AU718704B2 - Hard surface cleaner - Google Patents
Hard surface cleaner Download PDFInfo
- Publication number
- AU718704B2 AU718704B2 AU49585/97A AU4958597A AU718704B2 AU 718704 B2 AU718704 B2 AU 718704B2 AU 49585/97 A AU49585/97 A AU 49585/97A AU 4958597 A AU4958597 A AU 4958597A AU 718704 B2 AU718704 B2 AU 718704B2
- Authority
- AU
- Australia
- Prior art keywords
- composition according
- composition
- amide
- ethoxylated
- chain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000000203 mixture Substances 0.000 claims description 42
- 238000004140 cleaning Methods 0.000 claims description 19
- 150000001408 amides Chemical class 0.000 claims description 16
- 239000002216 antistatic agent Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- -1 glycol ethers Chemical class 0.000 claims description 9
- 102000011782 Keratins Human genes 0.000 claims description 8
- 108010076876 Keratins Proteins 0.000 claims description 8
- 229920001184 polypeptide Polymers 0.000 claims description 8
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 8
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 4
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical group CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001413 amino acids Chemical class 0.000 claims description 3
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 150000002191 fatty alcohols Chemical class 0.000 claims description 2
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 2
- 125000003275 alpha amino acid group Chemical group 0.000 claims 1
- 125000005313 fatty acid group Chemical group 0.000 claims 1
- 239000011521 glass Substances 0.000 description 11
- 238000009472 formulation Methods 0.000 description 8
- 230000003068 static effect Effects 0.000 description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910021653 sulphate ion Inorganic materials 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- SXQFCVDSOLSHOQ-UHFFFAOYSA-N lactamide Chemical compound CC(O)C(N)=O SXQFCVDSOLSHOQ-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 1
- 229940113162 oleylamide Drugs 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/645—Mixtures of compounds all of which are cationic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/526—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 are polyalkoxylated
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Description
Pat l01i9Pl l Light Duty Cleaner The present invention relates to compositions for cleaning hard surfaces, and in particular to compositions suitable for cleaning glass and glossy or shiny surfaces.
A particularly important feature of such compositions is that the surface when cleaned must not 1 have any streaks or smears and, although numerous compositions for cleaning glass and like materials have been proposed, providing compositions which clean effectively whilst avoiding streaking or smearing has been a particular technical challenge.
A further desirable feature of cleaning compositions for glass and shiny or glossy surfaces is the ability to reduce or to avoid the build up of static charge.
It will be appreciated that the presence of static charge on the surface causes the rapid re-deposition of dust and like particles by attraction of such particles onto the surface from the air. The benefits achieved by cleaning of the surface are thus rapidly diminished.
One known cleaning composition, in particular for glass, comprises an aqueous solution of less than 1% sodium alkyl sulphate and sodium alkyl ether sulphate surfactants together with a grease removing solvent.
Whilst this composition shows satisfactory cleaning and 4 non-smearing or non-streaking properties, the composition does not impart anti-static properties to the surface.
Elt-MNiDED SHi Pat 10119P I'A- European Patent Application EP-A-0621335 discloses cleaning compositions comprising 0.1 to 10' by weight of a non-ionic surfactant and 3.5 to 10' by wieht of a glycol ether solvent. The:.compositions are, however, not hard surface cleaning compositions but are instead aimed at achieving broad spectrum anti-microbial activity, an acceptable level of skin irritation and/or an acceptable cleaning efficacy.
DE-A-3614336 discloses hard surface cleaning compositions aimed at imparting an anti-static effect to the surface wichout smearing. The compositions disclosed comprise an amphoteric co/terpolymer having at least one nitrogen atom per acrylic acid derivative and a surfactant, preferably of the amine oxide rype.
However, the applicant has established that the choice of surfactant is essential for the reduction cf the smearing level.
Accordingly, the present invention seeks to provice a cleaning composition, in particular for glass and AM E~DET I I I a- Pat 10119P1 glossy or shiny surfaces, which has good cleaning properties, does not cause smears or streaks, and also has good anti-static properties, that is, the ability to reduce or prevent the build up of static charge on the surface.
According to the present invention, there is provided an aqueous cleaning composition for hard surfaces comprising byweight, 0.1% 0.5% of one or more alkyl or alkenyl ethoxylated amides with the proviso that polyethoxy lauryl amide is excluded, 1% 10% in total of at least one member selected from the group comprising glycol ethers and C 6
C
1 alcohols and, optionally, 0.005% to 0.5% of an anti-static agent.
The compositions may also include minor amounts (usually less than of further optional ingredients such as fragrances, colourants, and the like, as known in the art.
Particularly preferred for use in the present invention are ethoxylated amides having the general structure: 0
(CH
2 CH,0) -H R- C N
H
Where R is an alkyl or alkenyl radical having from to 25 carbon atoms, preferably 12 to 22 carbon atoms, AMENDED SHEET WO 98/22562 PCT/GB97/03133 -3and n is preferably an integer in the range of from to 20. Especially suitable are mono-unsaturated alkenyl ethoxylated amides of which oleyl ethoxylated amide and erucic ethoxylated amide are especially preferred. Suitable ethoxylated amides are available in the CromidetsTM series from Croda Chemicals Ltd, UK.
In preferred formulations, the ethoxylated amides are present in amounts of from 0.1% to 0.5% and more preferably from 0.2% to The glycol ethers and/or alcohols of the inventive compositions are preferably present in a total amount of from 1% to 10%, more preferably from 3% and especially from 3.5% to Preferred glycol ethers have the general formula R'-0-CH 2 -CH (OH) -R 2 where R 1 is a straight chain or branched lower alkyl radical, preferably having from 1 to 6 carbon atoms and
R
2 is a lower alkyl radical which may be straight chained or branched and preferably has from 1 to 4 carbon atoms. Particularly preferred glycol ethers are butoxypropanol and methoxyisopropanol. Ethylene glycol monobutyl ether is also efficacious, but is less preferred for environmental reasons.
Whilst formulations comprising essentially the above ethoxylated amides, and glycol ethers and/or alcohols provide excellent cleaning, anti-smear and anti-static properties on surfaces such as glass and many shiny or glossy hard surfaces, a sufficient reduction of the SUBSTITUTE SHEET (RULE 26) WO 98/22562 PCT/GB97/03133 -4static charge on plastic surfaces (such as vinyl, acrylic or polycarbonate surfaces) may not be achieved.
Such static charges are generated by the tribological effects of cleaning the surface with, for example, a cloth and also simply by movement of air across the surface. As mentioned above, dissipation of such static charge is important in order to avoid re-deposition of dust particles from the air. Plastic surfaces are, by their nature, more susceptible than is glass to tribologically induced charge, and this charge 1 is not easily dissipated.
The inventors have found that the static charge on such plastic surfaces after cleaning can be significantly reduced by incorporating an antistatic agent into the above compositions.
The anti-static agents of the invention are water soluble quaternary ammonium compounds which contain a polypeptide chain coupled to fatty alkyl groups. A typical structure of these compounds may be schematically represented as:
CH
3
CH
2 n+ 1
N*-A
1 Y X,
CH
3
A
2
I
H
3
C-N'-CH
3
-S
CmH2m+1 where Al and A 2 are portions of amino acids, X I is a portion of the polypeptide chain, X 2 is another portion of the polypeptide chain ending in a carboxy terminal WO 98/22562 PCT/GB97/03133 amino acid, Y represents a carbon atom in the polypeptide chain and n and m may be the same or different and are. integers in the range 8 to preferably 10 to 18, especially 12. The anti-static agents may include one or more further side chains S and have a molecular weight of not more than 10,000, preferably not more than about 2000 and especially 0about 1000. Particularly preferred compounds may be based on collagen or keratin proteins. Especially preferred is a keratin based fatty (C 1 2 H2,) quaternary 1 derivative of hydrolysed keratin (lauryldimonium hydroxypropyl hydrolysed keratin protein) which is commercially available as Croquat K (TM) from Croda Colloids Ltd, UK. The antistatic agent is preferably included in an amount of from 0.01% to and especially an amount of from 0.05% to 0.15%.
It is believed that the instant inventive formulations are particularly advantageous with regard to the prior art formulations based on sodium alkyl sulphate and sodium alkyl ether sulphate surfactants in that addition of antistatic agent to formulations including these surfactants results in smearing on cleaning.
Thus, the combination of the ethoxylated amides -and the antistatic agent, together with the glycol ethers provides excellent charge reduction on plastic surfaces whilst also avoiding streaking and smearing on the surface. The inventors believe that this combination of charge dissipation and non-streaking/smearing is not achieved by the prior art compositions.
SUBSTITUTE SHEET (RULE 26) I I I I Pat lOl0 9Pl The compositions of the invention may also advantageously include a wetting agent, in particular a fatty alcohol ethoxylate such as Volpo T7 T M available from Croda. Such a wetting agent may be present in amounts of from 0.001% to more especially from 0.002% to 0.1%.
The compositions of the invention may also include minor amounts of optional ingredients such as fragrances or colourants, provided that such optional ingredients do not deleteriously affect the anti-smearing or anti-static properties of the compositions.
In order to better illustrate the invention, Examples and Comparative Examples were prepared and tested as illustrated in Table 1 below. Examples 1 and 2 are examples of the invention and Examples V to Z are comparative examples.
In order to assess the level of smearing caused by these formulations, samples of the formulations were applied in predetermined amounts to a clean dry paper towel which was then applied to a clean glass mirror tile and moved once-with even pressure across the tile.
After allowing the tile to dry, the level of smearing was assessed using a scale of 0 to 4 where 4 indicates severe smears or streaks and 0 indicates no smears or streaks.
The anti-static properties of the formulations were -tested using a.Charge Decay Test Unit from John Chubb Instrumentation, Cheltenham, UK. The test procedure involves the induction of a static charge on a surface AMENDED
SHEE
WO 98/22562 PCT/GB97/03133 -7and measurement of the time taken for the charge to dissipate. The latter time is expressed as l/e and a lower value indicates a higher rate of charge dissipation and better antistatic properties. Tests were carried out on glass and on polycarbonate surfaces and the results are indicated in Table 1 below.
SUBSTITUTE SHEET (RULE 26) WO 98/22562 WO 9822562PCT/GB97/03133 TABLE 1.
1 rative 1. 21, kAJx IIi -1 1 1 I V 1W- X l Example /Compa Example Butoxypropanol 2.1 .2.1 Methoxyisopropalol 1.8 1.8 1.8 1.8 1.8 1.8 Pol-yoxyethylene 0.3 0.3 0.3 oleylamide Sodium laurylether 0.29 0.29 sulphate Sodium lauryl 0.43 0.43 sulphate Trideceth 7 0.006 0.006 Quaternised 0.1 0.1 hydrolysed keratin Polyethoxy lauryl 0.3 amide l Lactamide 0.3 monoethanolamide Cl) Water 100% 100% 100% 100%1 100% 100% Smearing level 0.56 0.25 1 1.89 4 t r Charge dissipation time (glass) Charge dissipation time (polycarbonate) 0.77 0.3 1 4-7. 91 1 1 >600 1>600>60C I -Polyethoxy lauryl amide and lactamide monoethanolamide are antistatic agents known in the art. SUBSTITUTE SHEET (RULE 26) WO 98/22562 PCT/GB97/03133 -9- Commercially available product claiming anti-static properties.
Untreated surfaces were also tested for which the charge dissipation times were: glass 1.6; polycarbonate >600.
SUBSTITUTE SHEET (RULE 26)
Claims (9)
1. An aqueous cleaning composition for hard surfaces comprising, by weight, 0.1% to 0.5% of one or more alkyl or alkenyl ethoxylated amides with the proviso that polyethoxy lauryl amide is excluded, 1% to 10% in total of at least one member selected from the group comprising glycol ethers and C, C, alcohols and, optionally, 0.005% to 0.5% of an anti-static agent.
2. A composition according to Claim 1 wherein the ethoxylated amide is present in an amount of 0.2% to
3. A composition according to Claim 1 or 2 wherein the ethoxylated amide has an alkyl or alkenyl chain comprising from 10 to 25 carbon atoms.
4. A composition as claimed in Claim 3 wherein the ethoxylated amide is oleyl ethoxylated amide and/or erucic ethoxylated amide. A composition as claimed in any preceding claim wherein the glycol ether has the general formula R I 0 CH 2 CH(OH) R 2 where R 1 is a straight chain or branched lower alkyl radical of from 1 to 6 carbon atoms and R 2 is a straight chain or branched lower alkyl radical of from 1 to 4 carbon atoms. AMENDED SiEEi 4 4 4 44 4444 4 4 4 4 4 411, 4 4 44 4. 4* 4 Pat 101 9P1
6. A composition according to Claim 5 wherein the glycol ether is butoxypropanol or methoxyisopropanol.
7. A composition according to any preceding claim wherein the glycol ether.is present in an amount of from 3.5% to
8. A composition according to any preceding claim comprising from 0.01% to 0.3% of an anti-static agent which is a water soluble quaternary ammonium compound including a polypeptide chain coupled to fatty acid groups and having the general formula: CH 3 CnHnl.1 N' A X, Y X, CH 3 H 3 C N' CH3 CmH 2 m+l where Al and A 2 are portions of amino acids, X, is a portion of the polypeptide chain, X, is another portion of the polypeptide chain ending in a carboxy terminal amino acid, Y represents a carbon atom in the polypeptide chain, n and m may be the same or different and are integers in the range 8 to 20 and S denotes a side chain. .B :2 0 0 00 60 00 0 a gO e0 s o 0 6 .0 0 Pat 101 9P
9. A composition according to claim 8 wherein the anti-static agent is a keratin based fatty quaternary derivative of hydrolysed keratin including lauryldimonium hydroxypropyl hydrolysed V keratin protein. composition.according to any preceding claim further comprising from 0.001% to 0.5% of a wetting agent, preferably a fatty alcohol ethoxylate.
11.A composition according to Claim 1 substantially as hereinbefore described with reference to Example 1 or 2. AMENDED SHEET
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9623823.3A GB9623823D0 (en) | 1996-11-16 | 1996-11-16 | Improvements in or relating to organic compositions |
| GB9623823 | 1996-11-16 | ||
| PCT/GB1997/003133 WO1998022562A1 (en) | 1996-11-16 | 1997-11-14 | Hard surface cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU4958597A AU4958597A (en) | 1998-06-10 |
| AU718704B2 true AU718704B2 (en) | 2000-04-20 |
Family
ID=10803013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU49585/97A Ceased AU718704B2 (en) | 1996-11-16 | 1997-11-14 | Hard surface cleaner |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6130197A (en) |
| EP (1) | EP0944698A1 (en) |
| CN (1) | CN1087771C (en) |
| AR (1) | AR010607A1 (en) |
| AU (1) | AU718704B2 (en) |
| BR (1) | BR9713043A (en) |
| CA (1) | CA2271466A1 (en) |
| GB (2) | GB9623823D0 (en) |
| ID (1) | ID22302A (en) |
| NZ (1) | NZ335494A (en) |
| WO (1) | WO1998022562A1 (en) |
| ZA (1) | ZA9710286B (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ID27945A (en) | 1997-03-20 | 2001-05-03 | Procter & Gamble | DETERGENT COMPOSITION USED BY A CLEANER CONTAINING A SUPERABSORBEN MATERIAL AND EQUIPMENT CONSIST OF A CLEANER AND SUPERABSORBEN |
| GB0023440D0 (en) * | 2000-09-25 | 2000-11-08 | Reckitt Benckiser Uk Ltd | Improvements in or relating to organic compositions |
| US20060258557A1 (en) * | 2005-05-11 | 2006-11-16 | Popplewell Lewis M | Hard surface cleaning compositions and methods for making same |
| CH705757B1 (en) * | 2011-11-13 | 2016-03-31 | Compad Consulting Gmbh | Sustainable detergents and cleaning agents. |
| MX348027B (en) * | 2012-04-25 | 2017-05-24 | Akzo Nobel Chemicals Int Bv | The use of an ethoxylated alkanolamide as a hydrotrope for an alkylene oxide adduct of an alcohol. |
| US8648027B2 (en) | 2012-07-06 | 2014-02-11 | The Clorox Company | Low-VOC cleaning substrates and compositions comprising a cationic biocide |
| US9096821B1 (en) | 2014-07-31 | 2015-08-04 | The Clorox Company | Preloaded dual purpose cleaning and sanitizing wipe |
| CN106753853A (en) * | 2016-11-22 | 2017-05-31 | 青岛净世家环保技术有限公司 | A kind of preparation method of dirt-resistant self-cleaning glass cleaner |
| US10982177B2 (en) | 2017-09-18 | 2021-04-20 | The Clorox Company | Cleaning wipes with particular lotion retention and efficacy characteristics |
| US10975341B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular MABDF characteristics |
| US10973385B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes having particular pore volume distribution characteristics |
| US10973386B2 (en) | 2017-09-18 | 2021-04-13 | The Clorox Company | Cleaning wipes system having particular performance characteristics |
| US11273625B2 (en) | 2018-12-21 | 2022-03-15 | The Clorox Company | Process for manufacturing multi-layer substrates comprising sandwich layers and polyethylene |
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| GB2203162A (en) * | 1987-04-01 | 1988-10-12 | D G Ind Limited | Anti-static compositions |
| EP0621335A2 (en) * | 1993-04-19 | 1994-10-26 | Reckitt & Colman Inc. | All purpose cleaning composition |
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| DE3431003A1 (en) * | 1984-08-23 | 1986-03-06 | Henkel KGaA, 4000 Düsseldorf | LIQUID DETERGENT |
| US4685030A (en) * | 1985-04-29 | 1987-08-04 | Energy Conversion Devices, Inc. | Surface mounted circuits including hybrid circuits, having CVD interconnects, and method of preparing the circuits |
| US4690818A (en) * | 1986-02-03 | 1987-09-01 | Charles Of The Ritz Group Ltd. | Shampoo and bath and shower gel |
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| DE69522875T2 (en) * | 1994-08-22 | 2002-04-11 | Kao Corp., Tokio/Tokyo | Detergent for hard surfaces |
| FR2725130B1 (en) * | 1994-09-29 | 1996-10-31 | Oreal | COSMETIC COMPOSITIONS CONTAINING A CERAMID-LIKE COMPOUND AND A FATTY CHAIN PEPTIDE, AND USES THEREOF |
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-
1996
- 1996-11-16 GB GBGB9623823.3A patent/GB9623823D0/en active Pending
-
1997
- 1997-11-14 US US09/297,492 patent/US6130197A/en not_active Expired - Fee Related
- 1997-11-14 EP EP97912352A patent/EP0944698A1/en not_active Withdrawn
- 1997-11-14 WO PCT/GB1997/003133 patent/WO1998022562A1/en not_active Application Discontinuation
- 1997-11-14 CA CA002271466A patent/CA2271466A1/en not_active Abandoned
- 1997-11-14 AR ARP970105349A patent/AR010607A1/en active IP Right Grant
- 1997-11-14 NZ NZ335494A patent/NZ335494A/en unknown
- 1997-11-14 ID IDW990344A patent/ID22302A/en unknown
- 1997-11-14 CN CN97199762A patent/CN1087771C/en not_active Expired - Fee Related
- 1997-11-14 ZA ZA9710286A patent/ZA9710286B/en unknown
- 1997-11-14 BR BR9713043-5A patent/BR9713043A/en not_active Application Discontinuation
- 1997-11-14 AU AU49585/97A patent/AU718704B2/en not_active Ceased
- 1997-11-17 GB GB9724119A patent/GB2319256B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2203162A (en) * | 1987-04-01 | 1988-10-12 | D G Ind Limited | Anti-static compositions |
| EP0621335A2 (en) * | 1993-04-19 | 1994-10-26 | Reckitt & Colman Inc. | All purpose cleaning composition |
Also Published As
| Publication number | Publication date |
|---|---|
| AR010607A1 (en) | 2000-06-28 |
| CN1237998A (en) | 1999-12-08 |
| GB2319256B (en) | 2000-09-27 |
| AU4958597A (en) | 1998-06-10 |
| CA2271466A1 (en) | 1998-05-28 |
| NZ335494A (en) | 2000-12-22 |
| ID22302A (en) | 1999-09-30 |
| CN1087771C (en) | 2002-07-17 |
| US6130197A (en) | 2000-10-10 |
| EP0944698A1 (en) | 1999-09-29 |
| GB9623823D0 (en) | 1997-01-08 |
| ZA9710286B (en) | 1998-06-10 |
| GB2319256A (en) | 1998-05-20 |
| GB9724119D0 (en) | 1998-01-14 |
| BR9713043A (en) | 2000-04-11 |
| WO1998022562A1 (en) | 1998-05-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| PC | Assignment registered |
Owner name: RECKITT BENCKISER (UK) LIMITED Free format text: FORMER OWNER WAS: RECKITT AND COLMAN PRODUCTS LIMITED |
|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |