AU670318B2 - Method of manufacturing galvanised open or closed steel sections - Google Patents

Description

I 1 OPI DATE 26/04/94 APPLN. ID 48118/93| IIll II| 11 AOJP DATE 14/07/94 PCT NUMBER PCT/AU93/00488 llill llll i 111111llI AU9348118 INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (51) International Patent Classification 5 International Publication Number: WO 94/08064 C23C 2/02, B21B 45/06 Al B24C 3/10 (43) International Publication Date: 14 April 1994 (14.04.94) (21) International Application Number: PCT/AU93/00488 (74) Agent: SPRUSON FERGUSON; P.O. Box 3898, Sydney, NSW 2001 (AU).

(22) International Filing Date: 22 September 1993 (22.09.93) (81) Designated States: AT, AU, BB, BG, BR, BY, CA, CH, Priority data: CZ, DE, DK, ES, FI, GB, HU, JP, KP, KR, KZ, LK, PL4948 25 September 1992 (25.09.92) AU LU, LV, MG, MN MW, NL, NO, NZ, PL, PT, RO, RU, SD, SE, SK, UA, US, UZ, VN, European patent (AT, BE, CH, DE, DK, ES, FR, GB, GR, IE, IT, LU, (71) Applicant (for all designated States except US): TUBEMAK- MC, NL, PT, SE), OAPI patent (BF, BJ, CF, CG, CI, ERS OF AUSTRALIA LIMITED [AU/AU]; 1 York CM, GA, GN, ML, MR, NE, SN, TD, TG).

Street, Sydney, NSW 2000 (AU).

(72) Inventors; and Published Inventors/Applicants (for US only): HEIGHT, Trevor, Max- With international search report.

well [AU/AU]; 22 Mirral Crescent, New Lambton, NSW 2305 SUTTON, Ross, Herbert [AU/AU]; 8 lan Street, Eleebana. NSW 2282 SHESTER, Gary, Anthony [AU/AU]; 13 Coronation Street, Warners Bay, NSW 2282 (AU).

(54)Title: METHOD OF MANUFACTURING GALVANISED OPEN OR CLOSED STEEL SECTIONS ACCUMULAT

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SYNTHETIC

SHOTBLA STING LUBRICANT BOTH SIDES (57) Abstract A method of manufacturing galvanised open or closed steel sections eliminates the steps of pickling and rinsing. The manufacturing process is modified in such a manner that shot blasting of both sides of a strip of substantially flat steel occurs prior to a forming step in the process. After the forming process, the formed section is emersed in a flux solution.

PC=i2AU 9 3 0 0 4 8.8 RECEIVED 0 5 APR 19! METHOD OF MANUFACTURING GALVANISED OPEN OR CLOSED STEEL SECTIONS Field of the Invention The following invention relates to a method of manufacturing galvanised open or closed steel sections. More particularly, though not exclusively, the invention relates to the manufacture of galvanised pipes.

Prior Art Conventional hot dip galvanising processes rely on acid pickling to ensure a clean steel surface which facilitates the subsequent metalurgical bonding of zinc to the steel in the galvanising bath. The steps of pickling and rinsing involve high space requirements, high operating costs, the requirement of effluent streams and their associated, and increasing, burden in treatment activities.

Object of the Invention It is the object of the present invention to remove the need for pickling and subsequent rinsing in a hot dip galvanising process.

Disclosure of the Invention This invention in one broad form provides a method of manufacturing galvanised open or closed steel sections., the method comprising a roll forming process followed by a hot dip galvanising process, the roll forming process comprising the steps of: removing scale on both sides of a substantially flat steel strip by way of in-line ,hot blasting prior to forming the strip into an open section or hollow welded section, after the roll forming process, immersing the formed section in a flux solution, and the hot dip galvanising process not including a pickling or subsequent rinsing step.

By way of the above described process, the requirement of pickling the surfaces and the necessary subsequent step of rinsing the acid residues prior to fluxing is eliminated.

Preferably, the in-line shot blasting step occurs after accumulation.

Preferably, the abrasive action of the blasting is designed to achieve a Class 2 1/2 finish.

Preferably, a synthetic water based lubricant is used as a mill coolant in the process.

Preferably, the mill coolant is passed through a cleaning or filtration station to remove suspended solids from the mill coolant prior LF/00901 AMENDED SHEET

IPEA/AU

PCT/AU y u 4 L 8 RECEIVED 0 5 APR 1994 -2 to use in the forming process.

Preferably, in a welding step of the process, use is made of air cooled or reverse flow impeders.

Definitions As used herein the phrase "open section" means a formed steel structure having U-shaped channels, V-shaped channels, open boxed channels, typically roll formed from a flat sheet. For example, a corrugated sheet having smooth corrugations, square corrugations or V-shaped corrugations is intended to fall within the scope of the term "open section".

The term "hollow welded section" is intended to encompass any closed section such as for example a circular pipe, or pipe of other cross section or shape, square or rectangular duct or any other form of closed cavity wherein transversely opposed longitudinal edges are mutually welded together to inscribe a closed space.

Brief Description of the Drawings A preferred form of the present invention will now be described by way of example with reference to the accompanying drawings, wherein: Fig. 1 is a schematic flow chart of the process steps in pipe making, and Fig. 2 is a schematic flow chart of the subsequent steps in a hot dip galvanising process.

Description of a Preferred Form of the Invention Figs. 1 and 2 set out the two parts in the formation of hot dip galvanised pipe. In each of the two processes shown, those being pipe making and hot dip galvanising, the top line of boxes represent individual stages In conventional manufacture. However, one additional step to the conventional process is the addition of filtration to the mill coolant to and from the forming location.

In the pipe making process, the additional process steps are shown below the horizontal dotted line A.

In the hot dip galvanising process, the optional degrease and rinse steps in the conventional process are illustrated in a dotted box B.

Conventional fully hot dip galvanising of electric resistance welded (ERN) steel pipe involves a processing train with the steps of degreasing, rinsing, pickling, rinsing, fluxing, galvanising, quenching, coating and collection as depicted in Fig. 2.

The first two stages are required if the steel surfaces are contaminated with grease or oily films. Both can usually be waived if

F/

00 901 AMENDED

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p WO 94/08064 PCT/AU93/00488 3 -3synthetic mill lubricants are employed in place of oil based emulsions as coolants in the pipe making processes.

The pickling section is necessary in order to produce a clean steel surface, free of oxide contamination, in order to facilitate metalurgical bonding in the subsequent galvanising operation. This cleaning action has traditionally been carried out using either sulphuric acid solutions at temperatures of 60-80°C, or hydrochloric acid solutions at temperatures of 20-40°C.

The second rinsing step is necessary to reduce the carry over of acid and iron salts into the flux solution. Such contamination interferes with the effectiveness of the fluxing solution and leads to defects in the subsequent galvanised coatings as well as increased dro:s make.

The galvanising step involves complete emersion of the fluxed pipe in a bath of molten zinc for a defined period of time. This time is controlled to achieve a desired thickness of iron/zinc alloy and zinc on the steel surfaces.

The pipes are then withdrawn from the zinc bath, excess molten metal removed from both the external and internal surfaces, and then quenched in a controlled manner.

In the final two stages the pipes are coated with an organic compound to offer protection against white rusting and then collected in bundles for subsequent finishing and handling.

The space requirements and facilities necessary to carry out these operations are stbstantial. A significant proportion of which are determined by the pickling and rinsing sections. In addition the waste liquid streams arising from each of these two operations is considerable and requires additional plant and infrastructure support for effluent treatment.

The benefit derived from the invention is the elimination of the pickling and rinsing sections and the elimination of all effluent streams from all operations preceeding galvanising.

This benefit is achieved by. modifying the pipe manufacturing process in such a manner that pipe with metalurgically clean and protected surfaces (both external and internal), is produced.

Conventional electric resistance welding (ERW) pipe making included in the depiction of Fig. i involves coil splicing, accumulation, forming, welding, cooling/quenching, sizing/shaping, cut-off and runout/collection.

WO 94/08064 PCr/AU93/00488 4 The most common feed for ERW pipe manufacture is hot rolled steel strip in coil form which has been slit from the coil produced at a steel works on a hot strip mill. The steel thus contains a strongly adherent thin film of iron oxides.

The coil splicing stage welds the nose end of the fresh coil to the tail end of the coil which has been fed into the mill line. The purpose here is to maintain a continuous strand in the mill line from the entry point through to the cut-off.

In order to allow the mill to continue to produce pipe while the splicing of fresh coils is taking place, a buffer is maintained in the accumulator.

From the accumulator the strip is taken through a forming section where the material is progressively bent inwards until a circular profile is achieved. Significant forces are involved in this work, which generates an amount of heat, and some of the oxide scale is broken off or crushed. As a consequence it is necessary to provide a medium to cool the rolls and to remove the released scale. This has traditionally been achieved with oil based emulsions but in more recent times with synthetic lubricants.

The open seam circular shell passes through an induction coil where a high frequency power source induces an electric current along the seam. The heated edges are brought together in a set of squeeze rolls in the welding station from which a welded pipe emerges. At the welding station a series of ferrite rods are held in the bore area to focus the current along the edges of the steel. These rods, known as impeders, absorb some of the induced energy and therefor must be cooled.

Traditionally this cooling has been achieved using the mill coolant directed along the impeders, a situation which leads to a liquid filled bore.

The welded pipe then passes through an external bead scarfing station and then a cooling/quenching zone where through combination of air cooling and mill coolant impingement on the weld zone, the pipe surface temperatures are brought into equilibrium.

The pipe then passes through a second set of roll stands to be reduced to a final pipe size or to be formed into the desired non-circular shape.

The pipe then continues into a cut-off where individual pieces of a desired length are automatically cut from the emerging mill continuous WO 94/08064 P07AU 9 U3/00488 strand. The individual pieces pass across a runout table, where inspection is routinely carried out, and then into collectors. Here the product is collated into manageable parcels, usually lots of between 1 and 7 tonne, in readiness for further operations, one of which can be fully hot dipped galvanising.

The modifications to the process which are disclosed herein are as follows: Firstly, the scale on the steel surfaces (both sides) is removed by way of in-line shot blasting located after the accumulator and prior to entry into the mill forming section. The abrasive action of the blasting is designed to achieve a Class 2 1/2 finish on both sides of the strip.

Secondly, the full effectiveness of the blasting before forming and the subsequent fluxing after cut-off may be achieved when the pipe is formed with a dry bore. Therefore, in the forming section, a synthetic water base lubricant may be used as the mill coolant to prevent oil contamination of the surface. The coolant is directed at the rolls in order to minimise any entrapment in the bore region. Subsequent wiping of the bore area prior to welding ensures that no coolant from the forming region is retained in the bore.

Furcher coolant ingress is avoided by using either reverse flow impeders, or air cooled impeders at the weld station.

Thirdly, within a short period after the pipe has been built up into the manageable parcels after this runout, the product must be emersed into a flux solution.

It has been found that ideally this time should not exceed one hour, although in favourable atmospheric conditions, acceptable results have been achieved with delays as long as 24 hours. It has also been found that in this period of time the product which may have come from the mill in a bent condition, can be processed through a rotary straightener without adversely affecting the subsequent action of the fluxing solution.

The flux solution should ideally be the zinc ammonium chloride tripple salt ZnCl 2 .3NH 4 Cl dissolved in water to achieve a density of 1.20 at 60 0 C, although a wider range of density values can still provide acceptable results. Some ferrous smut remaining from shot blasting together with some debris from the welding process is removed during the emersion and drainage of the flux. In order to prevent a build up of potential contaminants of material which will subsequently generate a WO 94/08064 PC~r/AU93/00488 -6higher dross make in the galvanising, this flux solution should be subjected to continuous filtration.

Best results may be achieved with initial emersion times of minutes although shorter periods might still provide adequate performance. Care should be taken during emersion to ensure that no air becomes entrapped in the bundle, either in the bores of the pipes or within the interstices between adjacent pipes.

After emersion, the bundle is drained and then either fed directly to the galvanising bath or placed in a storage area awaiting galvanising. The storage area should be such that no water can impinge on the pipe surface and adequate ventilation is provided to prevent the steam or water vapour refluxing in the bores or the interstices. Such refluxing action might wash the surfaces free of the protective flux layer leading to rusting of the steel. Such condition would subsequently result in faulty galvanising.

It should be appreciated that modifications and alterations to the process described herein which are obvious to those skilled in the art are not to be considered as beyond the scope of the present invention.

For example, whilst the above description is by way of example directed to pipe making, the process is equally applicable to the production of any other galvanised open or closed steel sections.

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Claims (9)

1. A method of manufacturing galvanised open or closed steel sections, the method comprising a roll forming process followed by a hot dip galvanising process, the roll forming process comprising the steps of: removing scale on both zides of a substantially flat steel strip by way of in-line shot blasting prior to forming the strip into an open section or hollow welded section, after the roll forming process, immersing the formed section in a flux solution, and the hot dip galvanising process not including a pickling or subsequent rinsing step.

2. The method of claim 1 wherein the in-line shot blasting occurs after accumulation.

3. The method of claim 1 wherein the abrasive action of the blasting achieves a class 2 1/2 finish.

4. The method of claim 1 wherein a synthetic water based lubrican' iF used as a mill coolant.

5. The method of claim 4 wherein the mill coolant is passed through a cleaning or filtration station to remove suspended solids from the mill coolant prior to use in the forming process.

6. The method of claim 1 wherein the said forming comprises a welding step wherein use is made of air cooled or reverse flow impeders.

7. The method of claim 1 wherein a hollow welded section having an internal bore is produced in the roll forming process, and wherein a synthetic water based lubricant is used as a mill coolant, the bore being kept substantially dry by directing coolant in order to S minimise any entrapment in the bore.

8. The method of claim 7 further comprising wiping of the bore surface prior to welding.

9. A ga',anised open or closed steel section formed in part by the method of any one of the preceding claims. A method of manufacturing galvanised open or closed steel sections, the method being substantially as hereinbefore described with reference to the accompanying drawings. Dated 16 May, 1996 Tuberrimakers of Australia Limited Patent Attorneys for the Applicant/Norninated Person SPRUSON FERGUSON IN:\LIBLLI30330:KEH