AU556104B2 - Preparation of 2-exo-hydroxy-7-oxabicyclo(2,2,1)heptanes, and intermediated in their syntheses - Google Patents

Preparation of 2-exo-hydroxy-7-oxabicyclo(2,2,1)heptanes, and intermediated in their syntheses

Info

Publication number
AU556104B2
AU556104B2 AU91488/82A AU9148882A AU556104B2 AU 556104 B2 AU556104 B2 AU 556104B2 AU 91488/82 A AU91488/82 A AU 91488/82A AU 9148882 A AU9148882 A AU 9148882A AU 556104 B2 AU556104 B2 AU 556104B2
Authority
AU
Australia
Prior art keywords
exo
hydroxy
heptanes
oxabicyclo
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
AU91488/82A
Other languages
English (en)
Other versions
AU9148882A (en
Inventor
George Bernson Payne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
SHELL INT RESEARCH
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHELL INT RESEARCH, Shell Internationale Research Maatschappij BV filed Critical SHELL INT RESEARCH
Publication of AU9148882A publication Critical patent/AU9148882A/en
Application granted granted Critical
Publication of AU556104B2 publication Critical patent/AU556104B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
    • C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
    • C07D493/08—Bridged systems
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
    • C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
    • C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
    • C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
    • C07C29/40—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing carbon-to-metal bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00—Thiols, sulfides, hydropolysulfides or polysulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic
    • C07C35/08—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings
    • C07C35/18—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring monocyclic containing a six-membered rings with unsaturation at least in the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C35/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a ring other than a six-membered aromatic ring
    • C07C35/48—Halogenated derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/178—Unsaturated ethers containing hydroxy or O-metal groups
    • C07C43/1781—Unsaturated ethers containing hydroxy or O-metal groups containing rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/513—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an etherified hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/14—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by free hydroxyl radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
AU91488/82A 1981-12-16 1982-12-11 Preparation of 2-exo-hydroxy-7-oxabicyclo(2,2,1)heptanes, and intermediated in their syntheses Ceased AU556104B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US33109581A 1981-12-16 1981-12-16
US331095 1981-12-16

Publications (2)

Publication Number Publication Date
AU9148882A AU9148882A (en) 1983-06-23
AU556104B2 true AU556104B2 (en) 1986-10-23

Family

ID=23292603

Family Applications (1)

Application Number Title Priority Date Filing Date
AU91488/82A Ceased AU556104B2 (en) 1981-12-16 1982-12-11 Preparation of 2-exo-hydroxy-7-oxabicyclo(2,2,1)heptanes, and intermediated in their syntheses

Country Status (18)

Country Link
EP (1) EP0081892B1 (Direct)
JP (1) JPS58110590A (Direct)
KR (1) KR880001427B1 (Direct)
AT (1) ATE25982T1 (Direct)
AU (1) AU556104B2 (Direct)
BG (1) BG38637A3 (Direct)
BR (1) BR8207274A (Direct)
CA (1) CA1255320A (Direct)
CS (1) CS248036B2 (Direct)
DD (1) DD209460A5 (Direct)
DE (1) DE3275721D1 (Direct)
DK (1) DK525982A (Direct)
ES (1) ES8405404A1 (Direct)
HU (1) HU190431B (Direct)
IE (1) IE53986B1 (Direct)
IL (1) IL67473A (Direct)
PL (1) PL139922B1 (Direct)
ZA (1) ZA829185B (Direct)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4579582A (en) * 1982-08-18 1986-04-01 Chevron Research Company 5-deoxy-3-O-arylmethyl or substituted arylmethyl-1,2-O-alkylidene-α-D-xylofuranose herbicide derivatives
GB8321713D0 (en) * 1983-08-12 1983-09-14 Shell Int Research Preparing oxabicycloalkane compounds
US4606753A (en) * 1984-06-15 1986-08-19 Shell Oil Company 4-substituted-2-oxabicyclo[2.2.1]heptane ether herbicides
US4883888A (en) * 1984-07-13 1989-11-28 The Procter & Gamble Company Oxa-fenchyl amines useful for preparing high intensity sweeteners
FR2996551B1 (fr) * 2012-10-05 2015-01-09 Mane Fils V Procede de synthese de cyclohexenones ainsi que leur utilisation en parfumerie
US9994584B2 (en) 2014-10-15 2018-06-12 Lixte Biotechnology, Inc. Process of synthesizing 3-(4-methylpiperazine-1-carbonyl)-7-oxabicyclo[2.2.1] heptane-2-carboxylic acid
US11866443B2 (en) 2017-05-19 2024-01-09 BASF Agro B.V. Method for separating optically active hydroxy cineole derivatives
EP4469543A1 (en) 2022-01-26 2024-12-04 Basf Se Compositions comprising 4-isopropyl-1-methyl-7-oxabicyclo[2.2.1]heptan-2-ol or esters or ethers thereof and their use as aroma chemicals
EP4627025A1 (en) 2022-12-02 2025-10-08 Basf Se Esters and ethers of 5-isopropyl-2-methylcyclohexan-1-ol as fragrance ingredients

Also Published As

Publication number Publication date
DK525982A (da) 1983-06-17
CA1255320A (en) 1989-06-06
BR8207274A (pt) 1983-10-18
ZA829185B (en) 1983-09-28
IL67473A (en) 1986-11-30
KR840002822A (ko) 1984-07-21
AU9148882A (en) 1983-06-23
DE3275721D1 (en) 1987-04-23
PL239510A1 (en) 1984-01-16
IE822968L (en) 1983-06-16
KR880001427B1 (ko) 1988-08-08
EP0081892B1 (en) 1987-03-18
BG38637A3 (en) 1986-01-15
DD209460A5 (de) 1984-05-09
JPS58110590A (ja) 1983-07-01
IE53986B1 (en) 1989-05-10
ATE25982T1 (de) 1987-04-15
IL67473A0 (en) 1983-05-15
ES518158A0 (es) 1984-06-01
ES8405404A1 (es) 1984-06-01
EP0081892A2 (en) 1983-06-22
CS248036B2 (en) 1987-01-15
EP0081892A3 (en) 1984-05-02
HU190431B (en) 1986-09-29
JPH0365348B2 (Direct) 1991-10-11
PL139922B1 (en) 1987-03-31

Similar Documents

Publication Publication Date Title
UA7088A1 (uk) Спосіб одержання солі 2-(2-гідроксіетоксі)етіламіна та 3,6-діхлор-2-метоксібензойної кислоти
IN176618B (Direct)
AU585216B2 (en) Process for the microbiological preparation of l-carnitine
AU9148882A (en) Preparation of 2-exo-hydroxy-7-oxabicyclo(2,2,1)heptanes, and intermediated in their syntheses
GB2152509B (en) Process for the production of l-lysine by fermentation and microorganisms for use therein
AU6740296A (en) Process for the preparation of potassium clavulanate
GR3004968T3 (Direct)
ES8506316A1 (es) Procedimiento de preparacion de1,1-dioxido del acido penicilanico por deshalogenacion de 1,1-dioxido del acido 6,6-dibromopenicilanico.
IE843217L (en) Antibiotic l 17392
HUT43644A (en) Process for producing 3-substituted-cephalosporines
AU6108586A (en) Process for the production of sorbitol by enzymatic reaction, and microorganisms suitable for the purpose
DE3572965D1 (en) Process for the production of optically active quinone derivatives
EP0073134A3 (en) Microbiological process for the preparation of hydroquinone
TW237480B (Direct)
IE821067L (en) Narasin
EP0098122A3 (en) Processes for producing l-glutamic acid and l-proline by fermentation and novel microorganism strains for use therein
AU6772887A (en) Process for producing 4-androstene-3,17-dion and 1,4- androstadiene-3,17-dion
DE3070066D1 (en) Process for the preparation of 11-alpha-hydroxy-20-alpha-hydroxymethyl-1,4-pregnadiene-3-one
PT80359B (en) (6,11-dihydro-11-oxodibenz<b,e>oxepinyl)pentanoic acids and derivatives a process and intermediates for their preparation and their use as medicaments
AU547645B2 (en) Production of l-amino acids using immobilised micro- organisms
GR3005494T3 (Direct)
PL242206A2 (en) Method of automated aerobic cultivation of microorganisms,especially of baker's yeast
PL242205A2 (en) Method of automated aerobic cultivation of microorganisms,especially of baker's yeast
GB2096992B (en) Process for producing l-glutamic acid by fermentation
AU2140488A (en) Enantio-selective process for the preparation of derivatives of hemi-caronic aldehyde of trans or cis structure and the intermediates obtained