AU658104B2 - Insect repellent tent fabric - Google Patents

Description

Our Ref: 455547 658U04

AUSTRALIA

P/00/011 Regulation 3:2 Patents Act 1990

ORIGINAL

COMPLETE SPECIFICATION STANDARD PATENT Applicant(s): Address for Service: Graniteville Co One Marshall Street GRANITEVILLE South Carolina 29829 UNITED STATES OF AMERICA DAVIES COLLISON CAVE Patent Trade Mark Attorneys Level 10, 10 Barrack Street SYDNEY NSW 2000 Insect repellent tent fabric Invention Title: The following statement is a full description of this invention, including the best method of performing it known to me:- 5020 Thsinvention relates to coated fabrics that are flam~e resistant and water repellent and are treated by the present invention to be insect repellent.

It is known to coat f abric with protective coating systems containing water repellent chemicals and f lame retardant chemicals to make the fabric suitable for use as military tenting in all climates of the world. See, for example, United states Patent Nos. 4,594,286 and 4,833,006.

it is, of course, desirable in most climates that the tent f abric also be insect repellent. Insect repellents are known but their effective life of only a few days renders them unsuitable for use in a protective coating system for tent fabrics.

There is, theref ore, a aniversal need for tent, tarpaulin, and shelter fabrics (collectively referred to herein as tent fabrics) which have a long term capability of repelling annoying and disease carrying insects.

Many insect repellents are effective when they are applied to the skin as a spray or lotion, but only f or a f ew hours. The protection time is extended to as much as a week or ten days when repellents are applied to clothing, gloves and body nets for outdoor use. insect repellents with such a short effective life are impractical for use in a coating for tent fabric.

The tent fabrics with which this invention is concerned are treated to be durably water repellent and f lame retardant, and to have an appearance that is pleasing to the eye. in order that these properties be retained, it is .0 necessary that the fabric be treated with insect repellents that are effective for their intended purpose without adversely affecting any other desired property of the fabric.

Several commonly known insecticides have been tried with the coating used for tent fabric. For example, a production trial has been made of water repellent and flame retardant tent fabric utilizing dimethyl pthtalate (DMP) as an insecticide. It did not compromise the flame retardant or water repellent properties of the tent fabric but its length of effectiveness was less than desired.

Benzil benzoate, while readily dispersed in typical fire retardant coatings, demonstrated an unsightly.

appearance upon application and drying. Dibutyl phthalate and dibutyl adipate showed this to a much lesser extent.

Permethrin is a synthetic pyrethroid which exhibits repellent as well as knock down and kill activity against insects. Pyrethroids, including both the naturally occurring compounds and their synthetically prepared analogs effectively control a variety of pests, such as houseflies, mosquitoes, cockroaches, etc.

They are not harmful to plants, food, animals and humans, and leave no harmful residues. Permethrin is environmentally safe and has been found to be compatible with coating compositions containing water repellent chemicals and flame retardant chemicals, used for tent fabric, without adversely affecting the desired properties of the coated fabric.

25 Despite these highly favorable characteristics, permethrin has had only limited general utility because of its relatively short-lived insecticidal activity. This is due to its decomposition into a non-active, non-insecticidal product in the presence of oxygen and ultraviolet light.

the speed of this decomposition is dependant upon the environment in which the permethrin is placed, but typically takes place in from several hours to several days or weeks.

This instability of permethrin severely limits its usefulness as an insecticide.

Prior attempts to stabilize pyrethroids against degradation have included encapsulation and the addition of antioxidants and photostable ultraviolet light absorbent compounds to solutions of pyrethroids. Encapsulation has not been effective because the pyrethroids degrade almost as quickly inside the capsules as they do unencapsulated. Only moderate success in reducing degradation has been obtained by the addition of antioxidants and photostable ultraviolet light absorbent compounds to solutions of pyrethroids.

Their moderate success is largely off-set by unsightly residues which are hard to remove.

Various techniques have been suggested for providing sustained release of a pyrethroid as an insect control agent. For example, Patent No. US 4,056,610 to Barber discloses a microcapsule insecticide composition in which a pyrethroid permeates a porous shell wall and maintains an effective level of the pyrethroid upon the outer surface of the shell wall to control insects for up to four days (then considered an extended length of time within the art).

Control is achieved by killing insects which contact the pyrethroid released through the capsule wall.

Patent No. US 4,765,982 to Ronning discloses an insect control device comprising a plurality of rough surfaced cellulosic fibers wherein there is self-adhered to the S" 25 surface of the fibers a liquid insecticide composition microencapsulated in a capsule whose shell is permeable to the liquid insecticide. The micro-encapsulated insect control agents disclosed in Patent No. US 4,056,610 to Barber are named as the preferred insecticide for use in Ronning's invention.

Ronning's insecticide-treated-rough-surfaced cellulosic fibers are formed into webs, tapes, sheets, pads, and various others relatively flat shapes suitable for use in particular locations, such as a ribbon-like tape for placement along the base of a building or door.

-4- Ronning teaches that smooth-surfaced fibers do not act as good sites for adhesion of microencapsulated insect control agents. Ronning's rough surfaced celluosic fibers treated with an insecticide are not suitable for tent fabric. The texture of the rough surfaced fibers is not satisfactory and they are neither water repellent or flame retardant.

SuHVR\-/ oF THIe ItVV;iflnO,) It is the primary object of this invcntion to provide a tent fabric with insect repellent properties that are effective for six months, or longer, without compromising the water repellence, flame retardance, or other desirable properties of the tent fabric, thereby offering maximum convenience and safety to the user.

The foregoing and further features of the invention may be more readily 10 understood from the following description with reference to the accompanying, in which:- SQFzf= S &cC\PT IK <s TC IRpDF ir"sM Figure 1 is a perspective view of a tent; Figure 2 is a sectional view taken substantially along the line 2-2 in Figure 1; 0 S S p:\wpdocsU1190.93.spc\DB:24 MARCH 1994 Figure 3 is a chart illustrating the percentage of mosquito bites each month during a year long test of two tents treated with different insecticides and an untreated control tent; Figure 4 is a chart illustrating the percentage of mosquitoes killed each month during the same year long test of two tents treated with different insecticides and an untreated control tent; and Figure 5 is a graphic illustration of the effects of ageing and weathering on tent fabrics treated with different insecticides and on an untreated control tent, as indicated by 2rotection from mosquito bites.

>£rjALtD -tjs 3 a eSc- %Pno oF TH-e Ivu VeLr-oro The substrate of the insect repellent tent fabric of this invention may be any suitable fabric. For example, it may be a plain weave polyester fabric or a 50/50 blend of polyester and cotton, woven as an oxford fabric. The invention has been practiced satisfactorily with a substrate made from continuous multifilament yarns with normal producer's twist of one of two turns per inch and woven into a plain weave fabric containing 84 yarns per inch in the warp and 32 yarns per inch in the weft.

The fabric is coated with a composition which renders it water repellent, flame retardant, and insect repellent.

The following composition is exemplary of coatings that can 25 be used to practice the invention: Example 1 Insect Repellent Coating for Tent Fabric COMPONENT PERCENTAGE FUCTION S Emkay B.C. 0.45 Defoamer Polyvinyl Chloride Polymer (Geon 576) 18.37 Binder Dioctyl Phthalate 5.99 Plasticizer Sodium Salt of Phosphated Ester 0.25 Surfactant Antimony Tzioxide 13.83 Flame Retardant y- Kaolin (Hydrated Aluminum Silicate) Methylated Melamine Formaldehyde Resin Methylcellulose Bromochlorinated Hydrocarbon Zirconium Wax Complex Pigment Systems Acrylic Copolymer 19.20 1.72 0.27 27.66 1.51 1.79 Flame Retardant Cross-linker Thickener Flame Retardant Water Repellent Color *e

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(Acrysol ASE-60) 0.98 Thickener Metasol TK-100 Powder 0.15 Mildew Inhibitoz Permethrin 07.83 Pesticide 100.oo% Permethrin is an immobile material but can be made mobile with a plasticizer. In addition to serving as a water repellent in the normal coating for tent fabric, the zirconium wax complex also serves as a plasticizer and as a protector against oxygen for the permethrin. The wax creates a shell around the permethrin that protects the permethrin from degradation by oxygen after the permethrin reaches the surface of the coating. The wax also mobilizes Pt the permethrin to the etent of keeping enough permethrin on the inner surface of the coating to be an effective insect repellent for a much longer period of time than has heretofore been possible.

As protection against environmental degradation such as ultra violet rays, the permethrin is not combined with the 30 coating to be on the outside of the tent but is only combined with the coating applied to the side of the fabric which will be inside the tent. The wax and plasticizer, which provides mobility to the permethrin, is combined with the permethrin in the coating for the inside of the tent.

35 Zirconium wax complex is also included as a water repellent in the coating for the outside of the tent.

14, V- Q Thus, as illustrated in Figures 1 and 2, insect repellent coating 13 for a water repellent and flame retardant tent 10 is applied only to the side of substrate 11 that will be inside the tent and a conventional water repellent and flame retardant coating 12 is applied to the side of the substrate 11 that will be outside the tent.

It is preferred that the coating on the outside of the tent be the coating described and claimed in United States Patent No. 4,833,006 issued May 23, 1989 to Graniteville Company of Graniteville, South Carolina. The disclosure of that patent is incorporated herein by reference.

The effectivness of permethrin as an insect repellent in the coating for tent fabric has been field tested for a year by the Agricultural Research Service of the United States Department of Agriculture. They were evaluated using Aedes aevpti mosquitoes to determine which treatment would most effectively prevent bites and cause the most knockdown (KD) of the insects entering the tents.

Specifically, tests were conducted to determine the persistence of compounds applied to tents to keep out or 0kill mosquitoes. Three tents were used in the test. Each tent (family tent type) was constructed from 24.4 square meters of 100% textured polyester fabric having a weather resistant vinyl coating and a nylon screen-zippered door 25 opening. One tent was treated with the permethrincontaining coating of Example 1, herein (inside only, including the floor); the second tep was treated with .6 dimethyl phthalate (DMP) inside4the tent; and the third tent Swas untreated, to be used as a control.

The three tents were erected October 30, 1989, at the USDA Medical Veterinary Entomology Research Laboratory, Gainesville, Florida, in an open grassy field, two meters apart in a north-south row, each with its doorway facing S east. They remained for one year, unshaded and fully exposed to the effects of weathering.

Efficacy assessments were made with weekly bioassays.

Through the screen door zipper opening of each tent were released from 75 to 80' "seven-day-old laboratory reared susceptible strain female Aedes aegvyti mosquitoes, Upon release, the screen door was zipped closed, and the tent flaps and rear screen-covered window were left open for ventilation (tent flaps were kept closed at all other times). Mosquitoes were free to land or fly about inside the tent for three hours. Each hour after release, mosquito KD, mosquitoes dead or moving but unable to fly, and bite counts were recorded. Bites were observed and recorded after a one minute exposure of a volunteer's arm in the tent through a small dpening unzipped in the screen door.

Hourly data indicated the rapidity of treatment effect on the mosquitoes during a three hour exposure, i.e., whether treatment effect was rapid (during the first hour) or additive (after two to three hours). The data also helped show when treatments began to lose potency because of •exposure to weathering.

S: 20 After three hours, mosquitoes were removed from each tent with a battery powered aspirator and counted. Care was taken to avoid contamination between treatments by entering the untreated, DMP-treated, and permethrin-treated tents in that order. Test data were recorded in terms of percent effect, number KD/biting divided by the total number S"of mosquitoes in the tent equals the percent KD/biting.

An attempt was made to keep the tests on a same-day schedule each week. Inclement weather at times made this difficult. However, forty eight of fifty two weeks of tests were completed. During cooler months, tests were scheduled in the warmer afternoons, whereas during very warm months, tests were done in the cooler early morning hours.

The three-hour means of KD and bite data for weekly tests were computed but not analyzed, because only one replicate '4 I i- '*1 Vz test of each treatment was made each week. Means of these weekly data were computed to provide a monthly view of treatment effect. Weekly bite data were calculated to percent protection by the following formula: the percentage of protection equals the percentage of mosquitoes biting in the control tent minus the percentage of mosquitoes biting in a treated tent divided by the percentage of mosquitoes biting in the control tent.

RESULTS

Presented in the following Table 1 are means of the monthly data shown as percent KD/biting during weekly exposures of Ae.aegypti to treated tents. Mean KD in the DMP-treated tent for the year was greater than in the untreated control However, the mean KD effect of DMP was never as high as that of permethrin Mean monthly KD in the control tent was rather consistent (0.87% plus or minus 0.78%) for the year. This was also true for 'the DMP tent, except for the first 12 weeks when KD averaged 8.5% plus or minus 10.4%.

S: 20 Mean biting in the permethrin-treated tent for the year was 11.9%, in the DMP-treated tent 43.8% and in the control tent 58.6%. With permethrin, biting averaged less than 1% for the first six months, 8.5% for the next three months and 33.8% for the last three months. Biting in the DMP-treated tent rose from 21.3 to more than 40% after the llth week and Scontinued at this or a somewhat higher level, for the duration of the study.

A comparison of the permethrin, DMP, and untreated control data are presented in Figures 3 and 4. Biting was reduced in the DMP-treated tent, and there was a KD effect with an overall average of 19.8% fewer bites and 2.7% more KD than in the control tent during the first 30 weeks.

TABLE 1 Monthly means percentages of Aedes aecrypvti mosquitoes biting or knocked down after weekly three hour exposures to three different tent fabrics, one treated* on its inner surface only with permethrin, one treated on the inner and outer surfaces with dimethyl phthalate (DMP), and the third tent fabric not treated with any insecticide.

Percent Knockdow Percent Biting Month Number Permethrin DMP Untr<

S

o

S.

C S 0

S

1 81.9 2.5 3 99.0 14.4 4 96.8 2.1 5 94.4 1.1 6 71.3 1.4 7 48.6 1.7 8 56.9 1.5 9 58.9 1.1 20 10 24.3 1.4 11 7.2 1.5 12 5.0 0.7 Year avg. 58.6 2.7 25 Treatment was 0.075 permethrin active ingredient.

aated 0.8 0.3 2.6 0.5 0.5 0.6 0.9 0.2 0.9 2.1 0.2 Permethrin DMP Untreated 0.4 24.2 47.6 0.0 26.1 52.3 0.5 43.6 67.4 1.5 46.9 66.2 2.1 50.5 61.5 13.4 57.3 75.9 4.9 49.6 56.6 7.1 42.8 58.8 27.2 48.4 51.7 34.9 46.9 54.3 39.3 45.4 45.5 0.9 ounces 11.9 43.8 per square yard 57.9 of 30 Data for weeks 1, 2, 3 and 8 are absent because no tests were run. Thus, data for weeks 4, 5, 6 and 7 were combined and analyzed for this two month period.

0S VI. The foregoing data is graphically illustrated in Figures 3, 4, and The average monthly percentage of biting and KD in the permethrin-treated tent was clearly superior to that in the DMP-treated tent and the tent treated without any insecticide. In the permethrin-treated tent from November to July, percent biting was well below 10% with the exception of May, which was 31.4%. This would provide the user with more than 96% protection from mosquito bites for

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i nine months. Average knock Down was only about 88% for six months (November through April), indicating that although the permethrin treatment provided less than 100% KD, mosquitoes were affected enough by the toxicant for it to strongly inhibit biting for nine months.

The long effective life (nine months) is attributed to the protection provided by the wax and plasticizer covering the permethrin, and to the fabric layer of the tent acting as a barrier that inhibits migration of the pyrethrin to the cuter surface of the fabric and consequently inhibits exposure of the permethrin to degrading environmental elements.

DISCUSSION

From November to July, means numbers of mosquitoes biting in the permethrin-treated tent were less than 4% of those released. High levels (more than 96%) of overall protection from bites of Ae. aegypti (Figure 1 existed for up to nine months.

Protection may be longer with intermittent rather than constant exposure of the treatment to weathering. Average KD was about 88% for six months (November through April).

Thus, even when the permethrin treatment produced less KD as the treatment aged weathered, there was sufficient residual toxicity to effectively reduce biting for up to nine months.

Variables such as temperature, humidity, solar radiation, precipitation and wind may account for some weekly differences in test data. For example, with permethrin there was a 14% drop in protection from bites the seventh month (figure a time when solar radiation was the 30 highest recorded. Unexpectedly, the DMP treatment caused some KD, indicating it had insecti 4 cidal activity. However, it is obvious that permethrin was superior to DMP in KD, protection from bites, and duration of persistence.

There is thus provided a tent fabric which is coated to be permanently water repellent and f lame retardant, ano, 'Insect -repel 'ent for' a's Ddhg7 efi ffine ibnths.

Although specific terms have been employed in S ecrbn the invention, they have been used in a descriptive and generic sense only and not for the purpose' of limitation. It is intended that the scope of the patent be determined from the following claims to invention, considered with the specification and drawings and with tEhe prior art.

Claims (4)

1. A coated tent fabric having a fabric substrate with a coated outer surface normally exposed to degrading elements of the atmosphere and a coated inner surface normally shielded by the fabric substrate from the degrading elements of the atmosphere, the coatings on the outer and inner surfaces of said fabric substrate each containing a polymeric binder, flame retardant chemicals and water repellent chemicals, wherein the improvement comprises the addition of permethrin as an insect repellent to the coating on the inner surface of the fabric substrate, whereby the fabric substrate acts as a barrier that inhibits migration of the permethrin to the outer surface of the fabric and 10 consequently inhibits exposure of the permethrin to the degrading elements of the gooe: atmosphere, thereby increasing the length of time the permethrin is an effective insect repellent.

S2. The invention of claim 1 wherein the coating on the inner surface of the fabric substrate also contains means for mobilizing the permethrin to the extent of keeping enough permethrin on the inner surface of the fabric substrate to be an effective insect repellent for at least nine months.

3. The invention of claim 2 wherein the permethrin is applied to only the coating on the inner surface of the fabric substrate.

4. The invention of claim 2 wherein the means for mobilizing the permethrin is a plasticizer. The invention of claim 4 wherein the plasticizer is zirconium wax. DATED this 29th day of March, 1994 GRANITEVILLE CO By Its Patent Attorneys DAVIES COLLISON CAVE p:\wpdocs\31190.93.spDB:24 MARCH 1994 1. A coated tent fabric 'having a fabric substrate with a coated outer warface normally exposed to degrading elements of the atmosphere and a coated inner surface normally shielded by the fabric substrate from the degrading elements of the atmosphere. The coatings on the outer and inner surfaces of said fabric substrate each contain a polymeric bineter, flame retardant chemicals and water repellent chemicals Permothrin is added as an insect repellent to the coating on the inner surface of the fabric substrate, whereby the fabric substrate acts as a barrier that inhibits migration of the permethrin to the outer surface of the fabric and consequently inhibits exposure of the permethrin to the degrading elements of the atmosphere, thereby increasing the length of time the permethrin is an effective insect repellent.