AU2014295774B2

AU2014295774B2 - Phosphate magnesium zinc fertilizer

Info

Publication number: AU2014295774B2
Application number: AU2014295774A
Authority: AU
Inventors: Mark Goodwin; Kerry Green
Original assignee: Compass Minerals Manitoba Inc
Current assignee: Compass Minerals Manitoba Inc
Priority date: 2013-07-23
Filing date: 2014-07-22
Publication date: 2018-05-10
Anticipated expiration: 2034-07-22
Also published as: CL2016000176A1; WO2015010203A1; CA2919270A1; AU2014295774A1; DOP2016000026A; CA2919270C; EP3024805A1; CN105473534A; US9365462B2; US20150027042A1; EP3024805A4; AR097035A1

Abstract

A fertilizer product for delivering starter fertilizer to crops in soils as an alternative to traditional phosphorus applications to enhance rapid early plant development. Specifically, the fertilizer product comprises a synergistic mixture of: from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P

Description

Title

Phosphate magnesium zinc fertilizer

International Patent Classification(s)

C05G 1/00 (2006.01) C05D 9/00 (2006.01)

C05B 7/00 (2006.01) C05G 5/00 (2006.01)

C05D5/00 (2006.01)

Application No: 2014295774 (22) Date of Filing: 2014.07.22

WIPONo: WO15/010203

Priority Data

Number (32) Date (33) Country

61/857,336 2013.07.23 US

Publication Date: 2015.01.29

Accepted Journal Date: 2018.05.10

Applicant(s)

Compass Minerals Manitoba Inc.

Inventor(s)

Goodwin, Mark;Green, Kerry

Agent / Attorney

IP Gateway Patent and Trade Mark Attorneys Pty Ltd, PO Box 1321, SPRINGWOOD, QLD, 4127, AU

Related Art

CN 1188754 A WO 2013053031 A1 wo 2015/010203 Al IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIN (12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization

International Bureau (43) International Publication Date 29 January 2015 (29.01.2015)

(10) International Publication Number

WIPOIPCT

WO 2015/010203 Al (51) International Patent Classification:

C05G1/00 (2006.01) C05D 9/00 (2006.01)

C05B 7/00 (2006.01) C05G 5/00 (2006.01)

C05D 5/00 (2006.01) (21) International Application Number:

PCT/CA2014/050690 (22) International Filing Date:

July 2014 (22.07.2014) (25) Filing Language: English (26) Publication Language: English (30) Priority Data:

61/857,336 23 July 2013 (23.07.2013) US (71) Applicant: COMPASS MINERALS MANITOBA INC.

[CA/CA]; 800 One Research Road, Winnipeg, Manitoba R3T 6E3 (CA).

(72) Inventors: GOODWIN, Mark; 6 Stonehaven Close, Winnipeg, Manitoba R3R 3G3 (CA). GREEN, Kerry; c/o 800 One Research Road, Winnipeg, Manitoba R3T 6E3 (CA).

(74) Agent: ADE & COMPANY INC.; 2157 Henderson Highway, Winnipeg, Manitoba R2G 1P9 (CA).

(81) Designated States (unless otherwise indicated, for every kind of national protection available)·. AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR,

KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME,

MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW.

(84) Designated States (unless otherwise indicated, for every kind of regional protection available)·. ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, ΓΓ, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG).

Published:

— with international search report (Art. 21(3)) (54) Title: PHOSPHATE MAGNESIUM ZINC FERTILIZER

PHOSPHATE MAGNESIUM ZINC FERTILIZER

Ratios of P2O5 to Zn to Mg and plant growth (grams of corn per trt)

Figure 1

H P20S:Zn:MgRatio 11.1:1:0)

P2O5:Zn:Mg Ratio (2.8:2.8:1} ii»P2O5:Zn:Mg Ratio (2.4:1.4:1}

8UTC (57) Abstract: A fertilizer product for delivering starter fertilizer to crops in soils as an alternative to traditional phosphorus applica tions to enhance rapid early plant development. Specifically, the fertilizer product comprises a synergistic mixture of: from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P₂O ₅: from about 1.4 to about 2.8 parts Zn.

2014295774 05 Apr 2018

TITLE: PHOSPHATE MAGNESIUM ZINC FERTILIZER

CROSS REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to provisional applications

U.S. Serial No. 61/857,336, fried July 23, 2013, herein incorporated by reference in its entirety.

FIELD

The present disclosure relates generally to the field of fertilizers.

BACKGROUND

The reference to prior art in this specification is not and should not be taken as an acknowledgment or any form of suggestion that the referenced prior art forms part of the common general knowledge in Australia or in any other country.

Starter fertilizer is defined as the small quantity of fertilizer nutrients applied in close proximity to the seed at planting by growers of crops. In some instances, the practice entails placing the fertilizer into the seed row directly with the seed and this is often referred to as a pop up fertilizer. Growers of crops use starter fertilizers to enhance the development of emerging seedlings by supplying essential nutrients in accessible locations near the roots. This is especially important when crops are planted into cold, wet soils and/or when seeding into minimum tillage situations.

Phosphorus is routinely used in starter fertilizers/pop up applications. However, phosphorus is immobile in the soil and subsequently small seedling roots have difficulty obtaining the necessary amounts for rapid growth. For these reasons, phosphorus is routinely used as a starter/pop up fertilizer, even when overall phosphorus levels in a field may be adequate or high. For example, recommendations call for 35 kg P2O5 per hectare. However, phosphate in the soil can interact with other nutrients and immobilize them. Furthermore, there are obvious environmental concerns regarding high soil phosphate levels leaching into the environment as well as potential toxicity to seeds and plants. As one skilled in the art knows, P2O5 is an industry term, used to refer to a source of phosphate.

2014295774 05 Apr 2018

In certain situations, zinc also may be used by growers as a component of a starter fertilizer. Like phosphorus, zinc is highly immobile in soil. In situations where soil tests indicate that zinc levels are inadequate or marginal, growers will often use zinc as a component of a starter as well.

Magnesium is not commonly considered as a starter fertilizer and consequently is typically not used as a component of a starter fertilizer. Rather, it is usually added as a secondary nutrient or alternatively as a portion of a liming program (Dolomitic lime).

Work in western Iran and published in the Journal of Soil and Sediment (Khanlari, Z. V. and Jalali, M, 2011; The effect of sodium and magnesium on kinetics ofphosphorus release in some calcareous soils of western Iran, Soil and sediment: An International Journal 20:4, 411-431) looked at the impact of magnesium and calcium ions in irrigation water on the availability of phosphorus in soils in Iran. The researchers noted that irrigation water that had a high calcium level relative to magnesium was detrimental to levels of available soil-P relative to the reverse situation (high Mg and low Ca) which was friendly to soil status with respect to high available P. However, this paper focuses solely on irrigation water and does not teach or suggest the potential for inventing a product that manipulated magnesium levels as a component of a synergistic approach to phosphorus fertilizer dynamics.

Work at Brigham Young University in 2011 attempted to characterize the interaction between zinc and phosphorus fertilizer (but not magnesium) and this work found that when varying both P and Zn, increasing Zn levels stimulated P uptake when ample P was present in the soil - but this did not occur when P was deficient. (Brandt, A, B Hopkins, V Jolley, B Webb, B greenwood and J Buck, 2012: Phosphorus and zinc interactions and their relationships with other nutrients in maize grown in chelator buffered nutrient solution, J Plant Nutrition 35:1, 123-141).

Thus, it has been demonstrated that water with low magnesium and high calcium was detrimental to uptake of soil-available phosphate while low calcium, high magnesium water was not detrimental.

Furthermore, it was established that zinc stimulated phosphate uptake when phosphate was present in excess but not when phosphate was deficient.

2014295774 05 Apr 2018

DEFINITION

In the present description and claims, the term “comprising” shall be understood to have a broad meaning similar to the term “including” and will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps. This definition also applies to variations on the term “comprising” such as “comprise” and “comprises”.

SUMMARY

According to an aspect of the disclosure, there is provided a fertilizer product comprising: from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.

According to another aspect of the disclosure there is provided a combination fertilizer product selected from the group consisting of granular fertilizer, prilled fertilizers and seed; and applied to it, a homogenous powdered coating mix of magnesium, phosphorous and zinc. The x ix being from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.

As discussed herein, the fertilizer product may be (a) a fine powder mixture, (b) a granular mixture or (c) a liquid solution or suspension. In some embodiments, the fertilizer product is formulated for application to an agronomic product or carrier.

The agronomic carrier may be selected from the group consisting of: an inert carrier, a biodegradable carrier, a fertilizer product or prill, a soil amending product, and a seed.

In those embodiments in which the fertilizer product is a fine powder mixture or a granular mixture, the Mg, P2O5 and Zn may be mixed together in a dry mill grinder.

In those embodiments in which the fertilizer product is a fine mixture, the fine mixture may be ground to a fine mesh size of at least through a 100 mesh, U.S. standard sieve or at least through a 325 mesh, U.S. standard sieve and then applied directly to a dry agronomic product.

The fine powder mixture may be applied at from about 0.1% to about 2.5% (w/w) of the agronomic product. Alternatively, the mixture may be applied at from about 0.3% to about 2.5% (w/w) of the agronomic product, or from about 0.1% to about 2.0% (w/w) of

2014295774 05 Apr 2018 the agronomic product or from about 0.3% to about 2.0% (w/w) of the agronomic product or from about 0.3% to about 1.5% (w/w) of the agronomic product.

The zinc in the fertilizer product may be zinc oxide, zinc sulphate or a mixture thereof.

The P2O5, i.e., phosphate, in the fertilizer product may be sourced from low pH monoammonium phosphate, diammonium phosphate or rock phosphate, but is preferably from monoammonium phosphate., which has a pH for example of 4 - 5.9.

The magnesium in the fertilizer product may be magnesium carbonate, magnesium oxide, magnesium sulphate or mixtures thereof.

According to a further aspect of the disclosure, there is provided a method of preparing a coated agronomic product for use as a pop-up fertilizer comprising:

coating an agronomic carrier with from about 0.1% to about 2.5% (w/w) of a fine powder comprising from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.

Alternatively, the mixture may be applied at from about 0.3% to about 2.5% (w/w) of the agronomic product, or from about 0.1% to about 2.0% (w/w) of the agronomic product or from about 0.3% to about 2.0% (w/w) of the agronomic product or from about 0.3% to about 1.5% (w/w) of the agronomic product.

According to a further aspect of the disclosure, there is provided a method of promoting improved early growth in a plant comprising:

coating an agronomic product with from about 0.1% to about 2.5% (w/w) of a fine powder comprising from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn;

applying said coated agronomic product to a region of soil suitable for planting of a seed or seedling;

allowing said seed or seedling to grow; and recovering the plant, wherein said plant will have improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of the fine powder.

In another aspect there is provided a method of promoting improved growth in a plant comprising coating an agronomic product with from about 0.1% to about 2.5% (w/w) of a fertilizer product, said fertilizer product comprising from about 0.5 to about 1 part Mg:

2014295774 05 Apr 2018 from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn; applying said coated agronomic product to a region of soil suitable for planting; planting a seed or seedling in said soil; allowing said seed or seedling to grow; and harvesting the plant, wherein said plant has improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of the fertilizer product.

Alternatively, the mixture may be applied at from about 0.3% to about 2.5% (w/w) of the agronomic product, or from about 0.1% to about 2.0% (w/w) of the agronomic product or from about 0.3% to about 2.0% (w/w) of the agronomic product or from about

0.3% to about 1.5% (w/w) of the agronomic product.

In another aspect, there is disclosed a method of promoting improved early growth in a plant comprising applying an agronomic product to a seed row, wherein the agronomic product is coated with a fertilizer product comprising: from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn as a powder coating; planting a seed or seedling in the seed row; allowing said seed or seedling to grow into a plant; and harvesting the plant, wherein said plant has improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of the fertilizer product powder coating.

BRIEF DESCRIPTION OF THE DRAWINGS

Figure 1 shows the ratios of P2O5 to Zn to Mg and their effect on plant growth (grams of corn per treatment).

Figure 2 shows ratios of P2O5 to Zn to Mg and plant growth (grams of corn per seedling).

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the disclosure belongs. Although any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present disclosure, the preferred methods and materials are now described. All publications mentioned hereunder are incorporated herein by reference.

2014295774 05 Apr 2018

Described herein is a unique fertilizer product for delivering starter fertilizer to crops in soils as an alternative to traditional phosphorus applications to enhance rapid early plant development.

As discussed herein, the fertilizer product may be formulated as (a) a fine powder 5 mixture, (b) a granular mixture or (c) a liquid solution or suspension. In some embodiments, the fertilizer product is formulated for application to an agronomic product or carrier. For example, the fine powder mixture may be applied directly to a suitable agronomic product prior to applying the coated agronomic product to the soil. The granular mixture may be co-applied during seeding, as discussed herein. The liquid solution or suspension may be co-applied during seeding or the liquid solution or suspension may be applied either directly to a suitable agronomic carrier or in combination with a suitable binder or adhesive agent.

As discussed above, it has been demonstrated that calcium can impair utilization of phosphate in soil and it was also demonstrated that zinc can promote phosphate uptake when soil phosphate is high. However, in no case does the prior art refer to the benefits that would arise from using a combination of phosphorus/zinc/ magnesium as a starter fertilizer or as an in-seed-row pop up fertilizer. Specifically, nowhere in the literature has a specific synergy between P2O5, Zn and Mg been described. As described herein, when these elements are applied in concert at a specific range of ratios, for example, onto an agronomic carrier as a liquid solution or suspension or in finely divided particles, or coapplied in seed row during seeding, considerable improvement in growth is seen, particularly in the roots and shoots of the plants. As discussed below, the criticality of these ratios is clearly demonstrated in Figures 1 and 2.

That is, while not wishing to be bound to a particular theory or hypothesis, it is believed that phosphate can induce zinc deficiency and that supplying a plant with phosphate only would induce a zinc deficiency in that plant, thereby reducing growth rate and growth efficiency. Similarly, zinc can induce a phosphate deficiency. Furthermore, magnesium, zinc and phosphate are all required during early stages of growth and accordingly, supplying all three in synergistic amounts as done here promotes improved growth, as discussed herein.

The applicant has discovered that by manipulating and refining sources of three

2014295774 05 Apr 2018 elements (Mg, P and Zn) it is possible to attain substantial increases in early plant growth. This occurs only when the following three conditions are met: (a) they must be applied together in a homogeneous mix, (b) they must be applied in a specific range of ratios and (c) they must be applied as powders coated upon conventional granular or prilled fertilizer or alternatively onto seed.

Phosphate can induce zinc deficiency and that supplying a plant with phosphate only would induce a zinc deficiency in that plant, thereby reducing growth rate and growth efficiency. Similarly, zinc can induce a phosphate deficiency. Furthermore, magnesium, zinc and phosphate are all required during early stages of growth and accordingly, supplying all three in synergistic amounts promotes improved growth.

The combination of ingredients used herein when applied in the specific manner described — results in creation of conditions that maximize positive conditions in the soil at the same time as they synergize plant growth characteristics. While not wishing to be bound by theory, the mode of action likely begins with the powdered Mg creating a positive micro environment for the co-formulated P by counterbalancing any negative impacts from ambient Ca ions. This initial step sets up the three-part formula for enhanced uptake of all three elements. Once taken up, the Mg helps drive photosynthesis, and the Zn and the P drive root growth to a level of early plant growth that only typically would be seen using tens of pounds of early season phosphate fertilizers.

From about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.

The fertilizer product may be applied to the outer surface of an agronomic product. For example, the agronomic product may be any suitable coat-able agricultural agent, that is, anything applied to the soil, for example, an inert carrier, a biodegradable carrier, a fertilizer product, a fertilizer prill, a fertilizer granule, a soil amending product, or a seed.

Alternatively, as discussed above, the fertilizer product in the form of a granular mixture or of a liquid solution or suspension may be co-applied in the seed row during the seeding process.

In a preferred embodiment, the components of the fertilizer product are mixed 30 together in a dry mill grinder, is ground to a fine mesh size of at least through a 100 mesh

U.S. standard sieve (about 149 pm) or at least through a 325 mesh U.S. standard sieve (about 149 pm) and then applied directly to a dry agronomic product. It is of note that the

2014295774 05 Apr 2018 dry powder is applied directly to the agronomic product without the use of a binder solution or adhesive solution.

In some embodiments, the fine powder mixture is applied at from about 0.1% to about 2.5% (w/w) of the agronomic product. In alternative embodiments, the powder mixture is applied at from about 0.1% to about 2.0% or from about 0.1% to about 1.5% or from about 0.3% to about 2.5% or from about 0.3% to about 2.0% or from about 0.3% to about 1.5% (w/w) of the agronomic product.

In other embodiments, the fertilizer product is in the form of a liquid suspension or solution and is applied either directly to the agronomic product or is applied subsequent to or in combination with application of a binder solution using means known in the art.

The zinc may be in any suitable format, for example but by no means necessarily limited to, zinc oxide, zinc sulphate or a mixture thereof.

The magnesium may be in any suitable format, for example but by no means necessarily limited to, magnesium carbonate, magnesium oxide, magnesium sulphate or 15 mixtures thereof.

As will be readily apparent to one of skill in the art, the oxide, sulphate and carbonate forms of magnesium and the oxide and sulphate forms of zinc have different uptake rates and consequently by varying the ratios of the different minerals in the fertilizer product, the amount of the specific mineral available to the plants at specific times following seeding can be varied.

The P2O5 may be in any suitable format, for example, sourced from monoammonium phosphate, diammonium phosphate or rock phosphate. In other embodiments, the P2O5 may preferably be the low pH form of monoammonium phosphate.

In one embodiment of the disclosure, there is provided a fertilizer product 25 comprising:

From about 0.5 to about 1 parts magnesium carbonate, magnesium oxide, magnesium sulphate or mixtures thereof;

From about 2.4 to about 2.8 parts monoammonium phosphate; and

From about 1.4 to about 2.8 parts zinc oxide, zinc sulphate or a mixture thereof.

According to another aspect of the disclosure, there is provided a method of preparing a coated agronomic carrier for use as a starter fertilizer comprising:

coating an agronomic carrier with from about 0.1% to about 2.5% (w/w) of a

2014295774 05 Apr 2018 fertilizer product comprising from about 0.5 to about 1 part Mg: from about 2.4 to about

2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.

In a preferred embodiment, the mixture is mixed together in a dry mill grinder and is ground to a fine mesh size of at least through a 100 mesh U.S. standard sieve (about 149 pm) or at least through a 325 mesh U.S. standard sieve (about 44 pm) and then applied directly to a dry agronomic carrier, as discussed above.

According to a further aspect of the disclosure, there is provided a method of promoting improved early growth in a plant comprising coating an agronomic product with from about 0.1% to about 2.5% (w/w) of a fertilizer product comprising from about 0.5% to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn; applying said coated agronomic product to a region of soil suitable for planting of a seed or seedling; allowing said seed or seedling to grow; and recovering the plant, wherein said plant will have improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of the fine powder. For example, the plant will show improved root structure and architecture, for example, more root density, compared to the control plant.

In alternative embodiments, the powder mixture is applied at from about 0.1% to about 2.0% or from about 0.1% to about 1.5% or from about 0.3% to about 2.5% or from about 0.3% to about 2.0% or from about 0.3% to about 1.5% (w/w) of the agronomic product.

It is of note that the fertilizer product or coated agronomic product may be coadministered to the soil with planting of the seed or seedling and that while these may be stated as separate steps herein for ease of comprehension, co-administration is within the scope of the disclosure. Alternatively, the agronomic product may be a seed coated with the fertilizer product which is planted. As will be appreciated by one of skill in the art, in this case, the seed and the fertilizer product are of course co-administered.

In another aspect of the disclosure, there is provided a method of improving early growth of a plant comprising providing a plant, seedling or seed a fertilizer product comprising:

from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn; and growing the plant under suitable growth conditions.

As discussed in the examples, a plant provided the fertilizer product will show

2014295774 05 Apr 2018 improved growth compared to a plant of similar type and age, grown under similar conditions except for the presence of the fertilizer product. For example, the treated plant may have at least a more extensive root structure, greater growth rate and greater plant weight compared to the untreated control plant.

The plant or seedling may be provided the fertilizer product by being grown from a seed coated with the fertilizer product.

EXAMPLES

The disclosure will now be described by way of examples; however, the disclosure is not necessarily limited by the examples.

Figures 1 and 2 describes two ratio experiments that shows the impact on early corn growth when the mixture comprising various ratios of the three elements as discussed herein and as shown in the figures are applied in a fashion wherein they are of a particle size as described above and applied as a coating onto urea prills.

In the experiments, the coating was applied to a urea blend to a level of 0.8% w/w and then broadcast into growth chamber trays. There were three replicates grown under greenhouse lights.

As can be seen in Figure 1, a mixture of 1 part P2O5: 1 part zinc: 1 part magnesium produced more shoot weight (3.7 g vs 3.1 g) and slightly more root weight (6.8 vs. 6.6) than an untreated control grown under similar conditions. However, mixtures of 2.8 parts P2O5: 2.8 parts zinc: 1 part magnesium and 2.4 parts P2O5: 1.4 parts zinc: 1 part magnesium both produced more substantial increases in root weight (7.9 g and 7.8 g) and shoot weight ( 4.5 g and 4.5 g) compared to the 1:1:1 ratio (6.8 g and 3.7 g) and especially the untreated control (6.6 g and 3.1 g).

As can be seen in Figure 2, different mixtures were tested in a manner similar to the experiment shown in Figure 1.

As can be seen, the mixture of 1 part P2O5: 1 part zinc but no magnesium (designated hereafter as 1:1:0) had the lowest growth (1.08 g).

Addition of 1 part magnesium (designated hereafter as 1:1:1) resulted in only a slight increase in growth (1.12 g).

Similarly, a mixture of 2 parts zinc, 1 part magnesium and no P2O5 (designated hereafter as 0:2:1) resulted in slightly improved growth (1.13 g) compared to the 1:1:0

2014295774 05 Apr 2018 ratio (1.08 g) and the 1:1:1 ratio (1.12 g).

Similarly, a mixture of 1 part P2O5: 4 parts zinc: 1 part magnesium (designated hereafter as 1:4:1) showed some improvement in growth (1.16 g) compared to the 1:1:1 mixture (1.12 g), the 0:2:1 mixture (1.13 g) and the 1:1:0 mixture (1.08 g).

However, surprisingly, a mixture of 2.8 parts P2O5: 2.8 parts zinc: 1 part magnesium (hereafter designated as 2.8:2.8:1) showed substantial growth improvement (1.40 g) over the other mixtures, including the 1:4:1 mixture.

While the preferred embodiments of the invention have been described above, it will be recognized and understood that various modifications may be made therein, and the appended claims are intended to cover all such modifications which may fall within the spirit and scope of the invention.

2014295774 05 Apr 2018

Claims

What is claimed:

1. A combination fertilizer product selected from the group consisting of:

granular fertilizer, prilled fertilizers and seed; and applied to it, a homogenous powdered coating mix of magnesium, phosphorous and zinc, said mix being from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.
2. The fertilizer product according to claim 1 wherein the fertilizer product is in a format selected from the group consisting of: a fine powder; a granular powder; a liquid solution; and a liquid suspension.
3. A method of preparing a coated agronomic product comprising:

coating an agronomic product with from about 0.1% to about 2.5% (w/w) of a fertilizer product comprising from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn.
4. A method of promoting improved growth in a plant comprising:

coating an agronomic product with from about 0.1% to about 2.5% (w/w) of a fertilizer product, said fertilizer product comprising from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn;

applying said coated agronomic product to a region of soil suitable for planting; planting a seed or seedling in said soil; allowing said seed or seedling to grow; and harvesting the plant, wherein said plant has improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of the fertilizer product.
5. The method according to claim 4 wherein the agronomic product is the seed that is planted in the soil.
6. The fertilizer product according to claim 1 or claim 2 or the method of any one of claims 3 to 5, wherein the fertilizer product is a fine powder that is ground to a fine mesh size of at

2014295774 05 Apr 2018 least through a 100 mesh, U.S. standard sieve (about 149 gm).
7. The fertilizer product according to claim 1 or claim 2 or the method of any one of claims 3 to 6, wherein the fertilizer product is a fine powder that is ground to a fine mesh size of at least through a 325 mesh, U.S. standard sieve (about 44 pm).
8. The method according to claim 6 or claim 7, wherein the fine powder is applied at from about 0.1% to about 2.0% (w/w) of the agronomic carrier.
9. The method according to claim 6 or claim 7 wherein the fine powder is applied at from about 0.3% to about 2.5% (w/w) of the agronomic carrier.
10. The method according to claim 6 or claim 7 wherein the fine powder is applied at from about 0.3% to about 2.0% (w/w) of the agronomic carrier.
11. The method according to claim 6 or claim 7 wherein the fine powder is applied at from about 0.3% to about 1.5% (w/w) of the agronomic carrier.
12. The method according to any one of claims 3 to 11, wherein the fine powder is applied directly to the agronomic carrier.
13. The method according to any one of claims 3 to 11, wherein the fine powder is applied as a dry powder directly to the agronomic carrier.
14. A method of promoting improved early growth in a plant comprising:

applying an agronomic product to a seed row, wherein the agronomic product is coated with a fertilizer product comprising: from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts Zn as a powder coating; planting a seed or seedling in the seed row;

allowing said seed or seedling to grow into a plant; and harvesting the plant, wherein said plant has improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of

2014295774 05 Apr 2018 the fertilizer product powder coating.
15. The method according to claim 14 wherein the fertilizer product is a fine powder that is ground to a fine mesh size of at least through a 100 mesh U.S. standard sieve (about 149 pm).
16. The method according to claim 14 wherein the fertilizer product is a fine powder that is ground to a fine mesh size of at least through a 325 mesh U.S. standard sieve (about 44 pm)
17. The method according to any one of claims 14 to 16 wherein the agronomic product is coated with from about 0.1% to about 2.0% (w/w) of the fertilizer product.
18. The method according to any one of claims 14 to 16 wherein the agronomic product is coated with from about 0.3% to about 2.0% (w/w) of the fertilizer product.
19. The method according to any one of claims 14 to 16 wherein the agronomic product is coated with from about 0.3% to about 1.5% (w/w) of the fertilizer product.
20. The method according to any one of claims 3 to 19, wherein the agronomic product is selected from the group consisting of: an inert carrier, a biodegradable carrier, a fertilizer product, a fertilizer prill, a seed and a soil amending product.
21. The fertilizer product according to claim 1 or claim 2 or the method of any one of claims 3 to 20, wherein the zinc is selected from the group consisting of zinc oxide, zinc sulphate and mixtures thereof.
22. The fertiliser product of claim 1 or claim 2 or the method according any one of claims 3 to 21, wherein the P2O5 is from low pH monoammonium phosphate.
23. The fertilizer product or the method of claim 22, wherein monoammonium phosphate has a pH of 4-5.9.

2014295774 05 Apr 2018
24. The fertilizer product according to claim 1 or claim 2, or the method of any one of claims 3 to 23, wherein the magnesium is selected from the group consisting of magnesium carbonate, magnesium oxide, magnesium sulphate and mixtures thereof.

25. A method of promoting improved early growth in a plant comprising:

applying a fertilizer product comprising from about 0.5 to about 1 part Mg: from about 2.4 to about 2.8 parts P2O5: from about 1.4 to about 2.8 parts zinc to a seed as a powder coating;

planting the coated seed in a seed row;

allowing said seed to grow into a plant;

and harvesting the plant, wherein said plant has improved growth characteristics over a comparable plant of similar variety grown under similar conditions but in the absence of the fertilizer product powder coating.

WO 2015/010203

PCT/CA2014/050690

PHOSPHATE MAGNESIUM ZINC FERTILIZER

Ratios of P2O5 to Zn to Mg and plant growth {grams of corn per trt)

Figure 1

B P20S:Zn:MgRatio (1.1:1:0) P2O5:Zn:Mg Ratio {2.8:2.8:1)

BP2O5:Zn:Mg Ratio {2.4:1.4:1) UTC

Ratios of P2O5 to Zn to Mg and plant growth (grams of corn per seedling)

1.00

1.40

1.35

1.30

1.25

1.20

1.15

1.05

P2G5:Zn:Mg ratio of 2.8:2.8:1 ---> P2O5:Z n:Mg ratio P2O5:Zn:Mg ratio P2O5_:Zn_:M_£ ratio ofoati of 1:1:1 \ . ... ....................\............................................................. \l $ \ Al 1.16 1.13 1.12 1.08

MG-tZN

MG +1702

ZN + 1702

140

Μβ + Ζη + 1702

Figure 2