AU2012201900A1 - Wood Impregnation - Google Patents

Abstract

-20 A process for treating dimensioned wood, dimensioned lumber or dimensioned timber ("timber") or veneer or particle based products or reconstituted wood products or other cellulosic materials ("product"), said process comprising or including impregnating the timber 5 or product to its core with a water based biocidal and/or other water based composition ("preservative") whereby the uptake is less than 80 IJm3. The process includes pressure variations.

Description

- 1 WOOD IMPREGNATION TECHNICAL FIELD The present invention relates to a process for preserving wood and cellulosic products (e.g. reliant on a biocidat active or biocidat actives to prevent fungal decay and/or 5 insect damage). BACKGROUND ART Impregnation procedures for wood, lumber or timber ("timber") has usually involved an impregnation procedure where the active agent, or a precursor of an active agent, is carried 10 in a liquid carrier. Sometimes the liquid carrier is water or water based. Sometimes the liquid carrier is an organic solvent or organic solvent based or maybe an inorganic solvent or inorganic solvent based. The well known LOSP procedure is a solvent based procedure which has the usual difficulties when handling solvent i.e. environmental consideration in respect of emissions, 15 flammability etc. The LOSP procedure however has an advantage in that it does not add moisture back into the timber. Excessive moisture uptake can affect dimensions of timber. Water based systems have been perceived as requiring a significant uptake of any water based treatment composition in order to provide the required penetration through to the core of the timber being treated. This has resulted in an increase of the moisture content of 20 the timber which has an effect on the dimensional stability of the timber and may also require that the timber be redried prior to use. The present invention recognises an advantage to be obtained from the reliance upon a water based treatment composition that nonetheless meets standards of active ingredient penetration but which nonetheless, owing to a low uptake of water, still provides a 25 dimensional stability of the timber preferably substantially at the dimensions prior to the treatment. It is recognised that a procedure with effective penetration can be obtained for a variety of different biocidally effective active agents having an antifungal or other biocidal role reliant surprisingly upon shorter exposure times (e.g. of a soak (pressure) step whether 30 above atmospheric or at atmospheric following an applied vacuum) uptakes of less than 80IJm 3 (and preferably less than 40IJm 3 ) to yield a moisture content of the just treated timber of less than 25% and preferably less than 20% (w of water / w of oven dried timber).

-2 The present invention recognises many different actives can be carried into the wood of timber or lumber without a need for resins and/or curing agents in the water or water based liquid carrier. The present invention recognises an option of including a wetting agent and/or surfactant. 5 Preferred actives include fungicides, insecticides and those to discourage termites. The present invention is derived from priority application NZ543124 filed 19 October 2005, the full contents of which is included by reference. In this specification where reference has been made to patent specifications, other external documents, or other sources of information, this is generally for the purposes of 10 providing a context for discussing the features of the invention. Unless specifically stated otherwise, reference to such external documents is not to be construed as an admission that such documents, or such sources of information, in any jurisdiction, are prior art, or form part of the common general knowledge in the art. 15 DISCLOSURE OF INVENTION In an aspect the invention is a process for treating dimensioned wood, dimensioned lumber or dimensioned timber ("timber") or veneer or particle based products or reconstituted wood products or other cellulosic materials ("product"), said process comprising or including impregnating the timber or product to its core using a pressure differential or pressure 20 differentials (i.e. vacuum/pressure and/or pressure/pressures) over one or more composition exposure time(s). wherein the composition to which the timber or product is exposed for uptake is a liquid based composition having a biocidal and/or preservative action; and wherein the liquid based composition is at least primarily water based but does 25 include (i) a glycol content or (ii) a glycol content and a surfactant or a wetting agent;, and wherein the liquid uptake is less than 80 IJm 3 . In another aspect the invention is a method of protecting wood, lumber or timber ("material"), which comprises or includes subjecting the material to be treated to at least a partial vacuum, and 30 exposing the material to an aqueous biocidal treatment composition at a pressure or pressures of at least about atmospheric pressure or above, (and optionally subjecting the material, when no longer to external exposure to such composition, to at least a partial vacuum); - 3 wherein the exposure is such that there is an uptake of less than 80 Urn 3 of the aqueous composition; and whereinthe aqueous composition, whilst the aqueous composition has a biocidal agent present and has (i) a glycol present or (ii) both a glycol and a wetting agent or surfactant 5 present, water accounts for at least 50% of the liquid content. In another aspect the invention is a process for treating dimensioned wood, dimensioned lumber or dimensioned timber ("timber") or veneer or particle based products or reconstituted wood products or other cellulosic materials("product"), said process comprising or including 10 impregnating the timber or product to its core using a pressure differential or pressure differentials (e.g.vacuum/pressure and/or pressure/pressure) over one or more composition exposure time(s), wherein the composition to which the timber or product is exposed for uptake is a liquid based composition having a biocidal and/or preservative action, 15 and wherein the liquid based composition is at least primarily water based but content does include one surfactant or at least one other liquid (i.e. includes (i) a glycol content or (ii) a glycol content and a surfactant or wetting agent content); and wherein the liquid uptake is less than 80 Um3. The wood, timber, or content of the product may be of any species but is preferably 20 of a pine preferably selected from the group Radiata, Slash, Hoop and Southern Yellow, Parana, and Brazilian. While the uptake may exceed 40 L/m3, preferably the uptake is less than 40IUm. The initial step (preferably) may be either a vacuum step of between 0 and -50kPa or a pressure (air pressure) step of between 0 and 100kPa. Either the vacuum or pressure 25 preferably should be held for between 0 and 10 minutes. Preferably the wood, timber or product prior to the at least one vacuum cycle is at a moisture content of less than 30% and more preferably less than 20% w water/w dry timber. The timber can have been subject to kiln or other drying such that the moisture is at that level but the treatment will work on material that has a moisture content of less than 30% w water / 30 w dry timber. Preferably the composition comprises or includesat least - water as at leastthe primary liquid carrier present -4 - a glycol content as a secondary liquid presentoptionally a wetting agent or surfactant (e.g. amine oxides) - at least one biocidal (e.g. antifungal or insecticidal) or other timber protecting agent dissolved in, suspended in and/or emulsified in the liquid carrier. 5 The concentration of the treatment solution or composition is preferably set at such a level that at the end of the treatment cycle, based on the uptake achieved by the cycle used, the retention of the active ingredients is higher than the minimum level required to prevent timber degradation by decay or insects/termites as appropriate, e.g. in the case of the borate/boric acids solution, a composition concentration of about 16%m/v (Boric Acid 10 Equivalence-BAE basis) with an average uptake of 40 Im 3 to ensure at least the required retention level of 0.4%m/m as required by NZS 3640. The time the aqueous composition is in contact with the wood will vary depending on the uptake required but is typically 1 - 10 minutes. The mandatory content of the aqueous composition is that the majority solvent or 15 composition component be water and there be a fungicide or insecticide content, or both, in the composition. The preservative is made available to the wood at pressures between -50kPa and +100kPa. During the filling of the vessel it may be beneficial to compensate for the increasing 20 hydrostatic head, e.g. if the charge height is 1.2m high and the fluid specific gravity is 1.10, there would need to be a 13 kPa reduction in air pressure during filling to offset this. The treated timber should at the completion of the treatment process have a moisture content of less than 25% but ideally less than 20%. Dimensional changes should be no greater than 2mm in either cross-sectional dimension. 25 Preferably the wood, timber or product after impregnation is at a moisture content of less than 20% w water/w dry timber. The timber can be of any suitable cross-sectional dimensions. A vacuum may be applied or reapplied when the timber is no longer exposed to the composition. This is not a critical step in the process. A final vacuum of anywhere between 0 30 and -95kPa held for anywhere from 0 - 60 minutes could be used. The liquid based biocidal and/or preservative composition includes a glycol (eg, preferably monoethylene glycol) but the majority of all liquid present is water.

-5 In another aspect the invention consists in a method of protecting wood, lumber or timber or cellulosic ("material") (e.g. such as timber previously described) which comprises or includes subjecting the material to be treated to at least a partial vacuum, and 5 exposing the material to an aqueous biocidal treatment composition at a pressure or pressures of at least about atmospheric pressure or above, (and (optionally) subjecting the material, when no longer to external exposure to such composition, to at least a partial vacuum, wherein the exposure is such that there is an uptake of less than 80 IJm 3 of the 10 aqueous composition (more preferably less than 40 IJm 3 ); and wherein whilst the aqueous composition has a biocidal agent present and has (i) a glycol biocidal content or (ii) both a glycol content and a wetting agent or surfactant present, water accounts for at least 50% of the liquid content. Preferably said composition is biocidal and preferably comprises an antifungal 15 species in a water carrier (which optionally may includes at least one other liquid and may include a wetting agent or surfactant, the liquid composition preferably no including any resin nor curing agent). Preferably the exposure is a single exposure but can be multiple exposures (e.g. after pressure reductions, etc). 20 Preferably the fungicidal active is a boron based active, CCA, ACQ, azoles including tebuconazole, propiconazole, cyproconazole, prochloraz and other triazoles, oxine copper IPBC, tributyltin, copper compounds and zinc compounds in either solution form or suspended particle form, copper or zinc naphthenate or the like and may be any combination of any such actives. 25 Preferably the insecticidal active is a synthetic pyrethroid such as permethrin, deltamethrin, cypermethrin or bifenthrin or other such insecticides such as imidachloprid, fipronil and chloropyrofos and may be any combination of any such actives or in combination with any fungicide. In one preferred form of the present invention the material being treated is 30 dimensioned wood, dimensioned lumber or dimensioned timber and the resultant moisture content is less than 20% w water/w dry timber after treatment so as to maintain the dimensions of the material treated to substantially those immediately prior to treatment.

-6 Preferably the material being treated both prior to and post exposure is at less than 20% w water/w dry timber. Optionally the active is a boron active, such as is appropriate for framing. Preferably the impregnation is of a conifer species wood and preferably a pine. 5 Preferred pines are Radiata, Slash, Hoop, Parana, Brazilian and Southern Yellow. The produce may be used with another conifer (e.g. Douglas fir or spruce) but we prefer the procedure for pines and particular the pine types specified. Alternatively if the impregnation is with an ACQ active the loading is to achieve the H3 loading of about 0.45% m/m in the cross section. 10 Preferably the concentration of active and the actives chosen for the load uptake of liquid which is the carrier therefor will result in retention levels of the active(s) in the material above the minimum required to protect the timber against decay, insect and, where required, termite attack. Accordingly the examples hereinafter discussed with respect to boron and ACQ are merely illustrative. 15 Preferably the formulation does not include any resins or curable agents. The procedure is preferably merely one whereby there is transport into the material being treated of the requisite biocidal active. The treatment conditions are preferably determined by the up take and concentration of actives so that a required penetration is achieved. 20 The invention is also product or timber that has been subject to a method or process of the present invention. As used herein "dimensioned" means or includes at least of a cross section of desired dimensions. As used herein "biocidal" includes species of active(s) able to discourage degradation 25 whether by fungal entities, insects, etc. As used herein the term "and/or" means "and" or "or", or both. As used herein the term "(s)" following a noun includes, as might be appropriate, the singular or plural forms of that noun. This invention may also be said broadly to consist in the parts, elements and features 30 referred to or indicated in the specification of the application, individually or collectively, and any or all combinations of any two or more of said parts, elements or features, and where specific integers are mentioned herein which have known equivalents in the art to which this -7 invention relates, such known equivalents are deemed to be incorporated herein as if individually set forth. The present invention will now be described with reference to the following examples and drawings. 5 BRIEF DESCRIPTION OF DRAWING In the drawing in which Figure 1 is a plot of Pressure against Time for a preferred embodiment of the process. We have developed a treatment cycle that enables the use of waterborne preservative systems to achieve low full sapwood penetration in kiln dried timber with uptakes preferably 10 less than 40 IJm3. Previously only LOSP (white spirits based) preservative systems have been used at such low uptakes and still achieve full sapwood penetration. Traditionally water borne preservative systems have required uptakes of >100 LJm3 and more often >200LJm3 to meet the sapwood penetration requirements. 15 We have developed a system that enables the use of low uptake cycles with water borne systems thus enabling us to achieve the benefits of LOSP systems (no or little timber swelling during treatment and no or little increase in moisture content) with the benefits of a water based system (no solvent odour, and no hold times after treatment prior to dispatch or painting). 20 Figure 1 represents outlines the basics of the treatment cycle: In Figure 1 there is depicted (a) The initial vacuum or air pressure to which the timber or other material is exposed to (b) The length of time for which the initial vacuum or air pressure is held and 25 during which time the preservative is pumped into the cylinder (c) The increase in pressure (hydraulic) (d) The length of time for which the pressure is held (e) Emptying of cylinder either by pumping out or gravity (f) Final vacuum level of between 0 and -95 kPa 30 (g) Length of final vacuum -8 The system preferably involves the use of specific treatment cycles and/or preferably involves use of surfactants/wetting agents in the preservative solution to enable the low uptake cycles to achieve the full sapwood penetration of preservative required. Preservative system: Preservative systems that are water based or whose 5 predominant solvent component is water. Specifically boron containing systems can be employed. Other systems such as boron based active, CCA, ACQ, azoles including tebuconazole, propiconazole, cyproconazole, prochloraz and other triazoles, oxine copper IPBC, tributyltin, copper compounds and zinc compounds in either solution form or suspended particle form, copper or zinc naphthenate or the like and may be any combination 10 of any such actives can also be employed. The preservative system may, but not essentially, contain a suitable wetting agent or surfactant at a level between 0.1 and 20% by weight. The preservative system may be heated or used at ambient temperature. The treatment cycle used preferably should be: 15 - Initial vacuum/pressure step. Pressure to be between -50kPa and 100kPa and held for a period of time (e.g. 2 minutes). - Flood vessel under the vacuum or pressure level used initially. - Release vacuum/pressure to atmospheric and allow timber to soak for between 1 and 60 minutes or optionally apply hydraulic pressure up to 200 kPa. 20 - Empty vessel. - Final vacuum of any level held for between 0 and 60 mins. - Release vacuum and drain cylinder. The wood that is to be treated can be any species and should be conditioned to a moisture content of less than 30%. Final preservative uptake in the wood will be less than 80 25 LJm3 but ideally less than 40 ILJm3. All product treated by the aforementioned specification is also covered. Example 1 Pre-cut studs 2.330m long 90 x 45 mm were measured for original width and thickness 30 using digital callipers. A diluted boron-glycol solution was prepared using Boracol 200RH and water; this contained 16% m/v boric acid equivalent (BAE) plus a red dye. The process used was: -9 - Draw initial vacuum and hold 2 minutes - Flood vessel under vacuum - Release vacuum to atmospheric and soak 2 minutes - Empty vessel using pump 5 - Draw final vacuum -85 kPa and hold 15 minutes - Release vacuum and drain residual fluid Some packs included a wetting agent (Silwet) at 0.67% v/v. Packs were weighed before and after treatment using 3000kg +/- 1kg calibrated weigh bars to allow uptake to be calculated. Solution density was taken as 1.14 g/mL. 10 10 samples per pack were taken immediately after treatment from the middle of the pack. These were measured for width and thickness using the digital calipers. Samples were then analysed samples for boron loadings in cross-section and core of sapwood. This also included a penetration spot-test and determination of moisture content. Results 15 Net Uptake Initial Wetting Net uptake Charge Pack Vacuum Strapping Agent I1m3 1 A -30 kPa loose strap none 57 2 B -20 kPa loose strap none 44 3 C -20 kPa loose strap SX 41 4 D -20 kPa orig strap SX 30 5 E -15 kPa orig strap SX 26 -10 Swelling Average Swell Untreated A B C D E Width 90.6mm +1.9mm +1.4mm +0.6mm +0.2mm +0.6mm Thickness 45.2mm +1.2mm +0.7mm +0.5mm +0.3mm +0.4mm Retention (targeting 0.4% in cross-section, 0.04% in central 1/9 ) Pack A Cross-section Core MC % BAE m/m MC % BAE m/m Mean 16% 2.09 11% 1.48 Minimum 14% 1.62 7% 0.42 Maximum 20% 2.85 15% 3.01 % Complying 100% 100% Pack B Mean 16% 1.55 9% 0.65 Minimum 12% 1.18 7% 0.11 Maximum 24% 2.57 12% 1.18 % Complying 100% 100% Pack C Mean 16% 1.19 13% 0.63 Minimum 12% 0.84 7% 0.09 Maximum 19% 1.58 16% 1.42 % Complying 100% 100% - 11 Pack D Mean 14% 0.98 11% 0.37 Minimum 10% 0.21 7% 0.00 Maximum 18% 1.66 16% 0.87 % Complying 100% 80% Pack E Mean 11% 0.69 12% 0.30 Minimum 9% 0.42 9% 0.03 Maximum 14% 1.01 13% 0.78 % Complying 100% 90% Example 2 Pre-cut studs 2.330m long 90 x 45 mm were weighed before and after treatment. A 5 solution containing ACQ and monoethyloene glycol or a standard ACQ in water solution such that the ACQ concentration was 5% m/v was used. The process used was: - Apply initial pressure to +4OkPa and hold 2 minutes - Flood vessel under +4OkPa pressure 10 - Increase pressure to 100kPa and hold for 2 minutes - Empty vessel under gravity - Draw final vacuum -85 kPa and hold 15 minutes - Release vacuum and drain residual fluid 6 samples were taken immediately after treatment and weighed. 15 Samples were tested for copper penetration.

-12 Results Net Uptake (a) ACQ in MEG Net uptake Sample L/m3 1 23 2 16 3 20 4 43 5 24 6 32 5 (b) ACQ in water Net uptake Sample L/m3 1 42 2 32 3 47 4 41 5 68 6 41 Example 3 Pre-cut studs 2.330m long 90 x 45 mm were used. A solution containing tebuconazole and propiconazole in a 1:1 ratio. The product is a microemulsion formulation commercially 10 available as Protim E415 that not only contains the actives but also a number of surfactants - 13 and emulsifiers to emulsify the two azoles in the water based system. Two treatment cycles were trialed. The process used was: - Apply initial pressure to +4OkPa in the first charge and +70 kPa in the second 5 and hold 2 minutes - Flood vessel under +4OkPa and +70kPa in the second treatment pressure - Increase pressure to 100kPa and hold for 2 minutes - Empty vessel under gravity - Draw final vacuum -85 kPa and hold 15 minutes 10 - Release vacuum and drain residual fluid Samples from the charge were taken and the central 1 /9h of the boards analysed qualitatively to determine the presence of both the propiconazole and tebuconazole. In all cases the presence of both tebuconazole and propiconazole was detected in the central 1

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9 th of 15 the sapwood indicating full sapwood penetration. Example 4 End sealed matched samples (500 x 90 x 45mm) of untreated MGP12 Radiata Pine framing were prepared. Each charge contained 16 matched samples. A 9%m/v CCA solution 20 was prepared from CCA Oxide. The schedules used are shown below. Charge Solution Initial Pressure Final Pressure Differential 1 9% CCA Oxide 50 too 50 2 9% CCA Oxide 100 130 30 3 9% CCA Oxide 100 150 50 4 9% CCA Oxide 100 180 80 - 14 Boards were weighed before and after treatment to allow uptake to be calculated. 6 samples were taken immediately after treatment and weighed. Samples were tested for copper penetration. 5 Results A summary of the average uptake and dimension changes are shown below. Average Uptake (lIn3) Schedule 50100 100130 100150 100180 CCA 67.1 56.0 75.9 97.9 Average Width Change (mm) Schedule 50100 100 130 100 150 100 180 CCA 2.5 2.3 2.9 3.0 Average Thickness Change (mm) Schedule 50100 100 130 100150 100180 CCA 1.1 1.1 1.2 1.2 Penetration** Schedule 50100 100 130 100150 100 180 CCA Marginal Fail Pass Pass ** Pass = >90% of samples with complete sapwood penetration 10 Some Double Vac treatments were done using CCA solutions concentrations suitable to achieve the required retention based on the expected uptake of preservative using the - 15 various treatment cycles to establish whether complete penetration could be obtained. The width, thickness and uptake results are shown below: Schedule Width Thickness Uptake Penetration Double Vac (MM) (mm) 1/n3 -15 1.711 0.902 49.7 Fail -20 2.457 1.102 60.3 Fail -25 2.437 1.097 66.1 Fail -30 2.513 1.089 71.2 Fail 5 The double vac process with CCA solutions shows increasing uptake with increasing pressure differential, however even at -30kPa, with uptakes of 71IJm3, penetration failed significantly. 10

Claims (25)

1. A process for treating dimensioned wood, dimensioned lumber or dimensioned timber ("timber") or veneer or particle based products or reconstituted wood products or other cellulosic materials ("product"), said process comprising or including 5 impregnating the timber or product to its core using a pressure differential or pressure differentials (ie. vacuum/pressure and/or pressure/pressure) over one or more composition exposure time(s), wherein the composition to which the timber or product is exposed for uptake is a liquid based composition having a biocidal and/or preservative action; 10 and wherein the liquid based composition is at least primarily water based but does include (i) a glycol content or (ii) a glycol content and a surfactant or a wetting agent;, and wherein the liquid uptake is less than 80 Lm 3 .

2. A process of claim 1 using at least one vacuum step.

3. A process of any one of the preceding claims wherein the wood, timber or content of 15 the product is of a conifer.

4. A process of claim 3 wherein the conifer is a pine.

5. A process of claim 4 wherein the pine is selected from the group Radiata, Slash, Hoop and Southern Yellow.

6. A process of any one of the preceding claims wherein the uptake is less than 40L/m 3 . 20

7. A process of any one of the preceding claims wherein there is an initial step of between 0 and -50kPa.

8. A process of any one of the preceding claims wherein there is a pressure (air pressure) step of between 0 and 100kPa.

9. A process of claim 7 or 8, or both claims 7 and 8, wherein the vacuum and/or 25 pressure is or is each held for between 0 and 10 minutes.

10. A process of any one of the preceding claims wherein timber or product at commencement of the process and prior to any vacuum step is at a moisture content of less than 30% w water / w dry timber or product.

11. A process of claim 10 wherein the moisture content at commencement is less than 30 20% w water/w dry timber or product.

12. A process of claim 10 or 11 wherein the timber or product has been subject to kiln drying. - 17

13. A process of any one of the preceding claims wherein the composition comprises or includes at least - water as at least the primary liquid carrier - monoethylene glycol 5 - a wetting agent or surfactant - at least one biocidat or other timber protecting agent dissolved in, suspended in and/or emulsified in the water carrier.

14. A process of any one of the preceding claims wherein the concentration of the treatment solution is set at such a level that at the end of the treatment cycle, based on the 10 uptake of solution achieved by the cycle used, the retention of the active ingredient or ingredients is higher than the minimum level required to prevent timber degradation (e.g. by decay and/or insects/termites as appropriate).

15. A process of any one of the preceding claims wherein the composition is a boron solution, the solution concentration be of about 16%m/v (BAE basis) with an average uptake 15 of 40 IJm 3 to ensure at least the required retention level of 0.4%m/m as required by NZS

3640.

16. A process of any one of the preceding claims wherein the time the composition is in contact with the wood is from 1 to 10 minutes.

17. A process of any one of the preceding claims wherein the composition has water as at 20 least the majority solvent component for a fungicide or insecticide, or both.

18. A process of any one of the preceding claims wherein the preservative is made available to the timber or product at pressures between -50kPa and +100kPa.

19. A process of any one of the preceding claims wherein the treated timber or product at the completion of the treatment process has a moisture content of less than 25% w water/w 25 dry timber or product without any drying post impregnation.

20. A process of claim 19 wherein the end of treatment moisture content is less than 20% w water/w dry timber or product.

21. A process of any one of the preceding claims wherein dimensional changes between the timber or product prior to and post the treatment are no greater than 2mm in any or either 30 cross-sectional dimension.

22. A process of any one of the preceding claims wherein a vacuum is applied or reapplied ("the final vacuum") when the timber or product is no longer exposed to the composition. - 18

23. A process of claim 22 wherein the final vacuum is between 0 and -95kPa held for from 0 - 60 minutes.

24. A process of any one of the preceding claims wherein the liquid based biocidal and/or preservative composition includes glycol but the majority of all liquid present is water. 5 25. A method of protecting wood, lumber or timber ("material"), which comprises or includes subjecting the material to be treated to at least a partial vacuum, and exposing the material to an aqueous biocidal treatment composition at a pressure or pressures of at least about atmospheric pressure or above, 10 (and optionally subjecting the material, when no longer to external exposure to such composition, to at least a partial vacuum); wherein the exposure is such that there is an uptake of less than 80 Um 3 of the aqueous composition; and whereinthe aqueous composition, whilst the aqueous composition has a biocidal 15 agent present and has (i) a glycol present or (ii) both a glycol and a wetting agent or surfactant present, water accounts for at least 50% of the liquid content. 26. A method of claim 25 wherein the uptake is less than 40 U'm 3 ). 27. A method of claim 25 or 26 wherein the composition has an antifungal species in a water carrier. 20 28. A method of claim 27 wherein the composition includes at least one other liquid. 29. A method of any one of claims 25 to 28 wherein the composition includes a wetting agent or surfactant. 30. A method of any one of claims 25 to 29 wherein the composition does not include any resin nor curing agent.

25 31. A method of any one of claims 25 to 30 wherein the exposure to the composition is a single exposure. 32. A method of any one of claims 25 to 30 wherein the exposure is multiple exposures. 33. A method of any one of the claims 25 to 32 wherein the composition has a fungicidal active selected from a boron based active, CCA, ACQ, azoles, oxine copper, IPBC, 30 tributyltin, copper or zinc naphthenate, or any combination of any such actives. 34. A method of claim 33 wherein the active is a boron active. 35. A method of claim 33 or 34 wherein the active is an ACQ active. - 19 36. A method of any one of claims 25 to 25 wherein the composition has the insecticidal active selected from a synthetic pyrethroid (such as permethrin, deltamethrin, cypermethrin or bifenthrin) or imidachloprid, any combination thereof. 37. A method of any one of claims 25 to 36 wherein the material being treated is 5 dimensioned wood, dimensioned lumber or dimensioned timber and the resultant moisture content is less than 20% w water/w dry material after treatment so as to maintain the dimensions of the material treated to substantially those immediately prior to treatment. 38. A method of any one of claims 25 to 37 wherein the material being treated both prior to and post exposure is at less than 20% w water/w dry material. 10 39. A method of any one of claims 25 to 38 wherein impregnation is of a conifer species wood. 40. A method of claim 39 wherein the wood is of a pine. 41. A method of claim 40 wherein the pine is one of Radiata, Slash, Hoop and Southern Yellow. 15 42. A method of claim 39 wherein the wood is of Douglas fir or spruce. 43. A method of claim 33 or 34 wherein the loading is to achieve the H3 loading of about 0.45% m/m in the cross section. 44. A method of any one of claims 25 to 43 wherein the concentration of active and the actives chosen for the load uptake of liquid which is the carrier therefor will result in retention 20 levels of the active(s) in the material above the minimum required to protect the timber against decay, insect and, where required, termite attack. 45. A method of any one of claims 25 to 44 wherein glycol is present as part of the liquid content of the aqueous treatment composition. 46. A product, timber or material that has been subject to a process or method of any 25 one of the preceding claims.