AU2746584A - Substituted phenothiazine and lewis acid catalyst system - Google Patents

Substituted phenothiazine and lewis acid catalyst system

Info

Publication number
AU2746584A
AU2746584A AU27465/84A AU2746584A AU2746584A AU 2746584 A AU2746584 A AU 2746584A AU 27465/84 A AU27465/84 A AU 27465/84A AU 2746584 A AU2746584 A AU 2746584A AU 2746584 A AU2746584 A AU 2746584A
Authority
AU
Australia
Prior art keywords
catalyst system
acid catalyst
lewis acid
substituted phenothiazine
phenothiazine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
AU27465/84A
Other versions
AU560949B2 (en
Inventor
Raymond Commandeur
Bernard Gurtner
Henry Mathais
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arkema France SA
Original Assignee
Atochem SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Atochem SA filed Critical Atochem SA
Publication of AU2746584A publication Critical patent/AU2746584A/en
Application granted granted Critical
Publication of AU560949B2 publication Critical patent/AU560949B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0218—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B01J31/30—Halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/36—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of vanadium, niobium or tantalum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • C07C17/12—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms in the ring of aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C205/00—Compounds containing nitro groups bound to a carbon skeleton
    • C07C205/07—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms
    • C07C205/11—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings
    • C07C205/12—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by halogen atoms having nitro groups bound to carbon atoms of six-membered aromatic rings the six-membered aromatic ring or a condensed ring system containing that ring being substituted by halogen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
    • B01J2231/4277—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AU27465/84A 1983-04-29 1984-04-27 Substituted phenothiazine and lewis acid catalyst system Ceased AU560949B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8307117 1983-04-29
FR8307117A FR2545004B1 (en) 1983-04-29 1983-04-29 DERIVATIVE N SUBSTITUTED FOR PHENOTHIAZINE AS CHLORINATION CATALYST ON THE CORE OF AROMATIC HYDROCARBONS

Publications (2)

Publication Number Publication Date
AU2746584A true AU2746584A (en) 1984-11-01
AU560949B2 AU560949B2 (en) 1987-04-30

Family

ID=9288384

Family Applications (1)

Application Number Title Priority Date Filing Date
AU27465/84A Ceased AU560949B2 (en) 1983-04-29 1984-04-27 Substituted phenothiazine and lewis acid catalyst system

Country Status (8)

Country Link
EP (1) EP0126669B1 (en)
JP (1) JPS59206051A (en)
AU (1) AU560949B2 (en)
BR (1) BR8401964A (en)
CA (1) CA1231332A (en)
DE (1) DE3460547D1 (en)
ES (1) ES8504483A1 (en)
FR (1) FR2545004B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106008143A (en) * 2016-04-25 2016-10-12 江苏扬农化工集团有限公司 Method for preparing dichlorobenzene and trichlorobenzene and increasing para-ortho ratio

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3718060A1 (en) * 1987-05-28 1988-12-08 Bayer Ag METHOD FOR THE NUCLEAR CHLORINATION OF AROMATIC HYDROCARBONS
US4925994A (en) * 1988-05-06 1990-05-15 Bayer Aktiengesellschaft Process for the ring chlorination of aromatic hydrocarbons
DE58901634D1 (en) * 1988-11-05 1992-07-16 Bayer Ag METHOD FOR THE NUCLEAR CHLORINATION OF AROMATIC HYDROCARBONS.
DE4028269A1 (en) * 1990-09-06 1992-03-12 Bayer Ag METHOD FOR PRODUCING DICHLORBENZOL WITH INCREASED P-RATE
DE4110051A1 (en) * 1991-03-27 1992-10-01 Bayer Ag PROCESS FOR THE PREPARATION OF P-DICHLOROBENZOLE
DE4445548A1 (en) * 1994-12-20 1996-06-27 Bayer Ag Process for the preparation of 3-fluoro-4,6-dichlorotoluene
US6222079B1 (en) 1999-10-28 2001-04-24 Occidental Chemical Corporation Method of increasing certain isomeric ratios in chlorinating substituted benzenes
DE10039722A1 (en) * 2000-08-14 2002-02-28 Bayer Ag Process for the core chlorination of ortho-xylene
JP4171627B2 (en) * 2002-09-04 2008-10-22 株式会社クレハ Method for producing p-dichlorobenzene
DE10242224A1 (en) 2002-09-12 2004-03-25 Clariant Gmbh Process for the core chlorination of ortho-xylene
DE10242223A1 (en) 2002-09-12 2004-03-25 Clariant Gmbh Process for the hydrodechlorination of nuclear chlorinated ortho-xylenes
US7012166B2 (en) * 2003-03-18 2006-03-14 General Electric Company Catalyst composition and method for chlorinating aromatic compounds
US7282615B2 (en) * 2004-06-16 2007-10-16 Sabic Innovative Plastics, Ip Bv Catalyst compositions and their use for chlorinating aromatic compounds
US7863209B2 (en) * 2004-06-16 2011-01-04 Sabic Innovative Plastics Ip B.V. Methods for recycling catalyst compositions for aromatic ring halogenation
US7763760B2 (en) 2004-06-16 2010-07-27 Sabic Innovative Plastics Ip B.V. Catalyst composition and method for halogenating aromatic compounds
JP5375024B2 (en) * 2008-10-24 2013-12-25 東ソー株式会社 Method for producing paradichlorobenzene
WO2010047392A1 (en) 2008-10-24 2010-04-29 東ソー株式会社 PROCESS FOR PRODUCING p-DICHLOROBENZENE
PL442737A1 (en) 2022-11-04 2024-05-06 Pcc Rokita Spółka Akcyjna Method for selective preparation of paradichlorobenzene with improved recovery of the catalytic system

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB873066A (en) * 1959-03-25 1961-07-19 Shell Res Ltd The preparation of phenothiazine derivatives
US3226447A (en) * 1960-12-22 1965-12-28 Union Carbide Australia Directed nuclear substitution-chlorination of aromatic hydrocarbons and halogenated aromatic hydrocarbons
FR2081989A5 (en) * 1969-11-24 1971-12-10 Inst Francais Du Petrole
CA1075221A (en) * 1975-06-16 1980-04-08 Ashley D. Bye Transition metal compound
US4024198A (en) * 1975-08-01 1977-05-17 Hooker Chemicals & Plastics Corporation Process for the chlorination of toluene
US4031142A (en) * 1975-08-01 1977-06-21 Hooker Chemicals & Plastics Corporation Process for the directed chlorination of alkylbenzenes
US4289916A (en) * 1979-06-28 1981-09-15 Ihara Chemical Industry Co., Ltd. Process for producing p-chloroalkylbenzene

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106008143A (en) * 2016-04-25 2016-10-12 江苏扬农化工集团有限公司 Method for preparing dichlorobenzene and trichlorobenzene and increasing para-ortho ratio

Also Published As

Publication number Publication date
ES531973A0 (en) 1985-04-16
ES8504483A1 (en) 1985-04-16
EP0126669B1 (en) 1986-08-27
AU560949B2 (en) 1987-04-30
JPH0425065B2 (en) 1992-04-28
BR8401964A (en) 1984-12-04
FR2545004A1 (en) 1984-11-02
JPS59206051A (en) 1984-11-21
EP0126669A1 (en) 1984-11-28
FR2545004B1 (en) 1987-04-17
CA1231332A (en) 1988-01-12
DE3460547D1 (en) 1986-10-02

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