BE441818A - Composite iron manufacturing process - Google Patents

Composite iron manufacturing process

Info

Publication number
BE441818A
BE441818A BE441818A BE441818A BE441818A BE 441818 A BE441818 A BE 441818A BE 441818 A BE441818 A BE 441818A BE 441818 A BE441818 A BE 441818A BE 441818 A BE441818 A BE 441818A
Authority
BE
Belgium
Prior art keywords
metal
manufacturing process
iron manufacturing
composite iron
spraying
Prior art date
Application number
BE441818A
Other languages
French (fr)
Original Assignee
Braunschweiger Hu Ttenwerk Gmb
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Braunschweiger Hu Ttenwerk Gmb filed Critical Braunschweiger Hu Ttenwerk Gmb
Publication of BE441818A publication Critical patent/BE441818A/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • C23C4/08Metallic material containing only metal elements
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Description

       

   <Desc/Clms Page number 1> 
 



  Procédé pour fabriquer des pièces composées par métallisation. 



   Il est connu de produire des revêtements sur des corps formant fond ou âme, par projection de métal fondu. 



  Afin d'empêcher autant que possible l'oxydation du métal projeté, se manifestant au cours de cette opération, on a proposé d'employer comme véhicule gazeux pour les gouttelet- tes de métal fondu un gaz inerte, par exemple l'azote, au lieu du courant d'air qui servait auparavant à projeter le métal, ou bien d'enrober le métal à projeter d'une couche d'un agent désoxydant qui est fondu et projeté en même temps que le métal. 



   Toutefois, comme l'ont montré des essais, il n'est guère possible d'empêcher par les procédés susmentionnés l'oxydation de la surface du fond, étant donné que le gaz iner-   @   

 <Desc/Clms Page number 2> 

 ne protège pas de manière sûre contre l'arrivée de l'oxygène atmosphérique tous les endroits du fond, qui s'échauffent, et qu'en raison de la grande force vive des gouttelettes métalli- ques l'agent désoxydant est repoussé de la surface du fond, qui doit être protégée contre l'oxydation. 



   Suivant   l'invention,   on obvie à cet inconvénient en appliquant un agent désoxydant sur le fond avant de pro- céder à la projection du métal ou de l'alliage métallique et en soumettant ultérieurement à un traitement thermique la couche produite par projection. 



   Dans le nouveau procédé l'agent désoxydant empêche tant l'oxydation du fond que l'oxydation des particules mé- talliques appliquées par projection et il est en état de réduire des couches d'oxyde formées éventuellement. Enfin, l'agent désoxydant compris entre le fond et la couche métal- lique appliquée par projection a aussi pour effet de proté- ger le fond contre une oxydation ultérieure au cours du trai- tement thermique subséquent et de réduire les oxydes pré- sents le cas échéant. 



   Le nouveau procédé, qui convient non seulement pour la fabrication de pièces mécaniques compliquées, par exemple de roues dentées ou clefs de robinet, mais encore pour la fabrication de coussinets, notamment de coussinets à couches multiples, permet de produire des revêtements extrêmement minces et très adhérents soit sur toute la surface d'une pièce, soit sur une partie seulement de celle-ci, par exemple sur les dents d'une roue dentée. 



   Le corps formant fond ou âme peut être en fer, acier ou métal analogue. 



   Pour la projection au moyen des pistolets métalli- seurs connus on peut partir d'un métal ou d'un alliage en forme de verges, de fils ou de poudre. 



    @   

 <Desc/Clms Page number 3> 

 
Avantageusement on exécute le traitement thermique, requis pour produire une diffusion entre la couche appliquée par projection et le fond, en empaquetant dans du sable le corps portant la couche produite par projection et en le chauffant ensuite pendant un certain temps. Pour empêcher l'oxydation, le sable peut contenir de la poudre de charbon ou matière analogue. 



   Quand par exemple on veut, par le nouveau procédé, revêtir un coussinet d'une garniture de bronze de plomb, on applique d'abord sur une coquille en acier un agent désoxy- dant, par exemple du borax et, on la métallise par projection de bronze de plomb, puis on   1 rempaqueté   dans du sable et on la chauffe à une température de 900 à 1000 C., pendant une à dix heures selon l'épaisseur de la pièce et le degré de diffusion à réaliser. Quand, par exemple, il s'agit d'une coquille de 5   mm   d'épaisseur, il suffit de maintenir pendant une heure la température de 900 à 1000 C. 



    REVENDICATIONS   --------------------------- 
1.- Procédé pour fabriquer des pièces composées par projection d'un métal ou d'un alliage métallique sur un corps formant fond ou âme, en employant un agent désoxydant et en procédant ultérieurement à un traitement thermique, caractéri- sé en ce qu'àvant la projection on applique un agent déso- xydant sur le corps formant fond ou âme. 

**ATTENTION** fin du champ DESC peut contenir debut de CLMS **.



   <Desc / Clms Page number 1>
 



  Process for manufacturing parts composed by metallization.



   It is known to produce coatings on bodies forming the bottom or core, by spraying molten metal.



  In order to prevent as far as possible the oxidation of the sprayed metal, which occurs during this operation, it has been proposed to use as a gaseous vehicle for the droplets of molten metal an inert gas, for example nitrogen, at the same time. instead of the air current which was previously used to project the metal, or to coat the metal to be projected with a layer of a deoxidizing agent which is melted and projected at the same time as the metal.



   However, as tests have shown, it is hardly possible to prevent the oxidation of the bottom surface by the above-mentioned methods, since the inert gas

 <Desc / Clms Page number 2>

 does not reliably protect against the arrival of atmospheric oxygen all the places of the bottom, which heat up, and that due to the great dynamic force of the metal droplets the deoxidizing agent is repelled from the surface bottom, which must be protected against oxidation.



   According to the invention, this drawback is obviated by applying a deoxidizing agent to the base before spraying the metal or the metal alloy and by subsequently subjecting the layer produced by spraying to a heat treatment.



   In the new process the deoxidizing agent prevents both the bottom oxidation and the oxidation of the metal particles applied by spraying and is able to reduce any oxide layers formed. Finally, the deoxidizing agent included between the base and the metallic layer applied by spraying also has the effect of protecting the base against subsequent oxidation during the subsequent heat treatment and of reducing the oxides present on the base. optionally.



   The new process, which is suitable not only for the manufacture of complicated mechanical parts, for example cogwheels or tap wrenches, but also for the manufacture of bearings, in particular of multi-layered bearings, allows the production of extremely thin and very adherent either over the entire surface of a part, or over only part of it, for example on the teeth of a toothed wheel.



   The body forming the bottom or core can be made of iron, steel or the like.



   For the spraying by means of known metallizing guns, it is possible to start from a metal or an alloy in the form of rods, wires or powder.



    @

 <Desc / Clms Page number 3>

 
Advantageously, the heat treatment required to produce a diffusion between the spray-applied layer and the bottom is carried out by encapsulating the body carrying the spray-produced layer in sand and then heating it for a certain time. To prevent oxidation, the sand may contain charcoal powder or the like.



   When, for example, by the new process one wishes to coat a bearing with a lead bronze lining, a deoxidizing agent, for example borax, is first applied to a steel shell and then sprayed with metal. lead bronze, then it is repackaged in sand and heated to a temperature of 900 to 1000 C., for one to ten hours depending on the thickness of the room and the degree of diffusion to be achieved. When, for example, it is a shell 5 mm thick, it is enough to keep the temperature at 900-1000 C. for an hour.



    CLAIMS ---------------------------
1.- Process for manufacturing parts composed by spraying a metal or a metal alloy onto a body forming the bottom or core, using a deoxidizing agent and subsequently carrying out a heat treatment, characterized in that before spraying, a deoxidizing agent is applied to the body forming the bottom or core.

** ATTENTION ** end of DESC field can contain start of CLMS **.


    

Claims (1)

2.- Procédé pour fabriquer des pièces composées par métallisation, en substance comme c'est décrit ci-dessus. **ATTENTION** fin du champ CLMS peut contenir debut de DESC **. 2.- Process for manufacturing parts composed by metallization, in substance as described above. ** CAUTION ** end of field CLMS may contain start of DESC **.
BE441818A 1940-08-03 1941-06-20 Composite iron manufacturing process BE441818A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE872921X 1940-08-03

Publications (1)

Publication Number Publication Date
BE441818A true BE441818A (en) 1941-07-31

Family

ID=6816195

Family Applications (1)

Application Number Title Priority Date Filing Date
BE441818A BE441818A (en) 1940-08-03 1941-06-20 Composite iron manufacturing process

Country Status (2)

Country Link
BE (1) BE441818A (en)
FR (1) FR872921A (en)

Also Published As

Publication number Publication date
FR872921A (en) 1942-06-23

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