AU671262B2 - Absorbent article having a nonwoven and apertured film coversheet - Google Patents

Description

OPI DATE 15/06/93 AOJP DATE 19/08/93 APPLN. ID 29177/92 Ii 11 IEEIIIII Ill lll III PCT NUMBER PCT/US92/09227 AU9229177 INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (51) International Patent Classification 5 (Il) International Publication Number: WO 93/09741 A61F 13/15 Al (43) International Publication Date: 27 May 1993 (27.05.93) (21) International Application Number: PCT/US92/09227 (74) Agents: REED, David et al.; The Procter Gamble Company, 5299 Spring Grove Avenue, Cincinnati, OH (22) International Filing Date: 30 October 1992 (30.10.92) 45202 (US).

Priority data: (81) Designated States: AU, BB, BG, BR, CA, CS, Fl, HU, JP, 794745 19 November 1991 (19.11.91) US KP, KR, LK, MG, MN, MW, NO, PL, RO, RU, SD, European patent (AT, BE, CH, DE, DK, ES, FR, GB, GR, IE, IT, LU, MC, NL, SE), OAPI patent (BF, BJ, CF, (71) Applicant: THE PROCTER GAMBLE COMPANY CG, CI, CM, GA, GN, ML, MR, SN, TD, TG).

[US/US]; One Procter Gamble Plaza, Cincinnati, OH 45202 (US).

Published (72) Inventors: AZIZ, Mohammed, Iqbal J1, Kemang Timur With international search report.

IV No. 10, Kelurahan Bangkai, JK, Selatan 74553 Before the expiration of the tie limit for amending the KIRKPATRICK, Sharon, Darlene 6313 Oak Creek claims and to be republished in the event of the receipt of Drive, Cincinnati, OH 45247 RUUSKA, Robert, amendments.

William 5530 Biscayne Avenue, Cincinnati, OH 45248 ASKIN, Robert, Eugene, II 640 Terrace View Drive, Cincinnati, OH 45255 (US).

(54)262Title: ABSORBENT ARTICLE HAVING A NONWOVEN AND APERTURED FILM COVERSHEET (54)Title: ABSORBENT ARTICLE HAVING A NONWOVEN AND APERTURED FILM COVERSHEET -26a (57) Abstract An absorbent article having improved strikethrough, rewet characteristics, and feel is disclosed. The absorbent article has a topsheet comprising a nonwoven material (24) and apertured thermoplastic film The apertured thermoplastic film is treated with a surfactant preferably by incorporating the surfactant into the resin used to make the thermoplastic film. The combination of the nonwoven material and the surfactant-treated apertured thermoplastic film permit liquids to rapidly penetrate the topsheet while preventing liquid in the absorbent core of the article from flowing back through the topsheet. The nonwoven material provides the topsheet with improved, less plastic-like feel.

WO 93/09741 PCT/US92/09227 ABSORBENT ARTICLE HAVING A NONWOVEN AND APERTURED FILM COVERSHEET FIELD OF THE INVENTION This invention relates to absorbent articles such as diapers, incontinent articles, sanitary napkins, and the like. More particularly, this invention relates to absorbent articles having a nonwoven and apertured film coversheet.

BACKGROUND OF THE INVENTION All manner and variety of absorbent articles configured for the absorption of body fluids are, of course, well known. Current types of absorbent articles include diapers, incontinent articles, and sanitary napkins.

A major in use problem encountered with known absorbent articles is leakage of waste product which contaminates clothing articles that contact the absorbent article, such as pants, shirts, and bedding. The amount of leakage experienced by the wearer can be reduced by improving the rate at which the liquid enters the absorbent core. Thus, an absorbent article in which the liquid rapidly penetrates the topsheet and is contained in the absorbent core will experience less leakage than an absorbent article in which liquid is able to run across the topsheet before penetrating into the absorbent core. Reducing run-off, therefore, reduces the amount of leakage experienced with the absorbent article.

SUBSTTTUTE SHEET WO 93/09741 PCr/UlS92/09227 -2- Another in-use problem associated with absorbent articles is the dryness of the skin contacting surface. Generally, the drier the skin contacting surface, the more comfortable the absorbent article. There have been several patents directed towards reducing the surface wetness in disposable diaper structures.

U.S. Patent 3,945,386 issued to Anczurowski on March 23, 1976 and U.S. Patents 3,965,906 and 3,994,299 issued to Karami on June 29, 1976 and November 30, 1976, respectively, teach diaper structures having a perforated thermoplastic film interposed between the topsheet and the absorbent core. U.S. Patent 4,324,247 issued to Aziz on April 13, 1982 describes an effort directed to both reducing run-off and reducing the surface wetness of absorbent articles.

Still another problem associated with absorbent articles is the feel of the skin contacting surface. A problem with utilizing formed films is that some consumers do not like the plastic feel associated with such films. A number of efforts have been directed at improving the feel of the surface of absorbent articles. One effort is described in U.S. Patent 3,967,623 issued to Butterworth, et al. The Butterworth patent is directed to an absorbent pad having a facing sheet comprising a perforated thermoplastic web having an integral fibrous or sueded outer surface.

The products described in most of the above references, however, are less than ideal in achieving a good combination of all three desired properties of reduced surface run-off, improved rewet characteristics, and improved feel. While the product described in the Aziz patent works quite well, the search for improved coversheets has continued.

It is therefore an object of the present invention to provide an absorbent article having a good combination of reduced surface run-off characteristics, improved surface dryness, and an improved softer, less plastic-like feel.

SUBSTITUTE SHEET 2a Other objects of the present invention will become more fully apparent in the following description of the embodiments of this invention and from the appended claims.

SUMMARY OF THE INVENTION This invention relates to absorbent articles such as diapers, incontinent articles, sanitary napkins, and the like. More particularly, this invention relates to absorbent articles having a nonwoven and apertured film coversheet.

The invention provides a liquid pervious topsheet for an absorbent article which has a longitudinal centerline defining a longitudinal direction, a transverse centerline defining a transverse direction, a body-facing side, and longitudinal edges, said topsheet comprising a nonwoven material comprising a plurality of fibers and an apertured, thermoplastic film placed together in a face-to-face relationship so that said nonwoven material forms the body-facing side of the absorbent article, and said film underlies said nonwoven material such that at 15 least a portion of the fibers of said nonwoven material are embedded in some •eo portion of said film, wherein said film is comprised of a liquid impervious thermoplastic resinous material which is treated with a surfactant to enhance the *overall permeability of said topsheet, and said film hcs a thickness of from 0.001 to 0.002 inches and is provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries each having a base opening adjacent said nonwoven material and an oppositely disposed apex opening, an angle of taper of from 100 to 600, a base opening dimension of from 0,006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch.

The capillaries enable the film to transport liquid through the topsheet to 25 the absorbent core and prevent liquid from flowing in the reverse direction.

Preferably both the nonwoven fabric and the film, are treated with a surfactant to enhance the permeability completely through the topsheet.

WO 93/09741 PCr/US92/09227 -3- -Other objects^.-obf n6p4sU"nt-inventinn will bhGoge more fu11^ apparent in the following description of the embodiments of is invention and from the appehded claims.

SUMMARY OF THE INVENTION This invention relates to absorbent articl such as diapers, incontinent articles, sanitary napkins, the like. More particularly, this invention relates to sorbent articles having a nonwoven and apertured film covershe The absorbent article compri es, in its basic form, a liquid pervious coversheet (or tops et), a liquid impervious backsheet joined to the topsheet, a an absorbent core positioned between the topsheet and back eet. The topsheet is comprised of a nonwoven material, p ferably a nonwoven fabric, and an apertured plastic film. e apertured plastic film preferably has a multiplicity o tapered capillaries. The capillaries enable the film to tr sport liquid through the topsheet to the absorbent core and revent liquid from flowing in the reverse direction. At least he film, and preferably both the nonwoven fabric and the fi are treated with a surfactant to enhance the permeability eely 1h 4Gn+ et The resulting absorbent article is believed to exhibit a good combination of all three desired characteristics of reduced surface run-off and improved surface dryness characteristics, as well as improved feel.

BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a simplified perspective view of an absorbent article of the present invention.

Figure 2 is a cross-sectional view taken along line 2-2 of Figure 1.

SUBSTITUTE SHEET WO 93/09741 P~3r/US92/09227 -4- Figure 3 is a cross-sectional view taken along line 3-3 of Figure 1.

Figure 4 is an edge view of the nonwoven fabric comprising part of the topsheet of the absorbent article.

Figure 5 is an edge view of the apertured plastic film comprising the other component of the topsheet.

Figures 6-8 are edge views of alternative embodiments of the completely assembled topsheet.

Figure 9 is a schematic representation of one process for making a coversheet for the absorbent article.

DESCRIPTION OF THE PREFERRED EMBODIMENTS I. The Absorbent Article.

This invention relates to absorbent articles such as diapers, incontinent articles, sanitary napkins, and the like. More particularly, this invention relates to absorbent articles having a nonwoven and apertured film coversheet.

The term "absorbent article", as used herein, refers to articles which absorb and contain body exudates. More specifically, the term refers to articles which are placed against or in proximity to the body of the wearer to absorb and contain the various exudates discharged from the body. The term "absorbent article" is intended to include diapers, incontinent articles, sanitary napkins, pantiliners, and other articles used to absorb body exudates. The term "disposable" refers to articles which are intended to be discarded after a single use and preferably recycled, composted, or otherwise disposed of in an environmentally compatible manner. (That is, they are not intended to be laundered or otherwise restored or reused as an absorbent article.) SUBSTITUTE SHEET WO 93/09741 PCrUS9)2/09227 5 The term "diaper" refers to a garment generally worn by infants and incontinent persons which is drawn up between the legs and fastened about the waist of the wearer. Suitable diapers that can be provided with the coversheet described herein are disclosed in U.S. Patent Re. 26,152, issued to Duncan, et al. on January 31, 1967; U.S. Patent 3,860,003 issued to Buell on January 14, 1975; U.S. Patent 4,610,678 issued to Weisman, et al. on September 9, 1986; U.S. Patent 4,673,402 issued to Weisman, et al. on June 16, 1987; U.S. Patent 4,695,278 issued to Lawson on September 22, 1987; U.S. Patent 4,704,115 issued to Buell on November 3, 1987; U.S. Patent 4,834,735 issued to Alemany, et al. on May 30, 1989; U.S. Patent 4,888,231 issued to Angstadt on December 19, 1989; and U.S. Patent 4,909,803 issued to Aziz, et al. on March 20, 1990.

The term "incontinent article" refers to pads, undergarments (pads held in place by a suspension system of same type, such as a belt, or the like), inserts for absorbent articles, capacity boosters for absorbent articles, briefs, bed pads, and the like, regardless of whether they are worn by adults or other incontinent persons. Suitable incontinent articles that can be provided with the coversheet described herein are disclosed in U.S. Patent 4,253,461 issued to Strickland, et al. on March 3, 1981; U.S.

Patents 4,597,760 and 4,597,761 issued to Buell; the above-mentioned U.S. Patent 4,704,115; U.S. Patent 4,909,802 issued to Ahr, et al.; U.S. Patent 4,964,860 issued to Gipson, et al. on October 23, 1990; and in U.S. Patent Application Serial Numbers 07/637,090 and 07/637,571 filed respectively by Noel, et al. and Feist, et al. on January 3, 1991.

The term "sanitary napkin" refers to an article which is worn by females adjacent to the pudendal region that is intended to absorb and contain various exudates which are discharged from the body blood, menses, and urine). Suitable sanitary napkins that can be provided with the coversheet described herein are disclosed in U.S. Patent 4,285,343, issued to McNair on August 1981; U.S. Patents 4,589,876 and 4,687,478, issued to Van Tilburg on May 20, 1986 and August 18, 1987 respectively; U.S. Patents SUBSTITUTE SHEET WO 93/09741 PC~US9209227 -6- 6 4,917,697 and 5,007,906 issued to Osborn, et al. on April 17, 1990 and April 16, 1991, respectively; and U.S. Patents 4,950,264 and 5,009,653 issued to Osborn on August 21, 1990 and April 23, 1991, respectively; and in U.S. Patent Application Serial No. 07/605,533 filed October 29, 1990 in the name of Visscher, et al.

The term "pantiliner" refers to absorbent articles that are less bulky than sanitary napkins which are generally worn by women between their menstrual periods. Suitable pantiliners that can be provided with the coversheet described herein are disclosed in U.S. Patent 4,738,676 entitled "Pantiliner" issued to Osborn on April 19, 1988.

The disclosures of all patents, patent applications (and any patents which issue thereon, as well as any corresponding published foreign patent applications), and publications mentioned throughout this patent application are hereby incorporated by reference herein. It is expressly not admitted, however, that any of the documents incorporated by reference herein teach or disclose the present invention. It is also expressly not admitted that any of the commercially available materials or products described herein teach or disclose the present invention.

Figure 1 shows a simplified absorbent article 10 that could represent a diaper prior to its being placed on a wearer.

It should be unders'iocd, however, that the present invention is not limited to the particular type or configuration of absorbent article shown in the drawings. As shown in Figure 2, such an absorbent article 10 basically comprises topsheet 12, backsheet 14, and absorbent core 16.

The absorbent article 10 has two surfaces, a body-contacting surface (or "body surface") 10a and a garment surface 1Ob. The body surface 10a is intended to be worn adjacent to the body of the wearer. The garment surface 10b of the absorbent article (shown in FIG. 2) is on the opposite side and is intended to be SUBSTITUTE SHEET WO 93/09741 PC/ US92/09227 7 -7placed adjacent to the wearer's undergarments or clothing when the absorbent article 10 is worn.

The absorbent article 10 has two centerlines, a longitudinal centerline 1 and a transverse centerline t. The terms "longitudinal" and "transverse" or "lateral" (the latter two being interchangeable), are defined in U.S. Patent 5,007,906 issued to Osborn, III, et al. and are applicable to the absorbent articles described herein. Figure 1 shows that the absorbent article has two spaced apart longitudinal edges 18 and two spaced apart transverse or end edges (or "ends") 20, which together form the periphery 22 of the absorbent article The individual components of the absorbent article 10 will now be looked at in greater detail.

The topsheet 12 is compliant, soft-feeling and non-irritating to the wearer's skin. Further, topsheet 12 is liquid permeable, permitting liquids to readily penetrate through its thickness.

The topsheet 12 has a body-facing side or face 12a and a garment-facing side or face 12b, two longitudinal or side edges 12c and two end edges 12d. (A similar numbering system will be used for the other components of the diaper 10. That is, the side of the component facing the wearer's body will be designated by the number of the component and a reference letter the side facing the wearer's undergarments by the number of the component and the letter and the side and end edges by the number of the component and the reference letters and respectively.) The topsheet 12 comprises two components, a nonwoven material, preferably in the form of a fabric 24, and a three dimensional apertured plastic film 26. The garment-facing side or face 24b of the nonwoven fabric 24 is preferably mal.,tained in close contact with, and more preferably bonded to, the body-facing face 26a of the apertured plastic film 26. The component parts of the topsheet 12 are examined in greater detail below.

SUBSTITUTE SHEET WO 93/09741 PC/US92/09227 8 The nonwoven fabric 24 may be any nonwoven fabric that is permeable to liquids. A suitable nonwoven fabric 24 may be manufactured from a wide range of materials such as natural fibers wood or cotton fibers), synthetic fibers polyester, polypropylene) or a combination thereof. The nonwoven fabric 24 is preferably made from fibers selected from a group consisting of polypropylene, polyester, polyethylene, polyvinylalcohol, starch base resins, polyurethanes, cellulose and cellulose esters.

Clearly, there are a number of manufacturing techniques which may be utilized to manufacture the nonwoven fabric 24. For example, nonwoven fabric 24 may be resin-bonded, needle punched, spunbonded, carded, the latter including, thermally bonded, air-thru bonded, and spunlaced fabrics. A preferred nonwoven fabric 24 is a thermally bonded polypropylene fabric.

The nonwoven fabric 24 should be lightweight having a weight from about 1 to about 40 g/sq m, preferably from about 1 to about 23 g/sq.m. For one embodiment, the nonwoven fabric 24 has a basis weight range of from about 18 to about 22 grams per square yard (about 21 to about 26 g/sq.m.) and a caliper C as shown in Figure 4, of from about 5 to about 15 mils (about 0.13 to about 0.38 mm.) when measured under a load of about 200 pascals. Such a nonwoven fabric 24 is further characterized by a minimum wet or dry tensile strength of at least about 400 grams per centimeter in the longitudinal or machine direction and at least about 55 grams per centimeter in the cross machine direction.

In ano'tier embodiment, the nonwoven fabric 24 has a lighter '"eight of from about 8 to about 12 g/sq m. Such lighter nonwoven Fabrics are highly preferred. They are preferred because they can be used (with a lightweight film) to form a composite topsheet 12 that is sufficiently thin and lightweight that it behaves as a single sheet of material. This provides the advantages that such a topsheet may be more flexible and use smaller amounts of raw materials.

SUBSTITUTE SHEET WO 93/09741 PC7/US9A'/9227 9 -9- The nonwoven fabric 24 preferably has a pattern of thermal bond sites 34. One preferred nonwoven fabric comprises a carded thermally dot bonded polypropylene web. The thermal bonds in such a fabric are preferably rectangularly-shaped in plan view. The bonds are preferably arranged in staggered rows. Another preferred nonwoven is a spunbonded polypropylene web with similarly arranged thermal bonds. Still another preferred nonwoven fabric 24 is a carded polypropylene web which is embossed in accordance with the method described in U.S. Patent 4,781,710 issued to Megison, et al. This nonwoven fabric 24 has embossed and thermal bonded areas that are diamond-shaped in plan view.

The diamond-shaped bonds are spaced apart and arranged in a diamond-shaped grid such as is shown in Figures 1 and 2 of the Megison, et al. patent. (The embossing need not extend into the underlying core, however.) The apertured plastic film 26 is preferably located between the nonwoven fabric 24 and the absorbent core 16. As shown in Figure 5, the apertured plastic film 26 is preferably a three-dimensional structure which has a plurality of tapered capillaries 40, each of which has a base opening 38, and an apex opening 42. The apex openings 42 are preferably in intimate contact with the absorbent core 16.

The apertured plastic film 26 is manufactured from a liquid impervious, preferably thermoplastic material. One suitable material is a low density polyethylene film having a thickness of from 0.001 to 0.002 inches (0.0025 to 0.0051 The thermoplastic material for use in the manufacture of the apertured plastic film 26 is selected from a group consisting generally of polyethylene, polypropylene, polyvinyl chloride, starch base resins, polyvinylalcohol, polyurethanes, polycaprolactone and cellulose esters. The thermoplastic material used in the present invention preferably has a density in the range of from about g/cm 3 to about 1.20 g/cm 3 with the more preferred range of densities being from about .91 g/cm 3 to about .92 g/cm 3 The general melt indices range for such material is preferably from SUBSTITUTE SHEET 9a about 2 to about 100, with the more preferred range being from about 4 to about In one preferred embodiment, the thermoplastic material is provided with a multiplicity of tapered capillaries 40 in a manner, size, configuration and orientation set forth in U.S. Patent 3,929,135 issued to Thompson on December 1975. Thus, in this preferred embodiment, the apertured plastic film is provided with tapered capillaries of critical opening dimensions and of critical angles of taper, each of which has a base in a plane of the topsheet and an apex remote from said plane of the topsheet. The critical angle of taper is from about 100 to about 600; base opening dimension is from about 0.006 to about 0.250 inch; apex opening dimension is from about 0.004 to about 0.100 inch. Other

S

o oe *e WO 93/09741 I'Cr/ US92/9227 10 hnut 2 to aih-t -100 with the mnre prforrai range bing about 4 to about In one preferred embodime e thermoplastic material is provided with a mul city of tapered capillaries 40 in a manner, si configuration, and orientation set forth in U.S.

135-r9-y--ueo.4-po-Dcomber 30, 1975. Othc suitable apertured plastic films are disclosed in U.S. Patent 4,324,426, issued to Mullane, et al. on April 1982, U.S.

Patent 4,342,314, issued to Radel, et al. on August 3, 1982, and U.S. Patent 4,463,045, issued to Ahr, et al. on July 31, 1984.

The apertured plastic film 26 can comprise other types of apertured plastic films that are not thermoplastic. The type of film used depends on the type of processing the film and nonwoven components are subjected to during the manufacture of the topsheet 12. Thermoplastic films are used when the nonwoven fabric 24 and the film 26 are integrally formed into a composite structure by melting. Other suitable types of apertured films include, but are not limited to hydro-formed films. Hydro-formed films are described in at least some of the following U.S. Patents: 4,609,518, 4,629,643, 4,695,422, 4,772,444, 4,778,644, and 4,839,216 issued to Curro, et al., and U.S. Patent 4,637,819 issued to Ouellette, et al.

The nonwoven fabric 24 and the apertured plastic film 26 may be placed into a face-to-face relationship. The two components may be secured or unsecured. The two components, if secured, may be secured to each other by many different methods (or securement means) or combinations of methods. Suitable methods for securing the two components include, but are not limited to adhesives, fusion including heat bonding and/or pressure bonding, ultrasonics, and dynamic mechanical bonding.

The adhesives can be applied in a uniform continuous layer, a patterned layer, or an array of separate lines, spirals, beads, or spots of adhesive. The adhesive attachment preferably comprises an open pattern network of filaments of adhesive as is disclosed SUBSTITUTE

SHEET

WO 93/09741 PCr/ US92/9227 11 in U.S. Patent 4,573,986 issued to Minetola, et al. on March 4, 1986, or an open pattern network of filaments comprising several lines of adhesive filaments swirled into a spiral pattern as illustrated by the apparatus and method shown in U.S. Patent 3,911,173 issued to Sprague, Jr. on October 7, 1975; U.S. Patent 4,785,996 issued to Zieker, et al. on No',ember 22, 1978; and U.S.

Patent 4,842,666 issued to Werenicz on June 27, 1989. A method of heat/pressure bonding that could be used is described in U.S.

Patent 4,854,984 issued to Ball, et al. on August 8, 1989.

The nonwoven fabric 24 and the apertured plastic film 26 may alternatively be indirectly secured. For instance, the two components could be secured to or through a thin layer of airfelt, or a layer of hydrophobic material positioned between the nonwoven fabric 24 and the apertured plastic film 26. Preferably, such additional layer or layers are treated with a surfactant (as described in greater detail below).

The nonwoven fabric 24 and the apertured plastic film 26 can alternatively be integrally formed into a composite structure.

The terms "composite", "composite structure" or "combination", as used herein, refer to relationships in which portions of the nonwoven fabric 24 extend into the film 26, and vice versa so that they are integrally attached. These components cease to exist as separate layers in a face-to-face relationship.

Figures 6 and 7 show several possible embodiments of such a composite structure. In the embodiments shown, at least a portion of the fibers in the nonwoven web 24 are embedded in some portion of the thermoplastic film 26. The relationship between the surfaces of the respective components differs in each embodiment.

However, in both embodiments shown in Figures 6 and 7, the garment-facing face 24b of the nonwoven material 24 is positioned between the body-facing and garment-facing surfaces of the apertured film 26. These can be contrasted with the embodiment shown in Figure 8 in which the components are separate layers in a face-to-face relationship.

SUBSTITUTE SHEET WO 93/09741 PC"/US92/09227 12 Figure 6 shows an example of a composite structure in which the body-facing sides of the two components, 24a and 26a, lie in approximately the same plane. Figure 7 shows a composite structure in which the body-facing side 24a of the nonwoven material 24 is above that of the fil, 26 so the body-facing side 26a of the film 26 is positioned between the surfaces of the nonwoven fabric 24. The embodiment shown in Figure 7 is bel.eved to be the more preferable of these two embodiments because it provides the softer nonwoven fabric 24 over the entire body-facing surface 12a of the topsheet 12. This can be contrasted with the embodiment shown in Figure 6. In the embodiment shown in Figure 6, portions of the fibers comprising the nonwoven fabric 24 are embedded into the film along at least a portion of the body-facing surface 12a of the topsheet 12. These embedded portions are typically not as soft as the nonwoven material alone.

In other alternative embodiments, the topsheet 12 could be constructed so that the film 26 underlies only a portion of the area of the nonwoven fabric 24. For example, the film 26 may be of a smaller size that it only covers the portion of the absorbent article into which liquids are deposited or absorbed. This could be in the crotch region of the absorbent article or in a urine "target zone".

The absorbent core 16 is positioned between the topsheet 12 and the backsheet 14. The absorbent core 16 provides the means for absorbing bodily exudates. The absorbent core 16 need not have an absorbent capacity much greater than the total amount of exudates to be absorbed. The absorbent core 16 is generally compressible, conformable, and non-irritating to the user's skin.

It can comprise any material used in the art for such purpose.

Examples include comminuted wood pulp which is generally referred to as airfelt, creped cellulose wadding, cross-linked cellulose fibers, absorbent foams, absorbent sponges, synthetic staple fibers, polymeric fibers, hydrogel-forming polymer gelling agents, peat moss, combinations of the foregoing, or any equivalent material or combinations of materials.

SUBSTITUTE

SHEET

WO 93/097941 'Cr/US92/09227 13 Suitable cross-linked cellulose fibers are described in U.S.

Patent 4,888,093, issued December 19, 1989 to Cook, et al.; U.S.

Patent 4,822,543, issued April 18, 1989 to Dean, et al.; U.S.

Patent 4,889,595, issued December 26, 1989 to Schoggen, et al.; U.S. Patent 4,889,596, issued December 26, 1989 to Schoggen, et al.; U.S. Patent 4,898,642, issued February 6, 1990 to Moore, et al.; and U.S. Patent 4,935,022, issued June 19, 1990 to Lash, et al.

The characteristics of the absorbent core 16 for particular types of absorbent articles are described in greater detail in the patents and documents incorporated by reference herein, and the patents and other documents incorporated by reference in those documents, the disclosures of which are all incorporated by reference herein. Other suitable absorbent core arrangements are described in U.S. Patents 4,988,344 and 4,988,345, and European Patent Application Publication No. 0 198 683, published October 22, 1986 in the name of Duenk, et al. which are also incorporated by reference herein. The absorbent article 10 could also include any additional layers or other components such as are described in the patents incorporated by reference. For example, the absorbent article 10 may comprise an acquisition layer or patch of cross-linked cellulose fibers positioned between the topsheet 12 and the absorbent core 16.

The backsheet 14 is impervious to liquids and is preferably manufactured from a thin plastic film, although other flexible liquid impervious materials may also be used. The backsheet 14 prevents liquid contained in absorbent core 16 from wetting articles which contact the absorbent article 10. Polyethylene films having a thickness of from about 0.001 to about 0.002 inches (0.0025 to 0.0051 cm.) have been used for the backsheet 14 with satisfactory results. As used herein, the term "flexible" refers to materials which are compliant and which will readily conform to the general shape and contours of the human body.

UBSTITUTE

SHEET

WO 93/097411 I'Cr/ US92/0227 14 The backsheet 14 is superimposed on the garment-facing side 16b of absorbent core 16 and preferably extends beyond the edges thereof. The topsheet 12 is superimposed over the body-facing side 16a of the absorbent core 16, and may also extend beyond the edges of the core 16. The absorbent core 16 is, therefore, positioned between the topsheet 12 and the backsheet 14. The topsheet 12 and backsheet 14 are joined to each other such as around their peripheries. The topsheet 12 and backsheet 14 can be joined in any suitable manner such as by the use of adhesives, crimping, heat-sealing, or ultrasonic bonding. A more detailed description of how topsheet 12, backsheet 14, and absorbent core 16 may be assembled for particular types of absorbent articles is provided in the documents incorporated by reference herein.

2. Method of Making the Absorbent Article.

A suitable process of preparing the topsheet 12 is shown in Figure 9. QOne ori-on of t he-pr-ocs--desc -w is il st forth in a patent -applicaonfle--i4-he-- ame--of-bewe--by Tredegar Fi-m Podut: s-on the- ame-day-as-he -res-ent-app-4a-t-on-.

The apparatus for making the topsheet for the absorbent article of the present invention is designated 100. The apparatus 100 includes a first supply source 102 and a second supply source 104. The supply sources (or "supply means") 102 and 104 feed the materials that will comprise the components of the topsheet into the system.

The nonwoven material is fed into the process at the place indicated by the letter A. The first supply source 102 feeds a first material 24' used to make the nonwoven fabric 24 into the system. The first material 24' can be any of those materials specified above as being suitable for use in or as the nonwoven fabric 24. The nonwoven material may be supplied by any suitable supply source. The first supply source 102 could include, but is not limited to any conventional means used to introduce a material into a laminating process. The first supply source 102 could be, SUBSTITUTE

SHEET

WO 93/09741 PCr/~US92/0227 15 but is not limited to an unwind roll; a web or fabric producing machine, such as a conventional carding machine, spunbonding machine; or a hopper for feeding a layer of loose fibers into the system.

In the process illustrated, the first supply source comprises a supply roll 102 which holds first material in the form of a nonwoven fabric web 24'. The nonwoven fabric web 24' is preferably of a thin, soft construction. Some preferred nonwoven fabrics are manufactured by the Fiberweb Group under the trademarks CELESTRA and HOLMESTRA.

The nonwoven fabric web 24' is preferably treated with an effective amount of surface active agent or surfactant. The surfactant provides the nonwoven fabric's surface with greater polarizability than it would have without the surfactant being added. Higher surface polarity yields higher wettability.

Suitable surfactants include a product known commercially as ATMER 645 manufactured by ICI Specialty Chemicals.

The nonwoven fabric 24 may be treated with a surfactant prior to or during the time it is manufactured. For example, it may be treated after it is unwound from supply roll 102, or at any other time during the process described herein. The surfactant may be applied to either surface of the nonwoven fabric. This may be done by any known techniques, such as by spraying, by padding, or by the use of transfer rolls. The surfactant can alternatively (or additionally) be incorporated into the nonwoven fabric such as between or within the fibers of the nonwoven fabric. Preferably, the nonwoven fabric is treated with a surfactant prior to the time it is supplied in the present process.

The thermoplastic material is fed into the process at the place indicated B. The second supply source ]V4 feeds a second material 26' used to make the thermoplastic film 26 into the system. The second material 26' can be any of those materials specified above as being suitable for use in making the SUBSTITUTE

SHEET

WO 93/09741 P'CIM S92/09~227 16 thermoplastic film 26. The thermoplastic material is supplied by any suitable supply source 104. Thus, the second supply source could be any conventional means used to introduce a film into a process. The second supply source 104 could be, but is not limited to an unwind roll, a film producing machine, or a supply of resin pellets from which the film is to be made. In the embodiment of the process illustrated, the second supply source is a die 104 in which thermoplastic material is extruded and from which the thermoplastic material flows.

The apertured plastic film 26 should also be treated with an effective amount of a surfactant. Treating the film with a surfactant is particularly helpful in eliminating a prior problem of liquids passi'g through the nonwoven material, and collecting at the interface between the nonwoven material and the apertured film and then passing back through the nonwoven to contact the wearer's skin. The surfactant, thus, enhances the permeability completely through the topsheet 12.

The apertured plastic film 26 may be treated with the surfactant in any of the general manners specified above (that are not inherently limited to use with fibrous materials).

Preferably, a small amount of surfactant is compounded into the resin pellets from which the film 26 is made. The surfactant can be compounded in!to polyolefin resin pellets such as polyethylene resin pellets. After processing, the surfactant chemical additive exudes to the film surface. Such exudation is due to the 'insolubility of the additive in the polyolefin at normal temperatures. During extrusion, the molten amorphous resin mass is quenched to a semi-crystalline web. As the ordered crystalline structure forms, the amorphous volume decreases. Since the additive molecules are incompatible in the crystalline structure and insoluble in the cooling amorphous region, they are squeezed or caused to migrate to the surface of the polyolefin.

The surfactant can be the same product referred to above known commercially as ATMER 645. The amount of the surfactant SUBSTITUTE SHEET WO 93/09741 PCr/US92/0227 17 added should be an amount sufficient to render the desired fluid transport through the topsheet 12 (after the corona discharge treatment described below). When a surfactant treated nonwoven fabric, is used, the amount of surfactant is preferably from about to about by weight, of the surfactant in relation to the thermoplastic material. If a non-treated nonwoven fabric is used, from about 2 to about 5% surfactant, by weight, in relation to the thermoplastic material should be used. It is believed that the excess surfactant may migrate into the nonwoven fabric.

The die 104 supplies the thermoplastic material as a hot film 26' which moves along a predetermined path. In the present embodiment, a rotary cylindrical vacuum drum 126 is located along the predetermined path. The nonwoven fabric web 24' is moved past an application roller 128 so that it comes in contact with the hot film 26'. The nonwoven fabric web 24' travels with the hot film 26' along the sid- of the drum 126. The film 26' is applied to the drum 126 where the nonwoven fabric web 24' is bonded to the hot film 26' by vacuum lamination to form a composite web 12'.

The three-dimensiona& apertures are formed by placing a perforated three-dimensional forming element or screen on the drum 126. As the film 26' is moved along the drum, an air pressure differential is applied across the film 26' toward a portion of the screen sufficient to distort the film into the perforations of the forming element. The pressure differential thus created causes a forming and rupture of the film 26' resulting in three-dimensional apertures. A process that can be used to create three-dimensional apertures in plastic film is described in detail in U.S. Patent Nos. 4,351,784, 4,456,570 and 4,535,020.

The composite web 12' passes between nip rollers 134 and 136 past a roller 138 to a corona treating roller 140. Although the chemically treated composite web 12' is more polar than an untreated web, corona discharge treatment of the web 12' provides the desired maximum wettability. The corona treating roller 140 is usually covered with a suitable dielectric material such as SUBSTITUTE SHEET WO 93/09741 PCTUS92/09227 18 epoxy, fluorinated polyethylene (TELFON), chlorinated polyethylene (HYPA-LON), or polyester (MYLAR). The electrode or corona bar 142 is suspended para!,l to the corona treating roller 140 at about 16 mm above the Paoll. The corona bar 142 is energized by a transformer and corona treating power source 144. The above described corona discharge treatment is described in detail in U.S. Patent Nos. 4,351,784, 4,456,570 and 4,535,020. This completes the formation of the topsheet material 12.

The finished topsheet material 12 continues past a second tension roller 146 to a slitter 148 where it is slit. The topsheet material 12 then proceeds past rollers 150 and 15c to winder 154.

In alternative embodiments of the process of making the topsheet 12, the nonwoven material 24 and the film 26 can be secured in other manners. Typically, in these other processes the nonwoven material 24' is not applied to the film until after the film is cooled. In one alternative process, adhesives can be used to bond the nonwoven material 24 and the film 26 at their faces.

In an adhesive bonding process, adhesive can be applied by any suitable commercial adhesive supply device. The adhesives can be applied using any suitable process. For example, the components may be separately manufactured and pre-coated with a pressure-sensitive adhesive, and thereafter secured in a subsequent process. In another example, adhesive could be applied to the nonwoven fabric 24 and the film 26 in a process similar to that shown in Figure 9, and these two components could be pressed together and bonded when they pass through the nip between nip rollers 134 and 136. Such adhesive bonding processes could, alternatively, be conducted without the application of pressure.

In other embodiments, one of the rollers 134 or 136 could be provided with a pattern and the other could serve as an anvil roller, and the two components could be bonded together in the presence of heat and/or pressure. In still other embodiments, the rollers 134 or 136 could be replaced by a commercially available ultrasonic welding device.

SUBSTITUTE SHEET WO 93/09741 PCTF/US92/09227 19 It is believed that the absorbent article 10 exhibits good strikethrough times and rewet values. Strikethrough time is a measure of the time liquid takes to penetrate through the topsheet 12. Rapid penetration of the topsheet 12 low strikethrough time) is important to reduce the possibility of liquid running over the surface of topsheet 12. Strikethrough may be determined using any suitable procedure. The shorter the strikethrough time, the better the strikethrough characteristics of the topsheet 12.

The rewet value is a measure of the amount of liquid which flows from the absorbent core 16 to the outer surface of the topsheet 12. Large quantities of liquid on the outer surface of the topsheet 12 high rewet values) are undesirable because they lead to the discomfort of the wearer of the disposable absorbent article. The rewet value of an absorbent article may be determined using any suitable procedure. Suitable procedures for measuring strikethrough and rewet are described in U.S. Patent 4,324,247 issued to Aziz. In an alternative version of the tests described in the Aziz patent, however, the rewet value is determined by subjecting the test sample to a pressure of about 1 psi.

The nonwoven fabric and surfactant-treated apertured film topsheet provides an article that has aesthetic qualities superior to that of the plastic film alone and functional properties superior to that of the nonwoven fabric alone. The nonwoven fabric provides a skin contact layer that is 'oft and aesthetically pleasing. When the film layer is three-dimensional and apertured, the film layer provides transport of fluids through the film and to an absorbent core while providing a barrier to fluid escape from the core that is difficult with a nonwoven fabric alone.

It will be understood by those skilled in the art that the invention has been described with reference to an exemplary preferred embodiment and that variations and modifications can be effected '4e described embodiment without departing from the scope anc of the invention.

SUBSTITUTE SHEET

Claims (12)

1. A liquid pervious topsheet for an absorbent article which has a longitudinal centerline defining a longitudinal direction, a transverse centerline defining a transverse direction, a body-facing side, and longitudinal edges, said topsheet comprising a nonwoven material comprising a plurality of fibers and an apertured, thermoplastic film placed together in a face-to-face relationship so that said nonwoven material forms the body-facing side of the absorbent article, and said film underlies said nonwoven material such that at least a portion of the fibers of said nonwoven material are embedded in some portion of said film, wherein said film is comprised of a liquid impervious thermoplastic resinous material which is treated with a surfactant to enhance the overall permeability of said topsheet, and said film has a thickness of from 0.001 to 0.002 inches and is provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries eacn having a base opening adjacent said nonwoven material and an oppositely disposed apex opening, an angle of taper of from 10° to 60°, a base opening dimension of from 0.006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch.

2. The topsheet of claim 1 wherein said surfactant was mixed with said thermoplastic resinous material and incorporated into said film.

3. The topsheet of claim 1 or claim 2 wherein said nonwoven material is also treated with a surfactant.

4. An absorbent article having a body-facing side, said absorbent article comprising: a liquid pervious topsheet, said topsheet comprising a nonwoven material comprising a plurality of fibers that forms the body-facing side of said absorbent article, and an apertured thermoplastic film that underlies said nonwoven material, such that, at least a portion of the fibers of said nonwoven material are embedded in some portion of said film, wherein said film is comprised of a liquid impervious thermoplastic resinous material which is treated with a surfactant to enhance the overall permeability of said topsheet, and said film has a thickness of from 0.001 to 0.002 inches and provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries each having a base opening adjacent said nonwoven material and an oppositely disposed apex opening, ar angle of taper of from 100 to 600, a base opening dimension of from 0.006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch; a liquid impervious backsheet joined to said topsheet; and an absorbent core positioned between said topsheet and said backsheet.

5. The absorbent article claim 4 wherein said surfactant has been incorporated into said film.

6. A method of making a liquid pervious topsheet for an absorbent article comprising the steps of: S providing a nonwoven web comprising a plurality of fibers; providing an apertured plastic film, said film defining a plane, wherein said film has a thickness of from 0.001 to 0.002 inches and is provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries each having a base opening in the plane of said film and an oppositely disposed apex opening, an angle of taper of from 100 to 600, a base opening dimension of from 0.006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch; treating said film with a surfactant; heating said film to its softening point; 'T R. s LU ^w 7 ~C) placing the nonwoven web and apertured film in a face-to-face relationship with the nonwoven web adjacent the base of the capillaries of the apertured film; and securing said nonwoven web and said film together such that at least a portion of the fibers of said nonwoven web are embedded in some portion of said film and said angle of taper, said base opening dimension, and said apex opening dimension are substantially maintained.

7. a method of making a liquid pervious topsheet for an absorbent article comprising the steps of: providing a nonwoven web comprising a plurality of fibers having a basis weight from 1 to 40 g/sq. m; providing a thermoplastic resinous material; heating said thermoplastic material to a temperature above its melting point; mixing a surfactant into said molten thermoplastic material; forming the mixture of molten thermoplastic material and surfactant :into an apertured film, said film d&fining a plane, wherein said film has a thickness of from 0.001 to 0.002 inches and is provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries each having a base opening in the plane of said film and an oppositely disposed apex opening, an angle of taper of from 10° to 600, a base opening dimension of from 0.006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch; allowing said film to cool; and securing said nonwoven web and said film together with said nonwoven web adjacent the base of the capillaries of the apertured film such that at least a portion of the fibers of said nonwoven web are embedded in some portion of said film and said angle of taper, said base opening dimension, and said apex opening dimension are substantially maintained. RAY

8. A method making a liquid pervious topsheet for an absorbent article comprising the steps of: providing a nonwoven web comprising a plurality of fibers having a basis weight from 1 to 40 g/sq. m; providing a thermoplastic resinous material; heating said thermoplastic material to a temperature above its melting point; mixing a surfactant into said molten thermoplastic material; forming the mixture of molten thermoplastic material and surfactant into an apertured film, said film defining a plane, wherein said film has a thickness of from 0.001 to 0.002 inches and is provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries each having a base opening in the plane of said film and an oppositely disposed apex opening, an angle of taper of from 100 to a base opening dimension of from 0.006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch; placing the nonwoven web and apertured film in a face-to-face relationship while said film is at least partially molten; and securing said nonwoven web and said film together with said nonwoven web adjacent the base of the capillaries of the apertured film such that at least a portion of the fibers of said nonwoven web are embedded in some portion of said film and said angle of taper, said base opening dimension,and said apex opening dimension are substantially maintained.

9. A liquid pervious topsheet for an absorbent article which has a body- facing side, said topsheet comprising a nonwoven material comprising a plurality of fibers and a three-dimensional apertured plastic film placed together so that said nonwoven material forms the body-facing side of the absorbent article and said film underlies said nonwoven material such that at least a portion of the fibers of said nonwoven web are embedded in some portion of said film, wherein: said fibers further comprise thermally bonded polypropylene fibers, said nonwoven material having a basis weight from 8 to 12 g/sq. m; and said film defines a plane and is comprised of a liquid impervious thermoplastic resinous material having a surfactant therein to enhance the overall permeability of said topsheet, and said film has a thickness of from 0.001 to 0.002 inches and is provided with tapered capillaries in the form of frustums of cones that define apertures, said tapered capillaries each having a base opening adjacent said nonwoven material and an oppositely disposed apex opening, an angle of taper of from 100 to 600, a base opening dimension of from 0.006 to 0.250 inch, and an apex opening dimension of from 0.004 to 0.060 inch.

The topsheet of claim 9 wherein said topsheet is incorporated into an absorbent article, said nonwoven material and said film each have a body-facing side and a garment-facing side, and said nonwoven material and said film are arranged so that the body-facing side of said nonwoven material and the body- facing side of said film lie in approximately the same plane, and the garment- facing side of said nonwoven material lies between the body-facing side of said film and the garment-facing side of said film.

11. The topsheet of claim 9 wherein when said topsheet is incorporated into an absorbent article, said nonwoven material and said film each have a body- facing side and a garment-facing side, and said nonwoven material and said film are arranged so that the body-facing side of said nonwoven material is disposed above the body-facing side of said film, and the garment-facinq side of said nonwoven material lies between the body-facing side of said film and the garment-facing side of said film, substantially interpenetrating said film.

12. The topsheet of claim 1 wherein said film is narrower in the transverse direction than said nonwoven fabric and underlies only that portion of the nonwoven fabric that is parallel to the longitudinal centerline and separate from the longitudinal edges of said absorbent article. DATED this 20th day of June, 1996 THE PROCTER GAMBLE COMPANY WATERI MARK PATENT TRADEMARK ATTORNEYS 290 BURWOOD ROAD HAWTHORN VICTORIA 3122 AUSTRALIA AU2917792.WPC[DOC. 007] LCG:EK 0 o *I