BE508198A - - Google Patents

Info

Publication number

BE508198A

BE508198A BE508198DA BE508198A BE 508198 A BE508198 A BE 508198A BE 508198D A BE508198D A BE 508198DA BE 508198 A BE508198 A BE 508198A

Authority

BE

Belgium

Prior art keywords

cellulose

wood pulp

chips

fatty acid

acid

Prior art date

Links

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• 229920002678 cellulose Polymers 0.000 claims description 26
• 239000001913 cellulose Substances 0.000 claims description 25
• 229920001131 Pulp (paper) Polymers 0.000 claims description 18
• 230000032050 esterification Effects 0.000 claims description 12
• 238000005886 esterification reaction Methods 0.000 claims description 12
• 239000002253 acid Substances 0.000 claims description 8
• 239000007788 liquid Substances 0.000 claims description 8
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
• 229930195729 fatty acid Natural products 0.000 claims description 7
• 239000000194 fatty acid Substances 0.000 claims description 7
• 150000004665 fatty acids Chemical class 0.000 claims description 7
• WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 claims description 6
• 238000000034 method Methods 0.000 claims description 6
• 230000003068 static effect Effects 0.000 claims description 6
• 150000005691 triesters Chemical class 0.000 claims description 6
• 239000000203 mixture Substances 0.000 claims description 5
• 239000003054 catalyst Substances 0.000 claims description 4
• 230000005484 gravity Effects 0.000 claims description 4
• 239000012442 inert solvent Substances 0.000 claims description 4
• 239000002904 solvent Substances 0.000 claims description 4
• 238000004519 manufacturing process Methods 0.000 claims description 3
• 239000000463 material Substances 0.000 claims description 2
• 238000002791 soaking Methods 0.000 claims 1
• 238000006243 chemical reaction Methods 0.000 description 11
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 7
• 238000006640 acetylation reaction Methods 0.000 description 6
• 229920000742 Cotton Polymers 0.000 description 4
• 230000021736 acetylation Effects 0.000 description 4
• YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
• 229960000583 acetic acid Drugs 0.000 description 3
• 150000008064 anhydrides Chemical class 0.000 description 3
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
• 239000000835 fiber Substances 0.000 description 2
• 239000012362 glacial acetic acid Substances 0.000 description 2
• VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
• VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
• 229920002284 Cellulose triacetate Polymers 0.000 description 1
• 229920000875 Dissolving pulp Polymers 0.000 description 1
• VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
• NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
• 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 description 1
• 150000008065 acid anhydrides Chemical class 0.000 description 1
• 239000003377 acid catalyst Substances 0.000 description 1
• 230000004913 activation Effects 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 238000005266 casting Methods 0.000 description 1
• 238000005119 centrifugation Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 235000019441 ethanol Nutrition 0.000 description 1
• 238000009434 installation Methods 0.000 description 1
• 238000003825 pressing Methods 0.000 description 1
• 238000007086 side reaction Methods 0.000 description 1
• 239000001632 sodium acetate Substances 0.000 description 1
• 235000017281 sodium acetate Nutrition 0.000 description 1
• 238000009987 spinning Methods 0.000 description 1
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1