AU7197394A - Method for cleaning a gas flow - Google Patents

Method for cleaning a gas flow

Info

Publication number
AU7197394A
AU7197394A AU71973/94A AU7197394A AU7197394A AU 7197394 A AU7197394 A AU 7197394A AU 71973/94 A AU71973/94 A AU 71973/94A AU 7197394 A AU7197394 A AU 7197394A AU 7197394 A AU7197394 A AU 7197394A
Authority
AU
Australia
Prior art keywords
gas flow
hot
desorption
conducted
combustion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU71973/94A
Other versions
AU675864B2 (en
Inventor
Jan-Mats Eneroth
Anders Persson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ABB Technology FLB AB
Original Assignee
ABB Flaekt AB
Flaekt AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ABB Flaekt AB, Flaekt AB filed Critical ABB Flaekt AB
Publication of AU7197394A publication Critical patent/AU7197394A/en
Application granted granted Critical
Publication of AU675864B2 publication Critical patent/AU675864B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/06Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with moving adsorbents, e.g. rotating beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/106Silica or silicates
    • B01D2253/108Zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0258Other waste gases from painting equipments or paint drying installations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/14Gaseous waste or fumes

Description

METHOD FOR CLEANING A GAS FLOW
This invention relates to a method for cleaning a humid gas flow containing gaseous impurities, such as an exhaust-air flow containing volatile solvents and origi¬ nating from a spray booth in a painting plant, in which method the gas flow is dehumidified by cooling, the cool¬ ed gas flow is reheated to subsequently be conducted through a device for the adsorption of gaseous impuri¬ ties, a desorption-gas flow is heated to form a hot-gas flow, which is conducted through the adsorption device in order to clean the latter and entrain impurities accumu¬ lated therein, the contaminated hot-gas flow is conducted to a combustion device in order to be burnt, and hot com¬ bustion gases are removed from the combustion device in order to take part in at least one of the heating pro- cesses.
The above method is used in a painting plant for cleaning an exhaust-air flow containing paint particles and volatile solvents and originating from a spray booth in the plant. In this prior-art method, the gas flow is conducted through a dust separator, where particulate impurities are separated from the gas flow, which is cooled when leaving the dust separator. Part of the gas flow leaving the dust separator is conducted, as cooling- gas flow, through the adsorption device in order to cool those parts of this device that have been heated by the hot-gas flow, whereupon the cooling-gas flow is used as desorption-gas flow. Hot combustion gases from the combustion device are conducted through a heat exchanger in order there to emit heat to the desorption-gas flow, which also is conducted through the heat exchanger. Further, a heat exchanger is used for reheating the cooled gas flow leaving the dust separator.
The object of the present invention is to provide a cleaning method in which the energy consumption is lower and there is less need of heat exchangers than in the above prior-art method, and which thus is less expensive to implement than the prior-art method.
According to the invention, this object is attained by a method which is of the type stated by way of intro¬ duction and is characterised in that hot combustion gases from the combustion device are introduced into and mixed with the cooled gas flow and the desorption-gas flow.
It will be appreciated that the two heat exchangers required for implementing the above prior-art method can be dispensed with when utilising the method according to the invention. The cooling-gas flow, which in the prior- art method is dimensioned to serve as hot-gas flow as well and thus is unnecessarily large, may, if used in a corresponding fashion when implementing the method according to the invention, be advantageously reduced to merely fulfil the cooling function, hot combustion gases being supplied to the desorption-gas flow so as to form the hot-gas flow. The invention will now be described in more detail with reference to the accompanying drawings, in which
Fig. 1 schematically illustrates a plant which is intended for implementing the inventive method and in which use is made of an incinerator with a recuperative heat exchanger; and
Fig. 2 schematically illustrates a plant which is intended for implementing the inventive method and in which use is made of an incinerator with a regenerative heat exchanger. In Figs 1 and 2, the encircled numerals at the dif¬ ferent flow arrows indicate a flow value for the respec¬ tive flows, this flow value bearing a relation to the air flow which prevails in a spray booth and whose flow value has been set at 100. The temperature of the respective flows is also indicated at some flow arrows.
Both the plant illustrated in Fig. 1 and that illu¬ strated in Fig. 2 are used for cleaning the exhaust-air flow containing paint particles, volatile solvents and water vapour that leaves a spray booth 1 in a plant for painting vehicle bodies. Via an air conditioner 2, an air flow is blown into the spray booth 1 by means of a fan 3. The major part (about 90%) of the air blown into the spray booth 1 is air that is circulated in the system in a manner to be described in more detail below, whereas the remainder (about 10%) is taken from the surrounding atmosphere. The air is conditioned in the air conditioner 2 in such a manner that an air flow having a temperature of about 23°C and a relative humidity of about 60% is obtained in the spray booth 1.
The air flow leaving the spray booth 1 and having a temperature of about 18°C is conducted through a dust separator 4, such as a wet electrostatic precipitator, where particulate impurities, such as paint particles, are separated from the air flow. When leaving the dust separator 4, the air flow is dehumidified by cooling in a cooler 5. The cooled air flow leaving the cooler 5 is, as will be described in more detail below, supplemented with an additional flow with which it is conducted, by means of a fan 6, through a device 7' (Fig. 1) or 7" (Fig. 2) for the adsorption of gaseous impurities, such as volatile solvents. The adsorption device 7' or 7", which is of known design, consists of a rotor composed of a plurality of segment-shaped adsorption elements containing a suitable adsorbing agent, which is zeolite in the rotor 7' shown in Fig. 1 and active carbon in the rotor 7" shown in Fig. 2. US-A-5,057,128, for instance, discloses a rotor of this type.
The flow path through the rotor 7' or 7" is, by means of fixed channel walls (not shown), divided into three sectors, namely a gas-cleaning sector which covers most of the circular cross-sectional area of the rotor and through which is conducted the main part of the gas flow to be cleaned, and two minor sectors, of which one is a cooling sector through which a minor part of the gas flow to be cleaned is conducted in order to cool the adsorption elements, and the other is a desorption sector through which a hot-gas flow is conducted in order to clean the rotor and entrain impurities accumulated there¬ in. The cooling-air flow is regulated by means of a register 8. The rotor 7' or 7" rotates during use, so that the portion thereof situated opposite to the gas- cleaning sector of the flow path is gradually inserted into the desorption sector of the flow path so as to be cleaned, and then inserted into the cooling sector of the flow path in order to be cooled.
The major part of the cleaned gas flow leaving the adsorption device or the rotor 7' or 7" is, as mentioned above, recycled to the air intake of the fan 3, whereas the remainder of the gas flow is discharged into the sur¬ rounding atmosphere.
The hot-gas flow, which has a high solvent concen¬ tration when leaving the adsorption device 7' or 7", is conducted to a combustion device 10' or 10" by means of a fan 9.
In the Example illustrated in Fig. 1, the combustion device 10' is an incinerator of the type described in e.g. DE-A1-30 41 269 and DE-A1-30 43 286 and has a corn- bustion chamber 11 and a recuperative heat exchanger 12 through which the heavily contaminated hot-gas flow is introduced into the combustion chamber 11. The combustion gases from the combustion chamber 11 are removed through the heat exchanger 12, where they emit heat to preheat the hot-gas flow, so that their temperature is reduced from about 730°C to about 350°C.
A part (about 40%) of the thus-cooled combustion gases is conducted, via a flow-regulating register 13, to the desorption sector there to be mixed with the cooling- air flow from the adsorption device 7' and form, together therewith, the hot-gas flow. The cooling-air flow leaving the adsorption device 7' has a temperature of about 60°C and is mixed with combustion gases having a temperature of about 350°C in such proportions (6:4) that the hot-gas flow obtains a temperature of about 180°C. When leaving the adsorption device 7' , the hot-gas flow has a tempera- ture of about 90°C.
A part (about 30%) of the combustion gases cooled in the heat exchanger 12 forms the above-mentioned additional flow and is conducted to the outlet of the cooler 5 to be mixed with the cooled air flow leaving this device. The cooled air flow leaving the cooler 5 has a temperature of about 15°C and is mixed with combustion gases having a temperature of about 350°C in such propor¬ tions (100:3) that a gas flow having a temperature of about 25°C is obtained. The remainder (about 30%) of the combustion gases cooled in the heat exchanger 12 is conducted through a heat-recovery device 14 before being let out into the surrounding atmosphere.
The plant illustrated in Fig. 2 differs from that illustrated in Fig. 1 in that active carbon, and not zeolite, is used in the adsorption device, as mentioned above, and in that an incinerator with a regenerative heat exchanger, and not a recuperative heat exchanger, is used as combustion device. The incinerator employed is of the type described in e.g. SE-A-8403330-7 and SE-A- 8802791-7.
The hot-gas flow, which has a high solvent concen¬ tration when leaving the adsorption device 7", is con¬ ducted to the combustion device 10", i.e. the regene- rative incinerator, where combustion takes place. The combustion gases removed from the combustion device 10" have a temperature of about 206°C. A part (about 45%) of the combustion gases is conducted, via a register 13, to the desorption sector there to be mixed with the cooling-air flow from the adsorption device 7" and form therewith the hot-gas flow. The cooling-air flow leaving the adsorption device 7" has a temperature of about 50°C and is mixed with combustion gases having a temperature of about 206°C in such proportions (5.5:4.5) that the hot-gas flow obtains a temperature of about 120°C. When leaving the adsorption device 7", the hot-gas flow has a temperature of about 70°C. The remainder (about 55%) of the combustion gases is conducted to the outlet of the cooler 5 to be mixed with the cooled air flow leaving this device. This air flow, which has a temperature of about 15°C as in the plant illustrated in Fig. 1, is mixed with combustion gases having a temperature of about 206°C in such proportions (100:5.5) that a gas flow hav¬ ing a temperature of about 25°C is obtained. In the plant illustrated in Fig. 2, the energy contained in the com¬ bustion gases is utilised to the full, for which reason there is no need of any special heat-recovery device.

Claims (4)

1. A method for cleaning a humid gas flow containing gaseous impurities, such as an exhaust-air flow contain¬ ing volatile solvents and originating from a spray booth (1) in a painting plant, in which method the gas flow is dehumidified by cooling, the cooled gas flow is reheated to subsequently be conducted through a device (7' ; 7" ) for the adsorption of gaseous impurities, a desorption- gas flow is heated to form a hot-gas flow, which is conducted through the adsorption device (7'; 7") in order to clean the latter and entrain impurities accumulated therein, the contaminated hot-gas flow is conducted to a combustion device (10'; 10") in order to be burnt, and hot combustion gases are removed from the combustion device (10'; 10") in order to take part in at least one of the heating processes, c h a r a c t e r i s e d in that hot combustion gases from the combustion device (10', 10") are introduced into and mixed with the cooled gas flow and the desorption-gas flow.
2. A method as set forth in claim 1, in which part of the gas flow leaving the adsorption device (7'; 7") is used as desorption-gas flow, c h a r a c t e r i s e d in that the hot-gas flow is formed by supplying hot com¬ bustion gases from the combustion device (10'; 10") to the desorption-gas flow.
3. A method as set forth in claim 1, in which part of the cooled and subsequently reheated gas flow is con- ducted through the adsorption device (7'; 7") as a cool¬ ing-gas flow for cooling those parts of the adsorption device that have been heated by the hot-gas flow, where¬ upon the cooling-gas flow is used as desorption-gas flow, c h a r a c t e r i s e d in that the hot-gas flow is formed by supplying hot combustion gases from the com¬ bustion device (10'; 10") to the desorption-gas flow.
4. A method as set forth in claim 2 or 3, c h a r a c t e r i s e d in that hot combustion gases from the combustion device (10'; 10") are supplied to the cooled gas flow before this is conducted through the adsorption device (7'; 7").
AU71973/94A 1993-07-06 1994-06-29 Method for cleaning a gas flow Ceased AU675864B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE9302329A SE502607C2 (en) 1993-07-06 1993-07-06 Process for the purification of humid gas flow containing impurities such as volatile solvents
SE9302329 1993-07-06
PCT/SE1994/000643 WO1995001827A1 (en) 1993-07-06 1994-06-29 Method for cleaning a gas flow

Publications (2)

Publication Number Publication Date
AU7197394A true AU7197394A (en) 1995-02-06
AU675864B2 AU675864B2 (en) 1997-02-20

Family

ID=20390536

Family Applications (1)

Application Number Title Priority Date Filing Date
AU71973/94A Ceased AU675864B2 (en) 1993-07-06 1994-06-29 Method for cleaning a gas flow

Country Status (8)

Country Link
EP (1) EP0707510A1 (en)
JP (1) JPH08512236A (en)
CN (1) CN1126954A (en)
AU (1) AU675864B2 (en)
BR (1) BR9406909A (en)
CA (1) CA2165478A1 (en)
SE (1) SE502607C2 (en)
WO (1) WO1995001827A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19716877C1 (en) * 1997-04-22 1998-12-10 Schedler Johannes Thermally-efficient incinerator plant for cost-effective destruction of volatile organic compounds contaminating air
JP2001050521A (en) * 1999-08-06 2001-02-23 Maejima Fumio Multi-function processing apparatus
JP4523146B2 (en) * 2000-12-19 2010-08-11 株式会社西部技研 Organic solvent vapor processing equipment
CN106524190A (en) * 2015-09-15 2017-03-22 江苏海阔生物医药有限公司 Waste gas incinerator for voglibose production technology
DE102017103204A1 (en) * 2017-02-16 2018-08-16 Krantz Gmbh Apparatus for treating a crude gas volume flow laden with oxidizable constituents
DE102017103182A1 (en) * 2017-02-16 2018-08-16 Krantz Gmbh Apparatus for treating a crude gas volume flow laden with oxidizable constituents
BE1025798B1 (en) * 2017-12-15 2019-07-17 Europem Technologies Nv Vapor combustion system and method with increased capacity
BE1025793B1 (en) * 2017-12-15 2019-07-17 Europem Technologies Nv COMBUSTION SYSTEM AND PROCESS FOR COMBUSTION OF A GAS IN A COMBUSTION SYSTEM

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE461808B (en) * 1988-08-02 1990-03-26 Flaekt Ab PROCEDURE AND DEVICE FOR GAS CLEANING
SE467238B (en) * 1990-02-02 1992-06-22 Raadia Kommanditbolag SETTING AND DEVICE TO CLEAN LARGE AIR VOLUMES WITH LOW CONCENTRATION OF THE PULP WATER

Also Published As

Publication number Publication date
SE9302329L (en) 1995-01-07
WO1995001827A1 (en) 1995-01-19
BR9406909A (en) 2000-04-18
SE9302329D0 (en) 1993-07-06
CN1126954A (en) 1996-07-17
AU675864B2 (en) 1997-02-20
JPH08512236A (en) 1996-12-24
SE502607C2 (en) 1995-11-20
EP0707510A1 (en) 1996-04-24
CA2165478A1 (en) 1995-01-19

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