BE409289A - - Google Patents

Info

Publication number

BE409289A

BE409289A BE409289DA BE409289A BE 409289 A BE409289 A BE 409289A BE 409289D A BE409289D A BE 409289DA BE 409289 A BE409289 A BE 409289A

Authority

BE

Belgium

Prior art keywords

butyloctanol

esters

acid

butyloctyl

water

Prior art date

Links

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• XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 claims description 19
• 150000002148 esters Chemical class 0.000 claims description 11
• QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
• -1 aromatic carboxylic acids Chemical class 0.000 claims description 4
• 238000000034 method Methods 0.000 claims description 4
• 239000002253 acid Substances 0.000 claims description 3
• 150000001735 carboxylic acids Chemical class 0.000 claims description 3
• 150000001298 alcohols Chemical class 0.000 claims description 2
• 125000001931 aliphatic group Chemical group 0.000 claims description 2
• 230000003197 catalytic effect Effects 0.000 claims description 2
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
• OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
• 150000001243 acetic acids Chemical class 0.000 claims 1
• 229910052739 hydrogen Inorganic materials 0.000 claims 1
• 239000001257 hydrogen Substances 0.000 claims 1
• 150000007524 organic acids Chemical class 0.000 claims 1
• 150000003022 phthalic acids Chemical class 0.000 claims 1
• KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims 1
• 235000011044 succinic acid Nutrition 0.000 claims 1
• 150000003444 succinic acids Chemical class 0.000 claims 1
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
• 239000000203 mixture Substances 0.000 description 9
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
• 238000006243 chemical reaction Methods 0.000 description 7
• 239000000047 product Substances 0.000 description 5
• CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
• 239000003054 catalyst Substances 0.000 description 4
• QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
• KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
• 238000009835 boiling Methods 0.000 description 3
• 230000005484 gravity Effects 0.000 description 3
• 239000007788 liquid Substances 0.000 description 3
• 238000010992 reflux Methods 0.000 description 3
• 238000007127 saponification reaction Methods 0.000 description 3
• 238000003756 stirring Methods 0.000 description 3
• 150000007513 acids Chemical class 0.000 description 2
• 150000008064 anhydrides Chemical class 0.000 description 2
• 238000004821 distillation Methods 0.000 description 2
• 239000004922 lacquer Substances 0.000 description 2
• 229910000029 sodium carbonate Inorganic materials 0.000 description 2
• KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
• DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
• UBFGBVUKMXIMNK-UHFFFAOYSA-N 2-butyloctyl acetate Chemical group CCCCCCC(CCCC)COC(C)=O UBFGBVUKMXIMNK-UHFFFAOYSA-N 0.000 description 1
• YTHVDYAWBBKDJX-UHFFFAOYSA-N 3-butyloctan-1-ol Chemical compound CCCCCC(CCO)CCCC YTHVDYAWBBKDJX-UHFFFAOYSA-N 0.000 description 1
• LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
• 125000003118 aryl group Chemical group 0.000 description 1
• JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
• 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
• 239000003795 chemical substances by application Substances 0.000 description 1
• 150000001875 compounds Chemical class 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 230000032050 esterification Effects 0.000 description 1
• 238000005886 esterification reaction Methods 0.000 description 1
• 239000012263 liquid product Substances 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 230000004048 modification Effects 0.000 description 1
• 238000012986 modification Methods 0.000 description 1
• 230000007935 neutral effect Effects 0.000 description 1
• 230000009965 odorless effect Effects 0.000 description 1
• 239000004014 plasticizer Substances 0.000 description 1
• 235000011118 potassium hydroxide Nutrition 0.000 description 1
• 239000011253 protective coating Substances 0.000 description 1
• 229920005989 resin Polymers 0.000 description 1
• 239000011347 resin Substances 0.000 description 1
• 239000000741 silica gel Substances 0.000 description 1
• 229910002027 silica gel Inorganic materials 0.000 description 1
• 239000002904 solvent Substances 0.000 description 1
• 239000001384 succinic acid Substances 0.000 description 1
• 239000002966 varnish Substances 0.000 description 1