BE900759A - PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE. - Google Patents
PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE.Info
- Publication number
- BE900759A BE900759A BE0/213783A BE213783A BE900759A BE 900759 A BE900759 A BE 900759A BE 0/213783 A BE0/213783 A BE 0/213783A BE 213783 A BE213783 A BE 213783A BE 900759 A BE900759 A BE 900759A
- Authority
- BE
- Belgium
- Prior art keywords
- diethylenetriamine
- monoethanolamine
- production
- ammonolysis
- ammonia
- Prior art date
Links
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 title abstract 3
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 title abstract 3
- 238000005915 ammonolysis reaction Methods 0.000 title 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract 2
- 229910021529 ammonia Inorganic materials 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
- B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/09—Diamines
- C07C211/10—Diaminoethanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
L'invention concerne la production de la diéthylènetriamine par la réaction de la monoéthanolamine sur l'ammoniac en présence d'une substance contenant phosphore et éthylènediamine en un rapport molaire de l'ammoniac à la monoéthanolamine élevé. On obtient ainsi de la diéthylènetriamine avec une excellente sélectivité et sans consommation sensible de l'éthylènediamine ajoutée.The invention relates to the production of diethylenetriamine by the reaction of monoethanolamine on ammonia in the presence of a substance containing phosphorus and ethylenediamine in a high molar ratio of ammonia to monoethanolamine. Diethylenetriamine is thus obtained with excellent selectivity and without appreciable consumption of the added ethylenediamine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP58185871A JPS6078945A (en) | 1983-10-06 | 1983-10-06 | Production of diethylenetriamine |
Publications (1)
Publication Number | Publication Date |
---|---|
BE900759A true BE900759A (en) | 1985-02-01 |
Family
ID=16178333
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE0/213783A BE900759A (en) | 1983-10-06 | 1984-10-05 | PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE. |
Country Status (9)
Country | Link |
---|---|
JP (1) | JPS6078945A (en) |
BE (1) | BE900759A (en) |
DE (1) | DE3436036A1 (en) |
FR (1) | FR2553089B1 (en) |
GB (1) | GB2147896B (en) |
IT (1) | IT1176876B (en) |
NL (1) | NL189347C (en) |
SE (1) | SE465125B (en) |
ZA (1) | ZA847588B (en) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4578517A (en) * | 1983-09-16 | 1986-03-25 | Air Products And Chemicals, Inc. | Polyalkylene polyamines from alkanolamine and ammonia or amines using group IIIB metal acid phosphate catalysts |
US4605770A (en) * | 1983-12-22 | 1986-08-12 | Air Products And Chemicals, Inc. | Noncyclic polyalkylene polyamines by the reaction of an alkanolamine compound and an alkyleneamine compound in the presence of a Group IIA or Group IIIB metal acid phosphate catalyst |
JPS6154241A (en) * | 1984-08-21 | 1986-03-18 | シ−ビ−エムエム・インタ−ナシヨナル・リミタ−ダ | Water containing niobium oxide solid acid catalyst |
US4617418A (en) * | 1984-11-26 | 1986-10-14 | Air Products And Chemicals, Inc. | Polyalkylene polyamines via vapor phase reaction |
US5202489A (en) * | 1987-12-22 | 1993-04-13 | Union Carbide Chemicals & Plastics Technology Corporation | Amines catalysis |
JP2764968B2 (en) * | 1988-02-10 | 1998-06-11 | 東ソー株式会社 | Method for producing alkyleneamines |
US4927931A (en) * | 1988-11-01 | 1990-05-22 | The Dow Chemical Company | Preparation of alkyl-extended, alcohol-extended or amine-extended piperazines |
US4973569A (en) * | 1988-11-01 | 1990-11-27 | The Dow Chemical Company | Preparation of group VB metal phosphate catalysts therefor |
US4950690A (en) * | 1988-11-28 | 1990-08-21 | Air Products And Chemicals, Inc. | Process for the animation of alcohols using activated phosphorus-containing catalysts |
US5210307A (en) * | 1988-12-20 | 1993-05-11 | The Dow Chemical Company | Catalytic reforming of alkyleneamines to linearly-extended polyalkylenepolyamines |
US5166442A (en) * | 1988-12-20 | 1992-11-24 | The Dow Chemical Company | Catalytic reforming of alkyleneamines |
US4996363A (en) * | 1988-12-20 | 1991-02-26 | The Dow Chemical Company | Catalytic reforming of alkyleneamines to linearly-extended polyalkylenepolyamines |
US5011999A (en) * | 1989-02-23 | 1991-04-30 | The Dow Chemical Company | Process of preparing non-cyclic polyalkylenepolyamines employing group VB metal catalysts |
JP2764093B2 (en) * | 1989-07-14 | 1998-06-11 | 三井化学株式会社 | Preparation of acyclic ethyleneamines |
JP2764078B2 (en) * | 1989-07-14 | 1998-06-11 | 三井化学株式会社 | Preparation of acyclic ethyleneamines |
US5082972A (en) * | 1989-07-17 | 1992-01-21 | Mitsui Toatsu Chemicals, Inc. | Process for preparation of acyclic ethyleneamines |
JP2938093B2 (en) * | 1989-07-17 | 1999-08-23 | 三井化学株式会社 | Method for producing acyclic ethyleneamines |
JPH0348643A (en) * | 1989-07-18 | 1991-03-01 | Mitsui Toatsu Chem Inc | Production of non-cyclic ethyleneamines |
JP2764094B2 (en) * | 1989-07-18 | 1998-06-11 | 三井化学株式会社 | Preparation of acyclic ethyleneamines |
US5101074A (en) * | 1989-08-08 | 1992-03-31 | Union Carbide Chemicals & Plastics Technology Corporation | Vicinal di(hetro) alkylene organometalates and processes for the production of amines therewith |
US5210306A (en) * | 1989-08-08 | 1993-05-11 | Union Carbide Chemicals & Plastics Technology Corporation | Promoted amines catalysis |
US5202492A (en) * | 1989-08-08 | 1993-04-13 | Union Carbide Chemicals & Plastics Technology Corporation | Amines catalysis using metallic phosphate condensation catalysts having a cyclic structure |
CA2022775C (en) * | 1989-08-08 | 1997-03-04 | Stephen Wayne King | Amines catalysis using group vib metal-containing condensation catalysts |
US4983736A (en) * | 1989-08-08 | 1991-01-08 | Union Carbide Chemicals And Plastic Company Inc. | Amines catalysis using metallic polyphosphate condensation catalysts having a condensed structure |
US5225600A (en) * | 1989-08-08 | 1993-07-06 | Union Carbide Chemicals & Plastics Technology Corporation | Amines catalysis using group VIB metal-containing condensation catalysts |
US5214213A (en) * | 1990-03-30 | 1993-05-25 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of linear tetraethylenepentamine and hydroxyethyldiethylenetriamine |
US5225598A (en) * | 1990-03-30 | 1993-07-06 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of linear pentaethylenehexamine and hydroxyethyldiethylenetriamine |
US5214215A (en) * | 1990-03-30 | 1993-05-25 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of aminoethylethanolamine |
US5231230A (en) * | 1990-03-30 | 1993-07-27 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of diethylenetriamine |
US5220071A (en) * | 1990-03-30 | 1993-06-15 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of pentaethylenehexamine and hydroxyethyltriethylenetetramine |
US5225599A (en) * | 1990-03-30 | 1993-07-06 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of linear triethylenetetramine and aminoethylethanolamine |
US5166415A (en) * | 1990-03-30 | 1992-11-24 | Union Carbide Chemicals & Plastics Technology Corporation | Selective production of diethylenetriamine and aminoethylethanolamine |
US5073635A (en) * | 1990-06-22 | 1991-12-17 | The Dow Chemical Company | Process of preparing linearly-extended polyalkylenepolyamines employing metal silicate catalysts |
DE10335991A1 (en) | 2003-08-01 | 2005-02-24 | Basf Ag | Process for the preparation of ethylene amines |
JP2006342745A (en) * | 2005-06-09 | 2006-12-21 | Nippon Sharyo Seizo Kaisha Ltd | Engine working machine |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1514306A (en) * | 1967-01-11 | 1968-02-23 | P Barnier Ets | Process for obtaining and applications of long chain hydrocarbon polyamine products |
US3869527A (en) * | 1971-08-17 | 1975-03-04 | Leo Ab | Secondary phosphate esters |
GB1424513A (en) * | 1972-06-13 | 1976-02-11 | Ciba Geigy Ag | Organic phosphates |
US4036881A (en) * | 1975-06-02 | 1977-07-19 | Texaco Development Corporation | Preparation of polyalkylene polyamines |
US4324917A (en) * | 1980-08-28 | 1982-04-13 | Texaco Inc. | Preparation of polyalkylene polyamines |
US4394524A (en) * | 1981-08-31 | 1983-07-19 | Air Products And Chemicals, Inc. | Preparation of polyalkylene polyamines from ammonia, alkyleneamine, and alkanolamine |
CA1202328A (en) * | 1981-09-30 | 1986-03-25 | William B. Herdle | Preparation of polyalkylene polyamines |
US4463193A (en) * | 1983-07-19 | 1984-07-31 | Air Products And Chemicals, Inc. | Production of noncyclic polyalkylene polyamines |
JPH05232283A (en) * | 1992-02-26 | 1993-09-07 | Toshiba Corp | Measuring equipment of radioactive substance released on accident of nuclear power plant |
KR930020867A (en) * | 1992-03-02 | 1993-10-20 | 빈센트 비.인그라시아 | Remote Sensing Units and Drivers |
-
1983
- 1983-10-06 JP JP58185871A patent/JPS6078945A/en active Granted
-
1984
- 1984-09-26 ZA ZA847588A patent/ZA847588B/en unknown
- 1984-10-02 SE SE8404920A patent/SE465125B/en not_active IP Right Cessation
- 1984-10-02 DE DE19843436036 patent/DE3436036A1/en active Granted
- 1984-10-03 NL NLAANVRAGE8403008,A patent/NL189347C/en not_active IP Right Cessation
- 1984-10-05 BE BE0/213783A patent/BE900759A/en not_active IP Right Cessation
- 1984-10-05 GB GB08425228A patent/GB2147896B/en not_active Expired
- 1984-10-05 FR FR8415322A patent/FR2553089B1/en not_active Expired
- 1984-10-05 IT IT23028/84A patent/IT1176876B/en active
Also Published As
Publication number | Publication date |
---|---|
SE8404920L (en) | 1985-04-07 |
NL189347B (en) | 1992-10-16 |
FR2553089A1 (en) | 1985-04-12 |
FR2553089B1 (en) | 1988-09-23 |
NL189347C (en) | 1993-03-16 |
JPS6078945A (en) | 1985-05-04 |
JPH0445505B2 (en) | 1992-07-27 |
SE8404920D0 (en) | 1984-10-02 |
IT1176876B (en) | 1987-08-18 |
GB2147896B (en) | 1987-04-08 |
SE465125B (en) | 1991-07-29 |
DE3436036A1 (en) | 1985-05-02 |
NL8403008A (en) | 1985-05-01 |
GB8425228D0 (en) | 1984-11-14 |
ZA847588B (en) | 1985-06-26 |
IT8423028A0 (en) | 1984-10-05 |
DE3436036C2 (en) | 1989-11-09 |
GB2147896A (en) | 1985-05-22 |
IT8423028A1 (en) | 1986-04-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
BE900759A (en) | PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE. | |
ES8706443A1 (en) | Acidic formulations of t-PA | |
ES2054198T3 (en) | PREPARATION OF 4,6-DINITRO-2-HALO-1,3-BENZENODIOL. | |
DE3586114D1 (en) | SYNTHESIS OF AMMONIAK. | |
RO92320B (en) | Process for preparing optically active carnitine nitrile chloride | |
ES8701737A1 (en) | Substituted quinazolinediones. | |
ATE23339T1 (en) | 6-( (CYCLIC AMINO) ALKYLAMINO )TETRAHYDROTRIAZOLO(3,4-A)PHTALAZINES | |
DE3685263D1 (en) | BIOLOGICALLY ACTIVE FLUORESCENT CYCLIC NUCLEOTIDES. | |
ES547124A0 (en) | PROCEDURE FOR HYDRATING NITRILE COMPOUNDS | |
IL84051A0 (en) | 7-((meta-substituted)phenylglycine)1-carba-1-dethiacephalosporins | |
TR21929A (en) | NOTROMETHED TUEREVI IN PESTICID FEATURE | |
FI834045A0 (en) | ISOKINOLINFOERENING | |
DE3665188D1 (en) | Finishing-gold composition | |
ZA87777B (en) | Production of cyanide hydratase | |
IL78156A0 (en) | Production of guanidines such as linogliride | |
NO870899L (en) | SUBSTITUTED 2,3-Naphthalenedicarboxaldehyde. | |
GB1501540A (en) | Process for the manufacture of bis-(2-cyanoethyl)-amine | |
MY101613A (en) | Diabrotica larvicidal agents | |
ES8506737A1 (en) | Phthalimido-methyl-di:methyl-di:thiophosphate | |
SU1100879A1 (en) | CHLORINE N- (Y-CHLORINE) ALKYLALLYLHEXAMETHYLENETHRAMINE AS BACTERICIDES TO SUPPRESS THE GROWTH OF SULFATER RESTORING BACTERIA | |
KR850001662A (en) | Plant Normal Growth Stock | |
SU997415A1 (en) | 1,3-Dimethyl-6-hydrazinouracil hydrazones exhibiting analgesic activity | |
SU1241748A1 (en) | Well-drilling filter | |
MA20140A1 (en) | A VARIETY OF ROSIER "CAROL JEAN", MINIATURE WITH FLOWERS | |
SU1394659A1 (en) | STABILIZER OF CHLORINE-CONTAINING HYDROCARBONS |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
RE | Patent lapsed |
Owner name: MITSUI TOATSU CHEMICALS INC. Effective date: 19951031 |