AU599866B2 - Enhanced livingness of polymerization using silylated oxyanions - Google Patents

Enhanced livingness of polymerization using silylated oxyanions Download PDF

Info

Publication number
AU599866B2
AU599866B2 AU71123/87A AU7112387A AU599866B2 AU 599866 B2 AU599866 B2 AU 599866B2 AU 71123/87 A AU71123/87 A AU 71123/87A AU 7112387 A AU7112387 A AU 7112387A AU 599866 B2 AU599866 B2 AU 599866B2
Authority
AU
Australia
Prior art keywords
catalyst
iii
enhancement agent
mma
pka
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
AU71123/87A
Other languages
English (en)
Other versions
AU7112387A (en
Inventor
Ira Bernard Dicker
Luke Valentine Schneider
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of AU7112387A publication Critical patent/AU7112387A/en
Application granted granted Critical
Publication of AU599866B2 publication Critical patent/AU599866B2/en
Anticipated expiration legal-status Critical
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AU71123/87A 1986-04-07 1987-04-06 Enhanced livingness of polymerization using silylated oxyanions Expired AU599866B2 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US84925186A 1986-04-07 1986-04-07
US849251 1986-04-07
US015727 1987-02-27
US07/015,727 US4736003A (en) 1986-04-07 1987-02-27 Enhanced livingness of polymerization using silylated oxyanions

Publications (2)

Publication Number Publication Date
AU7112387A AU7112387A (en) 1987-10-08
AU599866B2 true AU599866B2 (en) 1990-07-26

Family

ID=26687729

Family Applications (1)

Application Number Title Priority Date Filing Date
AU71123/87A Expired AU599866B2 (en) 1986-04-07 1987-04-06 Enhanced livingness of polymerization using silylated oxyanions

Country Status (12)

Country Link
US (1) US4736003A (no)
EP (1) EP0244953B1 (no)
KR (1) KR950000036B1 (no)
AU (1) AU599866B2 (no)
BR (1) BR8701551A (no)
CA (1) CA1253284A (no)
DE (1) DE3763740D1 (no)
DK (1) DK174887A (no)
ES (1) ES2016843B3 (no)
HK (1) HK95790A (no)
NO (1) NO168307C (no)
SG (1) SG78090G (no)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4866145A (en) * 1988-04-01 1989-09-12 E. I. Du Pont De Nemours And Company Catalyst for group transfer polymerization
US4978723A (en) * 1989-03-01 1990-12-18 E. I. Du Pont De Nemours And Company Phosphonate-capped polymers
US4939211A (en) * 1989-03-01 1990-07-03 E. I. Du Pont De Nemours And Company Phosphonate-capped polymers
US5153159A (en) * 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5268439A (en) * 1991-01-02 1993-12-07 Bridgestone/Firestone, Inc. Tin containing elastomers and products having reduced hysteresis properties
US5151469A (en) * 1991-05-21 1992-09-29 Bridgestone Corporation Method of preparing elastomers having reduced hysteresis properties with sulfoxides
US5276099A (en) * 1991-12-30 1994-01-04 Bridgestone Corporation (Vinyl sulfoxide)-capped elastomers and compositions containing them having reduced hysteresis properties
US5274106A (en) * 1991-12-30 1993-12-28 Bridgestone Corporation Amino-substituted aryllithium compounds as anionic polymerization initiators
US5519086A (en) * 1991-12-30 1996-05-21 Bridgestone Corporation Low-hysteresis elastomer compositions using amino-substituted aryllithium polymerization initiators
US5238893A (en) * 1991-12-30 1993-08-24 Bridgestone Corporation Method of preparing an anionic polymerization initiator
US5244966A (en) * 1991-12-30 1993-09-14 Bridgestone Corporation 1,3,2-dioxastannolane-modified elastomers and compositions containing them having reduced hysteresis properties
US5523371A (en) * 1991-12-30 1996-06-04 Bridgestone Corporation Functionalized polymer of improved hysteresis properties prepared using amino-substituted aryllithium polymerization initiators
ES2088188T3 (es) * 1992-05-22 1996-08-01 Bridgestone Corp Neumaticos que tienen resistencia reducida a la rodadura.
US6025450A (en) * 1992-10-02 2000-02-15 Bridgestone Corporation Amine containing polymers and products therefrom
US5552473A (en) * 1992-10-02 1996-09-03 Bridgestone Corporation Functionalized polymer and rubber compositions produced from solubilized anionic polymerization initiators
US5674798A (en) * 1992-10-16 1997-10-07 Bridgestone Corporation Hydrocarbon soluble anionic polymerization initiators
US5643848A (en) * 1992-10-30 1997-07-01 Bridgestone Corporation Soluble anionic polymerization initiators and products therefrom
EP0600208B1 (en) * 1992-10-30 1997-12-29 Bridgestone Corporation Soluble anionic polymerization initiators and products therefrom
US5317057A (en) * 1992-12-30 1994-05-31 Bridgestone Corporation (Halomethyl vinyl arene)-modified elastomers and compositions containing them having reduced hysteresis properties
EP0622381B1 (en) * 1993-04-30 1998-07-29 Bridgestone Corporation Anionic polymerization initiators and reduced hysteresis products therefrom
US5491230A (en) * 1993-12-29 1996-02-13 Bridgestone Corporation Anionic polymerization initiators containing adducts of cyclic secondary amines and conjugated dienes, and products therefrom
US5502129A (en) * 1994-05-13 1996-03-26 Bridgestone Corporation Triorganotin lithium, process to prepare same and anionic polymerization initiated therewith
US5521309A (en) * 1994-12-23 1996-05-28 Bridgestone Corporation Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same
US5574109A (en) * 1995-02-01 1996-11-12 Bridgestone Corporation Aminoalkyllithium compounds containing cyclic amines and polymers therefrom
US5496940A (en) * 1995-02-01 1996-03-05 Bridgestone Corporation Alkyllithium compounds containing cyclic amines and their use in polymerization
US5785778A (en) * 1995-02-01 1998-07-28 Bridgestone Corporation Aminoalkyllithium compounds containing cyclic amines and polymers therefrom
US6080835A (en) * 1995-02-01 2000-06-27 Bridgestone Corporation Aminoalkyllithium compounds containing cyclic amines and polymers therefrom
EP1266910A4 (en) * 2000-10-12 2004-08-18 Mitsui Chemicals Inc PROCESS FOR THE PRODUCTION OF LIVING (CO) POLYMERS AND USE OF SUCH (CO) POLYMERS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US68887A (en) * 1867-09-17 Improvement in hay-bakers and loaders
US4588795A (en) * 1985-03-01 1986-05-13 E. I. Du Pont De Nemours And Company Oxyanion-catalyzed polymerization
US4622372A (en) * 1985-03-01 1986-11-11 E. I. Du Pont De Nemours And Company Polymer life enhancement in oxyanion-catalyzed polymerization

Also Published As

Publication number Publication date
DK174887A (da) 1987-10-08
EP0244953B1 (en) 1990-07-18
AU7112387A (en) 1987-10-08
KR950000036B1 (ko) 1995-01-07
CA1253284A (en) 1989-04-25
NO871442D0 (no) 1987-04-06
HK95790A (en) 1990-11-23
BR8701551A (pt) 1988-01-26
ES2016843B3 (es) 1990-12-01
EP0244953A1 (en) 1987-11-11
KR880009994A (ko) 1988-10-06
US4736003A (en) 1988-04-05
DE3763740D1 (de) 1990-08-23
NO871442L (no) 1987-10-08
SG78090G (en) 1990-11-23
NO168307B (no) 1991-10-28
NO168307C (no) 1992-02-05
DK174887D0 (da) 1987-04-06

Similar Documents

Publication Publication Date Title
AU599866B2 (en) Enhanced livingness of polymerization using silylated oxyanions
EP0184863B1 (en) Tris(dimethylamino)sulfonium bifluoride catalysts
Yasuda et al. Rare earth metal initiated polymerizations of polar and nonpolar monomers to give high molecular weight polymers with extremely narrow molecular weight distribution
US4605716A (en) Lewis base-catalyzed polymerization
US20030144441A1 (en) Controlled copolymerization of methyl acrylate with olefins under mild conditions
US6284850B1 (en) Polymerization of vinyl monomers
EP0265091A1 (en) Group transfer polymerization and initiators therefor
US6300443B1 (en) Process for preparing polymeric microgels
US4622372A (en) Polymer life enhancement in oxyanion-catalyzed polymerization
US5478886A (en) Acrylic block copolymers
US20090253878A1 (en) Branched polyolefin polymer tethered with polymerizable methacryloyl groups and process for preparing same
EP0291212A1 (en) Polymerization of acrylic esters
EP0095086B1 (en) Polymerizable, optically active polymer and process for preparing polymerizable polymer
Webster The use of group transfer polymerization for the control of polymethacrylate molecular structure
EP0266062B1 (en) Group transfer polymerization catalyzed by mercury compounds
D'Agosto et al. Side‐Product of N‐Acryloyloxysuccinimide Synthesis or Useful New Bifunctional Monomer?
US4791181A (en) Rate-moderated group transfer polymerization
Sannigrahi et al. Copolymerization of methyl methacrylate with lauryl methacrylate using group transfer polymerization
EP0194110B1 (en) Polymer life enhancement in oxyanion-catalyzed polymerization
EP0662485A2 (en) Method of controlling the polymerization of acrylates
Pugh et al. Comparison of living polymerization mechanisms. Acrylates and carbocationic polymerization
US5166286A (en) Polymers having terminal halogen atoms
US4957973A (en) Uncatalyzed process for preparing "living" polymers
Florjańczyk et al. Reactivity of vinyl monomers in the copolymerization and terpolymerization with sulfur dioxide
JPH034563B2 (no)