BE493942A - - Google Patents
Info
- Publication number
- BE493942A BE493942A BE493942DA BE493942A BE 493942 A BE493942 A BE 493942A BE 493942D A BE493942D A BE 493942DA BE 493942 A BE493942 A BE 493942A
- Authority
- BE
- Belgium
- Prior art keywords
- boron
- rays
- cadmium
- cement
- compounds
- Prior art date
Links
- 239000004567 concrete Substances 0.000 claims description 10
- 229910052601 baryte Inorganic materials 0.000 claims description 9
- 239000010428 baryte Substances 0.000 claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 9
- 229910052796 boron Inorganic materials 0.000 claims description 9
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052793 cadmium Inorganic materials 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 9
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 7
- 239000002250 absorbent Substances 0.000 claims description 7
- 230000002745 absorbent Effects 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 239000004575 stone Substances 0.000 claims description 5
- 239000010426 asphalt Substances 0.000 claims description 4
- 150000001639 boron compounds Chemical class 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 239000004570 mortar (masonry) Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000004035 construction material Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 239000011505 plaster Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims description 3
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- 229910052925 anhydrite Inorganic materials 0.000 claims description 2
- 150000001662 cadmium compounds Chemical class 0.000 claims description 2
- 229940065285 cadmium compounds Drugs 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 150000004760 silicates Chemical class 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- 239000000057 synthetic resin Substances 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims 1
- 235000015450 Tilia cordata Nutrition 0.000 claims 1
- 235000011941 Tilia x europaea Nutrition 0.000 claims 1
- 239000010425 asbestos Substances 0.000 claims 1
- 239000011083 cement mortar Substances 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 239000004571 lime Substances 0.000 claims 1
- 229910052895 riebeckite Inorganic materials 0.000 claims 1
- 239000011269 tar Substances 0.000 claims 1
- 239000004576 sand Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- CXKCTMHTOKXKQT-UHFFFAOYSA-N Cadmium oxide Chemical compound [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- YSGQGNQWBLYHPE-CFUSNLFHSA-N (7R,8R,9S,10R,13S,14S,17S)-17-hydroxy-7,13-dimethyl-2,6,7,8,9,10,11,12,14,15,16,17-dodecahydro-1H-cyclopenta[a]phenanthren-3-one Chemical compound C1C[C@]2(C)[C@@H](O)CC[C@H]2[C@@H]2[C@H](C)CC3=CC(=O)CC[C@@H]3[C@H]21 YSGQGNQWBLYHPE-CFUSNLFHSA-N 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- -1 Betume Substances 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N Boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- QCUOBSQYDGUHHT-UHFFFAOYSA-L Cadmium sulfate Chemical compound [Cd+2].[O-]S([O-])(=O)=O QCUOBSQYDGUHHT-UHFFFAOYSA-L 0.000 description 1
- 230000031018 biological processes and functions Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- BEWFIPLBFJGWSR-AONZOJHOSA-N butyl (Z,12R)-12-acetyloxyoctadec-9-enoate Chemical group CCCCCC[C@@H](OC(C)=O)C\C=C/CCCCCCCC(=O)OCCCC BEWFIPLBFJGWSR-AONZOJHOSA-N 0.000 description 1
- 229940117941 cadmium sulfate Drugs 0.000 description 1
- 229910000331 cadmium sulfate Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000135 prohibitive Effects 0.000 description 1
- 238000001959 radiotherapy Methods 0.000 description 1
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000001225 therapeutic Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21F—PROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
- G21F1/00—Shielding characterised by the composition of the materials
- G21F1/02—Selection of uniform shielding materials
Description
<Desc/Clms Page number 1>
PROCEDE DE'FABRICATION DE MATERIAUX DE CONNSTRUCTION NOTRAM-
MENT DE BETON, POUR LA PROTECTION CONTRE LES RADIATIONS PE- NETRANTES.-
La présente invention concerne un procédé de fabrication de Maté- riaux,de Construction absorbants pour divers Rayonnements : Neutrons, Rayons Gamma, Rayons X, Rayons Alpha, Rayons Béta.-
Ces matériaux sont à base de liants, auxquels on ajoute des pro- duits absorbants pour les Radiations.
Ces liants peuvent être aériens ou hy- drauliquès, tels que Béton, Mortier, Ciment, Plâtre, Anhydrite ou analogues; peuvent aussi servir de liants, les Résines synthétiques, le Ciment magnésien, le.Ciment zincique, les Silicates, l'Asphalte, le Bétume, le Goudron ou ana- logues-
Dans un grand nombre d'applications, il est nécessaire de dispo- ser d'un Matériau de Construction absorbant pour les Radiations susceptibles de produire des actions biologiques nocives.-
Par exemple, dans le cas des générateurs d'énergie atomique, il faut se protéger contre les Neutrons et contre les Rayons Gamma, qui y sont produits en grande quantité.
Dans d'autres cas notamment dans les applications Thérapeutiques du Radium ou dans l'emploi des Rayons X pour le Radiodiagnos- tic et pour la Radiothérapie il importe de se protéger contre les Radiations.-
Il en résulte que par exemple dans les installations de produc- tion de l'énergie atomique, il faut assurer la protection du personnel affec- té aux manipulations et des personnes séjournant dans le voisinage.-
Pendant longtemps on a considéré que la protection contre les Rayons Gamma et contre les Rayons X était assurée par l'interposition d'une épaisseur suffisante de plomb ou d'un métal lourd.
La protection contre les Neutrons parait être 'assurée .au mieux par l'interposition de plaques de pa- raffine, d'eau en épaisseur suffisante ou le milieu hydrogéné.-
Une assez bonne protection peut aussi être réalisée contre les Rayons Gamma par le béton ordinaire à condition de disposer d'épaisseurs suf- fisantes. Ce même béton dans les mêmes conditions assure aussi déjà une cer- taine protection contre les Neutrons.-
<Desc/Clms Page number 2>
Ces divers procédés connus à ce jour présentent cependant en pra- tique de multiples inconvénients. Ils sont encombrants et coûteux. Le plomb qui protège contre les Rayons Gamma, absorbe relativement peu les Neutrons.
La Paraffine qui absorbe les Neutrons est pratiquement transparente aux Rayons Gamma, Le Béton ordinaire exige des épaisseurs souvent prohibitives. -
La présente invention a pour but, un procédé de fabrication qui tout en obviant aux inconvénients des procédés connus à ce jour, -permet d'ob- tenir un Matériau de Construction qui assure sous une épaisseur admissible, en même temps la protection contre les Neutrons et contre les Rayons Gamma.
Dans ce but est réalisé un béton spécial uniforme à structure dense, très absorbant pour les divers Rayonnements ; offrant une grande résistance, ayant un durcissement massique régulier et normal et à bas prix de revient.-
Dans ce but,selon l'invention, les matières premières employées pour la fabrication de béton se composent :
1) du liant; additionné à la fois d'éléments fins (sable), d'élé- ments plus gros (pierrailles, etc.); ou Asbest; ou Limailles de Fer ; ouana- logues.-
2) du milieu absorbant pour les Neutrons, on emploi dans ce but, soit le Bore ou un composé du Bore;
soit le Cadmium ou un des composés du Cadmium, en fine distribution.-
Selon l'invention, les éléments fins (sable) et les éléments gros (pierrailles) du mélange seront de préférence de la catégorie des éléments compacts, lourds à densité élevée, telle que la Baryte, la Barytine ou ana- logues. Les éléments gros (pierrailles) du mélange peuvent être remplacés par les éléments fins (sable) compacts et lourds.-
Selon l'invention, le Bore peut être remplacé par toute autre for- me de produit industriel contenant du Bore, du Verre au Bore par exemple, ou un composé approprié du Bore en fine distribution.
Le Cadmium peut aussi être introduit dans la masse sous forme d'un produit industriellement fabriqué con- tenant du Cadmium où un des composés du Cadmium en fine distribution.-
Selon l'invention, les absorbants peuvent être utilisés par exem- ple sous forme de graine ou de poudre, ou encore de morceaux de grosseur ap- propriée.-
Exemple 1.- Pierrailles 4.800 Kgs., Sable 1. 300 Kgs., Sulfate de Cadmium 100 Grs., Ciment 700 Grs., Eau 300 cm3.-
Exemple 2. - Baryle concassée 12.Kgs., Baryte sable 2.500 Kgs., Oxyde de Cadmium 125 Grs., Ciment 1.750 Kgs., Eau 700 cm3
Exemple 3. - Sulfate de Baryte concassé-15.300 Kgs., Sulfate de Baryte sable 3 Kgs., Carbure de Bore 75 Grs.
Ciment 2.100 Kgs., Eau 900 cm3 .-
Exemple 4.- Barytine 7.650 kgs. Acide borique 90 Grs., Plâtre 1.100 Kgs., Eau 525 cm3.-
Exemple 5.- Barytine 6.250 Kgs., Acide borique 100 Grs., Asphalte 2.100 Kgs., Goudron 120 Grs.- @
Il va de soi, que les indications numériques ci-dessus ne sont données qu'à titre d'exemple, non limitatif .-
REVENDICATIONS.
**ATTENTION** fin du champ DESC peut contenir debut de CLMS **.
<Desc / Clms Page number 1>
METHOD OF MANUFACTURING NOTRAM CONNSTRUCTION MATERIALS
CONCRETE MENT, FOR PROTECTION AGAINST PENETRANT RADIATION.
The present invention relates to a process for the manufacture of materials, of construction absorbent for various radiations: neutrons, gamma rays, x-rays, alpha rays, beta rays.
These materials are based on binders, to which are added radiation absorbing products.
These binders can be aerial or hydraulic, such as concrete, mortar, cement, plaster, anhydrite or the like; can also be used as binders, Synthetic resins, Magnesian cement, Zinc cement, Silicates, Asphalt, Betume, Tar or the like-
In a large number of applications it is necessary to have a Radiation-absorbent Building Material capable of producing harmful biological actions.
For example, in the case of atomic energy generators, you have to protect yourself against Neutrons and Gamma Rays, which are produced in large quantities.
In other cases, especially in Therapeutic applications of Radium or in the use of X-rays for Radiodiagnosis and for Radiotherapy, it is important to protect against Radiation.
As a result, for example, in atomic energy production installations, the protection of personnel assigned to handling operations and of persons staying in the vicinity must be ensured.
For a long time it was considered that protection against Gamma Rays and against X-Rays was provided by the interposition of a sufficient thickness of lead or a heavy metal.
Protection against Neutrons appears to be 'at best assured by the interposition of plates of paraffin, water of sufficient thickness or the hydrogenated medium.
Fairly good protection can also be achieved against Gamma Rays by ordinary concrete, provided sufficient thicknesses are available. This same concrete under the same conditions also already provides some protection against Neutrons.
<Desc / Clms Page number 2>
These various methods known to date, however, in practice have multiple drawbacks. They are bulky and expensive. Lead, which protects against Gamma Rays, absorbs relatively little Neutrons.
Paraffin which absorbs Neutrons is practically transparent to Gamma Rays, Ordinary Concrete requires often prohibitive thicknesses. -
The object of the present invention is a manufacturing process which, while obviating the drawbacks of the processes known to date, makes it possible to obtain a Construction Material which provides, under an admissible thickness, at the same time protection against Neutrons. and against Gamma Rays.
For this purpose, a special uniform concrete with a dense structure, very absorbent for the various radiations, is made; offering high resistance, having regular and normal mass hardening and at low cost.
For this purpose, according to the invention, the raw materials used for the manufacture of concrete consist of:
1) binder; added at the same time of fine elements (sand), of larger elements (stones, etc.); or Asbest; or Iron filings; ouanalogues.-
2) absorbent medium for Neutrons, for this purpose, either Boron or a Boron compound is used;
either Cadmium or one of the compounds of Cadmium, in fine distribution.
According to the invention, the fine elements (sand) and the coarse elements (stones) of the mixture will preferably be from the category of compact, heavy elements at high density, such as barite, barite or the like. The coarse elements (stones) of the mixture can be replaced by the fine elements (sand) compact and heavy.
According to the invention, the boron can be replaced by any other form of industrial product containing boron, boron glass for example, or a suitable boron compound in fine distribution.
Cadmium can also be introduced into the mass in the form of an industrially manufactured product containing Cadmium or one of the Cadmium compounds in fine distribution.
According to the invention, the absorbents can be used, for example, in the form of a seed or powder, or else of pieces of suitable size.
Example 1.- Stone 4,800 Kgs., Sand 1,300 Kgs., Cadmium sulfate 100 Grs., Cement 700 Grs., Water 300 cm3.-
Example 2. - Crushed baryl 12.Kgs., Barite sand 2.500 Kgs., Cadmium oxide 125 Grs., Cement 1.750 Kgs., Water 700 cm3
Example 3. - Crushed Barite Sulfate-15,300 Kgs., Baryte Sulfate Sand 3 Kgs., Boron Carbide 75 Grs.
Cement 2.100 Kgs., Water 900 cm3 .-
Example 4.- Barite 7.650 kgs. Boric acid 90 Grs., Plaster 1.100 Kgs., Water 525 cm3.-
Example 5.- Barite 6.250 Kgs., Boric acid 100 Grs., Asphalt 2.100 Kgs., Tar 120 Grs.- @
It goes without saying that the above numerical indications are given only by way of example, not limiting .-
CLAIMS.
** ATTENTION ** end of DESC field can contain start of CLMS **.
Claims (1)
Publications (1)
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BE493942A true BE493942A (en) |
Family
ID=137821
Family Applications (1)
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1040767B (en) * | 1953-02-14 | 1958-10-09 | Simon Missotten | Building wall protecting against neutron radiation |
DE1096818B (en) * | 1958-08-22 | 1961-01-05 | Mannesmann Ag | Process for the production of hardening masses with high radiation absorption capacity |
DE1115375B (en) * | 1960-01-12 | 1961-10-19 | Dolerit Basalt Ag | Decay container for radiating isotopes |
DE1136261B (en) * | 1959-07-01 | 1962-09-06 | Paul Jolly | Process for the production of slabs, stones and ramming masses containing bound anhydrite powder with a high resistance to radioactive rays and heat |
DE1167459B (en) * | 1959-05-27 | 1964-04-09 | Goodyear Tire & Rubber | Neutron screen |
DE1184687B (en) * | 1953-09-15 | 1964-12-31 | Heinrich Drath | Panel or block-shaped construction element made of concrete, artificial stone, stone wood or similar building materials in connection with metallic lead |
DE1219839B (en) * | 1953-09-15 | 1966-06-23 | Heinrich Drath | Slab or block-shaped construction element made of concrete, artificial stone, stone wood or similar building materials in connection with radiation-weakening or radiation-absorbing substances |
DE1230342B (en) * | 1963-06-04 | 1966-12-08 | Marxen Friedrich | Concrete shielding against radioactive rays |
DE1769563B1 (en) * | 1967-06-14 | 1972-05-25 | Commissariat Energie Atomique | Neutron absorbing material and process for its manufacture |
EP1512153A1 (en) * | 2002-02-21 | 2005-03-09 | Fletcher Building Holdings Limited | X-ray resistant lining system |
-
0
- BE BE493942D patent/BE493942A/fr unknown
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1040767B (en) * | 1953-02-14 | 1958-10-09 | Simon Missotten | Building wall protecting against neutron radiation |
DE1184687B (en) * | 1953-09-15 | 1964-12-31 | Heinrich Drath | Panel or block-shaped construction element made of concrete, artificial stone, stone wood or similar building materials in connection with metallic lead |
DE1219839B (en) * | 1953-09-15 | 1966-06-23 | Heinrich Drath | Slab or block-shaped construction element made of concrete, artificial stone, stone wood or similar building materials in connection with radiation-weakening or radiation-absorbing substances |
DE1096818B (en) * | 1958-08-22 | 1961-01-05 | Mannesmann Ag | Process for the production of hardening masses with high radiation absorption capacity |
DE1167459B (en) * | 1959-05-27 | 1964-04-09 | Goodyear Tire & Rubber | Neutron screen |
DE1136261B (en) * | 1959-07-01 | 1962-09-06 | Paul Jolly | Process for the production of slabs, stones and ramming masses containing bound anhydrite powder with a high resistance to radioactive rays and heat |
DE1115375B (en) * | 1960-01-12 | 1961-10-19 | Dolerit Basalt Ag | Decay container for radiating isotopes |
DE1230342B (en) * | 1963-06-04 | 1966-12-08 | Marxen Friedrich | Concrete shielding against radioactive rays |
DE1769563B1 (en) * | 1967-06-14 | 1972-05-25 | Commissariat Energie Atomique | Neutron absorbing material and process for its manufacture |
EP1512153A1 (en) * | 2002-02-21 | 2005-03-09 | Fletcher Building Holdings Limited | X-ray resistant lining system |
EP1512153A4 (en) * | 2002-02-21 | 2008-07-16 | Fletcher Building Holdings Ltd | X-ray resistant lining system |
AU2003206481B2 (en) * | 2002-02-21 | 2008-07-31 | Fletcher Building Holdings Limited | X-ray resistant lining system |
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