AU650042B2 - Insect repellent - Google Patents
Insect repellent Download PDFInfo
- Publication number
- AU650042B2 AU650042B2 AU83376/91A AU8337691A AU650042B2 AU 650042 B2 AU650042 B2 AU 650042B2 AU 83376/91 A AU83376/91 A AU 83376/91A AU 8337691 A AU8337691 A AU 8337691A AU 650042 B2 AU650042 B2 AU 650042B2
- Authority
- AU
- Australia
- Prior art keywords
- composition
- formula
- insect
- compounds
- insect repellent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000000077 insect repellent Substances 0.000 title claims description 37
- 239000000203 mixture Substances 0.000 claims description 90
- NEHNMFOYXAPHSD-UHFFFAOYSA-N citronellal Chemical compound O=CCC(C)CCC=C(C)C NEHNMFOYXAPHSD-UHFFFAOYSA-N 0.000 claims description 53
- 150000001875 compounds Chemical class 0.000 claims description 39
- 229930003633 citronellal Natural products 0.000 claims description 26
- 235000000983 citronellal Nutrition 0.000 claims description 26
- 238000009835 boiling Methods 0.000 claims description 17
- 241000238631 Hexapoda Species 0.000 claims description 15
- 239000002253 acid Substances 0.000 claims description 13
- 239000006210 lotion Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- HBAQYPYDRFILMT-UHFFFAOYSA-N 8-[3-(1-cyclopropylpyrazol-4-yl)-1H-pyrazolo[4,3-d]pyrimidin-5-yl]-3-methyl-3,8-diazabicyclo[3.2.1]octan-2-one Chemical class C1(CC1)N1N=CC(=C1)C1=NNC2=C1N=C(N=C2)N1C2C(N(CC1CC2)C)=O HBAQYPYDRFILMT-UHFFFAOYSA-N 0.000 claims description 9
- 230000002195 synergetic effect Effects 0.000 claims description 9
- 239000000443 aerosol Substances 0.000 claims description 8
- 241001465754 Metazoa Species 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- 230000001846 repelling effect Effects 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 150000001241 acetals Chemical class 0.000 description 40
- 150000002936 p-menthane-3,8-diol derivatives Chemical class 0.000 description 33
- 241000255925 Diptera Species 0.000 description 27
- 238000007363 ring formation reaction Methods 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 10
- 150000002009 diols Chemical class 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 230000002940 repellent Effects 0.000 description 7
- 239000005871 repellent Substances 0.000 description 7
- LMXFTMYMHGYJEI-IWSPIJDZSA-N (1R,2R,5R)-2-(1-hydroxy-1-methylethyl)-5-methylcyclohexanol Chemical compound C[C@@H]1CC[C@@H](C(C)(C)O)[C@H](O)C1 LMXFTMYMHGYJEI-IWSPIJDZSA-N 0.000 description 6
- LMXFTMYMHGYJEI-HLTSFMKQSA-N (1S,2R,5R)-2-(1-hydroxy-1-methylethyl)-5-methylcyclohexanol Chemical compound C[C@@H]1CC[C@@H](C(C)(C)O)[C@@H](O)C1 LMXFTMYMHGYJEI-HLTSFMKQSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- MMOXZBCLCQITDF-UHFFFAOYSA-N N,N-diethyl-m-toluamide Chemical compound CCN(CC)C(=O)C1=CC=CC(C)=C1 MMOXZBCLCQITDF-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000002304 perfume Substances 0.000 description 4
- 239000011541 reaction mixture Substances 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 244000165852 Eucalyptus citriodora Species 0.000 description 3
- 235000004722 Eucalyptus citriodora Nutrition 0.000 description 3
- 241000282414 Homo sapiens Species 0.000 description 3
- 229960001673 diethyltoluamide Drugs 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000257159 Musca domestica Species 0.000 description 2
- 241000258242 Siphonaptera Species 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 235000013351 cheese Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000004508 fractional distillation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- LMXFTMYMHGYJEI-UHFFFAOYSA-N p-menthane-3,8-diol Chemical compound CC1CCC(C(C)(C)O)C(O)C1 LMXFTMYMHGYJEI-UHFFFAOYSA-N 0.000 description 2
- 229930006948 p-menthane-3,8-diol Natural products 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- NEHNMFOYXAPHSD-SNVBAGLBSA-N (+)-Citronellal Chemical compound O=CC[C@H](C)CCC=C(C)C NEHNMFOYXAPHSD-SNVBAGLBSA-N 0.000 description 1
- DYLIWHYUXAJDOJ-OWOJBTEDSA-N (e)-4-(6-aminopurin-9-yl)but-2-en-1-ol Chemical compound NC1=NC=NC2=C1N=CN2C\C=C\CO DYLIWHYUXAJDOJ-OWOJBTEDSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 241000256111 Aedes <genus> Species 0.000 description 1
- 244000291564 Allium cepa Species 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 241001674044 Blattodea Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 241001124166 Musca vetustissima Species 0.000 description 1
- 241000257226 Muscidae Species 0.000 description 1
- 241000255129 Phlebotominae Species 0.000 description 1
- 241000224016 Plasmodium Species 0.000 description 1
- 238000010478 Prins reaction Methods 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 241000130767 Tineidae Species 0.000 description 1
- 238000005903 acid hydrolysis reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000005557 antagonist Substances 0.000 description 1
- -1 bicyclic acetal Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000013375 chromatographic separation Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000001999 effect on insects Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 description 1
- FLIBKIRHXYPCJV-UHFFFAOYSA-N ethanol;propan-2-yl tetradecanoate Chemical compound CCO.CCCCCCCCCCCCCC(=O)OC(C)C FLIBKIRHXYPCJV-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 201000004792 malaria Diseases 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 244000045947 parasite Species 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N49/00—Biocides, pest repellants or attractants, or plant growth regulators, containing compounds containing the group, wherein m+n>=1, both X together may also mean —Y— or a direct carbon-to-carbon bond, and the carbon atoms marked with an asterisk are not part of any ring system other than that which may be formed by the atoms X, the carbon atoms in square brackets being part of any acyclic or cyclic structure, or the group, wherein A means a carbon atom or Y, n>=0, and not more than one of these carbon atoms being a member of the same ring system, e.g. juvenile insect hormones or mimics thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S424/00—Drug, bio-affecting and body treating compositions
- Y10S424/10—Insect repellent
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Insects & Arthropods (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU83376/91A AU650042B2 (en) | 1990-08-06 | 1991-08-05 | Insect repellent |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPK1581 | 1990-08-06 | ||
| AUPK158190 | 1990-08-06 | ||
| AU83376/91A AU650042B2 (en) | 1990-08-06 | 1991-08-05 | Insect repellent |
| PCT/AU1991/000343 WO1992002136A1 (en) | 1990-08-06 | 1991-08-05 | Insect repellent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU8337691A AU8337691A (en) | 1992-03-02 |
| AU650042B2 true AU650042B2 (en) | 1994-06-09 |
Family
ID=3774869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU83376/91A Ceased AU650042B2 (en) | 1990-08-06 | 1991-08-05 | Insect repellent |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5298250A (enExample) |
| EP (1) | EP0543883B1 (enExample) |
| AU (1) | AU650042B2 (enExample) |
| BR (1) | BR9106719A (enExample) |
| CA (1) | CA2088687A1 (enExample) |
| DK (1) | DK0543883T3 (enExample) |
| GR (1) | GR3018975T3 (enExample) |
| HK (1) | HK1007096A1 (enExample) |
| IN (1) | IN179228B (enExample) |
| MX (1) | MX9100538A (enExample) |
| MY (1) | MY107439A (enExample) |
| NZ (1) | NZ239282A (enExample) |
| SG (1) | SG42338A1 (enExample) |
| WO (1) | WO1992002136A1 (enExample) |
| ZA (1) | ZA916141B (enExample) |
| ZM (1) | ZM3391A1 (enExample) |
| ZW (1) | ZW11091A1 (enExample) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5573700A (en) * | 1986-08-08 | 1996-11-12 | Colgate-Palmolive Co. | Liquid household cleaning composition with insect repellent |
| US5569411A (en) * | 1986-08-08 | 1996-10-29 | Colgate-Palmolive Co. | Liquid household cleaning composition with insect repellent |
| US5489433A (en) * | 1991-01-04 | 1996-02-06 | Safe-Tee Chemical Products Company | Environmentally safe insecticide |
| AU659625B2 (en) * | 1991-01-18 | 1995-05-25 | Clilco, Ltd. | Lice-repellant compositions |
| US5417009A (en) * | 1991-01-18 | 1995-05-23 | International Flavors & Fragrances Inc. | House fly, horn fly, and mosquito repellents and apparatus useful in testing efficacy of same |
| US5621013A (en) * | 1992-06-24 | 1997-04-15 | Primavera Laboratories, Inc. | Insect replellent blends, lotions, and sprays |
| GB2282534A (en) * | 1993-10-08 | 1995-04-12 | Paul Douglas Clarke | Insect repellent compositions |
| US6130255A (en) * | 1993-10-22 | 2000-10-10 | Ikemoto; Takeshi | Noxious-insect repellent |
| CA2157955A1 (en) * | 1994-09-30 | 1996-03-31 | Yoshinori Shono | Arthropod repellent composition |
| AUPO060596A0 (en) * | 1996-06-21 | 1996-07-18 | Nineteenth Maybarb Pty Ltd | Mosquito control |
| US5902595A (en) * | 1996-07-29 | 1999-05-11 | Effcon, Inc. | Pesticidal composition and method of use |
| JP3450680B2 (ja) * | 1997-10-28 | 2003-09-29 | 高砂香料工業株式会社 | パラ−メンタン−３，８−ジオールの製造方法 |
| US6355264B1 (en) | 1998-03-20 | 2002-03-12 | Avon Products, Inc. | Insect repellent composition |
| US6350724B1 (en) | 1999-04-20 | 2002-02-26 | Effcon Laboratories, Inc. | Lice removing composition |
| US7189421B2 (en) * | 1999-07-21 | 2007-03-13 | Paul Douglas Clarke | Antiseptic composition |
| US20040247708A1 (en) * | 1999-07-21 | 2004-12-09 | Clarke Paul Douglas | Antiseptic composition |
| US7282211B2 (en) * | 2001-05-21 | 2007-10-16 | Btg International Inc. | Pest treatment composition |
| EP1337145A4 (en) * | 2000-11-28 | 2009-05-27 | Avon Prod Inc | ANHYDROUS REPULSIVE COMPOSITION FOR INSECTS |
| DE10250898A1 (de) * | 2002-10-31 | 2004-05-19 | Franz Bencsits | Acetale als Insektenabwehrmittel |
| ATE491441T1 (de) * | 2004-03-12 | 2011-01-15 | Paul Douglas Clarke | Antivirale zusammensetzung mit p-menthan-3,8-diol |
| EP2142500B1 (en) | 2007-03-28 | 2013-07-31 | Contech Enterprises Inc. | Allyl sulfide compounds, and compositions and methods using said compounds for repelling blood-feeding arthropods |
| EP2638802A1 (en) | 2007-09-13 | 2013-09-18 | Ian Thomas Dell | Composition containing p-menthane-3, 8-diol and its use as insect repellent |
| JP6063559B2 (ja) * | 2012-05-02 | 2017-01-18 | ベドウキアン リサーチ， インコーポレイテッド | トコジラミの防除及び忌避 |
| FR3098373B1 (fr) | 2019-07-10 | 2022-12-16 | Centre Nat Rech Scient | Composition répulsive de moustique et procédé de préparation |
| FR3098374B1 (fr) | 2019-07-10 | 2022-12-23 | Centre Nat Rech Scient | Nouveau procédé de préparation d’un agent répulsif d’insectes |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2396735A1 (fr) * | 1977-07-04 | 1979-02-02 | Rhone Poulenc Ind | Procede de preparation de citronellal optiquement actif |
| JPS60199804A (ja) * | 1984-03-26 | 1985-10-09 | Nippon Kayaku Co Ltd | 有害生物忌避剤 |
| US4774082A (en) * | 1987-01-13 | 1988-09-27 | S. C. Johnson & Son, Inc. | Volatile insect repellents |
| CH676412A5 (enExample) * | 1988-01-27 | 1991-01-31 | Serge Andre Leuthold | |
| DE68920697T2 (de) * | 1988-10-31 | 1995-06-22 | Takiron Co | Insektenvertreibungsmittel mit gesteuerter Freisetzung. |
| JP2790678B2 (ja) * | 1989-10-18 | 1998-08-27 | 日本化薬株式会社 | 有害生物忌避剤 |
| JPH03176404A (ja) * | 1989-12-04 | 1991-07-31 | Nippon Kayaku Co Ltd | Ｐ―メンタン誘導体のマイクロカプセル化による害虫忌避組成物 |
| JP3013540B2 (ja) * | 1990-09-18 | 2000-02-28 | 住友化学工業株式会社 | 害虫忌避剤 |
-
1991
- 1991-08-02 ZM ZM33/91A patent/ZM3391A1/xx unknown
- 1991-08-05 AU AU83376/91A patent/AU650042B2/en not_active Ceased
- 1991-08-05 US US07/983,572 patent/US5298250A/en not_active Expired - Fee Related
- 1991-08-05 BR BR919106719A patent/BR9106719A/pt not_active Application Discontinuation
- 1991-08-05 HK HK98105906A patent/HK1007096A1/en not_active IP Right Cessation
- 1991-08-05 CA CA002088687A patent/CA2088687A1/en not_active Abandoned
- 1991-08-05 EP EP91914740A patent/EP0543883B1/en not_active Expired - Lifetime
- 1991-08-05 DK DK91914740.5T patent/DK0543883T3/da not_active Application Discontinuation
- 1991-08-05 SG SG1996001506A patent/SG42338A1/en unknown
- 1991-08-05 WO PCT/AU1991/000343 patent/WO1992002136A1/en not_active Ceased
- 1991-08-05 ZA ZA916141A patent/ZA916141B/xx unknown
- 1991-08-06 IN IN714DE1991 patent/IN179228B/en unknown
- 1991-08-06 MX MX9100538A patent/MX9100538A/es unknown
- 1991-08-06 NZ NZ239282A patent/NZ239282A/xx unknown
- 1991-08-06 ZW ZW110/91A patent/ZW11091A1/xx unknown
- 1991-08-06 MY MYPI91001418A patent/MY107439A/en unknown
-
1996
- 1996-02-14 GR GR960400376T patent/GR3018975T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZW11091A1 (en) | 1991-12-18 |
| DK0543883T3 (da) | 1996-01-29 |
| ZA916141B (en) | 1992-06-24 |
| GR3018975T3 (en) | 1996-05-31 |
| AU8337691A (en) | 1992-03-02 |
| EP0543883A4 (en) | 1993-04-02 |
| ZM3391A1 (en) | 1992-04-30 |
| EP0543883A1 (en) | 1993-06-02 |
| CA2088687A1 (en) | 1992-02-07 |
| IN179228B (enExample) | 1997-09-20 |
| US5298250A (en) | 1994-03-29 |
| MY107439A (en) | 1995-12-31 |
| MX9100538A (es) | 1992-04-01 |
| BR9106719A (pt) | 1993-08-31 |
| WO1992002136A1 (en) | 1992-02-20 |
| SG42338A1 (en) | 1997-08-15 |
| NZ239282A (en) | 1993-06-25 |
| HK1007096A1 (en) | 1999-04-01 |
| EP0543883B1 (en) | 1995-12-27 |
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| US6986898B1 (en) | Synergistic and residual pesticidal compositions containing plant essential oils with enzyme inhibitors | |
| EP1102540A1 (en) | Synergistic and residual pesticidal compositions containing plant essential oils | |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |