BE1018441A3 - EMULGABLE CONCENTRATE OF A PESTICIDE. - Google Patents

Abstract

Emulsifiable concentrate of a pesticide containing a solvent for the pesticide, wherein the solvent contains an alkylbenzene with at least one alkyl group where the alkyl group has a chain length of C10-C11.

Description

Embedible concentrate from a pesticide.

This invention relates to an absorbable concentrate according to the preamble of the first claim.

Emulsifiable concentrates are a commonly used formulation for pesticides. The emissible concentrate according to this invention is intended, inter alia, to process pesticides such as diphenoconazole.

Diphenoconazole is a pesticide, more specifically a fungicide, and is widely used as a crop protection agent that can be applied to the leaves or seeds of the crops to be protected. Difenoconazole has a very broad effect as an active substance and is active against a large number of harmful organisms, including the Ascomycetes, Basidiomycætè, nc'enf. '' DéutéfbmycetenpinGlüsiéfi, the Alternaria,

Aseoehyta ·, - Gereospora, -... Gercosporidium, -... Colletotrichum, - ·. · -Guignardia, -

Mycosphaerella, Phoma, Ramularia, Rhizoctonia, Septoria, Uncinula and Venturia spp. This relates to a tolerable concentrate of difenoconazole, which is offered in various forms, as well as various types of substances, substances, substances, substances, substances, substances, substances, substances, substances, and so on. are3 QSRi »^ 1 ^ ngi ^ .üigiSPr ^ OB5.uC0ncaDtfaten ^ contain i: töaesi '' b8fcGasiieyeibestan.ddeel.reen solvent that is not miscible with water such as xylene, ShellsoiA or Solvesso 200. Such spents are difficultly soluble ifywater. This makes it extremely suitable for creating a mixture of emulsion concentrates, in Jiet alger & a further or multiple surfactant, active substances such as detergents, or adjuvants. λ Bijr ^ .use :, depth · hgbendible: coricentrate ^ mixedçl; te ^ yvordenj, iji.etv; waierirzpdat; e ^ «mouse i'Γf i :: r - - - 'y' ~ i '' 'i; r: ~ · -Ij' · ί. . K ":" · • c "/ HryHV-:" it is obtained that can be applied immediately to the crops to be protected. "" "": - ·. · '': Due to the presence of ereir solvent, miscible concentrates have the advantage that they often display higher activity than other pesticide formulations in the form. of, for example, powders, dispersible granules or suspension concentrates.

Traditionally, solvents such as xylene or toluene are used. These solvents have the great advantage that they are powerful and therefore exhibit a large solution capacity. The afterthought of this! solvents, however, is that in addition to their high toxicity, they also have low flammability. Toluene is highly flammable (flash point of 4 ° C), so xylene has a flash range of 27-32 ° C (depending on the type of xylene) is highly flammable. The low flammability has the consequence that if special solvents are used, special warehouses must be installed. Storage: Store: 1 Qty ic Hèn 1 This problem can be avoided by: aromatic solvents with higher density. yl.an # uhten ;;; ^^ Qrgahie.chë; eolveqtehrkuhnen !! for example, geekQzen / .w.ôrdehiÎuitVde> -! g ^ dej.alkylbéózëner) · ^ eteeneen • chainlehgtesvahrrêsóeötieye ^ GlQnGilleóf # ,. ; How long: the jseienl.engte.ïihpe ^ and therefore- the safer the emulsifiable concentrate becomes> oi ents or ib'uëen These & oiv: At present, i'm ^ kt-iyef ^ heidene ^ ^ diphenpconazole-formulation-offered # .. 06, form, emulsifiable, levels: ^ alkyls of alkylbenzene with a chain length of C, 10bG, 1; 4vv: used · are used. These have a cooking potion. from 242-2909C and. a. viaPuhthyaneT40G.:; EehiyqorbeeldWan;: a; fhandei ^ aa wahieenvdefaale '; splveht'feGplveseCiZOOyr Γ.Η ·; "I,; rxi main toll 'daV ^ i use' vao. In, US. q§66308 B-lgvTo be; for example ^ ehi ei ^ lsie ^ pö ^ a ,, size, number,; pesticides (, Wäärpndei 'pkd.ifeh in, ppge! pst wprdén:; In addition.; simplicity: organi. <RTI ID = 0.0> 1, </RTI> dicarboxylates As an example of an organic solvent, Solvésso 200 is given as an example of an organic solvent.

In the case an emulsifiable concentrate '* ·', * <1 / 'V% ci · (.,>'. ': V r ·.; V' ** 'is formulated with such an alkylbenzene as solvent, the disadvantage is that a quantity of biphenyl will be present in the solvent Biphenyl is one component of interest with a boiling point of 256 ° C. Because of this boiling point, which is just in the middle of the distillation range of the C10 -C14 alkylbenzenes, biphenyl will always be present in such alkylbenzene mixture. Biphenyl is a substance that can be avoided in products used on plants, the defenses for which are that biphenyl is classed as a residue in European legislation, so that plants treated with products containing biphenyl can contain a bipheriyl content that is above the residue standard and thus become unsaleable .

It is also the object of the present invention to provide a sera-emulsifier concentrate based on alkylbenzene for any other dobs with a greatly reduced biphenyl content.

Ride wofdt5volgen.s5.de unambiguous | fèrwiy.nciingicfeené | iàidpör \ mlddèlivan / eeil emulsifiableiconcentresatsyp incidentally the characteristic part · ydnideieersté cooçlîÂi a fioeyaHhoai blpher-yi sat. Biphenyl is a ronethon DonkiUneiHiertQe ^ këténiehgtefVaht rni'ddc-n from>: deattëfuiotfsjovt of ·: ". Β Ci 0-C 4 alkylbenzenes left, i blplicny: always used kSolventeni.opjhasis

Ketg'i]!! Engtéf.vah ^ QlL0-G1: iohëbb.é ^ eeri »i kookp.üntcgoingävanol 8B? JQjtot’2M ° QeGfczièn 'rhiphédyl i <éejrj ^ 0.kp.MOjt; add to this 256 ° Vligtythis substance ibuitenoditskG> pktrgj, eotr # n; rzal - bipperiyh production. by;. mid.lnyan / jdosti | iation also; ini] eta awe? i9 «will be8; obtained alky; lb.enzee, mixture: iDiiti sheets; - the large size of the product, based on such acylbenzene mixtures, no biphenyl; contain .and no; problems .pplpyeronj v> nilRii ce, .rèy ^ ie !; in, Be. benzene group. in the alkylbenzenes, both mono, di, and polyalkylated sides can be alkylated.

Preferably, the active substance is selected from the group: from herbicides, insecticides, fungicides, bactericides, nematicides, algicides, moiluscicides, rodenticides, virucideri, drugs that induce resistance to plants, biological control agents such as viruses, bacteria, "nematódëriëriëriëriëriëriëriri organisms, repellerits for birds and animals, plant growth regulators, or a mixture of two or more of them. "1: More preferably, active substance and furigicin is any fungicide known to any fungicide. Examples of fungicides that can be used for terriulgible concentrate according to the present invention and that are additionally water-soluble are AC 382042, anilazine, azoxystrbbin, betaiaxyl, beriomyl, binapacryl, bitertanol, blasticidin S, Bordeaux mixture. bromuconazole, bupirimatè, eaptaföl, captan, carbendazim, c'rboxin, carpropänhid, chlorbëhzthiazon, chlorothalonil, c hlozolinate, cycloheximide, cymoxanil, cypofufam, cypropnazole, cyprodioil; ^ dichlorofluanjd ^ obichlon'ei; diphlpran ^ r · r-di4dpbiatcazQbeöcf! didoßyn5etv2ic -.-idic, lofne.ane ;; <^ .nfli ^ tb! 5feS »iiefbi, 4if§ia®0P, ai ! Bi5rjiïdifl! U ^ etórlrr! Pft.i djm ^ thjriçi ^ lckiçiimetbô'tearptîir * · diniconazoler, dïnócap, ditalimfóp; dithiarronTidodemorph, dodjne ;; edifenphosweppx eio ^ ooiphipool ofhipool ooiphipool ooiphipool ooipool ooiphipool oiphipool ooipool ooipool ooipool ooipool ooipool ooipool ooipool. onénfenarirpgliiMfenbüconazQlev ^ ^ Yfenhexamid.aifenpiclönilfivfenpfopiclin fenfuram, fenpropimöfph, fentin, fentin hydroxide acetates fentin ^. ^ erimzoneiufluaZiBèm, fludioxonil, flumetover, fluquinóönazQlevs Flusilazole ;; Mflusalfamidejsi flutolànib ^, ^ flutrià lïnaÎPlpetv ·, nfosetyl-aluminiur ^^^^ ifurametpypf '£ ^ az ^ j) ejif ^ è) (acóJWQ.iói vU $ * $ 16 & t imazalil, i: jmjn (^ dii! ie / jiidppoc ^ ltr.) iprödjojpe1.r_isoprothiolan iprovalicarb, kasugamycini; KH-728; l ·, kitazin; kresQxim-methyl; ·., .mancozeb · .. maneb, h; rnepanipyrim, hnepronilmetalaxyl; 17ietœB.azôJe.: wethfurqxàmif MON; r 655p0, <myclobutariil, dimgthyldithiocarbaniate., Mitrothalisppropyl, nuarimo | I.ofuraee ^ organp; rp.ecpmppunds, oxadLxyl ,, ioxycarboxin, .pencpnazolei pencycu.rpn, "phenazinepxide; ,. polyp ^ u.DiVi pQlyiam ^^ ep ^ le; «;.; prppamqcarb ,, tpropiCQnazpje, propine.b, .pyrazophos,., R pyrimethanil · ;, strpptpmycin,., .. sulfur, * ^ te, bucona? p | e,; .-. tecloftalaipne, .. tecnazene, - tetraconazole, - thiabèndazole, thifluzamide ,. thiophanatetiethyl, thiram. tolclofosmethyl ,. tolylfluanid, triadimefon, triadimenol, triazoxide, triazoxide, tricyclazole, tridemorph, trifloxystrobin, triflumizole, triforin, triticonazole, validamycin A, vinclozolin, XRD-563, zarilamid, tribezazorazole, tribe, azebarzole, tribe, azebarzole, tribe.

Preferably, the fungicide is selected from the group of strobilurin fungicides, conazole fungicides or a mixture of two. or several of these. :.

.'Νχ · ~ ν. ·. ·· Conazole fungicides contain a triazole group.

Active substances containing this group often exhibit strong antifungal activity. Also pesticides that belong to the. group of: destrobilurins properly exhibit strong antifungal activity.

More preferably, the fungicide gpközen from the group of diphenoconazole, propiconazole, tebuconazole, azoxystrobin, or a mixture of two, or more of these, is most preferred, it is fungicidal safe to use the emulsifiable concentrate with dispersidifenoconazpbv. tr ^ Eventyeel · is used:: difènoconaz ^^^; with propiponazoh tebuqonazoli or azoxystipbin. ó: am,'i: icwrM ^ <> i, S, Bijiyorkeur; isihetfcp ^ present in the emulsifiable concentrate in a concentration of iliQO-SOQag / liemetoimeenypprkeut! 15DtflOÖ; g / lii; with? D ©; most precursor20Qi-3GO..g / b!:; o ·: · one ίΤ | ίΚΛ -, ^ ί: ;;?; A; such; concentration ensures optimum and efficient functioning of: the, peeticide.rpalS;) active; etof>; at: the control of desired organisms. · - ·, s. · ... v% v; s.dïimn * {s: Krdnr ^,.%. nc;: - / ;: o.i.your preferential solvent in: iNerulerablelablyQuestreataanw, ezig is ^ i ^^^^^^ c «nc ^ ntration..yani55? Q ^ ewi%! ^;:. 1v; le '> r ··. Preferably, emulsifier, cp.centrate. .avf · onb: r · i; -o; -vfît: v> Pin. U son / -4 t '\. <: <-M'i'These additives; ï can be of any kind: isoorb aggregates}; ^ ;; dppr ^ de; For various reasons, a concentrate can be added to the mixture, for example surfactants, anti-foaming agents, and added, if desired. T = -,, v. "- - v ,,,...: .Yoqrkeui ;; peyat, pee ^^ eP ^ Y '^ raptive material.,, E .., ν, -; ,,, ,

To minimize the risk of crystallization of the pesticide, a surfactant such as a detergent or an adjuvant can be added to the emulsifiable concentrate. Adding a surfactant to the emulsifiable concentrate has the advantage that the one or more active substances are better kept in solution, and this also at low temperatures. Adjuvants have the additional advantage that the biological activity of the active substance, in this case the pesticide, can greatly increase.

Preferably, a surfactant is selected from the group of the calcium alkyl sulfonates, ethoxylated castorplie, ethoxylated alcohols, or a mixture of two or more of them.

Preferably, the emulsifiable concentrate further comprises an anti-foaming agent.

Foaming is a common problem with emulsifiable cOncéntrateno Certainly when. the emulsifiable concentrate in use diluted. i: becomes bijyopfbeeldcwaterii'kan, and. in particular fallen sea violent; Formation of foam. Xtredenr (watr ;; PnwenseJijktis;,.; The opinion of everyone: to be admissible: concentrate:. an anti-foaming agent has been added: ü -icitive substances are better kept in yossossing / · - M c ,, Bijb; i yopi ^ euri ^ rdtzn.hetiuzantirSçhuîmmiddejige ^ eesr.from the group of silicas: ,, po.| } ni?: o. '- selected CD from a particular preferred embodiment of the present invention which is also compatible with the present invention.

The addition of a single polymeric copolymer has the advantage that higher amounts of the pesticide or of an additive can be added to the emulsifiable concentrate. cani the.volume of '; the., emu (g, ee ^ ear ^ vigor; yeda £ | g ^ is getting updateddaardgprdeh ^ beinylpgd ^ ,., ·, .rer; ». · * ►: = ·:, rte- te '· .i ^ At ypprkeun; yyprdtAhet ^, corsplvp.nt ^ g [§gphUiyan ;; - yrbutyi; pleçtpn ,; k Nrmethylpyrrplidpne, N-cyclohexy, lpyrrplidpne, c · λ ··' Τ · .. -r ' -.-, ...;., ·. · .. · '·· · V..';.

cycloftexanone, glutanic acid dimethyl ester, succinic acid dimethyl ester, adjpipe acid dirpethyl ester, or a mixture of two or more of them. v ,,. This invention also relates to a method for preparing a pesticidal composition based on the emulsifiable concentrate described above, wherein the emulsifiable concentrate. is diluted with water in an emulsifiable concentrate: water ratio of 1 / 500-1 / 1000, more preferably in a ratio of 1/800 .; . This invention also relates to; on, the use of a pesticidal composition as described above, and, as a fungal pesticide on agricultural and horticultural crops. -

This invention also relates to a method for applying the pesticide composition described above wherein the pesticide composition is sprayed or sprayed on agricultural and agricultural crops. :: vuc di.Wihyi, öoiplnic acid.dinvtthyi; .Dec;! Uindinginding;; is shown in the following example in which an emulsifiable Concentrate; yan dife.noGonazob be.sGbre, veraMMprdtpr hei · herskir.,! from a & ~ ». ;: esilci’isrjsa.rner.; U.3iiiriü and bosis from the Xni.örl'oyen-be'iChri'-vo / t c'v ^ eotasai 'bijbij

Vooffbeeldcat me: "wekx yerour-u wet ra." A Vbrhoudioo .aùs "" | 9é ^; ba ;; srconc-bDife.noconapl: \ 23? / ÖiWlm. mg / g / m / y / y / y / y; uk, loding also dab-ekCr-g ophe. ": .g ^ P ^ ylpted; al <^ ©!.? i38èbVttóei.j.e; «Styling z-piv._ b .; ~ .TiOV2n .pte pen; η;? ρ | ν§ηί · t, 53r ^ §!%, w ^: o p. ig »you. o,;, \ r. ^ de / ·. · '* uibnnbha bciioUpria on a repeatable concentrate was prepared by mixing the ingredients: jnde ^ anxiety.howy (present:;: pi:; - c and tooth - on

Claims (6)

2. An emulsifiable concentrate as claimed in claim 11, characterized in that the alkyl group is unbranched. 3. Emulsifiable concentrate according to claim 1 or 2, characterized in that the pesticide is selected from the group of herbicides, insecticides, fungicides, bactericides, nematicides, algicides, molluscicides, rodenticides, virucides, substances that induce resistance in plant inducers, biological control agents such as viruses, bacteria, nematodes, fungi and other microorganisms, repellents for birds and animals, plant growth regulators, instead of a mixture of two or more of them. An emulsifiable concentrate as claimed in any one of claims 1 to 3, characterized in that the pesticidal pesticide is post-active. '' '1': 'I and contain a solvent \ §k} Formulable: jopncentrate yplgepsvéen ^ \ cona: zppl; fungieides or a mixture of two or more of them. 2. pas: rcncw: 1, for claim 1, rowing: it is dc. 6, emulsifiable concentrate according to any one of claims 1 to 4, characterized in that it is removed from the container. ^ ygropp; yanjjdifi ^ o ^ a ^ oivTpEPpicQnasQl., tebuconazpl ^ azoxystrpbin., pfiene ^ mepgseliyan | two; .pf multiple:, hieivan; ^ ;;; ice, v. • plasticizers. "TYPE", "MOYS" SIZES. 0 / .-: 880 /, 7.Y Emulsifiable, -; - Concentrate: According to "One / Deri ^ d ^ © ti ^ © i".: I <: eRlt ^ ei! kid3 | s | ^ et; fungijÇ »de / ^ ifenpjçp0 € IZ € Hne: natodenöchifni-w. ·.« :? cn ΐ.ΛΟΡ-ϊβ rv2,., 3 .._ Emblatable ;, concentrate: according to (-sensder, <^ @ ^ M, siesvnlr? oii -: ^. ettr ^ Qnciijey ^ .r-KCi.atr ', het. : pesticide ^ present ·: is ;, at a concentration of 100-500 g / l, fnet / iflee £ vvpqr {ceur.; 15ΜΑΡ ··: .ρ / Ι .. · 'Γηρί; ^ β; nfieesterVQbr) 5.eur 200: 300 g / l. >. -1 / 1 / Emulsifying agent: concentrate concentrate according to. a; den-, Κ © ΠΓΤ1 ^ ΓΜ ^^ tf i jSölyentö ^ aah ^ nc-, reen vnMws., · or Emulsifiable concentrate according to one of Claims 1 to 9, characterized in that the emulsifiable concentrate further contains one or more additives. An emulsifiable concentrate according to claim 10, characterized in that the emulsifiable concentrate contains a surfactant. ,,. . . .... 12. Emulsifiable concentrate according to claim 11, characterized in that the surfactant is selected from the group of the. calcium alkyl sulfonates, ethoxylated castor. oil, ethoxylated alcohols, or a mixture of two or more of them. . r v An emulsifiable concentrate according to any one of claims 10-12, characterized in that it is emulsifiable. concentrate. contains an anti-foaming agent. 14. An emulsifiable concentrate as claimed in claim 13, characterized in that the anti-foaming agent is selected from the group of silicic acid siloxanes - polyisylisiloxanes. phosphoaliphatic <Hra;: - p-fluoroalkylphosphonic acid or perfluoroalkylphosphinic acids or salts thereof, or a mixture of two or more multiple amino acid for ceramics. Marking of the emulsifiable concentrate yolge ^ e ^ der-eon.elusiesjl OalÆi has the characteristic that the emulsifiable concentrate contains a .co-solvent. -yar .roncff-nlioa * • follow '·: ·· tc .conclusion: K .met | v?' (kenrnork tjat qy OiljOiiEmulsifiable ^ neentraatiNatiponglusipi 1 .. 5yimet haf! cken.m © fk'i: 4aty ^ Q0rsolveat> N-methylpyrrolidone, N-cyclohexylpyrrolidone, cyclohexanpn, glutarin, acid, dimethyl ester, succinate of dimethyl, ester,, vadipine, etc. Dimethyl, ester, or a mixture of ee ^ pf multiple .from..y; ni r., j ^> 1. .s;, Thj> .yr ;; ddfai he;: h. 17. Method for preparing a pesticide composition based on; of the emulsifier, concentrated concentrate, one of the reductions, 1-16 with; -the.mark. That is, there is an emulsifiable emulsifier, concentrate, water, y 2, 4, 4, more specifically, a ratio of 1/800,; ir.e -., ot 'r. · - · 1öjv Gebnijk ^ van ,. a pesticidal composition obtained according to. the working method ^ .yan -, ... ·. cprip.!> jsie.; :: f-fungicide on agricultural and horticultural crops. .. ·. v ... ... . . A method for applying a pesticidal composition obtained according to the method according to claim 17, characterized in that the pesticidal composition on agricultural and horticultural crops is sprayed or sprayed. -