AU2014339010B2 - Herbicidal compositions containing N-(1,3,4-oxadiazol-2-yl)-aryl carboxylic acid amides - Google Patents

Herbicidal compositions containing N-(1,3,4-oxadiazol-2-yl)-aryl carboxylic acid amides Download PDF

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AU2014339010B2
AU2014339010B2 AU2014339010A AU2014339010A AU2014339010B2 AU 2014339010 B2 AU2014339010 B2 AU 2014339010B2 AU 2014339010 A AU2014339010 A AU 2014339010A AU 2014339010 A AU2014339010 A AU 2014339010A AU 2014339010 B2 AU2014339010 B2 AU 2014339010B2
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AU2014339010A9 (en
AU2014339010A1 (en
AU2014339010B9 (en
Inventor
Hartmut Ahrens
Ralf Braun
Simon Dorner-Rieping
Elmar Gatzweiler
Ines Heinemann
Arnim Kohn
Hubert Menne
Klaus Trabold
Christian Waldraff
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Bayer CropScience AG
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Bayer CropScience AG
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01C—PLANTING; SOWING; FERTILISING
    • A01C1/00—Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06—Coating or dressing seed
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01H—NEW PLANTS OR NON-TRANSGENIC PROCESSES FOR OBTAINING THEM; PLANT REPRODUCTION BY TISSUE CULTURE TECHNIQUES
    • A01H1/00—Processes for modifying genotypes ; Plants characterised by associated natural traits
    • A01H1/06—Processes for producing mutations, e.g. treatment with chemicals or with radiation
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
    • A01N33/18—Nitro compounds
    • A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
    • A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/10—Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • A—HUMAN NECESSITIES
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    • A01N37/34—Nitriles
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    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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    • A—HUMAN NECESSITIES
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
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    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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    • A—HUMAN NECESSITIES
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    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10S424/00—Drug, bio-affecting and body treating compositions
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Abstract

The invention relates to herbicidal compositions which contain active ingredients from the group of N-(1,3,4-oxadiazol-2-yl)-aryl carboxylic acid amides and other herbicides and optionally safeners. Said herbicidal compositions are particularly suitable for use against harmful plants in crops of useful plants.

Description

Herbicidal compositions containing N-(1,3,4-oxadiazol-2-yl)-aryl carboxylic acid amides Description
The present invention relates to agrochemically active herbicidal compositions, to processes for production thereof and to the use thereof for control of harmful plants. WO 2012/126932 A1 discloses particular N-(1,3,4-oxadiazol-2-yl)arylcarboxamides having herbicidal properties. However, these active ingredients do not always exhibit sufficient efficacy against harmful plants and/or some of them are not fully compatible with some important crop plants such as cereal species, corn or rice.
Embodiments of the present invention provide herbicidal compositions in which efficacy against harmful plants and/or selectivity of the abovementioned herbicides with respect to important crop plants is increased. In some embodiments the present invention provides the inventive herbicidal compositions described hereinafter, comprising particular N-(1,3,4-oxadiazol-2-yl)arylcarboxamides, further herbicides and optionally safeners.
The present invention provides herbicidal compositions comprising (A) one or more compounds of the formula (I) (component A) or salts thereof
(I), in which the substituents are defined as follows: A is N or CY, R is hydrogen, (Ci-Ce)-alkyl, R10-(CrC6)-alkyl, CH2R6, (C3-C7)-cycloalkyl, halo-(Ci-C6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C2-C6)-alkynyl, OR1, NHR1, methoxycarbonyl, ethoxycarbonyl, methoxycarbonylmethyl, ethoxycarbonylmethyl, methylcarbonyl, trifluoromethylcarbonyl, dimethylamino, acetylamino, methylsulfenyl, methylsulfinyl, methylsulfonyl, or heteroaryl, heterocyclyl, benzyl or phenyl each substituted by s radicals from the group of halogen, nitro, cyano, (CrC6)-alkyl, halo-(CrC6)-alkyl, (C3-C6)-cycloalkyl, S(0)n-(CrC6)-alkyl, (Ο-ι-Οβ)-alkoxy, halo-(CrC6)-alkoxy, (Ci-C6)-alkoxy-(CrC4)-alkyl, X is nitro, halogen, cyano, formyl, thiocyanato, (CrC6)-alkyl, halo-(CrC6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C3-C6)-alkynyl, (C3-C6)-cycloalkyl, halo-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(CrC6)-alkyl, halo-(C3-C6)-cycloalkyl-(CrC6)-alkyl, COR1, COOR1, OCOOR1, NR1COOR1, C(0)N(R1)2, NR1C(0)N(R1)2, 0C(0)N(R1)2, C(0)NR10R1, OR1, OCOR1, 0S02R2, S(0)nR2, SO2OR1, S02N(R1)2, NR1S02R2, NR1COR1, (CrC6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (CrC6)-alkyl-OCOR1, (Ci-C6)-alkyl-0S02R2, (Ci-C6)-alkyl-C02R1, (CrC6)-alkyl-S020R1, (C1-C6)-alkyl-CON(R1)2, (CrC6)-alkyl-S02N(R1)2, (CrC6)-alkyl-NR1COR1, (C1-C6)-alkyl-NR1S02R2, NR1R2, P(0)(0R5)2, CH2P(0)(0R5)2, (CrC6)-alkylheteroaryl, (CrC6)-alkylheterocyclyl, where the two latter radicals are each substituted by s halogen, (CrC6)-alkyl, halo-(CrC6)-alkyl, S(0)n-(CrC6)-alkyl, (CrC6)-alkoxy, halo-(Cr C6)-alkoxy radicals, and where heterocyclyl bears n oxo groups, Y is hydrogen, nitro, halogen, cyano, thiocyanato, (CrC6)-alkyl, halo-(CrC6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, halo-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(CrC6)-alkyl, halo-(C3-C6)-cycloalkyl-(CrC6)-alkyl, COR1, COOR1, OCOOR1, NR1COOR1, C(0)N(R1)2, NR1C(0)N(R1)2, 0C(0)N(R1)2, CO(NOR1)R1, nr1so2r2, nr1cor1, or1, OSO2R2, S(0)nR2, SO2OR1, S02N(R1)2, (CrC6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (Cr C6)-alkyl-OCOR1, (CrC6)-alkyl-0S02R2, (Ci-C6)-alkyl-C02R1, (CrC6)-alkyl-CN, (Cr C6)-alkyl-S020R1, (CrC6)-alkyl-CON(R1)2, (CrC6)-alkyl-S02N(R1)2, (CrC6)-alkyl-NR1COR1, (CrC6)-alkyl-NR1S02R2, N(R1)2, P(0)(0R5)2, CH2P(0)(0R5)2, (CrC6)-alkylphenyl, (CrC6)-alkylheteroaryl, (CrC6)-alkylheterocyclyl, phenyl, heteroaryl or heterocyclyl, where the 6 latter radicals are each substituted by s radicals from the group of halogen, nitro, cyano, (CrC6)-alkyl, halo-(CrC6)-alkyl, (C3-C6)-cycloalkyl, S(0)n-(Ci-C6)-alkyl, (C-i-C6)-alkoxy, halo-(CrC6)-alkoxy, (CrC6)-alkoxy-(CrC4)-alkyl and cyanomethyl, and where heterocyclyl bears n oxo groups, Z is hydrogen, halogen, cyano, thiocyanato, (CrC6)-alkyl, (CrC6)-alkoxy, halo-(CrC6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C2-C6)-alkynyl, (C3-C6)-cycloalkyl, halo-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(CrC6)-alkyl, halo-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR1, COOR1, OCOOR1, NR1COOR1, C(0)N(R1)2, NR1C(0)N(R1)2, 0C(0)N(R1)2, C(0)NR10R1, 0S02R2, S(0)nR2, so2or1, S02N(R1)2, NR1S02R2, NR1COR1, (CrC6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (CrC6)-alkyl-OCOR1, (CrC6)-alkyl-0S02R2, (CrC6)-alkyl-C02R1, (CrC6)-alkyl-S020R1, (Cr C6)-alkyl-CON(R1)2, (CrC6)-alkyl-S02N(R1)2, (CrC6)-alkyl-NR1COR1, (CrC6)-alkyl-NR1S02R2, N(R1)2, P(0)(0R5)2, heteroaryl, heterocyclyl or phenyl, where the last three radicals are each substituted by s radicals from the group of halogen, nitro, cyano, (Cr C6)-alkyl, halo-(Ci-C6)-alkyl, (C3-C6)-cycloalkyl, S(0)n-(Ci-C6)-alkyl, (CrC6)-alkoxy and halo-(Ci-C6)-alkoxy, and where heterocyclyl bears n oxo groups, R1 is hydrogen, (CrC6)-alkyl, (CrC6)-haloalkyl, (C2-C6)-alkenyl, (02-0β)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (Ci-C6)-alkyl-0-(Ci-C6)-alkyl, (C3-C6)-cycloalkyl-(CrC6)-alkyl, phenyl, phenyl-(CrC6)-alkyl, heteroaryl, (CrC6)-alkylheteroaryl, heterocyclyl, (CrC6)-alkylheterocyclyl, (CrC6)-alkyl-0-heteroaryl, (CrC6)-alkyl-0-heterocyclyl, (CrC6)-alkyl-NR3-heteroaryl, (CrC6)-alkyl-NR3-heterocyclyl, where the 21 latter radicals are substituted by s radicals from the group consisting of cyano, halogen, nitro, thiocyanato, OR3, S(0)nR4, N(R3)2, NR3OR3, COR3, OCOR3, SCOR4, NR3COR3, NR3S02R4, C02R3, COSR4, CON(R3)2 and (Ci-C4)-alkoxy-(C2-C6)-alkoxycarbonyl, and where heterocyclyl bears n oxo groups, R2 is (CrC6)-alkyl, (CrC6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (CrC6)-alkyl-0-(CrC6)-alkyl, (C3-C6)-cycloalkyl-(CrC6)-alkyl, phenyl, phenyl-(CrC6)-alkyl, heteroaryl, (CrC6)-alkylheteroaryl, heterocyclyl, (C1-C6)-alkylheterocyclyl, (Ci-C6)-alkyl-0-heteroaryl, (Ci-C6)-alkyl-0-heterocyclyl, (CrC6)-alkyl-NR3-heteroaryl, (Ci-C6)-alkyl-NR3-heterocyclyl, where the 21 latter radicals are substituted by s radicals from the group consisting of cyano, halogen, nitro, thiocyanato, OR3, S(0)nR4, N(R3)2, NR3OR3, COR3, OCOR3, SCOR4, NR3COR3, NR3S02R4, C02R3, COSR4, CON(R3)2 and (CrC4)-alkoxy-(C2-C6)-alkoxycarbonyl, and where heterocyclyl bears n oxo groups, R3 is hydrogen, (CrC6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C3-C6)-cycloalkyl or (C3-C6)-cycloalkyl-(Ci-C6)-alkyl, R4 is (CrC6)-alkyl, (C2-C6)-alkenyl or (C2-C6)-alkynyl, R5 is methyl or ethyl, R6 is acetoxy, acetamide, N-methylacetamido, benzoyloxy, benzamldo. N-m ethyl benzam ido, methoxycarbonyi, ethoxy carbonyl, benzoyl, methyicarbonyi, piperidinyicarbonyl. morphoiinyicarbonyi, trifluoromethyicarbonyi, aminocarbonyl, methylaminocarbonyl, dimothyiaminocarbonyl, (Ci-CeRalkcxy, (Cs-CeJ-cyoloaikyi, or heteroaryi. heteroeyciyl or phenyl each substituted by s radicals from the group of methyl, ethyl, methoxy, trifluoromethyl and halogen, n is 0,1 or 2, s Is.0.,1., 2 or 3, and (8): one or more herbicides (component B) selected from groups (81) to (Bi t): 81 1,3-diketo compounds comprising prohexadione, prohexadione-calcium, Lrinexapac-ethyi, alioxydim, allcxydim-sodium, huiroxydim, clethodim, cyeloxydim, ketospiradox, profoxydim, sethoxydirn, tepraloxydim, tralkoxydirn, mesotrione, suicotrione, tefuryitrlone, tembotrione, bicyciopyrone5: pinoxaden, B2 (sulfon)amides comprising beitubutamide, broraobutide, dimeihenamide, dimethenamide-F, diphenamide, napropamide, pethoxamid, N-[8-ch!0m-4-(1“methylethyl}-pher^l]“2~ rneihyipentanamide, propyzamide, diflufenican, etobenzanld, flufenacet, mefertacet, mefiuidlde,picolinaferx propanil, N-phenylphthalamic acid, acetochior, alschlor, amidochlor, butachlor, butonachlor, dsmethachlor, metazachior, rnetolachlor, S rnetoiachlor, pretilachlor, propachlor, propisochlor, {2-chiora-8'-ethy!~N-isopropoxymethyiaceto-Q-toluidide), thenviohior, asutam, carbafyi, earbetamide, ehiorpropRam, desmedipharn, phenmedipham, propharn, buiyiate. cycloate.. dimeplperate, ERTC, esprocarb, rnethasulfocarb,, rnoHpais, cHPenoarb, pebuiate, prasuifocas'fo, pypbuiicarfe, fhsobencarb, irbatiMe, vefpolate, amidosuifuron, azimsujfuron, bensuifyron, bensuliuronmiethyl, ehiorimuran:, ehibrimuron-ethyl, cbiorsuifuron, cinosulfuron, eyGldsuiiamyron, ethametsuifuron, ethametsuifuron-msiliyi, ethoxysuifuron, ilazasylfurGn, fluceiDaylfuron, rkipyrsylfurorv methyi-sodium, fbramsuifuron, halosulfuron^etbyk iraazosuifuron, iGdosuifurop, iodosulfϋrors-rnethyl·sodium! rnesosulfuron, meisosylfuron-metllyi, metazosulfurpri, methiopyrsuifuron. metsuifuron, metsy!furonynetiiyS,: monosulfuron, monosuifuron-ester. nicosulfuron:, orthosulfamuron, oxasuifuron, pnmisuifuron-meihyl, propyrisulfuron, prosuifuron, pyrazosuifuron, pyrazosulfuronaethyi, rimsulfuron. suifome.turon, sulfometuron-methyl, sulfbsuifuron, thifensuifurob, thifensalfuron-methyl, tnasulruron, tnbenuron, iribenuron-meihy!, trtfioxysulfuron, trifloxysuiiuron {scxJsum), triflusulfuron, frifiusulfuron-metbyl, tritosulfuron, (benzoic acid, 2--[[[[[4“methQXy-S'· (methyithio)-2-pyrimidinyi]amino]carbonyi3arnino]suifGnyi]methyi ester), flycarbazone, flucarbazone-sodium, ipfencarbazone, propoxycarbazone, propGXyGarbazpne-SGdium, ihiencarbazone, ihiencarbazone-rnerhyi, qioransulam, cioransiiiam-sTtethyi, diGiosuiam, florasulam, rlumsisuiam, metesulafn, p en o x s u! am, py rox s u I a m, 3~ch[oro~N'-i(4!6-dimethoxypyrimidin“2~yi)carbamoyt]-i':metf)yl:-4--(S-TOeihyf:--5,6--dihydrG«-1, 4,2-d ioxazi n-3-yl)-1H -pyrazo ie-5-su Iton a m i be, B3 aryinitriles comprising bmmoxyhil, bromoxynikbutyrate, bromoxynii-potassibm, bromoxynil-heptandate, forornoxynii-octanQate, detosyl-pyrazolate (DTP), dichiobenil, ioxynlr ioxyniPootanoate, ioxynH-poiasssurn, ioxynil-sodiurri, pyraclonil, B4 azoles comprising benzofenap, pyrazoiynate (pyrazoiate), pyrazoxyren, pyroxastilfoM, toprarnezDne, pyrasulfotole, 3~(3-ohjoFD»5-{i1 ‘methyb3^trifiyprometbyi)-1 H-pyrazoi-5-ypxy}phenoxy)~1-metbyi-3-(trifluoropietbyi)-1Hipyrazoie, 3-(3“lodp-5-{[1~metliyi-3-(tF!iuoromethyi)-1H-pyrazob3-yi]oxy}pnenoxy)~f"methyl-5~(trif[yoromeih:yi)"1H-pyrazsie, 1 -ethyS--343diyQFo-5-{[1 ”methyP3--(triiyoromethyi3~1 H-pyrazoi-5-y0oxy}phenoxy)-5-(tniluoromathyi)-d:H-pyrazoie! pyrafiuien, pyrafiufen-ethyi, fenoxasuifone, ispumn, isoxaben, isoxaflutole, imazametbabenz, Srmzamethabenz-methyl imazamox* imazamox^arnrnonium, imazapje* Imazapic-ammonium, imazapyr, ImazapyrdsoprGpybammonium, imazaguin, imazaqyirvamrnonjurn, imazethapyr, imazethapyr-lmmonlumazaienidin, oxadiargyi, oxadiazon, arnicad-azone, oarienirazone, caHePtrazone-othyl, suifenirazone. amitroie, padobutrazoi, uniconazole, uniconazofe-P, caienstrole, fentrazarnide, 65 other herbicides comprising aliidochior, aminocyclopyrachior, aminocyclopyrachlor-potassium, arninocyciepyrachior-methyi, N-aeetyithiazolidlne^-carhoxylic acid, aminopyralick ammonium pelargonate, ammonium suifamate, avigiycine, benazolin, benazo!i«^tfiyit benfluralin, henfuresate, bentazone, hetizoblcyclom ©“benzylamihopunne:, brassinoiide, brombfehoxim, butralin, cblorfenae, cblo^^ chiorfiurenol, Ghlos1iurenoi-methyi: chiondazom chlormeduat chloride, chicrpbihaiirn. chlorthaPdimethyl, einidon* oinidon-ethyl, einmethylin, clofencet, domazone, cloxyfonac, cyanamide, cycianilide, cydopyrirnorate, 6~isopentyiaminopurine, kinetin, zeatin, daiapon, daminozide, dazomet. n-decanoi, difenzoquai metf sulfate, 2,6-diisopropyinaphthaiene, dikegulae, dlkeguiao-sodium, dimethipin, dioitrarnine, dineierb, diquat, diquat dibromide, diihiopyr, DNGC, endotbal, endothai-dipotassiurn, enbolhai-disodium, endothai-monoihl.N-dimethylalkyiammonium), ethaflurailo, ethefumesate, ethylchiozate, fiamprop, fiamprop-Mdsopropyi, flamprop-IVI-metbyl, fiuchiaraiin, fiufenpyr, fiufenpyr-ethyi, flurnetraiin, fiumichiorac, fiumiclorac-pentyi, fiimTioxazih, flupropanate, fiurepot, flursnobbutyi, flurenobdlniethylammonidm-'methyl, Sundone, fteochioridone, flurtamohe, fiuthiacst, fiuthiacebmethyi:, gibberlilie acid, halauxifen, indanofan, isoprothiolane, maleic hydrazide, mepiquat chlorldeJ: melam, mefhiozoiin, rnethylarsonic acid, l-rnethyicyclopropene, methyl isothiooyanate, nltrophenolata mixture, nonanoic acid, norfiurazon, oleic acid, oryzaHn,; oxazidiomefene, paraquat, paraquat dichionde, pendimethalin. pentaGhlorophenol, pentoxazone, petroleum Oils, prbdlamlne, n-propy! dihydrqjasmonaie, pyridaioi, pyridate, quinoclarnine, slntofen, TCA, TCA sodium, iecnazehe, thiazopyr, triabontanob triafamone, tnfluraiin, urea sulfate, 86 {het)aryiGarboxyHG acids comprising; chioramben, dicamba, 2,3,6-TBA, ciopyraiid, fluroxypyr, iiuroxypyr-rnepiyi, inabenfide, pidoram, triciopyr, qumciorac, quinmerao, indoi-3~-yiaeetie acid, 4^lndob3"yl-butyrie acid, 2-(imaphthyl)acetamlde, Imaphthylacetic acid, 2-naphthyioxyacetio acid, 87 organic phosphorus compounds comprising armofos, behaulido, bilanafos, biianafGmsodium, butamiios, oiacyibs, fosarnine, giufosinaie, glufosinate salts, giufosinate-ammonium, gluiosinate-socilum, glufosinate-P, L~giufosinate~ammohium. L-glufosinate-sodlurn, glyphosate, glyphosate salts, glyphosate-isoptopyl-ammoniuro, glyphosate-arnrnonium, glyphosate·· dimednyiammonium, giyphosate-trimesiurn (-sulfosate), glyphosafe-diammonium, glyphosate-petassium, glyphosaie-sodlum, piperophos, ethephon, trifeafos, 88 phenyl ethers comprising acifIuorfen-sodium, aelonifen, fluaroglycoien, tluoroglycofen-ethyi, iomesafen, foroesaien-sodlum, haiosafen, lactofen, oxyfluerten, acduerfen. bifenox, ethoxyfem ethyl, clonieprop, cloprop, dlchlorprop, dlchiorprop-Ppmecoprop, mecopmpcsDdlum, mecoprop-butotyl, mecoprop-P, mecoprop-P-butotyi, mecoprdp-P'-dtmethyiamrrjonium, mecoprop-P-2-ethyihexyi. mecoprop-P-patassinm, 4-CP.A, 2,4-D, 2,4-D-butotyl, 2,4-D-pytyi. 2.4'D--dimeihyiamrnonium. 2,4-D~dioiam!ne, 2,4-O-ethyi, 2,4-0-2-ethyihexyl, 2,4-O-isobutyi, 2,4-Ddsooctyl, 2,4~D-lsopropylamroonium> 2,4~D~potasslum, 2,4-0-triisopropanoiammonium, 2,4~D-irblamine: ΜΟΡΑ, MCPA-butotyl, MCPA-dsmethySammonium, MGPA-2-ethyihexyl, MCPA~|soprdpyiamnioniym, ΜΟΡΑ-potassium, MiCPA-sodium, 2,4-DB, MCPB, MOPB-fnetnyl, MCPB-ethyhsodrum, dodioafop-ethyi, dodlnafop-propargyl, eyhalotop, eyhahfop-buiyl, dlcloiop, diclofbp-P, dldoiq pan ethyl, dldcriGp-P-methyl, fenoxaprop, fanoxaprop-P, fenoxaprop-P-ethyi, fluazifbp, ilusziiop-P, fluazifop-butyt, flyazifop-P-butyi, halaxyfop, haioxyfop-P, meiamifop, propaquizafop quizalotdp, quizaldfop^ethyl, quizalofop-P, qulzalofop-P~ ethyl, quizalofop-P-tefuryl, B9 pyrimidines, comprising anoynildoi, ilurprimidoi, pyrimlsuifan, bispyribac, teispyfsbae-sodlurn, pyrihenzoxtm,. pyrirolnobac, pynminobac-methyl, pynbambenz, pyrlbambenzdsapropyl, pyribambanz-propyl, pyriftaiid, pyrithiobac, pyrithiafoac-sodium, bromacil, butafenacii, lenacii, saflufenacil, terbadi, tifenacii, 2-chlQr©-44!Uoro-§-P“methyh2,6''dioxo-4-|tFifiuoromethy[>-3,6-dihydropyrimidin-1(2H)-yll-d-[meihyl(1- rnethyleihyi)syifarnoyljbenzamide:: athyl [(3-{2-ρΝογο-§-[2,6^ϊοχρ~4-0Λ 3,6-dihydropyrimidin~1l(2H)-yij-4-f!uGrdphanoxy}pyridin:-2"yi)oxyiaoetatei B10 {thiojureas comprising cumyluron, chlorbromuron, chlorotoluron, daimuron, diflufenzopyr, diflufenzopyr-sodium, dimefuron, diuron, fluometuron, forchlorfenuron, isoproturon, karbutilate, linuron, metobromuron, metoxuron, monolinuron, neburon, siduron, terbucarb, thidiazuron, tebuthiuron, methabenzthiazuron, B11 triazines comprising triaziflam, indaziflam, atrazine, cyanazine, cyprazine, propazine, simazine, terbumeton, terbuthylazine, trietazine, prometon, ametryn, dimethametryn, prometryn, simetryn, terbutryn, ethiozin, hexazinon, metamitron, metribuzin.
In a first aspect the present invention provides a herbicidal composition comprising (A) the compound of formula (A1 -13) (component A) or a salt thereof
(A1-13) and (B) one or more herbicides (component B) selected from the group consisting of amicarbazone, atrazine, bicyclopyrone, dicamba, dimethenamide-P, flufenacet, foramsulfuron, glufosinate-ammonium, glyphosate, halauxifen, isoxaflutole, mesosulfuron-methyl, mesotrione, metribuzin, nicosulfuron, pyroxasulfone, saflufenacil, and thiencarbazone-methyl.
In a second aspect the present invention provides a method of controlling harmful plants in crop plants, the method comprising applying a herbicidally active amount of a herbicidal composition as defined in the first aspect to the harmful plants, crop plants, plant seeds or the area on which the plants grow.
In a third aspect the present invention provides use of a herbicidal composition as defined in the first aspect for controlling harmful plants in crop plants.
In a further embodiment, these herbicidal compositions comprise (C) one or more safeners (component C) from the group consisting of benoxacor (C1), cloquintocet-mexyl (C2), cyprosulfamide (C3), dichlormid (C4), fenclorim (C5), fenchlorazole (C6), furilazole (C7), isoxadifen-ethyl (C8), mefenpyr-diethyl (C9), 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane (CAS 71526-07-3) (C10), 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (CAS 52836-31-4) (C11), 2-methoxy-N-({4-[(methylcarbamoyl)amino]phenyl}sulfonyl)benzamide (CAS 129531 -12-0) (C12).
Components B) and C) are known, for example, from "The Pesticide Manual", 16th edition, 2012, The British Crop Protection Council and the Royal Soc. of Chemistry.
The inventive herbicidal compositions may comprise or be used together with additional further components, for example other kinds of active crop protection ingredients and/or additives and/or formulation auxiliaries customary in crop protection.
The herbicides (A), (B) and optionally the safeners (C) can be applied in a known manner, for example together (for example as a co-formulation or as a tank-mix) or else at different times in short succession (splitting), for example to the plants, plant parts, plant seeds or the area on which the plants grow. It is possible, for example, to apply the individual active ingredients or the herbicide-safener combination in several portions (sequential application), for example by pre-emergence applications followed by post-emergence applications, or by early post-emergence applications followed by post-emergence applications at an intermediate or late stage. Preference is given to the joint or immediately successive application of the active ingredients in the respective combination. It is also possible to use the individual active ingredients or the herbicide-safener combination for seed treatment.
Preference is given to those inventive compositions which comprise, as herbicide (A), compounds of the general formula (I) and salts thereof in which A is N or CY, R is hydrogen, (Ci-C6)-alkyl, (C3-C7)-cycloalkyl, halo-(Ci-C6)-alkyl, (C3-C7)-cycloalkylmethyl, methoxycarbonylmethyl, ethoxycarbonylmethyl, acetylmethyl, methoxymethyl, methoxyethyl, benzyl, pyrazin-2-yl, furan-2-yl, tetrahydrofuran-2-yl, morpholine, dimethylamino, or phenyl substituted by s radicals from the group of methyl, methoxy, trifluoromethyl and halogen; X is nitro, halogen, cyano, (CrC6)-alkyl, halo-(CrC6)-alkyl, (C3-C6)-cycloalkyl, OR1, S(0)nR2, (Ci-C6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (Ci-C6)-alkyl-CON(R1)2, (CrC6)-alkyl-S02N(R1)2, (CrCeJ-alkyl-NR^OR1, (CrCeJ-alkyl-NR^OsR2, (CrC6)-alkylheteroaryl, (CrC6)-alkylheterocyclyl, where the two latter radicals are each substituted by s halogen, (CrC6)-alkyl, halo-(CrC6)-alkyl, S(0)n-(CrC6)-alkyl, (CrC6)-alkoxy, halo-(CrC6)-alkoxy radicals, and where heterocyclyl bears n oxo groups, Y is hydrogen, nitro, halogen, cyano, (CrC6)-alkyl, (CrC6)-haloalkyl, OR1, S(0)nR2, S02N(R1)2, N(R1)2j NR1S02R2, NR1COR1, (CrC6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (CrC6)-alkyl-CON(R1)2, (CrC6)-alkyl-S02N(R1)2, (CrC6)-alkyl-NR1COR1, (CrC6)-alkyl-NR1S02R2, (Ci-C6)-alkylphenyl, (CrC6)-alkylheteroaryl, (CrC6)-alkylheterocyclyl, phenyl, heteroaryl or heterocyclyl, where the 6 latter radicals are each substituted by s radicals from the group consisting of halogen, nitro, cyano, (Cr C6)-alkyl, halo-(CrC6)-alkyl, (C3-C6)-cycloalkyl, S(0)n-(CrC6)-alkyl, (CrC6)-alkoxy, halo-(CrC6)-alkoxy, (CrC6)-alkoxy-(CrC4)-alkyl and cyanomethyl, and where heterocyclyl bears n oxo groups, Z is halogen, cyano, nitro, methyl, halo-(Ci-C6)-alkyl, (C3-C6)-cycloalkyl, S(0)nR2, 1,2,4-triazol-1-yl, pyrazol-1-yl, or Z may also be hydrogen if Y is the S(0)nR2 radical, R1 is hydrogen, (Ci-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(CrC6)-alkyl, (Ci-C6)-alkyl-0-(CrC6)-alkyl, phenyl, phenyl-(CrC6)-alkyl, heteroaryl, (CrC6)-alkylheteroaryl, heterocyclyl, (CrC6)-alkylheterocyclyl, (Cr C6)-alkyl-0-heteroaryl, (CrC6)-alkyl-0-heterocyclyl, (CrC6)-alkyl-NR3-heteroaryl or (CrC6)-alkyl-NR3-heterocyclyl, where the 16 latter radicals are substituted by s radicals from the group consisting of cyano, halogen, nitro, OR3, S(0)nR4, N(R3)2, NR3OR3, COR3, OCOR3, NR3COR3, NR3S02R4, C02R3, CON(R3)2 and (CrC4)-alkoxy-(C2-C6)-alkoxycarbonyl, and where heterocyclyl bears n oxo groups, R2 is (CrC6)-alkyl, (C3-C6)-cycloalkyl or (C3-C6)-cycloalkyl-(CrC6)-alkyl, where these three aforementioned radicals are each substituted by s radicals from the group consisting of halogen and OR3, R3 is hydrogen or (CrC6)-alkyl, R4 is (CrC6)-alkyl, n is 0, 1 or 2, s is 0, 1,2 or 3.
Particular preference is given to inventive compositions which comprise, as herbicide (A), compounds of the general formula (I) and salts thereof in which A is N or CY, R is hydrogen, (Ci-C4)-alkyl, cyclopropyl, halo-(Ci-C4)-alkyl, (C3-C6)-cycloalkylmethyl, methoxymethyl, methoxyethyl, benzyl, X is nitro, halogen, cyano, (CrC6)-alkyl, halo-(CrC6)-alkyl, cyclopropyl, OR1, S(0)nR2, (Ci-C6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (CrC2)-alkylheteroaryl, (CrC2)-alkylheterocyclyl, where the two latter radicals are each substituted by s halogen, (Cr C6)-alkyl, halo-(CrC6)-alkyl, S(0)n-(Ci-C6)-alkyl, (Ci-C6)-alkoxy, halo-(CrC6)-alkoxy radicals, and where heterocyclyl bears n oxo groups, Y is hydrogen, nitro, halogen, cyano, (CrC6)-alkyl, (Ci-C6)-haloalkyl, OR1, S(0)nR2, S02N(R1)2, N(R1)2, NR1S02R2, NR1COR1, (C1-C6)-alkyl-S(0)nR2, (CrC6)-alkyl-OR1, (Ci-C6:}-aSky!-CON(R1)2; iCi-Cel-alkykSOsNiRns, (C-C An^RMR'COR1. (CvCR-alkyi-KlrGdQgR2, (Ci-Cehalkyiphenyi, (Ci-u&amp;j-aikylhsiero&amp;rvi, (Ri‘'^6y-s!kyihs|@ro:cyGlv!. phenyl* heieroaryl or heierocyclyl, where the 6: later radicals are each substituted by s radicals from the group consisting of halogen, nitro, cyano, (Gi-Ge/t-aikyl, halo-iCi-Ce)-alkyl, (Cs-CerRcycloaikyl, S{0)n~(Ci-Cs)-aiky!:i (CnCeRalkoxy, haie-(Gi-C6}~aikaxy, (Ci-C6>aikoxy-(Gi-G4)"aiky! and cyanomeihy!, and where heterocyoly! bears n oxo groups, 2 is halogen, cyano, nitro, methyl, haio-(Ci-Cel-alkyl, iCs-Csl-cydoalkyl, S.(0)MK 1,2,4-triazol-1-yi, pyrazoi-1-yl, or R1 is hydrogen, (Gi-Cel-aikyi, (Cz-CsRalkenyi:, (Go^sR-alkynyl, (Cs-GO-cycloaikyi, (G3-C6)~cycloalkyl-(Ci-G6)-alkyl, (Ci-Cel-aikyi-O-pwCeRaikyi, phenyl, phenyi-fCi-Cfi)-alkyl, heteraaryl, (Gi-Gel-alkylheteroaryi, heterocyclyl, {Ci-Cel-aikylheterocyclyl, |Ci-Gs)-a!kykQ-heteroaryi, (CnCs)~sikyi~0-heteroeyclyi,: {Ci~C6)~alkyl-MR3~beieroapyl or |Ci-G6)“alkyi-NR3-heterocyclyl, where the 16 latter radicals are substituted by s radicals from the group consisting of cyano, halogen, nitro, OR3, S(Q)nR4, N(R3}2, NR3OR3, GOR3, OGQR3, NR3COR3t NR3SG2R4, COsR3, CON(R3)2and IG1-G4V alkoxy-fCa-Cel-alkoxycarbonyi, and where heteroeyciyi hears n oxo groups, R2 is {Ci-Gel-alkyl, iOs-CeRoyoloalkyf or {G3-G6l-Gydoa!kyl-(Gi~G6)-aikyl, where these three aforementioned radicals are each substituted fey s radicals from the group consisting of halogen and OR3, R3 Is hydrogen or (C;-Cel-alkyl, R4 is (Ci-G^-alkyl, n is 0, 1 or 2, s is 0,1,1 or 3.
In the formula (1) and all the formulae which follow, alkyl radicals having more than two carbon atoms may be straighfechain: or branched. Alkyl radicals are, tor example, methyl, ethyl, n~ or l-propyl, rn, I-, t- orS-butyl, pentyls, hexyls such as n-hexyl, i-hexyl and 1,3~dimeihy;butyl. Analogously, alkenyl is, for example, ally!, 1mn€th0pfop-2-eo-t-yl, 2-“methylprop’-2-en--1--yL but-2-en- 1 -yl, hut-3-nn-1 -yl, T~methyibyt~3-e;vt~yi and 1-methyibut-2-eri-i~yl. Aikynyl is, for example, propargyi, but-2~yn-1-yi, but-3-ynl-yl, i-methylbut-3-y n-1 -yl. The multiple bond may be In any position in each unsaturaied radical. Cycloalkyl is a carbocyclic saturated ring system having three to six carbon atoms, for example eyeiopropyl, cydobutyi, cycio pentyl or cyolohexyl. Analogously, cycloaikenyi is a monocyclic alkenyl group having three to six carbon ring members, for example cyciopropehyl, cyclobutenyl. cyciopentenyl and cydohexenyi, where the double bond may be in any position.
Halogen is fluorine, chlorine, bromine or iodine.
Heterocycly! is a satumted, partly saturated or fully unsaturated oydic radical which contains 3 to 6 ring atoms, of which 1 to 4 are from the group of oxygen, nitrogen and sulfur, and which may additionally be fused by a benzo ring. For example, heterocydyi is piperidlnyi, pyrrolidinyi, tefrahydrofuranyi, dihydrofuranyi and oxeianyi.
Heteroaryi is an aromatic cyclic radical which contains 3 to 8 ring atoms, of which 1 to 4 are from the group of oxygen, nitrogen: and sulfur, and which may additionally be fused by a benzo ring. Heteroaryi represents, for example, benzimsdazo!-2-yl:j furanyl, imidazolyi, isoxazolyl, isothiazolyl, oxazolyi, pyrazinyl, pyrimidinyi, pyridazinyf, pyndinyl, behzisoxazoiyl, thiazoiyj, pyrrolyl, pyrazoiyi, thiophenyl, 1,2:13~oxadiazo!yi:, 1,2,4-oxadiazoiyi, i,2,5~oxadiazelyl, 1,3;,4~oxadiazoiyl, 1,2,4-tnazoiyi, 1,2,3-triazolyi, 1,2,5-triazolyi, 1,3,4-trlazolyi, 1,2,4-triazoiyi, ij^-thiadlazolyi, 1,3,4-tbiadiazolyi, 1,2,3-thiadiazoiyi, 1,2,5-thiadiazolyi, 2H-1,2,3,4-tetrazolyi, 114-1,2,3,446^3X010,1,2,3,4-oxatriazoiyl, 1,2,3,5-oxatriazolyi; 1,2,3,4-ihiafriazolyi and 1,2,3,S-thiatriazolyi.
When a group Is polysubstituted by radicals, this means that this group is substituted by one or more identical or different radicals from those mentioned. The same applies to the formation of ring systems by different atoms and elements, Aithe same time, the scope of the claims shall exclude those compounds known by the person skilled in the art to be chemicaiiy unstable under standard conditions.
The present invention also provides herbicide! compositions· comprising stereoisomers and mixtures thereof wHicH are encompassed by formula (!) or by the iohnutaeof component B. Such compounds of the formula (!) or of the formulae of component B contain, for example, one or more asymmetrically suhsdtuied carbon atoms or sulfoxides. The possible stereoisomers defined by the specific three-dimensional shape thereof, such as enantiomers and dfastereomers, are all encompassed by the formula (!) or by components (B) and (C); especially also theracemic mixtures and ~ where enantiomers are possible - both enantiomers and especially the respective biologically active enantiomer. The individual stereoisomers can be obtained by customary methods from mixtures of the stereoisomers or else be prepared by stereoselective reactions in combination with the use of stereochemioally pure starting materiais or auxlilaries.
Examples of compounds very particularly preferred as Herbicide (A) are listed in the tables which follow, in these tables, the abbreviations used mean:
Eft « ethyl jMe = methyl n-Pf ^ h-propyi i~Fr ~ isopropyl C“Pr 5* cyolopropyl Fh ~ phenyl Ac « acetyl i~Bu ~ isobutyi
Table 1: Compounds of the genera! formula (!) in which A is CY
Table 2: Compounds of the general formula (1} In which A is nitrogen
Preferred herbicides of group 81 are clethodlm, eethoxydirh.:, tepraioxydim, mesofrtone, suleotnone, tefurylfrione, tembotrione, hicyciopyrone, pinoxaden, iralkoxydim. Particularly preferred herbicides of group B1 are ciethodim (81-1), 0010010000 :(11--2), tefurylfrione (Bl -3), tembotrione (B1-4), hicyciopyrone pinoxaden (IB 1 ~β).
Preferred herbicides of group B2 are dimethenamide, dimeihenamide-P, naproparmde, pethoxamid, propyzamide, diflufenican, fjyfehaeet, mefenacet, pioolinafen, propanll, aceiochior, aiachlop butechior, metazaehior, metoiachfor, S-metoiachioo pretilachlor, thenyichiop esulam, oarbetamide, desmedipham, phenmedlpham, esprocarb, moilnate, prosyffocarb, thiobenoarb, arnidosuifuron, Ghlonniuron-efhyl, cyciosulfarnuron, elhoxysuifuron, ijupyrsulfurorwnethyl-sodiurn, foramsulfuron, lodosulfuron-methyi-sodium, roesosuifurcn-methyi, nicosulfuron, orthosuifamuron, prosuifuron, pyrazosylfuromefhyS, rirnsulfuron, trifloxysuifuroh (sodium), flucarbazone-sodium, propoxyoarbazone-sodium, thiencarhazone-methyl, fiorasulam, metoauiam, penoxsulam, meteulfuron-methyi, suifesuifuron. tbifeoeulfuron-methyL tribenuron--rnethyl, Iriiosulfuron, pyroxsuiam. rbI (θ;ΗΘ?' of ΟΓ-**^''Π R5* ?ΙΙ·”Θ H; γτ)a t-H0Γ«£>tTUCl 6**· Ρ ΓΒ?,1 V napropamide (82-2), difiuienican (82-3), fiufenaeel (82-4), raefanaoet 182-5). aoetochior (82-8), mefazachior (82-7), S-metoiaGhlor (B2-8), :asi)!arr! (82-9), desmedipham (82-10), phenroedipham (B2-11), moisnate (82-12), prosisffooarb (82-13), amidosulfuron (82-14), ethoxysuifuron (82-15), foramsulfuron (82-18), iodosuifurGn-methyi-sodsum (82-17), mesosuifuron-mefhyi (82-43), fludarbazone-sodium (82-19), propoxycarbazooe-sodium (B2-20), fhienGarbazone-methyl: (82-21}, floraaulam (82-22), metosulam (82-23), metsoifdroremefhyi (B2-24), sulfosuifuroa (82-25), ihiiensuifuron-meihyl (82-26), tnbenuron-mefhy! (82-27), tritosulfuron (B2-25), pyroxsuiam (82-29),
Preferred herbiddes of group B3 are broraoxynil (83-1) and ioxynii (83-2),
Preferred herbicides of group B4 are benzdfenap, topramezone, pyrasulfoiofe, IsoxaiiUtoie, imazarnox, imazefhapyr, oxadiargyl, oxadiazon, amiearhazone, carfenfrazone-ethyi, sulfentrazGhe, uniconazdle, caiensfrole, fenirazamida, 3-(3-chio?e-5-{f1-methyi-3-(infiuoromethyl)-1H-pyraZQi-5-y0oxy)phedexy)-1-methyi~8-(trifiuoromethyfel H-pyrazoie, 3-(3~iodo-5~{[1-meth:yi-3-(trifiuoromeihyO-1H-pyrazol-5-yi]oxy}phenoxy)-1 -mathyi-5-(trifiuorornethyl)-1 H-pyrazo!e, 1 -efcyP3-(3-f!udrO'-5-{[1 -rπeίhyi-3~(mfluoromethyi)-1H-pyrazc1-5-yί]oxy}ρl'^^r]OXy)-5-(trifiuoron^ethyϊ)-11-·|-pyrazoie, pyraflufen-ethyl
Pardoulariy preferred herbicides of group 84 are pyrasuifoiole (B4-1), isoxaflutoie (B4~ 2), oxadiargyi (B4-3), oxadiazon (B4-4), arrHcarbazoae (B4-5), fenirazamide (84-3). 3-(3-cbipro-5-([1-methyl-3-(trifiuerGmefhyi)~1 H-pyrazpl-S-ylJoxy)pteno>iy)4-m0jb^4“ (trifiuoromethyi)~1 H-pyrazoie (84-7), 3-(3-lodo-'5-{(1 -me!hy!-3-(trifiuororrsetHyi)-1 H~ pyrazoP5-yi]oxy}phenoxy)-1 -mefhy!-5~(tnf!uorometbyl)~1 H-pyrazoie (B4.8), 1 -etHyi-3-(3-5uore-5-{[1 -methyi-3-(trif1uorGmethyi>-1 H-pyrazof-5-yl|pxy|phenexy)~5" (irif!uoromethyl)~1 H-pyrazole (B4-9), pyrafiuien-efhyi (84-10), Imazarnox (84-11).
Preferred herbicides of group B5 are arninopyralid, benazolin, benfuresaie, beniazona, cinidon-ethyi, domazone, diquat dibromide, efhofumesate, fiuraiclorao-peniyf, fiumioxazin, flurtamone, oxaziciomefone, pendirneihaiin, pyridate and triiuraiin, Particuiariy preferred herbicides of group 85 are arninopyralid (85-1), benfuresafe (B5-2), eihofuroesafe (S6-3), flurtamone (85-4) and oxaziciomefone (85-5).
Preferred herbicides of group 86 are dicamba (86-1). dopyrsiid (B6-2). fiuroxypyr (B6~ 3), pidorarn (86-4), triciopyr (86-5). qusncioreo (B6-6).
Preferred herbicides of group 87 are anjlofos (®?-1}:,^gl:ulbSiRat^amm^riiu:fn (B7-2), 1-.-g i u tbs i n ate- a m rn ο π i u m (87-3), glyphosate (B7-4), glyphosate-isopropyi-ammonium (87-5), giyphcsate-ammonium (B7-6), glyphosaie-trirnesium (~suifosaie (87-7)), g! y pho saie-d la rn mo n iu m (87-7), glyphosate-pofassium (87-8).
Preferred herbicides of group 88 are acif ju orien-sodium, adonifen, fluorogiyeofen-ethyi, oxyiiuorien, hifenox, dichlorprop-P, meeopfop-P, 2,4-D, MCPA, clodinafop-propargyi, cyhaiofop-butyl, diclofop-methyi, dielofop-P-methyi, fenaxaprop-P~ethyi, iluazifap-P-foutyi, quizalofop-P,
Pariicuiariy preferred herbicides of group B8 are aelonifen (88-1), diclofop-methyi (88-2),. diciofop-P-rnethyi (88-3), fenoxaprop-P-ethy! (88-4), MCPA (88-5), 2,4-D (B8-8), ciodinafop-ethyi (88-7).
Preferred herbicides of group B9 are bispyribac (sodium), pyriffaiid, bromacii, ienaoii, 2-ch!oro-4~f!uoro-5~[3-meihyi-2,6-dioxo-4-(irif!uQromethyi)-3)8-dihydrQpynmMin-1(2H)- yij-N~[methyi(1~methyietbyl)suifamoylihenzamide,
Particularly preferred herbicides of group B9 are bispyribac (sodium) (8:9-4), bromacii (89-2).
Preferred herbicides of group BIO are cumyluron (810-1), daimuron (810-2), diuron (810-3), isoproturon (BIG-4), diflufenzopyr (B10-5).
Preferred herbicides of group 811 are atrazine, simazine,: terbuthylazine, ametryn, terbiitryn, metamitron, meinbuzin,
Parficuiariy preferred herbicides of group 811 are metamitron (811-1), mefribuzin (811-2), terbuthylazine (B11-2).
Examples of preferred compositions pfhei^jmdies.lAl^htf.herbtetdes |B) are given below. (A1 -18(81-1), (A1 -1 )-(61 -2), (A1 -1 )+(81-3), (A1-1)+(81-4), (Ai-i )+(81 -5), (A1-1)+(81-6):, (A 1-1 )7(132-1). (A1-1)-(82-2), (A1-1)+(82-3), (A1-1)+(62-4), (AI -1)+(82-5), (A1-1 )+(82-6), (A1-1 )+(82-7), (Al-1 )+(82-8), (AM )+(37-9), (AM )+(82-10). (AM )+(32-11). (A 1-1 )-(32-12). (AM )+(82-13). (Al-1 )+(82-14), {AI -1 )+(82-15), (AM )+(82-16), (Ai-1)+(82-17), (AM )+(82-18), (A1-1)+(82-19), (A1 -1 )+(82-20), (AM )+(82-21), (A1 -1 )+(82-22), (AM )+(82-23), (A1 -1)+(82-24), (A1-1 )+(82-25), (AM )+(82-26), (A1 -1 )+(82-27), (AM )+(82-23), (A1 -4)+(82-29), (AM)+(83-1), (AM )+(83-2), (A1 -1)+(84-1), (Ai-1)+(84-2), (AM )+(84-3), (A 1-1 )+(84-4), (A1-1 )+(84-5), (A1 -1 )+(8:4-6), (A1-1 )+(84-7), (A1 -1 )+(84-8), (Λ1-1)+(84-9), (AI-1)+(84-10), (A1 -1)+(84-11), (AI -1) +>(B5-1), (AI -1 >, (AI-1)+(85-3), (A1-1 )+(85-4), (AI-1)+(85-5), (AI-1)+(86-1):, (Α1-ί)+(Β3-2), (AI-1)+(86-3), (AM)+(86-4), (Al-1 )+(86-5), (AI-1)+(36-6),, (AM )+(87-1), (AI-1)+(87-2), (Al-1 )+(87-3), (Al-1 )+(87-4), (Al-1 )+(87-5), (AI-1:)+(87-6), (Al-1 )+(37-7)), (Al -1 )+(87-7), (AI-1 )+(87-8), (AM )+(83-1):, (AI-1)+(88-2), (A1-1)+(88-3), (A1-1)+(S8~4), (AM )+(88-5), (Al-15+(83-6):, (Al-1 ):+(88-7), (A1-1)+(88-1), (Al-1 )+(89-2), (Ai-1)+(810-1), (Al-1 )+(810:,2), (Al-1 )+(810-3), (A1 -1)+(8104), (A1 -1 )+(810-5), (A1-1 )+(811 -1), (Al-1 )+(81:4-2), (Al-1 )+(811 -2), (A1-2)+(B1-1), (AI -2)+(81-2), (AI-2)+(81-3), (A 1-2)+(81-4):, (A 1-2)+(81 -5), (AI-2)+(81-6), (A1-2)+(82-1), (A1 -2)+(82-2), (A1-2)+(82-3), (AI-2)+(82-4), (A1 -2)+(82,-5), (AI-2)+(82-6), (A1-2)+(B2-7), (A1-2)+(B2-8), (Ai:-2)+(82-9)> (A1 -2)+(82-10), (AI -2)+(82-11), (A1 -2)+(82-12), (Ai:-2)+(82-13), (A1 -2)+(82:-14), (A1 -2)+(82-15), (A1 -2)+(82-16), (A1 -2)+(82-17), (AI -2)+(82-18), (AI -2)+(82-19), (AI -2)+(82-20), (A1-2)+(82-21), (AI -2)+(82-22), (AI -2)+(82-23), (AI -2)+(82-24), (AI-2)+(82-25), (Ά1-2)+(82-26), (A1 ~2}+(B2-27), (Ai-2)+(82-28), (A1-2)+(82-29:), (A1 -2)+(83-1), (AI -2)+(83-2), (Ai-2)+(84-1), (A1 -2)+(84-2), (AI-2)+(84-3), (A1 -2)+(84-4), (A1 -2)+(84-5), (AI -2)+(84-6), (A1 -2)+(84-7), |Α1-2)+(Β4-8), (AI -2)+(84-9). (AI -2)+(84-10), (AI -2)+(84-11), (AI-2)+(85-1), (AI -2)+(85-2), (Ά1-2)+(85-3), (AI-2)+(85-4), (Al-2)+(B5-o), (AI-2)+(86-1), (A1-2)+(B6-2), (AI -2)+(86-3), (Ai -2)+(86-4), (A1-2)+(86-5), (A1-2)+(86-6), (AI -2)+(87-1), (A1-2)+(87-2), (AI-2)+(87-3), (AI-2)+(87-4), (A1-2)+(87-5), (AI -2)+(87-6), (A1 -2)+(87-7)), (A1 -2)+(87-7), (AI -2)+(87-3), (AI-2)+(88-1:),. (A 1 -2)+(88-2), (Ai-2)+(88-3), (A1 -2)+(88-4), (Ai-2)+(88-5), (AI-2)+(88-6), (AI-2)+(88-7), (AI -2)+(89-1), (AI-2)+(89-2), (Ai-2)+(810-1), (A1 -2)+(810-2), (AI-2)+(810:-3), (AI-2)+(810-4), (A1 -2:)+(810-6), (AI-2)+((511-1), (Al-2)+(B11-2). (AI-2)+(811-2), (AI-3)+(8:1-I), (AI-3)+(8:1-2), (Ai-3)+(81-3), (Αί-3)+(:Β1:-4), (AI-3)+(81-5), (A1-3)+(B1-6), (A1-3K(B2.1), (A 1-3)-^(82-2), (ΑΜΗ^3) (A1-3)+(B2-5). (Α1-35-ίΒ2-β), (Α1-φ(Β2-7), {ΑΙ-ΒΗ62"^ + (A1-3HS2-15) {A1-3H82-1®}, (A1-3WB2-iT), iAl-Si^bZ-lB/, (A1-3WB2-25). (A1 -3)+(62-26), (A1-3WB2-27), (A1-3)+(B2-z8) . (AMH .- -J), (A1-3)f(B3-1), (A1-3)HB3*2). (A1-3)+(B4-l), {A1-3)+iB4-2), (A1-3WB4-3), {A1-3)+(B4-4';, (A1-3)+(B4-5), (A1-3)+(B4-6). (A1-3WB4-7), (A1-3)+(B4-8). (A1 -3)+(84-9), (41 -3)+(84-10), (41+3)+(84-11¾ (41+3)+186-1¾ (A"-3)+(86-2¾ (A1 -3)+(65-3), (41 -3)+(85-4), (A1 -3)+(85-5), (Α'ϊ-3)+(66-1), (A 1-3)+ (83-2), (41 -3)+(86-3), (Al-3)+(B3-4), (41 -3)+(86-5), (41-3)+(86--5), ,(41-3)+(87-1), (41-3)+(67-2), (A1 -3)+(87-3:). :{A4 -3)+(67-4), (41-3)+(87-5), (41 -3)+(87-8), (41-3)+(87-7)), (41-3)+(87-7), (41-3)+(87-8): (41 -3)+(83-1), (41-3)+(88-211, (41-3)+(88-3), (41-3)+(88-4), (41-3)+(88-5),(4^3)+(:83-6), (41-3)+168-7), (41-3)+(89-1), (41-3)+(09-2), (41-3)+(819-1), (41-3)+(81(42), (41-3)+(810-3), (41-3)+(810-4), (41 -3)+(810-5), (41 -3)+(611-1)+ (41 -3)+(811-2), (41-3)+(8 (41 -4)+(81 -1), (41-4)+(81 -2), (41 -4)+(81 -3), (41-4)+(81-4), (41-4)+(:81 -5), (41-4)+(81-6), (41-4)+(82-1):, (41-4)+(82-2), (41-4)+(82-3), (41-4)+(82-4), (41-4)+(82-5), (41-4)+(82-6), (41-4)+(82-7),141-4:)+(:82-8), (41:-4)+(82-9), (41-4)+(82-10), (41-4)+(82-11), (41-4)+(82-12), (41-4)+(12-1:3), (41-4)+(62-14), (41-4)+(82-15), (41-4)+(82-16), (41-4)+(82-17¾ (:41-4)+(82-1:8), (41-4)+(82-19), (41-4)+(82-20), (41-4)+(82-21), (A1 -4)+(82-22), (41-4)+(82-,23), (:41-4)+(8:2-24), (41-4)+(82-25), (41-4)+(82-26), (41 -4)+(83-1), (41 -4)+(83-2), (41 -4)+(84-1), (41-4)+(8:4-2:), (A1 -4)+(84-3), (41 -4)+(84-4), (A1 -4)+(84-5), (41 -4)+(84-6), (41-4)+(84-7), :(41:-4)+(84-8), (41-4)+(64-9), (41+4)+(84-10), (41-4)+(84-11), (41-4)+(854), (41-4)+(85-2), (41-4)+(85-3), (41-4)+(85-4):, (41-4)+(85-5), (41-4)+(86-1 )f: (41 -4)+(:66-2), (41-4)+(66-3), (41 -4)+(86-4), (A1 -4)+(86-5), (41-4)+(86-6):,:(41 -4)+(87-1):, (41-4)+(87-2), (41+4)+(87-3), (41 -4)+(87-4), :(41-4)+:(87-3), (4:1-4)+(87-6), (41-4)+(87-7)), (41-4:)+(87-7), (Ά1-4}+(Β7-8}:, :(41-4)+(88-1):, (41-4)+(88-2), (41 -4)+(88-3), (41-4)+(88-4), (41 -4)+(86-5), (41 -4)+(88-6), (41-4)+(88-7¾ (41-4)+(89-1), (41+4):+(89-2), (41-4)+(810-1), (41+4)+(:810-2), :(41-4)+(810-3), (41 -4)+(810-4), (41-4)+(810-5), (41-4)+(811-14 (41-4)+(611 -2), (41 -4)+(811-2¾ (41-5)+(81-1:), (41-5)+(81 -2), (41-5)+(61-3), (41-5)+(81:-4¾ (41-5)+(81-5¾ (A1-SHS1 -6), (Al -5)+(82-1 ), (At-5)4(82-2), :475)+(82-3), (41-7+(82-7 (Al-5)+(82-5), (Ai ΑΗίΒΑδ), (Al-5)4-(82-7), (A1 -5)-4(82:-¾ ;(A1 -3)+(B2-9): (41-5)+(82-10), (Al-5)+(82-11), (Al~5>{B2~12), (Al-5)4(82-13):, (A 1-5)4(B2-15); (41-5)+(82-16), {A1^)+{B2~17), <Αΐ*δ)*(Β2ΑΤ8)ί ¥^^02^0), (A1 -5)4(82-20), (Al -5)+(82-21), (Al -5)+(82-22), (Al -5)+(82-23), (Al -5)+(82-24), (Al-5)4(82-25):, (A1 -5)+(82-28), (Al-5)+(82-27), (Al-5)+(82-28), (A 1-5)+(82-29), (Al -5)+(83-1), (Al -5)+(83-2), (Al -5)-4(84-1), (Al -5)+(84-2), (41-5)+(84-3), (Al-5)+(84-4), (Al-5)+(84-5), (A1 -5)4(84-8), (Al-5)+(84-7), (A1-5)+(84-8), (Al-5)4(84-9), (Al-5)+(84-10), (A 1-5)4(84-11), (Al-5)4(85-1), (A 1-5)4(85-2), (Al -5)4(85-3), (Al-5)4(8:5-4), (A1 -5)+(85-5), (Al -5)+(86-1 ), {A1-5)+(88-2), (A1 -5)+(85-3), (A1 -5)+(86-4), (Al -5)+(88-5), (41-5)+(88-6), (Al -5)+(87-1), (41-5)+(87-2), (At-5)+(87-3), (Al -5)+(87-4), (Al-5)+(87-5), (41-5)+(87-8), (Al-5)+(87-7)), (Al-5)+(87-7), (A 1-5)+(87-3), (Al-5)+(83-1), (Al-5)+(83-2), (Al-5)+(88-3), (Al -5)+(88-4), (A1-5)+(88-5), (Al -5)+(83-6), £41-5)+(88-7), (41-5)+(89-1), (Al-5)4(89-2), (A1-5)+(810-1), (Al-5)+(810-2), (A1-5)+(810-3), (Al-5)+(810-4), (Al-5)+(810-5). (41-5)+(811-1), (41-5)+(811-2), (475)+(81 1-2). (Al-8)+(81-1), (Al-6)+(81-2), (A1 -6)+(81 -3), (Al~6)+(B 1 -4), (Al-6)+(81-5), (Al-6)+(81 -8), (A 1-8)+(82-1), (Al-8)+(82-2), (A1-6)+(82-3), (Al-6)+(82-4), (Al-6)+(82-5), (Al -6)+(82-6), (Al-6)+(82-7), (Al-6)+(82-8), (Al -6)+(82-9), (A1 -6)+(82-10), (Al -6)+(82-11), (Al -8)+(82-12), (Al -6)+(82-13), (A1 -6)+(82-14), (A1 -8)+(82-15), (Al -6)+(82-16), (Al -6)+(82-17), (41-8)+(82-18), (A1-6)+(B2-19), (A1-41)+(82-20), (Al -6)4(82-21), (A1-6)+(82-227 (Al-8:)4(82-23), (Al -6)+(82,24), (41-6)+(82-25), (A1 -6)4(82-26), (41-6)+(82-27), (Al-6)+(82-28), (^1-8)+(82-29), (Al-6)+(83-1), (Al -6)-5-(83-2), (Al-6)+(84-1), (Al-6)-5 (84-2), (A 1-6)+(84-3), (Al -6)+(84-4), (A1 -6)+(84-5), (Al -6)+(84-6), (Al -6)+(84-7), (A1 -6)+(84-8), (Al-6)+(84-9), (Al -6)+(84-10.), {41-6)+(84-11), (Al -6)+(86-1), (Al -6)+(85-2), (A1 -6)+(85-3), (Al -6)+(05-4), (A1 -6)+(86-5), (Al -8)+(86-1:), (Al -6)+(86-2), (A1-6)+(86-3), (Al -6)+(86-4), (At-6)+(86-5), (Al-6)+(86-6), ^1-6)+(87-1), (41-6)+(87-2), (A !-0)+(87-3). (Al-6)+(87-4), (A1:-6)+(B7-5)f (A1-'6)+(B7-6), (M -6)+(87-7)), (Al -8)+(87-7), (Al -6)+(87-3), :(41-6)+(88-1), (A1 -6)+(83-2), (41-6)+(88-3), (A1-8)+(88-4), (A1-6)+(88-5), (A1 -6)+(83-8), (Al -6)+(83-7), (Ai -6)+(89-1)., (A1-6)+(89-2), (M -6)+(810-1), (A 1-6)+(810-2;, (Al-6):+(810-3), (Al-6)+(810-4), (Al-8)+(810-5), (A1>6)+(811-1), (.41-6)+(811-2), (41-0)+(81:1-2), (41-7)+(81-1), (41-7)+(81-2), (41-7)+(81-3), (41-7)+(81-4), (41-7)+(81-5), (A1-7)+(81-67 (AI-7)+(82-1), (AI-7)+(82-2), (41-7)+(82-3). (41-7)+(02-4), (AI-7)+(82-5), (41-7)+(82-6), (A1-7)+(82-7), (41-7)+(82-3), (41+7)+(82-91 (41+7)+(82-10), (A1-7)+(82-11), (A.1-7)+(B2-12>, (A1-7)+(82-13), (A1 -7)+(82-14), (A1-7)+(82-15), (A1 -7)+(82-16), (A 1 -7)+(82-17), (A 1-7)+(82-18). (A1 -7)+(82-19), (A1 -7)+(82-20), (Ai -7)+(82-21), (A1-7)+(82-22), (A1-7)+(82-237 (41-7)+(82-24), (A1 -7)+(82-25), (A1-7)+(82-26), (AI -7)+(82-27), (AI-7)+(82-28), (41-7)+(82-29), (AI -7)+(83-1), (AI-7)+(83-2), (AI-7)+(84-1), (A1-7)+(84-2), (AI-7)+(84-3), (AI-7)+(84-4), (AI-7)+(84-5), (A1-7)+(84-6), (AI-7)+(84-7), (AI-7)+(84-8), (AI-7)+(84-9), (A1 -7)+(84-10), (AI-7)+(84-11), (AI-7)+(86-1), (AI-7)+(85-2), (AI-7)+(85-3), (AI -7)+(85-4), (A1-7)+(85-5), (AI-7)+(86-1), (AI-7)+(88-2):, (AI-7)+(86-3), (A1-7)+(86-4), (Ai-7)+(86-5), (AI-7)+(86-6), (AI-7)+(87-1), (A1 -7)+(87-2), (AI-7)+(87-3), (AI-7)+(87-4), (A1 -7)+(87-5), (41-7)+(87-6), (AI -7)+(87-7)), (A1-7)+(87-7), (AI -7)+(87-8), (At-7)+(88-1), (41+7)+(06-2), (41-7)+(88-3), (A1-7)+(88-4), (AI -7)+(88-5), (AI -7)+(88-6), (A1-7)+(86-7), (41-7)+(89-1), (A1-7)+(89-2), (A1 -7)+(810-1), (AI -7)+(810-2), (AI-7)+(819-3), (AI -7)+(810-4), (At-7)+(810-5), (AI-7)+(811-1), (41-7)+(811-2), (AI -7)+(811-2), (AI-3)+(81-1), (Ai-8)+(81-2), (41-8)+(81-3), (AI -8)+(81-4), (AI -8)+(81 -5), (A1-3)+(81-6), (AI-3)+(82-1), (AI -8)+(82-2), (A1-8)+(82-3), (AI -8)+(82-4), (Ά1-3)+(82-5), (AI-8)+(82-6), (AI-3)+(82-7), (AI -8)+(82-8), (AI-8)+(82-9), (A1-8)+(82-10), (AI -8)+(82-11), (At-8)+(8242), (AI-8)+(82-13), (AI -8)+(82-14),. (AI-3)+(82-16), (AI-8)+(82-16), (AI-8)+(82-17), (AI-6)+(6.2-18), (At-8)+(82-19), (AI-3)+(82-20), (A1 -8)+(82-21), (41-3)+(82-22), (At-8)+(82-23), (41-8)+(82-24), (41-8)+(82-25), (AI-3)+(82-26), (41-8)+(82-27), (41-8)+(82-28), (41-8:)+(82-29), (AI-8)+(83-1), (A1 -8)+(83-2), (AI -8)+(84-1), (AI -8)+(84-2), (AI-8)+(84-3), (41-8)+(84-4), (AI-3)+(84-5), (A1-8)+(64-6), (Ai-8)+(84-7), (41-8)+(04-8), (AI-8)+(84-9), (AI-3)+(84-10), (A1 -8)+(84-11), (AI -8)+(85-1), (41-8)+(85-2), (A1-8)+(85-3), (41-3)+(85-4), (41-3)+(85-5), (AI -8)+(86-1), (41-8)+(86-2), (41 -8)+(86-3), (AI -8)+(86-4), (AI -8)+(86-5), (AI-8)+(86-6), (41-8)+(87-1 % (AI -8)+(87-2), (AI -8)+(87-3), (A1 -8)+(87-4), (AI-8)+(87-5), (4,1-3)+(87-6), (AI-8)+(87-7)), (AI-8)+(87-7), (Ai-8)+(87-8), (At-8)+(86-1), (Ai-8)+(88-2), (41-8)+(88-3), (A1 -8)+(88-4), (41-8)+(88-5), (41-8)+(83-6), (41-8)+(88-7), (41-8)+(89-1), (AI -8)+(89-2),. (AI-3)+(810-1), (41-8)+(810-2), (41-8)+(810-3), (41-8)+(810-4), (41-8)+(810-5), (41-8)+(811-1), (41-8)+(811-2), (41-8)+(811-2), (41-9)+(81-1), (41-9)+(81-2), (41-9)+(81-3), (41-9)+(81-4), (41-9)+(81-6), (Ai-9)+(81-6), (Ai -9)+(82-1), (AI -9)+(82-2), (AI -9)+(82-3), (A1-9)+(82-+), (A'l -9)+(82-5), (AI-9)-+(82-6), (Ai-9)-:-(82-7), (AI-9)+(82-8), (At-9)+(82-9), (AI-9)+(62-10), (AI -9)+(62-11), (AI -9)+(82-12), (AI -9)+(62-13), (A1 -9)+(62-14), (A1-9)+(62-16), (.41-9)+(62-16), (AI -9)+(62-17), (41-9)+(62-46), (M-9)+(82-19), (AI -9)+(82-20), (AI -9)+(62-21), (AI -9)+(62-22), (41-9)+(82-23), (41-9)+(82.24+ (AI-9)+(82-25), (AI-9)+(82-26), (AI -9)+(82-27), (41-9)+(82-20), (AI -9)+(82-29), (41-9)+(63-1), (AI-9)+(83-2), (AI-9)+(64-1 ), (A1-9)+(84-2), (A1-9)+P^3)s (AI-9)+(64-4), (At-9)+(84-5), (AI-9)+(84-6), (AI #)+(84-7), (A1-9)^(B4-8), (AI -9)+(64-9), (AI -9)+(84-10), (At-9)+(64-11), (At-9)+(65-1), (41-9)+(65-2), (AI -8)+(85-3), (A1 -9)+(65-4), (A1 -9)+(65-5), (At-9)+(65-1), (At-9)+(66-2), (AI-9)+(86-3), (A1-9)+(86-4), (AI -9)+(66-5), (AI-9)+(86-6), (41-9)+(87-1}, (41-9)+(67¾ (A 1-9)+(87-3), (A 1-9)+(67-4), (A 1-9)+(87-5), (AI -9)+(67-6), (AI-9)+(67-7)), (AI-9)+(67-7), (41-9)+(87-8), (41-9)+(88-1), (AI -9)+(138-2)¾ (41-9)+(86-3), (41-9)+(86-4), (41-9)+(88-5), (41-9)+(66-6), (41-9)+(88-7), (A 1-9)+(89-1), (AI -9)+(69-2), (41-9)+(610-1), (41 -9)+(810-2), (41 -9)+(810-3¾ (41-9)+(610-4), (41-9)+(810-5), (41-9)+(611-1), (41-9)+(611-2), (41-9)+(811¾ (41-10)+(61-1), (41-10)+(61-2), (41-10)+(81-3), (41-10)+(81-4), (41-10)+(81-5), (AI-10)+(81-6), (41-10)-:-(82-1), (A1 -10)+(82-2), (41-10)+(82-3), (41-10)+(62-4),.. (41-10)+(82-5), (AI-10)+(62-6), (41-10)+(82-7), (AI-10)+(82-8), (AI-10)+(82-9), (AI-10)+(82-10), (A 1 -10)+(8 2 -11), (A 1 -10)+(132-12),. (AI -10)+(8 2-13), (41-10)+(82-14), (41 -10)+(82-15), (41-10)+(62-16), (AI-10)+(82-17), (AI -10)+(82-18), (AI -10)+(82-19), (41-19)+(82-20), (AI-10)+(82-21), (AI-10)+(82-22), (AI-10)+(62-23), (41-10)+(82-24), (41-10)+(62-25), (41-10)+(82-26), (41-10)+(82-27), (A! -10)+(82-28), (41-10)+(82-29), (41-10)+(83-1), (Ai-10)+(63-2), (AI-10)+(84-1), (41-10)+(84-2), (41-10)+(84-3), (41-10)+(64-4), (41-10)+(84-5), (41-10)+(64-6), (AI-10)+(84-7), (AI -10)+(84-8), (41-10)+(84-9), (A1 -10)+(84-10), (41 -10)+(84-11), (AI-10)+(85-1), (AI-10)+(65-2), (41-10)+(85-3), (41 -10)+(85-4), (AI -10)+(65-5), (A1 -10)+(68-1), (41 -10)+(66-2), (A1 -10)+(86-3), (AI-10)+(66-4), (41 -10)+(68-5), (AI-10)+(86-6), (41 -10)+(87-1), (41-10)+(67¾ (AI-10)+(67-3), (41 -10)+(87-4:), (41-10)+(87-5), (AI-10)+(87-8), (41-10)+(87-7)), ‘CA1 -1(A1+1 Ρ>^(ΒΤ-8),. :(41-10)+(68¾ (41-10)+(83-3), (41-10)+(88-4), (41-10)+(68-5), (41-10.)+(68-6), (41-10)+(68-7), (41-10)+(89-1), (41-10)+(89-2), (41-10)+(610-1), (41-10)+(810-2), (41-10)+(610-8), (A1 -10)+(610-4), (AI -10)+(810-6), (AI -10)+(611 -1), (41-10)+(611 ~2),: (AM 0)+(6+14), (A1-11 )-5-(01 -1), (A1 -11 )-(61 -2), (A1.11)-(61 -3), <A141)+(81-4), (Al-11 )+(31-5), (A1--11 )+(61-8), (Al-11 )+(824 }t (Al-11)+(62-2),(AM 1 )+(82-3+(£.141)+(62-4), (Al-11)+(62-5), (AM 1 )+(82-8), (A1-11)+(82-7), (A1-11 )+(82-8), (Al-11 )+(824)), (A141 )+(82-10), (AMI )+(62-11), (Al -11 )+(82-12), (Al-11 )+(82-13), (Al-11 )+(8244), (A14:1 )+(6245),. (A1 -11 )+(82-18), (Al-11 )+(82-17), (Al-11)+(82-18), (AM 1 )+(8249), (A1 -11 )+(82-20), (Al-11)+(82-21). (A141)+(62-22), (A141)+(82-23), (AM 1 )+(82-24), (Al-11)+(82-25), (A1-11 )+(62-26), (Al -11 )+(82-27), (Al -11)+(62-28), (Al-11 )+(62-29), (A1 -11 )+(83-1), (Al -11 )+(83-2), (A1 ~11 )+(84-1), (Al-11)+(84-2), (Al-11)+(84-3), (A1 -11)+(84-4), (Al-11 )+(84-5), (A1 -11 )+(84-6):, (Al-11)+(84-7), (A1 -11 )+(64-8), (AM 1 )+(84-9), (Al-11)+(84-10), (A141 )+(8441), (A141)+(85-1), (Al-11)+(136-2), (AM 1)+(85-3):, (Al-11)+(85-4), (Al-11)+(85-5), (Al-11)+(86-1), (A141)+(86-2), (A'l 41)+(66-3), (A141 )+(66-4), (AM1 )+(66-5), (Al-11)+(66-6), (Al -11:)+(87-1), (Al 41 )+(87-2), (Al -11 )+(67-3), (Al -11 )+(67-4), (AM I )+(67-5), (Al-11 )+(137-0), (AI-11 )+(87-7)), (AM1)+(87-7), <Al4i )+(B7^), (AM1 )+(88-¾. (Al41 )+(83-2¾ (Al-11)+(88-3), (Al-11 )+(88-4), (A1-11 )+(88-6), (Al-11.)+(88-6), (AM 1 )+(63-7), (AM 1 )+(89-1), (Al-11 )+(89-2), (Al-11 )+(819-1), (Al-11 )+(810-2), (A.1 -11 )+(810-3), (Al-11 )+(810-4), (Al41 )+(810-5), (Al-11 )+(611 -1), (Al -11:)+(811 -2), (AM1)+:(811-2), (AM2)+(61-1), (Al-12)+(61-2),(Α1-12)+(Β1·3), (^44.2)+(81-4¾ (Al 42)+(811¾ (Al-12)+(61 -8), (Al -12)+(62-1), (Al -12)+(62-2), (Al -12)+(82-3:), (A14 2)+(82-4), (Al-12)+(82-5), (Al-12)+(82-8), (A1 -12)+(62-7), (AM2)+:(62-8), (Al-12)+:(82-3), (A1-12j+(82-10), (Al-12)+(8241), (A1-12)+(8242),(A1-12)+(8243), (Al-12)+(62-14), (Al-12)+(82-15), (A1 -12)+(62-18), (AM2)+(62-17), (Al-12)+(62-16), (Al-12)+(82-19), (Al-12)+(62-20), (Al-12)+(82-21), (A 1-12)+(82-22), (Al-12)+(82-23), (AM2)+(62-24), (Al-12)+(82-25), (Al-12)+(82-28), (AM2)+(62-27), (Al4 2)+(82-28), (A142)+{B2-29), (At- ;2Mts3~1 i, (Al-12)+(83-2), (Al 4 2)+(844):, (Al-12)+(84-2), (Al 42)+(84-3):, (AM2)+(b4~4+ (Al 42)+(64-5), (A1 -12)+(84-6), (Al-12)+(64-7), (A142)+(84-8), (A1 -12)+(64-9), (Al-12)+(64-10), (Al 4 2)+(8441), (Al42)+(65-1), (AM2)-(85-2), (AM2)+(85-3), (Al-12)+(86-4), (Al-12)+(85-5), (Al-12)+(66-1), (A1-i:2)+(86-2), (A 8-12)+(80-4), (Al-12)+(86-4), (Al4:2)+(86-5), (Al42)+(86-61, (ΑΜ2)+ίΒ74), {A1~12)+(B7~2), (41-12)+(87-3), (A1-12)+(87-4-), (A1-12}+(B7-5), (A1-12MB7-6), (A1 -12H(B7-7}).: (A1 -12)+(87--7), (A1 -12)+(87-8), (Ai-12)+(88-1). (A1-12)--(38-2). (A1-12)+(88-3), (Ai-12)+(88-4), (A1-12)+(88-5), (Al-12)+(88-6),: (A1-12)+(88-7), (A.1-12)+(89-1), (A.1-12)+(89-2), (A1-12)+(810-1), (A1-12)+(810-2), (AI-12)+(810-3), (A1 -12)+(810-4), (A1 -12)+(810-5), (AI -12)+(811 -1),. (A1-12)+(811-2), (AI-12)+(811-2), (AI-13)+(81-1), (A1-13)+(81-2), (AI-13)+(81 -3), (AI-13)+(81-4), (AT-13)+(81-5), (A1-13)+(81-6), (A1-13)+(82-1), (A1-13)+(82-2), (AI -13)+(82-3), (AI-13)+(82-4), (AI-13)+(82-5), (AI-13)+(82-6), (A1 -13)+(82-7), (A1-13)+(82-8), (AI-13)+(82-9), (AI-13)+(82-10), (AI-13)+(82-11), (AI-13)+(82-12), (AI-13)+(82-13), (AI-13)+(82-14), (AI-13)+(82-15), (AI-13)+(82-16), (AI -13)+(82-17), (AI-13)+(82-18), (At-13)+(82-19), (AI-13)+(82-20), (AI-13:)+(82-21), (Al-13)+(82-22), (AI-13)+(82-23), (AI-13)+(82-24), (A1 -13)+(82-25), (A't-13)+(82-26), (AI-13)+(82-27), (Ai-13)+(82-23), (A1-13)+(82-29), (AI-13)+(83-1), (A1-13)+(83-2.), (A1 -13)+(84-1), (Ai-13)+(84-2), (AI-13)+(84-3), (AI-13)+(84-4), (AI-13)+(84-5), (AI-13)+(84-6). (A1-13)+(84-7), (AI-13)+(84-8), (AI-13)+(84-9), (A1·-13)+(84-10), (A1 -13)+(84-11), (A1 -13)+(85-1), (AI-13)+(85-2), (AI-13)+(85-3), (A1-13)+(85-4), (A1 -13)+(85-5), (AI-13)+(86-1), (A1 -13)+(86-2), (AI-13)+(86-3), (AI-13)+(86-4), (At-13)+(86-5), (Al-13)+(86-6), (Ai-13)+(87-1), (AI-13)+(87-2), (Al-13)+(87-3), (Al-13)+(87-4), (Al-13)+(87-5), (Al-13)+(87-6), (AI-13)+(87-7)), (Al-13)+(87-7), (Al-13)+(87-8), (Al-13)+(86-1), (Al-13)+(88-2):, (Al-13)+(88-3), (A1-13)+(88-4), (A1-13)+(88-5), (Al-13)+(88-6), (Al-13)+(88-7), (Ai-13)+(89-1), (Al-13)+(89-2), (A1-13)+(810-1),. (AI-13)+(810-2), (A1-13)+(B10-3), (A1-13)+(810-4), (Al-13)+(810-5), (A1-1,3)+(81:1-1), (Al-13)+(811-2), (AI-13)+(811-2), (A1-14)+(B1~1), (AI-14)+(81-2), (A1~14)+(B1~3), (Al-14)+(81-4), (Al-14)+(81-5), (Al-14)+(81-6), (A1-14)+(B2-1), (A1 -14)+(82-2), (A1 -14)+(82-3), (Al-14)+(82-4), (At-14)+(82-5), (At-14)+(82-6), (Al-14)+(82-7), (Al-14)+(8:2-6), (Al-14)+(82-9), (AI-14)+(82-10), (A1-14)+(82-11). (Al-14)+(82-12), (Al-14)+(82-13), {.41--14)+(82-14), (A1 -14)+(82-15), (Al-14)+(82-16), (Al-14)+(82-17), (AI-14)+(82-18), (A1 -14)+(82-19), (AI-14)+(82-20), (A1 -14)+(82-21), (A1-14)+(82-22), (Al-14)+(82-23), (Al-14)+(82-24), (A1-14)+(82-25), (A1 -14)+(82-26), (AI-14)+(82-27), (AI -14)+(82-26), (A1 -14)+(82-29), ^1.14)+(83-1¾ (A1-14)+(83-2), (A1 -14)+(84-1), <Α1-14)+(84-2): (A1-14)+(84-3¾ (41-14)+(84-4), (A1 -14)+(84-5¾ (A1 -14)+(84-6):, <A1 -44)+:(84-7),(A1-14)+(84-:3), (A1 -14)+(84-9), (A1 -14)+(B4-10), (AM4)+(84-11),. (AM 4)+(86-1), (AM 4)+(85-2), (A1 -14)+(85-3), (A1-14)+(65-4)., :(A1 -14)+(85-5), (A1 -14)+:(86-1), (AM 4)+(86-2¾ (A1-·14)+(86-3), (AI-14)+(86-4), (A1 -14)+(86-5), (AI-14)+(86-8¾ (A1-14)+(87-1¾ (A1-14)+(B7-2), (AM 4)+(87-3), (Al-14)+(87-4), (AM 4)+(87-5¾ (A1 -1:4)+(87-6), (A1 -14)+.(87-7)), (A.1 -14)+(87-7), (A1 -14)+(87-8), (At-14)+(:88-1), (A1 -14)+(88-2¾ ^A1-14)+(88-3), (A1-14)+(88-4), (A1-14)+(88-6), (A1-14)+(88-6), (AI-14)+(88-7¾ (A1 -14)+(89-1), (A1 -14)+(89-2),. (A1 -14)+(810-1:), (A1 -14)+(810-2), (A1 -1:4)+(810-3:):, (A1-14)+(810-4), (AM4)+(810-5), (AM4)+(B1M), (AM4}+(B11-2), (ΑΊ-14)+(811-2), (A 1 -15)+(81-1), (A1 -15)+(81-2), (AM 5)+(81-3), (AM 5)+(81 -4), (A1 -15)+(81 -5¾ (A1-15)+(81-6), (A1-15)+(82-1), (A1-15)+(82-2), (AM 5)+(82-3), (A1-15)+(82-4), (A1-15)+(82-5), (AM 5)+(82-6), (A1-15)+(82-7), (AI-15)+(82-8), (AM 5)+(82-9¾ (AM5)+(8240¾ (A1 -16)+(82-11), (A1 -15)+(82-12), (At-15)+(82-13), (AM 5)+(82-14), (A1 -15)+(82-15), (AM 5)+(82^16), (AM 5)+(82-17), (AI-15)+(82-18), (AI-15)+(82-19), (AM 5)+(82-20), (AM 5)+(82-21), (A1 -15)+(82-22), (A1 -15)+(82-23), (A1 -15)+(82-24), (AM 5)+(82-26), (AM 5)+(82-26), (AM 5)+(82-27), (AM 5)+(82-28), (A1-15)+(82-29¾ (AM5)+(83-1), (A1 -15)+(83-2), (A1 -15)+(84-1), (AM 5)+(84-2), (AM5)+(84-8), (AM5)+(84-4), (A1 -15)+(84-5), (AM 5)+(844¾ (AM 5)+(84-7¾ (AI-15)+(84-8), (A1 -15)+(84-9), (A1 -15)+(84-10), (AM 5)+(84-14¾ (AI-15)+(85-1), (A 1 -15)+(85-2), (AI-15)+(85-3), (AI-15)+(85-4), (AI-15)+(85-5), (A1-15)+(B6-1), (AI-15)+(86-2), (AI-15)+(86-3),, (AI-15)+(86-4), (A1-1.5)+(86-8¾ (A1-15)+(86-6), (AM 5)+(87-1), (AM 5)+(67-2), (AI-15)+(87-3), (A1 -15)+(87-4), (AM 5)+(87-5), (A1-1:6)+(87-6), (AM5)+(B7~7)), (AI-15)+(87-7), (AI-15)+(87-8), (A1 -15)+(88-1), (AM5)+(B8-2), (A1 -15)+(88-3), (A1 -15)+(88-4), (A1 -15)+(88-6), (AM 5)+(88-6), (A1 -15)+(88-7¾ (A1 -15)+(89-1), (A1 -15)+(89-2), (A1 -15)+(810-1):, (AM 5)+(81 G-2), (AI-15)+(810-3), (AM 5)+(810-4¾ (A1 -15)+(810-5), (A1 -15)+(811-1¾ (AI-15)+(811-2), (AI-15)+(811-2), (AM6)+(81 -1), (AI-16)+(81 -2), (A1 -16)+(81 -3), (A1 -16)+(81 -4), (A1 -16)+(81-5), (A1 -16)+(81-6¾ (AM6)+(82-1:), (A1 -16)+(82-2), (AI-16)+(82-3), (A1 -16)+(82-4):, (A1 -16)+(82-5), (A1 -16)+(82-6), (AI-16)+(82-7), (A 1--16)+(B2-B), (AI-16)+(82-9), ('41-"16)+(82-107 (Al 469-(8241,). (Al -16)48242). (AM6)-(82-13), ^446,)+(8244)., (Al -16)-(32-15), (A"i-16)+(1:12-1:6). :(AM.6.)+(B24:7), ^146)+(8248), (A1--1 6)-(82-19), (A14 6)+(82-20), (Α146}+(Β2-21), )Ai 46)+(82-22), (Al 48)+(82-23), (Al -16)+(82-24), (Ai46)+(B2-257 (A1 -16)+(82-28), (A1 -16)+(82-27), (A1 -18)+(82-28), (At4 6)+(82-23), ;A1,16)+(83-1), (A14 6)+(83-2), (A1 ~18)+(844 )f (A146)+(84-2), (A1-16)+(84-3), (A1Ί 5)+(84-4), (A1-16)+(84-5), (A1 -16)+(84-6), (Α1-1'βΗ8Φ7), (A1-16)+(84-9), (A! -16)+(84-10), (Al -18)+(84-11), (A1 -16)+(86-1), (A1 -16)+(85-2), (A1-16)+(85-3), (A1 -13)+(85-4), (AM6)+(85-6), (A1-16)+(88-1 | (Al4 6^(136-2), (A14 8)+(86-3), (A1-18)+(86-4), (A1-18)+(88-5), (A1 -16)+(88-6), (A1-48)*(B74), (A14 6)+(87-2), (Al -16)+(87-3), (A1 -18)+(87-4), (A1-18)+(87-5), (AI46)+(87-8), (^146)+(87-7)), (A1-16)+(87-7): (Al -16)+(87-8), (A1-18)+(88-1), (Αΐ46)4Β8-2), (A1 -16)+(88-3), (Al-1 6)+(88-4), (A 1 --16)+-(B8-5), (A 1-16)+(88-6), (Al-.ig^+^g,,·^ (A1-16)+(89-1), (Al -16)+(89-2), (Al -16)+(810-1), (Al -16)+(810-2), (Al-16)+(810-3), (A1 -16)+(810-4), (Al -16)+(810-5), (Al -16)+(811-1), (Al-16)+(011 -2),. (A 1-16)+(811-2), (Al-17)+(81-1}, (AM 7)+(81-2), (A1-17)+(81-3), (A 1-17)+(81-4), (Al47)+(814%. (Al-17)+(81-6), (A1 -17)+(82-1), (A1 -17)+(82-2), (Al -17)+(82-3), (A1-17)^182-4), (AM7)+(82-5), (Al47)+(82-6), (Al-17)+(82-7), (A1-17)+(82-8), (Αΐ47)*(Β2_£% (A1 -17)+(82-10), (Al 4 7)+(8241), (Al 4 7)+(82-12), (Al -17)+(82-13). (Al-17)+(82-14), (Al-17)+(82-15), (A 14 7)+(8246), (Al-17)+(82-17), (Al -17)+(82-13), (Al -17)+(82-19), (A1 -17)+(82-20), (Al47)+(82-21), (Al -17)+(82-22), (Al -17)+(82-23), (Al -17)+(82-24), (Al -17)+(82-26), (Al-17)+(82-26), (Al-17)+(82-27), (Al-17)+(82-23), (Al-17)+(82-29), (Al-17)+(83-1), (A 1-17)+(83-2), (Al 4 7)+(84-1), (Al-17)+(84-2), CA147^B4^ (A1 -17)+(84-4), (Al-17)+(84-5), (Al-17)+(84-6), (Al-17)+(84-7), (AM 7)+(^4^ (Al-17)+(84-9), (Al 4 7)+(84-10.), (Al-17)+(84-11),. (A147)+(85-1), (A1,17)+(86-27 (Al -17)+(85-3), (Al 47)+(85-4), (A1 -17)+(85-5), (Al -17)+(86-1), (Al4 7)+(86-2), (Al-17)+(86-3), (Al -17)+(86-4), (A1 -17)+(86-5), (A1-17)+(86-6), (41.-1:7)+0741). (Al-17)+(8 7-2), (Al-17)+(87-3), (AM7)+(87-4), (Al-17)+(87-5), ίΜ-ί7)^(βΤ^ι (Al 47)+(87-7)), (A14 7)+(87-7), (Al -17)+(87-8), (Al-17)+(88-1), (Al47)+(88-2), (A14 /)+(88-3), (41-17)+(88-4), (Al4 7)+(88-5), (A1 47)+(86-6), (At-l 7)+(1314^ (A14 7)+(89-1), (A! -17)+(89-2), (A 1 -17)+(8 ID-1)..(A1-17)+(816-2), (A 1 «17)+( B10-3), (Al -17)+(810-4), (Al 4 7)+(110-5), iA14 7)+(811-1), (AM7)+(811-2), (AM7)+:(811-¾ (A1--18)+(81-1), (AI -18)+(01 -2), (A1-18)+(81 -3), (A1-18)+(81-4}, (A1 -18)+(61 -6), {AM8)+(82-1 ), (A1 -18)+(82-2), (A1 -18)+(82-3¾ (41 -18)+(82-4), (41-18)+(82-5), (41-18)+(82-6¾ (4148)+(82-7¾ (41-185+(82-8), (41-185+(82-9), (41-18)+(82-10), ,(41-18)+(82-11)^(41-1.8)+(82-12),/(41-18)+(82-18), (41 -18)+(82-14), (41-18)+(82-18), (Ai -16)+(02-16¾ (41-18)+(82-17), (A1-18)+(82-18), (A1 -18)+(82-19), (AM 8)+(82-20), (41 -18)+(82-21), (Ai-18)+(82-22), (41-18)+(82-23), {41-18)+(82-24), (41-18)+(82-25), (A1 -18)+(82-28), (AM 8)+(82-27), (41 -18)+(82-28), (41 -18)+(82-29), (4148)+(88-1.), (AM8)+(83-2), (41 -18)+(84-1), (41-18)+(84-2), (41:-18)+(84-3), (41-18)+(84-4), (41-18)+(84-5), (41-18)+(84-8), (41-18)+(84-7), (41-18)+(84-8), (41-18)+(84-9), (41-18)+(84-10), (41-18)+(84-11), (AM8)+(86-T), (41-18)+(85-2), (41-18)+(85-3), (41-18)+(88-4), (41-18)+(85-5), (AI-18)+(88-1), {41-18)+(80-2), (AM8)+(86-3), (41 -18)+(86-4), (41 -18)+(86-5), (41 -18)+(86-8), (41 -18)+(87-1), (41-18)+(87-2), (41-18)+(87-3), (AI-18)+(87-4), (41-18)+(07-5¾ (41-18)+(07-6¾ (41 -18)+(87-7)), (41-18)+(87-7), (41 ~i 8)+(87-8), (41 -18)+(88-1), (41-18)+(88,2), (41-18)+(88-3), (41-18)+(88-4), (AM 8)+(88-5¾ (41-18)+(88-6), (41-18)+(88-7), (41 -18)+(89-1), (41-18)+(89-2), (41 -18)+(810-1), (41 -18)+(8104¾ (41 -1:8)+(810-3), (41-18)+(810-4), (41-13)+(010-5), (41-18)+(811-1), (41-18)+(811-2), (41-18)+(811-2), (41-19)+(81-1), (41-13)+(81-2), (41-19)+(81-3), (41-19)+101-4), (41-19)+(81-5), (41-19)+(81-6), (41-19)+(82-1¾ (41-19)+(82-2),: (41-19)+(82-3), (41-19)+(82-4), (41-19)+(82-5), (41-19)+(82-8), (41-19)+(02-7), (41-19)+(82-8), (41-19)+(82-9), (41-19)+(02-10), (41-19)+(82-11), (41-19)+(82-12), (41-19)+(82-13), (41-19)+(02-14), (41-19)+(02-15), (41-19)+(82-16), (41-19)+(82-17), (41-19)+(82-18), (41 ~19)+(82-19), (41 -19)+(82-26), (41-19)+(82-21), (41 -19)+(82-22), (41-19)+(82-23), (41 -19)+(02-24), (AM 9)+(82^5¾ (41 -18)+(02-26), (41 -19)+(82-27), (41 -19)+(82-28¾ (41 -19)+(02-29), (41-19)+(83-1), (41 -19)+(83-2¾ (41 -19)+(84-1), (41 -19)+(04-2), (41-12)+(84-3¾ (41 -19)+(84-4), (41 -19)+(84-5), (41 -19)+(04-8), (41 -19)+(04-7), (41 -19)+(84-8), (41-19)+(84-0), {41-19)+(04-10¾ {41-19)+(84-11):, (AI-19)+(86-1), (41 -If )+(85-2), (41-19)+(85-3¾ (41 -12)+(85-4), (41 -19)+(86-5), (41 -19)+(08-1), (41 -19)+(86-2), (41-19)+(08-3), (A1~13)+(86-4¾ (AI -19)+(86-5), (AI -19)+(00--8):, :(41-19)+(87-1), (AΜ9we7.·2). ;Αΐ··ΐ9)~-(Β7“3) (A1-19)+(87-43 (A1-19KB7-5). (ΑΙ-19)+(87-6¾ (Α1 ^9)^(37-.7)):, (ΑΙΑ9)+(87-7), (ΑΙ -19)+.(87-8), (41-19)+-(88-1), (ΑΙ-19)+(88-2), (Α1-19)+(88-3), (Αΐ A 9)+(88-4), (Α1-19)+-(88-5), :(Α1-1:9)+(88~·8}, (Α1-19)+(88-7), (Α1-19)+(89-1), (Α1 -ΐ 9)+(89-2), (AVI 9)+(810-1), (Α1 -19)+(810-2), (At-19)+(810-3), (ΑΙ Α 9)+(810-4), (Α1A 9)+(810-5), (ΑΙ -19)+(811-1), (Α1 -19)+(811 -2| (A1A 9)+(811-2), (Α1 -20)+(81-1), (Α1 -20)+(81-2), (Α1 -20)+(81 -3), (Αί-20)+(Β1 -4),(A1-20)+(81+5), (Α:1 -20)+(81-6), (Αΐ-20)+(82-1),: (Α1-20)+(82-2),: (ΑΙ-20)+(82-3), (Α1-20)+(82^):, (Α1-20)+(82-5), (A4-20)+(82-8), (A1 -20)+(82-7), (ΑΙ -20)+(:82-8), (Α:1 -20)+(82-9), (A1-20)+(82-10). (Α1-20)+(82-11), (Α1 -20)+(132-12), (Α1 -20)+-(82-13), (Ά1-20)+(82-14), (Αΐ -20)+(82-16), (A1 -20)+(82-16), (Α1 -20)+(82-17% (Α1 -20)+(82-18), (Αΐ-20)+(82-19), (ΑΙ -20)+(82-20), (Α1-20)+(82-21), (Α1 -20)+(82-22), (Αΐ-20)+(82-23), (Α1-20)+(82-24), (ΑΙ -20)+(82-25), (Α1-20)+(82-20), (Αΐ -20)+(82-27), (Α1-20)+(82-28), (ΑΙ -20)+(82-29¾ (Α1-20)+(83-1), (Α1-20)+(83-2), (Α1-20)+(84-1 ), (Α1-20)+(84-2), (ΑΙ-20)+(84-% (A1-20)+(84-4), (Α1 -20)+(84-5), (Α1-20)+(84-8), (Α1-20)+(84-7), (ΑΙ-20)+(84-8), (Α1-20)+(84-9), (Α1-20)+(84-10), (Α1-20)+(84-11), (Α1-20)+(85-1). (Α1~20)+(Β5··2)! (A1-20)+(85-3), (Α1-20)+(85-4), (ΑΊ-20)+(85-51, (Α1 -20)+(86-1 }, (ΑΙ-20)+(86-2), (Α1-20)+(86-3), (Αί-20)+(86-4), (Α1-20)+(Β6-5), (ΑΙ-20)+(86-6), (Α1-20)+(87-1), (Α1-20)+(8/-2), (ΑΙ-20)+(87-3), (Α1 -20)+(87-4), (ΑΙ-20)+(87-5), (ΑΙ-20)+(87-6¾ (Α1-20)+(87-7)), (Α1-20)+(Β7-7), (Α1-20)+(87-8¾ (ΑΙ-20)+(88-1), (Α1-20)+(88-2), (Α1 -20)+(08-3), (A1 -20)+(88-4), (Α1 -20)+(88-6):, (ΑΙ-20)+(88-6), (Α1,20)+(86-7),: (Α1 ~20)+(Β9_ι)> (Α1 -20)+(80-2), (Α1 -20)+(810-1), (Α1 -20)+(810-2), (ΑΙ-20)+(810-3), (Α1~20)4·(βιο-4), (Ά1-20)+(810-5), (ΑΙ -20)+(811-1),: (Α1-20}+(Βΐ 1:-2):, (Α1"+Ό)+(8 il-2). (ΑΙ -21 Ή.(β1 -11 (ΑΙ-21)+(81 -2), (ΑΙ -21 )+(81-3), (Α1-21 )+(81-4), (Α1 -21 )+(81 -5), (ΑΙ -21 )+ρ1(A1 „2i )+(82-1), (Α1 -21 )+(82-2), (Ά1 -21 )+(82-3), ^1-21:)+(82-4), (ΑΙ -21 )+(82-5), (ΑΙ -21 )+(82-6), (ΑΙ -21 )+(82-7), (ΑΙ -21 )+(82-8), (ΑΙ -21 )+(82-9), (Α1-21 )+(82-10), (ΑΙ-21 )+(82-11), (ΑΙ-21 )+(82-12), (ΑΙ :-21)+(82-13), (ΑΙ-2'1 )+(82-14), (ΑΙ-21 )+(82-15), (ΑΙ-21 )+(82-18), (Α1 -21 )+(82-17), (A1-21)+(ggM8^ (Α1..21)+(Β2-19), (ΑΙ-21 )+(82-20), (ΑΙ-21 )+(82-21), (Α1 -21 )+(82-22), (ΑΙ -21:)+(82-23), (ΑΙ -21)+(82-24), (Α1-21 )+(82-26), (Α1-21 )+(^26), (Α1-21 )+(82-27), (ΑΙ -21)+(82-28), (Α1 -21)+(82-29¾ (Ά1 -21 )+(83-1), (Α1-21 )+(83-2), (Ά1-21 )+(84-1). (A1 -211+(8:4-2:1, ί'ΑΙ -21 )+(34-3), (Αΐ ..21)+(84-4), (Α1-21 )+(84-5), (Α1 -21 )+(84-5), (Α1 -21 )+(84-7), (Α1 :-21:)+(84-8):, (Α1-21 )+(84-9), (Α1-21 )+(84-10), (Αΐ-21 )+(84-11), (Α1-21 )+(85-1), (Α1-21 )+(85-2), (Α1-21 )+(85-3), (Α1-21 )+(85-4), (Α1-21)+(85-6), (Α1-21 )+(86-1), (A1-21 )+(88-2), (Αΐ -21 )+(86-3), (Α1 -21 )+(86-4). (Μ-21 )+(83-5), (Α1-21 )+(86-3), (Α1^1)+(8?^% (Α1-21 )+(87-2), (Α1 -21)+(87-3), (Α1 -21 )+(87-4), (Ά1-21)+(87-5), (Α1 -21)+(87-6), (Α1 -21 )+(87-7)), (Α1-21 )+(87-7), (Α1 -21)+(87-6), (Α1 -21 )+(83-1),(Α1 :-21)+:(88¾ (Α1 -21 )+(88-3), (Α1 -21 )+(88-4), (Α1 -21 )+(88-5), :(Α1 -21 )+(88,6), ^1-21)+(88-7), (Α1-21 )+(89-1), (Α1 -21 )+(89-2), (Α1 -21)+(810-1), (Α1 -21)+(810-2), (Α1 -21 )+(810-3), (Α1 -21)+(810-4), (Α1 -21 )+(810-5), (Α1-21)+(Β11-1), (Α1-21 )+(811-2), (Α1-21 )+(811-2), (Α1 -22)+(81 -1), (Α1 -22)+(81 -2), (Α1 -22)+(81-3), (Α1-22)+(81 -4);, (Α1-22)+(81-5), (A1:-22)+(B1-6)t (Α1 -22)+(82-1), (Αΐ-22)+(82-2), (Α1-22)+(82-3), (Α1 -22)+(8:2-4),, (Α1 -22)+(82-5), (Α1 -22}+(Β2-6), (Α1 -22)+(82-7), (Α1-22)+(82-8), (Ά1-22)+(82-9), (Α1 -22)+(82-10), (A 1-22)+(Β2-11¾ (Α1 -22)+(82-12), (Ά1-22)+(82-13), (Α1-22)+(82-14), (Α1 -22)+(82-15), (Α1 -22)+(82-16:):, (Α1 -22)+(82-17), (Α1 -22)+(82-18), (Α1-22)+(82-19), (Α1 -22)+(82-20), (Α1-22)+(82-21). (Α1 -22)+(82-22), (At -22)+(82-23), (Α1 -22)+(82-24), (Α1 -22)+(82-25), (A1 -22)+(82-26), (Α1 -22)+(82-27), (Α1 -22)+(82-28), (A1-22)+(82-29), (Α1 -22)+(83-1), (Αΐ-22)+(83-2), (Α1 -22)+(84-1), (Α1 -22)+(84-2), (A1 -22)+(84-3), (Αΐ -22)+(84-4), (A1-22)+(84-5), (Α1-22)+(84-6), (Α1 -22)+(84-7), :(Α1-22)+(84-8}, (Α1 -22)+(84-9), (Αΐ -22)+(84-10), (Α1 -22)+(84-11), (Α1 -22)+(86-11 -22)+(85-2), (Α1 -22)+(85-3), (Α1 -22)+(85-4), (Α1 -22)+(85-5), (Α1-22)+(86-1), (Αΐ-22)+(Β6-2), (Α1-22)+(86-3), (A1 -22)+(86-4), (A1-22)+(86-5), (A1-22)+(:88-6), (Α1 -22)+(87-1 A (Α1-22)+(87-2), (Α1 -22)+(87-3), (Α1522)+(Β7-4), (Α:1-22}+(:87-5), (At-22)+(87-6), (Α1 -22)+(87-7)), (Α1-22)+(87-7), (Α1-22)+(87-Β), (Α1-22)+(86-1):, (Α1 -22)+(88-2), (Α1-22)+(88-3), (A1 -22)+(88-4), (Α1-22)+(Β8-5), (Α1-22)+(88-6), (Α1 -22)+(83-7), (Α1--22)+(89-1 ), (Α1-22)+(89-2), (Α1 -22)+(810-1), (Α14?2)+(Β10~2), (Α1-22)+(810-3), (Α1-22)+(810-4), (Α1 -22)+(810-5), (Α1-22)+(Β11-1}, |Α1 -22)+:(811-2), (Α1-22)+(Β1ΐ~2), (A 1 -23:)+(81-1), £Α1 -23)+(81 -2), (Α1 -23)+(81-3), (Α1 -23)+(81 -4), (Α1-23)+(Β1 -5), (Α1-23:)+(81-6), (Α1-23)+(82-1), (Α1 -23)+(82-2):, (Α1-23)+(82-3), (Α1-23)+(82-4), (A1 -23:)+(82:-5), (Αΐ-23)+(Β2-6); (Α1-23}+(Β2-7), (Αΐ;-23)+(82-Β), (Α1-23)+( 82-9), (AI -23)+(82-10}; (A1 -23)-(32-11). (AI-23)+(82-12} :(Α1-23)-ϊ·{Β2--1:3): (Ai-23)+(82--14), (A 1-23)+(82-1 5), (A {A1--23MB2-17), (A1 -23)+(82-18), (A1 -23)+(82-19), (Ai -23)-(82-:20), (AI-23)+(82-21), CA1 -23)4-(82-22), (AI-23)+(82-23), (A 1 -23)+(82,24), (A1-23)+(82-25), (A1-23)+(82-26), (A1 -23)+(82-27), (A1-23)+(82-28), (A1-23)+(83-29), (A1-23)+(83-1), (AI -23)+(83-2), (AI-23)+(84-1), (A1-23)+(84-2), (A1-23)+(84-3), (AI -23)+(84-4), (AI -23)+(84-5), (AI -23)+(84-8), |A1 -23)+(84-7), (A1-23)+(84-8), (AI-23)+(84-9), (AI-23)+(84-10), (A1-23)+(84-11), (A1-23)+(85-1), (A 1-23)+(85-2), (A1 -23)+(85-3), (A:1 -23)+(85-4), (A1 -23)+(85-5), (Α1-23)+(Β6-1), (A1-23)+(8S-2), (A1 -23)+(86-3), (A1-23)+(86-4), (Ai-23)+(86-5), (AI-23)+(86-6), (Ai-23):+(87-1). (Ai -23)+(87-2), (AI -23)+(07-3), (A.1 -23)+(87-4):, (A1:4?3)+(B7-&amp;1 (Ά1 -23)+(87-6). (A1 -23)+(87-7)), (AI-23)+(87-7), :(A1-23)+(07-3), (A1-23|+(8S-1), (AI-23)+(88-2), (A1 -23)+(88-3), (AI -23)+(88-4), (AI -23)+(88,5), (Α1-23)+(ΒΒ-6), (A1 -23)+ (88-7), (AI -23)+(89-1), (AI -23:)+(89-2), (A1 -23)+(810-1), (A1-23)+(B 10-2), (AI-23)+(810-3), (AI -23)+(810-4), (AI -23)+(810-5), (Ά1 -23)+(811 -1), (Ai -23)+(811 -2), (AI-23)+(811-2), (Ai -24)+(81 -1), (Ai -24)+(81 -2), (AI -24)+(81-3), (A1 -24)+(81 -4), (AI -24)+(81 S), (AI-24)+(81-6), (AI-24)+(82-1), (AI -24)+(82-2), (A1 -24)+(82-3:):, (AI-24)+(82-4), (AI-24)+(82-5:), (Ai-24)+(82-6), (A1-24)+(82-7), (A1-24)+(82-8), (Ai-24)+(82-8), (A'1-24)+(82-10). (AI-24)+(82-11), (AI-24)+(82-12). (AI-24)+(82-13), (AI -24) +(82-14), (AI-24)+(82-16), (AI-24)+(82-16), (AI-24)+(82-17), (AI-24)+(82-13), (AI-24)+(82-19), (A1 -24)+(82-20¾ (AI-24)+(82-21), (AI-24)+(82-22), (AI -24)+(82-23), (A1-24)+(82-24), (AI-24)+(82-25), (AI -24)+(82-28), (AI -24)+(82-27), (Ai -24)+(82-28), (Ai -24)+(82-20), (Ai -24)+(83-1), (A 1 -2.4)+(B3-2), (A1 -24)+(84-1), (AI -24)+(84-2), (Ai-24)+(B4-3), (AI -24)+(84-4), (AI -24)+(84-5), (AI -24)+(84-6), (AI -24)+(84-7), (A1 -24)+(84-8), (AI -24)+(84-9), (AI -24)+(84-10), (AI -24)+(84-11), (AI -24)+(85-1), (AI -24)+(85-2), (A1 -24)+(85-3), (AI-24)+(85-4), (AI -24)+(85-5), (A:1 -24)+(06-1), ^1-24)+(86-2), (A1-24)+(86-3), (AI--24)+(86-4), (A1-24)+(B6-5), (AI-24)+(86-6), (AI-24)+(87-1), (AI -24)+(87-2), (AI-24)+(87-3), (AI-24)+(87-4), (AI-24)+(87-5), (AI-24)+(87-6), (A1 -24)+(87-7)), :(A1 -24)+(87-7), (AI -24)+(87-8), |A1-24)+(88-1), (AI -24)+(88-2), (AI-24)+(88-3), (AI -24)+(88-4), (AI-24)+(88-5), (Ai-24)+(88-6), (AI-24)+(88-7), (AI-24)+(89-1), (AI-24)+(89-2), (AI-2.4)+(810-1), (AI-24)+(810-4), (A1-24)+(BlO-5), (AI-24)+(811-1), (Ai-24)+(811-2), (A1-24)+(B11-2). (A145)+(81 -1), (Α1 45)+(814), (Αί -25}·ϊ (Β1 -S)( ^1-25)+(:61-4), (Α1 -25)+3(61 *$% (A 1 4ο)+(Β 1 -6), (Α.1 45)+(82-1), (ΑΙ -25)+(62-2), (Αί45)+(32-3¾ (Λ145)+(Β2~4), (ΑΙ -25)+(82-5), (Α1 -25)+(82-6), (Α1 -25)+(62-7), (Α1 -25)+(82-8), (Α145)+(Β2-9}, (A1 -25)+(82-10), (Α1-25)+(Β2-11), (Α1 -25)+(32-12), (ΑΙ-25)+(32-13), (ΑΙ-25)+(82-14), (ΑΙ-25)+(32-15), (Αί -25)+(32-15), (A1-25)+(82-17), (A1-25)+(32-18), (ΑΙ-25)+(82-19), (ΑΙ -25)+(62-20), (ΑΙ-25)+(82-21¾ (Α1 -25)+(82-22), (Α1-25)+(82-23), (ΑΙ -25)+(62-24), (ΑΙ-25)+(62-25), (ΑΙ-25)+(32-26), (ΑΙ -25)+(82-27), (ΑΙ -25)+(32-28), (A1-25)+(32-29¾ (ΑΙ-25)+(83-1), (ΑΙ-25)+(83-2), (Α'Ι-25)+(84-1), (ΑΙ 45)+(34-2). (ΑΙ-25)+(84-3), (ΑΙ -25)+(:84-4), (ΑΙ-25)+(84-5), (ΑΙ-25)+(84-6):, (Α1-25)+(84-7), (4145)+(84-8), (ΑΙ-25)+(84-9), (Α1-25)+(84-10), (ΑΙ -25)+(84-11), (ΑΙ -25)+(85-1), (ΑΙ -25)+(85-2), (ΑΙ-25)-+(354), (A145)+(35-4), (ΑΙ -25)+(35-5),, (ΑΙ-25)+(86-1}, (ΑΙ-25)+(86-2), (ΑΙ -25)+(36-3), (A1 -25)+(86-4), :(Α1 -25)+(86-5), (ΑΙ-25)+(86-6), (A1-25)+(87-1), (ΑΙ-25)+(87-2), (ΑΙ -25)+(87-3),. ,(Α1 -25)+(87-4):, :(Α1 -25)+(37-5), (ΑΙ -25)+(87-6), (ΑΙ-25)+(87-7)), (ΑΙ-25)+(67-7), (ΑΙ-25)+(87-8), (ΑΙ-25)+(88-1), (4145)+(38-2¾ (Α1-25)+(68-3), (Α.1 -25)+(88-4), (ΑΙ-25)+(38-5), (ΑΙ -25)+(88-6), (ΑΙ-26)+:(68-7), (Αί -25)+(89-1), (Α1 -25)+(89-2), (ΑΙ -25)+(316-1), (ΑΙ -25)+(810-2), (ΑΙ -25)+(8104), (Μ -25)+(810-4), (ΑΙ -25)+(610-5), (A1 -25)+(311 -ί), (ΑΙ -25)+(811-2), (ΑΙ-25)+(811-2), (ΑΙ -26)+(61-1), (ΑΙ-26)+(61-2), (ΑΙ-26)+(81-3), (Α1-26)+(81-4), (ΑΙ-26)+(81-δ), (ΑΙ-26)+(81-6), (ΑΙ46)+(82-1), (ΑΙ 46)+(Β2-2), (Α1-26)+(624), (ΑΙ 46)+(82-4), (Α146)+(82-5), (ΑΙ -26)+(82-6), (41-28)+(32-7¾ (ΑΙ-26)+(82-8),, (ΑΙ-26)+(82-9), (Α146)+(82-10), (ΑΙ 46)+(82-11), (ΑΙ-26)+(82-12), (A146)+(82-13), (ΑΙ 46)+(32-14), (ΑΙ-26)+(82-15), (ΑΙ46)+(82-16), (ΑΙ 46)+(82-17), (Αί46)+(82-18), (Α1-26)+(Β2-19), (ΑΙ 46)+(8240), (Αί 46)+(82-21), (4146)+(82-22¾ (A148)+(B2-23), (ΑΙ46)+(82-24),. (ΑΙ-26)+(6245):, (4146)+(3246¾ (A146)+(8247). (ΑΙ-26)+(82-28). (Α1-26)+(3249), (ΑΙ -26:)+(83-1), (ΑΙ -26)+(834), (Αΐ 46)+(84-ί), (ΑΙ-28)+(844), (ΑΙ 46)+(34-3¾ (Α146)+(84-4¾ (ΑΙ 46)+(84-5), (Α1-26)+(84-6), (ΑΙ46)+(84-7), (Α146)+(84-6), (ΑΙ 46)+(84-9):, (Α1 -26)+(84-10), (Α146}+(Β4-11), (ΑΙ 46)+(85-1), (ΑΙ-26)+(354), (ΑΙ-26)+(86-3), (A 146)+(85-4), (ΑΙ46)+(354¾ (ΑΙ46)+(86-1}, (ΑΙ-26)+(36-2), (ΑΙ -26)+(86-3), (ΑΙ46)+(86-4), (ΑΙ -26)+(86-5), (ΑΙ -26)+(86-6), (ΑΙ -26)+(37-1), (A1-26H(B7-2:)S ^1-26)+(87-3), (Ά1 -26)+(37-4), |Ai -26)+(:87-5):, (A 1 -26):+(87-6), {A1 -26)+(37-7)). (Al -26)+(87-7), (Al-26)+(87-8),, (Al -26)+(83-1):, (Ai -26:)+(83-2), (Al -26)+(88-3), (Al -26)+(88-4), (A1 -26)+(88-5), (Al -26)+(88-6), (Al -26)+(88-7), (Al-26)+(89-1), (At-26)+(89-2), (A1-26)+(B10-1),, (At-26)+(810-2), (Ά1-28)+(810-3), (Al-26)+(810-4), (At-26)+(810-6), (A1-26)+(811-1), (Α1:-26)+(Β11+2), (Al-26)+(811-2), (A1 -27)+(81-1), (Ai -27)+(81-2), (Al -27)+(81-3), (Al -27)+(81 -4), (Al-27)+(81-5), (Al -27)+(81 -6), (A1 -27)+(62-1), (Al-27)+(82-2), (Al -27)+(82-3), (Al-27)+(82-4), (Al-27)+(82-5), (Al-27)+(82-6), (Al-27)+(82-7), (Al-27)+(82-8), (A1-27)+(82-9), (A1 -27)+(82-10), (A1-27)+(82-11), (Al-27)+(82-12), {Al-27}+(B2A3), (A1 -27)+(82-14), (A1 -27)+(82-15), (Al -27)+(82-16), (Al-27)+(82-17), (A1 -27)+(82-18), (Al -27)+(82-19), (Al -27)+(82-20), (A1-27)+(82-21|5 (A1 -27)+(82-22), (Al-27)+(82-23), (Al -27)+(82-24), (A1-27)+(82-25), (Al-27)+(82-26), (A1-27)+(B2-27), (A1-27)+(82-28), (A1-27)+(82-29), (Al-27)+(83-1), (Al -27)+(83-2), (A1 -27)+(84-1), ;(A1-27)+(84-2), (Al-2:7)+(84-3), (Al -27)+(84-4), (Al -27)+(84-5), (A1-27)+(84-6), (Al-27)+(84-7), (A1-27)+(84-8), (Al -27)+(84-9), (A1-27)+(B4~10), (A1-27)+(84-11), (Al-27)+(85-1), (Α1-27)+(Βδ-2), (A1 -27)+(86-3), (Al -27)+(85-4), (A1-27)+(85-5), (Ai~27)+(86-1), (Al-27)+(86-2), (Al-27)+(86-3), (A1 -27)+(86-4), (A1-27)+(86-6), (A1-27)+(86-6), (Al-27)+(87-1), (A1 -27)+(87-2), (Al -27)+(87-3), (A1 -27)+(87-4), (A1 -27)+(87-5), (A1-27)+(87-6), (Al -27)+(87-7)), (A1 -27)+(87-7), (Al -27)+(87-8), (A1-27)+(88-1), (Al -27)+(88-2), (Al-27)+(88-3), (Al-27)+(88-4). 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(At-28^(B$4)v ·ψάΜ)+(βΒ~Ζ% (A1 -28)+(85-3), (A1 -28)+(65-4), (AI-28)+(85-5), (A1 -28)+(88-1), iA1~26)+(B8~2), (AI -28)+(86-3), (A1 -28)+(86-4), (A1 -28)+(86-5), (AI -28:)+(86-3), (AI -28)+(87-1:), (A1 -28)+(87-2), (Ai -28)+(87-3), (A1 -26)+(87-4), (AI -28:)+(87-6),,(A1 -28:)+(87-6):, (AI -28)+(87-7)), (AI -28)+(87-7), (AI -28)+(87-8), (AI -28)+(88-1), (A1 -28)+(88-2), (A1 -28)+(88-3), (A1-28)+(88-4), (A1-28)+(88¾ (A1-28)+(88-8):, (A«6)+|B8~?)t (A.1 -28)+(89-1), (A1-28)+(89-2), (A1-28)+(810-1), (AI -28)+(810-2), (A1:-28)+(818-3), (AI -28)+(810-4), (AI -28)+(810-5), (A1-28)+(811-1), (A1-28)+(81:1 -2), (AI -28)+(811-2), (A1 -29)+(81-1), (Al~29)+(B1-2), (AI-29)+(81-3), (Ai-29)+(81-4), (AI-29)+(81-5), (Ai-28)+(81-6), (AI-29)+(82-1), (Ai-29)+(82-2), (AI -29)+(82-3), (A1-29)+(82-4), (AI-29)+(82-5), (Ai-29)+(i2-6), (AI -29)+(82-7), (AI -29)+(82-3), (Α1-29)+(82-8), (AI -29)+(82-19), (A1-29)+(82-11), (Ai-29)+(82-12), (A1-29)+(B2-13), (AI -29)+(82-14), (Ai -29)+(82-15), (A1 -29)+(82-16), (AI -29)+(82-17), (AI-29)+(82-18), (Ai -29)+(82-19), (A1-29)+(B2-20), (A1-29)+(82-21), (AI -29)+(82-22), (A1-29)+(82-23), (AI-29)+(82-24), (A1-29)+(82-2S), (A1 -29)+(82-28), (A1 -29)+(82-27), (A1 ^9)+(82-28), (AI -29)+(82-29), (A1 -29)+(83-1)., (AI -29)+(83-2), (Ai -29)+(84-1), (AI -29)-884-2), (AI-29)+(84-3), (AI-29)+(84-4), (A1-29)+(84-5), (Ai -29)+(84-6), (A1-29)+(84-7):,^1-29)+(84-8), (AI -29)+(84-9), (AI -29)+(84-10), (AI -29)+(84-11), (A1-29)+fB6-i), (AI-29)+(85-2), (AI -29)+(85-3:), (A1 -29)+(85-4), (Ai-29)+(85-5), (A1-29)+(B8-1), (AI-29)+(86-2), (AI-29)+(88-3), (A1 -29)+(86-4), (AI -29)+(86-5), (A1-29)+(86-6), ^1-29)+(87-1), (AI-29)+(87-2), (AI -29)+(87-3), (AI-29)+(87-4), (AI-29)+(87-5), (AI -29)+(87-6), (AI-29)+(87-7)), (AI-29)+(87-7), (AI-29)+(87-3), (AI-29)+(83-1), (AI-29)+(88-2), (AI-29)+(86-3), (AI-29)+(88-4), (AI-29)+(88-5), (AI-29)+(88-6), (AI-29)-(88-7), (AI-29)+(89-1), :(Ά1-29)+(69-2), (AI-29)+(810-1), (Ai-29)+(810-2), (AI-29)+(810-3), (AI-29)+(810-4), (AI-29)+(810-5), (A1 -29)+(811 -1:), (Ai-29)+(811-2), (A1~29}+(B11-2), (AI -30)+(81 -1), (AI -30)+(81 -2), (AI -30)+(81 -3), (AI -30)+(81-4), (AI-30)+(81-5), (AI-30)+(81 -6), (AI-30)+(82-1), (AI -30)+(82-2), (AI-30)+(82-3), (AI--30)+(82-4), (A1-30)+(82-5), (AI-30)+(82-6), (AI-30)+(82-7), (AI-30)+(82-3), (Al-30)+(82-i), (Ai-30)+(82-1% (41 -30)+(82-1.1), (A1-30)+(B2-12 > (41-30)+(82-18):, (A1 -30)+(82-14),: (AI-30)- +32-15), (AI-30)+(82-16), (A 1-30)+(82-17), (AI-30)+(82-18), (A1 -30)+(82-19), (A 1 -30)+(82-20), (AI-30)+(82-21), (Ai -80)+(82-22), (AI -30)+(82-23), (41 -30)+(82-24), (AI -30)+(82-25), (Ai-30)+(82-26), {41-38)+(82-27), (AI-30)+(82-28), (AI-30)+(82-29), (AI-30)+(83-1), (At-30)+(83-2), (41-30)+(84-1), (A1-30)+(84-2), (41 -30)+(84-3), (AI-30)+(84-4), (A1 -30)+(84-5), (AI -30)+(84-6), (AI -30)+(84-7), (AI -30)+(84-8), (41-30)+(84-9), (41 -30)+(84-10), (AI -30)+(84-11), (41-30)+(88-1), (A1-30)+(85-2), (41-30)+(85-3). (41-30)+(85-4), (41-30)+(85-5), (41-30)+(86-1 ), (Λ1-30)+(86-2), (AI-30)+(80-3), {AI-30)+(86-4), (Ai-30)+(86-5), (AI-30)+(86-6). (Ai-30)-(87-1), (AI-30)+(87-2), (A1-30)+(87-3), (A1 -30)+(87-4), (41-30)+(87-5), (AI -30)+(87-6), (AI -30)+(87-7)), (41:-30)+(87-7), (AI-30)+(87-8), (AI-30)+(88-1), (AI-30)+(88-2), (41-30)+(88-3), (41-30)+(88-4),(41-30)+(86-5), (A1+30H8S+I), (Ai-30)+(88-7), (41-30)+(80-1), (41-30)4(89-2), (41-30)+(810-1), :(41-30)+(810-2), (41-30)+(818-3), (AI -30)+(810-4), (41230)+(810-5), (AI -30)+(81 i -1), (41-30)+(841-2), (AI -30)+(811-2), (AI-31 )+(81-1), (A'1-31 )+(81 -2), (Ai -31 )+(8 1 -3), (AI -31 )+(81-4), (A1-31 )+(81-6), (A1-31.HB2-1), (A 1 -31 )+(82-2):, (A 1 -31 )+(82-3), (AI -31 )+(82-4):, (41-31)+(82-5), (41-31)+(82-6), (AI ~31 )*(B2-?)? (A1:4l)+(12-8), (Ai -31)+(^0), (41-31)+(82-10), (41-31)+(82-11), (41-31)+(82-12), (41:-31:::)+(82-13), (41-31)+(82-14), (Al^n+CBa-IS), (41-31)+(82-16), (4.1-31 )+(82-17):,: (41 -31 )+(82-16), (At -31 )+(B2-19), (41-31 )+(82-20), (41-31)+(82-21), (At -31 )+032722), (A1 ^1.)+(82-2% (41 -31)+(82-24), (AI -31 )+(82-25), (AI -31)+(82-26), (A1 -31 )^(82-27), (41-31 )+(82-28), (41 -31 )+(82-29), (41-31)+(83-1), (41-31)+(83-2), (41.31 )+(84-1), (41-31 )+(84-2), (41 -31 )+(84-3), (41-31)+(84-4), (Al+31 )+(84-5), (41-31)+(84-6), (41-31 )+(84-7), (41->31 )+(84-8), (41-31)+(84-9), (41-31^(84-10), (41-31)+(84-11), (41-31)+(85-1), (41-31)+(85-2), (4)-31)+(85-% (41-31)+(85-5), (AI-31 )+(86-1.), (41:-31)+(88-2),: (41-31)+(86-3), (A W)+(8^1), (41-31)+(87-2), (A1-31 )+(87^3), (At ~31 )+(17-4), (41:-31)+(87-5)^ (41-31)+(87-7)), (41-61)+(87-7), (41-31)+(87-8), (41-31)+(88-1:), (41-31)+(88-2), (41-31 )+(88-3), (Μ -31 <A1 -31 )+(88-5), (41 -31 )+(88-6), (41 -31 )+(88-7), (AI -31 :)+(89-1), (A^ )+(S9-2); (41 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(AI-38)+(84-9), (AI-36)+(844 0), (AI-36)+(84-11), (41-36)+(85-1), (41-36)+(654), (41-36)+(85-3), (41-38)+(85-4), (AI-36)+(85-5), (41-36)+(884), (41-36)+:(86-2):, (AI -36)+(86-3), (41-36)+(66-4), (41-36)+(88-5), (41-36)+(86-6):. (41-36)+:(87-1), (41-36)+(67-2), (41-36)+(87-3), (41-36)+(87-4), (41-36)+:(67-5), (41-36)+(87-6), (41-36)+(67-7)), (41-36)+(87-7), (41-36)+(67-8), (41-36)+(834)441 -36)+(88-2), (41-36)+(88-3), (41-36)+(88-4), (A1-86)+(88-5), (A1-30)+(B8-6), (41-36)+(86-7), (41-36)+(89-1)» (41-36)+(69-2), (41-38)+(810-1),(41-36)+(6½^ (41-36)+(810-4), (41-36)+(810-3), (41-36)+(811-1), (41-36)+(811-2), (41-36)+(611-2), (41-37)+(814), (41-37)+(81-2), (41-37)+(81-3¾ (41-37)+(81-4), (41-37)+(81-5), (41-37)+(81 -6), (41-37)+(62-1), (AI -37)+(62.2¾. (41-37)+(62-3), (41-37)+(62-4), (41-37)+(62-5), (41-37)+(82-6), (41-37)+(82-7), (41-37)+(82-6), 141-37)+(82-9), (Al -37)+(62-10), (Al-37)4-(82-11). (A 1-37)4(82-12). :(41-37)+(82-1:3), :(A1 -37)4-(82-14), (Al-37)4(62-15), (Al-37)4(8:2-16), {41-37)+(82-17), (41-37)+(82-18), (Al -37)4(82-19), (A1 -37)4(82-20), (A1-37)4(82-21), (41-37)+(82-22), (41-37)+(82-23), (A1 -37)4(82-24), (41-37)+(82-25), (Al-37)4(82-26), (A1-37)+(82-27), (41-37)+(82-28), (A1-37)4(82-29), (Al -37)4(83-1), (Al -37)+(83-2), (A1 -37)4(84-1:), (Al -37)4-(84-2), (Al -37)4(84-3), (A1-37)4(84-4), (A1 -37)4(84-5). (Al -37)+(84-6), (41-37)+(84-7), (A1-37)+(84-8), (A1 -37)4(84-9), (A1 -37)+(84-10), (Al -37)4(84-11);, (41-37)+(85-1), (A1 -37)4(85-2), (Al -37)4(85-3), (41 -37)+(85-4), (41-37)+(85-5), (Al -37)+(86-1), (A1 -37)4(86-2), (Al-37)4(86-3), (Al -37)+(86-4), (Al -37)+(86-5), (41+37):+(8:6-6), (Al-37)4(87-1), (Al -37)4(87-2), (Al-37)+(87-3), (A1 -37)+(87-4), (Al -37)4(87-5), (Al -37)4(87-6), (41-37)+(87-7)), (A1-37)+(87-7), (Al-37)+(87-8), (41:-37)+(88-1), (41-37)4(83.2), (A1-37)+(88-3), (Al -37)+(88-4), (41-37)+(88-5), (Al-37)4(88-6), (41-37)+(83-7), (A1 -37)4(89-1), (Al-37)+(89-2), (41-37)4(810-1), (41-37)4(810-2):, (4:1-37)4(810-3), (41-37)4(810-4), (41-37)4(810-5), (41-37)+(811-1), (41-37)4(811-2), (41-37)4(811-2), (41-38)4(814), (Al-38)4(81-2), (41-38)+(81-3), (41-38)+(81-4), (41-38)4(81-5):, (41-38)+(81-6), (A1 -38)+(82-1), (41-38)+(82-2), (41-38)+(82-3), (41-38)+(82-4¾ (41-38)4(82-5), (41-38)4(82-6), (41-38)+(82-7), (41-38)+(82-8), (41-38)+(:82-9), (41-38)4(82-10), (Al -38)+(82-11), (A1-38)+(82-12), (41-38)+(82-13), (41-38)+(82-14), (41-38)+(82-15), (41-38)+(82-16), (41-38)+(82-17), (41-38)+(82-18), (41-38)+(82-19), (Al -38)+(82-20), (41-38)+(82-21), (41-38)+(82-22), (A1 -38)+(82-23), (41-38)+(82-24):, (41-38)+(82-25), (41-38)4(82-26), (Al -38)+(82-27), (41-38)+(82-28), (41 -38)+(82:-29:), (41-38)+(83-1), (41-38)+(83-2), (41-31)+:(64-1), (41-38)4(84-2), (4:1-3:8)4(84-3), (41-33)+(84-4), (Al -38)+(84-5), (Al -38)+(84-6), (41-38)+(84-7), (41-38)4(84-8), (41-38)+(84-9), (41-38)+(84-10), (41-38)+(84-11), (Al -38)+(85-1), (Al-38)4:(85-2):, (41-38)+(85-3), (41-38)+(85-4), (41-38)+(85-5), (A1-38)+(86-1), (41-38)+(86-2), (41-38)4(86-3), (A1 -38)+(86-4), (41-38)+(86-5), (A1-38)+(86-6), (41-38)+(87^1), (41-38)+(87-2), (41-38)+(87-3), (41-38)+(87-4), (A1 -38)+(84-5), (A1-38)+(87-6), (A1-33)+(B7-7)), (Al-38)+(87-7), (41 -38)+(87-8), (41 -38)+(88-1), (41-38)+(88-2), (41-38)+(88-3), (41-38)+(83-4), (Al-38)+(88-5), (41-38)+(88-6), (41-38)+(88-7¾ (41-3:8)+(89-1), (A1 -38)+(89-2), :(41-38)+:(810-1¾ :(41-38)+(610-2), (4:1-3:8)+(840-3), (Al -38)+(810-4), (Al-38)+(810-5), (Al-88)+(811-1), (Al -:38)+(81:::1-2),: (Α1-38)+(Β11·2). (A 1-39)-(31-1), (A 1-38)-(61-2), (41-39)+(81-3), (A1-39}+(B1-4), (41-39)+(81-5), (At-39)+(31-6), (41-39)+(82-1), (41-39)+(82-2), (41-39:)+(82-3), (A1 -39)+(82-4), (41-39)+(82-5), (A1-39)+(82-6), £A1-39)+(B2-7), (41 -38)+(82-8), (A1 -39)+(82-9), (A1 -39)+(82-10), (A1 -39)+(82-11), (A1--39)+(82-12), (41 -39)+(82-13), (41 -39)+(82-14), (A1 -39)+(82-15), (41 -39)+(8:2-16), (A1-39)+(82-17). (A1-30)+(82-16), (41-39)+(82-19), (41 -39)+(82-20), {41:-39)+(82-21), (A1 -39)+(82-22), (A1 -39)+(82-23), (A1 -39)+(82-24), (A1-39)+(82-25), (41-39)+(82-26), (At-39)+(82-27), (A1-39)+(82-28), (41-39)+(82-29), (A1 -39)+(83-1), (A1 -39)+(83-2), (A1 -39)+(84-1), (4149)+(84-2), (At-39)+(84-3),. (A1 -39)+(84-4), (41 -39)+(84-5), (41-39)+(84-6), {41:-39)+(84-7), (A1~33)+(B4-Si (A1-39)+(84-9), (A1-39)+(84-10), (A1 -39)+(64-41):, (A1-39)+(85-1), (A1-39)+(85-2), (41-39)+(85-3), (At-39)+(85-4), (A1-39)+(85-5), (A1-39)+(B6-1), (A44t|+(8^2;),. (41 -39)+(86-3), (A1 -39)+(86-4), (41 -39)+(86-5), (41-33)+(86-6), (41-39)+(87-1), (A1 -39)+(87-2), (41-39)+(87-3), (41 -39)+(87-4), (41 -39:)+(87-5), (41-39)+(87-6), (41-39)+(87-7)), (41-39)+(87-7), (41-39)+(87-8), (41-39)+(88-1), (41-39)+(88-2), (A1 -39)+(88-3), (A1 -39)+(88-4), (41-39)+(88-5), (.41 -39)+(88-6), (41-39)+(88-7), (41-39)+(89-1), (A1 -39)+(89-2), (41-39)+(819-1), (41-39)+(810-2), (41-39)+(810-3), (41-39)+(810-4), (41-39)+(810-5), (41-39)+(811-1), (41-39)+(811-2), (41-39)+(811-2), (41-40)+(81-1), (41-40)+(81-2), (41-40)+(81-3), (44-40)+(81-4), (41-40)+(81-5), (41-40)+(81 -6), (41-40)+(82-1), (41-40)+(82-2), (41 -40)+(82-3), .(41-40)+(82-4), (41-40)+(82-5), (A1-40)+(82-6), (A1-40)+(82-7), (41-40)+(82-8), (41-40)+(82-9), (41-40)+(82-10), (41-40)+(82-11), (41 -40)+(82-12), (41 -49)+(82-13), (41-40)+(82-14), (41-40)+(82-15), (41-40)+(82-16), (41-40)+(82-17), (41-40)+(82-18), (41-40)+(82-19), (41-40)+(82-20), (41-40)+(82-21), (41 -40)+(82-22), (41 -40)+(82-23), (41 -40)+(82-24), (41 -40)+(82-25), (41 -40)+(82-26), (41-40)+(82-27), (41 -40)+(82-28), (41 -40)+(82-29), (41 -40)+(83-1), (41 -40)+(83-2), (41 -40)+(84-1), (41 -40)+(84-2):, (41-40)+(84-3), (41-40)+(84-4), (41-40)+(84-5), (41-40)+(84-6), (41-40)+(84-7), (41-40)+(84-8), (41-40)+(84-9), (41-40)+(84-10), (41-40)+(84-11), (41-40)+(85-1), (41-40)+(85,2^ (41-40)+(85-3), (41-40)+(85-4), (41-40)+(85-5), (41-40)+(86-1), (41-40)+(36-2), (41-40)+(86-3), (41-40)+(86-4), (41 -40)+(86-5), (41 -40:)+(86-6), (41 4u) t { 6 7-1) (41-40)+(87-2). (41-40)+(87-3), (41-40)+(87-4), (41-40)+(8/-5¾ \A1-40)+(:87-6). 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(Α1 -44)+(82-19), (ΑΙ -44)+(82-20). 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(A 1--47)^(07-7). 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(Al-49)+(8441), (Al-49)+(854:), (41-49)+(85--2), (A149)+(35-3), (A149)+(BS4)s (A1-49)+(85-5), (A149)+(66-1), ,^149)+(86-2), (Ai -49)+(86-3), (Al49)+(86-4), (A1 -49)+(86-5), (Al -49)+(88-6), (A1-49)+(874),: (Al-49)+(87-2), (Ai-49)+(iA3), (Al-49)+(874), (A1-49)+(874), (A1-49)+(374), (Al-49)+(67-7)), (Ai49)+(67-7), (A149)+(67-8), (A 1-49)+(88-1), (A149)+(88-2), (Al 49)+(88-3), (AI-49)+(884), (A1 -49)+(88-5), (AI 49)+(68-6), (AI 49)+(86-7), (AI-49)+(89-1), (A1-49)+(89-2), (Al-49)+(8104), (A1 -49)+(8104), (Ai-49)+(816-3), (Al43)+(810-4),(Al-49}+(B10-5), (Al49)+(811-1), (Al49)+(811-4), (A1 -49)+(811 -2), (Ai -50)+(81-1), (Al-60)+(81-2), (Al 40)+(81-3), (Al 40)+(81-4), (A1:-S0)+(Bi4), (Al-50)+(81-6), (A140)+(82-1), (Al40)+(82-2), :(A1-50)+(82-3), (Ai40)+(82-4), (Al -50)+(82-5), (A140)+(82-6), (Al -50)+(82-7), (A1 -50)+(62-8), (Al -50)+(82-9), (Al 40)+(62-10), (A1 -50)+(82-11), (Al -50)+(6242), (Al -50)+(1243), (A1 -50)+(624 4), (A140)+(82-15), (Al-50)+(82-16), (Al-50)+(82-17), (Al40)+(82-18), (A 1-50)+(82-19), (A140)+(82-20), (Ai40)+(82-21), (Al-50)+(8:2-22), (A1 -50)+(82-23), (A140)+(82-24), (A140)+(82-25), (,41-50)+(62-26), (Al 40)+(82-27), (Ai 40)+(82-23), (A140)+(62-29), (Al40)+(83-1 ), (A140)+(B3“2), (Al40)+(844), (Al40)+(64¾ (A140)+(84-3), (Al-50)+(84-4), (Al40)+(844), (Al40)+(84-6), (Al40)+(84-7), (Al 40)+(84-8), (Al-50)+(84-9), (Al-50)+(84-10), (A1 -50)+(84-11), |A140)+(854), (Al-50)+(854), (Al 40)+(85-3), (Al -50)+(65-4), (Al 40)+(85-5), (Al40)+(834), (Α1~59)+(88-2), (Al 40)+(86-3), (Al-50)+(86-4), (Al -50)+(86-6), (Al40)+(86-6):, (Al-50)+(87-1), (Al -60)+(87-2), (A140)+(87-3), (Al -50)+(87-4), (Al40)+(874), (Al-50)+(87-6), (Al-50)+(87-7)), (Al-50)+(87-7), (A1-50)+(87-8), (Al-50)+(88-1), (Al40)+(86-2), (M-50)+(83-3), (A1-50)+(88-4), (A140)+(884), (Al 40)+(88-6), (Α1-5Ό)+(Β8-7), <Α1·-50)+(89-1), (Al-50)+(89-2), (Al-50)+(810-1), (Al 40)+(819-2), (Al 40)+(810-3), (A1 -50)+(810-4), (Ai-50)+(810-5), (Al-50)+(811-1), (Al-50)+(811-2), (Al-50)+(811-2), (A141 )+(81-1), (A141 )+(81-2), (A1-51 )+(814), (A141 )+(81-4):, (A141 )+(814), (Al-51 )+(81-6), (Al -51 )+(82-1), (A 1-51 )+(88-2),, (A1-51 )+(82-3), (A141 )+(82-4), (A1-51 )+(82-5), (Al -51)+(824), (Al -51 )+(82-7), (Al-51 )+(824), (Al -51 )+(82-9), (A141 )+(82-10), (Al41)+(82-11),, (Al-51 )+(82-12% (At-51)+(82-13), (A 1-51)+(62-14), (A 1-61)+(62A 5). (A 1+51)+(62-16), (A1-51 )+(62-17), (A1-51)+(82-16), (A1--51 )+(62-19), £A1 -51 )+(62:-20)., (A1-51 )+(62-21), (A1 -51 )+(62-22), (ΑΊ-51)+(62-23), (A1-51 )+(B2-24):I (A1-51)+(62-25), (A1 -51 )+(62-26), (A1 -51 )+(82-27), <A1-51 )+(82-28), (A1-51 )+(82-29), (A1-51 )+(63-1), (A1 -51)+(63-2), (A1-51 )+(64-1), (At-51)+(64-2), (At-51)+(84-3), (A1-51 )+(64-4), (A1 -51)+(84-5), (A1 -51 )+(84-6), (A!-51)+(64-7), (A1 -54)+(64-8), (A1 -51 )+(84-9), (A1 -51)+(64-10), (A1 -51 )+(64-11), (A1-51 )+(65-1), (A1-51 )+(85-2), (A1 -51 )+(85-3), (A1 -51 )+(65-4), (A1 -51 )+(65-5), (A1 -51 )+(65-1), (AT-51 )+(86-2), (A1 -51)+(86-3), (A1-51 )+(66-4), (A1-51 )+(66-5), (A1-51 )+(86-6), (A1-51 )+(87-1), (A1 -51 )+(67-2), (A1-S1 )+(67-3), (A1 -51 )+(67-4), (A1 -61 )+(87-5), (A1 -51 )+(87-6), (A1-51 )+(67-7)), (A1-51)+(B7-7), (A1 -51 )+(87-8), (A1 -51 )+(68-1), (A1 -51 )+(63-2), (A1-51 )+(88-3), (A1-51 )+(88-4), (A1 -51 )+(88-5), (A1 -51 )+(68-6), (A1-51 )+(6:8-7), (A 1-51 )+(89-1), (A1 -51 )+(89-2), (A1 -51 )+(810-1), (A1 -51 )+(810-2), (A1 -51)+(610-3), (A1-51)+(810-4), (A 1 -51)+(B10-5), (A 1 -51)+(B41 -1), (At-51 )+(811-2), (A1 -51 )+(611-2), (At-52)+(81-1), (A1-52)+(81-2), (A1-52)+(B1-3), (A1 -52)+(81-4), (A1 -52)+(61 4>), (A1-52)+(81-6), (A1-52)+(82-1), (A1-52)+(82-2), (A1-52)+(82-3), (A1-52)+(62-4), (A1-52)+(82-5), (A1 -52)+(62-6), (A1 -52)+(62-7), (A1-52)+(82-8), (A1 -52)+(62-9), (A1-52)+(62-10), (A1 -52)+(82-11), (A1-52)+(62-12), (Ai-52)+(62-13), (A1 -52)+(82-14), (A1 -52)+(62-15), (AI -52)+(62-16), (A1 -52)+(62^17), (A1-52)+(62-18), (A1 -52)+(62-19),. (A1-52)+(82-2()), (A1-52)+(82-21), (A1 -52)+(82-22), (Ai -52)+(62-23), (A1 -52)+(82-24), (A1 -62)+(82-25), (AI -52)+(B2-26), (A1 -52)+(82-27), (At-52)+(82-28), |A1 -52)+(82-29):,:. (A1 -62)+(83-1), (At-52)+(63-2), (At-52)+(64-1), (AI -52)+(84-2), (A 1-52)+(134-3), (Ai -52)+(64-4), (A1 -52)+(84-5), (At-52)+(84-6), (At -52)+(64-7), (AI -62)+(64-6), (A1-52)+(84-9), (A1-52)+(84-10), (A1-52)+(64-11), (A 1-52)+(65-1), (A1-52)+(85-2), (A 1-52)+(85-3), (At-52)+(85-4), (A1 -52)+(85-5), (Ai -52)+(86-1), (A1 -52)+(86-2), (A1 -52)+(86-3), (AI -52)+(86-4), (A1 -52)+(66-5), (A1-62)+(86-6), (A1-52)+(87-1), (A1 -52)+(87-2), (A1 -52)+(87-3), (A1 -52)+(87-4), (A1 -52)+(87-5), (A1 -52)+(87-6), (At-52)+(87-7)), (At-52)+(87-7), (A1-52)+(87-8), (At-52)+(88-1), (A1-52)+(88-2), (At -62)+(68-3), (A1 -52)+(88-4), (A1 -62)+(88-5), (A1 -52)+(88^8), (A1 -52)+(88-7), (At -52)+(89-1), (At-52)+(89-2), (AI -52)+(810-1), (A 1-52)+(810-2), (At-52)+(8t0-3), (A1-52)+(810-4), (A1-52)+(810-5), (A1 -52)+(611-1), (At-52)+(81:1-2), (A1-52)+(811-2), (Ai"53H(B1 -1); (Αΐ-53»+(δ1-2}, (A1-53)AB1-3}: (41-53)+(81-4), (Λ1-53)+(81-5). (A1~S3)+(B1 -6), (AI -53)+(82-1), (Ai -53)+(82-2), (A1 -53)+(82-3), (A1-53)+(82-4¾ (Ά1-53)+(82-5). (A1 -53)+(82-8), (A1-53)+(82-7), (AI-53)+(82-3), (A1-53)+(82-8), (A1 -53)+(82-10), (A1 -53)+(82-11), (A1-53)+(82-12), (A1-53)+(82-13), (A1 -53)+(82-14), (Ai·-53)+(82-15), (A1 -53)+(82-13), (A1 -53)+(82-17), (A1-53)+(82-13), (AI-63)+(82-19), (AI -53)+(82-20), (AI -53)+(82-21), (A1 -53)+(82-22), (AI -53)+(82-23), (AI -53)+(82224), (A1-53)+(82-25):, (A 1-53)+(82-26), (AI-53)+(82-27), (AI-53)+(82-28), (AI-53)+(82-29), (AI -53)+(83-1), (AI-53)+(83-2), (AI -53)+(84-1), (AI-53)+(84-2), ^1-63)+(84-3), (AI -53)+(84-4), (AI-53)+(84-5), (AI-53)+(84-6), |Α1-53)+(Β4-7):, (A1-S3)+(B4~8)i: (A1 -53)+(84-9), (AI -53)+(84-10), (AI -53)+(84-11), (41:-53)+(85-1), (A1-53)+(85-2), (A1-53)+(85-3), (AI-53)+(85-4), (AI-53)+(85-5), (AI-53)+(86-1), (AI-53)+(86-2), (AI-53)+(86-3), (AI-53)+(86-4), (AI-53)+(86-5), (A1-53)+(86-6), (A1-53)+(BJ-1), (AI-53)+(87-2), (AI-53)+(87-3), (AI-53)+(87-4), (A1-53)+(87-5). (A1~53)+(B7-6):, (AI-53)+(87-7)), (AI-53)+(87-7), (AI-53)+(87-3), (AI-53)+(88-1), (41-53)+(88-2), (AI -53)+(88-3), (AI-53)+(88-4), (A1 -53)+(88-5), (A1-53)+(88-6), (41-53)+(88-7), (A1:-63)+:(B^D> (Al-53)+(B9-^)j (AI-53)+(810-1), (A1-63)+(B10-2), (AI-53)+(810-3), (AI -53)+(810-4), (AI -53)+(810-5), (AI -53)+(811-1), 441-53)+(811-2), (Ai-53)+(811-2), (At-54)+(81-1), (A1-54)+(81-2), (A1-54)+(B1-3), (AI-54)+(81-4), (AI -54)+(81 -5), (AI:-54)+(81-8), (A1 -54)+(82-1), (41-54)+(82-2), (Ai-54)+(82-3), (41-54)+(82-4), (AI-54)+(82-5), (Ai-54)+(82-6), (AI -54)+(82-7), (AI-54)+(82-8), (A1-54)+(82-9), (AI-54)+(82-10), (AI -54)+(82-11), (AI -54)+(82-12), (A1-54)+(82-13), (41-64)+(82-14), (Ai -54)+(82-15), (AI-54)+(82-16), (AI-54)+(82-17), (AI-54)+(88-18), (AI -54)+(82-10), (Αΐ-64)+(Β|~2ί)}, (AI-54)+( B2-£1), (A1-54)+(82-22.), (A1-54)+(82-23), (AI -54)+(82-24), (AI-54)+(82,25), (AI-54)+(82-26), (AI -54)+(82-27), (AI-54)+(82-28);, (A1-54)+(82-29), (A1-54)+(83-1), (A1~64)+(B3-2), (AI-54)+(84-1), (A1-54)+(84-2), (41-64)+(84-3), (AI -54)+(84-4), (AI -54)+(84-5), (AI -54)+(84-6), (41-64)+(84-7), (AI-54)+(84-8), (AI -54)+(84-9), (AI -54)+(84-10), (AI -54)+(84-11), (AI -54)+(86-1), (A1 -54)+(85-2), (AI-54)+(85-3), (A1-54)+(85-4), (A1-54)+(85-5), ;(A1;-54)+(B6-1)i (AI-54)+(86-2), (AI -64)+(86-3), (AI -54)+(86-4), (41-54)+(86-5), (41-54)+(88-6), (AI -54)+(87-1), (AI -54)+(87-2), (AI-54)+(87-3), (41-54)+(87.4), (41-54)+(87-5), (AI-54)+(87-8), ,^54Κ(Β?-7\}:. (AI--54)+(87--7¾ (41-54)+(87-% ^A1~S4)^CB8-7(41-54)+(88.-2¾ (A1 -54)+(88-3), (41 -54)+(88-4), (41 -54)+(88-5), :(41-54)+(88-8), (41 -:54)4(88-7), (At -54)+(89-1},: (41434)+(89-2}. (AI -54)+(818-1,),. (41-54)+(810-2), (41 -54)+(810-3), (41-54)+(810-4), (Α1 -64)+(810-5). (41 -54}+(811 -1}, (41-54)+(811-2), (A1-54)+(811-2), (41-55)+(81-1), (Α1 -55)+(81 ~2), (41 -55)+(81 -3), (41 -55)+(81-4), (41-55)+(81-5), (41-55)+(81-6), (41-55)+(82-1), (41-55)+(82-2), (41-65)+(82-3), (41-55)+(82-4), (41-55)+(82-5), (A1 -55)+(82-6), (41-55)+(82-7), (41-55)+(82-6), (41-55)+(82-0), (41-55)+(82-10), (41-55)+(82-11), (41-55)+(82-12), (41-55)+(82-13), (41 -55)+(82-14), (41-55)+(82-15), (Ai -55)+(82-16), (Α1 -55)+(82-17), (41 -55)+(82-16}, (41 -55)+(82-19), (41-55)+(82-20), (41-55)+(82-21),. (41 -65)+(82-22), (41 -55)+(82-23), (41-55)+(82-24), (41 -55)+(82-25), (41 -55)+(82-26), (41 -55)+(82-27), (41 -55)+(82-28), (41 -55)+(82-20), (41-55)+(83-1), (41 -55)+(83-2), (41 -55)+(84-1), (41 -56)+(84-2), (41-55)+(84-3), (41-55)+(84-4), (41-55)+(84-5), (41-55)+(84-6), :(41-53)+(84-7), (4:1-65)+(84-8),. (41-55)+(84-9), (41-55)+(84-10), (41-55)+(84-11), (41-55)+(85-1), (41-55)+(85-2):, (41-55)+(85-3), (41-55)+(85-4), (41-55)+(85-5), (41-55)+(86-1):, (41 ~55}+(86~4> (41-55)+(86-3), (41-55)+(86-4), (41-55)+(86-5), (41-55)+(86-6), (41-55)+(8 /-1), (41-55)+(87-2), (41-55)+(87-3), (41-55)+(87-4), (41-55)+(87-5), (41-55)+(87-6), (41:-55)+(87-7)), (41-55)+(87-7), (41 -55)+(87-8), (4:1-55)+(88-1), :(41-55)+(88-2), (41 -55)+(88-3), (41-55)+(88-4), (41 -55)+(88-5), (41-55)+(88-6), (41-45)+(86-7¾ (41-65)+(89-1), (41 -55)+(89-2), (41-55)+(816-1), (41-65)+(810-2), (41-55)+(810-3¾ (41-55)+(816-4), (41-55)+(810-5), (41-55)+(811-1), (41-55)+(811-2), (41-55)+(811-2), (41-58)+(81-1:), (41-56)+(81-2), (41-56)+(81-3)ν(41-56)+(81-4), (41-56)+(81-5:¾ (41-56)+(81-5), (41-56)+(82-1), (41-56)+(82-2), (41-56)+(82-3), (41-06)+(82-4), (41-56)+(82-6), (41-56)+(82-6), (41-66)+(82-7), (41:-56)+(82-8), (41-56)+(82-9), (41-56)+(82-10), (41-56)+(82-11), (41-56)+(82-12), (41-56)+(82-13), (41-56)+(82-14), (41-56)+(82-15),. (41 -56)+(82-16), (41 -56)+(82-17), (41-56)+(82-16), (41-56)+(82-19), (41-56)+(82-20), (41-56)+(82-21), (41-56)+(82-22), :(41-56)+(82-23), (41-56)+(82-24), (41-56)+(82-25), .{Ai-66)+(82-26), (41 -56)+(82-27¾ (41 -58)+(82-28). (41:-56)+(82-20¾ (41-56)+(:83-1), (41-:56)+(83-2), (41-56)+(84-1), (41-56)+(84-2), (41-56)+(^4-3¾ (A 1-56)+( 84-4), (A 1-68)484-5), (AI -56)484-6), iAI-66)4-(34-7), (A1-56)-(84-86 (A1 -56)4-(04-6). (A1 -56)-684-10), (Ai-50)434414 (A 1-56)-485-14 (A 1-56)4(85-5). (AI-56)+(85-3), (A1 -56)+(85-4), (A1 -56)+(85-54 (A1-66)+(864), (Α1~6§)+(ΒΘ-2)> (A1-56)+(86-3), (AI -56)+(86-4), (A1 -56)+(86-5), (A1 -56)+(86-6), (A1-36)+(B74), (AI-56)+(87-2), (AI -56)+(87-3), (Ά1-56)+(87-4), (AI -56)+(87-5), (Ai -56)+(87-6), (A1 -56)+(87-7)), (A1-56)+(87-7), (Αΐ*δβ:).+{87+8)., (A1-56)+(884), ^1-56)+(88-2), (A1-56)+(88-3), (Ai -56)+(88-4), (A1-58)+(88-S), (A1-56)+(88~6)s (A1-56)+(B8-7), (AI-58)+(80-1), (A1 -56)+(89-2), (A1 -56)+(81 04), (AI-68)+(810-2), (AI-56)+(810-3), (A1-56)+(810-4), (A1-56)+(810-5), (A1-56)+(811-1), (A1-56)+(811-2), (AI -56)+(811-2), (A1-57)+(81-1), (A1-57)+(81-2), (A1 -57)+(81 -3), (A1~67)+(B1-4)i (Al-57)+(Bl-5), (A1~57)+(8i~6), (A1-57)+(82-1), (Ai -57)+(82-2), (AI -57)+(82:-3), (A1 -57)+(8:2-4), (A 1-57)+(82-5), (AI-57)+(82-6), (AI-67)+(82-7)): (Αΐ-57)+(Β2-8)! |A1 -67)+(824),: (AI-57)+(82-10), (A1-57)+(8241), (A1-S7)*(B242l, (AI-57)+(824 3), (AI-57)+(82-14), (A1-57)+(82-15), (A1-57)+(824 6), (AI-57)+(824 7), (AI -57)+(8248), (A1 -57)+(82-19), (Ai-57)+(82-20), (AI-57)+(82-21), (A1 -57)+(82-22), (AI-57)+(82-23), (AI-67)+(82-24), (A 1-57)+(82-25), (AI -57)+(82-26), (Ai -57)+(82-27), (A1 -57)+(82-26), (AI -57)+(82-28), (AI -57)+(83-1 >, (A1-57)+(83-2), (AI -57)+(84-1), (AI -57)+(84-2), (A1 -57)+(84-3), (AI-57)+(84-4), (Ai-57)+(84-5), (AI-57)+(84-6), (A1-67)+(84-7), (AI-67)+(84-6), (AI-57)+(84-9), (Ai-57)+(84-10), (AI-57)+(84-11,), (A1~57)+(854), (AI-57)+(85-2), (AI-57)+(85-3), (AI -57)+(85-4), (AI-57)+(85-5), :(A1-57)+(86-1.):, (AI-57)+(86-2), (AI-57)+(86-3), (A1-57)+(86-4)! (AI-57)+(86-5), (Ai-5?)+(86-6), (A1-57)+(B744 CA1-57)+(B7-2), (AI-57)+(87-3), (AI-57)+(87-4), (AI-57)+(87-5), (^1-57)+(87-6), (AI-57)+(87-7)), (A1 -57)+(87-7), (AI-57)+(87-6), (AI-57)+(884), (A1 -57)+(864), (AI -57)+(86-3), (A1 -57)+(86-4), (A1 -57)+(88-6), (A1 -57)+(88-6), (AI -57)+(884), (AI-57)+(894), (AI-57)+(89-2.), (A1 -57)+(8104), (AVS7)+(B10-2), (AI-57)+(81:0-3), (A1-57)+(B 10-4), (AI-57)+(810-5), (A1-57)+(811-1), (AI-57)+(811-2), (At~57)+(B11-2), (Ai -56)+(81-1), (AI-58)+(814), (AI-58)+(81-0), (A1 -56)+(81-4), (AI-58)+(81-6), (A1 -56)+(81 -6), (AI-58)+(82-1), (A1-58}+(82-2), |A1 -58)+(824), (AI-58)+(82-4). (A1 -58)+(82-5), (A1 -58)+(82-6), (A 1 -58)+(82-7), (AI -68)+(824), (AI -58)+(82-9):, (AI-56)+(82-10), (A1 -58)+(82-11), (AI-58)+(824 2), (A1-58)+(82-13), (Al-58)+(62-14), (A:t-68)+(82-15), (Al-58)+(82-1:0), (A1-58)+(82-l 7), (A 1 -58)+(82-1 8), (A1 -58)+:(82-19). (At-58)+(S2-2Q}, (ΑΊ-58)+(82-21), (AT-58)+(82-22), (Ai-58)+(B2~23), (Al -88)+(82-24), (ΑΤ«δ8:)*ρ&amp;25χ (A1 -88)+(82-28), (A1 -58)+(82-27), (Al -58)+(82-28), |A1 -53)+(82-29), (A1-58)+(83-1), (Al -58)+(83-2), (A1 -58)+(84-1), {A1~53)+(iA-2), (At-S8)*(B4-6), (A1 -58)+(84-4), (A1-58)+(84-5):, (A1 -58)+(84-8), (A1-58)+(84-7), (Α1-58}+(Β4-8), (Al-58)+(84-9), (Al -58)+(84-10), (Al-58)+(84-It), (Α1-58)+(85-1), (AT-88)+(B5-2), (A1-58)+(B5-3), (Al -68)+(65-4), (Α1~58)+(Βδ-5), (A1 -88)+(86-1), (A1 -58)+(86-2), (Al -58)+(86-3), (A1 -58)+(88-4), (A1 -58)+(86-5),: |A1 -58)+(86-6),(A1 -58)+(87-1 % (Al-58)+(87-2), (AT-58)+(B/'-3)! (A1-58)+(87-4), (At-58)+(67-5), (A1-58)+(S7-S), (At-58)+(87-:7)), (A1-58)+(87-7), (Al -58)+(87-8), (Ά1-55)+(88-1), (Al-53)+(SS-2), (A1 -58)+(68-3), (A1-58)+(68-4), (A1-58)+(68-5), (A1-58)+(68-6), (Al-53)+(68-7), (A1 -58)+(69-1), (A1 -58)+(89-2), (Al -58)+(610-1), (Ai-58)+(B10-2), (Al-58)* (8:10,3), (A1 -58)+(810-4), (Al -58)+(810-6), (A1-58)+(611-1), (A1-58)+(811-2), (A 1-58)+(811-2), (Al-59)+(81+1), (Al -69)+(81-2:), (Al -59)+(61-3),. (ΑΤ·6δΗΒΤ*5)( (Al-69)+(81-8), (Al-59)+(82-1), (Al -69)+(62-2¾ (A1-59)+(82-3), (Al-59)+(182-4), (A1-59)+(82-5), (Al -69)+(82-6), (A1-59)+(82-7), (Al-59)+(62-8), (Al-59)+(82-9), (A1 ^59)+(62-10), (Al -69)+(82-11), (Al-59)+(8242), ^1-59)+(6243),, (Al-59)+(82-14), (Al -59)+(82-15), (Al -59)+(82-16), (At-59 )+(82-17), (Al -59)+(82-18), (A1 -59)+(82-19), (Al -59)+(:82-2:0), (A1-69)+(82-21), (A1-59)+(82-22), (A1 -59)+(62-23), (A1 -59)+(82-24), (Al -69)+(82-25), (Al-59)+(82-26), (A1-59)+(82-27), (Al -69)+(82-28), (41-59)+(82-29), (Al-59)+(63-1), (Al-59)+(63-2), (Al-59)+(64-1), (A1-59)+p4-2), (Al-59)+(64-^ (Al-59)+(84-4), (Al-59)+(84-5), (A1-59)+(84-6), (A1-59)+(84-7), (A1-59}+(84,„g)[ (Al -59)+(84-9), (Al -59)+(84-10), (Al -59)+(84-11), (Al-59)+(85-1), (Al (A1 -59)+(65-3), (A1 -59)+(65-4), (Al -59)+(85-5), (Al -59)+(86-1), (A1 -59)+(86¾)^ (At-59)+(86-8), (Al-59)+(89-4), (Al-59)+(66-5), (Al-89)+(86-8), (At-69)+(87-4 ^ (A1-5S)+(8?-2), (A1-59)+(B7-3), (Al-59)+(87-4), (Al-39)+(67-5), (A1-59)+:(B7-6), (Al -69)+(67-7)), (Al -59)+(87-7), (Al-59)+(87-3), (Al-59)+(88-1), (Al-59)+(88^ (Α1-59)+(68-3), (A1-59)+(88-4), (41-69)+(83:-5), (41-69)+(88-6¾(A1 ~69)+(Bg.,?^' (Al-59)+(89-1), CA1 -59)+(89-2), (At -59)+(610-1), (Al -59)+(810-2), (A14S9)^1q (A1 -59)+(810-4), (Al-59)+(610-5), (A1 -59)+(811 -1% (Al-59)+(811-2), (Al -59)+(811-2), (Λ1 -60)-(61-1), (41-50)+(81-2), (A 1-60)-(81-3), (Al-00)+(81-4), (Al -601+(01--5), (Ά1-60ΗΒ2-3), (M-60)+(82-4), (A1 -60)+(82-5), (At-60)+(82-6), (A 1-60)+(82-7), {A1-60)+(B2-8), (ΑΐΑ30)+(β2-37 (A1-60)+(82-10), (A1 -60)+(82-11), (A1 -60)+(82-12%. (A1 -00)+(82-13). (A1-60)+(82-14), (A1 -60)+(82-15:), (A1 -60)+(82-16), (A1-O0)+(82-17), (A1-60)+(82~18), (A1 -60)+(82-19), (Al-60)+(82-20), (A1-60)+(82-21), (A1-60)+(82-22), (Ά1-80)+(02-23), (A1-60)+(82-24:), (A1-60)+(82-25), (A1-60)+(82-26), (Al -60)+(82-27), (At-60)+(82-28), (Al-60)+(82-29), (A1-60)+(83-1), (A1·-60)+(83-2), (Ά1 -60)+(84-1), (A1-60)+(84-2), (Al -60)+(84-3), (A1 -80)+(84-4), (Al-80)+(84-5), (A1 -60)+(84-6), (A1-60)+(84-7), (A1-60):+(84-8)t: (A 1-60)+(84-8), (Al-60)+(84-10), (Al -60)+(84-11), (Al-60)+(85-1), (Al-60)+(85-2), (Al -60)+(85-3), (Al -60)+(85-4), (Al -60)+(85-5), (Al -60)+(86-1), (Al -60)+(86-2), (Al -60)+(86-3), (Al 40)+(86-4),. (Al -60)+(86-5), (Al -60)+(80-6), (Al -60)+(87-1), (Al -60)+(87-2), (Al-60)+(87-3), (Al-60)+(87-4), (A1-60)+(87-5), (At~60)+(8?~8), (A1 -60)+(87-7)), (A1-60)+(87-7), (A1 -60)+(87-8), (A1 -60)+(88-1), (Al-60)+(88-2):, (A1 -60)+(88-3), (Al -60)+(88-4), (A1 -60)+(86-5), (A1-6Q)+(B8-6). (Al -60)+(88-7), (Al-60)+(89-1), :(A1-60)+(89-2), (A1-6O)+(B10-1), (Al-60)+(810-2), (Al-60)+(810-3), (Al-60)+(810-4), (A1 -60)+(810-5), (Al-60)+(811 ~T), (Al -60)+(811-2), (A1-60}+(B11-2), (Al-61 )+(81-1), (Al-61 )+(81-2), (A1 -61)+(81-3), (Al-61,)+(81-4), (A1-61 )+(81-6):, (Al -61 )+(81-6), (A1 -61 )+(82-1), (Al -61)+(82-2), (A1 -61)+(82-3), (Al -61 )+(82-4), (Al-61 )+(82-5), (A 1-61 )+(82-6), (Al -61)+(32-7), (Al-61 )+(82-3), (Al-61)+(82-9), (Al-61 )+(82-10), (Al-61 )+(82-11), (A 1-61)+(82-12), (Al-61 )+(82-13), (Al -61)+(82-14), (A 1-81 )+(82-157 (Al -61 )+(82-16), (Al-61 )+(82-17),. (Al--61 )+(82--16), (Al-61)+(82-10), (A1-61 )+(82-20), (Al-61 )+(82-21), (Al-61)+(82-22), (Al-61:)+(82-23), (At-61 )+(82-24), (A1-61)+(82-25), (A1-61 )+(82-26), (Al-61 )+(82-27), (A1 -61)+(82-28), (A1 -61)+(82-20), (Al-61 )+(83-1), (Al-61 )+(83-2), (At-61)+(84-1), (At-61 )+(84-2), (Al -61)+(84-3), (Al-61:)+(84-4), (Al-61 )+(84-5), (At-61)+(84-6), (Al-61 )+(84-7), (Al-61)+(84-8):, (Al-61 )+(84-9), (Al-61 )+(84-10), (Al-01 )+(84-11), (A1~61 )+(85-1), (Al-61 )+(85-2), (Α1-βί)+(85-3), (Al-61 )+(85-4), (Al-61)+(85-5), (Al-01 )+(86-1), (A1-61 )+(86-2), (Al-61 )+(86-3), (Al-61 )+(86-4), (Al-61 )+(88-5), (Al-61)+:(86-6), (A 1-61)+(87-1), (Al-61 )+(87-2), (Al -61 )+(87-3), (Al-61 )+(:87+4), (A1 -61 )+(8:74), (Al-61 )+(87-6), (41-61)+(87-7)), (A1-01)+(37-7). (81-61)+(87-8). (A1:~81 (A1 -^)+(88-2), (A 1-61 )-:-(88-3), (A1 -61)+(88--4), (A1 -61 )+(88-5), (Al+61: )+(88-6), (A1 -:51 )+(8 8-7;, (81-61)+(89-1), (A1 -61 )+(08-2), (A1-61 )+(810-2), (81-61)+(810-3), (At-61 )+(810-4), (A1-61 )+(810-5)* (A1-61)+(B1 1-1), (A1-61 HE 11-2), (A1-61 )+(811-2), (A2-1)+(81-1), (A2-1 )+(81-2), (A2-1 )+(81 -3), (Ά2-1 )+(81-4), (A2-1 )+(81-5),: (A2-1)+(B1~6), (A2-1 )+(82-1), (A2-1 )+(82-2), (Aa-D+IBa-O), (A2-1 )+(82-4), (A2-1 )+(132-5), (A2-1 )+(82-6), (A2-1 )+(82-7), (A2-1 )+(82-:8), (A2-1 )+(82-9), (Ά2-1 )+:(82-10), (A2-1 )+(82-11), (A2-1 )+(82-12), (Α2-1)+(82-13),. (A2-1 )+(82-14), (A2-1 )+(82-15), (A2-1 )+(82-16), (A2.-1 )+(82-17), (A2-1 )+(82:-18), (A2~1 )+(82-19), (A2~i )+(82-20), (A2-1 )+(B2-2i), (A2-1 )-+(82-22):, (A2-1 )+(8:2-23), (A2-1)+(82-24), (A2-1 )+(82-25), (A.2-1 )+(82-26), (A2-1 )+(82-27), (A2-1)+(82-28), (A2-1 )+(82-29), (A2-1 )+(83-1), (A2-1 )+(83-2), (A2-1 )+(84-1), (A2-1 )+(84-2), (A2-1 )+:(84-3), (A2-1 )+(84-4), (42-1)+(84-6), (A2-1 )+(84-6), (A2-1)+(84-7), (A2-T)+(B4~8), (A2-1 )+(84-8), (A2-1 )+(84-10), (A2-1 )+(84-11), (A2-1 )+(85-1¾ (A2-1 )+(86-2), (A2-1 )+(85-3), (82-1)+(85-4), (A2-1 )+(85-5), (A2-1 )+(86-1), (42-1:)+(86-2), (A2-1 )+(86-3), (82-1)+(86-4), (82-1)+(88-5), (A2-1)+(85^8), (A2-1 )+(87-1), (42-1)+(87-2), (A2-1 )+(87-3), (A2-1 )+(87-4), {42-1)+(87-5), (A2+! )+(87-6), (42-1)+(87-7)),. (A2-1 )+(87-7), (A2-1 )+(87-8), (Α2-ΐ:)+|Β8-1), (A2-1 )+(88-2), (A2-1 )+(88-3), (A2-1 )+(88-4), (82*1 )+(88-5), (A2-1 )+(8:8-6:), (82-1)+(88-7), (A2-1 )+(89-1), (82-1 )+(89-2), (A2-1 )+(810-1), (42-1)+(810-2), (A2.-1 )+(810-3), (42-1)+(810-4), (A2~i )+(810-5), (A2-1 )+(811-1), (A2-1 )+(811-2), (A24 )+(8.11:-2):, (82-2)+(81~1), (A2-2)+(81-2), (42-2)+(81-3), (A2-2)+(B1-4), (42--2)+(81-5), (42-2)+(81 -6), (42-2)+(82-1), (42-2)+(82-2), (42-2)+(82-3), (48-2)+(82-4), (42-2)+(82-5), (42-2)+(82-6), (42-2)+(82-7), (82-2)+(82-8), (A2-2)+(B2-9), (82-2)+(82-10), (A2-2)+(82-11), (42-2)+(82-12):, (A24)+(82~13), (42-2)+(82-14), (42-2)+(82-15), (42-2)+(82-16),. (A2-2)+(B2-17), (A2-2)+(82~18), (42-2)+(82-1:8), (42--2)+(82-20), {42-2)+(82-21}, (42-2)+(82--22), {42-2)+(82-23), (42.2)+(82-24), (42.2)+(82-25), (42-2)+(82-26), (42-2)+(82-27), (A2-2|+(:B2-26), {42-2)+(82-29), (42-2)+(83-1), (42-2)+(83-2), (42-2)+(84-1), {42-2)+(84-2), (82-2)+(84-3¾ (82-2)+(84--4), (A2-2)+(84-6), (82-2)+(84-6), (42-2)+(84-7¾ (42-2)+(84-8¾ (42-2)+(84-9¾ (42-2)+(84-10), (42-2)+(84-11¾ :(42-2)+(85+1), (Α2,2)+|Β6*2)5 (42-2)+(85-3¾ 642-2)+(85-4), {42-2)+(65-5), (42-2)+(86-1), (82-2)4-(86-2), (42-2)+(86-3), (42-2)+(06-4), (42-2)406-5), (42-21+(86-6), (42:-2)+(g7-i.), (42-2)+(07-2), (42-2)+(87-3): (42-2)+(87-4), (42-2)+(87-8), (Α3-2)+(β7-8): (42-2)+(87-7)), (42-2)+(07-7), (42-2)+(87-8), (42-2)+(88-1), (42-2)+(88-2):, (42-2)+(88-3), (42-2)+(88-4), (42-2)+(88-5), (42-2)+(88-6), (A2~2)+(BS-7), (42-2)+(89-1), (42-2)+(89-2), (42-2)+(810-1), (42-2)+(810-2), (42-2)+(810-3), (42-2)+(810-4), (42-2)+(810-5), (42-2)+(811-1), (42-2)+(811-2), (42-2)+(811-2), (42-3)+(81 -1), (42-3)+(81-2), (42-3)+(81 -3), (42-3)+(81 -4), (42-3)+(131 -5), (42-3)+(81-6), (42-3)+(82-1), (42-3)+(82-2), (42-3)+(82-3), (42-3)+(82-4), (42-3)+(82-5), (42-3)+(82-6), (42-3)+(82-7), (42-3)+(82-8), (42-3)+(82-9), (42-3)+(82-10), (42-3)+(132-11), (42-3)+(82-12), (42-3)+(82-13), (42-3)+(82-14), (42-3)+(82-15), (42-3)+(82-16), (42-3)+(82-17), (42-3)+(02-18), (42-3)+(82-19), (42-3)+(82-20), (42-3)+(82-21), (42-3)+(82-22), (42-3)+(82-23), (42-3)+(82-24), (42-3)+(82-25), (42-3)+(82-26), (42-3)+(82-27), (42-3)+(82-28), (42-3:)+(82-29), (42-3)+(83-1), (42-3)+(83-2), (42-3)+(84-1), (42-3)+(84-2), (42-3)+(84-3), (42-3)+(84-4), (42-3)+(84-5), {42-3)+(84-8), (42-3)+(84-7), (42-3)+(84-8), (42-3)+(84-9), (42-3)+(84-10), (42-3)+(84-14), (42-3)+(85-1), (42-3)+(85-2), (42-3)+(85-3), (42-3)+(85-4), (42-3)+(85-5), (42-3)+(86-1), (42-3)+(:86-2), {42-3)+(86-3), (42-3)+(86-4), (42-3)+(88-5), (42-3)+(86-6):, (42-3)+(87-1), (42-3)+(87-2), (42-3)+(87-3), (42-3)+(87-4), (42-3)+(87-5), (42-3)+(87-0), {42-3)+(87-7)), :(42-3)+(87-7), (42-3)+(87-8), (42-3)+(13-1), (42-3)+(88-2), (42-3)+(88-3), (42-3)+(03-4), (42-3)+(88-5), (42-3)+(88-6), (42-3)+(83-7):, (42-3)+(89-1),: (42:-3)+(89-2), (42-3)+(810-1), (42:-3)+(010-2), (42-3)+(810-3), (42-3)+(810-4:), (42-3)+(810-5), (42-3)+(811-1), (42-3)+(011-2), (42-3)+(811-2), (42-4)+(81-1), (42-4)+(81-2), (42-4)+(81-3), (42-4)+(81-4):, (42-4)+(81-5), (42-4)+(81-6), (42-4)+(82-1), (42-4)+(82-2), (42-4)+(82-3), (42-4)+(02-4), (42-4)+(02-5),(42-4)+(82-6), (42.4)+(1^-7),^ (42-4)+(02-10). (42-4)+(82-11), (42-4)+(02-12), (42-4)+(82-13), (42-4)+(82-14), (42-4)+(82-15), (42-4)+(02-16), {42-4)+(82-17), (42-4)+(82-18:), (42-4)+(02-19), (42-4)+(82-20), (42-4)+(82-21), (42-4)+(82-22), {42-4)+(82-23), (42-4)+(02-24):, (42-4)+(62-25),: (42-4)+(82-28), (42-4)+{82-27), (42-4)+(82-28:), (42-4)+(82-29), (42-4)+(83-1), (42-4)+(63-2), (42-4)+(84-1), (42-4)+(84-2), (42-4)+(84-3), (42-4)+(84-4), (42-4)+(84-5), (42-4)+(84-6), (42-4)+(84-7):, (42-4)+(84-8):, (42-4)+(84-9), (42-4)+(84-10), (42-4)+(84-11), (42-4)+(85-1¾ (42-4)+(85-2), (£2-4)+(85-3¾ (A2-4)+(85-4), (£2-4)+(05-5¾ (£2-4)+(85-1),. (£2-4)+36-2), (Α2-4)+(ΒΒ-3): {Α2-4}4·(Β6-4), (Ά2-4Η(Β6-·5), (Α2--4 Η(Β6~β;ι (Α2~4Η87~1), (Α2-4)+(Β7-2), (£2-4)+(87-3), (£2-4)+(87-4¾ (£2-4)+(87-5), (£2-4)+(87-6), {£2-4)+(87-7)¾ (£2-4)+(87-7), (£2-4)+(67-8), (Α2~4)+(Β8~1), (£2-4)+(88-2¾ (£2-4)+(88-3), (£2-4)+(88-4), (£2-4)+(88-5), (£2-4)+(88-6¾ (Μ-4}+(Β8·-7), (£2-4)+(89-1),, (Α2-4)+(Β9-2), (Α2-4)+(Β10-1), (£2-4)+(810-2), (£2-4)+(810-3), (£2-4)+(810-4), (£2-4)+(810-5), {£2-4)+(81 1-1), (Α2-4)+(8ΐ1-2), (£2-4)+(811-2), in the inventive herbieida! aompositlons, the application rate of the herbioides of the general formula (!) (component A) Is typically 1 to 500 g of active ingredient (a ,I.) per hectare, preferably 2 to 300 g of al/ha, more preferably 3 to 200 g of a.i./ba, The application rate of the herbicides of component B is typically 1 to 5600 g of active ingredient per hectare, preferably 2 to 3000 g of a.I./ha, more preferably 3 to 2000 g of a.I./ha. The application rate of the safeners of component C Is typically 1 to 500 g of active ingredient per hectare, preferably 2 to 490 g of a-i./ha, more preferably 3 to 300 g of a.I./ha.
On application of the inventive herbicide! compositions, a very broad spectrum of harmful plants is controlled pre-emergence and post-emergence, for example annuaf and perennial mono- Or dicotyledonous weeds and unwanted crop plants. The inventive herbicidai compositions are particularly suitable for use In crops suob as cereals, corn, rice, soya, oilseed rape, sugar beet, cotton, sugar cane, and also for use in perennial crops, plantations and Oh non-crop land. They are likewise highly suitable for use in transgenic crops of corn, cereals, sugar beet, nee, cotton and Glycine max. (e.g, RR soya or 11 soya) and crossbreeds thereof), Phaseolus, Plsum, Vida and Arachis, or vegetable crops from various botanical groups seel? as potato, leek, cabbage, carrot tomato, onion, and also perennial and plantation crops such as pome fruit and stone fruit, soft fruit, wine, Hevea, bananas, sugar cane, coffee, tea, citrus, nut plantations, lawn, pairn crops and forest crops, For the use of the inventive herbicide-safener combinations (£)+(8), these crops are likewise preferred, particular preference being given to use In cereals (e,g. wheat, barley, rye, oats), rice, corn, miilefrsorghum, sugar beet, sugar cane, sunflower, oilseed rape and cotton. The herbicide-safensr combinations (£)+(8) can also be used in tolerant and non-folerant mutant crops and toterantand non-tolerant transgenic crops, preferably of corn, rice, cereals, oilseed rap®, cotton, sugar beef and soya, for example those reliant idImi^ipilRone herbicides, cbozine. qiufoslnate. giyphosate, 2,4 D. dicamba and herbicides from the group of the inhibitors of hydroxyphenyipyru'/ate dioxygenase, such as suieoinone, mesetrione, tenibotnbne, tefuryitrione, henzobiGyeion, bioydopyroee and ketosplradox. A herbioidally effective amount in the context of the invention means an amount of one or more herbicides capable of adversely affecting plant growth. An antidoticaliy effective amount in the context of the invention means an amount of one or more safeners capable-of reducing the phytotoxic effect of crop protection active Ingredients (for example of herbicides) on crop piants.
According to their properties, the safeners (€) present in the inventive herbicidai compositions can also be used for pretreatment of the seed of the crop plant (for example for dressing of the seed) or introduced into the seed furrows prior to sowing or employed together with the herbicide prior to or after emergenoe of the plants. Preemergence treatment includes both the treatment of the area under cultivation (Including any water present in the area under cultivation, for example in the esse of applications to rice) prior to sowing and the treatment of the areas under cultivation in which seeds have been sown but which are not yet covered by growing plants. Preference is given to application together with the herbicide, For this purpose, it is possible to use tank-mixes or ready-made formulations, in a preferred embodiment, the seed (for example grains, seeds or vegetative propagation organs such as tubers or budded parts of shoots) or seedlings are pretreated with the safeners (C), optionally In combination with ether active agrochemical ingredients. For pretreatment of the seed, the active ingredients can be applied to the seed, for example by dressing, Or the active ingredients and the seed can be added to water or other solvents, and the active ingredients can be taken up, for example, by adsorption or diffusion in a dipping process or by swelling or pre* germination. For pretreatment of seedlings, the young plants can be contacted with the safeners, optionally in combination with other active agrochemical ingredients, for example by spraying, dipping or watering, and then transplanted and optionally aftertreated with the herbicides (A) and (B).
The seed or seedlings can be treated with the safeners (C) alone or together with other active igrochemjoaf ingredients - such as fungicides, insecticides or plant fortifiers, fertilizers or swelling and cierntenation accelerators.. After the pretrestment application; the safeners. may subsequently be applied once again; before, after or together with one or more herbicides of the formula (!) (A) and herbicides (B), possibly also in combination with other known herbicides, The pretreatment of the seed or seedlings can achieve improved long-term efficacy of the safeners.
The present invention thus further provides a method of controlling unwanted plants in plant crops, which is characterized in that components (A), (B) and optionally (C) of the Inventive herbicide! compositions are deployed, for example separately or together, on the plants (for example harmful plants such as mono- or dicotyledonous weeds or unwanted crop plants), the seed (for example grains, seeds or vegetative propagation organs such as tubers or budded parts of shoots) or the arpa on which the plants grow (for example the area under cultivation). One or more safeners (C) may be applied before, after or simultaneously with the herblcide(s) of the general formula (I) (A) and the herbicides (B) to the .plants, the seed or the area on v#lc!r'tto0.plants Qfow.psr example the area under cultivation). In a preferred embodiment, the safeners (C) are used for seed treatment.
Unwanted plants are understood to mean all plants which grow at sites where they are unwanted. These may, for example, be harmful plants (for example monocotyiedonous or dicotyledonous weeds or unwanted crop plants), including, for example, those which are resistant to certain active herbicidal compounds, such as glyphosate, atrazin#» giufosinate or imidazoiinone herbicides.
Monocotyiedonous weeds are classified, for example, in the genera iSchinochloa, Setarte, Panscuro, Digitaria, Phleum, Poa, Festuca, Eleusine, Brachiaria. Loiium, Bromus, Avena, Cypefus, Sorghum, Agropyron, Synodon. Monochoria, Fimbrisfyiis, Sagittaria, Eieocharls, Scirpus, Paspalum, Ischaemum, Sphenoeiea, Dactyioctenium, Agrostis, ASopecurus, Apera. Phalaris. Dicotyledonous weeds are classified, for example, in the genera Sinapis, Lepldium, Galium,. Steteia^/Matdcaria^Anthem^k Galinsoga, Chenppodiurn, tirtica, Senecio, Aroaranthus, Portuteca, Xanthium, Convolvulus. Ipomoea, Polygonum, Sesbania, Ambrosia, Cirsiurm Carduus, Sonchus, Soianum, Rorippa, Rotate, Undemte, Lamium, Veronica, Abutiion, Emex, Datura,
Viola, Gateopsia, Papaver, Gentaurea, Trifolium:, ^hidhSMfdSj: Tan3x$.cU:f% ^uphbl^f#:·,. Kochia, Bidbn, Stellana.
The invention: also provides for the use of the inventive hemioidai compositions Tor controlling unwanted, vegetation, preferably in plant crops.
The inventive herbicidal compositions can be prepared by known methods, for example as mixed formulations of the individual components, optionally with further active Ingredients, additives and/or customary formulation auxiliaries, and these are then applied in a customary manner after dilution with water, or as tank mixes by joint dilution of the separately formulated or partly separately formulated individual components with water, Likewise possible is the application at different times (split application) of the separately formulated or partly separately formulated individual components,. It is also possible to apply the individual 1 components dr the herbicide! compositions in a plurality of portions (sequential application), for example by preemergence applications followed by post-emergence applications or by early po# emergence applications followed by medium or late past-emergence applications, Preference is given to the joint or immediately successive application of the active ingredients in the respective combination.
The inventive herhicidai compositions can also fee used for control of harmful plants in crops of genetically modified plants which are known or are yeti© be developed.
In general, transgenic plants are characterized by particular advantageous properties, for example by resistances to certain pesticides, in particular certain herbicides, resistances to plant diseases or pathogens of plant diseases, such as certain insects or microorganisms such as fungi, bacteria or viruses. Other particular properties relate, for example, to the harvested material with regard to quantity, quality, storabiiity, composition and specific constituents, For instance, there are knownTransgehic piants with an elevated starch content or altered starch: quality, or those with a different fatty acid composition in the harvested material. Other particular properties may be tolerance or resistance to abiotic stressors, for example heat, low temperatures, drought, salinity and ultraviolet radiation.
Preference is given to the use of the inventive compositions. important transgenic crops of useful plants and ornamentals, for example of cereals such as wheat, barley, rye, oats, nfillet/sorghurni rice, cassava and corn, or else crops of sugar beet Gotten, soybean, oilseed rape, potato, tomato, peas and other vegetables.
Conventional ways of producing novel plants which have modified properties in comparison to existing plants consist, for example, in traditional breeding: methods and the generation of mutants. -Alternatively, novel plants with modified properties can be generated with the aid of recombinant methods (see, for example, EFeM5221844, EP-A-0131824), For example, there have been descriptions In several cases of: genetic modifications of crop plants for the purpose of modifying the starch synthesized in the plants (for example WO 92/11378, WQ 92/14827,, WO 91/19808), transgenic crop plants which are resistant to particular herbicides of the gtufosinate type (cl, for example, EP~A~0242238i :ΕΡ-·Α»:242248) or gjyphesafe type (WO 92/00377) or of the sulfonylurea type :pPvVQ257993, US-A-8013859), transgenic crop plants, for example cotton, with the ability to produce Bacillus thuringiensis toxins (Bi toxins), which make the plants resistant to particular pests (EP-A-0142924, EP-A-0193259), transgenic crop plants with a modified fatty acid composition (WQ 91/13972), genetically modified crop plants with nova! constituents or secondary metabolites, for example novel phytoalexins, which bring about an increased disease resistance (ERA 308882, EPA0464481), genetically modified plants having reduced photorespirafion, which have higher yields and higher stress tolerance (ERA 0305388), transgenic crop plants which produce pharmaceutically or diagnostically important proteins ("molecular charming"), transgenic crop plants which feature higher yfoids or better guality, transgenic crop plants which feature a combination, for example, of the abovementioned novei properties ("gene stacking").
Numerous molecular biology techniques which can be used to produce novel transgenic plants with modified properties ara known in: principle; see, for example, l Potrykus and G, Spangenberg (eds. ) Gene Transfer to Plants, Springer lab Manual (1895), Springer Vsfiag Berlin, Heicteiberg,:pr in Riant Science” 1 (1996) 423-431).
For such recombinant manipulations, nucleic acid molecules which allow mutagenesis or sequence--alteration hv recombination of DNA sequences can be introduced into piasmids. With the aid of standard methods, ills possible, for example, to undertake base exchanges, remove parts of sequences or add natural or synthetic sequences. For the connection of the DNA fragments to one another, it is possible to add adapted or linkers to the fragments; see, for example, Samhrook et at* 1:989* Molecular Cloning, A Laboratory Manual, 2nd ed., Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Wlnnacker "Gene und Klone", VCHWeinheim,; 2nd edition, 1996,
For example, the generation of plant cells with a reduced activity of a gene product can be achieved by expressing at least one corresponding antisense RNA, a sense RNA for achieving a cosu ppression effect, or by expressing at least one suitably constructed nbozyme which specsficaliy cleaves transcripts of the abovemehtiened gene product
To this end, it is firstly possible to use DNA molecules which encompass the entire coding sequence of a gene product Inclusive of any flanking sequences which may fee present, and also DNA molecules which only encompass portions of the coding sequence, in which case It Is necessary for these portions to be long enough to have an antisense effect in the cells. It is also possible to use DNA sequences which have a high degree of homology to the coding sequences of a gene product, but are not completely identical to them.
When expressing nucleic acid molecules in plants, the protein synthesized may be localized in any desired compartment of the plant cell. However, to achieve localization in a particular compartment, it is possible, for example, to join the coding region to DNA sequences which ensure localization in a particular compartment. Such sequences are known to those skilled in the art (see, for example, Braun etai.,: EMBQ J. 11 (1992), 3219-3227; Wolter et al., Pros. Natl, Acad. 8ci. USA 8:5 (1988), 848450; Sonnewaid etaL PianU. 1 (1991), 95-108). The nucleic acid rnclecules can also be expressed in the organelles of the plant cells.
The transgenic plant ceils can be regenerated by known techniques to give rise to entire plants, in principle, the transgenic plants may be plants of any desired plant species, i.e, not only monocotyiedonous but also dicotyledonous pianis.
Thus, transgenie plants can be obtained whose properties are altered by overexpression, suppression or inhibition of homologous (~ natural) genes or gene sequences or expression of heterologous (= foreign) genes or gene sequences.
Preferably the inventive compositions can be used in transgenic crops which are resistant to growth regulators such as, for example, dicamba, or to herbicides which inhibit essential plant enzymes, for example acetolaetate synthases (ALS)* EPSP synthases, glutamine synthases (GS) or hydroxyphenylpyruvate djoxygenases (HPPD), or to herbicides from the group of the suifenylureas, the glyphosates, glufosinates or benzoylisoxazoles and analogous active ingredients.
On employment of the inventive compositions in transgenic crops, not only bo the effects toward harmful plants observed in other crops occuq but often also effects wbfch are specific to application in the particular transgenic crop, for example an altered or 'Specifically widened spectrum of weeds which can be controlled, altered application rates which can be used for the application, preferably good cornbinabiiity with the herbicides to which the transgenic crop is resistant, and Influencing of growth and yield of the transgenic crop plants.
The Invention therefore also provides for the use of the inventive compositions for control of harmful plants in transgenic crop plants.
Preference is given to the use of the inventive compositions in economically Important transgenic cmps of useful plants and ornamenfaisyfor example Of cereals (e.g, wheat, barley, rye, oats), milief/sorghurn, rice» cassava and corn, or else crops of sugar beet, cotton, soybean, oilseed rape, potato, tomato, peas and other vegetable crops.
The invention therefore also provides for the use of the inventive cPmppsItiohs for control of harmful plants in transgenic crop plants or crop plants having tolerance through selective breeding.
The herbicides (A), (B) and the safeners (£)) can be converted together or separatelv to customary formulations, for example for application by spraying, watering, sphnkliha and seed dressing, such as solutions, emulsions, suspensions, powders, foams, pastes, granules, aerosols, active ingredleniumpregnaied natural' and synthetic substances, mlcroencapsulatiGns in polymeric substances. The formulations may comprise the customary auxiliaries and additives,
These formulations are produced in a known manner, for example by mixing the active ingredients with extenders, i,e. liquid solvents, pressurized liquefied gases and/or solid carriers, optionally with use of surfactants, le. emulsifiers and/or dispersants and/or foam formers. if the extender used is water, it is also possible to use, for example, organic solvents as auxiliary solvents. Useful liquid solvents essentially include: aromatics such as xylene, toluene or alkyinaphthaisnes, chlorinated aromatics or chlorinated aliphatic hydrocarbons such as chlorobenzenes, chioroefhyienes or methylene chloride, aliphatic hydrocarbons such as cyclohexane or paraffins, for example mineral oil fractions, mineral and vegetable oils, alcohols such as butanol or glycol and the ethers and esters thereof, ketones such as acetone, methyl ethyl ketone, methyl isohutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide or dimethyl sulfoxide, and water.
Useful solid carriers include: for example ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgife, montmorliioriite or diafomaoeous earth, and ground synthetic minerals, such as finely divided silica, alumina and silicates; useful solid carriers for granules include: for example crushed and fractionated natural rocks, such as calcite, marble, pumice, seplolite, dolomite and synthetic granules of inorganic and organic flours, and granules of organic material, such: as sawdust, coconut shells, corn cobs and tobacco stalks; useful emulsifiers and/or foam formers include: for example nonionic and anionic emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers,: e.g, alkyiary!; polyglycol ethers, aikylsulionaies,aiky!suifates1,.ary!sulf0.nate$':and protein hydrolyzates; useful dispersants include: for example lighosuifite waste liquors and methylceilulo-se. in the formulations, it is possible to use tackifiers such as carboxymefhyieelSulose, natural and synthetic polymers in the form of powders, granules or iatices, such as gum arable, polyvinyl alcohol and polyvinyl acetate, or else natural phospholipids such as cephalitis and lecithins and synthetic phospholipids. Further additives may be mineral and vegetable oils. it is possible to use colorants such as inorganic pigments, for example Iron oxide, titanium oxide and Prussian blue, and organic colorants such as alizarin colorants, azo colorants and metal phthalocyanine colorants, and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
The formulations contain generally between 9.1 and 95 percent by weight of active Ingredient, preferably between 0.5 and 90% by weight.
As such or in their formulations, the herbicides (A), and the safeners (C) can also be used as a mixture with other active agrochemical ingredients for controlling Unwanted vegetation, for example for controlling weeds or for controlling unwanted crop plants, finished formulations or tank mixes, for example, being possible.
Also possible are mixtures with other known active ingredients such as fungicides, insecticides, acancides, nemaiicides, bird antifeedanis,.plant nutrients and soil structure improvers, and likewise with additives and formulation auxiliaries customary In crop protection.
The herbicides (A), (8) and the safeners (C) can be used as such, in the form of their formulations or the use forms prepared therefrom by further dilution,; such as ready-louse solutions, suspensions, emulsions, powders, pastes and granules. Application is typically accomplished, for example, by watering, sprinkling, spraying, broadcasting.
The active ingredients can be deployed on the plants, plant parts, seed or area under cultivation (farmland), preferably on the seed or the green plants and plant parts, and optionally additionally on the farmland. One means of application is the co-deployment of the active ingredients in the form of tank-mixes, by mixing the optimally formulated concentrated formulations of the individual active ingredients together in the tank with water and deploying the spray liquor obtained. A co-formulation of the inventive combination of active ingredients (A), (B) and {0} has the advantage of easier applicability, because the amounts of the components can already be set in the optimal ratio with respect to one another. Moreover, the auxiliaries in the formulation can be optimized to one another.
For application, the formulations in commercial form are, if appropriate, diluted in a customary manner, for example in the case of weiaMe powders, emulsif'labie concentrates, dispersions and water-dispersible granules with water. Dust-type formulations, granules for sol! application or granules for scattering and sprayabie solutions are not normally diluted further with other inert substances prior to application.
Biological examples:
Ail trials whose results are shown were conduced in a greenhouse by the methodology specified below. The effect of the inventive herbioidai compositions was examined on the following harmful' plants 14 arid 21 days after application: Echinochloa crus-galli (ECHCG), ESeusine indica (ELEiN), Setaria viridis (SETVi), Amaranthus retrofiexus (AMARE), Chenopodidm album (CHEAL.), Kochia scoparla (KCHSC), Soianum nigrum (SOLNi), Avena fatua (AMEFA), Bromus sterilis (BRGST), iolsum muififiorum (LOIMU), Phelans minor (PHAM!), Poa annua (POAAM|> Galium aparine (GALAP), Matricaria inodora (MATIN) and Polygonum convolvulus (P0LCQ).
The harmful plant seeds were sown in pots (diameter 8 cm) with sandy loam soli and germinated under optimal conditions. The inventive herbicidal compositions or the active ingredients alone were applied post-emergence to the planted pots with a spray volume of 300 L/ha, The trial was conducted in a greenhouse under optimum growth: conditions, The herbioidai effects were assessed visually by comparison of untreated and treated plants. The percentages mean: 0% ~ no effects, 100% ~ the plants die off completely). The percentages are used to calculate interactions between individual treatments and combination treatments according to SIR. Colby, Weeds 15, pages 20 to 22 (1987).
The abbreviations mean; a.l. - active ingredient E° e expected value according to Colby (Ec =1 * B - A x S/100)
Diff; = difference (%} of measured value from expected value (%} (pleasured value minus expected value)
Assessment; - measured value E is greater than Ec: -> synergism (* cliff.) - measured value E equals Ec; -> additive effect - measured value E is smaller than Ec: ~> antagonisrnC diff.)
The results are shown in the tables below.
Table 1: Efficacy against ECHCG, 14 days after application
Table 2: Efficacy against ECHCG, 14 days after application
Table d; Efficacy against EL BN, 14 days after application
Table 4; Efficacy against ELEIN, 14 days after application
Table 5; Efficacy against KCHSC, 14 days after application
Table 6: Efficacy against DIGSA; 14 days after application
Table 7: Efficacy against ECHCG, 14 days after application________________________________________________
Table 8; Efficacy against ECHCG, 14 days after application··
Table 9: Efficacy against SETV1, 14 days after
application: __
Table 10: Efficacy against SETVI, 14 days after application
Table 11: Efficacy against CHEAL, 14 days after application
Table 12: Efficacy against KC-H.SG, 14 days after application
Table 13: Efficacy against KCHSC, 14 days after application
Table 14; Efficacy against Di-<3SA, 14 days after application:
Table 15: Efficacy against DiGSA, 14 days after application
Table 16; Efficacy against EGHCG, ‘4 daysaffer application ....................................
Table 17: Efficacy against ECHCC3, 14 days after application
Table 13: Efficacy against ELEiN, 14 days after application
Table 19: Efficacy against ELEiN, 14 days after application
Table 20: Efficacy against ELEftT 14 days after application
Table 21: Efficacy against ELEJN, 14 days after application
Table 22: Efficacy against 'SETVi, 14 days after application
Table 23; Efficacy against SETVI, 14 days after application
Table 24; Efficacy against AMARE, 14 days after application
Table 25: Efficacy against GHEAL, 14 days after application-
Table 26; Efficacy against D1GSA, 14 days after application
Table 27: Efficacy against ECHCG, 1.4 days aftei application.
Table 28: Efficacy against ECHCG, 14 days after application
Table 29: Efficacy against ECHCG, 14 days after application
Table 30: Efficacy against ELEIM, 14 days after application
Table 31: Efficacy against ELEibl, 14 days after application
Table 32: Efficacy against ECHCG, 14 days after application
Table 33: Efficacy against ECHCG, 14 days after application
Table 34; Efficacy against DIGSA, 14 days after application
Table 35; Efficacy against ELE1N, 14 days after application
Table 36; Efficacy against ELE1N, 14 days after application
Table 37: Efficacy against SETVi, 14 days after application
Table 38: Efficacy against SETVI, 14 days after application
Table 39: Efficacy against AMARE, 14 days after application
Table 40: Efficacy against CHEAL, 14 days after application
Table 4f: Efficacy against HiCWSCft 14 days after application
Table 42: Efficacy against D1GSA, 14 days after application:
Table 43; Efficacy against AMARE, 14 days after application
Table 44: Efficacy against AiVlARE, 14 days after application
Table 45: Efficacy against CHEAL, 14 days after application
Table 46: Efficacy against CHEAL; 14 days after application
Table 47: Efficacy against CHEAL, 14 days after application
Tab!® 48: Efficacy against CHEAP, 14 days after application
Table 49: Efficacy against KGHSC, 14 days after application:
Table 50: Efficacy against KGHSC, 14 days after application
Table 51: Efficacy against SOLNi, 14 days after application
Table 52: Efficacy against SOLNi, 14 days after application
Table 58: Efficacy against SOLNi, 14 days after application'
Table 54; Efficacy against SOLNi, 14 days after application
Table oS. Efficacy against DiGSA, 14 days after application
Table 58: Efficacy against DiGSA, 14 days after application
Table 57: Efficacy against ECHCG, 14 days after application
Table 58: Efficacy against EGHCG, 14 days after application
Table 59: Efficacy against ECHCG, 14 days after application
Table 80: Efficacy against ECHCG, 14 days after application
Table 81: Efficacy against ELEIN, 14 days after application
Table 62; Efficacy against ELEUT 14 days suer application
Table 63; Efficacy against ELE1N, 14 days after application
Table 64; Efficacy against ELEIN, 14 days after application
?able 65; Efficacy against 5ETVI 14 days after application
Table 66: Efficacy against SETVf, 14 days after application
Table· 67: Efficacy against SETVI, 14 days after application
Table 88.: Efficacy against AMARE, 14 days after application
Table 68: Efficacy against SGL.isii. 14 days after sppiicalion
Table 70: Efficacy against SOLN1, 14 days after application
Table 71: Efficacy against S0L.NI, 14 days after application
Table 72: Efficacy against SOLNl, 14 days after application
Table 73: Efficacy against OiGSA, 14 days after .application':
Table 74: Efficacy against DIGSA, 14 days after application ___
Table 75: Efficacy against ECHCG, 14 cays after application
Tabie 76; Efficacy against ECHCG, 14 days after application
Table 77; Efficacy against ELEiN, 14 days after application
Table 78; Efficacy against ELEIN, 14 days after application
Table 79; Efficacy against SETVI, 14 clays after application
Table 80; Efficacy against SETVI, 1.4 days after application
Table 81: Efficacy against AWARE, 14 days after application
Table 82: Efficacy against AMARE, 14 days after application
'Table 63: Efficacy against CHEAL, 14 days after application
Table 84; Efficacy against CHEAL, 14 days after application
Table 85: Efficacy against CHEAL, 14 days after application
Table 88; Efficacy against KCHSC, 14 days after application
Table 87: Efficacy against KCMSC, 14 days after application
Table 88: Efficacy against KCHSC, 14 days after application
Table 89: Efficacy against SOLNI, 14 days alter application
Table 90; Efficacy against SOLNi, 14 days after application
Table 91: Efficacy against SOLNi, 14 days after application
Table 92: Efficacy against SOLNi, 14 days after application
Table 93: Efficacy against ECHCG, 21 days after application
Table 94: Efficacy against EGHCG, 21 days after application
Table 96: Efficacy against ECHCG, 21 days after application
] j i
I
I
Table 96: Efficacy against ELEiN, 21 days after application
Table 9?: Efficacy against EL.E1K 21 clays after application
Table 98: Efficacy against SETVi, 2.1 days after application
Table 99: Efficacy against SETVi, 21 days after application:
Table 100: Efficacy against CHEAL, 21 days after application
Table 101: Efficacy against KCHSG, 21 days after application
Table 102: Efficacy against KCHSG, 21 days after application
Table 103; Efficacy against ECHCG, 21 days after application:
Table 104: Efficacy against EGHCG, 21 days after ago;teat;on
Table 105: Efficacy against ELE-IN, 21 days after application
Table 106; Efficacy against ELEIN, 21 days alter application
Table 107: Efficacy against SETVi, 21 days after application
Table 108: Efficacy against SETVi·, 21 days after application
Table 100: Efficacy against KCHSC, 21 days after application
Table 110: Efficacy against AM ARE, 21 days after application
'Table 111: Efficacy against AiVIAR.E. 21 days a Her application
Table 112: Efficacy against CHEAL., 21 days after application
Table 113: Efficacy against CHEAL, 21 days after application
Table 114; Efficacy against SOLNI, 21 days after application
Table 115; Efficacy against OIGSA, 21 days after application
Table 118; Efficacy against DiGSA, 21 days after application
Table 117: Efficacy against ECHCG, 21 days after application
Table 118: Efficacy against SETVL 21 clays after application
Table 1 T9: Efficacy against SETVl, 21 days after application
Table 120: Efficacy against CHEAL, 21 days after application
Table 121: Efficacy against D1GSA, 21 days after application
Table 122: Efficacy against ECHCG, 21 days after-application
Table 123: Efficacy against ECHCG, 21 days after.application
Table 124: Efficacy against ECHCG, 21 days after application
Table 125: Efficacy against ECHCG, 21 days after application
Table 126: Efficacy against ELElN, 21 days after application
Table 127: Efficacy against ELElN, 21 days after application
Table 128: Efficacy against SETVI, 21 days after application
Table 129: Efficacy against. SETVI, 21 days after application
Table 130: Efficacy against AMARE, 21 clays after application
Table 131: Efficacy against AMARE, 21 days after application
Table 132: Efficacy against B0LN1, 21 days after application
Table 133: Efficacy against EQHCG, 21 days after application
Table 134: Efficacy against ELEIN, 21 days after application
Table 135: Efficacy against ELEIN, 21 days after application
Table 136; Efficacy against SET VI, 2.1 days after application
Table 137: Efficacy against KCHSC, 21 days after application
Table 138: Efficacy against KCHSC, 21 days after-application
Table 139: Efficacy against SOtffii, 21 days after application
Table 1.40: Efficacy against DiGSA, 21 days after application
Table 141: Efficacy against ELEIN, 21 days after application
Table 142: Efficacy against ELGIN, 21 days after application
Table 143: Efficacy against SETVi* 21 days after application
Table 144: Efficacy against SETVi, 21 clays after application
Table 145: Efficacy against AMAR1E, 21 days after application
Tabie 146: Efficacy against ELESN, 21 days after application
Table 147: Efficacy against CHEAL, 21 days after application
Table 148: Efficacy against KCHSC, 21 days after application
Tabie 149; Efficacy against KCHSC, 21 clays after application
Table 160: Efficacy against DIGSA, 21 days after application
Table 151: Efficacy against SET VI, 21 days after application
Table 152: Efficacy against SETVI, 21 days after application
Table 153: Efficacy against CHEAP, 21 days after application
Table 154: Efficacy against CHEAL, 21 days after application
Table 155: Efficacy against CHEAL, 21 days after application
Table 156; Efficacy against CHEAL, 21 days after application
Table 157; Efficacy against KCHSC, 21 days after application
Table 158: Efficacy against SOl.Nl, 21 days after application
Table 159: Efficacy against SOLN!, 21 days after application
Table 160: Efficacy against SOLNi, 21 days after application
Table 161: Efficacy against SOLNi, 21 days after application
Table 162: Efficacy against DIGSA, 21 days after application
Table 163; Efficacy against DIGSA, 21 days after application
Table 164; Efficacy against ECHCG, 21 days after application
Table 165: Efficacy against ECHCG, 21 days after application
Table 166: Efficacy against ECHCG, 21 days after application
Table 167: Efficacy against ECHCG, 21 days after application
Table 168: Efficacy against ELEiN, 21 days after application
Table 169.: Efficacy against ELEIN, 21 days after application
Table-170: Efficacy against ELEIN, 21 days after application
Table 171: Efficacy against ELEiN, 21 days after application
Table 172: Efficacy against SETVI, 21 days after application
Table 173: Efficacy against SETVI, 21 days after application
Table 174: Efficacy against SET'vi, 21 days after application
Table 175: Efficacy against AMARE, 21 days after application
Table 176: Efficacy against AMARE, 21 days after application
Table 177: Efficacy against AMARE, 21 days after applicatidn
Table 178: .Efficacy against SOLNJ, 21 days after application
Table 179: Efficacy against SQl.NI, 21 days after application
Table 160: Efficacy against SOiNI, 21 clays after application
Table 181: Efficacy against SOLNI, 21 days after application
Table 182: Efficacy against ECHCG, 21 days after application
Table 183: Efficacy against ECHCG, 21 days after application
Table 184: Efficacy against ECHOS, 21 days after application
Table 185: Efficacy against EL.EIN, 21 days after application
Table 1.86: Efficacy against ELEIN, 21 days after application
Table 187: Efficacy against ELEIN, 21 days after application
[ ci:j:iΘ ! BB . LCliCOUV SCSinSl S \/i. I GOVS ri", ί oT CCD: ί'·.,ηΐΊΟ: i _____:____—
Table Ί89: Efficacy aqainsf SETVS, 21 days after aopiicaiion ___———
Table 190; EffiOaev against SETVI, ,21 davs after aPpHeattera __——-—
Table 191: Efficacy against AWARE, 21 days after application ___________—f
Table 192: Efficacy acsainsi AMARE, 21 days after application ___________—,,
Table 193: Efficacy against CHEAL, 21 days after application, ____ Λ ~ .-.a f rv______ r„, ~.c _ : .0 1 r r^.cx; ^ , . ΤΟ/ Ί
Table 1:04: Efficacy against CHEAL, 21 days after application _________ λ :.. ______ί' i. x*\~ ~ ,.j: :.. * 0,η I τλ/Τ
Table 195: Efficacy againsl KCHSC. 21 days after application
Table 196: Efficacy against KCHSC, 21 days after application
Table 197: Efficacy against KCHSC, 21 days after application
Table 198: Efficacy against KCHSC, 21 days after application:
Table 199: Efficacy against SOLNI, 21 days after application
Table 200: Efficacy against SOLNI, 21 days after application:: ______________i
Tabie 201: Efficacy against AVEFA. 14 days after application _____________ _________
Table. 202: Efficacy against AVEFA,. 14 days after application
Table 203: Efficacy against BROST, 14 days after application
Table 204: Efficacy against BRO.ST, 14 days after application
Table 205: Efficacy against BROST, 14 days after application
Table 206: Efficacy against BROST, 14 days after application
Table 207: Efficacy against LQLMU, 14 days after application
Table 208: Efficacy against PHAM!, 14 days after application
Table 209: Efficacy against PHAlvil, 14 cays after application
Table .210: Efficacy against PHAMi 14 days after application
Table 211: Efficacy against PHAMi, 14 days after application
Table 212: Efficacy against POAAN, 14 days after application
Table 213: Efficacy against POAAN, 14 days after application
Table 214: Efficacy against POAAN, 14 days after application
Table 215: Efficacy against GALAP, 14 days after application
Table 216; Efficacy against MATIN, 14 days after application
Table 217: Efficacy against PQLCO, 14 days after application:
Table 218: Efficacy against POLCO, 14 days after application
Table 219: Efficacy against POLGO, 14 days after application
Table 220: Efficacy against POLGO, 14 days after application
Table 221: Efficacy against AVEFA, 14 days after application
Table 222: Efficacy against PHAMi, 14 days after application
Table 223: Efficacy against PKAMb 14 clays after application _ ________________________
Table 224; Efficacy against. PHAiVH, 14 days after application .-. _
Table 225: Efficacy against POAAN, 14 clays after·application ................
Table 226; Efficacy against POMN, 14 days after application
Table 227: Efficacy against POAAN, 14 days after application
Table 22B; Efficacy against OALAP, 14 days after appiication
Table 229: Efficacy against GALAP, 14 days after application;
Table 230: Efficacy-against MATIN, 14 days eftsr application
Table 231: Efficacy against MATIN, 14 days after application
Table 232: Efficacy against MATIN, 14 days after application
Table 233: Efficacy against BROST, 14 days after application
Table 234: Efficacy against LOLMU,. 14 days -after application
Table 235: Efficacy against LOLMU, 14 days after application
Table 238: Efficacy against LOLMU, 14 days after application
Table 237: Efficacy against PHAML 14 days after application:
Table 238: Efficacy against PD.AAN, 14 days after application
Table 239; Efficacy against POAAN, 14 days after application
Table 240; Efficacy against GALAP, 14 days after application
Table 241; Efficacy against POLCO, 14 days after application
Table 242: Efficacy against POLCO, 14 days after application
Table 243: Efficacy against BROS!., 14 days after application
Table 244; Efficacy against BROST, 14 days after application
Table 245: Efficacy against LOLSviU, 14 days after application
Table 246: Efficacy against LGLMU, 14 days after application
Table 247: Efficacy against LOLMU, 14 days after application
Table 248: Efficacy against PH AMI, 14 days after application
Table 249: Efficacy against PHAMI, 14 days after application
Table 250; Efficacy against PHAMI, 14 days after application
Table 251: Efficacy against POAAN, 14 days after application
Table 252: Efficacy against PQAAN, 14 days after application _____ _
Table 253: Efficacy against MATIN, 14 days after application
Table 254: Efficacy against MATIN, 14 days after application____ __
Table 255: Efficacy against MATIN, 14 days after application
Table 258: Efficacy against POLCQ, 14 days after application
Table 257: Efficacy against POLCO, 14 days after application_________
Table 258: Efficacy against POLCO, 14 cays after application
Table 259: Efficacy against POLCO, 14 days after application
Table 260: Efficacy against AVEFA, 14 days after application
Table 261; Efficacy against AVEFA, 14 days after application _ _____
Table 262: Efficacy against AVEFA, 14 days after application
Table 263: Efficacy against AVEFA, 14 days after application __
Table 264: Efficacy against BROST, 14 days after application __ _
Table 265; Efficacy against BEOST, 14 days after application
Table 266: Efficacy against LOLMU, 14 days after application
Table 267; Efficacy against PH AMI, 14 days after application ___
Table 288: Efficacy against PHAMi, 14 days after application
Table 269: Efficacy against PHAMi, 14 days after application _
Table 270: Efficacy against GALAP, 14 days after application
Table 271: Efficacy against GALAP, 14 days after application:
Table £72: Efficacy against GALAP, 14 days after application
Table 273: Efficacy against MATIN, 14 days after application
Table 274: Efficacy against MATIN, 14 days after application ___
Table 275: Efficacy against MATIN, 14 days after application
Table 276: Efficacy against MATIN, 14 days after application
Table 277: Efficacy against POLCO, 14 days -after application
Table 278: Efficacy against POLCO, 14 days after application
Table 279: Efficacy against AVEFA, 14 days· after application' _ ____ __
Table 280: Efficacy against AVEFA, 14 days after .application______ ______
Table 281: Efficacy against BROS!, 14 days after application _ _ _
Table 282: Efficacy against LOLM.U, 14 days -after application ____
Table 283: Efficacy against LOLMU, 14 days after application____
Table 284; Efficacy against PHAMS, 14 days after application
Table 285: Efficacy against PQAAM, 14 days after application
Table 266: Efficacy against POL.CO, 14 days after application
Table 287: Efficacy against AVEFA, 14 days after application ___
Table 288: Efficacy against AVEFA, 14 days after application
Table 289: Efficacy against BRQST, 14 days after application ___ _
Table 290: Efficacy against LOLMU, 14 days after application ____ _
Table 291: Efficacy against LOL.MU, 14 days after application _______
Table 292: Efficacy against LOLMU, 14 clays after application ...................................................................______
Table 293: Efficacy against PHAMI, 14 days after application
Table 294: Efficacy against PHAM, 14 days after application _______
Table 295; Efficacy against PHAM!, 14 days after application ________________________________________________________________
Table 296: Efficacy against PHAMI, 14 days after application
Table 297: Efficacy against POAAN, 14 days after application
Table 298; Efficacy against POAAN, 14 days after application _ ___^
Table 299; Efficacy against QALAP, 14 days after application- __
Table 300: Efficacy' against GALAP, 14 days after application _
Table 301: Efficacy against MATIN, 14 days after application _
Table 302; Efficacy against MATIN, 14 days after-application
Table 303; Efficacy against MATIN, 14 days after application __
Table 304; Efficacy against MATIN, 14 days Sifter application
Table 305: Efficacy against POLCO, 14 days after application_____
Table 306: Efficacy against POLCO, 14 days after application
Tab!» 307: Efficacy against POLCO, 14 days after application
Table 308: Efficacy against POLCO, 14 days after application
Table 309: Efficacy against AVEFA. 14 days after application
Table 310: Efficacy against AVEFA, 14 days after application ___
Table 311: Efficacy against AVEFA, 14 days after application
Table 312: Efficacy against AVEFA, 14 days after applicatien ........................................._................
Table 313; Efficacy against BROS!, 14 days after application____
Table- 314: Efficacy against 8ROST, 14 days after application
Table 315.: Efficacy against BROST, 14 days after application
Table 316: Efficacy against LOLMU, 14 days after application
Table 317; Efficacy against LOLMU, 14 days after application ______
Table 31S: Efficacy against PHAM), 14 days after application
Table 319: Efficacy against FHAMI, 14 days after application _ _
Table 320: Efficacy against FHAMI, 14 days after application ___
Table 321; Efficacy against POAAN, 14 days after application
Table 322: Efficacy against POAANi 14 days after application
Table 323: Efficacy against POAAN, 14 days after application
Table 324: Efficacy against POAAN, 14 days after application
Table 325: Efficacy against GALAP, 14 days after application
Table 326; Efficacy against GALAP. 14 days after application
Table 327: Efficacy against MATIN, 14 days after application
Table 328; Efficacy against MATIN, 1.4 days after application ___
Table 329; Efficacy-against MATIN, 14 days after-application ___
Table 330; Efficacy against POLCO, 14 days after 'sppii.caii.Gft' ______
Table 331; Efficacy against POLCO, 14 days after application_ _
Table 332; Efficacy against AVEFA, 14 days after application _
Table 333: Efficacy against LOLMU. 14 days after application _
Table 334; Efficacy against LOLMU, 14 days after application.
Table 335: Efficacy against POLCO, 14 days after application
Table 336: Efficacy against POLCO, 14 days after application__
Table 337; Efficacy against POLCO, 14 days after application
Table 338; Efficacy against POLCO, 14 days after application
Table 33S: Efficacy against AVEFA, 14 days after application _
Table 340: Efficacy against AVEFA, 14 days after application
Table 341; Efficacy against AVEFA, 14 days after application
Table 342; Efficacy against BROST, 14 days after application
Table 343; Efficacy against BROST, 14 days after application _ _ _
Table 344: Efficacy against BROST, 14 days after application:
Table 345: Efficacy against BROST, 14 days after application
Table 346; Efficacy against LOtivlU, 14 days after application _
j
Table 347: Efficacy against LOLMU, 14 days after application
Table 348; Efficacy against LOLMU, 14 days after application _
Table 349: Efficacy against LOUVIU, 14 days after application
Table 350: Efficacy against PHAMi, 14 days after application
Table 351: Efficacy against PHAMi, 14 days after application _ ____
Table 352: Efficacy against PHAM!, 14 days after application
Table 353: Efficacy against POAAN, 14 days after application
Table 354: Efficacy against POAAN, 14 clays after -application __
Table 355: Efficacy against POAAN, 14 days after application___
Table 356: Efficacy against GALAP, 14 clays after application _
Table 357: Efficacy against GALAP, 14 days after application
'Fable 358; Efficacy against GALAP, 14 days after application
Table 359: Efficacy against GALAP, 14 days after application .....
Table 360: Efficacy against PHAM), 14 days after application _
Table 351: Efficacy against PHAMI, 14 days after application
Table 362; Efficacy against GALAP, 14 days after application _
Table 363: Efficacy against GALAP. 14 days attar application·
Table 364: Efficacy against MATIN, 14 days after application
Table 366: Efficacy against MATIN, 14 days after application
Table 366: Efficacy against LOLiVIU, 21 days after application
Tabie 367: Efficacy against LOLMU, 21 days after application ____
Table 368: Efficacy against PHAMi, 21 days after application_ _____
Tabie 369: Efficacy against PHAM!, 21 days after application................................................... ................
Table 370: Efficacy against POAAN, 21 days after application _
Table 371: Efficacy against POAAN, 21 days after application _ _
Table 372: Efficacy against GALAP, 21 days after application: _
Table 373: Efficacy against GALAP, 21 days after application ___
Table 374; Efficacy against GALAP, 21 days after application _
"Fable 375: Efficacy against POLOO, 21 days after application _
Table 376: Efficacy against PGLCO, 21 days after application
Table 377: Efficacy against AV'EFA, 31 days after application
Table 378: Efficacy against AVEFA, 21 days after application ______
Table 379; Efficacy against BROST, 21 days after application
Table 380: Efficacy against BROST, 21 days after application_
Table 381: Efficacy against BROST, 21 days after application __
Table 332; Efficacy against LOLMU, 21 days after application__
Table 383; Efficacy against PHAMi, 21 days after application _
Table 384: Efficacy against FHAMK 21 days after application
Table 385; Efficacy against PHAMI, 21 days after application
Table 388; Efficacy against POAAN, 21 days after application
Table 387; Efficacy against POLCO, 21 days after application: ____
Table 388: Efficacy against POLCO, 21 days after application
Table 389: Efficacy against AVEFA, 21 days after application ___________
Table 390; Efficacy against BROS!, 21 days after application _____
Table 391: Efficacy against BROS!, 21 days after application _
Table 392: Efficacy against GAL.AP, 21 days after application
Table 393; Efficacy against GALAP, 21 days after application
Table 394: Efficacy against MATIN, 21 days after application
Table 395; Efficacy against PGLCO, 21 days after application
Table 396; Efficacy against POLCO, 21 days after application________ _
Table 397; Efficacy against BROST, 21 days after application
Table 398: Efficacy against PHAlvll, 21 days after application
Table 399: Efficacy against PHAM!, 21 days after .application ___ _
Table 400: Efficacy against POAAN, 21 days after application
Table 401: Efficacy against POAAN, 21 days after application__
Table 402: Efficacy against GALAP, 21 days after application
Table 403; Efficacy against GALAP, 21 days after Application _ _
Table 404: Efficacy against MATIN, 21 days after application _ ____
Table 405; Efficacy against POLCO, 21 days after application
Table 406: Efficacy against POLCO, £1 days after application _ _ __________
Table 407; Efficacy against POLCO, 21 days after application _
Table 408: Efficacy against POLCO, 21 days after application_____
Table 409: Efficacy against AVEFA, 21 days after application
Table 410: Efficacy against AVEFA, 21 days after application_____
Table 411: Efficacy against AVEFA, 21 days after application
Table 412: Efficacy against AVEFA. 21 days after application __
Table 413: Efficacy against BROST, 21 days after application- _____
Table 414: Efficacy against BROST, 21 days after application
Table 415: Efficacy against LOLMU, 21 days after application_ __
Table 416: Efficacy against PHAMT 21 days after application
Table 417: Efficacy against GALAP, 21 days after application __
Table 416: Efficacy against GALAP, 21 days after application _
Table 419: Efficacy against GALAp, 21 days after application
Table 420: Efficacy against MATIN, 21 days after application
Table 421; Efficacy against MATIN, 21 days after application
Table 422; Efficacy against MATIN, 21 days after application
Table 423: Efficacy against MATIN, 21 days after application
Table 424; Efficacy against POLCO, 21 days after'application ___
Table 425; Efficacy against POLCO, 21 days after application
Table 426: Efficacy against AVEFA, 21. days after application
Table 427: Efficacy against AVEFA, 21 days after application _ _
Table 428: Efficacy against BRQST, 21 days after application
Table 429: Efficacy against LOLMU, 21 days after application
Table 430: Efficacy against PHAfvll, 21 days after application
Table 431: Efficacy against PHAM I, 21 days after application_ _____
Table 432: Efficacy against POAAN, 21 days after application _ _
Table 433: Efficacy against PQAAK 21 days after application
Table 434; Efficacy against MATIN, 21 days after application _____
Table 435: Efficacy against MATIN, 21 days after application ____ ___
Table 436; Efficacy against ΜΑΤίΗ 21 days after application _______________________
Table 437: Efficacy against MATIN, 2Tdays after application _____
Table 438: Efficacy against POLCO, 21 days after application ________________
Table 439: Efficacy against POLCO, 21 days after application ________________________
Table 440: Efficacy against AVEFA, 21 days after application
Table 441: Efficacy against AVEFA, 21 days after application ____
Table 442: Efficacy against BROS!, 21 clays after application
Table 443: Efficacy against BROST, 21 days after application ......
Table 444: Efficacy against LOLM'U, 21 days after application
Table 445; Efficacy against IGLMU, 21 days after application _ _
Table 446; Efficacy against PHAM!, 21 days after application____
Table 447: Efficacy against PHAM!, 21 days after application
Table 448: Efficacy against PHAMi, 21 days after application.................................................
Table 449; Efficacy againsfPHAMf, 21 days after application _____________________________
Table 450: Efficacy against POAAN, 21 days after application
Table 451: Efficacy against POAAN, 21 days after application _____^
Table 452: Efficacy against GALAP, 21 days after application
Table 453: Efficacy against MATIN, 21 days after application
Table 454; Efficacy against MATIN, 21 days after application
Table 455; Efficacy against MATIN, 21 days after application
Table 456: Efficacy against MATIN, 21 days after application
Table 457; Efficacy against FOLCO, 21 days after application
Table 458: Efficacy against POLCO, 21 days after.application
Table 459; Efficacy against AVEFA, 21 days after application _ _
Table 460; Efficacy against BROST, 21 days after application _ _
Table 461; Efficacy against BROS!, 21 days after application
Table 462: Efficacy against PHAMI, 21 days after application
Table 463: Efficacy against PHAMf, 21 days after application
Table 464; Efficacy against POAAN, 21 days after application
Table 465; Efficacy against POAAN, 21 days after application
Table 466: Efficacy against POAAN, 21 days after application
Table 467: Efficacy against GALAP, 21 days after application
Table 456; Efficacy against MATIN, 21 days after application
Table 469: Efficacy against POLGO, 21 days after application
Table 470; Efficacy against 8ROST, 21 days after application
Table 471; Efficacy against POLCO, 21 days -after application:
Table 472: Efficacy against POLCO, .21 days after application
Table 473; Efficacy against POLCO, 21 days after application
Table 474: Efficacy against POLCO, 21 days after application..................................................................................
Table 475: Efficacy against AVEFA. 21 days after application
Table 476: Efficacy against AVEFA, 21 days after application
Table 477: Efficacy against AVEFA, 21 days after application
Table 478; Efficacy against BROS!, 21 days after application __
Table 47S; Efficacy against BROST, 21 days after application
Table 480: Efficacy against LOLMU, 21 days after application
Table 481; Efficacy against LOLMU, 21 days after application
Table 482; Efficacy against PHAM!, 21 days after application
Table 483; Efficacy against PHAMi, 21 days after application
Table 484; Efficacy against POAAN, 21 days after application
Table 485; Efficacy against GAlAP, 21 days after application ...................................................
Table 488; Efficacy against GALAP, 21 days after application
Table 487; Efficacy against GALAP, 21 days after application
Table 488; Efficacy against GALAP, 21 days after application
Table 489: Efficacy against fviATIN, 21 clays after application
Table 490: Efficacy against MATIN,, 21 days after application ________
Table 491: Efficacy against AVEFA, 21 days after application ___
Table 492; Efficacy against AVEFA, 21 days after application
Table 493: Efficacy against BROST, 21 days after application
Table 494: Efficacy against LOLMU. 21 days after application ________
Table 495; Efficacy against FRAMi, 21 days after appjioaiion
Table 496: Efficacy against PHAMI, 21 days after application
Table 497: Efficacy against POAAN, 21 days after application
Table 498: Efficacy against GALAP, 21 days after application
Throughout this specification and the claims which follow, unless the context requires otherwise, the word "comprise", and variations such as "comprises" or "comprising", will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
The reference in this specification to any prior publication (or information derived from it), or to any matter which is known, is not, and should not be taken as an acknowledgment or admission or any form of suggestion that that prior publication (or information derived from it) or known matter forms part of the common general knowledge in the field of endeavour to which this specification relates.

Claims (8)

  1. The claims defining the invention are as follows:
    1. A herbicidal composition comprising (A) the compound of formula (A1 -13) (component A) or a salt thereof
    and (B) one or more herbicides (component B) selected from the group consisting of amicarbazone, atrazine, bicyclopyrone, dicamba, dimethenamide-P, flufenacet, foramsulfuron, glufosinate-ammonium, glyphosate, halauxifen, isoxaflutole, mesosulfuron-methyl, mesotrione, metribuzin, nicosulfuron, pyroxasulfone, saflufenacil, and thiencarbazone-methyl.
  2. 2. The herbicidal composition as claimed in claim 1 further comprising one or more safeners (component C) selected from the group consisting of benoxacor, cloquintocet-mexyl, cyprosulfamide, dichlormid, fenclorim, fenchlorazole, furilazole, isoxadifen-ethyl, mefenpyr-diethyl, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane, and 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine.
  3. 3. A method of controlling harmful plants in crop plants, the method comprising applying a herbicidally active amount of a herbicidal composition as claimed in claim 1 or claim 2 to the harmful plants, crop plants, plant seeds or the area on which the plants grow.
  4. 4. The method as claimed in claim 3, wherein the crop plants are selected from the group consisting of sugar cane, corn, wheat, rye, barley, oats, rice, sorghum, cotton and soya.
  5. 5. The method as claimed in claim 3 or claim 4, wherein the crop plants have been genetically modified.
  6. 6. Use of a herbicidal composition as claimed in claim 1 or claim 2 for controlling harmful plants in crop plants.
  7. 7. Use as claimed in claim 6, wherein the crop plants are selected from the group consisting of sugar cane, corn, wheat, rye, barley, oats, rice, sorghum, cotton and soya.
  8. 8. Use as claimed in claim 6 or claim 7, wherein the crop plants have been genetically modified.
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Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW201715968A (en) * 2015-08-07 2017-05-16 拜耳作物科學公司 Herbicidal compositions comprising N-(tetrazole-5-yl)- or N-(1,3,4- oxadiazole-2-yl)aryl amides and an 3-isoxazolidinone derivative
GB201515141D0 (en) * 2015-08-26 2015-10-07 Syngenta Participations Ag Improvements in or relating to organic compounds
EA201891962A1 (en) * 2016-03-07 2019-04-30 Байер Кропсайенс Акциенгезельшафт HERBICIDE COMPOSITIONS CONTAINING ACTIVE CONNECTIONS FROM GRFD INHIBITORS GROUP, SAFENEROV AND TRIAZINS
CN107410320A (en) * 2017-06-09 2017-12-01 北京科发伟业农药技术中心 A kind of Herbicidal combinations containing pyribenzoxim
CN107410330A (en) * 2017-06-23 2017-12-01 北京科发伟业农药技术中心 Herbicidal combinations containing flufenacet and benzene flumetsulam
CN107410321A (en) * 2017-06-23 2017-12-01 北京科发伟业农药技术中心 A kind of Herbicidal combinations containing fluorochloridone and pyrithiobac-sodium
CN107232192A (en) * 2017-07-10 2017-10-10 安徽众邦生物工程有限公司 A kind of composition for Weed Control in Zero-tillage field weed
CN107372561A (en) * 2017-08-04 2017-11-24 北京科发伟业农药技术中心 A kind of grand Herbicidal combinations of sulphur of ketone containing thiophene
US11350631B2 (en) 2017-08-09 2022-06-07 Basf Se Herbicidal mixtures comprising l-glufosinate or its salt and at least one VLCFA inhibitor
CN107455382A (en) * 2017-08-11 2017-12-12 北京科发伟业农药技术中心 A kind of sulphur of ketone containing thiophene is grand and pyroxasulfone Herbicidal combinations
CN108013040A (en) * 2017-12-08 2018-05-11 北京科发伟业农药技术中心 The Herbicidal combinations of flumetsulam containing benzene and smart napropamide
EP3892618B1 (en) * 2019-01-14 2024-04-10 Qingdao KingAgroot Chemical Compound Co., Ltd. 4-pyridinyl formamide compound or derivative thereof, preparation method therefor, herbicidal composition and use thereof
WO2020172305A1 (en) 2019-02-19 2020-08-27 Gowan Company, L.L.C. Stable liquid compositions and methods of using the same
CN113258109B (en) * 2021-05-21 2022-07-15 吉林大学 Hybrid proton exchange membrane based on polyacid/piperidine aryl copolymer and preparation method thereof
WO2024041926A1 (en) 2022-08-25 2024-02-29 Bayer Aktiengesellschaft Herbicidal compositions
WO2024041925A1 (en) 2022-08-25 2024-02-29 Bayer Aktiengesellschaft Herbicidal compositions

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012126932A1 (en) * 2011-03-22 2012-09-27 Bayer Cropscience Ag N-(1,3,4-oxadiazol-2-yl)arylcarboxamides and use thereof as herbicides

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MA19269A1 (en) * 1980-09-16 1982-04-01 Lilly Co Eli IMPROVEMENT RELATING TO N-ARYLBENZAMIDE DERIVATIVES.
EP0094349B1 (en) 1982-05-07 1994-04-06 Ciba-Geigy Ag Use of quinoline derivatives for the protection of cultivated plants
WO1984002919A1 (en) 1983-01-17 1984-08-02 Monsanto Co Plasmids for transforming plant cells
BR8404834A (en) 1983-09-26 1985-08-13 Agrigenetics Res Ass METHOD TO GENETICALLY MODIFY A PLANT CELL
BR8600161A (en) 1985-01-18 1986-09-23 Plant Genetic Systems Nv CHEMICAL GENE, HYBRID, INTERMEDIATE PLASMIDIO VECTORS, PROCESS TO CONTROL INSECTS IN AGRICULTURE OR HORTICULTURE, INSECTICIDE COMPOSITION, PROCESS TO TRANSFORM PLANT CELLS TO EXPRESS A PLANTINIDE TOXIN, PRODUCED BY CULTURES, UNITED BY BACILLA
EP0221044B1 (en) 1985-10-25 1992-09-02 Monsanto Company Novel plant vectors
EP0242236B2 (en) 1986-03-11 1996-08-21 Plant Genetic Systems N.V. Plant cells resistant to glutamine synthetase inhibitors, made by genetic engineering
EP0305398B1 (en) 1986-05-01 1991-09-25 Honeywell Inc. Multiple integrated circuit interconnection arrangement
US5013659A (en) 1987-07-27 1991-05-07 E. I. Du Pont De Nemours And Company Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase
IL83348A (en) 1986-08-26 1995-12-08 Du Pont Nucleic acid fragment encoding herbicide resistant plant acetolactate synthase
DE3733017A1 (en) 1987-09-30 1989-04-13 Bayer Ag Stilbene synthase gene
CA2077896C (en) 1990-03-16 2008-02-19 Gregory A. Thompson Plant desaturases - compositions and uses
ATE212670T1 (en) 1990-06-18 2002-02-15 Monsanto Technology Llc INCREASED STARCH CONTENT IN PLANTS
DK0536330T3 (en) 1990-06-25 2002-04-22 Monsanto Technology Llc Glyphosate tolerant plants
DE4107396A1 (en) 1990-06-29 1992-01-02 Bayer Ag STYLE SYNTHASE GENES FROM VINEYARD
SE467358B (en) 1990-12-21 1992-07-06 Amylogene Hb GENETIC CHANGE OF POTATISE BEFORE EDUCATION OF AMYLOPECT TYPE STARCH
DE4104782B4 (en) 1991-02-13 2006-05-11 Bayer Cropscience Gmbh Novel plasmids containing DNA sequences that cause changes in carbohydrate concentration and carbohydrate composition in plants, as well as plants and plant cells containing these plasmids
US5591695A (en) * 1995-02-08 1997-01-07 American Cyanamid Co. Herbicidal [1,3,4]oxadiazoles and thiadiazoles
AU7527898A (en) 1997-04-23 1998-11-13 Novartis Ag Herbicide
DE19742951A1 (en) 1997-09-29 1999-04-15 Hoechst Schering Agrevo Gmbh Acylsulfamoylbenzoic acid amides, crop protection agents containing them and process for their preparation
PL207109B1 (en) 2001-01-31 2010-11-30 Bayer Cropscience Ag Herbicide-safener combination based on isoxozoline carboxylate safeners
DE10145019A1 (en) 2001-09-13 2003-04-03 Bayer Cropscience Gmbh Combinations of herbicides and safeners
TW200305368A (en) * 2001-12-19 2003-11-01 Basf Ag Herbicidal mixtures based on 7-pyrazolylbenzoxazoles
UA78071C2 (en) 2002-08-07 2007-02-15 Kumiai Chemical Industry Co Herbicidal composition
US8551918B2 (en) 2003-12-04 2013-10-08 Syngenta Crop Protection Llc Herbicidal composition
ES2297709T3 (en) 2004-04-30 2008-05-01 Syngenta Participations Ag HERBICIDE COMPOSITION.
CA2690072A1 (en) * 2007-06-12 2008-12-18 Eike Hupe Herbicidally active composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012126932A1 (en) * 2011-03-22 2012-09-27 Bayer Cropscience Ag N-(1,3,4-oxadiazol-2-yl)arylcarboxamides and use thereof as herbicides

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