0207835A (en) 2004-06-22

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