BE432776A - - Google Patents

Info

Publication number

BE432776A

BE432776A BE432776DA BE432776A BE 432776 A BE432776 A BE 432776A BE 432776D A BE432776D A BE 432776DA BE 432776 A BE432776 A BE 432776A

Authority

BE

Belgium

Prior art keywords

compounds

desc

dione

parts

present

Prior art date

Links

• Espacenet
• Global Dossier
• Discuss

• 150000001875 compounds Chemical class 0.000 claims description 13
• 238000000034 method Methods 0.000 claims description 7
• 239000003470 adrenal cortex hormone Substances 0.000 claims description 4
• 238000002360 preparation method Methods 0.000 claims description 2
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
• RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
• NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• 235000000346 sugar Nutrition 0.000 description 3
• IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
• 235000001727 glucose Nutrition 0.000 description 2
• 239000000203 mixture Substances 0.000 description 2
• 229910001923 silver oxide Inorganic materials 0.000 description 2
• 150000008163 sugars Chemical class 0.000 description 2
• JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
• 150000004043 trisaccharides Chemical class 0.000 description 2
• XDFFTQFZNBRIQC-TZLZSRMRSA-N (18R,19S,20R,21R)-18,19,20-trihexadecyl-18,19,20,21-tetrahydroxy-21-(hydroxymethyl)heptatriacontan-17-one Chemical compound C(CCCCCCCCCCCCCCC)[C@@]([C@]([C@@]([C@](C(=O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CCCCCCCCCCCCCCCC)(O)CO XDFFTQFZNBRIQC-TZLZSRMRSA-N 0.000 description 1
• 241000566113 Branta sandvicensis Species 0.000 description 1
• WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
• CYAYKKUWALRRPA-RGDJUOJXSA-N [(2r,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-bromooxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@H]1O[C@H](Br)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O CYAYKKUWALRRPA-RGDJUOJXSA-N 0.000 description 1
• WRYNUJYAXVDTCB-UHFFFAOYSA-M acetyloxymercury Chemical compound CC(=O)O[Hg] WRYNUJYAXVDTCB-UHFFFAOYSA-M 0.000 description 1
• 239000002253 acid Substances 0.000 description 1
• 230000001476 alcoholic effect Effects 0.000 description 1
• 150000001722 carbon compounds Chemical class 0.000 description 1
• 238000007865 diluting Methods 0.000 description 1
• 238000001704 evaporation Methods 0.000 description 1
• 238000001914 filtration Methods 0.000 description 1
• 150000002256 galaktoses Chemical class 0.000 description 1
• 239000008103 glucose Substances 0.000 description 1
• 150000002304 glucoses Chemical class 0.000 description 1
• 229930182478 glucoside Natural products 0.000 description 1
• 150000008131 glucosides Chemical class 0.000 description 1
• 239000005556 hormone Substances 0.000 description 1
• 229940088597 hormone Drugs 0.000 description 1
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
• 239000000155 melt Substances 0.000 description 1
• 230000003472 neutralizing effect Effects 0.000 description 1
• 229910052757 nitrogen Inorganic materials 0.000 description 1
• 239000000843 powder Substances 0.000 description 1
• 238000007127 saponification reaction Methods 0.000 description 1
• 239000010802 sludge Substances 0.000 description 1
• QDRKDTQENPPHOJ-UHFFFAOYSA-N sodium ethoxide Chemical compound [Na+].CC[O-] QDRKDTQENPPHOJ-UHFFFAOYSA-N 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000007858 starting material Substances 0.000 description 1