BE441941A - - Google Patents

Info

Publication number

BE441941A

BE441941A BE441941DA BE441941A BE 441941 A BE441941 A BE 441941A BE 441941D A BE441941D A BE 441941DA BE 441941 A BE441941 A BE 441941A

Authority

BE

Belgium

Prior art keywords

hydrogenation

carbon monoxide

acid

paraffin

paraffins

Prior art date

Links

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• 239000012188 paraffin wax Substances 0.000 claims description 30
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
• 239000002253 acid Substances 0.000 claims description 20
• UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 17
• 239000000839 emulsion Substances 0.000 claims description 16
• 229910002091 carbon monoxide Inorganic materials 0.000 claims description 15
• 238000005984 hydrogenation reaction Methods 0.000 claims description 13
• 238000002844 melting Methods 0.000 claims description 13
• 230000008018 melting Effects 0.000 claims description 13
• 239000000203 mixture Substances 0.000 claims description 13
• 150000007513 acids Chemical class 0.000 claims description 11
• 235000014113 dietary fatty acids Nutrition 0.000 claims description 11
• 239000000194 fatty acid Substances 0.000 claims description 11
• 229930195729 fatty acid Natural products 0.000 claims description 11
• 150000004665 fatty acids Chemical class 0.000 claims description 11
• 230000003647 oxidation Effects 0.000 claims description 9
• 238000007254 oxidation reaction Methods 0.000 claims description 9
• RXQNKKRGJJRMKD-UHFFFAOYSA-N 5-bromo-2-methylaniline Chemical compound CC1=CC=C(Br)C=C1N RXQNKKRGJJRMKD-UHFFFAOYSA-N 0.000 claims description 6
• 238000000034 method Methods 0.000 claims description 6
• GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous oxide Inorganic materials [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 claims description 5
• KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 4
• 238000001816 cooling Methods 0.000 claims description 4
• AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 4
• 238000004519 manufacturing process Methods 0.000 claims description 4
• 238000005660 chlorination reaction Methods 0.000 claims description 3
• 150000002148 esters Chemical class 0.000 claims description 3
• 238000000926 separation method Methods 0.000 claims description 3
• 230000001804 emulsifying effect Effects 0.000 claims description 2
• 239000000126 substance Substances 0.000 claims description 2
• CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
• 229910001854 alkali hydroxide Inorganic materials 0.000 claims 1
• 229910052783 alkali metal Inorganic materials 0.000 claims 1
• 150000008044 alkali metal hydroxides Chemical class 0.000 claims 1
• -1 alkali metal salts Chemical class 0.000 claims 1
• 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
• 239000001569 carbon dioxide Substances 0.000 claims 1
• 150000004649 carbonic acid derivatives Chemical class 0.000 claims 1
• 229910052801 chlorine Inorganic materials 0.000 claims 1
• 239000000460 chlorine Substances 0.000 claims 1
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
• 238000006386 neutralization reaction Methods 0.000 description 8
• 238000007127 saponification reaction Methods 0.000 description 8
• 239000001993 wax Substances 0.000 description 6
• 239000003995 emulsifying agent Substances 0.000 description 5
• BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 5
• VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 4
• 238000007792 addition Methods 0.000 description 4
• 238000009903 catalytic hydrogenation reaction Methods 0.000 description 4
• 239000003077 lignite Substances 0.000 description 4
• 239000003381 stabilizer Substances 0.000 description 4
• 239000007789 gas Substances 0.000 description 3
• 230000001590 oxidative effect Effects 0.000 description 3
• 239000000344 soap Substances 0.000 description 3
• 238000007711 solidification Methods 0.000 description 3
• 230000008023 solidification Effects 0.000 description 3
• 238000003756 stirring Methods 0.000 description 3
• QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
• 125000004432 carbon atom Chemical group C* 0.000 description 2
• 229910000027 potassium carbonate Inorganic materials 0.000 description 2
• 235000011181 potassium carbonates Nutrition 0.000 description 2
• 239000007787 solid Substances 0.000 description 2
• 239000007858 starting material Substances 0.000 description 2
• DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
• 238000013019 agitation Methods 0.000 description 1
• 150000001298 alcohols Chemical class 0.000 description 1
• 150000001447 alkali salts Chemical class 0.000 description 1
• 229910052799 carbon Inorganic materials 0.000 description 1
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
• 230000015556 catabolic process Effects 0.000 description 1
• 238000006731 degradation reaction Methods 0.000 description 1
• 235000021588 free fatty acids Nutrition 0.000 description 1
• 150000002314 glycerols Chemical class 0.000 description 1
• 229930195733 hydrocarbon Natural products 0.000 description 1
• 150000002430 hydrocarbons Chemical class 0.000 description 1
• WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
• 239000010985 leather Substances 0.000 description 1
• 239000007800 oxidant agent Substances 0.000 description 1
• 235000011837 pasties Nutrition 0.000 description 1
• 239000011505 plaster Substances 0.000 description 1
• 229940072033 potash Drugs 0.000 description 1
• 229910052700 potassium Inorganic materials 0.000 description 1
• 239000011591 potassium Substances 0.000 description 1
• 235000015320 potassium carbonate Nutrition 0.000 description 1
• 229930195734 saturated hydrocarbon Natural products 0.000 description 1
• 238000005204 segregation Methods 0.000 description 1
• 230000006641 stabilisation Effects 0.000 description 1
• 238000011105 stabilization Methods 0.000 description 1
• 230000000087 stabilizing effect Effects 0.000 description 1
• 238000003860 storage Methods 0.000 description 1
• 239000000725 suspension Substances 0.000 description 1
• 238000005406 washing Methods 0.000 description 1