AU771123B2 - Cleansing compositions - Google Patents

Description

WO-00/42985 PCTln/ n ~ll 1n WO-OO/42985 PCT/1 5Ul l/ 1390 1 CLEANSING COMPOSITIONS Technical Field The present invention relates to cleansing compositions. In particular it relates to mild personal cleansing compositions which display improved deposition of skin care actives such as antimicrobials, sunscreens and vitamins. In addition, the compositions herein display improved rinse feel in combination with good skin feel attributes, and foaming properties which are suitable for simultaneously cleansing and conditioning the skin and/or the hair and which may be used, for example, in the form of foam bath preparations, shower products, skin cleansers, hand, face and body cleansers, shampoos, etc.

Background Of The Invention Mild cosmetic compositions must satisfy a number of criteria including cleansing power, foaming properties and mildness/low irritancy/good feel with respect to the skin, hair and the ocular mucosae. Skin is made up of several layers of cells which coat and protect the underlying tissue. The keratin and collagen fibrous proteins that form the skeleton of its structure. The outermost of these layers is referred to as the stratum corneum. Hair similarly has a protective outer coating enclosing the hair fibre which is called the cuticle. Anionic surfactants can penetrate the stratum corneum membrane and the cuticle and, by delipidization destroy membrane integrity and loss of barrier and water retention functions.

This interference with skin and hair protective membranes can lead to a rough skin feel and eye irritation and may eventually permit the surfactant to trigger immune response creating irritation.

WO 00/42985 PCT/US00/01390 2 Ideal cosmetic cleansers should cleanse the skin or hair gently, without defatting and/or drying the hair and skin and without irritating the ocular mucosae or leaving skin taut after frequent use. Most lathering soaps, shower and bath products, shampoos and bars fail in this respect.

Certain synthetic surfactants are known to be mild. However, a major drawback of some mild synthetic surfactant systems when formulated for shampooing or personal cleansing is that they have what can be described as a "slippy" or "non-draggy" rinse feel which is not liked by some consumers. The use of certain surfactants such as potassium laurate, on the other hand, can yield a "draggy" rinse feel but at the expense of clinical skin mildness. These two facts make the selection of suitable surfactants in the rinse feel and mildness benefit formulation process a delicate balancing act.

Thus a need exists for personal cleansing compositions which deliver a "draggy" rinse feel while at the same time having excellent skin mildness, in addition to excellent product characteristics such as lather, cleansing, stability, thickening, rheology and in-use skin feel attributes.

It is also desirable to deliver skin active components to the skin from a personal cleansing composition. Such skin active components include for example sunscreens, antimicrobials and vitamins.

Attempts have been made in the past to deliver skin care actives from personal cleansing compositions. However, these have not always been successful from the viewpoint of providing sufficient deposition of these actives on the skin such that they can be effective.

W097/16168 discloses personal cleansing compositions comprising surfactant, a hydrophobic active component selected from skin conditioning, skin protection and antibacterial agents, a hydrocarbon containing component and a cationic polymer, the quantities of and selected so that the effect on the skin by 3 component is enhanced over the additive effects of and alone.

Surprisingly, it has now been found that personal cleansing compositions having improved deposition of hydrophobic skin care actives at the same time as having a draggy rinse feel and excellent mildness characteristics are provided by the combination of certain water-insoluble oils, such as certain polyalphaolefin oils and certain hydrophobic skin active components, in combination with a mild, water-soluble surfactant system.

Throughout the description and claims of the specification the word "comprise" and variations of the word, such as "comprising" and "comprises", is not intended to exclude other additives, components, integers or steps.

The above discussion of documents, acts, materials, devices, articles and the like is included in this specification solely for the purpose of providing a context for the present invention. It is not suggested or represented that any or all of these matters formed part of the prior art base or were common general knowledge in the field relevant to the present invention as it existed in Australia before the priority date of each claim of this application.

Summary Of The Invention According to the present invention there is provided a rinse-off liquid personal cleansing composition comprising: 2 water; from about 1% to about 60% by weight of a water-soluble surfactant, a water-insoluble oil selected from highly branched polyalphaolefins having the following formula: i oooooo •i: JMN Y:\Viotet-GraceNo Delete\28539-O.doc R' C (CH 2 )n)m R 4 3

R

3 wherein R 1 is H or C1-C20 alkyl, R 4 is C1-C20 alkyl, R 2 is H or C1and R 3 is C3-C20 preferably from C5-C20, n is an integer from 0 to 3 and m is an integer of from 1 to 1000 and having a number average molecular weight of from about 1000 to about 25,000 and a viscosity of from about 300 cst to about 5,000 cst at 400C using the ASTM D-445 method for measuring viscosity; and a hydrophobic skin active component selected from antimicrobial agents, sunscreens, vitamins, perfume oils insect repellants, anti fungal agents, and mixtures thereof, wherein the hydrophobic skin active component has a ClogP value of greater than 3; wherein the composition comprises less than about 5% by weight, of soap.

S**

e *o JMN Y:\Violet-Grace\No Delete\28539-00.doc WO 00/42985 PCT/US00/01390 4 The compositions of the present invention provide an improvement in deposition of skin active components while at the same time being exceptionally mild to the skin and providing a "draggy" rinse feel.

All concentrations and ratios herein are by weight of the cleansing composition, unless otherwise specified. Surfactant chain lengths are also on a weight average chain length basis, unless otherwise specified.

Detailed Description of the Invention The liquid cleansing compositions herein comprise water, surfactant, hydrophobic skin active component, and a certain water-insoluble oil which will be described below.

As used herein the term "rinse feel" means the feeling of the skin during the process of rinsing lather from the skin after cleansing with a cleansing composition. The type of rinse feel which is provided by the compositions of the present invention can be described by terms such as a "draggy" rinse feel, a "soap-like" rinse feel and a "nonslippery" or "non-slimy" rinse feel. Such a "draggy", "soap-like", "nonslippery" or "non-slimy" rinse feel can be detected by an increase in friction between the hand and skin during the process of rinsing lather from the skin.

As used herein the term "water-insoluble" in relation to oils is a material which is substantially insoluble in distilled water at room temperature without the addition of other adjuncts and/or ingredients such as described herein.

As used herein the term "hydrophobic" in relation to skin active component means a material which is more lipid soluble, i.e. non aqueous soluble, than aqueous soluble. It is preferred that the materials have little solubility in water and are essentially nonionic in character as opposed to ionic.

Water-insoluble oil The water-insoluble oil for use herein is selected from highly branched polyalphaolefins having the following formula:

R

2 R (C (CH 2 )n)m-R 4

R

3 wherein R 1 is H or C 1

-C

20 alkyl, R 4 is C 1

-C

20 alkyl, R 2 is H or C 1

-C

2 0 and R 3 is

C

3

-C

2 0 preferably C 5

-C

20 n is an integer from 0 to 3 and m is an integer of from 1 to 1000 and having a number average molecular weight of from about 1000 to about 25,000, preferably from about 2500 to about 6000, more preferably from about 2500 to about 4000. Preferably the polyalphaolefins of type use herein have a viscosity of from about 300cst to about 50,000cst, preferably from about 1000cst to about 12,000 cst, more preferably from about 1000cst to about 4000cst at 40 0 C using the ASTM D-445 method for measuring viscosity. The oils of type may also have a degree of unsaturation, but are preferably S saturated.

Suitable polyalphaolefins of type as described above can be derived from 1alkene monomers having from about 4 to about 20 carbon atoms, preferably from about 6 to about 12 carbon atoms, especially from about 8 to about 12 carbon atoms. The polyalphaolefins useful herein are preferably hydrogenated 30 polyalphaolefin polymers.

Non-limiting examples of 1-alkene monomers for use in preparing the polyalphaolefin polymers herein include 1-hexene, 1-octene, 1-decene, 1o. dodecene, 1-tetradecene, branched chain isomers such as 4-methyl- -pentene, 35 and combinations thereof. Also suitable for preparing the polyolefin liquids are 1-hexene to 1-hexadecenes and JMN Y:\Violet-GraceNo Delete\28539-00.doc WO 00/42985 PCT/US00/01390 6 combinations thereof, more preferably 1-octene to 1-dodecene or combinations thereof.

Examples of such oils include polydecene oils such as those commercially available from Mobil Chemical Company, P.O. Box 3140, Edison, New Jersey 08818, USA, under the tradename Puresyn 40 and Puresyn 100.

Particularly preferred from the viewpoint of improving rinse feel of the composition is a highly branched polyalphaolefin material of type (a) having a number average molecular weight of from about 2500 to about 4000 and a viscosity of from about 100cst to about 2000 cst (ASTM D-445 at 45°C) such as that commercially available from Mobil under the tradename Puresyn 100.

Mixtures of the above oils are also suitable for use herein.

In preferred embodiments the number average particle diameter for the water-insoluble oil used herein lies in the range of from about 1 micron to about 500 microns, preferably from about 5 to about 200 microns, more preferably from about 5 to 50 microns, especially from about 5 to about 20 microns.

The compositions herein preferably comprise from about 0.1% to about 20%, more preferably from about 0.5% to about especially from about 1% to about 5% by weight of water-insoluble oil.

Hydrophobic Skin Active Component The compositions herein comprise a hydrophobic skin active component preferably at a level of from about 0.01% to about more preferably from about 0.01 to about especially from about 0.1 to about 3% by weight of composition.

WO 00/42985 PCT/US00/01390 7 Suitable hydrophobic skin actives for use herein include antimicrobial agents, sunscreens, vitamins, perfume oils, insect repellants, anti fungal agents, and mixtures thereof.

Suitable hydrophobic skin actives for use herein can be selected based upon their octanol/water partition coefficient. (P or Kow). The Kow provides an estimation of a chemical's lipophilicity. The Kow is the ratio of the concentration of a substance in the n-octanol phase to its concentration in the aqueous phase in an equilibrated two-phase octanol-water system. The partition coefficients of the hydrophobic skin care actives of this invention are conveniently given in the form of their logarithm to the base 10, log P.

The "log P" can be experimentally determined (MlogP) or can be calculated (ClogP). ClogP values can be calculated for instance with the "ClogP for Windows" software from Biobyte (Claremont, CA, USA) or with the ACD/LogP Calculator program from Advanced Chemistry Development Inc. (Toronto, Ontario, Canada). The Biobyte program also contains some measured logP values where available. It will be understood by those skilled in the art that for some chemicals it is difficult to obtain calculated logP values and that in such cases measured logP values can be used instead.

Conversely, for some chemicals, measured logP values are difficult to obtain and in such cases calculated logP values can be used instead. In general, the measured logP values and the calculated logP values are found to be comparable.

The hydrophobic skin actives suitable herein are those selected from skin actives having a Clog P value of greater than 3, preferably greater than 5. It is preferable that the hydrophobic skin actives herein have a ClogP value of no greater than Examples of suitable antibacterial agents which can be used herein include, but are not limited to, the dicarbanilides, for example, triclocarban also known as trichlorocarbanilide, triclosan, WO 00/42985 PCT/US00/01390 8 hexachlorophene and 3,4,5-tribromosalicylanilide. A preferred antibacterial agent herein is triclorocarbanilide.

Examples of suitable sunscreens for use herein include but are not limited to Octyl dimethyl paraaminobenzoate, 3,3,5- Trimethylcyclohexylsalicylate (Homosalate), 2-hydroxy-4-methoxybenzophenone (Benzophenone-3), Butyl methoxy dibenzoyl methane, Octyl Methoxy-cinnamate, 4-methoxy-2,2'dihydroxybenzophenone (Dioxybenzone), Dihydroxy dimethoxy benzophenone (Benzophenone-6), Guaiazulene, 2-cyano-3,3diphenyl acrylic ester-2-ethylhexylester (octocrylene), and mixtures thereof. A preferred sunscreen herein is Octylmethoxycinnamate.

Examples of suitable vitamins for use herein include but are not limited to vitamin A and its esters, vitamin E and its esters, vitamin D and vitamin K, and mixtures thereof.

Examples of suitable insect repellants for use herein include but is not limited to Dibutylphthalate.

Examples of suitable perfume oils for use herein include but are not limited to Ambrettolide commercially available from International Flavors Fragrances (IFF), Liebegerweg 72-98, 1221 JT Hilversum, The Netherlands, Ambrinol T commercially available from Takasago International Corp. (USA), 11 Volvo Drive, Rockleigh, NJ 07647- 0932, USA, Benzylsalicylate, Citronellylacetate, Damascenone commercially available from Firmenich SA, 1, Route des Jeunes, CH- 1211 Geneva 8, Switzerland, Habanolide (Firmenich), lonone gamma Methyle (available from Givaudan-Roure, 19-23 voie des Bans, BP98, 95101 Argenteuil Cedex France), lonone beta (available from Givaudan-Roure), Norlimbanol (Firmenich), Sanjinol (IFF), Undelactone gamma (available from Givaudan-Roure), Vetiverylacetate (available from Bonpard, HGH Fragrance Resources, Borstelmannsweg 169, D-20537 Hamburg, Germany, Vertofix Coeur (IFF), and mixtures thereof.

WO 00/42985 PCT/US00/01390 9 Examples of suitable anti-fungal agents for use herein include but are not limited to Butylparaben, hexachlorophene, Cloflucarban, undecylenic acid and its esters and mixtures thereof.

Particularly preferred hydrophobic skin actives for use herein are antimicrobials, vitamins and their derivatives and sunscreens, especially antimicrobials, in particular, trichlorocarbanilide.

Surfactant System As a further essential feature the compositions of the present invention comprise a surfactant system of water-soluble surfactants.

Water-soluble, as defined herein, means a surfactant having a molecular weight of less than about 20,000 wherein the surfactant is capable of forming a clear isotropic solution when dissolved in water at 0.2 w/w under ambient conditions. Surfactants suitable for inclusion in compositions according to the present invention generally have a lipophilic chain length of from about 6 to about 22 carbon atoms and can be selected from anionic, nonionic, zwitterionic and amphoteric surfactants and mixtures thereof. The total level of surfactant is preferably from about 2% to about 40%, more preferably from about 3% to about 25% by weight, and especially from about to about 20% by weight. The compositions preferably comprise a mixture of anionic with zwitterionic and/or amphoteric surfactants.

The weight ratio.of anionic surfactant: zwitterionic and/or amphoteric surfactant is in the range from about 1:10 to about 10:1, preferably from about 1:5 to about 5:1, more preferably from about 1:3 to about 3:1. Other suitable compositions within the scope of the invention comprise mixtures of anionic, zwitterionic and/or amphoteric surfactants with one or more nonionic surfactants.

The compositions of the invention can comprise a water-soluble anionic surfactant at levels from about 0.1% to about 25%, more preferably from about 1% to about 20%, and especially from about to about 15% by weight.

WO 00/42985 PCTIUSOO/01390 Water soluble anionic surfactants suitable for inclusion in the compositions of the invention include alkyl sulfates, ethoxylated alkyl sulfates, alkyl ethoxy carboxylates, alkyl glyceryl ether sulfonates, ethoxy ether sulfonates, methyl acyl taurates, fatty acyl glycinates, Nacyl glutamates, acyl isethionates, alkyl sulfosuccinates, alkyl ethoxysulphosuccinates, alpha-sulfonated fatty acids, their salts and/or their esters, alkyl phosphate esters, ethoxylated alkyl phosphate esters, acyl sarcosinates and fatty acid/protein condensates, soaps such as ammonium, magnesium, potassium, triethanolamine and sodium salts of lauric acid, myristic acid and palmitic acid, acyl aspartates, alkoxy cocamide carboxylates, (ethoxylated) alkanolamide sulphosuccinates, ethoxylated alkyl citrate sulphosuccinates, acyl ethylene diamine triacetates, acylhydroxyethyl isethionates, acyl amide alkoxy sulfates, linear alkyl benzene sulfonates, paraffin sulfonates, alpha olefin sulfonates, alkyl alkyoxy sulfates, and mixtures thereof. Alkyl and/or acyl chain lengths for these surfactants are C6-C22, preferably C12-C18 more preferably C12-C14.

Additional water-soluble anionic surfactants suitable for use in the compositions according to the present invention are the salts of sulfuric acid esters of the reaction product of 1 mole of a higher fatty alcohol and from about 1 to about 12 moles of ethylene oxide, with sodium, ammonium and magnesium being the preferred counterions.

Particularly preferred are the alkyl ethoxy sulfates containing from about 2 to 6, preferably 2 to 4 moles of ethylene oxide, such as sodium laureth-2 sulfate, sodium laureth-3 sulfate, .mmonium laureth-3 sulfate and magnesium sodium laureth-3.6 sulfate. In preferred embodiments, the anionic surfactant contains at least about especially at least about 75% by weight of ethoxylated alkyl sulfate.

In addition to the broad range ethoxylated alkyl sulfates obtained via conventional sodium catalysed ethoxylation techniques and subsequent sulphation processes, ethoxylated alkyl sulfates obtained from narrow range ethoxylates (NREs) are also suitable water- WO 00/42985 PCT/US00/01390 11 soluble anionic surfactants for use in the present compositions.

Narrow range ethoxylated alkyl sulfates suitable for use herein are selected from sulphated alkyl ethoxylates containing on average from about 1 to about 6, preferably from about 2 to about 4 and especially about 3 moles of ethylene oxide such as NRE sodium laureth-3 sulfate. NRE materials suitable for use herein contain distributions of the desired ethylene oxide (EOn) in the ranges of from 15% to about by weight of EOn, from about 10% to about 20% by weight of EOn+1 and from about 10% to about 20% by weight of EOn-1.

Highly preferred NRE materials contain less than about 9% by weight of ethoxylated alkyl sulfate having 7 or more moles of ethylene oxide and less than about 13% by weight of non-ethoxylated alkyl sulfate.

Suitable laureth 3 sulfate NRE materials are available from Hoechst under the trade names GENAPOL ZRO Narrow Range and GENAPOL Narrow Range.

The compositions of the present invention may contain, as a watersoluble anionic surfactant alkyl ethoxy carboxylate surfactant at a level of from about 0.5% to about 15%, preferably from about 1% to about 10%, more preferably from about 1% to about 6% and especially from about 1% to about 4% by weight. Alkyl ethoxy carboxylate surfactant is particularly valuable in the compositions according to the present invention for the delivery of excellent skin mildness attributes in combination with excellent rinsing performance and desirable lather characteristics.

Alkyl ethoxy carboxylates suitable for use herein have the general formula

R

3 0(CH2CH20)kCH2COO-M wherein R 3 is a C10 to C16 alkyl or alkenyl group, preferably a C11more preferably a C12-C14 alkyl or C12-C13 alkyl group, k is an average value of ethoxylation ranging from 2 to about 7, preferably from about 3 to about 6, more preferably from about 3.5 to about 5.5, especially from about 4 to about 5, most preferably from WO 00/42985 PCTUSO/01390 12 about 4 to about 4.5, and M is a water-solubilizing cation, preferably an alkali metal, alkaline earth metal, ammonium, lower alkanol ammonium, and mono-, di-, and tri-ethanol ammonium, more preferably sodium, potassium and ammonium, most preferably sodium and ammonium and mixtures thereof with magnesium and calcium ions.

Particularly preferred as water-soluble anionic surfactants suitable for use herein are alkyl ethoxy carboxylate surfactants having a selected distribution of alkyl chain length and/or ethoxylate. Thus, the alkyl ethoxy carboxylate surfactants suitable for use in the compositions according to the present invention may comprise a distribution of alkyl ethoxy carboxylates having different average values of R 3 and/or k.

The average value of k will generally fall in the range of from about 3 to about 6 when the average R 3 is C11, C12, C13 or C14. Preferred water-soluble anionic alkyl ethoxy carboxylate surfactants suitable for use herein are the C12 to C14 (average EO 3-6) ethoxy carboxylates and the C12 to C13 (average EO 3-6) ethoxy carboxylates. Suitable materials include salts of NEODOX 23-4 (RTM) available from Shell Inc. (Houston, Texas, USA) and EMPICOL (RTM) CBCS (Albright Wilson). Highly preferred for use herein are alkyl ethoxy carboxylate surfactants wherein, when R 3 is a C12-C14 or C12-C13 alkyl group and the average value of k is in the range of from about 3 to about 6, more preferably from about 3.5 to about 5.5, especially from about 4 to about 5 and most preferably from about 4 to about In preferred embodiments the compositions are substantially free of soap, i.e. they contain less than about preferably less than about preferably by weight, of soap.

The compositions according to the present invention may additionally comprise water-soluble nonionic surfactant at levels from about 0.1% to about 20%, more preferably from about 0.1% to about 10%, and especially from about 1% to about 8% by weight. Surfactants of this WO 00/42985 PCT/US00/01390 13 class include sucrose polyester surfactants, C10-C18 alkyl polyglycosides and polyhydroxy fatty acid amide surfactants having the general formula (Ill).

o R9 1i I

R

8

-C-N-Z

2 The preferred N-alkyl, N-alkoxy or N-aryloxy, polyhydroxy fatty acid amide surfactants according to formula (III) are those in which R8 is C5-C31 hydrocarbyl, preferably C6-C19 hydrocarbyl, including straight-chain and branched chain alkyl and alkenyl, or mixtures thereof and R9 is typically, hydrogen, C1-C8 alkyl or hydroxyalkyl, preferably methyl, or a group of formula -R1-O-R 2 wherein R1 is C2- C8 hydrocarbyl including straight-chain, branched-chain and cyclic (including aryl), and is preferably C2-C4 alkylene, R 2 is C1-C8 straight-chain, branched-chain and cyclic hydrocarbyl including aryl and oxyhydrocarbyl, and is preferably C1-C4 alkyl, especially methyl, or phenyl. Z 2 is a polyhydroxyhydrocarbyl moiety having a linear hydrocarbyl chain with at least 2 (in the case of glyceraldehyde) or at least 3 hydroxyls (in the case of other reducing sugars) directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z2 preferably will be derived from a reducing sugar in a reductive ammination reaction, most preferably Z2 is a glycityl moiety. Suitable reducing sugars include glucose, fructose, maltose, lactose, galactose, mannose, and xylose, as well as glyceraldehyde. As raw materials, high dextrose corn syrup, high fructose corn syrup, and high maltose corn syrup can be utilised as well as the individual sugars listed above. These corn syrups may yield a mix of sugar components for Z 2 It should be understood that it is by no means intended to exclude other suitable raw materials. Z2 preferably will be selected from the group consisting of CH2-(CHOH)n-CH20H, CH(CH20H)-(CHOH)n-1- CH2(CHOH)2(CHOR')CHOH)CH 2 0H, where n is an integer from 1 to 5, inclusive, and R' is H or a cyclic mono- or polysaccharide, and alkoxylated derivatives thereof. As noted, most WO 00/42985 PCT/US00/01390 14 preferred are glycityls wherein n is 4, particularly CH2-(CHOH) 4 The most preferred polyhydroxy fatty acid amide has the formula R8(CO)N(CH 3

)CH

2 (CHOH)4CH 2 0H wherein R8 is a C 6

-C

19 straight chain alkyl or alkenyl group. In compounds of the above formula, R8-CO-N< can be, for example, cocoamide, stearamide, oleamide, lauramide, myristamide, capricamide, caprylicamide, palmitamide, tallowamide, etc.

Exemplary non-ionic surfactants suitable for use in the compositions according to the present invention include primary amines such as cocamine (available as Adagen 160D (TM) from Witco) and alkanolamides such as cocamide MEA (available as Empilan CME (TM) from Albright and Wilson), PEG-3 cocamide, cocamide DEA (available as Empilan CDE (TM) from Albright and Wilson), lauramide MEA (available as Empilan LME (TM) from Albright and Wilson), lauramide MIPA, lauramide DEA, and mixtures thereof.

Suitable amphoteric surfactants for use herein include ammonium derivatives of formula

R

1

CON(CH

2 2 N CH2CO 2

M

R3

R

2 wherein R1 is C 5

-C

2 2 alkyl or alkenyl, R2 is CH2CH 2 0H or CH2CO 2 M, M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium and R3 is CH2CH20H or H; aminoalkanoates of formula [VI] R1NH(CH2)nCO2M iminodialkanoates of formula [VII] R1N[(CH2)mCO2M]2 WO 00/42985 PCT/USOO/01390 and iminopolyalkanoates of formula (VIII) RI[N(CH2)p]q N [CH2CO 2

M]

2 CH2CO2M wherein n, m, p, and q are numbers from 1 to 4, and R1 and M are independently selected from the groups specified above; and mixtures thereof.

Suitable amphoteric surfactants of type include compounds of formula in which R1 is C8H17 (especially isocapryl), C9H 1 9 and C1i1H23 alkyl. Suitable amphoteric surfactants of type are marketed under the trade name Miranol and Empigen.

In CTFA nomenclature, materials suitable for use in the present invention include cocoamphocarboxypropionate, cocoamphocarboxy propionic acid, cocoamphoacetate, cocoamphodiacetate (otherwise referred to as cocoamphocarboxyglycinate), sodium lauroamphoacetate (otherwise referred to as sodium lauroamphocarboxyglycinate). Specific commercial products include those sold under the trade names of Ampholak 7TX (sodium carboxy methyl tallow polypropyl amine), Empigen CDL60 and CDR (Albright Wilson), Miranol H2M Conc. Miranol C2M Conc. N.P., Miranol C2M Conc. Miranol C2M SF, Miranol CM Special, Miranol Ultra L32 and C32 (Rh6ne-Poulenc); Alkateric 2CIB (Alkaril Chemicals); Amphoterge W-2 (Lonza, Inc.); Monateric CDX-38, Monateric CSH-32 (Mona Industries); Rewoteric AM-2C (Rewo Chemical Group); and Schercotic MS-2 (Scher Chemicals).

It will be understood that a number of commercially-available amphoteric surfactants of this type are manufactured and sold in the form of electroneutral complexes with, for example, hydroxide WO 00/42985 PCTIUSOO/01390 16 counterions or with anionic sulfate or sulfonate surfactants, especially those of the sulfated C8-C18 alcohol, C8-C 1 8 ethoxylated alcohol or C8-C18 acyl glyceride types. Preferred from the viewpoint of mildness and product stability, however, are compositions which are essentially free of (non-ethoxylated) sulfated alcohol surfactants.

Note also that the concentrations and weight ratios of the amphoteric surfactants are based herein on the uncomplexed forms of the surfactants, any anionic surfactant counterions being considered as part of the overall anionic surfactant component content.

Examples of suitable amphoteric surfactants of type include Nalkyl polytrimethylene poly-, carboxymethylamines sold under the trade names Ampholak X07 and Ampholak 7CX by Berol Nobel and also salts, especially the triethanolammonium salts and salts of Nlauryl-beta-amino propionic acid and N-lauryl-imino-dipropionic acid.

Such materials are sold under the trade name Deriphat by Henkel and Mirataine by Rh6ne-Poulenc.

The compositions herein can also contain from about 0.1% to about more preferably from about 0.1% to about 10%, and especially from about 1% to about 8% by weight of a zwitterionic surfactant.

Water-soluble betaine surfactants suitable for inclusion in the compositions of the present invention include alkyl betaines of the formula R5R6R7N (CH2)nCO2M and amido betaines of the formula

(IX)

R

6

R

5

CON(CH

2 )mN (CH 2 nCO 2

R

7 wherein R5 is C5-C22 alkyl or alkenyl, R6 and R7 are independently C1-C3 alkyl, M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium, and n, m are each numbers from 1 to 4.

Preferred betaines include cocoamidopropyldimethylcarboxymethyl WO 00/42985 PCTIUSOO/01390 17 betaine, commercially available from TH Goldschmidt under the tradename Tego betaine, and laurylamidopropyldimethylcarboxymethyl betaine, commercially available from Albright and Wilson under the tradename Empigen BR and from TH Goldschmidt under the tradename Tegobetaine Water-soluble sultaine surfactants suitable for inclusion in the compositions of the present invention include alkylamido sultaines of the formula; R2

R

1

CON(CH

2 )mN+(CH 2 )nCH(OH)CH 2

SO

3

-M

R

3 wherein R1 is C 7 to C22 alkyl or alkenyl, R2 and R3 are independently Ci to C3 alkyl, M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium and m and n are numbers from 1 to 4. Suitable for use herein is coco amido propylhydroxy sultaine which is commercially available under the tradename Mirataine CBS from Rhone-Poulenc.

Water-soluble amine oxide surfactants suitable for inclusion in the compositions of the present invention include alkyl amine oxide R5R6R7NO and amido amine oxides of the formula R6 R5CON(CH2)mN O R7 WO 00/42985 PCT/US00/01390 18 wherein R5 is C11 to C22 alkyl or alkenyl, R6 and R7 are independently C1 to C3 alkyl, M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium and m is a number from 1 to 4. Preferred amine oxides include cocoamidopropylamine oxide, lauryl dimethyl amine oxide and myristyl dimethyl amine oxide.

Suspending Agents The compositions herein preferably also include one or more suspending agents. Suitable suspending agents for use herein include any of several long chain acyl derivative materials or mixtures of such materials. Included are ethylene glycol esters of fatty acids having from about 16 to about 22 carbon atoms. Preferred are the ethylene glycol stearates, both mono and distearate, but particularly the distearate containing less than about 7% of the mono stearate.

Other suspending agents found useful are alkanol amides of fatty acids, having from about 16 to 22 carbon atoms, preferably from about 16 to 18 carbon atoms. Preferred alkanol amides are stearic monoethanolamide, stearic diethanolamide, stearic monoisopropanolamide and stearic monoethanolamide stearate.

Still other suitable suspending agents are alkyl (C16-C22) dimethyl amine oxides such as stearyl dimethyl amino oxide and trihydroxystearin commercially available under the tradename Thixcin (RTM) from Rheox. A preferred suspending agent for use herein is Thixcin (RTM) from Rheox.

The suspending agent is preferably present at a level of from about 0.1% to about preferably from about 0.1% to about The suspending agents serves to assist in suspending the water-insoluble oil and may give pearlescence to the product. Mixtures of suspending agents are also suitable for use in the compositions of this invention.

Optional Ingredients WO 00/42985 PCT/US00/01390 19 Polymeric Cationic Conditionina Aaent The compositions according to the present invention can optionally include a polymeric cationic conditioning agent. Polymeric cationic conditioning agents are valuable in the compositions according to the present invention for provision of desirable skin feel attributes. Also, the addition of a polymeric cationic conditioning agent may be advantageous in combination with the water-insoluble oil for providing enhanced deposition of hydrophobic skin care active. If present, the polymeric skin conditioning agent is preferably present at a level from about 0.01% to about preferably from about 0.01% to about 3% and especially from about 0.01% to about 2% by weight.

Suitable polymers are high molecular weight materials (massaverage molecular weight determined, for instance, by light scattering, being generally from about 2,000 to about 5,000,000, preferably from about 5,000 to about 3,000,000 more preferably from 100,000 to about 1,000,000).

Representative classes of polymers include cationic guar gums, cationic polysaccharides; cationic homopolymers and copolymers derived from acrylic and/or methacrylic acid; cationic cellulose resins, quaternized hydroxy ethyl cellulose ethers; cationic copolymers of dimethyldiallylammonium chloride and acrylamide and/or acrylic acid; cationic homopolymers of dimethyldiallylammonium chloride; copolymers of dimethyl aminoethylmethacrylate and acrylamide, acrylic acid/dimethyldiallylammonium chloride/acrylamide copolymers, quaternised vinyl pyrrolidone acrylate or methacrylate copolymers of amino alcohol, quaternized copolymers of vinyl pyrrolidone and dimethylaminoethylmethacrylamide, vinyl pyrollidone/vinyl imidazolium methochloride copolymers and polyalkylene and ethoxypolyalkylene imines; quaternized silicones, terpolymers of acrylic acid, methacrylamidopropyl trimethyl ammonium chloride and methyl acrylate, and mixtures thereof.

WO 00/42985 PCT/US00/01390 By way of exemplification, cationic polymers suitable for use herein include cationic guar gums such as hydroxypropyl trimethyl ammonium guar gum of from 0.11 to 0.22) available commercially under the trade names Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and also Jaguar C-16(RTM), which contains hydroxypropyl substituents of from 0.8-1.1) in addition to the above-specified cationic groups, and quaternized hydroxy ethyl cellulose ethers available commercially under the trade names Ucare Polymer JR-30M, JR-400, LR400, Catanal (RTM) and Celquat. Other suitable cationic polymers are homopolymers of dimethyldiallylammonium chloride available commercially under the trade name Merquat 100, copolymers of dimethyl aminoethylmethacrylate and acrylamide, copolymers of dimethyldiallylammonium chloride and acrylamide, available commercially under the trade names Merquat 550 and Merquat S, acrylic acid/dimethyldiallylammonium chloride/acrylamide copolymers available under the trade name Merquat 3330, terpolymers of acrylic acid, methacrylamidopropyl trimethyl ammonium chloride and methyl acrylate commercially available under the tradename Merquat 2001, quaternized vinyl pyrrolidone acrylate or methacrylate copolymers of amino alcohol available commercially under the trade name Gafquat, for example Polyquaternium 11, 23 and 28 (quaternized copolymers of vinyl pyrrolidone and dimethyl aminoethylmethacrylate Gafquat 755N and quaternized copolymers of vinyl pyrrolidone and dimethyl aminoethylmethacrylamide HS-100), vinyl pyrrolidone/vinyl imidazolium methochloride copolymers available under the trade names Luviquat FC370, Polyquaternium 2, and polyalkyleneimines such as polyethylenimine and ethoxylated polyethylenimine. Also suitable for use herein are those cationic polymers commercially available under the tradename Aqualon N-Hance.

The compositions of the invention may also contain from about 0.1% to about 20%, preferably from about 1% to about 15%, and more preferably from about 2% to about 10% by weight of an oil derived nonionic surfactant or mixture of oil derived nonionic surfactants. Oil derived nonionic surfactants are valuable in compositions according WO 00/42985 PCT/US00/01390 21 to the invention for the provision of skin feel benefits both in use and after use. Suitable oil derived nonionic surfactants for use herein include water soluble vegetable and animal-derived emollients such as triglycerides with a polyethyleneglycol chain inserted; ethoxylated mono and di-glycerides, polyethoxylated lanolins and ethoxylated butter derivatives. One preferred class of oil-derived nonionic surfactants for use herein have the general formula (XII) 0

RCOCH

2 CH (OH)CH 2

(OCH

2

CH

2 )nOH wherein n is from about 5 to about 200, preferably from about 20 to about 100, more preferably from about 30 to about 85, and wherein R comprises an aliphatic radical having on average from about 5 to carbon atoms, preferably from about 7 to 18 carbon atoms.

Suitable ethoxylated oils and fats of this class include polyethyleneglycol derivatives of glyceryl cocoate, glyceryl caproate, glyceryl caprylate, glyceryl tallowate, glyceryl palmate, glyceryl stearate, glyceryl laurate, glyceryl oleate, glyceryl ricinoleate, and glyceryl fatty esters derived from triglycerides, such as palm oil, almond oil, and corn oil, preferably glyceryl tallowate and glyceryl cocoate.

Suitable oil derived nonionic surfactants of this class are available from Croda Inc. (New York, USA) under their Crovol line of materials such as Crovol EP40 (PEG 20 evening primrose glyceride), Crovol EP 70 (PEG 60 evening primrose glyceride) Crovol A-40 (PEG almond glyceride), Crovol A-70 (PEG 60 almond glyceride), Crovol (PEG 20 maize glyceride), Crovol M-70 (PEG 60 maize glyceride), Crovol PK-40 (PEG 12 palm kernel glyceride), and Crovol (PEG 45 palm kernel glyceride) and under their Solan range of materials such as Solan E, E50 and X polyethoxylated lanolins and Aqualose L-20 (PEG 24 lanolin alcohol) and Aqualose W15 (PEG lanolin alcohol) available from Westbrook Lanolin. Further suitable surfactants of this class are commercially available from Sherex WO 00/42985 PCT/US00/01390 22 Chemical Co. (Dublin, Ohio, USA) under their Varonic LI line of surfactants and from Rewo under their Rewoderm line of surfactants.

These include, for example, Varonic LI 48 (polyethylene glycol glyceryl tallowate, alternatively referred to as PEG 80 glyceryl tallowate), Varonic LI 2 (PEG 28 glyceryl tallowate), Varonic LI 420 (PEG 200 glyceryl tallowate), and Varonic LI 63 and 67 (PEG 30 and PEG 80 glyceryl cocoates), Rewoderm L15-20 (PEG-200 palmitate), Rewoderm LIS-80 (PEG-200 palmitate with PEG-7 glyceryl cocoate) and Rewoderm LIS-75 (PEG-200 palmitate with PEG-7 glyceryl cocoate) and mixtures thereof. Other oil-derived emollients suitable for use are PEG derivatives of corn, avocado, and babassu oil, as well as Softigen 767 (PEG(6) caprylic/capric glycerides).

Also suitable for use herein are nonionic surfactants derived from composite vegetable fats extracted from the fruit of the Shea Tree (Butyrospermum Karkii Kotschy) and derivatives thereof. This vegetable fat, known as Shea Butter is widely used in Central Africa for a variety of means such as soap making and as a barrier cream, it is marketed by Sederma (78610 Le Perray En Yvelines, France).

Particularly suitable are ethoxylated derivatives of Shea butter available from Karlshamn Chemical Co. (Columbos, Ohio, USA) under their Lipex range of chemicals, such as Lipex 102 E-75 and Lipex 102 E-3 (ethoxylated mono, di-glycerides of Shea butter) and from Croda Inc. (New York, USA) under their Crovol line of materials such as Crovol SB-70 (ethoxylated mono, di-glycerides of Shea butter). Similarly, ethoxylated derivatives of Mango, Cocoa and Illipe butter may be used in compositions according to the invention.

Although these are classified as ethoxylated nonionic surfactants it is understood that a certain proportion may remain as non-ethoxylated vegetable oil or fat.

Other suitable oil-derived nonionic surfactants include ethoxylated derivatives of almond oil, peanut oil, rice bran oil, wheat germ oil, linseed oil, jojoba oil, oil of apricot pits, walnuts, palm nuts, pistachio nuts, sesame seeds, rapeseed, cade oil, corn oil, peach pit oil, poppyseed oil, pine oil, castor oil, soybean oil, avocado oil, safflower 23 oil, coconut oil, hazelnut oil, olive oil, grapeseed oil, and sunflower seed oil.

Oil derived nonionic surfactants highly preferred for use herein from the viewpoint of optimum mildness and skin feel characteristics are Lipex 102-3 (RTM) (PEG-3 ethoxylated derivatives of Shea Butter) and Softigen 767 (RTM) (PEG-6 caprylic/capric glycerides).

The compositions according to the present invention can also comprise lipophilic emulsifiers as additional skin care actives. Suitable lipophilic skin care actives include anionic food grade emulsifiers which comprise a di-acid mixed with a monoglyceride such as succinylated monoglycerides, monostearyl citrate, glyceryl monostearate diacetyl tartrate and mixtures thereof.

In addition to the water-insoluble polyalphaolefin oils described above other water-insoluble oils can be used in the compositions of the present invention.

Additional water-insoluble oils for use in the personal cleansing compositions of the present invention those of type which are branched alk(en)yl materials having the following formula:

R

2

I

R C( (CH 2

R

4

R

3

R

S i wherein R 1 is H or C1-C4 alkyl, R 4 is Cl-C4 alkyl, R 2 is H or C1-C4 alkyl or C2-C4 alkenyl, and R 3 is H or C1-C4 alkyl or 02-04 alkenyl, n is an integer from 0 to 3 and m is an integer of from 1 to 1000 and having a number average molecular weight of from about 600 to about 1000, preferably from about 750 to about 30 1000, especially from about 800 to about 1000. Preferably the branched *alk(en)yl materials of type have a viscosity in the range of from about 500cst to about 50,000cst, preferably from about 1000cst to about 10,000cst measured at 400C using the ASTM method D-445 for measuring viscosity.

*I

JMN Y:Violet-GracelNo Delete\28539-00.doc WO 00/42985 PCT/USOO/01390 24 Suitable alk(en)yl materials of type for use herein are polymers of butene, isoprene, terpene, styrene or isobutene, preferably butene or isobutene.

Examples of alk(en)yl oils of type include polybutene oils such as those commercially available from Amoco under the tradename Indopol 40 and Indopol 100 and polyisobutene oils such as those commercially available from Presperse Inc. under the tradename Permethyl 104A and Parapol 950 from Exxon Chemicals Co..

Also suitable for use herein are hydrophobically modified silicones having the following formula: hydrophobically modified silicones having the following formula: R'-Si-O Si-O Si-O--Si-R' I I I I R' (CH2)z R R' c CH 3 x wherein R is C1-C4 alkyl or phenyl, R' is C1-C20 alkyl or phenyl, z is to 21, and x has a number average value in the range of from about to 400, y has a number average value in the range of from about 0 to about 10 and x y lies in the range of 30 to 400. Preferred materials have values for x of from 40 to 200, preferably 60 to 100, values for y of from 0 to 5, preferably 0, and values for the sum of x and y of from 60 to 100. The alkylene chain z may be linear or branched. In addition, the silicone backbone may contain a small degree of branching to yield a resin (eg. MDQ or MDT resins).

Examples of such oils include those hydrophobically modified silicones available from GE Silicones under the tradename SF1632 (C16-C18 alkyl methicone), and octyl and decyl methicone.

WO 00/42985 PCT/US00/01390 In preferred embodiments the number average particle diameter for the additional water-insoluble oil used herein lies in the range of from about 1 micron to about 500 microns, preferably from about 5 to about 200 microns, more preferably from about 5 to 50 microns, especially from about 5 to about 20 microns.

Another water-insoluble, skin/hair care ingredient suitable for use in the foaming compositions herein is a liquid, polyol carboxylic acid ester.

The polyol ester preferred for use herein is a nonocclusive liquid or liquifiable polyol carboxylic acid ester. These polyol esters are derived from a polyol radical or moiety and one or more carboxylic acid radicals or moieties. In other words, these esters contain a moiety derived from a polyol and one or more moieties derived from a carboxylic acid. These carboxylic acid esters can also be derived from a carboxylic acid. These carboxylic acid esters can also be described as liquid polyol fatty acid esters, because the terms carboxylic acid and fatty acid are often used interchangeably by those skilled in the art.

The preferred liquid polyol polyesters employed in this invention comprise certain polyols, especially sugars or sugar alcohols, esterified with at least four fatty acid groups. Accordingly, the polyol starting material must have at least four esterifiable hydroxyl groups.

Examples of preferred polyols are sugars, including monosaccharaides and disaccharides, and sugar alcohols.

Examples of monosaccharides containing four hydroxyl groups are xylose and arabinose and the sugar alcohol derived from xylose, which has five hydroxyl groups, xylitol. The monosaccharide, erythrose, is not suitable in the practice of this invention since it only contains three hydroxyl groups, but the sugar alcohol derived from erythrose, erythritol, contains four hydroxyl groups and accordingly can be used. Suitable five hydroxyl group-containing monosaccharides are galactose, fructose, and sorbose. Sugar alcohols containing six -OH groups derived from the hydrolysis WO 00/42985 PCT/US00/01390 26 products of sucrose, as well as glucose and sorbose, sorbitol, are also suitable. Examples of disaccharide polyols which can be used include maltose, lactose, and sucrose, all of which contain eight hydroxyl groups.

Preferred polyols for preparing the polyesters for use in the present invention are selected from the group consisting of erythritol, xylitol, sorbitol, glucose, and sucrose. Sucrose is especially preferred.

The polyol starting material having at least four hydroxyl groups is esterified on at least four of the -OH groups with a fatty acid containing from about 8 to about 22 carbon atoms. Examples of such fatty acids include caprylic, capric, lauric, myristic, myristoleic, palmitic, palmitoleic, stearic, oleic, ricinoleic, linoleic, linolenic, eleostearic, arachidic, arachidonic, behenic, and erucic acid. The fatty acids can be derived from naturally occurring or synthetic fatty acids; they can be saturated or unsaturated, including positional and geometrical isomers. However, in order to provide liquid polyesters preferred for use herein, at least about 50% by weight of the fatty acid incorporated into the polyester molecule should be unsaturated.

Oleic and linoleic acids, and mixtures thereof, are especially preferred.

The polyol fatty acid polyesters useful in this invention should contain at least four fatty acid ester groups. It is not necessary that all of the hydroxyl groups of the polyol be esterified with fatty acid, but it is preferable that the polyester contain no more than two unesterified hydroxyl groups. Most preferably, substantially all of the hydroxyl groups of the polyol are esterified with fatty acid, the polyol moiety is substantially completely esterified. The fatty acids esterified to the polyol molecule can be the same or mixed, but as noted above, a substantial amount of the unsaturated acid ester groups must be present to provide liquidity.

To illustrate the above points, a sucrose fatty triester would not be suitable for use herein because it does not contain the required four WO 00/42985 PCTIUSOO/01390 27 fatty acid ester groups. A sucrose tetra-fatty acid ester would be suitable, but is not preferred because it has more than two unesterified hydroxyl groups. A sucrose hexa-fatty acid ester would be preferred because it has no more than two unesterified hydroxyl groups. Highly preferred compounds in which all the hydroxyl groups are esterified with fatty acids include the liquid sucrose octasubstituted fatty acid esters.

The following are non-limiting examples of specific polyol fatty acid polyesters containing at least four fatty acid ester groups suitable for use in the present invention: glucose tetraoleate, the glucose tetraesters of soybean oil fatty acids (unsaturated), the mannose tetraesters of mixed soybean oil fatty acids, the galactose tetraesters of oleic acid, the arabinose tetraesters of linoleic acid, xylose tetralinoleate, galactose pentaoleate, sorbitol tetraoleate, the sorbitol hexaesters of unsaturated soybean oil fatty acids, xylitol pentaoleate, sucrose tetraoleate, sucrose pentaoletate, sucrose hexaoleate, sucrose hepatoleate, sucrose octaoleate, and mixtures thereof.

As noted above, highly preferred polyol fatty acid esters are those wherein the fatty acids contain from about 14 to about 18 carbon atoms.

The preferred liquid polyol polyesters preferred for use herein have complete melting points below about 300C, preferably below about 27.50C, more preferably below about 250C. Complete melting points reported herein are measured by Differential Scanning Calorimetry

(DSC).

The polyol fatty acid polyesters suitable for use herein can be prepared by a variety of methods well known to those skilled in the art. These methods include: transesterification of the polyol with methyl, ethyl or glycerol fatty acid esters using a variety of catalysts; acylation of the polyol with a fatty acid chloride; acylation of the polyol with a fatty acid anhydride; and acylation of the polyol with a fatty acid, per se. See U.S. Patent No. 2,831,854; U.S. Patent No.

WO 00/42985 PCT/US00/01390 28 4,005,196, to Jandacek, issued January 25, 1977; U.S. Patent No.

4,005,196, to Jandacek, issued January 25, 1977.

The present compositions can also comprise an auxiliary nonionic or anionic polymeric thickening component, especially a water-soluble polymeric materials, having a molecular weight greater than about 20,000. By "water-soluble polymer" is meant that the material will form a substantially clear solution in water at a 1% concentration at 250C and the material will increase the viscosity of the water.

Examples of water-soluble polymers which may desirably be used as an additional thickening component in the present compositions, are hydroxyethylcellulose, hydroxypropyl cellulose, hydroxypropyl methylcellulose, polyethylene glycol, polyacrylamide, polyacrylic acid, polyvinyl alcohol (examples include PVA 217 from Kurary Chemical Co., Japan), polyvinyl pyrrolidone K-120, dextrans, for example Dextran purified crude Grade 2P, available from D&O Chemicals, carboxymethyl cellulose, plant exudates such as acacia, ghatti, and tragacanth, seaweed extracts such as sodium alginate, propylene glycol alginate and sodium carrageenan. Preferred as the additional thickeners for the present compositions are natural polysaccharide materials. Examples of such materials are guar gum, locust bean gum, and xanthan gum. Also suitable herein preferred is hydroxyethyl cellulose having a molecular weight of about 700,000.

Hydrotrope The compositions according to the present invention may contain as an optional feature a hydrotrope. Suitable for use herein as hydrotropes are those well known in the art, including sodium xylene sulphonate, ammonium xylene sulphonate, sodium cumene sulphonate, short chain alkyl sulphate and mixtures thereof.

Hydrotrope may be present in the compositions according to the invention at a level of from about 0.01% to about preferably from about 0.1% to about more preferably from about 0.5% to about 3% by weight. Hydrotrope, as defined herein, means, a material WO 00/42985 PCT/US00/01390 29 which, when added to a non-dilute, water-soluble surfactant system can modify its viscosity and rheological profile.

In addition to the water-insoluble oil described above, the compositions of the invention may also include an insoluble perfume or cosmetic oil or wax or a mixture thereof at a level up to about preferably up to about 3% by weight wherein the oil or wax is insoluble in the sense of being insoluble in the product matrix at a temperature of 25 0

C.

Suitable insoluble cosmetic oils and waxes for use herein can be selected from water-insoluble silicones inclusive of non-volatile polyalkyl and polyaryl siloxane gums and fluids, volatile cyclic polydimethylsiloxanes, polyalkoxylated silicones, amino and quaternary ammonium modified silicones, rigid cross-linked and reinforced silicones and mixtures thereof, C1-C24 esters of C8-C30 fatty acids such as isopropyl myristate, myristyl myristate and cetyl ricinoleate, C8-C30 esters of benzoic acid, beeswax, saturated and unsaturated fatty alcohols such as behenyl alcohol, hydrocarbons such as mineral oils, petrolatum, squalane and squalene, fatty sorbitan esters (see US-A-3988255, Seiden, issued October 26th 1976), lanolin and oil-like lanolin derivatives, animal and vegetable triglycerides such as almond oil, peanut oil, wheat germ oil, rice bran oil, linseed oil, jojoba oil, oil of apricot pits, walnuts, palm nuts, pistachio nuts, sesame seeds, rapeseed, cade oil, corn oil, peach pit oil, poppyseed oil, pine oil, castor oil, soyabean oil, avocado oil, safflower oil, coconut oil, hazelnut oil, olive oil, grapeseed oil, and sunflower seed oil, and C1-C24 esters of dimer and trimer acids such as diisopropyl dimerate, diisostearylmalate, diisostearyldimerate and triisostearyltrimerate.

The viscosity of the final composition (Brookfield DV II, with Cone CP41 or CP52, 25°C, neat) is preferably at least about 500 cps, more preferably from about 1,000 to about 50,000 cps, especially from about 1,000 to about 30,000 cps, more especially from about 1,000 to about 15,000 cps.

WO 00/42985 PCT/US00/01390 The cleansing compositions can optionally include other hair or skin moisturizers which are soluble in the cleansing composition matrix.

The preferred level of such moisturizers is from about 0.5% to about by weight. In preferred embodiments, the moisturizer is selected from essential amino acid compounds found naturally occurring in the stratum corneum of the skin and water-soluble nonpolyol nonocclusives and mixtures thereof.

Some examples of more preferred nonocclusive moisturizers are squalane, sodium pyrrolidone carboxylic acid, D-panthenol, lactic acid, L-proline, guanidine, pyrrolidone, hydrolyzed protein and other collagen-derived proteins, aloe vera gel, acetamide MEA and lactamide MEA and mixtures thereof.

Compositions according to the present invention may also include an opacifier or pearlescing agent. Such materials may be included at a level of from about 0.01% to about preferably from about 0.1% to about 1.3% by weight.

Opacifiers/pearlescers suitable for inclusion in the compositions of the present invention include: titanium dioxide, TiO2; EUPERLAN 810 (RTM); TEGO-PEARL (RTM); long chain (C 1 6 C22) acyl derivatives such as glycol or polyethylene glycol esters of fatty acid having from about 16 to about 22 carbon atoms and up to 7 ethyleneoxy units; alkanolamides of fatty acids, having from about 16 to about 22 carbon atoms, preferably about 16 to 18 carbon atoms such as stearic monoethanolamide, stearic diethanolamide, stearic monoisopropanolamide and stearic monoethanolamide and alkyl (C16 C22) dimethyl amine oxides such as stearyl dimethyl amine oxide.

In preferred compositions the opacifier/pearlescer is present in the form of crystals. In highly preferred compositions the opacifier/pearlescer is a particulate polystyrene dispersion having a particle size of from about 0.05 microns to about 0.45 microns, WO 00/42985 PCT/US00/01390 31 preferably from about 0.17 microns to about 0.3 microns, such dispersions being preferred from the viewpoint of providing optimum rheology and shear-thinning behaviour. Highly preferred is styrene acrylate copolymer and OPACFIER 680 (RTM) commercially available from Morton International.

A number of additional optional materials can be added to the cleansing compositions each at a level of from about 0.1% to about 2% by weight. Such materials include proteins and polypeptides and derivatives thereof; water-soluble or solubilizable preservatives such as DMDM Hydantoin, Germall 115, methyl, ethyl, propyl and butyl esters of hydroxybenzoic acid, EDTA, Euxyl (RTM) K400, natural preservatives such as benzyl alcohol, potassium sorbate and bisabalol; sodium benzoate and 2-phenoxyethanol; other moisturizing agents such as hyaluronic acid, chitin and starchgrafted sodium polyacrylates such as Sanwet (RTM) IM-1000, IM- 1500 and IM-2500 available from Celanese Superabsorbent Materials, Portsmith, VA, USA and described in US-A-4,076,663; solvents low temperature phase modifiers such as ammonium ion sources NH4 CI); viscosity control agents such as magnesium sulfate and other electrolytes; colouring agents; TiO2 and TiO2coated mica; perfumes and perfume solubilizers; and zeolites such as Valfour BV400 and derivatives thereof and Ca 2 +/Mg 2 sequestrants such as polycarboxylates, amino polycarboxylates, polyphosphonates, amino polyphosphonates, EDTA etc, water softening agents such as sodium citrate and insoluble particulates such as zinc stearate and fumed silica. Water is also present at a level preferably of from about 20% to about 99.89%, preferably from about 40% to about 90%, more preferably at least about 75% by weight of the compositions herein.

The pH of the compositions is preferably from about 3 to about more preferably from about 5 to about 9, especially from about 5 to about 8 and most preferably from about 5 to 7.

WO) n0/42985 PCT/USOn/01390 32 The compositions of the present invention can be used for a variety of skin and hair care applications such as shower gels, body washes, hair shampoos, and the like.

The compositions of the present invention may be applied with the hand or preferably with a personal cleansing implement such as a puff. Suitable personal cleansing implements for use with the compositions of the present invention include those disclosed in the following patent documents which are incorporated herein by reference: US-A-5,144,744 to Campagnoli, issued September 8,1992, US-A-3,343,196 to Barnhouse, W095/26671 to The Procter Gamble Company, W095/00116 to The Procter Gamble Company and W095/26670 to The Procter Gamble Company.

The compositions according to the present invention are illustrated by the following non-limiting examples.

Examples I-111 are body shampoo compositions.

wash compositions. Example IV and V are 11% 111% 111% IV/% V/% Ammonium laureth-3 8.4 8.4 10.5 15 sulphate (Empicol

EAC/TP)

1 Ammonium Lauryl 5 Sulphate (Empicol AL30) 1 Na Lauroamphoacetate 3.6 3.6 4.5 2 (Empigen CDL60P) 1 Na Lauroyl Sarcosinate 0.5 0.5 3 (Hamposyl L30) 2 cocamido MEA (Empilan -1.0

CME)

1 Cetyl Alcohol 0.4 0.4 Stearyl Alcohol__ 0.2 0.2 Ethylene Glycol 2.0 Distearate WO 00/42985 WO 0042985PCTIUSOO/01390 Thixcin R 3 1.5 1.5 0 .3 Polyalphaolefin (Puresyn 6.0 0 3.0 4.0 0 100)4 Polyalphaolefin (Puresyn 0 5 0 0 2 40)4 Perfume 0.5 0.5 1.0 1.0 EDTA 0.11 0.11 0.11 0.11 0.11 Sodium Benzoate 0.25 0.25 0.25 0.25 0.25 DMDM Hydantoin 0.138 0.138 0.138 0.138 0.138 NaCI 0.5 0.5 1.3 0.5 Trichlorocarbanilide 0.15 0.0 0.0 0.15 0.15 Octyl Methox cinnamate 0.0 2.1 0.0 0.0 0.0 Vitamin E actetate 0.0 0.0 0.2 0.0 0.0 Citric acid 0.9 0.9 0.9 0.4 0.4 to Example VI is a body wash.

vi Ammonium laureth-3 sulphate 9 (Empicol EACITP) 1 Ammonium Xylene Sulfonate 0-1.66 Ammonium alkyl sulfate Zinc Sterate Monosodium phosphate 0-0.6 Disodium phosphate 0-0.6 Cetyl Alcohol 0.4 Stearyl Alcohol 0.2 Polyethylene Glycol 600 1.4 Polybutene 0.1-1.2 Perfume 0.6 Disodium EDTA 0.1 Coconut monoethanolamide (CMEA)l Ethylene Glycol Disterate (EGDS) NaCl 0-2 WO 00/42985 PCT/USOO/01390 Kathon CG 0.02 Trichlorocarbanilide 0.15 Triclosan 0.25 water to 100 1. Supplied by Albright Wilson UK Limited, P.O. Box Whitehaven, Cumbria, CA28 9QQ 2. Supplied by Hampshire Chemicals, Corp., 55 Hayden Ave., Lexington, MA 02173, USA 3. Supplied by Rheox, Inc., Wyckoffs Mill Road, P.O.Box 700, Hightstown, NJ 08520, USA 4. Supplied by Mobil Chemical Company, P.O.Box 3140, Edison, New Jersey, 08818-3140, USA Method of Manufacture Compositions can be prepared by firstly making a premix of part of the surfactants, the suspending agent and thickening agents. This premix contains 50-70% by weight of the total composition of surfactants and contains all of the Lauroamphoacetate. This is done by combining the surfactants (except sarcosinate), a portion of the water, powder preservatives and the pH adjuster with mild agitation.

This mixture is then heated up to about 90 0 C during which time, the suspending agent is added with agitation.

The mixture is held at high temperatures for a few minutes before being cooled at a controlled rate via a heat exchanger so that the suspending agent crystallizes out.

To this premix the remaining water is then added followed by the remaining surfactants, preservatives, perfume, sodium chloride and the hydrophobic skin active component. For some hydrophobic skin actives high shear mixing will be required. Finally the water insoluble oil is added. This part of the process is done at room temperature WO 00/42985 PCT/USOO/01390 using mild agitation to yield the preferred mean droplet size of 5 to microns.

The products provide excellent deposition of skin care actives, an excellent rinse feel and mildness benefits together with excellent rheological attributes in storage, in dispensing and in-use, in combination with good efficacy benefits including skin conditioning, skin moisturising, good product stability, cleansing and lathering.

Claims (18)

1. A rinse-off liquid personal cleansing composition comprising: water; from about 1% to about 60% by weight of a water-soluble surfactant, a water-insoluble oil selected from highly branched polyalphaolefins having the following formula: R 2 1 R 1 (CH 2 R 4 R 3 wherein R 1 is H or Cl-C20 alkyl, R 4 is 01-020 alkyl, R 2 is H or Cj- and R 3 is C 3 -C 2 0 preferably from C5-C 2 0 n is an integer from 0 to 3 and m is an integer of from 1 to 1000 and having a number average molecular weight of from about 1000 to about 25,000 a viscosity of from about 300cst to about 50,000cst at 40 0 C using the ASTM D-445 method of measuring viscosity; and a hydrophobic skin active component selected from antimicrobial agents, sunscreens, vitamins, perfume oils insect repellants, anti fungal agents, and mixtures thereof, wherein the hydrophobic skin active component has a ClogP value of greater than 3; 25 wherein the composition comprises less than about 5% by weight, of soap.

2. A personal cleansing composition according to Claim 1 wherein the hydrophobic skin active component has a ClogP value of greater than

3. A personal cleansing composition according to any one of Claims 1 or 2 wherein the hydrophobic skin active component is an antimicrobial agent.

4. A personal cleansing composition according to any one of claims 1 to 3 35 wherein the antimicrobial agent is selected from dicarbanilides such as trichlorocarbanilide, hexachlorophene, 3,4,5-tribromosalicylanilide, and mixtures thereof. JMN Y:\Violet-GraceNo Delete'8535-0.doc A personal cleansing composition according to any one of Claims 1 to 4 wherein the antimicrobial agent is trichlorocarbanilide.

6. A personal cleansing composition according to any one of Claims 1 to comprising from about 0.1% to about 5% by weight of hydrophobic skin active component.

7. A personal cleansing composition according to any one of Claims 1 to 6 wherein the water-insoluble oil has a number average molecular weight of from about 2500 to about 6000.

8. A personal cleansing composition according to Claim 7 wherein the number average molecular weight is from about 2500 to about 4000.

9. A personal cleansing composition according to Claim 1 wherein the water-insoluble oil has a viscosity of from about 1000cst to about 12,000cst at 0 C using the ASTM D-445 method for measuring viscosity.

10. A personal cleansing composition according to Claim 9 wherein the water-insoluble oil has a viscosity of from about 1000cst to about 4000cst at 400C using the ASTM D-445 method for measuring viscosity.

11. A personal cleansing composition according to any one of Claims 1 to S 25 comprising from about 0.1% to about 10% by weight of water-insoluble oil. S

12. A personal cleansing composition according to Claim 11 comprising from about 2% to about 7% by weight of water-insoluble oil. S JMN Y:\Violet-Grace\No Delete\28539-00.doc 38

13. A personal cleansing composition according to any one of Claims 1 to 12 wherein the water-soluble surfactant is selected from anionic surfactant, nonionic, zwitterionic and amphoteric surfactants and mixtures thereof. 14 A personal cleansing composition according to Claim 13 wherein the water-soluble anionic surfactant is selected from alkyl sulfates, ethoxylated alkyl sulfates, alkyl glyceryl ether sulfonates, alkyl ethoxy glyceryl ether sulfonates, acyl methyl taurates, fatty acyl glycinates, alkyl ethoxy carboxylates, N-acyl glutamates, acyl isethionates, alkyl sulfosuccinates, alkyl ethoxy sulfosuccinates, alpha-sulfonated fatty acids, their salts and/or their esters, alkyl phosphates esters, ethoxylated alkyl phosphate esters, acyl sarcosinates and fatty acid/protein condensates, acyl aspartates, alkoxy acyl amide carboxylates, (ethoxylated) alkanolamide sulfosuccinates, ethoxylated alkyl citrate sulfosuccinates, acyl ethylene diamine triacetates, acyl hydroxyethyl isethionates, acyl amide alkoxy sulfates, linear alkyl benzene sulfonates, paraffin sulfonates, alkyl alkoxy sulfates, and mixtures thereof. A personal cleansing composition according to Claim 13 or 14 wherein the water-soluble anionic surfactant is ethoxylated alkyl sulfate.

16. A personal cleansing composition according to Claim 13 wherein the water-soluble amphoteric surfactant is selected from ammonium derivatives of formula S.6: 25 R 1 CON(CH 2 2 NCH 2 CO 2 M I R3 R2 wherein R 1 is C 5 -C 2 2 alkyl or alkenyl, R 2 is CH 2 CH20H or CH 2 CO 2 M, M is H, 30 alkali metal, alkaline earth metal, ammonium or alkanolammonium and R 3 is CH 2 CH 2 0H or H.

17. A personal cleansing composition according to Claim 13 wherein the 0* zwitterionic surfactant is selected from alkyl betaines of the formula R(CH2)nC2M and amido betaines of formula R 5 R 6 R 7 N'(CH 2 )nCO 2 M and amido betaines of formula (IX): JMN Y:\Violet-Grace\No Delete\28539-00.doc I R 5 CON(CH 2 )mN(CH 2 )nCO 2 M I R7 wherein R 5 is C 5 -C 22 alkyl or alkenyl, R 6 and R 7 are independently Cl-C 3 alkyl, M is H, alkali metal, alkaline earth metal, ammonium or alkanolammonium, and n, m are each numbers from 1 to 4.

18. A composition according to any one of Claims 1 to 17 additionally comprising from about 0.01% to about 5% by weight of cationic polymeric skin conditioning agent selected from cationic guar gums, cationic polysaccharides, cationic homopolymers and copolymers derived from acrylic and/or methacrylic acid, cationic cellulose resins, quaternized hydroxy ethyl cellulose ethers, cationic copolymers of dimethyldiallylammonium chloride and acrylamide and/or acrylic acid, cationic homopolymers of dimethyldiallylammonium chloride, copolymers of dimethyl aminoethylmethacrylate and acrylamide, acrylic acid/dimethyldiallylammonium chloride/acrylamide copolymers, quaternised vinyl pyrrolidone acrylate or methacrylate copolymers of amino alcohol, quaternized copolymers of vinyl pyrollidone and dimethylaminoethylmethacrylamide, vinyl pyrollidone/vinyl imidaolium methochloride copolymers and polyalkylene and ethoxypolyalkylene imines, S 25 quaternized silicones, terpolymers of acrylic acid, methacrylamido propyl trimethyl ammonium chloride and methyl acrylate, and mixtures thereof. O

19. A personal cleansing composition according to any one of Claims 1 to 18 wherein the water-insoluble oil has a number average particle diameter of from about 1 micron to about 500 microns. °oo JMN Y:\Violet-GraceNo Delete\28539-00.doc A personal cleansing composition according to Claim 19 wherein the water-insoluble oil has a number average particle diameter from about microns to about 200 microns.

21. A personal cleansing composition according to Claim 19 wherein the water-insoluble oil has a number average particle diameter from about microns to about 50 microns.

22. A personal cleansing composition according to claim 1 substantially as hereinbefore described with reference to the examples. DATED :21 January, 2004 PHILLIPS ORMONDE FITZPATRICK Attorneys For: THE PROCTER GAMBLE COMPANY S* *o JMN Y:\Vioet-GraceNo Delete\28539-OO.doc