AU2020103173A4 - Apparatus and method for generating electricity and producing carbon and heat via biomass fixed bed gasification - Google Patents
Apparatus and method for generating electricity and producing carbon and heat via biomass fixed bed gasification Download PDFInfo
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- 238000002309 gasification Methods 0.000 title claims abstract description 80
- 239000002028 Biomass Substances 0.000 title claims abstract description 70
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 62
- 230000005611 electricity Effects 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000007789 gas Substances 0.000 claims abstract description 90
- 238000002485 combustion reaction Methods 0.000 claims abstract description 79
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 230000000694 effects Effects 0.000 claims abstract description 3
- 238000005338 heat storage Methods 0.000 claims description 39
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 12
- 239000003546 flue gas Substances 0.000 claims description 12
- 239000003245 coal Substances 0.000 claims description 11
- 238000010438 heat treatment Methods 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 7
- 230000002093 peripheral effect Effects 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011449 brick Substances 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims description 3
- 239000010431 corundum Substances 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 claims 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract description 30
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 239000002918 waste heat Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 description 14
- 238000010248 power generation Methods 0.000 description 7
- 239000003638 chemical reducing agent Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 235000021168 barbecue Nutrition 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K23/00—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids
- F01K23/02—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled
- F01K23/06—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle
- F01K23/067—Plants characterised by more than one engine delivering power external to the plant, the engines being driven by different fluids the engine cycles being thermally coupled combustion heat from one cycle heating the fluid in another cycle the combustion heat coming from a gasification or pyrolysis process, e.g. coal gasification
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/86—Other features combined with waste-heat boilers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
- F22B1/1838—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
- F22B1/1846—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations the hot gas being loaded with particles, e.g. waste heat boilers after a coal gasification plant
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G5/00—Incineration of waste; Incinerator constructions; Details, accessories or control therefor
- F23G5/02—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
- F23G5/027—Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K3/00—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein
- F01K3/18—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters
- F01K3/185—Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein having heaters using waste heat from outside the plant
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2201/00—Pretreatment
- F23G2201/40—Gasification
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2203/00—Furnace arrangements
- F23G2203/40—Stationary bed furnace
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23G—CREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
- F23G2206/00—Waste heat recuperation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/12—Heat utilisation in combustion or incineration of waste
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Sustainable Development (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
A method and apparatus for generating electricity and producing carbon and heat
via biomass fixed bed gasification, said method and apparatus utilising medium
calorific value combustible gas to satisfy high-temperature high-pressure boiler
heat requirements, and increasing overall electricity generation efficiency. The
method and apparatus have low nitrogen oxides amounts, satisfy environmental
protection requirements, and do not require denitrification treatment. The method
comprises the following steps: feeding a biomass raw material into a gasification
apparatus to prepare a medium calorific value biomass combustible gas, and
performing gasification on the biomass raw material at 700-850°C under the
effect of an air/water vapour pre-mixed gasification agent to produce a
combustible gas, the calorific value of the combustible gas being 1600-1800kcal,
the temperature being 200-300°C; directly feeding the combustible gas into an
environmentally friendly combustion chamber for combustion, and then into a
high-temperature high-pressure boiler, the gas combusting within the high
temperature high-pressure boiler to produce high-temperature high-pressure
steam, which drives a steam turbine to generate electricity; utilising steam waste
heat discharged by the steam turbine; using boiler tail gas to heat air by means of
an air preheater, the hot air being respectively fed into the combustion chamber
and the gasification apparatus by means of an air blower, and utilising the waste
heat.
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Description
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[01] The invention relates to a method and apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, belonging to the field of biomass energy.
[02] Under the dual pressures of energy and environment, vigorously developing clean renewable energy has become a very urgent global issue facing governments around the world. Comparing with other new energy sources, biomass energy has the characteristics of being renewable, less polluting, and transportable and storage, and most compatible with the current energy industry, therefore, it is particularly concerned. China is a large agricultural country with abundant resources, large quantities and diverse varieties of agricultural and forestry resources. In the context of favorable policies, the utilization of biomass resources has achieved considerable development in China, but at the same time it has produced many problems in technology and equipment.
[03] As a method of thermo chemical conversion in the utilization of biomass resources, biomass gasification has been studied in many universities in China. People have successively developed many gasification power generation processes and equipment.
[04] Throughout the current biomass resource utilization gasification power generation process and equipment , there are the following problems: single product, low economic efficiency; the use of wet purification system causes water pollution; due to incomplete purification, the stability of the internal combustion engine and gas turbine power generation system is poor. The Nanjing Forestry University team proposed a multi-generation process for biomass gasification hot gas-fired boiler to drive steam turbine power generation. It has achieved staged success, but it also encountered two major problems:
[05] 1) for biomass gasification gas combustion, although the exhaust gas produces low levels of nitrogen oxide content, due to the increasing environmental requirements, it is bound to require exhaust gas gentrification treatment which is expensive, and small-scale industrial projects are not suitable for use;
[06] 2) the calorific value of combustible gas produced by biomass gasification is low, and it is not suitable for use in high-temperature high-pressure boiler, which affects the overall efficiency of power generation. Therefore, it is necessary to propose a new process to solve the problem of calorific value and combustible gas environmentally friendly combustion.
[07] The present invention provides a method for generating electricity and producing carbon and heat via biomass fixed bed gasification, the purpose of which is to solve the above defects existing in the prior art, and generate a medium calorific value combustible gas, which satisfies the high-temperature high-pressure boiler heat requirements, and increasing overall electricity generation efficiency; after adopting the method, the nitrogen oxide content is low, satisfy environmental protection requirements, and do not require gentrification treatment.
[08] A method for generating electricity and producing carbon and heat via biomass fixed bed gasification according to the present invention comprises the following steps:
[09] 1) feeding a biomass raw material into a gasification apparatus to prepare a medium calorific value biomass combustible gas, and performing gasification on the biomass raw material at 700-850°C under the effect of an air/water vapour pre-mixed gasification agent to produce a combustible gas, the calorific value of the combustible gas being 1600-1800kcal, the temperature being 200-300°C;
[010] 2) directly feeding the combustible gas into an environmentally friendly combustion chamber for combustion, and then into a high-temperature high-pressure boiler, the gas combusting within the high-temperature high-pressure boiler to produce high-temperature high-pressure steam, which drives a steam turbine to generate electricity; utilizing steam remaining heat discharged by the steam turbine;
[011] 3) collecting carbon discharged from the gasification apparatus after cooling;
[012] 4) using boiler exhaust gas to heat air by means of an air preheater, the hot air being respectively fed into the combustion chamber and the gasification apparatus by means of an air blower, and utilizing the remaining heat.
[013] The above-mentioned method for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the low temperature water generated by the steam turbine is used for replenish to the boiler after heat exchanged with the boiler exhaust gas in the economizer 500.
[014] The present invention also provides an apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification which can generate a medium calorific value combustible gas, satisfy the high-temperature high-pressure boiler heat requirements, and increasing overall electricity generation efficiency, and do not require gentrification treatment.
[015] An apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to the present invention comprises a gasification apparatus 200 for preparing a medium calorific value biomass combustible gas, a stable and environmentally friendly combustion chamber for stable combustion for biomass gasification combustible gas 300, a high-temperature high-pressure boiler 400, an air preheater 600, a flue gas exhaust fan 700, a steam turbine 900, and a generator; the combustible gas outlet in the gasification apparatus 200 communicates with the combustion pipe in the environmentally friendly combustion chamber 300, and the outlet high-temperature flue gas pipe in the environmentally friendly combustion chamber 300 communicates with the gas inlet in the high-temperature high-pressure boiler 400; the steam outlet in the high-temperature high-pressure boiler 400 communicates with the steam inlet in the steam turbine 900; the exhaust pipe of the high-temperature high-pressure boiler 400 communicates with the shell path of the air preheater 600 ,after the air preheating pipe passes through the pipe path of the air preheater 600,it is respectively communicated with the combustion pipe and the gasification apparatus.
[016] The above-mentioned apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the low temperature water outlet in the steam turbine 900 through the coal economizer 500 communicates with the filling port of 400 in the high-temperature high-pressure boiler; the exhaust pipe in the high-temperature high-pressure boiler 400 is in turn communicates with the coal economizer 500 and the air preheater 600.
[017] The above-mentioned apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the gasification apparatus 200 for preparing a medium calorific value biomass combustible gas comprises a gasifier and a steam generating air intake system; a closed feed device 2 is arranged in the upper portion of the gasifier, a spiral discharge air distribution device 5 is arranged at the bottom of the gasifier, and a screw shaft 29 rotating in the spiral discharge air distribution device 5 is a hollow shaft having a spiral blade on the outer circumference, and an air outlet for communicating the inside of the hollow shaft with the inside of the gasifier is uniformly disposed on the hollow shaft; the steam generating air intake system includes a skirt drum 11, a circulating heat pump 12, and a heating tube sheet 4 disposed at the gasifier, a mixer 13, a fan 17 and a valve; the outlet of the heating tube sheet 4 is connected to the water intake of the steam drum 9 through the circulating heat pump 12; the steam outlet 7 of the steam drum is connected to the inlet of the mixer 13 via the valve 15; the outlet of the fan 17 is connected to the inlet of the mixer 13 via the valve 14; the outlet of the mixer 13 is connected to the end of the screw shaft 29 through the rotaryjoint 30; the inlet of the fan 17 is connected to the air outlet of the air preheater 600.
[018] The above-mentioned apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the spiral discharge air distribution device 5 comprises a plurality of parallel trapezoidal carbon trough 28 passing through the bottom of the gasifier, each trapezoidal carbon trough 28 is provided with a rotating screw shaft 29; the end of each trapezoidal carbon trough 28 extending outside the gasifier is connected to a carbon warehouse 26; a rotating secondary carbon spiral 27 is placed in the carbon warehouse 26.
[019] The above-mentioned apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the environmentally friendly combustion chamber 300 is divided into a first stage cavity and a second stage cavity body 48 through a honeycomb shaped heat storage body 46; a combustion pipe 41 is connected to a biomass gas inlet and a primary air distribution pipe 54 the combustion pipe 41 is connected to the first stage cavity body 45, and an ignition gun 42 and a thermocouple TI are arranged on the first stage cavity body 45, a secondary air distribution pipe 47, opposite to the honeycomb-shaped heat storage body 46, and a thermocouple T2 are arranged within the second stage cavity body 48 and the second stage cavity body 48 is connected to the outlet high-temperature flue gas pipe 51, the primary air distribution pipe 54, a primary air volume adjustment valve 52, the secondary air distribution pipe 47 and a secondary air volume adjustment valve 53 are connected to a air supply fan 49,and a controller 50 is connected to the thermocouple TI, the thermocouple T2, the primary air volume adjustment valve 52, the secondary air volume adjustment valve 53, and the air supply fan 49, the inlet of the blower 49 is connected to the air outlet of the air preheater 600.
[020] The above-mentioned apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the distance between the honeycomb-shaped heat storage body 46 and the end of the inlet combustion pipe 41 is 1.1-1.3 times of the length of the combustion flame, the heat storage body is coaxial with the combustion pipe, the middle portion of the heat storage body has a non-opening area that is as large as the cross-sectional area of the combustion pipe, the peripheral portion of the heat storage body is opened a through hole, the flow area of the through hole is 40-50% of the cross-sectional area of the peripheral portion of the heat storage body, the material of the heat storage body is zirconium corundum brick or magnesia chrome brick.
[021] The above-mentioned apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, wherein the primary air volume entering the combustion pipe through the primary air distribution pipe (54) is about % of the required air volume of the combustible gas; the secondary air volume entering the second stage cavity body through the secondary air distribution pipe is 10% of the required air volume of the combustible gas; the temperature of the first stage cavity body is below 1000°C.
[022] The present invention has the following beneficial effects: the present invention collects and shaves the biomass raw material to 3-5cm, and then is sent into the gasification apparatus using a medium calorific value biomass combustible gas under the action of the leather conveyor or hoister. The hot gas produced by the gasification is sent into the high-temperature high-pressure boiler after being burned through the stable and environmentally friendly combustion chamber, the gas is burned in the high-temperature high-pressure boiler to generate high-temperature high pressure steam, so that drive the steam turbine to generate electricity, and the steam turbine exhausts the remaining heat of the steam for heating, and after cooling and collecting the carbon discharged from the bottom of the gasification apparatus, according to different biomass materials, it can be used to make barbecue carbon, carbon-based fertilizer, activated carbon and the like.
[023] The boiler exhaust gas is heated by the air preheater, and the hot air is sent into the combustion chamber and the gasification apparatus by the drum fan, and the remaining heat is utilized.
[024] 1) No external heat is required to increase the calorific value of the combustible gas, satisfying the heat demand of the high-temperature high-pressure boiler, and improving the power generation efficiency.
[025] 2) Using the environmentally friendly combustion chamber to ensure complete combustion under the fluctuation of the calorific value of the gas, stable operation and reduce the nitrogen oxide content generation, which is more environmentally friendly.
[026] 3) Diversifying the product and fully utilizing the exhaust gas preheating.
[027] Fig. 1 is a flow chart of generating electricity and producing carbon and heat via biomass fixed bed gasification;
[028] Fig. 2 is the gasification apparatus for preparing medium calorific value biomass combustible gas;
[029] Fig. 3 is a schematic diagram of the closed feed device;
[030] Fig. 4 is a front view of the spiral discharge air distribution device;
[031] Fig. 5 is a top view of the spiral discharge air distribution device;
[032] Fig. 6 is a side view of the spiral discharge air distribution device;
[033] Fig. 7 is a schematic view of the structure of the stable and environmentally friendly combustion chamber for biomass gasification combustible gas;
[034] Fig. 8 is a schematic diagram of the heat storage body;
[035] Fig. 9 is a schematic diagram of another heat storage body;
[036] Fig. 10 is a schematic diagram of the secondary air distribution pipe;
[037] Fig. 11 is a left side view of Fig. 10;
[038] Fig. 12 is a partial enlarged view of Fig. 11;
[039] Reference number in drawings are as follows in sequence:
[040] In the drawings, 100 is a biomass pretreatment device, 200 is a gasification apparatus for preparing a medium calorific value biomass combustible gas, 300 is a stable and environmentally friendly combustion chamber for biomass gasification combustible gas, 400 is a high-temperature high-pressure boiler, 500 is a coal economizer, 600 is an air preheater, 700 is a flue gas exhaust fan, 800 is an exhaust, 900 is a steam turbine, and 1000 is a generator.
[041] 1 is a reducer-driven rotating spreader, 2 is a closed feed device, 3 is a combustible gas outlet, 4 is a heating tube sheet, 5 is a spiral discharge air distribution device, 6 is a bridge breaking device, 7 is a steam outlet, 8 is a filling port, 9 is a water inlet, 10 is a water outlet, 11 is a spark drum, 12 is a circulating heat pump, 13 is a mixer, 14 is a first valve, 15 is a second valve, 16 is a third valve, 17 is a fan.
[042] 18 is a hopper, 19 is a first knife valve, 20 is a feeding device level gauge, 21 is an intermediate transition silo, 22 is a second knife valve, and 23 is a feeding spiral.
[043] 24 is a carbon spiral blade within boiler, 25 is a reducer, 26 is a carbon warehouse, 27 is a secondary carbon spiral, 28 is a trapezoidal carbon trough, 29 is a screw shaft, 30 is rotaryjoint, 31 is mixed gasification agent inlet, 32 is a level gauge.
[044] 41 is a combustion pipe, 42 is an igniter, 43 is a fire door, 45 is a first stage cavity body, 46 is a heat storage body, 461 is an intermediate portion of the heat storage body, and 462 is a peripheral portion of the heat storage body (open area) , 463 is through hole; 47 is a secondary air distribution pipe, 471 is a secondary air distribution pipe air outlet, 48 is a second stage cavity body, 49 is a blower, 50 is a controller, 51 is an outlet high-temperature flue gas pipe, 52 is a primary air volume adjustment valve, 53 is a secondary air volume adjustment valve, 54 is a primary air distribution pipe.
[045] Referring to the apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification shown in Fig. 1, the combustible gas outlet in the gasification apparatus 200 communicates with the combustion pipe in the environmentally friendly combustion chamber 300, and the outlet high-temperature flue gas pipe in the environmentally friendly combustion chamber 300 communicates with the gas inlet in the high-temperature high-pressure boiler 400; the steam outlet in the high-temperature high-pressure boiler 400 communicates with the steam inlet in the steam turbine 900; the exhaust pipe in the high-temperature high-pressure boiler 400 is in turn communicates with the shell path of the coal economizer 500 and the air preheater 600. After the air preheating pipe passes through the pipe path of the air preheater 600, it is respectively connected to the inlet of the fan 17 in the gasification apparatus 200 and the inlet of the blower 49 in the environmentally friendly combustion chamber 300, so that the hot air is sent into the combustion pipe and the gasification apparatus. The low temperature water outlet in the steam turbine 900 through the coal economizer 500 communicates with the filling port of the high-temperature high pressure boiler 400. The steam turbine 900 drives the generator 1000 to generate electricity.
[046] Referring to the gasification apparatus for preparing a medium calorific value biomass combustible gas shown in Fig. 2, the upper portion of the gasifier is provided with a reducer-driven rotating spreader 1 for flattening the gasification raw material from the closed feed device 2, and the closed feed device 2 according to the level gauge 32 disposed on the gasifier body controls the feeding thereof, and the heating tube sheet 4 is disposed on the boiler wall 300mm above the spiral discharge air distribution device 5, and a bridge breaking device 6 is disposed at the lower portion of the boiler body to prevent bridging of the reaction layer.
[047] The steam generating air intake system is composed of a steam drum 11, a circulating heat pump 12, a mixer 13, a valve, a fan 17, and the like. The steam drum 11 is provided with a filling port 8, a water inlet 9, a water outlet 10, and a water vapor outlet 7. The outlet of the heating tube sheet 4 is connected to the steam drum water inlet 9 through a circulating heat pump 12, the water vapor outlet 7 of the steam drum 11 is connected to the mixer 13 through the second valve 15, the outlet of the fan 17 providing the gasifying agent is connected to the mixer 13 through the first valve 14 and the outlet of the mixer 13 is connected to the screw shaft 29 through the rotary joint , and the mixer 13 realizes the mixing of the air with the water vapor generated by the heat in the reaction zone of the gasifier, and uniformly passes them into the reaction zone through the screw shaft 29.
[048] According the closed feed device shown in Fig. 3, including a hopper 18, a intermediate transition silo 21, a bottom silo, a feeding spiral 23, and so on. The first knife valve 19 is disposed between the hopper 18 and the intermediate transition silo 21, and the second knife valve 22 is disposed between the intermediate transition silo 21 and the bottom silo, and the lower portion of the bottom silo is arranged extending into the feeding spiral 23 within the gasifier. The raw material first enters the hopper 18, and then opens the first knife valve 19, the raw material enters the intermediate transition silo 21, closes the first knife valve 19, opens the second knife valve 22, and the raw material enters the bottom silo. Then turn on the feeding spiral 23 and the raw material enters the gasifier while the second knife valve 22 is closed, thereby achieving the closed feed.
[049] The spiral discharge air distribution device 5 is used to achieve uniform gas distribution in addition to carbon. Referring to the schematic diagram of the spiral discharge air distribution device shown in Figs. 4-6, it consists of a carbon spiral blade within boiler 24, a reducer 25, a carbon warehouse 26, a secondary carbon spiral 27, a trapezoidal carbon trough 28, and a rotary joint 30. The reducer 25 drives the screw shaft 29 with the carbon spiral blade within boiler 24 to rotate the carbon, the carbon warehouse 26 is connected to the two ends of the trapezoidal carbon trough 28, and the carbon warehouse 26 is connected to the secondary carbon spiral 27. On the screw shaft tube 29 of the carbon spiral blade within boiler 24, an air outlet for the air distribution is evenly distributed for uniformly distributing the gasifying agent into the boiler.
[050] The advantages of the gasification apparatus for preparing a medium calorific value biomass combustible gas are that the valve is connected to the mixer, and the outlet of the fan providing the gasifying agent is connected to the valve and the mixer, and the mixer outlet is connected to the intermediate shaft of the discharging screw, so that realizes the mixing of the air with the water vapor generated by the heat in the reaction zone of the gasifier, and uniformly passes them into the reaction.
[051] In the spiral discharge air distribution device, the screw shaft, which is a hollow shaft, uniformly arranges the air outlets, realizes a dual-purpose machine, uniformly distributes the air while uniformly discharging, and preheats the gasifying agent.
[052] It is simple and convenient to arrange the tube sheet in the reaction zone and use the heat of the reaction zone to obtain water vapor.
[053] The pre-mixing system of air and water vapor outside the boiler ensures that the water vapor reaction can provide sufficient heat without causing a drop in the reaction temperature and ensure stable gasification.
[054] Referring to Fig. 7, a stable and environmentally friendly combustion chamber for biomass gasification combustible gas comprising: a combustion pipe 41 is connected to a biomass gas inlet and a primary air distribution pipe 54; the combustion pipe 41 is connected to a primary chamber body 45. The first stage cavity body 45 is provided with an ignition gun 42, a fire door 43, and a thermocouple TI. The rear end of the first stage cavity body is connected to the honeycomb-shaped heat storage body 46, and the rear side of the honeycomb-shaped heat storage body 46 is connected to the second stage cavity body 48, the second stage cavity body 48 (the rear side of the honeycomb-shaped heat storage body 46) is provided with a secondary air distribution pipe 47, a thermocouple T2, the second stage cavity body 48 is connected to the outlet high-temperature flue gas pipe 51, the primary air distribution pipe 54 is connected to the air blower 49 through the primary air volume adjustment valve 52 and the secondary air distribution pipe 47 is connected to the air blower 49 through the secondary air volume adjustment valve 53, and the controller 50 is connected to the thermocouple T1, the thermocouple T2, the primary air volume adjustment valve 52, the secondary air volume adjustment valve 53, the air supply fan 49, a pressure transmitter P1, and a pressure transmitter P2, thereby formed a combustion chamber.
[055] The function of the controller 50 is that:
[056] 1) controlling the primary air volume to be about 90% of the required air volume of the combustible gas, the secondary air volume is about 10% of the required air volume of the combustible gas; and
[057] 2) the temperature of the first stage cavity body is controlled at1000°C, the controller obtains the overheat temperature signal from the thermocouple TI, adjusting the primary air volume adjustment valve 52 and the secondary air volume adjustment valve 53 to reduce the primary air volume and simultaneously increase the secondary air volume.
[058] Referring to the heat storage bodies shown in Figs. 8 and 9, the shape of the heat storage body 46 may vary depending on the shape of the cavity body, and may be a square shape or a circular shape. The distance between the front end surface of the heat storage body 46 and the end portion of the inlet combustion pipe 41 is 1.1-1.3 times of the length of the combustion flame. The flow area of the through hole of the heat storage body is 4 0 -5 0 % of the cross-sectional area of the honeycomb-shaped heat storage body, and the intermediate portion 461 of the heat storage body is not opened, and the cross-sectional area of the non-opening area is substantially the same as the cross-sectional area of the combustion tube, and the peripheral portion 462 of the heat storage body is an open area, and the area is provided with a through hole 463, and the sum of the flow areas (cross-sectional areas) of the through holes is 40-50% of the cross-sectional area of the open area of the peripheral portion of the heat storage body, the heat storage body material is zirconium corundum brick or magnesia chrome brick which has a heat storage capacity and a high-temperature resistance.
[059] Referring to the secondary air distribution pipe shown in Figs. 10 and 11, the secondary air distribution pipe 47 is located at a distance of 100-200cm from the rear end surface of the heat storage body 46, and the air distribution pipe is also vary according to the shape of the cavity body, and may be a square shape or may be designed in a circular shape, and the secondary air distribution pipe 47 has a secondary air pipe outlet 471 uniformly open toward the side of the heat accumulator 46.
[060] The advantages of the stable and environmentally friendly combustion chambers for biomass gasification combustible gas are that:
[061] 1) the burner can adapt to the wide fluctuation of the calorific value of the combustible gas. The combustion chamber uses honeycomb-shaped heat storage body, and the heat storage body dissipates heat slowly, ensuring that the temperature thereof is always higher than the combustible gas burning point , that is, ensuring the stable combustion of the low calorific value; and
[062] 2) the combustion chamber adopts a two-stage combustion chamber and a two-stage automatic air distribution structure to control the combustion temperature and create a reducing atmosphere for combustible gas, so that achieve the purpose of controlling the nitrogen oxide amounts of the exhaust gas.
[063] Referring to Fig. 1, taking the wood material as an example, the sliced material is passed through a biomass pretreatment device 100 (sliced to about 3-6cm with a drum slicer), and the hoist enters the gasifier through the closed feed device 2 in the gasification apparatus 200. The fan 17 drums in hot air from air preheater10; at the same time, the water within the heating tube sheet 4 in the lower portion of the gasifier gradually absorbs the heat in the reaction zone to form steam in the fan drum, and after passing through the second valve 15, the steam and the hot air are mixed in the mixer 13, and then the fan 17 sent them into the carbon spiral shaft of the gasifier, and then they are uniformly distributed into the gasifier through the air outlet on the screw shaft, and an oxidation-reduction reaction occurs at 700-850°C. At the same time, a hydrogenation reaction occurs due to a certain proportion of water vapor, and hot gas is generated after gasification (the hot gas temperature is 200-300°C, and contains extract, tar, dust), the calorific value is 1600-1800kcal. The biomass coal produced in the lower portion of the gasification apparatus200 is cooled by the spiral of water passing through the inner shaft and the outer casing of the conventional equipment, and is packaged and stored in the warehouse after collection, according to the different biomass materials, it can be used for making barbecue carbon, carbon-based fertilizer, activated carbon and the like.
[064] A bridge breaking device is arranged at the bottom of the gasifier to prevent the reaction zone from bridging; a unique spiral discharge air distribution device is provided to ensure uniform discharge air distribution; the steam generating air intake system using the heat of the reaction zone and the external mix air intake method using steam and hot air ensure the reaction is stable, and the mixed gasification increases the calorific value of the combustible gas to 1600-1800kcal, meeting the requirements of high-temperature high-pressure boiler.
[065] The hot gas containing the extract, tar, and dust is sent into the environmental combustion chamber 300 for combustion under the positive pressure of the fan 27. The controller 50 controls the primary air volume sent into the first stage cavity body 45 to be 90% of the total air volume, and the secondary air volume sent into the second stage cavity body 48 is 10% of the total air volume. It forms an oxygen limited combustion environment in the first stage cavity body, while the fuel-type nitrogen oxides is produced under an oxidizing atmosphere, and the amount of the combustion-type nitrogen oxide amounts produced by the first stage cavity body is greatly reduced. There is also 10% of the combustible gas that is not burned; the oxygen is supplied through the second stage cavity body for combustion. The temperature of the first stage cavity body is controlled to be below 1000°C by controlling the air supply volume of the first stage cavity body. If the temperature is exceeded, the controller will automatically reduce the amount of the air volume, thus reduces the generation of thermal nitrogen oxides. The heat storage body 46 keeps the temperature under the burning of the combustible gas combustion flame. When the combustible gas has large fluctuations, for example, the calorific value of the combustible gas suddenly drops to 650Kacl, at this time, the flame may be instantaneously broken due to the air distribution, when the combustible gas is directly sprayed onto the high-temperature heat storage body and re-ignites immediately (even if it can't be burned immediately, the low-calorific value combustible gas will be oxidized immediately). At the same time, the controller automatically adjusts the supply air volume to ensure oxygen supply, thus ensuring that the combustible gas does not fluctuate due to the calorific value. The non-combustible gas will not accumulate in the subsequent boiler to cause a safety accident, and also ensuring the stable operation of the combustion chamber. The combustion chamber of the present invention can realize the stable combustion of the biomass gasification hot gas with the fluctuation of the calorific value, and reduce the nitrogen oxide amounts, thereby ensuring the environmental protection of the combustion.
[066] The high-temperature flue gas combusted by the combustion chamber 300 is through the outlet high-temperature flue gas pipe 51 directly sent into the boiler 400. The boiler 400 generates high-temperature high-pressure steam to drive the steam turbine 900, thereby driving the generator 1000 to generate electricity, and the steam passed through the steam turbine and is partially for heating, and the low-temperature water enters the condenser and returns to the coal economizer 500 for boiler hydration. The exhaust gas of the boiler 400 is first passed through the coal economizer 500, and then the gasifying agent is preheated by the air preheater 600. After the preheating, the air is sent into the combustion chamber 300 and the gasifier 200, and the exhaust gas is finally discharged through the exhaust 800.
[067] The present invention adopts the gasification apparatus for preparing a medium calorific value biomass combustible gas to generate a calorific value of 1600 1800kcal, and the combustion can meet the heat generation requirement of the high temperature high-pressure boiler, and the power generation efficiency can be improved; by adopting an environmentally friendly combustion chamber, while the combustion is stable, the nitrogen oxide content of the exhaust gas can be reduced, and the exhaust gas can meet the discharge requirement without adding a denitration device; the product is diverse, the economic benefit is good, and can be used on a large scale.
[068] Although the invention has been described with reference to specific examples, it will be appreciated by those skilled in the art that the invention may be embodied in many other forms, in keeping with the broad principles and the spirit of the invention described herein.
[069] The present invention and the described embodiments specifically include the best method known to the applicant of performing the invention. The present invention and the described preferred embodiments specifically include at least one feature that is industrially applicable
Claims (9)
1. A method for generating electricity and producing carbon and heat via biomass
fixed bed gasification, characterized in that:
the method comprising the following steps:
1) feeding a biomass raw material into a gasification apparatus to prepare a medium calorific value biomass combustible gas, and performing gasification on the biomass raw material at 700-850°C under the effect of an air/water vapor pre-mixed gasification agent to produce a combustible gas, the calorific value of the combustible gas being 1600-1800kcal, the temperature being 200-300°C;
2) directly feeding the combustible gas into an environmentally friendly combustion chamber for combustion, and then into a high-temperature high-pressure boiler, the gas combusting within the high-temperature high-pressure boiler to produce high-temperature high-pressure steam, which drives a steam turbine to generate electricity; utilising steam remaining heat discharged by the steam turbine;
3) collecting carbon discharged from the gasification apparatus after cooling;
4) using boiler exhaust gas to heat air by means of an air preheater, the hot air being respectively fed into the combustion chamber and the gasification apparatus by means of an air blower, and utilizing the remaining heat.
2. The method for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 1, characterized in that:
the low temperature water generated by the steam turbine is used for replenish to the boiler after heat exchanged with the boiler exhaust gas in the coal economizer (500).
3. An apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification, characterized in that:
the apparatus comprising a gasification apparatus (200) for preparing a medium calorific value biomass combustible gas, a stable and environmentally friendly combustion chamber for stable combustion for biomass gasification combustible gas (300),a high-temperature high-pressure boiler (400), an air preheater (600), a flue gas exhaust fan (700), a steam turbine (900), and a generator; the combustible gas outlet in the gasification apparatus (200) communicates with the combustion pipe in the environmentally friendly combustion chamber (300), and the outlet high-temperature flue gas pipe in the environmentally friendly combustion chamber (300) communicates with the gas inlet in the high-temperature high-pressure boiler (400); the steam outlet in the high-temperature high-pressure boiler (400) communicates with the steam inlet in the steam turbine (900); the exhaust pipe of the high-temperature high-pressure boiler (400) communicates with the shell path of the air preheater (600),after the air preheating pipe passes through the pipe path of the air preheater (600), it is respectively communicated with the combustion pipe and the gasification apparatus.
4. The apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 3, characterized in that:
the low temperature water outlet in the steam turbine (900) through the coal economizer (500) communicates with the filling port of the high-temperature high pressure boiler(400); the exhaust pipe in the high-temperature high-pressure boiler (400) is in turn communicates with the coal economizer (500) and the air preheater (600).
5. The apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 3, characterized in that:
the gasification apparatus (200) for preparing a medium calorific value biomass combustible gas comprises a gasifier and a steam generating air intake system;
a closed feed device (2) is arranged in the upper portion of the gasifier, a spiral discharge air distribution device (5) is arranged at the bottom of the gasifier, and a screw shaft (29) rotating in the spiral discharge air distribution device (5) is a hollow shaft having a spiral blade on the outer circumference, and an air outlet for communicating the inside of the hollow shaft with the inside of the gasifier is uniformly disposed on the hollow shaft; the steam generating air intake system includes a skirt drum (11), a circulating heat pump (12), and a heating tube sheet (4) disposed at the gasifier, a mixer (13), a fan (17) and a valve; the outlet of the heating tube sheet (4) is connected to the water intake of the steam drum (9) through the circulating heat pump (12); the steam outlet (7) of the steam drum is connected to the inlet of the mixer (13) via the valve (15); the outlet of the fan (17) is connected to the inlet of the mixer (13) via the valve (14); the outlet of the mixer (13) is connected to the end of the screw shaft (29) through the rotary joint (30); the inlet of the fan (17) is connected to the air outlet of the air preheater (600).
6. The apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 5, characterized in that:
the spiral discharge air distribution device (5) comprises a plurality of parallel trapezoidal carbon trough (28) passing through the bottom of the gasifier, each trapezoidal carbon trough (28) is provided with a rotating screw shaft (29);
the end of each trapezoidal carbon trough (28) extending outside the gasifier is connected to a carbon warehouse (26);
a rotating secondary carbon spiral (27) is placed in the carbon warehouse (26).
7. The apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 3, characterized in that:
the environmentally friendly combustion chamber (300) is divided into a first stage cavity and a second stage cavity body (48) through a honeycomb shaped heat storage body (46); a combustion pipe (41) is connected to a biomass gas inlet and a primary air distribution pipe (54), the combustion pipe (41) is connected to the first stage cavity body (45), and an ignition gun (42) and a thermocouple Ti are arranged on the first stage cavity body (45), a secondary air distribution pipe (47), opposite to the honeycomb-shaped heat storage body (46), and a thermocouple T2 are arranged within the second stage cavity body (48) and the second stage cavity body (48) is connected to the outlet high-temperature flue gas pipe (51), the primary air distribution pipe (54), a primary air volume adjustment valve (52), the secondary air distribution pipe (47) and a secondary air volume adjustment valve (53) are connected to a air supply fan (49),and a controller (50) is connected to the thermocouple T1, the thermocouple T2, the primary air volume adjustment valve (52), the secondary air volume adjustment valve (53), and the air supply fan (49), the inlet of the blower (49) is connected to the air outlet of the air preheater (600).
8. The apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 7, characterized in that:
the distance between the honeycomb-shaped heat storage body (46) and the end of the inlet combustion pipe (41) is 1.1-1.3 times of the length of the combustion flame,
the heat storage body is coaxial with the combustion pipe,
the middle portion of the heat storage body has a non-opening area that is as large as the cross-sectional area of the combustion pipe,
the peripheral portion of the heat storage body is opened a through hole,
the flow area of the through hole is 40-50% of the cross-sectional area of the peripheral portion of the heat storage body,
the material of the heat storage body is zirconium corundum brick or magnesia chrome brick.
9. The apparatus for generating electricity and producing carbon and heat via biomass fixed bed gasification according to Claim 7, characterized in that: the primary air volume entering the combustion pipe through the primary air distribution pipe (54) is about 90% of the required air volume of the combustible gas; the secondary air volume entering the second stage cavity body through the secondary air distribution pipe is 10% of the required air volume of the combustible gas; the temperature of the first stage cavity body is below 1000°C.
hot
electricity raw material
vapor water
air 1/7
hot gas
water carbon carbon
hot air
Figure 1
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113150829A (en) * | 2021-04-19 | 2021-07-23 | 东方希望晋中铝业有限公司 | Low-calorific-value gas generating device for photovoltaic glass melting furnace |
| CN115415275A (en) * | 2022-10-17 | 2022-12-02 | 国能新疆化工有限公司 | Gasification slag solid waste recycling equipment |
| CN115848610A (en) * | 2022-11-07 | 2023-03-28 | 中国船舶集团有限公司第七○八研究所 | Ship air conditioning device utilizing biomass energy and working method |
-
2020
- 2020-11-02 AU AU2020103173A patent/AU2020103173A4/en not_active Ceased
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113150829A (en) * | 2021-04-19 | 2021-07-23 | 东方希望晋中铝业有限公司 | Low-calorific-value gas generating device for photovoltaic glass melting furnace |
| CN115415275A (en) * | 2022-10-17 | 2022-12-02 | 国能新疆化工有限公司 | Gasification slag solid waste recycling equipment |
| CN115415275B (en) * | 2022-10-17 | 2023-10-31 | 国能新疆化工有限公司 | Coal gas slag solid waste recycling equipment |
| CN115848610A (en) * | 2022-11-07 | 2023-03-28 | 中国船舶集团有限公司第七○八研究所 | Ship air conditioning device utilizing biomass energy and working method |
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