AU6519194A - Apparatus and method for burning combustible gases - Google Patents
Apparatus and method for burning combustible gasesInfo
- Publication number
- AU6519194A AU6519194A AU65191/94A AU6519194A AU6519194A AU 6519194 A AU6519194 A AU 6519194A AU 65191/94 A AU65191/94 A AU 65191/94A AU 6519194 A AU6519194 A AU 6519194A AU 6519194 A AU6519194 A AU 6519194A
- Authority
- AU
- Australia
- Prior art keywords
- gas
- air
- stack
- mixture
- pipe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G7/00—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
- F23G7/06—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
- F23G7/08—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases using flares, e.g. in stacks
- F23G7/085—Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases using flares, e.g. in stacks in stacks
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C2202/00—Fluegas recirculation
- F23C2202/40—Inducing local whirls around flame
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2207/00—Ignition devices associated with burner
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23D—BURNERS
- F23D2209/00—Safety arrangements
- F23D2209/20—Flame lift-off / stability
Landscapes
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Incineration Of Waste (AREA)
- Feeding And Controlling Fuel (AREA)
- Pre-Mixing And Non-Premixing Gas Burner (AREA)
Description
Apparatus and Method for Burning Combustible Gases HELD OF THE INVENTION:
The present invention relates to an apparatus for burning combustible gas and a method for using the apparatus.
BACKGROUND:
Gases containing common air pollutants, such as hydrocarbons, alcohols, ethers, soot and other combustibles, are frequently encountered in industries wherein combustion furnaces are utilized. In order to reduce the emission of pollutants and waste smoke into the atmosphere, a variety of devices have been proposed for burning the combustible gases.
A commonly utilized device is referred to as a flare stack wherein combustible gas is burned and discharged into the open air. Several exemplary prior art techniques are disclosed in the following patents.
U.S. Patent No. 3,828,700 to Ragot discloses an apparatus and process for the smokeless burning of residues. The apparatus consists of a chimney designed for the introduction of air into the burning zone, and a mechanism for introducing the residue into the chimney in the form of a spray. Thus the disclosed apparatus and process require that the residues to be burned off be pulverized or otherwise converted to a spray before introduction into the chimney.
U.S. Patent No. 3,852,023 to Itoh et al. discloses an apparatus for disposing of gas by burning. The apparatus consists of a plurality of branch pipes connected to a main pipe carrying combustible gas. The gas is channeled into one or more of the branch pipes according to the -flow rate in the main pipe. The branch pipes are connected to a combustion furnace having a plurality of stages arranged in vertical order, gas introduced into the combustion furnace through the branch pipes is ignited and burned by ignition means located in the lowermost stage of the furnace.
U.S. Patent No. 3,898 17 to Hemsath et al. discloses an incineration system for incinerating flue gases which contain a combustible component. The system uses two
chambers that are added to a stack emitting industrial gases. The first chamber terminates at the exit end of the stack in an annular passage so that high velocity air, which acts as an air pump, is directed longitudinally relative to the stack. The second chamber is disposed downstream of the first chamber and includes a plurality of burners and a thermocouple that senses the temperature of the gases. A preset temperature is achieved in the chambers by varying the quantities of air emitted from the first chamber as well as the amount of fuel and air supplied to the burners in the second chamber.
U.S. Patent No. 3,954,386 discloses a flare burner for burning combustible gases. The flare burner consists of a venturi burner tube having specified dimensions, a gas supply pipe having a gas outlet opening at the throat of the venturi burner tube and pilot burner jets for burning combustion gases.
U.S. Patent No. 4,003,693 discloses a flare stack gas burner consisting of a stack with a centrally disposed combustible gas delivery pipe having a divider with arms for upward delivery of the combustible gas through a plurality of slots to a mixing space. The flare stack also includes a rotary diffuser for mixing the combustible gas with air which is introduced under pressure into the stack.
It is an object of the present invention to provide a method and apparatus for burning the combustible components of gases with the advantages which will become apparent from the following discussion.
SUMMARY OF THE INVENTION:
The present invention relates to a method and apparatus for burning the combustible components of gases produced in industrial processes. The method and apparatus are particularly well suited for use in burning the combustible components of the gas stream exiting from a carbon black furnace during the production of carbon blacks.
The apparatus of the present invention comprises: a stack pipe having one end in communication with a gas supply pipe for receiving a gas stream;
means for introducing air into the stack pipe to produce an air and gas mixture; a mixing zone; means for igniting the air and gas mixture; means for stabilizing the ignited mixture; and means located at the other end of the stack pipe for inhibiting downwash of the exiting gaseous products resulting from combustion of the gas and air mixture.
The method of the present invention comprises: introducing a gas stream containing combustible components into one end of a stack pipe; introducing air into the stack pipe to produce an air and gas mixture; mixing the air and gas mixture in a mixing zone; igniting the air and gas mixture; stabilizing the ignited air and gas mixture; and allowing the gaseous products resulting from combustion of the gas and air mixture to exit the stack pipe and inhibiting downwash of the gaseous products. The method of the present invention is preferably performed using the apparatus of the present invention.
The gas supply pipe refers to the pipe or conduit emitting gases produced in an industrial process. The gas stream flows from the supply pipe into one end of the stack pipe. In the case of a carbon black furnace reactor, the gas supply pipe emits the gas stream resulting from the production of carbon black. The communication between the gas supply pipe and the end of the stack pipe in the apparatus of the present invention should be sufficient to minimize the possibility of gas escaping into the atmosphere at, or near, the position where the supply pipe and the stack pipe are in communication. As explained below, in a preferred embodiment of the apparatus of the present invention, the gas supply pipe and the stack pipe overlap.
The means for introducing air may be any means known to the art. The amount of air introduced should be sufficient to produce an ignitible mixture of air and gas. Such
determination is within the skill of those of ordinary skill in the art. In a preferred embodiment of the apparatus of the present invention, the means for introducing air comprises an annular space formed between the gas supply pipe and the end of the stack pipe, through the use of different diameter pipes.
The introduced air and the gas mix in the mixing zone. The ignitible gas and air mixture is then ignited. The means for igniting the gas and air mixture may comprise any means known to the art for igniting combustible gases, including, but not limited to, pilot burners, spark generators and the like. The means for igniting may be located at any position in the apparatus of the present invention where sufficient mixing of the gas and air mixture has occurred to produce an ignitible mixture. Preferably, the means for igniting is located at a position where the flame, or other igniting means, penetrates the recirculation zone created by the means for stabilizing the ignited gas and air mixture.
In the apparatus and method of the present invention, the ignited gas and air mixture is stabilized to promote substantially complete burning of the combustible components of the gas stream. The means for stabilizing the ignited gas and air mixture comprise means for creating a recirculation zone wherein the ignited gas and air mixture recirculates. As described below in the more detailed description of the invention, the means for stabilizing may comprise a step between a first stack pipe that communicates with the gas supply pipe and a second stack pipe that emits the burned gas and air mixture into the atmosphere. The means for stabilizing may alternatively comprise an object, preferably a cone or hemisphere, located in the interior of the stack pipe that creates recirculation.
After combustion of the combustible components of the gas stream has been achieved, the resultant gaseous products are emitted from the stack pipe into the atmosphere. The emitting end of the stack pipe includes downwash inhibiting means to ensure that the gaseous products resulting from combustion of the gas and air mixture are emitted upwardly into the atmosphere.
The method and apparatus of the present invention advantageously burns the combustible components of a gas stream to minimize the emission of pollutants and smoke into
the atmosphere.
Further details and advantages of the apparatus and method of the present invention are set forth in the following more detailed description of the invention.
BRIEF DESCRIPTION OF THE DRAWINGS:
Figure 1 depicts an embodiment of the apparatus of the present invention. Figure 2 depicts an alternate embodiment of the apparatus of the present invention.
DETAILED DESCRIPTION OF THE INVENTION:
As set forth above, the apparatus of the present invention comprises: a stack pipe having one end in communication with a gas supply pipe for receiving a gas stream; means for introducing air into the stack pipe to produce an air and gas mixture; a mixing zone; means for igniting the air and gas mixture; means for stabilizing the ignited mixture; and means located at the other end of the stack pipe for inhibiting downwash of the gaseous products resulting from combustion of the gas and air mixture.
The apparatus of the present invention is particularly advantageous for use on the end of smoke stacks emitting combustible gases from industrial processes.
An embodiment of the apparatus of the present invention is depicted in Figure 1. As will be readily understood by those of ordinary skill in the art, the apparatus shown in Figure 1 is designed to be constructed over the end of a smoke stack emitting combustible gases.
With reference to Figure 1, the apparatus of the present invention, 1, includes a stack pipe, 4, in communication with a gas supply pipe, 2. The inner diameter of the gas supply pipe, 2, is shown as Dl and the inner diameter of the stack pipe, 4, is shown as D2. The arrangement of supply pipe, 2 and stack pipe, 4 should be such that the possibility of gas escaping into the atmosphere is minimized. In a preferred embodiment of the apparatus of the present invention,
the pipes overlap as shown in Figure 1. In Figure 1, Dl is smaller than D2, and gas supply pipe 2, extends into stack pipe 4, thereby creating means, 5, for introducing air into the stack pipe, 4. The distance that the pipes overlap is shown as HI.
In the embodiment of the apparatus of the present invention shown in Figure 1, the means for introducing air into the stack pipe, 5, comprises the annular space between the gas supply pipe, 2 and the stack pipe, 4. Air is drawn through the annular space into the stack pipe 4. As set forth above, the amount of air drawn into stack pipe, 4 should be sufficient to produce an ignitible gas and air mixture. Such determination is within the skill of those of ordinary skill in the art. As also set forth above, the means for introducing air into stack pipe, 4, may alternately comprise other means known in the art such as an air supply pipe in communication with stack pipe, 4.
The air mixes with the gases emitted from gas supply pipe, 2, in mixing zone, 6, to form an air and gas mixture. The length of the mixing zone should be sufficient to allow sufficient mixing time for the introduced air and gas to produce an ignitible air gas mixture. In Figure 1, the length of the mixing zone is shown as H2.
Stack pipe, 4, containing mixing zone, 6, communicates with one end of stack pipe, 10, having inner diameter, D3, and containing means, 14 for igniting the air and gas mixture. Means 14, may comprise any means known to the art for igniting combustible gases, including, but not limited to: pilot burners, spark generators and the like.
The means for igniting, 14 may be located at any position in the apparatus of the present invention where sufficient mixing of the gas and air mixture has occurred to produce an ignitible mixture. Preferably, the means for igniting is located at a position wherein the flame, or other igniting means, penetrates the recirculation zone created by the means for stabilizing the ignited gas and air mixture. In the embodiment depicted in Figure 1, the means for igniting, 14, are located a distance P from the end of stack pipe, 4, containing mixing zone, 6. The apparatus of the present invention includes at least one means for igniting, and preferably includes more than one means for igniting spaced around the periphery of stack pipe, 10.
Once the gas and air mixture has been ignited, the mixture will generally remain
burning. Thus, once ignition occurs, the means for igniting may be turned off. Preferably, however, the means for igniting is not turned off to ensure a constant burning of the air and gas mixture.
In the embodiment of the present invention depicted in Figure 1, D3 is greater than D2, thereby creating step, 8, having a cross sectional width of W2. The width, W2 should be sufficient to create a stabilization zone for the ignited air and gas mixture. Stabilization is achieved by recirculation of the ignited air and gas mixture.
The length of stack pipe, 10, is shown as H3. Preferably, the length H3 should be sufficient to permit substantially complete combustion of the combustible components of the ignited air and gas mixture.
The other end of stack pipe, 10, communicates with the atmosphere and includes means for inhibiting downwash, 12, to ensure that the gaseous products resulting from combustion of the gas and air mixture are emitted upwardly into the atmosphere. As shown in Figure 1, the means for inhibiting downwash, 12, may comprise a frustoconically flared portion of stack pipe, 10, which increases the diameter of stack pipe, 10, to diameter D4. The length and width of the flared portion of stack pipe, 10, which comprises the downwash inhibiting means, are shown as H4 and W3 respectively.
The apparatus of the present invention may be constructed from materials known to those of ordinary skill in the art Suitable materials include, but are not limited to: stainless steel, refractory materials and the like.
With reference to Figure 1, in the method of the present invention, gas emitted from gas supply pipe, 2 mixes with air in mixing zone, 6. The resulting air and gas mixture travels into stack pipe, 10 where the mixture is ignited by ignition means, 14. The resulting ignited mixture is stabilized as a result of step, 8. The combustible components of the air and gas mixture continue to burn in stack pipe, 10 and are discharged into the atmosphere. Downwash inhibiting means, 12, helps to ensure that the combustion products from the ignited gas and air mixture are emitted upwardly into the atmosphere.
Figure 2 depicts an alternate embodiment of the apparatus of the present invention. In
the apparatus depicted in Figure 2, internal flame stabilization means, 20, is provided in stack pipe, 10. The internal flame stabilization means, 20, comprise any object that creates recirculation, preferably a cone or hemisphere and are suspended in the stream flowing through stack pipe 10. The remainder of the apparatus shown in Figure 2 is similar to the apparatus shown in Figure 1 except that in the Figure 2 apparatus, the step, 8, between stack pipes, 4 and 10, has been omitted. The dimensions, including length and internal diameter, of the stack pipes, downwash inhibiting means, and other parts of the apparatus depicted in Figure 2 may, or may not, be the same as those described with reference to Figure 1.
In another alternative embodiment of the apparatus of the present invention, the apparatus is constructed with both the internal flame stabilization means, 20, and external flame stabilization means in the form of the step, 8, between stack pipes 4 and 10.
With reference to Figure 2, in the method of the present invention, gas emitted from gas supply pipe, 2 mixes with air in mixing zone, 6. The resulting air and gas mixture travels into stack pipe, 10 where the mixture is ignited by ignition means, 14. The resulting ignited mixture by stabilizing means 20. The combustible components of the air and gas mixture continue to burn in stack pipe, 10 and are discharged into the atmosphere. Downwash inhibiting means, 12, helps to ensure that the combustion products from the ignited gas and air mixture are emitted upwardly into the atmosphere.
Further details of the apparatus and method of the present invention, and their advantages, will become apparent from the following Example.
A vacuum generator Prima 600 process industrial mass spectrometer, manufactured by VG Gas Analysis System, Ltd. of the United Kingdom was utilized to determine the composition of the gas streams referred to in the following Example. Instructions for utilizing the spectrometer accompany the machine. The gas streams were dried to approximately 2% water, by weight, prior to analysis using Perma Pure dryers, manufactured by Perma Pure Products, Incorporated, of Toms River, New Jersey.
EXAMPLE:
This example illustrates the effectiveness of the method and apparatus of the present invention.
An apparatus of the present invention, as depicted in Figure 1, was placed in communication with the combustion gas stream emitted from a carbon black furnace reactor during a carbon black production run. The apparatus of the present invention was constructed from stainless steel and utilized a propane burner to ignite the air and gas mixture. The geometry, and operating conditions, utilized are set forth in Table 1.
Table 1 - Apparatus Geometry
D-l (in.) 3.00
D-2 (in.) 4.31
D-3 (in.) 7.50
D-4 (in.) 12.38
H-l (in.) 3.00
H-2 (in.) 10.50
H-3 (in.) 7.50
H-4 (in.) 2.44
W-l (in.) 0.66
W-2 (in.) 1.59
W-3 (in.) 2.44
P (in.) 1.50
Propane Flow to Ignitor (scfh) 2.67
Ignitor Nozzle Size (in.) 0.50
Feed gas Rate (kscfh) 9.35
Feed gas Moisture (vol. %) 35.3
Feed gas Heat Value (BTU/SCF) 66
Temperature in Supply Pipe, 2 (°F) 254
Stream Velocity in Supply Pipe, 2 (ft/s) 73 in. = inch(es); scfh = standard cubic feet per hour; kscfh = thousand standard cubic feet per hour; vol. % = volume percentage; BTU = British thermal unit; °F = degrees Fahrenheit; ftJs = feet per second
The compositions of the gas streams entering and leaving the apparatus of the present invention were determined, after drying, according to the procedures described herein. The results are set forth in Table 2 below:
Table 2 - Dried Gas Stream Composition
Compound Entering Stream Exiting Stream
N2 (vol. %) 62.50 84.18
O2 (vol. %) 3.56 0.00
CO2 (vol. %) 2.44 13.61
Ar (vol. %) 0.67 0.99
C2H2 (vol. %) 0.223 < 0.003
H2 (vol. %) 14.99 0.18
CO (vol. %) 14.55 0.82
CH4 (vol. %) 0.772 < 0.003
H2S (ppmv) 626 <31
SO2 (ppmv) 631 2249
CS2 (ppmv) 959 < 15
COS (ppmv) 233 < 15 vol. % = volume percentage; ppmv = volume parts per million.
The results provided in Table 2 indicate that the method and apparatus of the present invention reduce the emission levels of all of the combustible components, including CS2, COS, and H2S in the gas stream. These results also make it apparent that the combustion efficiency of the apparatus of the present invention is high.
These results indicate that the method and apparatus of the present invention are advantageous for use in burning the combustible components of gases.
It should be clearly understood that the forms of the present invention herein described are illustrative only and are not intended to limit the scope of the invention.
Claims (3)
1. An apparatus for burning the combustible components of a gas stream comprising; a stack pipe having one end in communication with a gas supply pipe for receiving a gas stream; means for introducing air into the stack pipe to produce an air and gas mixture; a mixing zone; means for igniting the air and gas mixture; stabilization means for stabilizing the ignited mixture; and means located at the other end of the stack pipe for inhibiting downwash of the gaseous products resulting from combustion of the gas and air mixture.
2. The apparatus of claim 1 further comprising a plurality of stack pipes wherein a first stack pipe contains said mixing zone, said means for igniting the air and gas mixture are located in a second stack pipe in communication with said first stack pipe and having a diameter larger than said first stack pipe, and wherein said flame stabilization means comprise the step between the first and second stack pipes.
3. A method for burning the combustible components of a gas stream comprising: introducing a gas stream containing combustible components into one end of a stack pipe; introducing air into the stack pipe to produce an air and gas mixture; mixing the air and gas mixture in a mixing zone; igniting the air and gas mixture; stabilizing the flame produced by igniting the air and gas mixture; allowing the gaseous products resulting from combustion of the gas and air mixture to exit the stack pipe; inhibiting downwash of the gaseous products.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB939305820A GB9305820D0 (en) | 1993-03-20 | 1993-03-20 | Apparatus and method for burning combustible gases |
| GB9305820 | 1993-03-20 | ||
| PCT/US1994/002715 WO1994021967A1 (en) | 1993-03-20 | 1994-03-14 | Apparatus and method for burning combustible gases |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU6519194A true AU6519194A (en) | 1994-10-11 |
| AU686151B2 AU686151B2 (en) | 1998-02-05 |
Family
ID=10732448
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU65191/94A Ceased AU686151B2 (en) | 1993-03-20 | 1994-03-14 | Apparatus and method for burning combustible gases |
Country Status (14)
| Country | Link |
|---|---|
| EP (2) | EP0913639B1 (en) |
| JP (1) | JPH08507852A (en) |
| CN (1) | CN1110648C (en) |
| AU (1) | AU686151B2 (en) |
| BR (1) | BR9406185A (en) |
| CA (1) | CA2158560A1 (en) |
| CZ (1) | CZ290561B6 (en) |
| DE (2) | DE69419737D1 (en) |
| ES (1) | ES2133550T3 (en) |
| GB (1) | GB9305820D0 (en) |
| HK (2) | HK1015166A1 (en) |
| PT (1) | PT913639E (en) |
| TW (1) | TW240282B (en) |
| WO (1) | WO1994021967A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2794846B1 (en) * | 1999-10-12 | 2001-07-20 | Gaz De Petrole | OBSTACLE BURNER CREATING TURBULENCE |
| FR2880103B1 (en) * | 2004-12-23 | 2007-07-20 | Air Liquide | BURNER WITH ELECTRICAL IGNITION |
| GB0509944D0 (en) * | 2005-05-16 | 2005-06-22 | Boc Group Plc | Gas combustion apparatus |
| US7707818B2 (en) * | 2008-02-11 | 2010-05-04 | General Electric Company | Exhaust stacks and power generation systems for increasing gas turbine power output |
| JP5404031B2 (en) * | 2008-12-26 | 2014-01-29 | 三菱重工業株式会社 | Grand Flare |
| JP5657335B2 (en) * | 2010-10-18 | 2015-01-21 | 株式会社桂精機製作所 | Oil mist removing burner and apparatus for generating oil smoke using the same |
| CN107448943B (en) * | 2013-02-14 | 2020-11-06 | 美一蓝技术公司 | Perforated flame holder and burner comprising a perforated flame holder |
| CN103912884B (en) * | 2014-01-13 | 2017-04-12 | 沈阳农业大学 | Biomass carbonization furnace tail gas treatment device |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1193820A (en) * | 1969-04-19 | 1970-06-03 | Ivor Hawkes | Improvements in or relating to Gas Burners |
| GB1249967A (en) * | 1970-07-09 | 1971-10-13 | Joshua Swithenbank | Improvements in or relating to waste gas burners |
| FR2178829B1 (en) | 1972-04-06 | 1974-12-13 | Melle Bezons | |
| US3898317A (en) | 1972-07-24 | 1975-08-05 | Midland Ross Corp | Method for incinerating flue gases |
| US3893810A (en) * | 1972-12-18 | 1975-07-08 | La Clede Lientz | Flare stack burner for odor and pollutant elimination |
| US3852023A (en) | 1972-12-27 | 1974-12-03 | Hitachi Shipbuilding Eng Co | Apparatus disposing waste gas by burning |
| GB1422906A (en) | 1973-05-18 | 1976-01-28 | Huettenwerksanlagen Mbh Ges Fu | Flare burner for burning off combustible waste gases |
| US4003693A (en) * | 1975-03-06 | 1977-01-18 | Combustion Unlimited Incorporated | Flare stack gas burner |
| JP2713627B2 (en) * | 1989-03-20 | 1998-02-16 | 株式会社日立製作所 | Gas turbine combustor, gas turbine equipment including the same, and combustion method |
-
1993
- 1993-03-20 GB GB939305820A patent/GB9305820D0/en active Pending
-
1994
- 1994-01-26 TW TW83100651A patent/TW240282B/zh active
- 1994-03-14 CA CA 2158560 patent/CA2158560A1/en not_active Abandoned
- 1994-03-14 JP JP6521143A patent/JPH08507852A/en not_active Ceased
- 1994-03-14 EP EP99100417A patent/EP0913639B1/en not_active Expired - Lifetime
- 1994-03-14 BR BR9406185A patent/BR9406185A/en not_active IP Right Cessation
- 1994-03-14 CZ CZ19952432A patent/CZ290561B6/en not_active IP Right Cessation
- 1994-03-14 CN CN94192025A patent/CN1110648C/en not_active Expired - Fee Related
- 1994-03-14 ES ES94912778T patent/ES2133550T3/en not_active Expired - Lifetime
- 1994-03-14 AU AU65191/94A patent/AU686151B2/en not_active Ceased
- 1994-03-14 WO PCT/US1994/002715 patent/WO1994021967A1/en active IP Right Grant
- 1994-03-14 PT PT99100417T patent/PT913639E/en unknown
- 1994-03-14 DE DE69419737T patent/DE69419737D1/en not_active Expired - Lifetime
- 1994-03-14 DE DE69904244T patent/DE69904244D1/en not_active Expired - Lifetime
- 1994-03-14 EP EP94912778A patent/EP0688414B1/en not_active Expired - Lifetime
-
1998
- 1998-12-28 HK HK98119159A patent/HK1015166A1/en not_active IP Right Cessation
- 1998-12-28 HK HK00102123A patent/HK1024943A1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08507852A (en) | 1996-08-20 |
| CZ290561B6 (en) | 2002-08-14 |
| EP0913639A2 (en) | 1999-05-06 |
| PT913639E (en) | 2003-04-30 |
| HK1015166A1 (en) | 1999-10-08 |
| CN1110648C (en) | 2003-06-04 |
| CA2158560A1 (en) | 1994-09-29 |
| GB9305820D0 (en) | 1993-05-05 |
| CZ243295A3 (en) | 1996-03-13 |
| CN1122629A (en) | 1996-05-15 |
| ES2133550T3 (en) | 1999-09-16 |
| DE69904244D1 (en) | 2003-01-16 |
| EP0688414A1 (en) | 1995-12-27 |
| AU686151B2 (en) | 1998-02-05 |
| WO1994021967A1 (en) | 1994-09-29 |
| BR9406185A (en) | 1996-02-06 |
| EP0913639A3 (en) | 1999-08-11 |
| EP0688414B1 (en) | 1999-07-28 |
| HK1024943A1 (en) | 2000-10-27 |
| DE69419737D1 (en) | 1999-09-02 |
| EP0913639B1 (en) | 2002-12-04 |
| TW240282B (en) | 1995-02-11 |
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