BR0010883A - Catalytic esterification compositions that include new compounds of organotitanium, organozirconium or organoaluminium - Google Patents

Catalytic esterification compositions that include new compounds of organotitanium, organozirconium or organoaluminium

Info

Publication number
BR0010883A
BR0010883A BR0010883-9A BR0010883A BR0010883A BR 0010883 A BR0010883 A BR 0010883A BR 0010883 A BR0010883 A BR 0010883A BR 0010883 A BR0010883 A BR 0010883A
Authority
BR
Brazil
Prior art keywords
organotitanium
compositions
organozirconium
organoaluminium
catalytic
Prior art date
Application number
BR0010883-9A
Other languages
Portuguese (pt)
Inventor
Charles Mark Lindall
John Ridland
Neville Slack
Original Assignee
Acma Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Acma Ltd filed Critical Acma Ltd
Publication of BR0010883A publication Critical patent/BR0010883A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0257—Phosphorus acids or phosphorus acid esters
    • B01J31/0258—Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

"COMPOSIçõES CATALìTICAS DE ESTERIFICAçãO QUE ABRANGEM COMPOSTOS NOVOS DE ORGANOTITâNIO, ORGANOZIRCÈNIO OU ORGANOALUMìNIO". Uma composição catalítica adequada para o uso como um catalisador para a preparação de um éster abrange: (a) um composto organometálico que é o produto de reação de um ortoéster ou de um ortoéster condensado de titânio, zircónio ou alumínio, um álcool contendo pelo menos dois grupos de hidroxilas, um composto organofósforo contendo pelo menos um grupo P-OH e, preferivelmente, uma base e (b) um composto de germânio, antimónio ou estanho. Um processo de preparação de um éster abrange realizar uma reação de esterificação na presença de uma composição catalítica. Em uma outra incorporação, o composto organometálico abrange o produto da reação, em adição, a um ácido 2-hidroxicarboxílico."CATALYTIC STERIFICATION COMPOSITIONS COVERING NEW ORGANOTITANIUM, ORGANOZIRCUM OR ORGANO ALUMINUM COMPOUNDS". A catalytic composition suitable for use as a catalyst for the preparation of an ester comprises: (a) an organometallic compound which is the reaction product of an orthoester or a condensed orthoester of titanium, zirconium or aluminum, an alcohol containing at least two hydroxyl groups, an organophosphorus compound containing at least one P-OH group and, preferably, a base and (b) a germanium, antimony or tin compound. An ester preparation process involves performing an esterification reaction in the presence of a catalytic composition. In another embodiment, the organometallic compound comprises the reaction product, in addition, to a 2-hydroxycarboxylic acid.

BR0010883-9A 1999-05-25 2000-05-02 Catalytic esterification compositions that include new compounds of organotitanium, organozirconium or organoaluminium BR0010883A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9912210.3A GB9912210D0 (en) 1999-05-25 1999-05-25 Esterification catalysts
PCT/GB2000/001674 WO2000071252A1 (en) 1999-05-25 2000-05-02 Esterification catalysts

Publications (1)

Publication Number Publication Date
BR0010883A true BR0010883A (en) 2002-02-13

Family

ID=10854167

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0010883-9A BR0010883A (en) 1999-05-25 2000-05-02 Catalytic esterification compositions that include new compounds of organotitanium, organozirconium or organoaluminium

Country Status (14)

Country Link
US (1) US20020087027A1 (en)
EP (1) EP1181096A1 (en)
JP (1) JP2003500492A (en)
KR (1) KR20020010671A (en)
CN (1) CN1129478C (en)
AR (1) AR024070A1 (en)
AU (1) AU4767200A (en)
BR (1) BR0010883A (en)
CO (1) CO5231205A1 (en)
GB (1) GB9912210D0 (en)
MX (1) MXPA01011984A (en)
UY (1) UY26149A1 (en)
WO (1) WO2000071252A1 (en)
ZA (1) ZA200109202B (en)

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US6372879B1 (en) 2000-01-07 2002-04-16 Atofina Chemicals, Inc. Polyester polycondensation with catalyst and a catalyst enhancer
TW546330B (en) * 2000-01-07 2003-08-11 Teijin Ltd Biaxially oriented polyester film for metal sheet laminating molding
GB0002156D0 (en) * 2000-02-01 2000-03-22 Acma Ltd Esterification catalyst compositions
PT1327648E (en) 2000-09-12 2007-08-31 Toyo Boseki Polymerization catalyst for polyester, polyester produced with the same, and process for producing polyester
AU2002216669A1 (en) 2000-11-21 2002-06-03 Honeywell International Inc. Esterification catalyst, polyester process and polyester article
US6914107B2 (en) * 2001-01-24 2005-07-05 E. I. Du Pont De Nemours And Company Catalyst composition and process therewith
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US6489433B2 (en) * 2001-02-23 2002-12-03 E. I. Du Pont De Nemours And Company Metal-containing composition and process therewith
JP4930665B2 (en) * 2001-08-01 2012-05-16 東洋紡績株式会社 Polyester polymerization catalyst and polyester production method (orthoester)
US6723768B2 (en) * 2002-03-27 2004-04-20 Eastman Chemical Company Polyester/polycarbonate blends with reduced yellowness
KR20030084183A (en) * 2002-04-25 2003-11-01 켐엔텍 주식회사 Method for preparing polyester
US6841505B2 (en) 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
US6953768B2 (en) 2002-11-26 2005-10-11 Teck Cominco Metals Ltd. Multi-component catalyst system for the polycondensation manufacture of polyesters
GB0228267D0 (en) 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
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US8557950B2 (en) 2005-06-16 2013-10-15 Grupo Petrotemex, S.A. De C.V. High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates
US7655746B2 (en) 2005-09-16 2010-02-02 Eastman Chemical Company Phosphorus containing compounds for reducing acetaldehyde in polyesters polymers
US8431202B2 (en) 2005-09-16 2013-04-30 Grupo Petrotemex, S.A. De C.V. Aluminum/alkaline or alkali/titanium containing polyesters having improved reheat, color and clarity
US7932345B2 (en) 2005-09-16 2011-04-26 Grupo Petrotemex, S.A. De C.V. Aluminum containing polyester polymers having low acetaldehyde generation rates
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JP2008266359A (en) * 2007-04-16 2008-11-06 Toyobo Co Ltd Polyester polymerization catalyst, polyester manufactured by using the same, and method for manufacturing polyester
US20090286907A1 (en) * 2008-01-23 2009-11-19 Beltz Mark W Fumaric Acid/Diol Polyesters and Their Manufacture and Use
WO2010123087A1 (en) * 2009-04-23 2010-10-28 帝人デュポンフィルム株式会社 Biaxially stretched polyester film for solar battery
CN101962437B (en) * 2009-07-24 2013-04-17 常州化学研究所 Novel aluminum catalyst for use in synthesis of PET by esterification condensation method
TWI423993B (en) * 2011-06-16 2014-01-21 Univ Kaohsiung Medical A method for polyesterification by tin catalysts
US8653224B1 (en) * 2013-02-08 2014-02-18 Lotte Chemical Corporation Resin composition for manufacturing thermoplastic polyester resin by using green catalyst
TWI537304B (en) * 2013-08-06 2016-06-11 Shinkong Synthetic Fibers Corp Preparation of copolyester
CN103435792B (en) * 2013-09-10 2015-05-20 杭州金海湾化工有限公司 Antimony-titanium composition and preparation method and application thereof
JP6866727B2 (en) * 2016-03-31 2021-04-28 荒川化学工業株式会社 Method for producing rosin ester and rosin ester
CN106349062A (en) * 2016-08-30 2017-01-25 深圳市普利凯新材料股份有限公司 Method for synthesizing diethyleneglycol diformate by composite catalyst
CN106975475B (en) * 2017-04-26 2019-12-20 中国石油化工股份有限公司 Catalyst for synthesizing trimethylolpropane ester and preparation method and application thereof
TWI664186B (en) * 2017-10-05 2019-07-01 遠東新世紀股份有限公司 Phosphate ester material and preparation method thereof, polyester resin containing phosphate ester material and preparation method thereof
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Also Published As

Publication number Publication date
JP2003500492A (en) 2003-01-07
UY26149A1 (en) 2001-11-30
WO2000071252A1 (en) 2000-11-30
CN1129478C (en) 2003-12-03
US20020087027A1 (en) 2002-07-04
GB9912210D0 (en) 1999-07-28
CO5231205A1 (en) 2002-12-27
KR20020010671A (en) 2002-02-04
ZA200109202B (en) 2003-04-30
EP1181096A1 (en) 2002-02-27
AU4767200A (en) 2000-12-12
CN1351520A (en) 2002-05-29
AR024070A1 (en) 2002-09-04
MXPA01011984A (en) 2002-05-06

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

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