BE1002221A4 - NOVEL UNSATURATED BENZYLIDENE-3 CAMPHER DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR USE AS ABSORBERS OF ULTRA-VIOLET RADIATION IN COSMETICS AND AS INTERMEDIATES OF SYNTHESIS OF ORGANO-SILICAN COMPOUNDS. - Google Patents

NOVEL UNSATURATED BENZYLIDENE-3 CAMPHER DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR USE AS ABSORBERS OF ULTRA-VIOLET RADIATION IN COSMETICS AND AS INTERMEDIATES OF SYNTHESIS OF ORGANO-SILICAN COMPOUNDS. Download PDF

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Publication number
BE1002221A4
BE1002221A4 BE8801432A BE8801432A BE1002221A4 BE 1002221 A4 BE1002221 A4 BE 1002221A4 BE 8801432 A BE8801432 A BE 8801432A BE 8801432 A BE8801432 A BE 8801432A BE 1002221 A4 BE1002221 A4 BE 1002221A4
Authority
BE
Belgium
Prior art keywords
radical
benzylidene
preparation process
synthesis
silican
Prior art date
Application number
BE8801432A
Other languages
French (fr)
Inventor
Herve Richard
Serge Forestier
Gerard Lang
Original Assignee
Oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oreal filed Critical Oreal
Application granted granted Critical
Publication of BE1002221A4 publication Critical patent/BE1002221A4/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/70—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form
    • C07C45/71—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction with functional groups containing oxygen only in singly bound form being hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/657—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings
    • C07C49/683—Unsaturated compounds containing a keto groups being part of a ring containing six-membered aromatic rings having unsaturation outside the aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/703—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups
    • C07C49/747—Unsaturated compounds containing a keto groups being part of a ring containing hydroxy groups containing six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/753—Unsaturated compounds containing a keto groups being part of a ring containing ether groups, groups, groups, or groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Emergency Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un dérivé insaturé du benzylidène-3 camphre caractérisé par le fait qu'il répond à la formule dans laquelle R1 représente un atome d'hydrogène, un radical alkyle en C1-C6, un radical alcoxy en C1-C6 ou un radical -(O)n-(CH2)P-C(R4)=CH2 dans lequel n = 0 ou 1, p représente un nombre entier compris entre 1 et 10 et de préférence entre 1 et 4 et R4 représente un atome d'hydrogène ou un radical alkyle en C1-C4; R2 représente un atome d'hydrogène, un radical alkyle en C1-C6, un radical alcoxy en C1-C6 ou un radical -(CH2)p-C(R4)=CH2 dans lequel p et R4 ont les significations mentionnées ci-dessus; R3 représente un atome d'hydrogène, un radical alkyle en C1-C6 ou un radical alcoxy en C1-C6; sous réserve que l'un des restes R1 ou R2 représente respectivement un radical -(O)n-(CH2)p-C(R4)=CH2 ou un radical -(CH2)p-C(R4)=CH2 dans lesquels n, p et R4 ont les significations indiquées ci-dessus, son procédé de préparation et son utilisation en tant que filtre solaire et intermédiaire de synthèse.The invention relates to an unsaturated derivative of benzylidene-3 camphor, characterized in that it corresponds to the formula in which R1 represents a hydrogen atom, a C1-C6 alkyl radical, a C1-C6 alkoxy radical or a radical - (O) n- (CH2) PC (R4) = CH2 in which n = 0 or 1, p represents an integer between 1 and 10 and preferably between 1 and 4 and R4 represents a hydrogen atom or a C1-C4 alkyl radical; R2 represents a hydrogen atom, a C1-C6 alkyl radical, a C1-C6 alkoxy radical or a - (CH2) p-C (R4) = CH2 radical in which p and R4 have the meanings mentioned above; R3 represents a hydrogen atom, a C1-C6 alkyl radical or a C1-C6 alkoxy radical; provided that one of the residues R1 or R2 represents respectively a radical - (O) n- (CH2) pC (R4) = CH2 or a radical - (CH2) pC (R4) = CH2 in which n, p and R4 have the meanings indicated above, its preparation process and its use as a sunscreen and synthesis intermediate.

BE8801432A 1987-12-23 1988-12-23 NOVEL UNSATURATED BENZYLIDENE-3 CAMPHER DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR USE AS ABSORBERS OF ULTRA-VIOLET RADIATION IN COSMETICS AND AS INTERMEDIATES OF SYNTHESIS OF ORGANO-SILICAN COMPOUNDS. BE1002221A4 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
LU87093A LU87093A1 (en) 1987-12-23 1987-12-23 NOVEL UNSATURATED BENZYLIDENE-3 CAMPHOR DERIVATIVES, PROCESS FOR THEIR PREPARATION AND THEIR USE AS ABSORBERS OF ULTRA-PURPLE RADIATION IN COSMETICS AND AS INTERMEDIATES OF SYNTHESIS OF ORGANO-SILICON COMPOUNDS

Publications (1)

Publication Number Publication Date
BE1002221A4 true BE1002221A4 (en) 1990-10-16

Family

ID=19731006

Family Applications (1)

Application Number Title Priority Date Filing Date
BE8801432A BE1002221A4 (en) 1987-12-23 1988-12-23 NOVEL UNSATURATED BENZYLIDENE-3 CAMPHER DERIVATIVES, THEIR PREPARATION PROCESS AND THEIR USE AS ABSORBERS OF ULTRA-VIOLET RADIATION IN COSMETICS AND AS INTERMEDIATES OF SYNTHESIS OF ORGANO-SILICAN COMPOUNDS.

Country Status (9)

Country Link
JP (1) JP2612922B2 (en)
BE (1) BE1002221A4 (en)
CH (1) CH678180A5 (en)
DE (1) DE3843325C2 (en)
FR (1) FR2625195B1 (en)
GB (1) GB2212048B (en)
IT (1) IT1234233B (en)
LU (1) LU87093A1 (en)
NL (1) NL8803129A (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4027980A1 (en) * 1990-09-04 1992-03-05 Merck Patent Gmbh DIALKOXYBENZYLIDENKAMPFER DERIVATIVES
EP2422763A1 (en) 2010-08-27 2012-02-29 Colomer Beauty and Professional Products, S.L. Process and kit for treating hair

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2025957A (en) * 1978-07-11 1980-01-30 Oreal Oxybenzylidenebornanones their preparation and their use in cosmetics
FR2556592A1 (en) * 1983-12-14 1985-06-21 Oreal Pharmaceutical compositions containing camphormethylidenecinnamic acid derivatives

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU67061A1 (en) * 1973-02-19 1974-09-25
GB1575370A (en) * 1977-03-15 1980-09-17 Oreal Benzylidene-camphors processes for their preparation and cosmetic compositions containing them
LU85139A1 (en) * 1983-12-14 1985-09-12 Oreal NOVEL 3-BENZYLIDENE CAMPHOR DERIVATIVES, PROCESS FOR THEIR PREPARATION AND THEIR USE AS PROTECTIVE AGENTS AGAINST UV RAYS AND AS MEDICAMENTS

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2025957A (en) * 1978-07-11 1980-01-30 Oreal Oxybenzylidenebornanones their preparation and their use in cosmetics
FR2556592A1 (en) * 1983-12-14 1985-06-21 Oreal Pharmaceutical compositions containing camphormethylidenecinnamic acid derivatives

Also Published As

Publication number Publication date
GB2212048B (en) 1991-07-17
DE3843325A1 (en) 1989-07-06
GB2212048A (en) 1989-07-19
JP2612922B2 (en) 1997-05-21
CH678180A5 (en) 1991-08-15
FR2625195B1 (en) 1990-06-15
DE3843325C2 (en) 2000-05-18
JPH01211546A (en) 1989-08-24
FR2625195A1 (en) 1989-06-30
NL8803129A (en) 1989-07-17
IT1234233B (en) 1992-05-13
GB8830181D0 (en) 1989-02-22
LU87093A1 (en) 1989-07-07
IT8868141A0 (en) 1988-12-22

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Date Code Title Description
RE Patent lapsed

Owner name: L' OREAL

Effective date: 19971231