BE817439A - Selective polymn of norbornene at the double bond - using catalyst contg. titanium salt and organo aluminium cpd - Google Patents
Selective polymn of norbornene at the double bond - using catalyst contg. titanium salt and organo aluminium cpdInfo
- Publication number
- BE817439A BE817439A BE146377A BE146377A BE817439A BE 817439 A BE817439 A BE 817439A BE 146377 A BE146377 A BE 146377A BE 146377 A BE146377 A BE 146377A BE 817439 A BE817439 A BE 817439A
- Authority
- BE
- Belgium
- Prior art keywords
- norbornene
- double bond
- polymn
- selective
- titanium salt
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
Abstract
Norbornene is selectively (co)polymerised at the double bond using a catalyst system comprising (i) a Ti cpd. TiX4-n(OR)n or TiX3 where X = halogen, R =(cyclo) alkyl, aryl, alkylaryl or arylalkyl and n = 0-4 and (ii) organoaluminium cpds. AlR'3-mX'm where X' = halogen or ligand (OR), R' = H (cyclo)alkyl or arylalkyl and m = 1 or 2. Product is a polymer with low double bond content with improved resistance to heat and oxidation. In an example 2.5 moles norbornene were polymerised for 60 mins. at 50 degrees C with 50 mmol TiCl4 and 100 mmol Al(Et)2Cl in n-heptane to a total volume of 1 l, to yield 190 g polynorbornene with a melting range of 280-290 degrees C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DD17241973A DD109224A1 (en) | 1973-07-10 | 1973-07-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
BE817439A true BE817439A (en) | 1974-11-04 |
Family
ID=5492153
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE146377A BE817439A (en) | 1973-07-10 | 1974-07-09 | Selective polymn of norbornene at the double bond - using catalyst contg. titanium salt and organo aluminium cpd |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE817439A (en) |
CS (1) | CS183000B1 (en) |
DD (1) | DD109224A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5629398A (en) † | 1990-10-05 | 1997-05-13 | Idemitsu Kosan Co., Ltd. | Process for producing cyclic olefin based polymers, cyclic olefin copolymers, compositions and molded articles comprising the copolymers |
ES2397870T3 (en) | 2006-10-05 | 2013-03-12 | Treofan Germany Gmbh & Co. Kg | Opaque film made of PLA simultaneously stretched |
DE102007055491A1 (en) | 2007-11-21 | 2009-06-04 | Mitsubishi Polyester Film Gmbh | Low-density polyester film for polar substrates |
EP2598330A1 (en) | 2010-07-27 | 2013-06-05 | Exxonmobil Oil Corporation | Film composition and method of making the same |
-
1973
- 1973-07-10 DD DD17241973A patent/DD109224A1/xx unknown
-
1974
- 1974-07-09 BE BE146377A patent/BE817439A/en unknown
- 1974-07-10 CS CS62177A patent/CS183000B1/en unknown
Also Published As
Publication number | Publication date |
---|---|
CS183000B1 (en) | 1978-05-31 |
DD109224A1 (en) | 1974-10-20 |
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