AU678682B2 - Adhesive ink composition - Google Patents
Adhesive ink composition Download PDFInfo
- Publication number
- AU678682B2 AU678682B2 AU15091/95A AU1509195A AU678682B2 AU 678682 B2 AU678682 B2 AU 678682B2 AU 15091/95 A AU15091/95 A AU 15091/95A AU 1509195 A AU1509195 A AU 1509195A AU 678682 B2 AU678682 B2 AU 678682B2
- Authority
- AU
- Australia
- Prior art keywords
- glass
- monomer
- photoinitiator
- adhesive
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000853 adhesive Substances 0.000 title claims description 42
- 230000001070 adhesive effect Effects 0.000 title claims description 42
- 239000000203 mixture Substances 0.000 title claims description 33
- 239000011521 glass Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 25
- 239000000178 monomer Substances 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 10
- 229910000077 silane Inorganic materials 0.000 claims description 7
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical group C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 5
- 125000003118 aryl group Chemical group 0.000 claims description 5
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 5
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 4
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 claims description 4
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 3
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical group C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 claims description 3
- 239000004593 Epoxy Substances 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- VNTPGSZQKARKHG-UHFFFAOYSA-N trimethyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical group C[Si](C)(C)CCCOCC1CO1 VNTPGSZQKARKHG-UHFFFAOYSA-N 0.000 claims description 2
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 claims 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 claims 1
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims 1
- 239000011888 foil Substances 0.000 description 15
- 238000005034 decoration Methods 0.000 description 10
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 7
- 239000000758 substrate Substances 0.000 description 7
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 230000005855 radiation Effects 0.000 description 4
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000012216 screening Methods 0.000 description 2
- 150000004756 silanes Chemical class 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
Description
AUSTRALIA
Patents Act COMPLETE SPECIFICATION
(ORIGINAL)
Class Int. Class Application Number: Lodged: Complete Specification Lodged: Accepted: Published: Priority Related Art: 0 0* *D 0* *0 Name of Applicant: Revlon Consumer Product- Corporation Actual Inventor(s): Melvin E. Kamen Bhupendra Patel Phillip Bernstein Address for Service: PHILLIPS ORMONDE FITZPATRICK Patent and Trade Mark Attorneys 367 Collins Street Melbourne 3000 AUSTRALIA Invention Title: ADHESIVE INK COMPOSITION Our Ref 406190 POF Code: 200181/184113 The following statement is a full description of this invention, including the best method of performing it known to applicant(s): -L-_LIL I IL IL_ I ADHESIVE INK COMPOSITION Technical Field The invention relates to an adhesive ink composition which may be used in applying decorative coatings to glass.
This application is a divisional of Australian Patent Application 39832/93.
Background of the Invention Hot stamping is the heat transfer of a pigmented color or metallized surface from a polyester carrier onto a thermoplastic substrate. A heated die or roller is used to apply pressure to a foil. The pressure forces the pigmented or metallized portion of foil Sa:"'i into contact with the plastic substrate. The combination of heat and pressure softens the plastic substrate and activates the foil coating to form a strong chemical physical bond. When the foil is pulled away, only the areas subjected to the hot stamp remain affixed to the plastic substrate. A vertical stamping or roll-on machine is used for the operation. The vertical stamping machine contains a heated die of brass, stee! or silicone rubber to transfer an area or a specific pattern as each part is placed in 20 position. Roll-on methods utilize a silicone rubber roller or arced die to apply the foil in a continuous or batch process. Hot stamping is an efficient, inexpensive way to apply decoration to thermoplastic substrates. Hot stamping of this nature cannot be used with glass, however, because glass melts at a much higher temperature than most thermoplastic materials.
Generally decoration in the form of gold leaf, color design,
T-
or printing, etc. is applied to glass by a glazing process similar to that used with ceramics. For example, in gold leafing the gold decoration is applied to the glass container by a variety of methods such as silk screen, printing, etc. The container is then subjected to extremely high kiln temperatures and the decoration is, in essence, baked on. Unfortunately this process is time consuming, expensive, energy intensive, and subject to safety considerations due to the high temperatures and gases necessary to operate the kilns.
There is thus a great need for a simple, economical and ultra-safe procedure for applying decoration to glass substrates and for an adhesive ink which may be used in such applications.
The invention provides a curable adhesive ink composition including, by weight of the total composition: 20-90% of a monomer.
b) 10-35% of a polymer dissolved in the monomer.
c) 3-10% photoinitiator.
.9 9 9.
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Detailed Description A wide variety of glass container may be suitable used with the composition of the invention, including but not limited to bottles, dishes, cups, glasses, and so on.
The composition of the invention may be "painted" onto the glass to provide decoration. The "painting" may be accomplished by silk screening, stenciling, actual painting, or any of a wide variety of methods known to those skilled in the art. In the preferred embodiment of the invention the adhesive ink is applied by silk screening the ink onto the glass container utilizing the traditional screen and squeegee well known to those skilled in the art.
The preferred "adhesive ink" is a curable polymeric composition comprised of a mononer, a polymer dissolved in the monomer, and a photoinitiating agent. Other ingredients, such as silanes may be added to improve adhesion. It is particularly S preferred that the adhesive ink composition include f. om 1 to 10% by weight of the total composition of silane. Suitable monomers include ,,obornyl acrylate, urethane 15 methacrylate, urethane acrylate, tetrahydrofurfuryl acrylate, acrylic resins, aromatic urethane acrylic resin, etc. on mixtures thereof. A wide variety of polymers is suitable including but not limited to polyethylmethacrylate, polymethylmethacrylate, polyurethane, polyester acrylates, epoxy acrylates, etc. or mixtures thereof.
A wide variety of photoinitiators may be utilized including photoinitiators activated by
S..
20 heat, various chemicals, or actinic 'L~L 0 I -1 II r radiation, often in the ultraviolet spectrum. Photoinitiators suitable with actinic radiation include 1-hydroxycyclohexylphenylketone, 2,2 -dimethyoxy-2-phenyl acetophenone, diethyoxyacetophenone, and 2-methyl-l-(methylethiophenyl)-2-(4-morpholinyl)-1-propanone. In the preferred embodiment of the invention the monomer is isobornyl acrylate dr urethane methacrylate. The preferred polymer is polyethylmethacrylate, and the preferred photoinitiator is l-hydrocyclohexylphenylketone which is marketed under the tradename Irgacure 184 (Ciba-Geigy, Hawthorne, NY). It is desireable to add a silane, specifically 3-glycidoxy-propyl trimethyl silane to the adhesive ink composition. Silane is a known coupling agent with glass and will increase bond strength.
Generally the monomer concentration of the adhesive ink ranges 4 from 20-90%. About 10-35% of polymer is suggested, and about 3-10% photoinitiator. If silane is added to the composition, about 1-10% is suggested. Other ancillary ingredients may be added to the composition to enhance adhesion and cure rate. For example, acrylic acid derivatives, stabilizers, inert fillers, and so on.
In another preferred embodiment of the invention, pigments are added to the ink. The ink may then be silkscreened or painted onto the glass container and cured as usual. Foil may or may not be applied, as desired. The addition of pigment to the adhesive provides certain advantages. The adhesive, which is then visible on the glass can be used alone or combined with the use of foil to provide a two tone effect. Suitable colored II. L -s a I adhesives are made by simply adding about 1-20% of a pigment to the adhesive. For example, suitable colored adhesives can be made by adding 10% titanium dioxide to the adhesive (white) or carbon black to the adhesive (black).
As mentioned previously, the adhesive is cured according to the type of photoinitiator used. If actinic radiation sensitive photoinitiators are used, then the adhesive is cured by passing the decorated container under the appropriate intensity of ultraviolet light. In the preferred embodiment of the invention the adhesive is curable by actinic radiation, so the container is passed under ultraviolet light using a convention UV conveyer.
After the adhesive on the container has been cured, gold or silver foil is compressed against the container by means of a stamp, roller, or any suitable instrument known in the art for this purpose. The stamp must be heated to a temperature of at least 2500 F, and is compressed tightly against the foil covered glass container. A hand held heated roller works well for this purpose such as the rollers made by Silicon Limited, .i Lancaster New York.
The roller or stamp is compressed against the foil covered container for 1-3 seconds.
When the roller is removed and the foil peeled away, the foil adheres only to the portion of the container decorated with the adhesive ink.
The foil decoration according to the invention is inexpensive, simple, and eliminates the need for use of kilns and high temperatures to accomplish gold leaf-like designs on glass containers.
1 9- ~-~e~CI I' I I- I The invention is also directed to glass substrates decorated according to the methods set forth above.
The invention will be further described in connection with the following examples which are set forth for the purpose of illustration only.
Example 1 Preparation of UV curable adhesive and hot stamping glass container therewith Isobornyl acrylate, 37.5 grams, (Borden Chemical Co., Cincinnati, Ohio) and 12.5 grams Elvacite 2-13 (Dupont Co., Wilmington, DE) was mixed and warmed in a microwave oven for one minute or until the Elvacite was completely dissolved. Irgacure 184, 2.5 grams by weight, was added and mixed until dissolved.
e The above ink adhesive was used to silk screen designs on a glass container. The screen consisted of a 255 line (255 0* fibers/square inch) screen with the decorative design imprinted on it. The ink was brushed over with a squeegee, resulting in a glass container with ink decoration thereon.
The adhesive ink was cured utilizing a 300 watt feet/minute UV conveyer. The container was passed through the conveyer from one to three times to achieve appropriate curing of the polymer.
Gold hot stamping foil (Crown, Royal Leaf, Paterson, NJ) was compressed against the container utilizing a heated hand held roller (Silicon Limited, Lancaster, NY). The heated roller was applied for a few seconds. The foil was then peeled away. Foil adhered only to the adhesive ink decoration.
s 'I 'I '11~P I~ u_ Isl LL The UV adhesive provided an excellent, smooth surfaced decoration with no irregularities.
Example 2 Preparation of UV curable adhesive An adhesive of the following formulation was prepared: grams Ebecryl 6700, (aromatic urethane methacrylate) (RadCure Specialties, Atlanta,1GA) grams 203 Tetrahydrofurfuryl acrylate (Sartomer, Exton, PA) grams 506 isobornyl acrylate #506 (Sartomer) 0.5 grams BYK-052 (Ciba-Geigy, Hawthorne, NY) (defoaming agent), 5.0 grams Irgacure 184 The formulation was mixed as set forth in Example 1. The formulation was transferred to a glass slide utilizing a silk screen method. The adhesive was cured utilizing a UV conveyer with a 300 watt lamp and 30 feet/minute speed. Four passes were required to cure the adhesive.
The formulation was smooth and the cure time acceptable but adherence of the gold foil after the hot stamping process was spotty.
Example 3 Preparation of adhesive A UV curable adhesive was prepared as follows: 24 grams isobornyl acrylate 203 (Sartomer) 17 grams Urethane acrylate #9625 (Sartomer) grams Ebecryl A827 (aromatic urethane acrylate) (Radcure) 11 grams Ebecryl 6700 (aromatic urethane acrylate) (Radcure) grams Irgacure 184 grams BYK-501 (Union Carbide)(wetting agent) -r i~i _II grams FC 171 (Union Carbide)(wetting agent) grams A 151 (Union Carbide)(leveling agent) The adhesive was transfered to a glass container using a silk screen process. The ink was smooth, provided a surface without irregularities, and adhered well to the glass.
Example 4 Preparation of adhesive ink An adhesive ink was prepared as follows: grams Loctite 36331 (Loctite Corp., Newington, CT) 25 grams Elvacite 2043 acrylic resin (Polymethylmethacrylate) (Dupont Corp., Wilmington DE) 0 2 grams Irgacure 184 This composition was mixed for about one hour with the mixer. The ink was then silk screened onto a glass container through a 255 line screen. The adhesive was cured by four passes through a 300 watt 30 feet/minute UV conveyer.
The surface was a bit bumpy and uneven after hot stamping.
Example Preparation of adhesive ink An adhesive ink was prepared as follows: 27 parts urethane methacrylate parts high boiling methacrylate resin parts acrylic acid parts hydroxyethylmethacrylate, 5 parts photoinitiator 3 parts substituted silane (Dow Corning, Huls Silane Ester "Scatterway") The resulting formulation provides an excellent, easily r ICPII pl~ I curable ink which works well with hot stamping.
While the invention has been described in connection with the preferred embodiment, it is not intended to limit the scope of the invention to the particular form set forth, but, on the contrary, it is intended to cover such alternatives, modifications, and equivalents as may be included within the spririt and scope of the invention as defined by the appended claims.
*t e** o seo o* s os o *s .5 5 a oo .o os
S
S 55 P
Claims (14)
1. A method of decorating glass including: i) applying to the surface of the glass a UV curable composition including a) 20-87% of a monomer. b) 10-35% of a polymer dissolved in the monomer. c) 3-10% photoinitiator. ii) applying ultraviolet light to the composition to thereby cure the curable adhesive ink on the glass and wherein the coated surface is not fired.
2. The method of claim 1, said curable composition additionally including 1- by weight of the total composition, of silane.
3. The method of claim 1 or claim 2 wherein the curable composition additionally includes 1-20% pigment.
4. The method of any one of claims 1 to 3 wherein the monomer is isobornyl acrylate, urethane methacrylate, urethane acrylate, tetrahydrofurfuryl acrylate, acrylic resins, aromatic urethane acrylic resin, or mixtures thereof. 20
5. The method of any one of claims 1 to 4 wherein the polymer is polyethylmethacrylate, polymethylmethacrylate, polyurethane, polyester acrylates, epoxy acrylates, or mixtures thereof.
6. The method of any one of claims 1 to 5 wherein the photoinitiator is selected from 1-hydroxycyclohexylphenylketone,2,2-dimethoxy-2- phenylacetophenone, diethoxyacetophenone, and 2-methyl-1- (methylethiophenyl)-2-(4-morpholinyl) 1 -propanone.
7. The method of any one of claims 1 to 6 wherein the polymer is polyethylmethacrylate. C:\WINWORDUULIEDAVID\15091A.DOC I I IL- L 11
8. The method of any one of claims 1 to 7 wherein the photoinitiator is 1-hydroxycyclohexylphenylketone.
9. The method of any one of claims 1 to 8 wherein the monomer is isobornyl acrylate, urethane metiiacrylate or mixtures thereof.
The method of claim 2 wherein the silane is 3-glycidoxy-propyl trimethyl silane.
11. The method of any one of claims 1 to 10 wherein the decorated glass comprises a glass container. 0:
12. A glass surface coated with a curable composition according to the method any one of claims 1 to
13. A glass container decorated by the method of any one of claims 1 to 11.
14. A method according to claim 1 substantially as herein described with reference to any one of the examples. S.. DATED: 16 January 1997 PHILLIPS ORMONDE FITZPATRICK S"Attorneys for: REVLON CONSUMER PRODUCTS CORPORATION C:\WINWORDJUUEUNAVIDM501A.DOC ~M ABSTRACT A curable adhesive ink composition including, by weight of the total composition: a) 20-90% of a monomer. b) 10-35% of a polymer dissolved in the monomer. c) 3-10% photoinitiator. I
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU15091/95A AU678682B2 (en) | 1993-05-26 | 1995-03-27 | Adhesive ink composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU661580 | 1993-05-26 | ||
| AU15091/95A AU678682B2 (en) | 1993-05-26 | 1995-03-27 | Adhesive ink composition |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU39832/93A Division AU661580B2 (en) | 1993-05-25 | 1993-05-26 | Hot stamping glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU1509195A AU1509195A (en) | 1995-07-27 |
| AU678682B2 true AU678682B2 (en) | 1997-06-05 |
Family
ID=3705211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU15091/95A Ceased AU678682B2 (en) | 1993-05-26 | 1995-03-27 | Adhesive ink composition |
Country Status (1)
| Country | Link |
|---|---|
| AU (1) | AU678682B2 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU567891B2 (en) * | 1982-10-08 | 1987-12-10 | Johnson Matthey Public Ltd. Co. | Radiation curable and firable printing inks |
| AU3983293A (en) * | 1993-05-25 | 1994-12-01 | Revlon Consumer Products Corporation | Hot stamping glass |
-
1995
- 1995-03-27 AU AU15091/95A patent/AU678682B2/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU567891B2 (en) * | 1982-10-08 | 1987-12-10 | Johnson Matthey Public Ltd. Co. | Radiation curable and firable printing inks |
| AU3983293A (en) * | 1993-05-25 | 1994-12-01 | Revlon Consumer Products Corporation | Hot stamping glass |
Also Published As
| Publication number | Publication date |
|---|---|
| AU1509195A (en) | 1995-07-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |