BE548857A - - Google Patents
Info
- Publication number
- BE548857A BE548857A BE548857DA BE548857A BE 548857 A BE548857 A BE 548857A BE 548857D A BE548857D A BE 548857DA BE 548857 A BE548857 A BE 548857A
- Authority
- BE
- Belgium
- Prior art keywords
- product
- salts
- product contains
- ammonium
- desc
- Prior art date
Links
- 240000001016 Solanum tuberosum Species 0.000 claims description 9
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 9
- 239000011780 sodium chloride Substances 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 240000000218 Cannabis sativa Species 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 230000002363 herbicidal Effects 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- SUZRRICLUFMAQD-UHFFFAOYSA-N 2-(methylamino)ethanesulfonic acid Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims description 2
- YNJBWRMUSHSURL-UHFFFAOYSA-N Trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 claims description 2
- 239000000853 adhesive Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000004009 herbicide Substances 0.000 claims description 2
- 229920005610 lignin Polymers 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 229960004319 Trichloroacetic Acid Drugs 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 150000004982 aromatic amines Chemical class 0.000 claims 1
- 241000894007 species Species 0.000 claims 1
- 150000003460 sulfonic acids Chemical class 0.000 claims 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 238000003306 harvesting Methods 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 235000012015 potatoes Nutrition 0.000 description 3
- 239000000080 wetting agent Substances 0.000 description 3
- GWGZFNRFNIXCGH-UHFFFAOYSA-N 4-Nitro-2-(trifluoromethyl)benzenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1C(F)(F)F GWGZFNRFNIXCGH-UHFFFAOYSA-N 0.000 description 2
- FDRCDNZGSXJAFP-UHFFFAOYSA-M Sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 2
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Chemical compound NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-M naphthalene-1-sulfonate Chemical compound C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000001187 sodium carbonate Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZOQOPXVJANRGJZ-UHFFFAOYSA-N 2-(trifluoromethyl)phenol Chemical class OC1=CC=CC=C1C(F)(F)F ZOQOPXVJANRGJZ-UHFFFAOYSA-N 0.000 description 1
- -1 3-Trifluormethyl-1-nitro-phenol Chemical compound 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N Oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- SAQSTQBVENFSKT-UHFFFAOYSA-M TCA-sodium Chemical compound [Na+].[O-]C(=O)C(Cl)(Cl)Cl SAQSTQBVENFSKT-UHFFFAOYSA-M 0.000 description 1
- 229960003080 Taurine Drugs 0.000 description 1
- 241000625014 Vir Species 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 230000004520 agglutination Effects 0.000 description 1
- 230000024126 agglutination involved in conjugation with cellular fusion Effects 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 201000009910 diseases by infectious agent Diseases 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 230000003000 nontoxic Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000002522 swelling Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000014599 transmission of virus Effects 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
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Lors de la culture des pommes de terre, particulièrement de la grande culture, il y a avantage à détruire l'herbe de pommes de terre avant la récolte pour faciliter celle-ci et pour empêcher la transmission de viroses et de Phytophtora infestans aux tuber- cules, Un autre avantage réside, par exemple, dans la possibilité de rentrer les pommes de terre le plus tôt possible et d'empêcher la production de tubercules trop, grands dans le cas de pommes de terre de semence. Depuis quelques années, on a remplacé l'enlèvement
<Desc/Clms Page number 2>
manuel de l'herbe de pommes de terre par l'extermination par pro- jection d'agents chimuiques On pouvait ainsi économiser énormé- ment de main-d'oeuvre. On a appliqué en général dans ce but des produits qui ne sont pas tout à fait sans danger pour les êtres à sang chaud..
.Or, la demanderesse a découvert que l'on pouvait obtenir le même effet par appliaction d'un mélange presque non toxique pour les êtres à sang chaud, qui est composé de sels des acides mono- et que et qui contient une proportion prépon- dérante du premier acide.. On mentionnera particulièrement les sels des métaux alcalins et alcalino-terreux, de magnésium, de nickel, de cuivrf- et d'ammoniac ainsi que les sels avec des bases organiques inférieures.
L'effet des sels des acides mono- et trichloracétique, qui est déjà bonnes! encore augmenté par addition de trifluor- méthylphénols qui sont avantageusement substitués par un groupe nitré. Il s'est révélé particulièrement avantageux d'utiliser le 2-trifluorméthyl-4-nitrophénol ou le 3-trifluométhyl-1-4-ni trophénol ainsi que les sels avec des métaux mono- ou bivalents, de l'ammoniac, des xxxx amines aliphatiques et aromatiques. Ces dérivés de phénol se comportent envers'les êtres à sang chaud d'une manière considérablement moins toxique que les produits utilisés habituellement pour l'extermination par projection de l'herbe de pommes de terre. On diminue la toxicité encore davan- tage en incorporant les phénols en pourcentages relativement mini- mes dans le produit suivant la présente invention.
Il faut que la destruction de l'herbe de pommes de terre soit terminée en un temps aussi court que possible afin que l'on puisse exécuter le traitement relativement tard et combiner l'a- vantage d'une récolte hâti ve (par exemple l'empêchement d'une infection du tubercule par des vires ou la Phytophtora) avec ce- lui d'un mûrissage intense des tubercules. Cette exigence est réalisée de la manière la plus perfe tionnée par les produits
<Desc/Clms Page number 3>
EMI3.1
contenant du phénol, du fait, que 1(38 Lri±luormélJliyl-n1l3rophénoli montrent un effet herbicide extraordinairement rapide.
On exige d'un agent, d'arrosage soluble dans l'eau qu'il se dissolve rapidement et sans laisser un résidu. On peut attein- des .ce but par addition d'amidosulfonate d'ammonium en combinai-
EMI3.2
son avec les di.spersifs et mouillants usuels. L'amidosulfonate' d'ammonium non seulement facilite et accélère la solubilité des phénols et leurs sels mais favorise aussi à son tour, p; . son caractère herbicide, la destruction de l'herbe de pommes de ter- re. Comme dispersifs, on utilise avec avantage les oléylamides de méthyltaurine et les suif ouates de lignine. Pour augmenter l'effet mouillant, il y a avantage à utiliser des mouillants ionogènes pulvérulents, tels que les sulfonates d'alcoyl-naphta- lène.
Des mouillants non-ionogènes et liquides sont moins appro- priés, car ils favorisent une agglutination des mélanges,
On peut encore améliorer le pouvoir adhésif par addi- tion de substances gonflantes et de résines solubles dans l'eau telles que la carboxyméthyl-cellulose ou l'alcool polyvinylique.
On peut aussi utiliser les produits suivant la présente invention pour l'extermination des mauvaises herbes. Les agents, préférablement ceux qui contiennent des trifluorméthyl-nitrophé- nols, peuvent être appliqués avec avantage somme herbicides totaux dans les cas où il s'agit d'obtenir un effet rapide.
EXEMPLE 1
EMI3.3
3-Trifluorméthyl-l-nitro-phénol 10% monochlorracétate de sodium 70/j amidosulfonate d'ammonium 10% carbonate- de sodium, .cale.. 4%
EMI3.4
"'Carboxyméthylcelluloc9 -,0-léylamide de taurine 2 sulfonate de 'sodium d'alcoyl-naphtalène 2%
EMI3.5
La quantité utilisée s'61ève,â 10 - ;1O k;/ha, dissoute dans la quantité usuelle d'eau
<Desc/Clms Page number 4>
EXEMPLE 2
EMI4.1
-Trifluorntcthyl-4-nitro-phénol 1G, - mono chloracétate de sodium 50% trichloracétate de sodium 15%
EMI4.2
, ru.1idosulfonate d'ammonium lÔ5; carbonate de sodium, calc. 3i; carboxymétl1ylcellulose 2;. oléylamide de taurine 2% sulfonate de sodium d'alcoyl-naphtalène 2% La quantité utilisée s'élève aussi à 10 - 20 kg/ha .
EXEMPLE
EMI4.3
2-Trifluorméthyl-4-nitro-phénol, sel d'ammonium 20% monochloracétate de sodium 52% amidosulfonate d'ammonium 15% carboxyméthylcellulose 3% sulfonate d'ammonium de lignine 8% sulfonate de sodium d'alcoyl-naphtalène 2% La quantité utilisée s'élève à 8 15 kg/ha.
EXEMPLE 4
Monochloracétate de sodium 70,05
EMI4.4
trichloranétate de sodium 28 e 5cli alcool polyvinylique 0.5% sulfonate de sodium d'alcoyl-naphtalène 1,0% La quantité utilisée s'élève à 30 - 50 kg/ha.
<Desc / Clms Page number 1>
When growing potatoes, especially field crops, it is advantageous to destroy the potato grass before harvesting to facilitate harvesting and to prevent the transmission of viruses and Phytophtora infestans to tuber- Another advantage lies, for example, in the possibility of bringing in the potatoes as early as possible and preventing the production of too large tubers in the case of seed potatoes. In recent years, we replaced the kidnapping
<Desc / Clms Page number 2>
Manual of potato grass by chemical spray extermination This could save a lot of manpower. In general, products have been applied for this purpose which are not entirely safe for warm-blooded beings.
However, the Applicant has discovered that the same effect could be obtained by applying a mixture which is almost non-toxic to warm-blooded beings, which is composed of salts of mono- acids and which and which contains a prepon- derivative of the first acid. Particular mention will be made of the salts of the alkali and alkaline earth metals, of magnesium, of nickel, of copper and of ammonia, as well as the salts with lower organic bases.
The effect of salts of mono- and trichloroacetic acids, which is already good! further increased by addition of trifluoromethylphenols which are advantageously substituted by a nitro group. It has been found to be particularly advantageous to use 2-trifluormethyl-4-nitrophenol or 3-trifluomethyl-1-4-ni trophenol as well as salts with mono- or bivalent metals, ammonia, xxxx amines aliphatic and aromatic. These phenol derivatives behave towards warm-blooded beings in a considerably less toxic manner than the products usually used for the extermination of potato grass by blasting. The toxicity is further reduced by incorporating the phenols in relatively small percentages into the product of the present invention.
The destruction of the potato grass should be completed in as short a time as possible so that the treatment can be carried out relatively late and combine the advantage of an early harvest (eg. (prevention of infection of the tuber by vires or Phytophthora) with that of intense ripening of the tubers. This requirement is fulfilled in the most perfected manner by the products
<Desc / Clms Page number 3>
EMI3.1
containing phenol, because 1 (38 Lri ± luormélJliyl-n1l3rophenoli show an extraordinarily rapid herbicidal effect.
A water soluble sprinkler agent is required to dissolve quickly and without leaving a residue. This can be achieved by the addition of ammonium amidosulfonate in combination.
EMI3.2
sound with the usual mixtures and wetting agents. Ammonium amidosulfonate not only facilitates and accelerates the solubility of phenols and their salts but also in turn promotes, p; . its herbicidal character, the destruction of potato grass. As dispersants, methyltaurine oleylamides and lignin tallow wadding are advantageously used. To increase the wetting effect, it is advantageous to use powdered ionogenic wetting agents, such as alkyl-naphthalene sulfonates.
Non-ionogenic and liquid wetting agents are less suitable, as they promote agglutination of the mixtures,
The adhesive power can be further improved by the addition of swelling substances and water soluble resins such as carboxymethyl cellulose or polyvinyl alcohol.
The products according to the present invention can also be used for the extermination of weeds. The agents, preferably those which contain trifluormethyl-nitrophenols, can be applied with advantage as total herbicides in cases where a rapid effect is to be obtained.
EXAMPLE 1
EMI3.3
3-Trifluormethyl-1-nitro-phenol 10% sodium monochlorracetate 70 / d ammonium amidosulfonate 10% sodium carbonate, .cale .. 4%
EMI3.4
"'Carboxymethylcelluloc9 -, 0-taurine-leylamide 2 sodium alkyl-naphthalene sulfonate 2%
EMI3.5
The quantity used increases to 10 - 10 k / ha, dissolved in the usual quantity of water.
<Desc / Clms Page number 4>
EXAMPLE 2
EMI4.1
-Trifluorntcthyl-4-nitro-phenol 1G, - sodium mono chloroacetate 50% sodium trichloroacetate 15%
EMI4.2
, ru.15 ammonium idosulfonate; sodium carbonate, calc. 3i; carboxymethylcellulose 2 ;. taurine oleylamide 2% sodium alkyl naphthalene sulfonate 2% The amount used is also 10 - 20 kg / ha.
EXAMPLE
EMI4.3
2-Trifluormethyl-4-nitro-phenol, ammonium salt 20% sodium monochloroacetate 52% ammonium amidosulfonate 15% carboxymethylcellulose 3% ammonium lignin sulfonate 8% sodium alkyl-naphthalene sulfonate 2% The quantity used is 8 15 kg / ha.
EXAMPLE 4
Sodium monochloroacetate 70.05
EMI4.4
sodium trichloranetate 28 e 5cli polyvinyl alcohol 0.5% sodium alkyl naphthalene sulfonate 1.0% The amount used is 30 - 50 kg / ha.
Claims (1)
Publications (1)
Publication Number | Publication Date |
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BE548857A true BE548857A (en) |
Family
ID=175303
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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BE548857D BE548857A (en) |
Country Status (1)
Country | Link |
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BE (1) | BE548857A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1115517B (en) * | 1958-11-03 | 1961-10-19 | Progil | Combined weed killer |
DE1149197B (en) * | 1959-10-22 | 1963-05-22 | Norddeutsche Affinerie | Means for killing weeds in the pre-emergence method in beet crops |
DE1151975B (en) * | 1960-08-17 | 1963-07-25 | Hoechst Ag | Selective means of destroying undesirable plant species |
-
0
- BE BE548857D patent/BE548857A/fr unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1115517B (en) * | 1958-11-03 | 1961-10-19 | Progil | Combined weed killer |
DE1149197B (en) * | 1959-10-22 | 1963-05-22 | Norddeutsche Affinerie | Means for killing weeds in the pre-emergence method in beet crops |
DE1151975B (en) * | 1960-08-17 | 1963-07-25 | Hoechst Ag | Selective means of destroying undesirable plant species |
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