BE760222A - Reduction of residual monomer in poly- - styrene - Google Patents

Reduction of residual monomer in poly- - styrene

Info

Publication number
BE760222A
BE760222A BE760222A BE760222A BE760222A BE 760222 A BE760222 A BE 760222A BE 760222 A BE760222 A BE 760222A BE 760222 A BE760222 A BE 760222A BE 760222 A BE760222 A BE 760222A
Authority
BE
Belgium
Prior art keywords
pref
styrene
reduction
residual monomer
poly
Prior art date
Application number
BE760222A
Other languages
French (fr)
Inventor
L R Davis
J B Kubec
P Shapras Ett Shusman
P Shapras
T Shusman
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of BE760222A publication Critical patent/BE760222A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Reduction of residual monomer in polymerisation of ethylenically unsaturated aromatic compounds (I) is attained by incorporation of 0.1-0.6 pts. of an aliphatic acid (II) per 100 pts. of I. Pref. (II) is 12-22C aliphatic acid. Concn. of ferrous or ferric salts of C1-22 aliphatic acids is (II) is determined and opt. adjusted to >=0.1 wt.% of salt (based on (II)). (I) is pref. styrene, (II) is pref. stearic acid and the salt is pref. ferric or ferrous stearate and is 0.1-5.0 wt.% (on (II)). The presence of small amounts of an iron salts of (II) reduces monomer content and polymerisation time.
BE760222A 1969-12-12 1970-12-11 Reduction of residual monomer in poly- - styrene BE760222A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US88469069A 1969-12-12 1969-12-12

Publications (1)

Publication Number Publication Date
BE760222A true BE760222A (en) 1971-06-11

Family

ID=25385153

Family Applications (1)

Application Number Title Priority Date Filing Date
BE760222A BE760222A (en) 1969-12-12 1970-12-11 Reduction of residual monomer in poly- - styrene

Country Status (1)

Country Link
BE (1) BE760222A (en)

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