AU7418187A - Substituted phenyl alpha-fluoroacrylates - Google Patents

Substituted phenyl alpha-fluoroacrylates

Info

Publication number
AU7418187A
AU7418187A AU74181/87A AU7418187A AU7418187A AU 7418187 A AU7418187 A AU 7418187A AU 74181/87 A AU74181/87 A AU 74181/87A AU 7418187 A AU7418187 A AU 7418187A AU 7418187 A AU7418187 A AU 7418187A
Authority
AU
Australia
Prior art keywords
alpha
fluoroacrylates
substituted
substituted phenyl
phenyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU74181/87A
Other versions
AU602699B2 (en
Inventor
Werner Groh
Peter Herbrechtsmeier
Rudolf Heumuller
Gunter Siegemund
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Publication of AU7418187A publication Critical patent/AU7418187A/en
Application granted granted Critical
Publication of AU602699B2 publication Critical patent/AU602699B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62—Halogen-containing esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles

Abstract

Certain esters of alpha -fluoroacrylic acid are available via hydrolysis of alpha -hydroxymethyl- alpha -fluoromalonic esters, followed by decarboxylation of the hydrolysis product. Phenyl alpha -fluoroacrylates which are substituted on the phenyl radical can be prepared by hydroxymethylation of dimethyl alpha -fluoromalonates, decarboxylation and dehydration of the resultant dimethyl alpha -hydroxymethyl- alpha -fluoromalonate and esterification of the resultant alpha -fluoroacrylic acid with substituted phenols. The substituted phenyl alpha -fluoroacrylates are colourless liquids or colourless solids which are polymerisable. They are suitable as starting material for the preparation of fluorinated polymers.
AU74181/87A 1986-06-14 1987-06-12 Substituted phenyl alpha-fluoroacrylates Ceased AU602699B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3620050 1986-06-14
DE19863620050 DE3620050A1 (en) 1986-06-14 1986-06-14 SUBSTITUTED (ALPHA) -FLUORACRYLIC ACID PHENYLESTER

Publications (2)

Publication Number Publication Date
AU7418187A true AU7418187A (en) 1987-12-17
AU602699B2 AU602699B2 (en) 1990-10-25

Family

ID=6303005

Family Applications (1)

Application Number Title Priority Date Filing Date
AU74181/87A Ceased AU602699B2 (en) 1986-06-14 1987-06-12 Substituted phenyl alpha-fluoroacrylates

Country Status (10)

Country Link
EP (1) EP0249867B1 (en)
JP (1) JPS62298556A (en)
KR (1) KR950008086B1 (en)
CN (1) CN1014236B (en)
AT (2) ATE71081T1 (en)
AU (1) AU602699B2 (en)
CA (1) CA1309106C (en)
DE (2) DE3620050A1 (en)
ES (1) ES2038617T3 (en)
GR (1) GR3003804T3 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6005137A (en) 1997-06-10 1999-12-21 3M Innovative Properties Company Halogenated acrylates and polymers derived therefrom
JP4599948B2 (en) * 2003-09-18 2010-12-15 チッソ株式会社 α-Fluoroacrylate compound, composition and polymer thereof
JP5040259B2 (en) * 2005-12-08 2012-10-03 Ｊｎｃ株式会社 Lateral α-substituted acrylate compound and polymer thereof
JP5582032B2 (en) * 2009-02-05 2014-09-03 三菱レイヨン株式会社 Method for producing (meth) acrylic acid ester
ES2738421T3 (en) * 2014-06-18 2020-01-22 Saltigo Gmbh Procedure for the preparation of esters of 2-haloacrylic acid
KR20210064190A (en) * 2018-09-25 2021-06-02 니폰 제온 가부시키가이샤 Copolymer and positive resist composition
CN114867710A (en) * 2019-11-14 2022-08-05 维福(国际)有限公司 One-step synthesis of 2-fluoroacrylic acid alkyl ester

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5518638A (en) * 1978-07-27 1980-02-08 Chiyou Lsi Gijutsu Kenkyu Kumiai Ionized radiation sensitive positive type resist
FR2444052A1 (en) * 1978-12-15 1980-07-11 Onera (Off Nat Aerospatiale) TRANSPARENT ORGANIC MATERIAL
FR2444022A1 (en) * 1978-12-15 1980-07-11 Onera (Off Nat Aerospatiale) ACRYLIC MONOMER
EP0128517B1 (en) * 1983-06-10 1992-09-02 Daikin Industries, Limited Optical material
JPS6078940A (en) * 1983-10-04 1985-05-04 Daikin Ind Ltd Production of alpha-fluoroacrylic acid ester
US4572805A (en) * 1984-03-27 1986-02-25 Nippon Shokubai Kagaku Kogyo Co., Ltd. 2,3,5,6-Tetrafluorophenyl (meth) acrylates and method for production thereof

Also Published As

Publication number Publication date
DE3620050A1 (en) 1987-12-17
EP0249867B1 (en) 1992-01-02
CA1309106C (en) 1992-10-20
CN1014236B (en) 1991-10-09
AU602699B2 (en) 1990-10-25
CN87104092A (en) 1988-02-10
EP0249867A3 (en) 1988-12-21
DE3775626D1 (en) 1992-02-13
AT388727B (en) 1989-08-25
KR950008086B1 (en) 1995-07-25
EP0249867A2 (en) 1987-12-23
ATA258787A (en) 1989-01-15
ES2038617T3 (en) 1993-08-01
ATE71081T1 (en) 1992-01-15
KR880000376A (en) 1988-03-25
GR3003804T3 (en) 1993-03-16
JPS62298556A (en) 1987-12-25

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