AU727307B2 - A process and apparatus for dewatering of coal and mineral slurries - Google Patents

Description

I ('A6 1- P/00/O1i1 Regulation 3.2

AUSTRALIA

Patents Act 1 990

ORIGINAL

COMPLETE SPECIFICATION STANDARD PATENT 0* 0 S @0 0 Invention Title: A PROCESS AND APPARATUS FOR DEWATERING OF COAL AND MINERAL

SLURRIES

The following statement is a full description of this invention, including the best method of performing it known to me/us: GH&CO REF: P23045AS/JT:MR 2 A Process and Apparatus for the Dewatering of Coal and Mineral Slurries The present invention relates to an apparatus and method for reducing moisture content of a particulate mass such as ground mineral material e.g. coal.

Typically minerals and especially coal products contain a substantial percentage by weight of water and accounting for as much as 10% of the mass. In this specification, particular attention will be given to the treatment of coal, but it is to be understood that apparatus embodying the invention and the methods of the invention may also be applicable to other similar mineral masses which in their initial state are described as slurries.

Conventional processes for moisture removal from 15 minerals such as coal include screening, centrifugation e0 and vacuum filtration. In the case of coal products, it is economically important to reduce the moisture content prior to land transport of the particulate mass as 0 transport costs are essentially according to weight and 20 it is an economic penalty to transport as much as 10% of the weight of the product as unwanted water.

4*SSSO S Furthermore, in some industrial processes using coal products, such as power generation, it is a substantial thermal penalty to have a significant level of moisture 25 in the coal as energy in burning the coal is then Sutilised in drivingoff the moisture as steam.

For many years, it has been conventional to use centrifuges to reduce moisture levels to around 6 to 8 3 wt% where the particle size range is typically less than 30 30 mm and greater than 0.5 mm. With conventional practice, a practical limit for dewatering is controlled by the relative opposing magnitudes of capillary forces causing the water to be retained in the particulate mass and the applied forces attempting to strip the water from the mass.

In a method aspect, broadly the present invention consists in a method of reducing moisture content of a bed of solid particles comprising subjecting the bed to a S:23045AS -3stream of gas to establish turbulent flow through the bed to strip a significant proportion of the moisture contained in the bed.

In an apparatus aspect, the present invention consists in an apparatus for processing a bed of solid particles containing moisture, the apparatus comprising a processing zone for receiving the bed, means for admitting and injecting into the bed a gas stream so as to establish a turbulent flow through the bed and to strip moisture, discharge means being provided for discharging the gas with entrained moisture. The processing zone is provided by apparatus selected from a vibrating basket centrifuge having a conically shaped basket rotatable about a horizontal axis with its wider end open and within which is disposed a manifold adapted to discharge air into the bed in the processing zone, a scroll centrifuge having a conical inner wall, apertures being provided on the exterior of the conical inner wall for discharging a gas stream into the processing zone, a vibratory conveyor having a closed tunnel for continuously advancing the bed of solid particles along a processing path; or a chute for introducing the bed of solid particles to and discharging S. the bed of solid particles from the apparatus, and means cooperating with said chute for steadily advancing the bed 25 through said chute.

A most important embodiment of the invention is one in which processing of the bed takes place in a centrifuge which for a practical commercial embodiment would be a S• continuously operating centrifuge. However other 30 embodiments are possible such as advancing the particulate solids in the form of a bed which is moved along a vibratory conveyor such as downwardly inclined tunnel containing a processing zone in which the gas is injected to strip moisture.

It is believed the present invention can successfully reduce the residual moisture in a mineral such as coal and 4 it is considered that a significant advantage can be -3Aachieved by reducing the moisture level by 1 wt% of the mass over and above that achievable by known methods such as centrifugation. While not being bound by any particular theory, as an aid to understanding the present invention, the inventors suggest that useful results of the present invention are due to enhanced kinetics resulting from a mass transport mechanism brought about by the superimposition of a turbulent gas flow through the bed.

Preferably, the invention is operated with particles in the range of mainly 0.5 mm to 30 mm although it is acceptable to have a proportion of the particles outside this range. The invention has been found to operate advantageously where 90% of the particles in the mass have a size greater than 1.5 mm and the particle e e* •eg* e* 4 distribution is such that a very low level of fines i.e.

less than 0.5 mm are present whereby turbulent gas flow can readily be sustained. It is thought that it is in the turbulent flow which entraps free moisture and removes it.

By contrast, prior published proposals do not include other than using air flow with very fine coal particles and wherein laminar flow conditions were applied.

Preferably the present invention is implemented using a relatively low pressure air flow as the turbulent gas and this is believed to be particularly successful in promoting hydrodynamic drag of liquid from within the inter-particle voids.

15 The present invention is believed to be particularly 00 applicable to particles having a strong hydrophobic 0000 characteristic. It has been found that coal has such a characteristic but other minerals also share this i "feature. Another application of the invention is one where the method comprises preliminary treatment of particulate matter with a compound to provide a surface @00 ~effect on the particles whereby a substantial hydrophobic characteristic is established. Then the material can be successfully processed according to principles of the 25 present invention. For convenience and economy, air has 00 been found to be an effective medium for the turbulent gas flow. The air can be at ambient temperature.

However other gas flows can be used such as steam and 0000 oo 3 other gases of elevated temperature.

30 The speed of air flow passing through the particulate mass can be conveniently chosen and in general, it has been found that a speed in the range of 1 000005 se 00 to 20 m/sec is beneficial and preferably around 10 m/sec offers a convenient and economic choice.

The invention can be implemented by adaptation of known types of centrifuges of which a vibrating basket type continuous centrifuge is particularly attractive for commercial operations. Preferably a vibrating basket S:23045AS centrifuge is used with a novel air inlet manifold provided to inject air at a multiplicity of locations spaced from and around the axis of the basket. Air can be injected through a manifold having a series of short pipes substantially parallel to the axis of the basket and having apertures for directing air jets radially outwardly.

However, other types of centrifuge could be used such as scroll and screen bowl centrifuges.

Particularly, when a vibrating basket centrifuge is used, operation at a G force in a range 25G to 120G is suitable with basket speeds in the range of 200 to 450 rpm.

Aspects of the invention and experimental reports concerning the invention will now be described with :reference to the accompanying drawings of which:- Figure 1 is a schematic diagram of a laboratory c scale centrifuge suitable for batch operations which has •been used to demonstrate principles of the present invention; Figure 2 is a second embodiment shown schematically cccco: and being a scroll-type centrifuge having a gas injection system; Figure 3 illustrates the results of testing 25 contrasting centrifuging with and without turbulent air purging; Figure 4 illustrates rate of moisture loss as a function or air speed; 3 Figure 5 illustrates the results of centrifuging with steam; Figure 6 illustrates the results of tests to demonstrate the effect of air speed on moisture cc. c" reduction; Figure 7 illustrates centrifuging with and without air purge on fine coal particles; Figure 8 illustrates centrifuging with and without air purge on coarse coal particles; Figure 9 is a schematic representation of S:23045AS 6 particulate coal containing water; Figure 10 is a schematic diagram of an embodiment applied to a vibratory conveyor for particulate solids; Figure 11 is a schematic axial cross-sectional view through a vibrating basket centrifuge modified to form an embodiment of the invention; and Figure 12 is a schematic sectional view along the line XII-12.

Referring to Figure i, a centrifuge basket 10 is mounted on a rotary bearing 11 drilled through the centre to provide an air inlet 12 leading to a chamber 13 from which radially outwardly bores 14 pass to an outer chamber 15. A batch of particulate coal is located in an annular basket 16.

The illustrated centrifuge is for laboratory scale batch operations and has been used to test out the 0000 principles of the invention which will be described further below with reference to data derived from S "testing. As it was not possible to measure air speed 20 while the centrifuge was spinning, an anemometer was used *0 on the outside of the stationary basket packed with coal 600 ~before starting centrifuge operations in order to measure air velocity through the coal bed.

Referring now to Figure 2, a more practical 25 continuous centrifuge is illustrated. This is a scroll g centrifuge of known type but modified for the introduction of pressurised gas such as air or steam to implement the concepts of the present invention. In this 0060 centrifuge 20, there is a cone 21 mounted on a rotor 22 S" 30 and the cone carrying a series of flights 23 down which the coal mass progressively moves to annular discharge location 24. Coal is fed into the centrifuge through an upper axial inlet 25. The rotor is mounted on a hollow drive shaft 26 connected to an air pressure line through an air seal 27 whereby pressurised air is introduced into the cone from which it is radially outwardly discharged through apertures 28 in the cone.

Referring to Figure 3, data are presented for coal S:23045AS 7 particles ranging from 0.5 mm to 9.5 mm which were subject to centrifuging. Curve 30 represents wet coal with no air purge, curve 31 represents air dried coal treated without air purge and curves 32 and 33 are for wet coal and air dried respectively with air injected at m/sec for a purge time of 10 seconds during the centrifuge operation in order to strip moisture.

Resulting residual moisture level in the coal bed is indicated for different G force values corresponding with different centrifuge basket speeds. The results indicate a substantial improvement in reducing moisture level when contrasting data for use of the air purge with the centrifuging as opposed to centrifuging alone without the air purge.

In each case the initial moisture content was about 0e 10 wt%.

oooo 0Referring now to Figure 4, the plot of the rate of moisture loss with varying air speed shows a marked change in the rate of moisture loss corresponding to gas 00o 20 flow velocities above about 1 m/sec. This indicates a .ochange of mechanism from evaporation at low flow rates to bulk mass transport.

01 t Figure 5 demonstrates that steam is an alternative to air and significant moisture reduction can be achieved 25 according to this experimental data.

e S"Figure 6 illustrates the data to show a typical O profile for moisture reduction plotted against air velocity. Thus it will be seen that with coal particles 00""with a size range typically 1 mm to 10 mm in the main, 12 30 m/sec is an effective and economically feasible air flow 0 0velocity to be utilised.

•Figure 7 illustrates an experiment on fine coal particles in the range below 3.35 mm but greater than mm using an air speed of 10 m/sec and purge time of sec. The contrasting data of using an air purge as against merely centrifuging shows a substantial reduction in moisture with, particularly in the case of air purge, only a small improvement when increasing centrifuge speed S:23045AS 8 to correspond with an increase in G force from 50G to 200G.

Figure 8 corresponds to Figure 7 data but uses relatively coarse coal particles in the size range below 9.5 mm and above 3.35 mm.

The above data demonstrates the principles of the invention can be effectively applied to a range of particulate sizes. Reference will now be made to Figure 9 illustrating various states in which water is thought to be present in a particulate bed of coal particles. In the saturated state (Fig. 9A), water is held under capillary forces to fill the inter-particulate voids. In the pendular state (Fig. 9C), moisture is retained at points of contact between individual coal particles but there is believed to be an intermediate state referred to *0 as the funicular state (9B) in which moisture exists in d046 o equilibrium with air dispersed throughout the porous structure. It is suggested that by normal centrifugation :of typically coal products (which have not been air 0.0." 20 dried) there is a limit to the level to which free a. moisture can be reduced and this is determined primarily by the amount of pendular moisture which, depending on the mode of packing, can be shown theoretically to be around 5 to 7 wt% for a wetting liquid. This figure is 25 in fact consistent with measured values for residual

OS

moisture from reported commercial coarse coal centrifuge processes. Figures 7 and 8 provide data contrasting fine and coarse coal particle masses but otherwise processed under similar conditions. The residual moisture levels 30 are considerably higher with the fine coal fractions but the moisture reduction achieved by the combination of air purge and centrifugation was considerably greater for the "finer fractions at all levels of spin speed. Thus at a speed equivalent to 50G, a reduction in moisture achieved for fine particles was about 3 wt% compared with about 1 wt% for the coarse particles.

Without being bound to any particular theory the present inventors suggest this data may show two possible S:23045AS phenomena occurring. It is suggested that for the finer coal particles there will be a greater amount of pendular moisture present and which will be available for displacement by the air purge during centrifugation.

Secondly the finer the size of the coal particles, the finer will be the size of the inter-particle pores within the bed. This in turn should lead to an increase in turbulence as the air purge occurs and the inventors suggest that this greater turbulence and a thinner boundary layer would make the air purge more effective at removing water. Accordingly, when a complete sized distribution of coal particles is used (say less than mm and above 0.5 mm) dewatering characteristics can be achieved more akin to fine coal particles rather than coarse coal particles due to turbulence within pores of the structure. A particulate batch of coal particles mainly in the range of 1 mm to 10 mm is believed to have a greater amount of moisture present in the pendular state.

Referring now to the embodiment of Figure 10, which is a vibratory conveyor system, the apparatus comprises a o. shute 40 having an inlet hopper 41 for receiving particulate coal and a lower discharge port 42, the shute o being mounted on a vibratory feeder 43 which causes steady advance of the particulate matter in the form of a bed.

In its upper mid-portion, the shute has a manifold 44 connected to a compressed air supply line 45 which discharges a band of air downwardly through the bed for discharge through a suitable grating (not shown in the :drawing) covering an air outlet 46. The air is supplied at such flow rate and pressure having regard to the oparticle sizes in the bed so that turbulent air stream establishes through the bed whereby moisture and in particular moisture in a pendular state is stripped from the bed.

Referring now to Figures 11 and 12, this embodiment has a novel manifold arrangement applied to a vibrating basket centrifuge 50. The centrifuge comprises a frustoconical basket 51 having an end wall 52 and at its F:\Speci300 399\300 349\31059. I.doc 10 opposite end an air manifold 53 comprising a part circular tube having ports 54 at each end for the introduction of pressurised air and lateral air discharge tubes 55 each having a series of apertures for directing air jets generally radially outwardly. As shown in Figure 11 pressurised air is fed through line 56 to each of the ports 54. Particulate coal or other mineral is supplied into the basket through a tubular duct 57 which discharges the particulate coal adjacent the wall 52.

The basket is rotated and vibrated horizontally and dried, treated coal particles are discharged at the bottom of the basket as indicated by arrow A into a receiving hopper 58.

In this apparatus the coal particles move under the influence of the vibrations to the wider open end of the basket where discharge takes place. This apparatus is suitable for use in dewatering coal particles with particle sizes in the range of 30 to 0.5 mm.

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Claims (15)

1. 2. A method as claimed in claim 1 and wherein the bed is arranged in a processing zone of a centrifuge.
2. 3. A method as claimed in claim 2 and wherein the centrifuge is a vibrating basket centrifuge having an air discharge manifold located nearer the open end of the basket and having air discharge nozzles extending into the basket.
3. 4. A method as claimed in claim 3 and comprising using an air discharge manifold wherein the nozzles are provided spaced along tubes which are disposed parallel to the axis of the centrifuge and the nozzles directing airflow radially outwardly.
4. 5. A method as claimed in claim 2 and comprising using a scroll centrifuge providing a pressurised gas *i stream which is discharged through apertures in a conical inner wall of the centrifuge.
5. 6. A method as claimed in any one of claims 2 to o and wherein the bed is subjected to centrifugal force of rabout
6. 7. A method as claimed in claim 1 and wherein the bed of solid particles is continuously advanced along a :path and the path is intersected with the stream of air *o*o which is discharged together with moisture removed from the bed. A method as claimed in any one of the preceding claims and including selecting the bed of particles to be principally sized in the range 0.5 mm to 30 mm.
7. 9. A method as claimed in any one of the preceding claims, and including selecting the bed of solid particles with at least 90% of the particles sized greater than mm and less than 30 mm. A method as claimed in claim i, and wherein the stream of gas is air which is injected into the bed at the F:\Speci300 399\300 349\31059. I.doc 12 speed of the order of 10 M/sec.
8. 11. An apparatus for processing a bed of solid particles containing moisture, the apparatus including a centrifuge providing a processing zone for receiving the bed, the centrifuge being a vibrating basket centrifuge having a conically shaped basket rotatable about a horizontal axis with its wider end open and within which is disposed a manifold adapted to discharge air into the bed in the processing zone to establish a turbulent flow through the bed and to strip moisture, discharge means being provided for discharging the gas with entrained moisture.
9. 12. An apparatus as claimed in claim 11, and wherein nozzles are provided spaced along tubes which are disposed parallel to the axis of the centrifuge and the nozzles direct airflow radially outwardly.
10. 13. An apparatus for processing a bed of solid particles containing moisture, the apparatus including a centrifuge providing a process zone for receiving the bed, the centrifuge being a scroll centrifuge having a conical inner wall, apertures being provided on the exterior of the conical inner wall for discharging a gas stream into the processing zone to establish a turbulent flow through the bed and to strip moisture, means for providing a pressurized gas stream to the apertures, and means being provided for discharging the gas with entrained moisture.
11. 14. An apparatus as claimed in any one of claims 11 to 13, and wherein the centrifuge is adapted to apply a centrifugal force of about 60G to particles in the bed. An apparatus for processing a bed of solid :particles containing moisture, the apparatus having a 0 vibratory conveyor having a closed tunnel for continuously advancing the bed of solid particles along a processing path, the apparatus further including a means for admitting and injecting a gas stream into the bed transversely to movement of the bed of particles and through the bed of particles with a turbulent flow to stip moisture, and discharge means for discharging the gas with entrained moisture. F:\Speci\300- 399\300 349\31059.I.doc -13-
12. 16. Apparatus as claimed in any one of claims 11 to and wherein the gas stream means is adapted to provide a stream of air injected into the particle bed at a speed of the order of 10 m/sec.
13. 17. An apparatus for processing a bed of solid particles containing moisture, the apparatus comprising means providing a processing zone for receiving the bed, means for admitting and injecting a gas stream into the bed transversely to movement of the bed of particles and through the bed of particles with a turbulent flow to strip moisture, a chute for introducing the bed of solid particles to and discharging said bed of solid particles from said apparatus, means cooperating with said chute for steadily advancing the bed through said chute, and discharge means being provided for discharging the gas with entrained moisture.
14. 18. Apparatus substantially as herein described with reference to Fig. 1, Fig. 2, Fig. 10 of Figs. 11 and 12 of the accompanying drawings. :19. Apparatus as claimed in any one of claims 11 to 18 when used for processing a mineral slurry. 0%.20. Apparatus as claimed in claim 19 when used with a mineral slurry comprising particles principally sized in the range 0.5 mm to 30 mm.
15. 21. A method of reducing moisture in a mineral slurry substantially as herein described with reference to Fig. 1, Fig. 2, Fig. 10 or Figs. 11 and 12 of the accompanying :drawings. r ~22. A method as claimed in any one of claims 1 to wherein the velocity of the stream of gas is chosen in relation to the particle size parameters to cause the turbulent flow through the bed to operate predominantly by a mass transport mechanism. Dated this 29th day of September 2000 COMMONWEALTH SCIENTIFIC AND INDUSTRIAL RESEARCH ORGANISATION SBy their Patent Attorneys GRIFFITH HACK CO 399\300 349\31059. I.doc