BE900759A - PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE. - Google Patents

PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE.

Info

Publication number
BE900759A
BE900759A BE0/213783A BE213783A BE900759A BE 900759 A BE900759 A BE 900759A BE 0/213783 A BE0/213783 A BE 0/213783A BE 213783 A BE213783 A BE 213783A BE 900759 A BE900759 A BE 900759A
Authority
BE
Belgium
Prior art keywords
diethylenetriamine
monoethanolamine
production
ammonolysis
ammonia
Prior art date
Application number
BE0/213783A
Other languages
French (fr)
Original Assignee
Mitsui Toatsu Chemicals
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsui Toatsu Chemicals filed Critical Mitsui Toatsu Chemicals
Publication of BE900759A publication Critical patent/BE900759A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B01J27/18—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr with metals other than Al or Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
    • C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • C07C211/09—Diamines
    • C07C211/10—Diaminoethanes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne la production de la diéthylènetriamine par la réaction de la monoéthanolamine sur l'ammoniac en présence d'une substance contenant phosphore et éthylènediamine en un rapport molaire de l'ammoniac à la monoéthanolamine élevé. On obtient ainsi de la diéthylènetriamine avec une excellente sélectivité et sans consommation sensible de l'éthylènediamine ajoutée.The invention relates to the production of diethylenetriamine by the reaction of monoethanolamine on ammonia in the presence of a substance containing phosphorus and ethylenediamine in a high molar ratio of ammonia to monoethanolamine. Diethylenetriamine is thus obtained with excellent selectivity and without appreciable consumption of the added ethylenediamine.

BE0/213783A 1983-10-06 1984-10-05 PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE. BE900759A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58185871A JPS6078945A (en) 1983-10-06 1983-10-06 Production of diethylenetriamine

Publications (1)

Publication Number Publication Date
BE900759A true BE900759A (en) 1985-02-01

Family

ID=16178333

Family Applications (1)

Application Number Title Priority Date Filing Date
BE0/213783A BE900759A (en) 1983-10-06 1984-10-05 PRODUCTION OF DIETHYLENETRIAMINE BY AMMONOLYSIS OF MONOETHANOLAMINE.

Country Status (9)

Country Link
JP (1) JPS6078945A (en)
BE (1) BE900759A (en)
DE (1) DE3436036A1 (en)
FR (1) FR2553089B1 (en)
GB (1) GB2147896B (en)
IT (1) IT1176876B (en)
NL (1) NL189347C (en)
SE (1) SE465125B (en)
ZA (1) ZA847588B (en)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4578517A (en) * 1983-09-16 1986-03-25 Air Products And Chemicals, Inc. Polyalkylene polyamines from alkanolamine and ammonia or amines using group IIIB metal acid phosphate catalysts
US4605770A (en) * 1983-12-22 1986-08-12 Air Products And Chemicals, Inc. Noncyclic polyalkylene polyamines by the reaction of an alkanolamine compound and an alkyleneamine compound in the presence of a Group IIA or Group IIIB metal acid phosphate catalyst
JPS6154241A (en) * 1984-08-21 1986-03-18 シ−ビ−エムエム・インタ−ナシヨナル・リミタ−ダ Water containing niobium oxide solid acid catalyst
US4617418A (en) * 1984-11-26 1986-10-14 Air Products And Chemicals, Inc. Polyalkylene polyamines via vapor phase reaction
US5202489A (en) * 1987-12-22 1993-04-13 Union Carbide Chemicals & Plastics Technology Corporation Amines catalysis
JP2764968B2 (en) * 1988-02-10 1998-06-11 東ソー株式会社 Method for producing alkyleneamines
US4927931A (en) * 1988-11-01 1990-05-22 The Dow Chemical Company Preparation of alkyl-extended, alcohol-extended or amine-extended piperazines
US4973569A (en) * 1988-11-01 1990-11-27 The Dow Chemical Company Preparation of group VB metal phosphate catalysts therefor
US4950690A (en) * 1988-11-28 1990-08-21 Air Products And Chemicals, Inc. Process for the animation of alcohols using activated phosphorus-containing catalysts
US5210307A (en) * 1988-12-20 1993-05-11 The Dow Chemical Company Catalytic reforming of alkyleneamines to linearly-extended polyalkylenepolyamines
US5166442A (en) * 1988-12-20 1992-11-24 The Dow Chemical Company Catalytic reforming of alkyleneamines
US4996363A (en) * 1988-12-20 1991-02-26 The Dow Chemical Company Catalytic reforming of alkyleneamines to linearly-extended polyalkylenepolyamines
US5011999A (en) * 1989-02-23 1991-04-30 The Dow Chemical Company Process of preparing non-cyclic polyalkylenepolyamines employing group VB metal catalysts
JP2764093B2 (en) * 1989-07-14 1998-06-11 三井化学株式会社 Preparation of acyclic ethyleneamines
JP2764078B2 (en) * 1989-07-14 1998-06-11 三井化学株式会社 Preparation of acyclic ethyleneamines
US5082972A (en) * 1989-07-17 1992-01-21 Mitsui Toatsu Chemicals, Inc. Process for preparation of acyclic ethyleneamines
JP2938093B2 (en) * 1989-07-17 1999-08-23 三井化学株式会社 Method for producing acyclic ethyleneamines
JPH0348643A (en) * 1989-07-18 1991-03-01 Mitsui Toatsu Chem Inc Production of non-cyclic ethyleneamines
JP2764094B2 (en) * 1989-07-18 1998-06-11 三井化学株式会社 Preparation of acyclic ethyleneamines
US5101074A (en) * 1989-08-08 1992-03-31 Union Carbide Chemicals & Plastics Technology Corporation Vicinal di(hetro) alkylene organometalates and processes for the production of amines therewith
US5210306A (en) * 1989-08-08 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Promoted amines catalysis
US5202492A (en) * 1989-08-08 1993-04-13 Union Carbide Chemicals & Plastics Technology Corporation Amines catalysis using metallic phosphate condensation catalysts having a cyclic structure
CA2022775C (en) * 1989-08-08 1997-03-04 Stephen Wayne King Amines catalysis using group vib metal-containing condensation catalysts
US4983736A (en) * 1989-08-08 1991-01-08 Union Carbide Chemicals And Plastic Company Inc. Amines catalysis using metallic polyphosphate condensation catalysts having a condensed structure
US5225600A (en) * 1989-08-08 1993-07-06 Union Carbide Chemicals & Plastics Technology Corporation Amines catalysis using group VIB metal-containing condensation catalysts
US5214213A (en) * 1990-03-30 1993-05-25 Union Carbide Chemicals & Plastics Technology Corporation Selective production of linear tetraethylenepentamine and hydroxyethyldiethylenetriamine
US5225598A (en) * 1990-03-30 1993-07-06 Union Carbide Chemicals & Plastics Technology Corporation Selective production of linear pentaethylenehexamine and hydroxyethyldiethylenetriamine
US5214215A (en) * 1990-03-30 1993-05-25 Union Carbide Chemicals & Plastics Technology Corporation Selective production of aminoethylethanolamine
US5231230A (en) * 1990-03-30 1993-07-27 Union Carbide Chemicals & Plastics Technology Corporation Selective production of diethylenetriamine
US5220071A (en) * 1990-03-30 1993-06-15 Union Carbide Chemicals & Plastics Technology Corporation Selective production of pentaethylenehexamine and hydroxyethyltriethylenetetramine
US5225599A (en) * 1990-03-30 1993-07-06 Union Carbide Chemicals & Plastics Technology Corporation Selective production of linear triethylenetetramine and aminoethylethanolamine
US5166415A (en) * 1990-03-30 1992-11-24 Union Carbide Chemicals & Plastics Technology Corporation Selective production of diethylenetriamine and aminoethylethanolamine
US5073635A (en) * 1990-06-22 1991-12-17 The Dow Chemical Company Process of preparing linearly-extended polyalkylenepolyamines employing metal silicate catalysts
DE10335991A1 (en) 2003-08-01 2005-02-24 Basf Ag Process for the preparation of ethylene amines
JP2006342745A (en) * 2005-06-09 2006-12-21 Nippon Sharyo Seizo Kaisha Ltd Engine working machine

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1514306A (en) * 1967-01-11 1968-02-23 P Barnier Ets Process for obtaining and applications of long chain hydrocarbon polyamine products
US3869527A (en) * 1971-08-17 1975-03-04 Leo Ab Secondary phosphate esters
GB1424513A (en) * 1972-06-13 1976-02-11 Ciba Geigy Ag Organic phosphates
US4036881A (en) * 1975-06-02 1977-07-19 Texaco Development Corporation Preparation of polyalkylene polyamines
US4324917A (en) * 1980-08-28 1982-04-13 Texaco Inc. Preparation of polyalkylene polyamines
US4394524A (en) * 1981-08-31 1983-07-19 Air Products And Chemicals, Inc. Preparation of polyalkylene polyamines from ammonia, alkyleneamine, and alkanolamine
CA1202328A (en) * 1981-09-30 1986-03-25 William B. Herdle Preparation of polyalkylene polyamines
US4463193A (en) * 1983-07-19 1984-07-31 Air Products And Chemicals, Inc. Production of noncyclic polyalkylene polyamines
JPH05232283A (en) * 1992-02-26 1993-09-07 Toshiba Corp Measuring equipment of radioactive substance released on accident of nuclear power plant
KR930020867A (en) * 1992-03-02 1993-10-20 빈센트 비.인그라시아 Remote Sensing Units and Drivers

Also Published As

Publication number Publication date
SE8404920L (en) 1985-04-07
NL189347B (en) 1992-10-16
FR2553089A1 (en) 1985-04-12
FR2553089B1 (en) 1988-09-23
NL189347C (en) 1993-03-16
JPS6078945A (en) 1985-05-04
JPH0445505B2 (en) 1992-07-27
SE8404920D0 (en) 1984-10-02
IT1176876B (en) 1987-08-18
GB2147896B (en) 1987-04-08
SE465125B (en) 1991-07-29
DE3436036A1 (en) 1985-05-02
NL8403008A (en) 1985-05-01
GB8425228D0 (en) 1984-11-14
ZA847588B (en) 1985-06-26
IT8423028A0 (en) 1984-10-05
DE3436036C2 (en) 1989-11-09
GB2147896A (en) 1985-05-22
IT8423028A1 (en) 1986-04-05

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Legal Events

Date Code Title Description
RE Patent lapsed

Owner name: MITSUI TOATSU CHEMICALS INC.

Effective date: 19951031