BE466877A - - Google Patents

Info

Publication number

BE466877A

BE466877A BE466877DA BE466877A BE 466877 A BE466877 A BE 466877A BE 466877D A BE466877D A BE 466877DA BE 466877 A BE466877 A BE 466877A

Authority

BE

Belgium

Prior art keywords

manganese

molybdenum

ore

liquid

solution

Prior art date

Links

• Espacenet
• Global Dossier
• Discuss

• 239000011572 manganese Substances 0.000 claims description 88
• PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 84
• 229910052748 manganese Inorganic materials 0.000 claims description 84
• 229910052750 molybdenum Inorganic materials 0.000 claims description 61
• 239000011733 molybdenum Substances 0.000 claims description 61
• ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 60
• 239000007788 liquid Substances 0.000 claims description 59
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 32
• PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
• 238000000034 method Methods 0.000 claims description 19
• 229910052742 iron Inorganic materials 0.000 claims description 16
• CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical class [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 15
• 229910052759 nickel Inorganic materials 0.000 claims description 14
• 150000001875 compounds Chemical class 0.000 claims description 13
• 239000007800 oxidant agent Substances 0.000 claims description 13
• 239000010941 cobalt Substances 0.000 claims description 12
• 229910017052 cobalt Inorganic materials 0.000 claims description 12
• GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 12
• 238000000605 extraction Methods 0.000 claims description 12
• 235000007079 manganese sulphate Nutrition 0.000 claims description 9
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 9
• SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 9
• 230000008569 process Effects 0.000 claims description 9
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 8
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
• 238000011282 treatment Methods 0.000 claims description 8
• 239000011702 manganese sulphate Substances 0.000 claims description 7
• BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
• 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
• 235000011130 ammonium sulphate Nutrition 0.000 claims description 6
• 239000006256 anode slurry Substances 0.000 claims description 6
• 239000002198 insoluble material Substances 0.000 claims description 6
• 238000004519 manufacturing process Methods 0.000 claims description 6
• UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 5
• 150000002500 ions Chemical class 0.000 claims description 5
• AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 5
• PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 claims description 5
• 239000002244 precipitate Substances 0.000 claims description 5
• ZGSDJMADBJCNPN-UHFFFAOYSA-N [S-][NH3+] Chemical compound [S-][NH3+] ZGSDJMADBJCNPN-UHFFFAOYSA-N 0.000 claims description 4
• 230000009471 action Effects 0.000 claims description 4
• 239000003638 chemical reducing agent Substances 0.000 claims description 4
• 239000012535 impurity Substances 0.000 claims description 4
• 238000000746 purification Methods 0.000 claims description 4
• 229910021653 sulphate ion Inorganic materials 0.000 claims description 4
• 229940099596 manganese sulfate Drugs 0.000 claims description 3
• 239000010802 sludge Substances 0.000 claims description 3
• 239000000126 substance Substances 0.000 claims description 3
• 150000004763 sulfides Chemical class 0.000 claims description 3
• -1 1'6.17 Substances 0.000 claims description 2
• 239000001166 ammonium sulphate Substances 0.000 claims description 2
• 230000007423 decrease Effects 0.000 claims description 2
• 239000000919 ceramic Substances 0.000 claims 1
• KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical class [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 claims 1
• 239000000706 filtrate Substances 0.000 claims 1
• UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 claims 1
• 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 1
• 239000000463 material Substances 0.000 description 10
• 239000003792 electrolyte Substances 0.000 description 5
• 239000000047 product Substances 0.000 description 5
• 230000000694 effects Effects 0.000 description 4
• 238000005868 electrolysis reaction Methods 0.000 description 4
• 229910052751 metal Inorganic materials 0.000 description 4
• 239000002184 metal Substances 0.000 description 4
• 239000002994 raw material Substances 0.000 description 4
• 238000000926 separation method Methods 0.000 description 4
• 230000008021 deposition Effects 0.000 description 3
• 239000012530 fluid Substances 0.000 description 3
• 230000000505 pernicious effect Effects 0.000 description 3
• AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
• PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
• QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
• UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 2
• 230000008859 change Effects 0.000 description 2
• 238000006243 chemical reaction Methods 0.000 description 2
• 238000003487 electrochemical reaction Methods 0.000 description 2
• 229910052500 inorganic mineral Inorganic materials 0.000 description 2
• 239000011707 mineral Substances 0.000 description 2
• 235000010755 mineral Nutrition 0.000 description 2
• 239000000203 mixture Substances 0.000 description 2
• VRRFSFYSLSPWQY-UHFFFAOYSA-N sulfanylidenecobalt Chemical class [Co]=S VRRFSFYSLSPWQY-UHFFFAOYSA-N 0.000 description 2
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
• QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
• 241000567557 Bajacalifornia Species 0.000 description 1
• RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
• 239000002253 acid Substances 0.000 description 1
• 230000002378 acidificating effect Effects 0.000 description 1
• 229910052787 antimony Inorganic materials 0.000 description 1
• WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
• 239000006227 byproduct Substances 0.000 description 1
• 238000011109 contamination Methods 0.000 description 1
• 229910052802 copper Inorganic materials 0.000 description 1
• 239000010949 copper Substances 0.000 description 1
• 230000029087 digestion Effects 0.000 description 1
• 230000008030 elimination Effects 0.000 description 1
• 238000003379 elimination reaction Methods 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 239000012467 final product Substances 0.000 description 1
• 238000009472 formulation Methods 0.000 description 1
• 150000002697 manganese compounds Chemical class 0.000 description 1
• 150000002739 metals Chemical class 0.000 description 1
• 238000012986 modification Methods 0.000 description 1
• 230000004048 modification Effects 0.000 description 1
• 230000003647 oxidation Effects 0.000 description 1
• 238000007254 oxidation reaction Methods 0.000 description 1
• 230000001590 oxidative effect Effects 0.000 description 1
• 150000002978 peroxides Chemical class 0.000 description 1
• 238000001556 precipitation Methods 0.000 description 1
• 230000009467 reduction Effects 0.000 description 1
• 230000001105 regulatory effect Effects 0.000 description 1
• 150000003839 salts Chemical class 0.000 description 1
• 239000010703 silicon Substances 0.000 description 1
• 229910052710 silicon Inorganic materials 0.000 description 1
• 239000011343 solid material Substances 0.000 description 1