BG50933A3 - Method for chlorine production - Google Patents
Method for chlorine productionInfo
- Publication number
- BG50933A3 BG50933A3 BG80342A BG8034287A BG50933A3 BG 50933 A3 BG50933 A3 BG 50933A3 BG 80342 A BG80342 A BG 80342A BG 8034287 A BG8034287 A BG 8034287A BG 50933 A3 BG50933 A3 BG 50933A3
- Authority
- BG
- Bulgaria
- Prior art keywords
- hydrogen chloride
- gas
- oxygen
- chlorine
- water
- Prior art date
Links
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000460 chlorine Substances 0.000 title abstract 5
- 229910052801 chlorine Inorganic materials 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 8
- 239000007789 gas Substances 0.000 abstract 7
- 229910000041 hydrogen chloride Inorganic materials 0.000 abstract 7
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 abstract 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 5
- 239000001301 oxygen Substances 0.000 abstract 5
- 229910052760 oxygen Inorganic materials 0.000 abstract 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 235000011149 sulphuric acid Nutrition 0.000 abstract 2
- 239000001117 sulphuric acid Substances 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- 150000001845 chromium compounds Chemical class 0.000 abstract 1
- 229910000423 chromium oxide Inorganic materials 0.000 abstract 1
- 230000006835 compression Effects 0.000 abstract 1
- 238000007906 compression Methods 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
This method is used in the chemical industry, and utilizes the hydrocarbon-containing effluent gases. It ensures a high degree for conversion of hydrogen chloride into chlorine over a long period of time without any large power, or sulphuric acid expenditures, or the need for any organic solvents.Description : the hydrogen chloride is oxidized to chlorine with oxygen, at a correlation of oxygen and hydrogen chloride between 0.5 and 2, temperatures between 300 and 450 degrees C, pressures between 1 and 10 atmospheres, and in the presence of a chromium oxide catalyst. The reactor, in which the hydrogen chloride is oxidized, is prepared from nickel and is coated with nickel. The derived product (as a result of the oxidation gas, containing mainly water, non-reacting hydrogen chloride, oxygen and vapours from chromium compounds), is cooled quickly and then washed in water, during which the chromium is extracted in the liquid phase. The remaining part of the gas is washed again with water to absorb non-reacting hydrogen chloride, and remove it as a hydrochloride. The remaining part of the gas is washed with sulphuric acid to remove water from it. After the dehydration, a part of the derived gas remains, containing mainly chlorine and a non-reacting oxygen, which is subjected to compression and cooling, while the chlorine is liquefied and extracted as a liquid phase from the remaining part of the extracted gas, containing mainly oxygen. Part of this residual part of the gas is recycled to the oxidation stage of the hydrogen chloride.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BG80342A BG50933A3 (en) | 1987-06-29 | 1987-06-29 | Method for chlorine production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BG80342A BG50933A3 (en) | 1987-06-29 | 1987-06-29 | Method for chlorine production |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG50933A3 true BG50933A3 (en) | 1992-12-30 |
Family
ID=3919237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG80342A BG50933A3 (en) | 1987-06-29 | 1987-06-29 | Method for chlorine production |
Country Status (1)
| Country | Link |
|---|---|
| BG (1) | BG50933A3 (en) |
-
1987
- 1987-06-29 BG BG80342A patent/BG50933A3/en unknown
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