AU615762B2 - Method for laminating polymer films - Google Patents
Method for laminating polymer films Download PDFInfo
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- AU615762B2 AU615762B2 AU37250/89A AU3725089A AU615762B2 AU 615762 B2 AU615762 B2 AU 615762B2 AU 37250/89 A AU37250/89 A AU 37250/89A AU 3725089 A AU3725089 A AU 3725089A AU 615762 B2 AU615762 B2 AU 615762B2
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- Prior art keywords
- assembly
- film
- laminated assembly
- resultant
- making
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
- B29C65/40—Applying molten plastics, e.g. hot melt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/80—General aspects of machine operations or constructions and parts thereof
- B29C66/83—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools
- B29C66/834—General aspects of machine operations or constructions and parts thereof characterised by the movement of the joining or pressing tools moving with the parts to be joined
- B29C66/8341—Roller, cylinder or drum types; Band or belt types; Ball types
- B29C66/83411—Roller, cylinder or drum types
- B29C66/83413—Roller, cylinder or drum types cooperating rollers, cylinders or drums
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C65/00—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
- B29C65/02—Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
- B29C66/024—Thermal pre-treatments
- B29C66/0242—Heating, or preheating, e.g. drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/02—Preparation of the material, in the area to be joined, prior to joining or welding
- B29C66/028—Non-mechanical surface pre-treatments, i.e. by flame treatment, electric discharge treatment, plasma treatment, wave energy or particle radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/40—General aspects of joining substantially flat articles, e.g. plates, sheets or web-like materials; Making flat seams in tubular or hollow articles; Joining single elements to substantially flat surfaces
- B29C66/41—Joining substantially flat articles ; Making flat seams in tubular or hollow articles
- B29C66/45—Joining of substantially the whole surface of the articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/10—Surface shaping of articles, e.g. embossing; Apparatus therefor by electric discharge treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/01—General aspects dealing with the joint area or with the area to be joined
- B29C66/05—Particular design of joint configurations
- B29C66/10—Particular design of joint configurations particular design of the joint cross-sections
- B29C66/11—Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
- B29C66/112—Single lapped joints
- B29C66/1122—Single lap to lap joints, i.e. overlap joints
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C66/00—General aspects of processes or apparatus for joining preformed parts
- B29C66/70—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
- B29C66/71—General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Plasma & Fusion (AREA)
- Laminated Bodies (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
Description
S008547 V i ;1 COMMONWEALTH OF AUSTRALIA Patent Act 195261572 7 Tc' l AP T E E S P E C IF ICATION
(ORIGINAL)
Class Int. Class Application Number Lodged Complete Specification Lodged Accepted Published Priority: 29 July 1988 4#4* 4 4.
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4' 4 0 Related Art Name of Applicant Address of Applicant Actual Inventor 4 4 .4 0 4; 4' S 14 AMP Incorporated 470 Friendship Road, Harrisburg, Pennsylvania United States of America John Franklin Jasinski Robert Philip McCormick Ricky Charles Mellinger James Kenneth Draper Navin Naryan Vyas Address for Service F.B. RICE CO., Patent Attorneys, 28A Montague Street, BALMAIN. 2041.
Complete Specification for the invention entitled: "METHOD FOR LAMINATING POLYMER FILMS" The following statement is a full description of this invention including the best method of performing it known to Us:-
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I a 1 Signeddm A Status Declaran t ame ,.Jay Sit:chik. 1 1 4
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E B. RICE CO PATENT ATTORNEYS This form is sullabl for nny type of Patont Application. No l g llsgition required.
i' fcl I, 1 J 2 u*in:,,i '1*111 44,, o <i 1 4 4 4 4 6 I 1
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ft 4 *o 41 4 4 4 This invention relates to laminating layers of polymer films and in particular to laminates that form an assured bond with a further substrate to form a resultant laminated assembly, the bond having sufficient strength to withstand further processing and forming of the resultant assembly.
Laminating films are generally made from polyethylene, polypropylene, polyesters, polyimides, polyetherimides, polysulphones and the like. In general Sthese polymer films have surfaces that are chemically inert and non-porous. These surfaces have low surface energies that cause them to be non-receptive to bonding with adhesives, printing inks, coating and the like.
Typically the surface of these materials are subjected to a surface treatment to improve their bonding characteristics. One method for achieving a bond between a layer of polymer film and another layer of film, such as an adhesive film, is to form a laminate by using a primer adhesive, which prepares the surface of one of the layers 20 of polymer film for bonding to the other layer of film.
This method, however, generally requires the use of an adhesive having volatile organic solvents, which react with the surface of the polymer film to render it more receptive to subsequent bonding. The organic solvents, however, may pose both safety and health risks. It is g i 44.4 4 4 4 6 C4 a 44 4 a a a a 1t6 Iaq 4 a «r i 4 444 rX i *4" uri~aLco r desirable, therefore, to have a method of laminating films that will eliminate the use of such organic solvents, it is also desirable to have an in-line method for treating the surface of a film shortly before lamination to insure a strong bond.
A number of other methods are known for treating the surfaces of film layers to increase the bonding characteristics. These methods include corona discharge; etching by means of acid or plasma. and i flame treatment. Generally the latter two means are reserved for molded parts, while corona treatment is used when bonding sheets or strips of film. The object of the corona treatment is to improve the wetability of surface I* 4 of the film to improve the ability of the film to bond to 44 q adhesives. In bonding two polymer webs it is recognized that both webs should generally be corona treated prior to *o 4 thermal laminating the layers. A discussion of the surface treatment of polymer films and corona treating in general is found in Chapter 14, "Surface Treatment" pp 2 241-249 of Web Processing and Converting Technology and Equipment, Satas, ed. 1984), Van Nostrand Reinhold o 0 Company, New York, N.Y.
Once the adhesive has been bonded to a surface of the oOo polymer film, the laminate is typically bonded to another S' article. One particular application of a use of a laminate is in manufacturing of preinsulated electrical i: r.l r -ii ~I connectors and in particular preinsulated crimpable connectors. This type of connector has an insulating sheath bonded to a metal ferrule member. Typical connectors of this type are disclosed in U.S. Patent Nos.
3,320,354 and 3,611,262. Tools such as the devices disclosed in U.S. patent No. 3,328,872 have been designed to crimp the connectors of the above patents onto wires.
Such connectors have long been used to splice insulated wires particularly wires such as telephone cables.
1 In forming the insulating sheaths for such connectors, it is necessary to adhere the metal to a polymer film, such as a polyester film. In assembling ooo such connectors the film layer is first laminated to a r film of adhesive and then to a strip of metal that has been stamped into a series of connector blanks. The unit 44 Seo comprising the sheath, adhesive and metal is then formed into a U-shaped connector. The insulating sheath must have sufficient flexibility and bond strength to withstand the force exerted in forming the connector without 20 delamination occurring between the adhesive film and the metal or the adhesive film and the outer film layer. In 4 40 °°addition, the formed connector should be resistant to environmental changes, such as fluctuations in temperature and humidity, without delamination thereby assuring a long o 4$shelf life.
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It is desirable, therefore, to have a means for assuring the bond between the outer sheath film and the adhesive film and the bond between the adhesive film and the metal that are capable of withstanding such forming forces as well as subsequent crimping forces, which may be in excess of 500 kilogram/square centimeter (7000 pounds/square inch).
In addition it is desirable to have a method for assuring a bond that does not require the use of volatile organic solvents.
The present invention is directed to a method for laminating film layers without the need of adhesive primer materials and to a method for bonding that assures a 00 too secure bond even when the materials are subjected to high 00 tensile forces.
00 0 It is an object of the invention to provide a method 0o 0 for laminating a layer of dielectric film to a layer of adhesive film without the need for a primer adhesive.
00 ~It is a further object of the invention to provide a .o0o 20 method for assuring a secure bond in a laminate that will 0 006 oo withstand high tensile forces.
It is yet another object of the invention to provide 4 an in-line method for treating the films to ensure OO bondability.
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It is a further object of the invention to provide a cost effective method for achieving a laminate having an assured bond between the layers.
It is an additional object to provide a method for laminating continuous strips of the film.
The present invention is directed to making an intermediate laminated product comprising at least two 1layers of film, each film having inner and outer major surfaces, one layer of film having a lower melting point IO than the other. The method comprises treating the inner surface of at least one layer of film to a high voltage electrical discharge to form a treated inner surface, ,0o heating the strip of treated film; aligning the inner 44..
(4 surface of the treated film with the inner surface of the 4 4 ,other film layer in an opposed facing relationship; applying pressure to urge these films relatively together 44 04 and heating the pressed-together films to a temperature greater than the melting point of the lower melting film, whereby said layers of film adheres to one another to form ror9 o0 i o 20 said intermediate laminated assembly and said intermediate ao oo o assembly is bondable to another substrate to form a o o resultant laminated assembly, the resultant assembly being formable to include formations extending outwardly of the *CJ plane of the resultant laminated assembly, and an article 8 6o so formed therefrom remains assuredly bonded to achieve a 1 oI j- 4; 0 000w 4 r0 0 ito 00 0 a a, .4 0O bond between the films such that they act as an integral unit.
The present invention is directed more particularly to a method for laminating an adhesive film to a dielectric film comprising the steps of: selecting an adhesive film with a melting point TI, the adhesive film having inner and outer major surfaces; selecting a dielectric film with a melting point T 2 where T 2
>T
1 the dielectric film having inner and outer major surfaces; subjecting the inner surface of the dielectric film to a high voltage electric discharge to form a treated inner surface; heating the dielectric film having the treated inner surface to a temperature greater than T 1 aligning the inner adhesive surface and the inner treated dielectric surface in opposed facing relationship; applying pressure to urge the films relatively together; and heating said pressed together films to a temperature greater than T 1 whereby the adhesive film adheres to the dielectric film to form the intermediate laminated 20 assembly and the intermediate assembly is bondable to another substrate to form a resultant laminated assembly, the resultant assembly being formable to include formations extending outwardly of the plane of the resultant laminated assembly, and an article so formed therefrom remains assuredly bonded.
Ii r 40 0 0 0O a 0 I 0 0 00 00 *j 4 4 -6- 4400 0 4 4 84 8 t 44 a 0,4 8 @8 4 4 44 44 .4
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4 04 .4 0 4 00 t A 4 0 04 8 4440 0440 0 0 4*04 o. 40 44 4 4 0 In the preferred embodiment, the dielectric film is a polyester film. other suitable films 'may be bonded in accordance with the invention, such as those made from polyimides, polyetherimides, polysulphones and the like.
In the preferred method the inner surfaces of both of the film layers are subjected to the high voltage electric discharge known as corona discharge. It has been found that by preheating the layer of film having the higher melting point T 2 to a temperature greater than TV, the point of the other layer of film, immediately prior to bringing the two film layers together and applying heat and pressure to the aligned layers to urge the layers together, gives an intermediate laminate or composite film that is bondable to a metal substrate to form a resultant laminate having a bond that is surprisingly and unexpectedly superior to similar bonds formed in accordance with the prior art. Connectors made from the resultant laminate of the present invention exhibit markedly superior performance in environmental 20 tests when compared with connectors made in accordance with the prior art. The performance of the connectors increased by greater than an order of magnitude.
In accordance with the present invention a method for laminating two layers of film is provided that achieves a secured bond between the layers such that the intermediate laminated product may be subsequently adhered to a further -7- 4 '4 1~' ti
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.1 wmft substrate, such as a strip of metal, to form a resultant laminated assembly that may be subjected to forming forces without delamination.
The invention itself, together with further objects and the intended advantages, will be best understood by reference to the following detailed description, taken in conjunction with the accompanying drawings.
Figure 1 is a diagrammatic cross-sectional representation of the intermediate laminated assembly of the prior art.
so Figure 1A is a diagrammatic cross-sectional i o° representation of the prior art laminated assembly of Figure 1 adhered to a metal strip.
9 0* Figure 2 is an end view of the formed preinsulated ferrule-type electrical connector of the prior art using the laminated assembly of Figure 1.
Figure 3 is a schematic drawing of the process for forming the intermediate laminated assembly of the invention.
Figure 3A is a schematic drawing of an alternative embodiment of the process for forming the intermediate 0 000 laminated assembly of the invention. i i oO Figure 4 is a diagrammatic cross-sectional representation of the intermediate laminated assembly made in accordance with the invention.
-8- 1 j- 1 Figure 4A is a diagrammatic cross-sectional representation of the laminated assembly of Figure 4 adhered to a layer of metal.
Figure 5 is an end view of a preinsulated crimpable ferrule-type electrical connector using the laminated assembly of the present invention.
Figure 6 is a perspective view of the connector of Figure Figure 7 is a perspective view of the crimped i fO connector of Figure 6.
Referring now to Figure 1, the prior art intermediate saQ4 oo laminated assembly 10 is comprised of a first dielectric oo layer 12 having inner and outer major surfaces 14, 16 S od respectively; second dielectric layer 20 having inner and outer major surfaces 22, 24 respectively adhered to each other by means of adhesive primer layer 18, which is disposed between inner surfaces 14, 22 of first and second 0409 o dielectric layers 12 and 20 respectively. The second or oinner layer 20 is a hot melt adhesive film that is S00 20 compatible with the first layer and will adhere to the rao other material that will be used in making the resultant assembly.
0 Ficgure IA is a diagrammatic cross-sectional representation of the prior art intermediate laminated assembly of Figure 1 adhered to a metal substrate 28 to form the resultant laminated assembly 26 of the prior art.
+4 When forming electrical connectors of the type shown in Figure 2, metal substrate 28 is generally tin plated phosphor bronze or tin plated brass, but other metals suitable for electrical connectors may be used. The particular materials used for the film layers and the metal or other substrate must be compatible with each other. As can be seen from Figure 2, edges 35 of intermediate assembly 10 extend beyond the edges of the metal substrate 28. Figure 2 shows an end view of a prior Sart ferrule-type connector 34 formed from resultant to laminated assembly 26 of Figure 1A. In forming the 0 typically subjected to forming forces of 1000 :I kilogram/square centimeter (15,000 pounds/square inch).
Prior art connector 34, shown in figure 2, is in the general shape of a The first or sheath layer 12 is subjected to a great degree of stress owing to an amount oo of stretching necessary to form the bends at 36. The 00 0 p 00 °000 stresses created at 36 tend to cause delamination of 0 o 20 intermediate assembly 10 at 38. Tests have shown that the 0000 outer layer is stretched to or beyond its elastic limit at the bend 36. This stretching also puts a great deal of ocr 0 0 00o stress on the bond between layers 12 and 20 and they too may delaminate, usually at 39.
In accordance with the present invention, intermediate laminated assembly or composite film 40, as 2: i_ Ii_ I_ .Ibest seen in Figures 4, and 4A, uses the same type of film layers 12 and 20 as the prior art. The same reference numerals, therefore, will be used throughout the description to refer to the same parts. Intermediate laminated assembly 40 is comprised of first layer 12 having inner and outer surfaces 14, 16 respectively and second film layer 20 having inner and outer layer surfaces 22, 24. Intermediate assembly 40 of the present invention, however, requires no primer adhesive such as i that of the prior art.
1 .oo In the preferred embodiment of the invention, first S2or sheath layer 12 is a polyester, such as MYLAR 500EL available from E. I. Du Pont de Nemours and Co., Inc., Wilmington, DE; MELINEX 442, available from ICI Americas Inc., Wilmington, DE; HOSTAPHAN 3900, available from American Hoecst Corp., Somerville, NJ; and LUMIRROR, Grade E, available from Toray Marketing and Sales (America Co.), **0 *O New York, NY. The melting point of polyesters is in 0000 0 0 o*o excess of 200 C (392°F). The adhesive film in the 00 .Oo 20 preferred embodiment is a corona treated polyethylene acrylic acid copolymer, available from Dow Chemical Co.
o,.o under the trade name DAF Dow Adhesive Film 899. The 0i o0.o melting point of the polyethylene acrylic acid copolymer film is in the range of 98-105°C (208-221°F). In the presently preferred embodiment, the polyester sheath layer is 125 microns (0.005 inches) thick, and the adhesive film -11-
I
is 37 microns (0.0015) inches thick. This produces an intermediate assembly having a thickness of about 162 microns (0.0065 inches), which is compatible with present manufacturing equipment and application tooling. Other thicknesses of films may be used, depending upon the article being made from the resultant laminated assembly.
Figure 4A is a diagrammatic cross-sectional representation of composite film or intermediate laminated assembly 40 adhered to a metal substrate 28 to form the it resultant laminated assembly 42 of the present invention.
As can be seen from Figure 5, edges 45 of intermediate assembly 40 extends beyond the edges of the metal 'I 4 substrate 28, which is bonded to intermediate assembly as is known in respect to making terminal 34 of Figure 2.
,Figure 5 shows an end view and Figure 6 is a perspective view of a ferrule-type connector 44 formed from laminated assembly 42 of Figure 4A. Connector 44, shown in Figures 49.4 a 5 and 6 is in the general shape of a It is to be *4 0.o understood that this connector shape is only 0: o: representative of the types of connectors that may be used in accordance with the present invention. Figure 7 shows Sconnector 44 after it has been crimped to wires. As can !4 o be seen from Figure 7, the edges 45 of intermediate Qo assembly 40, are bent inwardly and follow the ferrule 32 as connector 44 is crimped. It is essential, therefore, that the sheath layer 12, and adhesive layer 20 remain -12i-i~
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0 0 4009 00 0 O 0 0 0 a6 00 00 6 bonded to the surface of ferrule 32 so that proper crimping may occur. The present invention provides an assured bond between intermediate assembly 40 and metal 28 that is unexpectedly and surprisingly more resistant to delamination than the bond attainable in the prior art.
Connectors made from the resultant laminate of the present invention exhibit markedly superior performance in environmental tests when compared with connectors made in accordance with the prior art. Samples of connectors made in accordance with the present invention remain laminated even after immersion in boiling water for 10 seconds. The performance of the connectors increased by greater than an order of magnitude. Prior connectors delaminated essentially immediately upon being dropped into the boiling water.
It is particularly essential that the outer dielectric and the inner adhesive layer of the laminate remain bonded together when used in making connectors of the type shown in Figure 5 and 6. The "U"ing, or forming operation produces considerable stress on the bond between the layers of the laminate. The present invention provides a bond that will remain secure despite the force applied to it in such a forming operation. Owing to the absence of the adhesive primer, the outer layer 12 is bent at even a sharper angle at 46 in the present invention than it is at 36 in the prior art. Despite this sharper
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|.SNf -13- L ?sl b .~1I~1IYI~ _1 i 1 _r c- i o* o 0 o 00 O0 t 0 It t 1 t t 4 1 4 0* S0 0 a o 00 t a o 4 0 angle, the present invention exhibits unexpected and surprising results in that the residual stress is lower and the bond is more secure. It is thought that the preheating step may relieve some internal stress within the sheath layer, thus giving an intermediate assembly that exerts less force at 46 against the adhesive bond between metal 28 and adhesive layer 20 than the force exhorted at 36 in prior art connector 34 of Figure 2.
Figure 3 illustrates schematically the method used for forming intermediate laminated assembly 40 of the present invention. A strip of a first layer of film 12 from reel 50 and a strip of adhesive film 20 from reel 56 are passed through a nip roll laminator illustrated by nip rolls 60, 62 to form intermediate assembly 40, which is then wound on reel 66. The tension of strips 12 and 20 as they exit their respective reels 50, 56 and the tension of the strip of intermediate assembly 40 as it enters reel 66 .re adjusted, as known in the art, to prevent stretching and uneven rolling of the respective strips, in accordance with the invention, inner surface 14 of layer 12 is subjected to a high voltage electric discharge as it passes a corona discharge system 52. The treated strip is then preheated in oven 54 to a temperature that is greater than the melting point of the adhesive layer 20. The inner surface 14 of the preheated an treated film layer 12 is then aligned with the inner surface 22 of adhesive -14i i i .a a 1; t i -la- 1 p p 0 O a sn a 6 pD p ft 0 B o ap a~ u, o e 0 9 p.
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o o pp8 p o a O Lr p p p p) p o pq po o p p p p layer 20 in opposed facing relationship and are sequentially passed between nip rolls 60, 62 to form intermediate laminated assembly 40. Assembly 40 is then cooled by roll 64, prior to being would on reel 66. This cooling prevents "blocking", which is the term used to describe the problem of successive layers of strip adhering to each other as they are wound on a reel.
In the presently preferred process for the materials described above, the polyester layer 12 is subjected to a corona treatment sufficient to raise the surface energy of the film to about 60 ergs per square centimeter. Strip 12 is preheated by passing the strip through an IR tunnel oven having a temperature of approximately 620°C (1150°F).
Strip 12 is moved through the oven at a rate sufficient to raise the temperature of the strip to about 177-182°C (350-360°F). To assure a good bond between the layers of film, the temperature of the sheath layer should be sufficient to produce a temperature between the sheath and adhesive layers or glue line temperature sufficient to 20 melt the adhesive. For the lamination of polyester and polyethylene acrylic acid copolymer films, the optimum glue line temperature should be in the range of 143-188°C (290-370°F), and preferably in the range 154-177°C (310-350°F). For ease of alignment of strips 12 and the strips are first passed through a set of unheated nip rolls 60 under a pressure of about 3.2 kilogram/square -2centimeter (45 pounds/square inch), reheated by passing the partially bonded strips over roll 61, which has been heated to about 177°C (350°F), prior to being passed through heated nip rolls 62. At least one of nip rolls 62 is heated to a temperature of about 177°C (350 0 which is approximately the temperature of the film layers. Nip rolls 62 exert a pressure of about 3.2 .kilogram/square centimeter (45 pounds/square inch) against the two layers causing them to be bonded together. Under highly humid I0 conditions, if necessary, the polyester film 12 may be o0^o, passed through a drying oven 51 to remove any excess moisture prior to being subjected to the corona treatment.
Figure 3A illustrates schematically an alternative embodiment of the method used for forming intermediate laminated assembly 40 of the present invention. In this process, the IR tunnel oven is placed between unheated nip rolls 60 and heated rolls 62. The partially laminated .LO intermediate assembly 40 is heated as a unit prior to 0 being passed through heated rolls 62. In both 4°4 20 embodiments, an IR tunnel oven is preferred because the film is heated essentially more uniformly and through the thickness of the film layer or layers, rather than just on S. the surface of the film. This uniform heating and relatively rapid heating of the film produces a quality product and allows the laminating line to be run at a a -16- L. -3faster speed than is possible with other methods of heating.
It is preferable that the corona treatment be on-line and applied to the film shortly before lamination occurs.
Generally the corona treatment increases the wetability of the surface and improves the ability of the surface to bond to adhesives. Since the adhesive of the present invention is a solid film, it is important that the maximum effect of the corona treatment be available on the surface prior to lamination. Generally thermal bonds made by thermal laminators, such as for example the nip rolls, ro require that both polymer webs be treated to the corona discharge. The Dow film used in the present invention is I, i corona treated by the manufacturer. It is to be tit understood that additional corona treatment may be provided on-line as well. The level of the corona treatment required depends upon the type of material used.
451* 4 When laminating polyester with the polyethylene acrylic 4 *4 ,4 acid copolymer, a corona treatment for the polyester that 20 produces a surface energy in the range of 30-60 ergs per square centimeter has produced satisfactory results. The oodegree of corona treatment will vary with a change in °ooo materials used for the adhesive film and/or the sheath layer.
The preheating treatment of the polyester sheath layer is preferably done with an IR heater, which rapidly -17it brings the temperature of the film to 177-182°C (350-360 thus enabling the line to be run at a faster speed than is possible with a heater that takes a longer period of time to heat the polyester film to the desired temperature.
It is to be understood that the amount of corona treatment, the temperature to which the first layer is heated, the temperature and pressure of the nip rolls, etc. may be varied depending upon the materials used for the first and second layers of the intermediate strip, S and/or depending upon the speed at which the assembly line is operated. As the speed of the line is varied, the temperatures of the heated nip rolls and the oven should be varied so as to maintain essentially constant film 84 temperatures. The processing window is primarily defined by the parameters that allow a glue line temperature sufficient to melt the adhesive. For the lamination of 4 polyester and polyethylene acrylic acid copolymer films, *4 44 the optimum glue line temperature should be in the range 20 of 143-188°C (290-370 0 and preferably in the range 154-177°C (310-350°F).
Table 1 (below) compares the results of environmental 4 44 44 tests performed on production run samples of electrical connectors made with the intermediate laminated assembly including the adhesive primer in accordance with the prior art (Group connectors made with an intermediate L -18l 1 1 i assembly wherein the sheath layer was subjected to corona surface treatment without preheating prior to bonding with the adhesive film (Group and connectors made in accordance with the invention, which included corona treatment plus preheating of the sheath layer with an IR heater (Group C).
The production run connector samples were formed into the general shape of the connector of Figure 6. A connector sample was considered to have passed the test if the layers of the intermediate laminate .remained adhered to each other and to the metal member after testing was to completed. A connector was considered to have failed the test if any delamination occurred. Each test was performed on new groups of samples.
S*t The following tests were performed: 1. Immersion in boiling water for 5 seconds.
2. Immersion in boiling water for 10 seconds.
3. Dry heat at 175 F for 2 hours.
4. Dry heat at 180°F for 2 hours.
S 20 5. Dry heat at 1850F for 30 minutes.
00.4 iO 0 o 'a 6 OD i -19- Lir Yt~r TABLE 1 ENVIRONMENTAL TESTS 1 SAMPLE TEST GROUP 1 2 3 4 A F F P F F B F F P P F C P P P P P 00009 0 0 00 00 0 @0 0 o e a 0 0 o 0 0 00 a a 1. F fail; P Pass 4000 So 0 00 o 0 oo00 0 0 0a 00 0 o0 0 As can be seen from the results of the test, the connectors made in accordance with the invention have a 10 bond between the intermediate laminate and metal substrate that is surprisingly and unexpectedly superior to similar bonds formed in accordance with the prior art. Connectors made from the resultant laminate of the present invention exhibit markedly superior performance in environmental tests when compared with connectors made in accordance with the prior art.
s
I:
i i i:
I:
ii i: i
F
ii i
I
i
-I-
'I
Other suitable polymer films may be bonded in accordance with the invention, such as films made from polyimides, polyetherimides, polysulphones and the like.
Samples of connectors have been made with intermediate assemblies made from the above materials wherein the polymer films were subjected to corona treatment and preheated prior to lamination with the polyethylene acrylic acid copolymer film. Upon visual inspection, no delamination was seen in these samples.
The invention is described by way of example only.
It is to be understood that the electrical connectors used 0000 o 0 with the laminate of present invention are representative 0 0 \o samples only. It is to be further understood that the 0 form and shape of the connectors with which this laminate may be used are numerous. The connectors 40 are only exemplary of the many types of preinsulated crimpable ferrule-type connectors available.
4000 S00 a o 0 o 0 oooo 0 -21-
Claims (5)
- 2. The method for making an intermediate laminated assembly as defined in claim 1 wherein said polymer film is selected from the group of films consisting of polyester, polyimide, polyetherimide, and polysulphone films.
- 3. The method for making an intermediate laminated assembly as defined in claim 1 or 2, wherein said adhesive assembly as defined in claim 1 or 2, wherein said high voltage electric discharge produces a surface energy in the range of 30-60 ergs per square centimeter on said inner surface of said polymer film. The method for making an intermediate laminated assembly as defined in claim I or 2, whereinf said polymer film is heated by an infrared heating means. 6 44 S6. The method for making an intermediate laminated assembly as defined in claim 1 or 2, wherein said pressed together films are heated by an infrared heating means. S. The method for making an intermediate laminated assembly as defined in claim 1 or 2, wherein said polymer is togetfe fism heated gba nn ifrared hheting means.
- 7. The method for making an intermediate laminated assembly as defined in claim 1 further including the step of preheating said polymer film to remove excess moisture -23- S"mai 1 1 asemby as efind in laim1 o hrinsi hg f v f LL prior to subjecting said inner surface of said polymer film to a high voltage electric discharge.
- 8. A resultant laminated assembly formed by bonding a substrate to said intermediate substrate as defined in claim 1 or 2 or 7, said resultant assembly being formable to include formations extending outwardly of the plane of the resultant laminated assembly.
- 9. An article formed from the resultant assembly of claim 8, said article including portions extending outwardly of the plane of the resultant laminated assembly, said article including further portions that remain assuredly bonded to said intermediate assembly. An article formed from the resultant assembly of claim 8, said article including portions extending outwardly of the plane of the resultant laminated assembly, said article including further portions that remain assuredly bonded to said intermediate assembly, said article comprising a preinsulated electrical connector. Dated this 29th day of June 1989 I 44 AMP Incorporated Patent Attorneys forthe Applicant 4,46 F.B. RICE CO. 4 4 -24- 'i A
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US22617988A | 1988-07-29 | 1988-07-29 | |
US226179 | 1988-07-29 |
Publications (2)
Publication Number | Publication Date |
---|---|
AU3725089A AU3725089A (en) | 1990-02-01 |
AU615762B2 true AU615762B2 (en) | 1991-10-10 |
Family
ID=22847895
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU37250/89A Ceased AU615762B2 (en) | 1988-07-29 | 1989-06-30 | Method for laminating polymer films |
Country Status (7)
Country | Link |
---|---|
JP (1) | JP2683939B2 (en) |
KR (1) | KR940006648B1 (en) |
AR (1) | AR247997A1 (en) |
AU (1) | AU615762B2 (en) |
BR (1) | BR8903720A (en) |
IT (1) | IT1230295B (en) |
MX (1) | MX171419B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2017122797A1 (en) * | 2016-01-14 | 2017-07-20 | 日東電工株式会社 | Method for manufacturing surface-modified thermoplastic resin, method for manufacturing bonded structure, bonded structure, thermal transfer surface-modified sheet, thermoplastic resin with thermal transfer surface-modified sheet, and surface-modified thermoplastic resin |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0064219A1 (en) * | 1981-05-01 | 1982-11-10 | Erwin Kampf GmbH & Co. Maschinenfabrik | Process for laminating at least two sheets |
AU6434486A (en) * | 1985-10-25 | 1987-04-30 | Astrapak Limited | Flexible laminated structure and method of lamination |
AU584099B2 (en) * | 1984-06-25 | 1989-05-18 | Strong Plastics Limited | Improvements in or relating to laminating methods and apparatus |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4464541A (en) | 1983-03-21 | 1984-08-07 | Amp Incorporated | Flame retardant preinsulated electrical connector |
JPS6357227A (en) * | 1986-08-28 | 1988-03-11 | 日本鋼管株式会社 | Resin laminated steel plate |
-
1989
- 1989-06-30 AU AU37250/89A patent/AU615762B2/en not_active Ceased
- 1989-07-05 IT IT8921106A patent/IT1230295B/en active
- 1989-07-20 MX MX016863A patent/MX171419B/en unknown
- 1989-07-26 KR KR1019890010542A patent/KR940006648B1/en not_active IP Right Cessation
- 1989-07-26 BR BR898903720A patent/BR8903720A/en not_active IP Right Cessation
- 1989-07-28 JP JP1196428A patent/JP2683939B2/en not_active Expired - Lifetime
- 1989-07-28 AR AR89314539A patent/AR247997A1/en active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0064219A1 (en) * | 1981-05-01 | 1982-11-10 | Erwin Kampf GmbH & Co. Maschinenfabrik | Process for laminating at least two sheets |
AU584099B2 (en) * | 1984-06-25 | 1989-05-18 | Strong Plastics Limited | Improvements in or relating to laminating methods and apparatus |
AU6434486A (en) * | 1985-10-25 | 1987-04-30 | Astrapak Limited | Flexible laminated structure and method of lamination |
Also Published As
Publication number | Publication date |
---|---|
KR940006648B1 (en) | 1994-07-25 |
BR8903720A (en) | 1990-03-20 |
JPH0280229A (en) | 1990-03-20 |
IT1230295B (en) | 1991-10-18 |
MX171419B (en) | 1993-10-26 |
KR900001506A (en) | 1990-02-27 |
JP2683939B2 (en) | 1997-12-03 |
AU3725089A (en) | 1990-02-01 |
AR247997A1 (en) | 1995-05-31 |
IT8921106A0 (en) | 1989-07-05 |
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