BE765064A - Silicone resin prepn - using primary and tertiary aliphatic alcohol coreactants - Google Patents
Silicone resin prepn - using primary and tertiary aliphatic alcohol coreactantsInfo
- Publication number
- BE765064A BE765064A BE765064A BE765064A BE765064A BE 765064 A BE765064 A BE 765064A BE 765064 A BE765064 A BE 765064A BE 765064 A BE765064 A BE 765064A BE 765064 A BE765064 A BE 765064A
- Authority
- BE
- Belgium
- Prior art keywords
- mole
- coreactants
- prepn
- primary
- silicone resin
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/06—Preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/18—Polysiloxanes containing silicon bound to oxygen-containing groups to alkoxy or aryloxy groups
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Silicon Polymers (AREA)
Abstract
The resin is prepared by reaction of a mixture of halogenosilanes with a mixture of (a) t-aliphatic (4 - 8C) alcohols and (b) pri. or sec. aliphatic (1-8C pref. 1 - 4C) alcohols in amounts of 0.4 - 0.6 mole (a) per mole halogen atom linked to Si and 0.5 - 1 mole (b) per mole (a), at 10 - 90 degrees C (pref. 20 - 40 degrees C) followed by condensation. It has a proportion of R groups/Si groups of 0.95 - 1.5 where R is methyl and/or phenyl (replaceable by up to 20 mole% vinyl) and Si valencies are saturated by O and alkoxy groups (present as 0.75 mole alkoxy/100 g). The resin has excellent long term heat resistance and is prepared in good yield with hig reproducibility.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19702020244 DE2020244A1 (en) | 1969-04-29 | 1970-04-25 | Agricultural machinery, especially combine harvesters |
Publications (1)
Publication Number | Publication Date |
---|---|
BE765064A true BE765064A (en) | 1971-08-16 |
Family
ID=5769335
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE765064A BE765064A (en) | 1970-04-25 | 1971-03-31 | Silicone resin prepn - using primary and tertiary aliphatic alcohol coreactants |
Country Status (1)
Country | Link |
---|---|
BE (1) | BE765064A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4996174A (en) * | 1986-03-27 | 1991-02-26 | Imperial Chemical Industries Plc | Production of ceramic materials |
-
1971
- 1971-03-31 BE BE765064A patent/BE765064A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4996174A (en) * | 1986-03-27 | 1991-02-26 | Imperial Chemical Industries Plc | Production of ceramic materials |
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