AU500570B2 - Method for cleaning holes in resin-containing materials - Google Patents
Method for cleaning holes in resin-containing materialsInfo
- Publication number
- AU500570B2 AU500570B2 AU86328/75A AU8632875A AU500570B2 AU 500570 B2 AU500570 B2 AU 500570B2 AU 86328/75 A AU86328/75 A AU 86328/75A AU 8632875 A AU8632875 A AU 8632875A AU 500570 B2 AU500570 B2 AU 500570B2
- Authority
- AU
- Australia
- Prior art keywords
- hole
- solution
- resin
- period
- barrel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
- C23C18/22—Roughening, e.g. by etching
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/12—Chemical modification
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K3/00—Apparatus or processes for manufacturing printed circuits
- H05K3/0011—Working of insulating substrates or insulating layers
- H05K3/0055—After-treatment, e.g. cleaning or desmearing of holes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
- H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
- H05K2203/0786—Using an aqueous solution, e.g. for cleaning or during drilling of holes
- H05K2203/0793—Aqueous alkaline solution, e.g. for cleaning or etching
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2203/00—Indexing scheme relating to apparatus or processes for manufacturing printed circuits covered by H05K3/00
- H05K2203/07—Treatments involving liquids, e.g. plating, rinsing
- H05K2203/0779—Treatments involving liquids, e.g. plating, rinsing characterised by the specific liquids involved
- H05K2203/0786—Using an aqueous solution, e.g. for cleaning or during drilling of holes
- H05K2203/0796—Oxidant in aqueous solution, e.g. permanganate
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Printing Elements For Providing Electric Connections Between Printed Circuits (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Chemically Coating (AREA)
Description
FORM 4 COIYION14EAT.TH OF AUSTRALIA Patents Act 1952-69
CONVMENTION APPLICATION FOR A PAT 4 i. We, Kolimorgen Ccrporation,
of 60 Washington Street, Hartfo'd, Connecticut, United States of America, hereby apply for the grant of a Patent for an invention entitled
METHOD FOR CL-EANING HOLES IN RESIN-CONTAINING MATERIALS which is described in the accompanying complete specification. This application is a Convention Application and is based on the application numbered 521,890
for a patent or similar protection made in the United States rof America
c~ on 7 November 1974.
M, Our address for serviice i&L1CATV N ACQEPTeDA eq C C C
CC Care: Spruson Ferguson C Cb. Patent Attorneys Esso House, 127 Kent Street Sydnpy, New South Wales, Australia.
Dated this ZiA 4 day of 4f j~975~ *4* C C
Mall Offloor The Comnu Seal of Kollmorjgen Corporation war hereto a2fxJin Signature 4 z N '1pcant P. Bur# %'Ajce President ;rob
DECLARA~TION IN SUPPORT OF A CONVENTION APPLICATION FOR A PATENT OR PAIENT OF ADDITION In support of the Convention Application made for a patent for an invention entitled -*METHOD FOR CLEANING HOLES IN RESIN-CONTAINING MATERIALS!$
IRobert P. Burr
olC R.D. 3, Lloyd Lane, Lloyd Harbor, co Huntington, New York, United States of America
do solemnly and sincexely declare as follows:-
1. 1 am authorised by Kolimorgen Corporation the
*.applicant for the patent to make this decle-ration on its behalf.
The basic application as defined by Section 141
of the Act was ,made in the United States of America
*on the 7th day of November 1974 by Joseph Polichette, Edward J. Leech, John G. Branigan and Joseph P. Hammond.
3. Joseph Polichette, 9 Hitchcock Lai, South Farmingdale, Edward J. Leech, Center Island, Oyster Bay, John G. Braaigan, 10 'Hazel Drive, Smithtown, Joseph Hammond, 67-IOB 190 Lane, Fresh Meadows, all of the State of *New York, the United States ofAmrc-. AUSTRALIAN
XK/are the actual iriventor(s) of the inv- nti~hi".anri4 he facts upon which the a~-'licant is entitled to make the application are as follow,-s: The said applicant is the assignee of the actuial inventor(s).
4. The basic applicatiou refEerred to in paragrapb. 2 of this Declaration was the first application made in a Convention count'ry in respect of the invention dte subject of tk.he application.
Declared at G-k6L i ,tth is Z JN4 d ay o f 1E~l7
Signature of Declarant Robert P. Burr, Vic' President, g(11) AU-B 86328/75
(12) PATENT SPECIFICATION ABRIDGEMENT (19) AU
(21) 86328/75 500,570 (22) 5.11.75 (23) 5.11.75 (24) 7.11.-4 (31) 521890 (32) 7.11.74 (33) US 12.5,77 (44) 24.5.79 2 (51 B05D 3/10 B08B 9/02 C08J 7/12 H05K 3/00 (54) METHOD FOR CLEANING HOLES IN RESIN-CONTAINING MATERIALS (71) KOLLMORGEN CORP. (72) POLICHETTE, J. LEECH, BRANIGAN, J.G. HAMMOND, J.P. (74) SF (56) 61759/73 480398 07.6 47.7-57 47.7-77 52.8 11553/66 70,8 75.8 8622/66 410403 75,8 73.1 (57) CLAIM I. In a process for the manufactur-e of articles comprising at least one hole formed in resin-cc:itaining materials, the improvement in cleaning smears of resin froir the barrel of said hole consisting cf contacting said hole barrel with an alkaline permanganate solution having a pH of at least 13 and an elevated temperature above room temperature for a period ranging from twenty to fifty minutes.
18/4
COMMONWEAP.TH OF AUSTRALIA Form 3 PATENTS ACT 195269
0 Class int. Class Application Number Lodged
rpmplet,- Specification Lodged Accepted Published
'or Ity
:Ve at ed Art
P~ fh t -k r
XOLLK0RGN CORPORAT ION jAome of Applicant
*Address of Applicant 60 Wasbington Street, Hartford, Connecticut, 9 United States of America~
ActualIlnventors. JOSEPHi tOLICHETE, ED10ARD J LEECH, jOHW BpP.NI(~1N and JOSEPH P. HA.MMOND 66.
Address for Service Spruson Ferguson, Patent Attorneys,__Esso House, 127 K~ent Street, Sydt, ty, !New South Wales, 2000 Australia. ~-5NOV iZ
Complete Specification for the invention intitled: "METHOD FOR CLEANING HOLES IN RES IN-CONTAINING MATERIALS"
The following statenment is a full description of this invention, includjing the best rnethod of performing it known to suus r V F A? ramut" f -LXIsclosure
A method c the use of alkaline permanganate
treating solutions to remove resin timea the interior
%ialls of holes formed in resin-containing materials.
Hole-forming operations in resin-containing materials CO C often result in the smearing of the resin over the interior walls or barrels of the holes. This cesin smear is primarily attributable to the generation or utilization of temperatures exceeding the melting point of a resinous component of the material during hole-forming operations.
When holes are drilled in epoxy-impregnated fiber-
S. glase larinate materials, for example, the friction of the drill hit against the material raises the temperature of the bit. Numerically controlled drilling machines are in common use today, and they are capable of a very rapid drilling se- quence, up to 200 holes per minute. Under these conditions, drill bit temperatures of 500 to 600°F occur, and such temper- S*,
atures exceed the melting temperature of epoxy resins. The
drill tt thus picks up melted epoxy resin on its course through 1 20 the material being drilled, and upon withdrawal of the bit this melted epoxy accretion is smeared in the barrel of the
hole. While the resin smeared on the hole walls may be ignored in some applications, it is at times imperative that it be removed. Consider, for example, a hole that has been formed in a resin-containing material which includes a plural- ity of parallel planar conductors, with the hole perpendicular to, and communicating with, two or more of the parallel con- ductors. If it is desired to metallize the hole walls in or-
Q der to form a conductive path between two or more of the 'a 2
t-
conductors, the resin smear must ,1 removed from the edges of the hole through the conductors if conductive contact between
the metallized hole wall and the conductors is to be achieved.
to Plated throuch-holes as described above are useful
oO as electrical connectors between printed circuits having con-
ductors on both sides or between two or more of the various
.e planes in multilayer boards. The electrical and mechanical 00 integrity required for this function can only be attained by
insuring complete removal of resinous materials from the en-
10 tire inner circumference of the portion of the conducting lay-
*er exposed by the hole. Another instance where resin smear removal is essen- S
tial is in the formation of wire assemblies according to U.S.
o Patent No. 3,646,572 to Burr, the disclosure of which is here-
by incorporated by reference. This is also the preferred
application of the instant invention. Such wire assemblies may
include, for example, networks of fine insulated wires imbedded
in a resinous surface of a substrate. Interconnection between
these wires and other conductors may be established by, for
20 example, drilling a hole perpendicular to the wire planes of such a diameter and location that it intersects the wire, met-
allizing the barrel of the hole and the intersected tip of the
wire, and soldering a connection to the metallized hole. If
resin smears are not thoroughly removed from the hole wall and
the wire tip, poor or no electrical contact between the metal-
lized hole wall and the wire tip may result. Moreover, even
if acceptable electrical contact should be initially achieved
when an unclean hole is metallized, this contact may be lost in a later soldering operation due to expansion of the resin smear rupturing the physical contact between the metal hole
wall and the intersected wire.
Numerous methods are known for removing the resin smear. One approach is a mechanical one and involves the channeling of a dry or wet stream of abrasive particles through such holes. A similar method is the use of hydraulic pressure to force a thick slurry of abrasive material through the holes. 00 Mechanical methods generally are relatively slow and difficult C9 C"D to control. Moreover, complete smear removal is rarely assured o since good reproducibility with respect to all of the holes in a given circuit board is difficult to achieve. S
LO The more popular and reliable known methods of 6* smear removal include the use of chemicals that attack the 0 smeared resinous coating. .9
S S *SS* Concentrated sulfuric acid down to abo ut 90 percent concentration has been successfully used. Smeared resin,
which is usually less than about 0.001 inch thick, can be re- moved with about one minute's treatment with such an agent. S Unfortunately, the high sulfuric acid concentration required
5 for effective smear removal also demands extraordinary precau- tions by operators, which generally result in a slow, uneconom- S
20 icaL overall process. S S 5* 4
Concentrated chromic acid is also a known useful smear-removal agent. It is slower-acting than sulfuric acid, requiring from five to fifteen minutes for equivalent smear removal, and also requires operator caution. Special tank linings and immersion racks are also required. Increasingly
strict water quality regulations and the difficulty of dispos- ing of chromic metal residuals in an ecologically satisfactory manner also weigh against this method of smear removal. Various ratios and combinations of sulfuric and fluorine-containing acids are also useful, but these are extremely toxic, requiring specially designed equipment, fume exhaust, and so forth.
Permanganate has been suggested as a useful smear-
removal agent, as it does not require special equipment or
0 extraordinary safety precautions 'or operators and presents 04 C no ecological hazard in wast disposal. <c e It is an object of this invention to present an
effective smear-removal process utilizing permanganate.
It has been found that an effective permanganate 10 hole-cleaning process is highly time-dependent once the vari-
ables of temperature and agent concentration have baen optim-
ized.
SS S 9 An effective industrial process for the removal of
Sresin smears from hole walls includes treatment for about
twenty to about fifty minutes with an alkaline permanganate
solution, preferably at a temperature of from about 40 C to about
Figures 1 to 3 illustrate the resin-removal rate of
solutions according to the invention for various concentrations
S 20 of permanganate at 40°C. The effects of solutions at 60°C are
depicted in Figures 4 to 6 f-r various concentrations, and
Figure 7 illustrates resin-removal rates according to a known
treatment with chromic acid.
Surprisingly, we have found that at constant perman-
ganate concentration and constant temperature, the rate of
smear removal is nonlinear, When a resinous sample is first
immersed in a treatment bath according to the invention, the
amount of material removed is directly proportional to the
treatment time for an initial period. It is believed that
there then occurs, through phenomena that are not understood, a second period during which the resinous material being treated undergoes a weight gain, which is followed by still another period of weight loss. This is especially surprising in view of the fact that similar tests with a chromic acid 00 solution revealed a linear increase of smear removal with respect to time. One possible explanation for the observed 00 cycle of weight loss-weight gain-weight loss is that after an initial weight loss a crust accumulates on the initially- attacked area. Such a crust could be formed, for example, 10 of oxidation by-products resulting from the permanganate et- ching, The second period of weight loss could follow u slough- ing off of such a crust, resulting in the exposure of a fresh su-face to oxidative attack by the alkaline permanganate. We have also found that processing circuit boards to removc resin smears for times running significantly into the second weight-loss period results in inferior printed circuits and wire assembly circuit boards. It is believed that the further etching occurring in I the second weight-loss period results in a conversion of the
20 substrate from resin-rich to, for example, glass-rich where the substrate is a resin/fiberglass laminate. It is further believed that the inferior results are attributable to metal- lization occurring in glass-rich voids in overly-etched hole walls, and that upon through-hole plating, there is a wicking action along the glass strands that results in poor or unaccep- table plated through-holes. Operationally, we have noted that hole-cleaning treatment times extending significantly into the second weight- loss period have resulted in wire assembly circuit boards ex- hibiting blow-holes and gas-caps during soldering where the metallized surface was autocatalytic to electroless metal de- position, and we have noted a breakdown in insulation resis- tance in such boards where the metallized surface was seeded ia to render it catalytic to electroless metal deposition. 00 Practice of the processes of this invention also requires a balancing of the solution components to best effect desired relative etching where more than one resinous material i00 is to be etched. For example, if holes in wire assemblies are to be etched, the insulated wire may have a polyimide coat-
4. 4* ing, the base laminate may be G-10, an epoxy-glass laminate, 4
and there may be a third resinous component in the form of a
*4C resinous adhesive on the surface of the bape. Resin smeared 4 9 in holes formed in such wire assemblies will likely be a mix-
ture of all three resin components. Moreover, it would be de-
a. sirable to etch back the polyimide insulation on the wire tip
at the same time the r-sin smear is cleaned from the hole
barrel in order to insure a firm connection between the wire
tip and the metallized hole wall and avoid a simple butt joint
Su following through-hole plating. The preferred processes of
4 this invention are directed to the wire assembly herein des-
cribed. Those skilled in the art may easily adapt the perman-
ganate etchants disclosed to suit particular applications and
resin-containing compounds.
It is desirable to effect smear removal in pernan-
ganate solutions over periods of time not significantly exten-
ding into the second weight-loss portion of the etch cycle. BC
The preferred treatment times for compositions, concentrations
and temperatures disclosed are within the range of from ebet-
twenty to ahet fifty minutes, with the most preferred treat-
ment periods ranging from abou thirty to aet forty-five minutes. The smear removal rate increasea with increasing per- manganate concentration. We have found the optimum perman- ganate concentration to be that corresponding to about 60 grams/ liter potassium permanganate. CID We also found the smear removal rate to be directly proportional to the temperature of the treating solution, with
00 elev-ed temperatures from abee 400 C to ebeat 60°C yieldinq
satisfactory results. Our preferred temperature is about 600 C.
Operating smear-removal baths according to the present invent- 0 0 ion at temperatures significantly less than about 40 C gener-
S 0 ally results in an unsatisfactorily slow smear-removal rate *5 and leads to difficulty in maintaining sufficient amounts of
permanganate in solution. Temperatures significantly above *0
result in increased permanganate demand in order to main-
tain the bath composition without yielding any apparent ad-
vantages, the overall process becomes less efficient in
terms of permanganate consumption. S We further prefer the pH of the solution to be at
least abcw 13, with the preferred pH being aheem 13.4 to abeet
13.5. Sodium hydroxide is the preferred pH adjuster. All 0 If a pH of pH values herein are measured at about 25 C.
significantly less than 13 is used, the etch ratio among the
different resin components is changed and is less desirable in
the herein described wire assembly applications.
Improved smear removal is obtained by the addition
of a small amount of wetting agent, such as the fluorinated
hydrocarbon wetting agents. The most preferred species of
the latter wetting agents is FC-128, sold u der theeade-ase Fluorad by the Min\~ota Mining and Manufacturing Company, St. h~ 6 C1 8
~I
Paul, Minnesota. The foll~owing examples illustrate processes according t~j the inventio., with the solutions of Examples .1tbrough 7 resulting in pH 'values above 13. I' Example 1 An aqueous jeolution of alkaline permangar&te was formed of 20 grams/liter potassium perzaanganate, 37.5 grams' liter sodium hydroxide, and the remainder water. The solution
4~ was brought to 40 0 C and maintained constant at that temperature. e 10 Three-inch squares of epoxy-impregnated material (Norplex S. S S S S so S one-sixteenth inch thick and weighing about 17 grams were S 5 immersed in the heated solutii~n for varying lan-gths of time, .4 .9 S 5595 S resulting ia the percent weight losses indicated below as a S.
S S S function of time; Table I Sample No. Treatment Time Percent Weight Loss (minutes) (X 104) 0S
1 10 1.3 2 20 2.8 3 30 3.8 a
4 40 1.8 50 1.2 6 60
These data are plotted ILn Figure 1 and yield the smoothed curve illustrated. Example 2 T
The procedure of Example 1 was followed, excepting that the solution contained 40 grams/liter potassium, permangan- ate, and the following results obtained.
7/
Table II Sample No. Treatment Time Percent Weight Loss
7 10 2.6 1I a 20 4.7 9 30 3.9 40 3.1 11 50 4.8
a. 12 60 1.6 a a a 10 The above data are plotted in Figure 2 and yield a. a 0. a
a the depicted smoothed curve. a. *a a. a a a Example 3 a. a S a. S The procedure of Example 1 was followed, excepting a. a a a that the solution contained 60 grams/liter potassium perman- *9
ganate, with the following results:
Tablae II a. a a a a a. Sample No. Treatment Time Percent Weicht Loss a. a a.. A (minutes) (X 0.90.. a 13 10 2.9 a :~o 1.4 20 3.2 a *a a a 15 30 R*S S
16 40 4.3
17 50 4.1
18 60 4.6 The data are plottLed in Figure 3 and yield the smoothed curve illustrated. Example 4 The procedure of Example 1 was followed, excepting that the solution was maintained at a constant temperature of
60c aqd the results of Table IV obtained:
Table I V Sample No. Treatment Time Percent Weight 'joss
fminutes) (x 10 4) 19 10 3.2 20 4,4 21. 30 5.4
22 40 4.7
23 50 3.2
24 60 ~0 B B B 10 These data are plotted in Figure 4 and yield the in- ta B B b *B B dioated smoothed curve. B. OB B. 0 0 Example B. .0 B -B B. B P The procedure of Example 2 was followed, enrcept B* iB B B that the solution temperatur~e was according to Example 4: B.
Table V Sample No. Treatment Time Percent Weight Loss BE B B B (minutes) (X 10'4 B. 0 0*h a 25 10 4.8
a 26 20 6.3 B *BB* BO B 27 30 6.7 0
a p. B 2840 B
29 50 4.2 60
These results are illustrated in Figure ExamTple 6
The procedure of Example 3 was followed, except that
the solution teniparatare was according to Example 4:
il
Sample No. Treatment Time Percent Weight Loss
31. 10 5.7 32 20 6.6 0- 33 30 7.3
34 40 5.9
0035 50 7.6
te36 60 Figure 6 illustratee the plot of these data and .th smoothed curVt fitting the. ExS.e 7*
SA control bath utilizing a known hole-c.Leaning form-
::ulation of e4,hromic acid was prepared by adding 915 grams/liter cr0 3 to water. The procedure of the preceding examples was followed, with the bath being at room temperature (about 200 C). Table VII *Samuple No.. Treatment Time Percent Weight Loss
(minutes) (x iQ0 37 1.0 2.9 38 20 4.2 39 30 5.7 40 B.7 41 50 11 These data are plotted in Figure 7 and yield the straight line indicated. As demonstrated in the examples below, marked in- creases in smear-iemovai3 rates may be obtained through the addition of a wetting agent to the preferred treating solution.
The. preferred wetting agents are characterized by a stable
'i 117,V
fluorocarbon taiA*l and a solubiliving group, ~.The solubiliz- ing group can be organic or inorganilc, anionic, cationlic, nonionic, amphoteric and water soluble. The wetting agents
shou1 be active in basic solutions and have good thermal
stability. 3Especially preferred are those wherein Z is anionic. Particularly useful fluorinated hydrocarbon wetting agents of this type are a01d under the trade name Fluorad by the Minnes- ota Mining and Manufacturing Company, St. Paul, Minnesota, and include species such as Fluorad PC-95, FC-98 and PC-128, with 0 a
.0 PC-95 and FC-128 being preferred and FC-128 being most pre- ferred. It4 Example 8
.00.a An aqi~teous alkaline permanganate solution was formed 6* If
It consisting of 60 grams/liter KMnO 4 38 grams/liter NaQE, and
water. The solution was divided into seven treating b,.aths. too.*: of S
0004 Wetting agent was added and properties of the baths determined as indicated in Table VIII. Table VIII
Bath No. Wetting Agent Surface Tension Sp.Gr. pH
(grams/liter) (dynes/cm)
I none 77.5 1.060 13.40
2 .01 P0-95 58.0 It
.0 5 44.0 I 3
.1 38.5 t 4 q .2 32. 32.0
6 -1 FC-128 35.0 It 13.45
7 .2 it t 25.2 it
Y,,oxy-impregnated samples were water-blasted and
immersed with constant agitation in the above baths with the
results iThdicated in Table IX. immersion time was forty minutes
Io 7 and the baths were maintained at 60 C.
Table IX
Bath No. Percent Weight Loss
(x 103 1, 6.3
6.6
6.6
6.9
7.2 0 4 a. 0* 0
aS S 7.4 a. ~0 S a a Example 9 a *0 a S 0 The procedure of Example 8 was followed, except a. 0 S 0 that the samples were not water-blasted prior to immersion and& there was no agitation.. Table X S. a S Ba* a Bath N~o. Percent Weight Loss a. a 5*W (x 10 3 a a 1 .2 a
20 2 2.2
S. 3 3.2 a a 4 2.2
3.4
6 3.3
7 3.7
Example
Trhe procedure of Example 9 was followed, except that the samples were agitated at the beginning of the Jmmer- sion witth no further agitation.
W Table X3:
Bath No*. Percenit Weight Losn (x i0 3 4.9 4.7
5.2
cx~ 5.7 4. 7 0@ S S 5 9 10 5.8 4. V 54 55 S
*4 55 0 B 4 0 5
.5 S S S
S. B S B S .5
#5 S S 5S4 S
4 0
~S S S
Claims (1)
- The claims defining the invention are as follows: 1. In a process for the manufacture of articles com- prising at least one hole formed in resin-containing materials, the improvement in cleaning smears of resin from the barrel ofsaid hole consisting of contacting said hole barrel with analkaline permanganate solution having a pH of at least about 4 13 and an elevated temperature/for a period ranging ftom about Aa kC" twenty to about fifty minutes. 2. The process of claim 1, wherein said pH is fromabout 13.4 tr about 13.5 and said contacting period ranges to from about thirty to Lbout forty-five minutes.o3. The process of claim 2, wherein said alkaline per-manganate solution is an aqueous solution comprising potassium9 permanganate and a strong base. 4. Th.- proce ss of claim 3, wherein said aqueous sol-ution also includes a wetting agent.5. The process of claim 4, wherein said w,'tt .ng agentis a fluorinated hydrocarbon.6. In a process for -e manufacture of articles com-prising at least one hole formed in resin-containing materials,the improvement in cleaning smears of resin from the barrelof said hole consisting of contacting said hole barrel with an aqueous solution comprising from about 20 to about 60 grams/liter potassium permanganate and about 40 grams/liter sodiumhydroxide, wherein said solution is at an elevated temperatureof from about 40°C to about 60 0 C and the period of said con-tacting is from about twenty to about fifty minutes.7. The process of claim 6, wherein said solutionincludes a wetting agent.The pr'-_s 7 of claim 7, wherein said contactingt 16- period is from thirty to forty-five minutes. 9. The process of claim 8, wherein said wetting agent comprises from 0.01 to 0.2 grams/liter of a fluorinated hydrocarbon. The process of claim 9, wherein said aqueous solution comprises 60 grams/liter potassium permanganate, grams/liter sodium hydroxide and 0.2 yrams/liter 2luorin- ated hydrocarbon wetting agent and said elevated temperature is about 600 C. 11. In a process for the manufacture of articles comprising at least one nole formed in resin-containing mat- 04 erials, the improvement in cleaning smears of resin from the a barrel of said hole consisting of contacting said hole barrel with an alkaline permanganate solution having a pH of at least 13 at an elevated temperature above room temperature for a period of time sufficient to remove said smears of resin*a and essentially terminating prior to the second weight-loss period of th cleaning cycle, said period ranging from 20 to 0* 0* U a 0 50 minutes. 12. The process of claim 11, wherein said alkaline permanganate solution has a temperature of at least 400 C. 913. Ths process of claim 12, wherein said alkaline permanganate solution is an aqueous solution comprising potas- 00siwi permanganate and a strong base. 14. The process of claim 13, wherein said solution includes a wetting agent.r 15. The process of claim 14. wherein said wetting agent comprises a fluorinated hydrocarbon. 16. The process of claim 15, wherein said solutionis at a temperature of 60 0 C.*444 @440 S@ O' 0 4* 00 0* SR a 0. S *eS 0 0 3 4 0 0 *00 0 @0 0 0 a 0 0 0 0.00 900 0 '0 4 40* 03 4404 *4* 0* 0 3086,32S 8-7s least one hole formed in a wire assembly circuit board for adherent metallization by contacting the barrel of said hole with an alkaline permanganate solution having a pH of at least-bee 13 and an elevated temperature/for a period of timesufficient to remove resin smears from said barrel, with saidperiod essantiall terminating prior to the second weight-loss t^C-t- t jo yv >o -tcnO iO period of the cleaning'cycle 18. The process of claim 17, wherein said elevated o0 IO temperature is from- alemat 40 C to-ev*®.19. The process of claim 18, wherein said contactingperiod is from ab~wk thirty to -ae forty-five minutes.20. The process of claim 18, wherein said pH is fromS: abet 13.4 to aelte 13.5.21. The process of claim 20, wherein said solutionalso comprises a strong base.22. The process of claim 21, wherein said solutioncompriseA water, a-bui 60 grams/liter potassium permanganate,and 6d1t 38 grams/liter sodium hydroxide, with the temperatureof said solution being "am23. The process of claim 22, wherein said solutionincludes a wetting agent.24. The process of claim 23, wherein said wetting ag-ent is a fluorinated hydrocarbon.In a process for the formation of a wire assemblycircuit board, the improvement for insuring a good conductivejoint between the tip of an intersected wire and the vall ofa hole in said board intersecting said wire comprising thesteps:a. treating said hole according to claim 17 so as toA \simultaneously remove zesin smeared in the barrel of said holeL 6i7" 7 and etch insulation back from said intersected wire tip. and b. metallizing said hole and intersected wire tip, thereby insuring a final joint in which the intersected wire tip is firm imbedded in the metallized hole wall. 00 C-4 o DATED this FOURTH day of NOVEMBER, 197500 KOLLMORGEN CORPORATIONPatent Attorneys for the Applicant 0* SPRUSON FERGUSONe0* o* 00 0 0 6 0* 00 0099000000*0S. *9 0 00*
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US52189074A | 1974-11-07 | 1974-11-07 | |
| USUS521890 | 1974-11-07 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU8632875A AU8632875A (en) | 1977-05-12 |
| AU500570B2 true AU500570B2 (en) | 1979-05-24 |
Family
ID=24078571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU86328/75A Expired AU500570B2 (en) | 1974-11-07 | 1975-11-05 | Method for cleaning holes in resin-containing materials |
Country Status (13)
| Country | Link |
|---|---|
| JP (1) | JPS595616B2 (en) |
| AT (1) | AT346957B (en) |
| AU (1) | AU500570B2 (en) |
| CH (1) | CH619823A5 (en) |
| DE (1) | DE2550598C3 (en) |
| DK (1) | DK154600C (en) |
| ES (1) | ES442440A1 (en) |
| FR (1) | FR2290822A1 (en) |
| GB (1) | GB1479556A (en) |
| IT (1) | IT1052168B (en) |
| NL (1) | NL180684C (en) |
| SE (1) | SE447045B (en) |
| ZA (1) | ZA756783B (en) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3110415C2 (en) * | 1981-03-18 | 1983-08-18 | Ruwel-Werke Spezialfabrik für Leiterplatten GmbH, 4170 Geldern | Process for the manufacture of printed circuit boards |
| US4525247A (en) * | 1982-07-12 | 1985-06-25 | Rogers Corporation | Microwave circuit boards and method of manufacture thereof |
| US4425380A (en) | 1982-11-19 | 1984-01-10 | Kollmorgen Technologies Corporation | Hole cleaning process for printed circuit boards using permanganate and caustic treating solutions |
| US4515829A (en) * | 1983-10-14 | 1985-05-07 | Shipley Company Inc. | Through-hole plating |
| JPS60154416U (en) * | 1984-03-23 | 1985-10-15 | 三国 慶耿 | Snowplow snow chute |
| US4820548A (en) * | 1984-06-07 | 1989-04-11 | Enthone, Incorporated | Three step process for treating plastics with alkaline permanganate solutions |
| US4948630A (en) * | 1984-06-07 | 1990-08-14 | Enthone, Inc. | Three step process for treating plastics with alkaline permanganate solutions |
| US4601784A (en) * | 1985-05-31 | 1986-07-22 | Morton Thiokol, Inc. | Sodium permanganate etch baths containing a co-ion for permanganate and their use in desmearing and/or etching printed circuit boards |
| US4601783A (en) * | 1985-05-31 | 1986-07-22 | Morton Thiokol, Inc. | High concentration sodium permanganate etch batch and its use in desmearing and/or etching printed circuit boards |
| DE3806884C1 (en) * | 1988-03-03 | 1989-09-21 | Blasberg-Oberflaechentechnik Gmbh, 5650 Solingen, De | Through-plated contact printed circuit and method for fabricating it |
| US5032427A (en) * | 1988-04-25 | 1991-07-16 | Macdermid, Incorporated | Process for preparation printed circuit through-holes for metallization |
| US5213840A (en) * | 1990-05-01 | 1993-05-25 | Macdermid, Incorporated | Method for improving adhesion to polymide surfaces |
| AT1147U1 (en) * | 1996-01-10 | 1996-11-25 | Grundmann Schliesstechnik | LOCKING CYLINDER AND OR FLAT KEY |
| DE59804686D1 (en) | 1997-09-01 | 2002-08-08 | Rieter Ag Maschf | REGULATED STRETCHER |
| JP5330474B2 (en) * | 2011-09-22 | 2013-10-30 | 上村工業株式会社 | Desmear liquid and desmear treatment method |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3276927A (en) * | 1963-07-01 | 1966-10-04 | North American Aviation Inc | Smoothing of mechanically drilled holes |
| US3276106A (en) * | 1963-07-01 | 1966-10-04 | North American Aviation Inc | Preparation of multilayer boards for electrical connections between layers |
| US3652351A (en) * | 1970-05-13 | 1972-03-28 | Carus Corp | Processes for etching synthetic polymer resins with alkaline alkali metal manganate solutions |
| GB1401600A (en) * | 1972-12-13 | 1975-07-16 | Kollmorgen Corp | Composition and process for the activation of resinous bodies for adherent metallization |
| DE2316720A1 (en) * | 1973-04-04 | 1974-10-31 | Licentia Gmbh | Removal of colophony residues from electrical appts. - by agent contg. alcohols, hydrocarbon and wetting agent |
-
1975
- 1975-10-28 DK DK485175A patent/DK154600C/en not_active IP Right Cessation
- 1975-10-28 ZA ZA00756783A patent/ZA756783B/en unknown
- 1975-11-04 SE SE7512335A patent/SE447045B/en not_active IP Right Cessation
- 1975-11-05 JP JP50133932A patent/JPS595616B2/en not_active Expired
- 1975-11-05 NL NLAANVRAGE7512992,A patent/NL180684C/en not_active IP Right Cessation
- 1975-11-05 GB GB45878/75A patent/GB1479556A/en not_active Expired
- 1975-11-05 AU AU86328/75A patent/AU500570B2/en not_active Expired
- 1975-11-06 AT AT845775A patent/AT346957B/en not_active IP Right Cessation
- 1975-11-06 CH CH1435375A patent/CH619823A5/en not_active IP Right Cessation
- 1975-11-07 FR FR7534080A patent/FR2290822A1/en active Granted
- 1975-11-07 IT IT52113/75A patent/IT1052168B/en active
- 1975-11-07 ES ES442440A patent/ES442440A1/en not_active Expired
- 1975-11-07 DE DE752550598A patent/DE2550598C3/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS595616B2 (en) | 1984-02-06 |
| DK485175A (en) | 1976-05-08 |
| SE7512335L (en) | 1976-05-10 |
| NL7512992A (en) | 1976-05-11 |
| ATA845775A (en) | 1978-04-15 |
| DE2550598C3 (en) | 1979-03-08 |
| DE2550598B2 (en) | 1978-07-13 |
| NL180684B (en) | 1986-11-03 |
| AT346957B (en) | 1978-12-11 |
| NL180684C (en) | 1987-04-01 |
| IT1052168B (en) | 1981-06-20 |
| CH619823A5 (en) | 1980-10-15 |
| DK154600B (en) | 1988-11-28 |
| SE447045B (en) | 1986-10-20 |
| ZA756783B (en) | 1976-10-27 |
| JPS5170268A (en) | 1976-06-17 |
| ES442440A1 (en) | 1977-04-01 |
| DE2550598A1 (en) | 1976-05-13 |
| DK154600C (en) | 1989-04-17 |
| AU8632875A (en) | 1977-05-12 |
| FR2290822A1 (en) | 1976-06-04 |
| FR2290822B1 (en) | 1978-05-12 |
| GB1479556A (en) | 1977-07-13 |
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